Canada
Optimal Design and Operation of Dual-Ejector PEMFC Hydrogen Supply and Circulation System
Jul 2022
Publication
A proton exchange membrane fuel cell (PEMFC) system requires an adequate hydrogen supply and circulation to achieve its expected performance and operating life. An ejector-based hydrogen circulation system can reduce the operating and maintenance costs noise and parasitic power consumption by eliminating the recirculation pump. However the ejector’s hydrogen entrainment capability restricted by its geometric parameters and flow control variability can only operate properly within a relatively narrow range of fuel cell output power. This research introduced the optimal design and operation control methods of a dual-ejector hydrogen supply/circulation system to support the full range of PEMFC system operations. The technique was demonstrated on a 70 kW PEMFC stack with an effective hydrogen entrainment ratio covering 8% to 100% of its output power. The optimal geometry design ensured each ejector covered a specific output power range with maximized entrainment capability. Furthermore the optimal control of hydrogen flow and the two ejectors’ opening and closing times minimized the anode gas pressure fluctuation and reduced the potential harm to the PEMFC’s operation life. The optimizations were based on dedicated computational fluid dynamics (CFD) and system dynamics models and simulations. Bench tests of the resulting ejector-based hydrogen supply/circulation system verified the simulation and optimization results.
Large-Scale Hydrogen Production Systems Using Marine Renewable Energies: State-of-the-Art
Dec 2023
Publication
To achieve a more ecologically friendly energy transition by the year 2050 under the European “green” accord hydrogen has recently gained significant scientific interest due to its efficiency as an energy carrier. This paper focuses on large-scale hydrogen production systems based on marine renewable-energy-based wind turbines and tidal turbines. The paper reviews the different technologies of hydrogen production using water electrolyzers energy storage unit base hydrogen vectors and fuel cells (FC). The focus is on large-scale hydrogen production systems using marine renewable energies. This study compares electrolyzers energy storage units and FC technologies with the main factors considered being cost sustainability and efficiency. Furthermore a review of aging models of electrolyzers and FCs based on electrical circuit models is drawn from the literature and presented including characterization methods of the model components and the parameters extraction methods using a dynamic current profile. In addition industrial projects for producing hydrogen from renewable energies that have already been completed or are now in progress are examined. The paper is concluded through a summary of recent hydrogen production and energy storage advances as well as some applications. Perspectives on enhancing the sustainability and efficiency of hydrogen production systems are also proposed and discussed. This paper provides a review of behavioral aging models of electrolyzers and FCs when integrated into hydrogen production systems as this is crucial for their successful deployment in an ever-changing energy context. We also review the EU’s potential for renewable energy analysis. In summary this study provides valuable information for research and industry stakeholders aiming to promote a sustainable and environmentally friendly energy transition.
A Review on the Long-Term Performance of Proton Exchange Membrane Fuel Cells: From Degradation Modeling to the Effects of Bipolar Plates, Sealings, and Contaminants
Jul 2022
Publication
Proton-exchange membrane fuel cells (PEMFCs) are regarded as promising alternatives to internal combustion engines (ICEs) to reduce pollution. Recent research on PEMFCs focuses on achieving higher power densities reducing the refueling time mitigating the final price and decreasing the degradations to facilitate the commercialization of hydrogen mobility. The design of bipolar plates and compression kits in addition to their coating can effectively improve performance increase durability and support water/thermal management. Past reviews usually focused on the specific aspect which can hardly provide readers with a complete picture of the key challenges facing and advances in the long-term performance of PEMFCs. This paper aims to deliver a comprehensive source to review from both experimental analytical and numerical viewpoints design challenges degradation modeling protective coatings for bipolar plates and key operational challenges facing and solutions to the stack to prevent contamination. The significant research gaps in the long-term performance of PEMFCs are identified as (1) improved bipolar-plate design and coating (2) the optimization of the design of sealing and compression kits to reduce mechanical stresses and (3) stack degradation regarding fuel contamination and dynamic operation.
Innovations in Clean Energy Technologies: A Comprehensive Exploration of Research at the Clean Energy Technologies Research Institute, University of Regina
Nov 2024
Publication
The Clean Energy Technology Research Institute (CETRI) at the University of Regina Canada serves as a collaborative hub where a dynamic team of researchers industry leaders innovators and educators come together to tackle the urgent challenges of climate change and the advancement of clean energy technologies. Specializing in low-carbon and carbon-free clean energy research CETRI adopts a unique approach that encompasses feasibility studies bench-scale and pilot-plant testing and pre-commercial demonstrations all consolidated under one roof. This holistic model distinguishes CETRI fostering a diverse and inclusive environment for technical scientific and hands-on learning experiences. With a CAD 3.3 million pre-commercial carbon capture demonstration plant capable of capturing 1 tonne of CO2 per day and a feed-flexible hydrogen demonstration pilot plant producing 6 kg of hydrogen daily CETRI emerges as a pivotal force in advancing innovative reliable and cost-competitive clean energy solutions essential for a safe prolific and sustainable world. This paper provides a comprehensive overview of the diverse and impactful research carried out in the center spanning various areas including decarbonization zeroemission hydrogen technologies carbon (CO2 ) capture utilization and storage the conversion of waste into renewable fuels and chemicals and emerging technologies such as small modular nuclear reactors and microgrids.
Component and System Levels Limitations in Power-Hydrogen Systems: Analytical Review
Jun 2024
Publication
This study identifies limitations and research and development (R&D) gaps at both the component and system levels for hydrogen energy systems (HESs) and specifies how these limitations impact HES adoption within the electric power system (EPS) decarbonization roadmap. To trace these limitations and potential solutions an analytical review is conducted in electrification and integration of HESs renewable energy sources (RESs) and multi-carrier energy systems (MCESs) in sequence. The study also innovatively categorizes HES integration challenges into component and system levels. At the component level technological aspects of hydrogen generation storage transportation and refueling are explored. At the system level HES coordination hydrogen market frameworks and adoption challenges are evaluated. Findings highlight R&D gaps including misalignment between HES operational targets and techno-economic development integration insufficiency model deficiencies and challenges in operational complexity. This study provides insights for sustainable energy integration by supporting the transition to a decarbonized energy system.
An Overview of the Photocatalytic Water Splitting over Suspended Particles
Jan 2021
Publication
The conversion of solar to chemical energy is one of the central processes considered in the emerging renewable energy economy. Hydrogen production from water splitting over particulate semiconductor catalysts has often been proposed as a simple and a cost-effective method for largescale production. In this review we summarize the basic concepts of the overall water splitting (in the absence of sacrificial agents) using particulate photocatalysts with a focus on their synthetic methods and the role of the so-called “co-catalysts”. Then a focus is then given on improving light absorption in which the Z-scheme concept and the overall system efficiency are discussed. A section on reactor design and cost of the overall technology is given where the possibility of the different technologies to be deployed at a commercial scale and the considerable challenges ahead are discussed. To date the highest reported efficiency of any of these systems is at least one order of magnitude lower than that deserving consideration for practical applications.
Towards Hydrogen-powered Electric Aircraft: Physics-informed Machine Learning Based Multi-domain Modelling and Real-time Digital Twin Emulation on FPGA
Mar 2025
Publication
In response to environmental concerns related to carbon and nitrogen emissions hydrogen-powered aircraft (HPA) are poised for significant development over the coming decades driven by advances in power electronics technology. However HPA systems present complex multi-domain challenges encompassing electrical hydraulic mechanical and chemical disciplines necessitating efficient modeling and robust validation platforms. This paper introduces a physics-informed machine learning (PIML) approach for multi-domain HPA system modeling enhanced by hardware accelerated parallel hardware emulation to construct a real-time digital twin. It delves into the physical analysis of various HPA subsystems whose equations form the basis for both traditional numerical solution methods like Euler’s and Runge-Kutta methods (RKM) as well as the physics-informed neural networks (PINN) components developed herein. By comparing physics-feature neural networks (PFNN) and PINN with conventional neural network strategies this paper elucidates their advantages and limitations in practical applications. The final implementation on the Xilinx® UltraScale+™ VCU128 FPGA platform showcases the PIML method’s high efficiency accuracy data independence and adherence to established physical laws demonstrating its potential for advancing real-time multi-domain HPA emulation.
Recent Advancements of Polymeric Membranes in Anion Exchange Membrane Water Electrolyzer (AEMWE): A Critical Review
Apr 2023
Publication
The formation of green hydrogen from water electrolysis is one of the supreme methodologies for understanding the well-organized consumption of sporadic renewable energies and the carbon-free future. Among the different electrolysis techniques the evolving anion exchange membrane water electrolysis (AEMWE) shows the utmost promise for manufacturing green hydrogen in an inexpensive way. In the present review we establish the most current and noteworthy achievements of AEMWE which include the advancements in increasing the ionic conductivity and understanding the mechanism of degradation of AEM and the most important topics regarding the designing of the electrocatalyst. The crucial issues that affect the AEMWE behavior are highlighted and future constraints and openings are also discussed. Furthermore this review article provides the appreciated strategies for producing extremely dynamic and robust electrocatalysts and evolving the construction of AEMWE equipment.
Hydrogen Behavior and Mitigation Measures: State of Knowledge and Database from Nuclear Community
Sep 2023
Publication
Hydrogen has become a key enabler for decarbonization as countries pledge to reach net zero carbon emissions by 2050. With hydrogen infrastructure expanding rapidly beyond its established applications there is a requirement for robust safety practices solutions and regulations. Since the 1980s considerable efforts have been undertaken by the nuclear community to address hydrogen safety issues because in severe accidents of water-cooled nuclear reactors a large amount of hydrogen can be produced from the oxidation of metallic components with steam. As evidenced in the Fukushima accident hydrogen combustion can cause severe damage to reactor building structures promoting the release of radioactive fission products to the environment. A number of large-scale experiments were conducted in the framework of national and international projects to understand the hydrogen dispersion and combustion behaviour under postulated accidental conditions. Empirical engineering models and numerical codes were developed and validated for safety analysis. Hydrogen recombiners known as Passive Autocatalytic Recombiner (PAR) were developed and have been widely installed in nuclear containments to mitigate hydrogen risk. Complementary actions and strategies were established as part of severe accident management guidelines to prevent or limit the consequences of hydrogen explosions. In addition hydrogen monitoring systems were developed and implemented in nuclear power plants. The experience and knowledge gained from the nuclear community on hydrogen safety is valuable and applicable for other industries involving hydrogen production transport storage and use.
Recent Advances in Power-to-X Technology for the Production of Fuels and Chemicals
Jun 2019
Publication
Environmental issues related to greenhouse gas emissions are progressively pushing the transition toward fossil-free energy scenario in which renewable energies such as solar and wind power will unavoidably play a key role. However for this transition to succeed significant issues related to renewable energy storage have to be addressed. Power-to-X (PtX) technologies have gained increased attention since they actually convert renewable electricity to chemicals and fuels that can be more easily stored and transported. H2 production through water electrolysis is a promising approach since it leads to the production of a sustainable fuel that can be used directly in hydrogen fuel cells or to reduce carbon dioxide (CO2) in chemicals and fuels compatible with the existing infrastructure for production and transportation. CO2 electrochemical reduction is also an interesting approach allowing the direct conversion of CO2 into value-added products using renewable electricity. In this review attention will be given to technologies for sustainable H2 production focusing on water electrolysis using renewable energy as well as on its remaining challenges for large scale production and integration with other technologies. Furthermore recent advances on PtX technologies for the production of key chemicals (formic acid formaldehyde methanol and methane) and fuels (gasoline diesel and jet fuel) will also be discussed with focus on two main pathways: CO2 hydrogenation and CO2 electrochemical reduction.
Outlook and Challenges for Hydrogen Storage in Nanoporous Materials
Feb 2016
Publication
Darren P. Broom,
Colin Webb,
Katherine Hurst,
P. A. Parilla,
Thomas Gennett,
C. M. Brown,
Renju Zacharia,
E. Tylianakis,
E. Klontzas,
George E. Froudakis,
Th. A. Steriotis,
Pantelis N. Trikalitis,
Donald L. Anton,
B. Hardy,
David A. Tamburello,
Claudio Corgnale,
B. A. van Hassel,
D. Cossement,
Richard Chahine and
Michael Hirscher
Considerable progress has been made recently in the use of nanoporous materials for hydrogen storage. In this article the current status of the field and future challenges are discussed ranging from important open fundamental questions such as the density and volume of the adsorbed phase and its relationship to overall storage capacity to the development of new functional materials and complete storage system design. With regard to fundamentals the use of neutron scattering to study adsorbed H2 suitable adsorption isotherm equations and the accurate computational modelling and simulation of H2 adsorption are discussed. The new materials covered include flexible metal–organic frameworks core–shell materials and porous organic cage compounds. The article concludes with a discussion of the experimental investigation of real adsorptive hydrogen storage tanks the improvement in the thermal conductivity of storage beds and new storage system concepts and designs.
Fracture Toughness Assessment of Pipeline Steels Under Hydrogen Exposure for Blended Gas Applications
Jan 2025
Publication
Hydrogen embrittlement (HE) is a critical concern for pipeline steels particularly as the energy sector explores the feasibility of blending hydrogen with natural gas to reduce carbon emissions. Various mechanical testing methods assess HE with fracture toughness testing offering a quantitative measure of defect impacts on structural safety particularly for cracks arising during manufacturing fabrication or in-service conditions. This study focuses on assessing the fracture toughness of two pipeline steels from an existing natural gas network under varying hydrogen concentrations using double cantilever beam (DCB) fracture tests. A vintage API X52 steel with a ferritic–pearlitic microstructure and a modern API X65 steel with polygonal ferrite and elongated pearlite colonies were selected to represent old and new pipeline materials. Electrochemical hydrogen charging was employed to simulate hydrogen exposure with the charging parameters derived from hydrogen permeation tests. The results highlight the differing impacts of hydrogen on the fracture toughness and crack growth in vintage and modern pipeline steels. These findings are essential for ensuring the safety and integrity of pipelines carrying hydrogen–natural gas blends.
AMHYCO Project - Advances in H2/CO Combustion, Recombination and Containment Modelling
Sep 2023
Publication
During a severe accident in a nuclear power plant one of the potential threats to the containment is the occurrence of energetic combustion events. In modern plants Severe Accident Management Guidelines (SAMG) as well as dedicated mitigation hardware are in place to minimize/mitigate this combustion risk and thus avoid the release of radioactive material into the environment. Advancements in SAMGs are in the focus of AMHYCO an EU-funded Horizon 2020 project officially launched on October 1st 2020. The project consortium consists of 12 organizations (from six European countries and one from Canada) and is coordinated by the Universidad Politécnica de Madrid (UPM). The progress made in the first two years of the AMHYCO project is here presented. A comprehensive bibliographic review has been conducted providing a common foundation to build the knowledge gained during the project. After an extensive set of accident transients simulated both for phases occurring inside and outside the reactor pressure vessel a set of challenging sequences from the combustion risk perspective for different power plant types were identified. At the same time three generic containment models for the three considered reactor designs have been created to provide the full containment analysis simulations with lumped parameter models 3-dimensional containment codes and CFD codes. In order to further consolidate the model base combustion experiments and performance tests on passive auto-catalytic recombiners under explosion prone H2/CO atmospheres were performed at CNRS (France) and FZJ (Germany). Finally it is worth saying that the experimental data and engineering models generated from the AMHYCO project are useful for other industries outside the nuclear one.
Recent Developments on Carbon Neutrality through Carbon Dioxide Capture and Utilization with Clean Hydrogen for Production of Alternative Fuels for Smart Cities
Jul 2024
Publication
This review comprehensively evaluates the integration of solar-powered electrolytic hydrogen (H2) production and captured carbon dioxide (CO2) management for clean fuel production considering all potential steps from H2 production methods to CO2 capture and separation processes. It is expected that the near future will cover CO2-capturing technologies integrated with solar-based H2 production at a commercially viable level and over 5 billion tons of CO2 are expected to be utilized potentially for clean fuel production worldwide in 2050 to achieve carbon-neutral levels. The H2 production out of hydrocarbon-based processes using fossil fuels emits greenhouse gas emissions of 17-38 kg CO2/kg H2. On the other hand . renewable energy based green hydrogen production emits less than 2 kg CO2/kg H2 which makes it really clean and appealing for implementation. In addition capturing CO2 and using for synthesizing alternative fuels with green hydrogen will help generate clean fuels for smart cities. In this regard the most sustainable and promising CO2 capturing method is post-combustion with an adsorption-separation-desorption processes using monoethanolamine adsorbent with high CO2 removal efficiencies from flue gases. Consequently this review article provides perspectives on the potential of integrating CO2-capturing technologies and renewable energy-based H2 production systems for clean production to create sustainable cities and communities.
Parametric Study and Optimization of Hydrogen Production Systems Based on Solar/Wind Hybrid Renewable Energies: A Case Study in Kuqa, China
Jan 2024
Publication
Based on the concept of sustainable development to promote the development and application of renewable energy and enhance the capacity of renewable energy consumption this paper studies the design and optimization of renewable energy hydrogen production systems. For this paper six different scenarios for grid-connected and off-grid renewable energy hydrogen production systems were designed and analyzed economically and technically and the optimal grid-connected and off-grid systems were selected. Subsequently the optimal system solution was optimized by analyzing the impact of the load data and component capacity on the grid dependency of the grid-connected hydrogen production system and the excess power rate of the off-grid hydrogen production system. Based on the simulation results the most matched load data and component capacity of different systems after optimization were determined. The grid-supplied power of the optimized grid-connected hydrogen production system decreased by 3347 kWh and the excess power rate of the off-grid hydrogen production system decreased from 38.6% to 10.3% resulting in a significant improvement in the technical and economic performance of the system.
Role of Flame-expansion Wave Interactions on Burning Rate Enhancement and Flame Acceleration in Hydrogen-air Mixtures
Sep 2023
Publication
Hydrogen flames are much thinner than hydrocarbon flames. They have a higher propensity to wrinkle and are subject to thermo-diffusive instabilities in lean conditions. The large scale experiments of Sherman under partially vented conditions have shown that the transition to detonation is possible with only modest flame acceleration to approximately 200 m/s which is much lower than the commonly accepted limits corresponding to choked flames. At present the reason for this transition is not known. Vented H2-air explosions have also demonstrated the role played by expansion/flame interactions in deforming the flame. The state of the art on flame burning rate enhancement by expansion waves will be provided along with the recent experimental and numerical results of head on interaction of flames with an expansion wave conducted in our group. We show that the expansion wave interaction can generate local burning rate increases by more than an order of magnitude. The role of thermo-diffusive instability is also assessed. The mechanism of flame deformation is via the vorticity generation by the misaligned pressure gradient controlled by the expansion wave and the density gradient of the flame. Expansion waves originating from the unburned gas severely elongate the cells until the flame folds burn out. Expansion waves originating from the burned gas side first invert the flames then elongate them by the same mechanism. The rate of elongation is controlled by the volumetric expansion of the gas and the curvature-enhanced growth.
The Global Shift to Hydrogen and Lessons from Outside Industry
Sep 2023
Publication
The recognition of hydrogen as a technically viable combustion fuel and as an alternative to more carbon intensive technologies for all forms of industrial applications has resulted in significant global interest leading to both public and private investment. As with most shifts in technology public acceptance and its safe production and handling will be key to its growth as a widespread energy vector. Specific properties of hydrogen that may prompt concern from the public and that need to be considered in terms of its use and safe handling include the following:<br/>• Hydrogen in its natural state is a colourless odourless and tasteless gas that is combustible with very low ignition energy burns nearly invisibly and is explosive at a very wide range of concentrations with an oxidate.<br/>• Hydrogen as any other gas except oxygen is an asphyxiant in a confined space.<br/>• Hydrogen is an extremely small molecule and interacts with many materials which over time can alter the physical properties and can lead to embrittlement and failure. Additionally due to the small molecular size its permeation and diffusion characteristics make it more difficult to contain compared to other gases.<br/>As hydrogen production use and storage increases these properties will come under greater scrutiny and may raise questions surrounding the cost/benefit of the technology. Understanding how the public sees this technology in relation to their safety and daily lives is important in hydrogen’s adoption as a low carbon alternative. A review of deployable experience relevant to the handling of hydrogen in other industries will help us to understand the technology and experience necessary for ensuring the success of the scaling up of a hydrogen economy. The social considerations of the impacts should also be examined to consider acceptance of the technology as it moves into the mainstream.
Strategic Analysis of Hydrogen Market Dynamics Across Collaboration Models
Oct 2024
Publication
The global energy landscape is experiencing a transformative shift with an increasing emphasis on sustainable and clean energy sources. Hydrogen remains a promising candidate for decarbonization energy storage and as an alternative fuel. This study explores the landscape of hydrogen pricing and demand dynamics by evaluating three collaboration scenarios: market-based pricing cooperative integration and coordinated decision-making. It incorporates price-sensitive demand environmentally friendly production methods and market penetration effects to provide insights into maximizing market share profitability and sustainability within the hydrogen industry. This study contributes to understanding the complexities of collaboration by analyzing those structures and their role in a fast transition to clean hydrogen production by balancing economic viability and environmental goals. The findings reveal that the cooperative integration strategy is the most effective for sustainable growth increasing green hydrogen’s market share to 19.06 % and highlighting the potential for environmentally conscious hydrogen production. They also suggest that the coordinated decision-making approach enhances profitability through collaborative tariff contracts while balancing economic viability and environmental goals. This study also underscores the importance of strategic pricing mechanisms policy alignment and the role of hydrogen hubs in achieving sustainable growth in the hydrogen sector. By highlighting the uncertainties and potential barriers this research offers actionable guidance for policymakers and industry players in shaping a competitive and sustainable energy marketplace.
Quantitative Risk Assessment for Hydrogen Systems: Model Development and Validation
Sep 2023
Publication
Quantitative Risk Assessment (QRA) is a risk-informed approach that considers past performances and the likelihood of events and distinguishes must-haves from nice-to-haves. Following the approach applied for the HyRAM code developed by the Sandia National Laboratories a QRA toolkit for hydrogen systems was developed using MATLAB by Canadian Nuclear Laboratories (CNL). Based on user inputs for system components and their operating parameters the toolkit calculates the consequence of a hydrogen leak from the system. The fatality likelihood can be estimated from the severity of a person’s exposure to radiant heat flux (from a jet fire) and overpressure (from an explosion). This paper presents a verification and validation exercise by comparing the CNL model predictions with the HyRAM code and available experimental data including a QRA case study for a locomotive. The analysis produces risk contours recommending personnel (employees/public) numbers time spent and safe separation distances near the incident (during maintenance or an accident). The case study demonstrated the importance of hydrogen leak sensors’ reliability for leak detection and isolation. The QRA toolkit calculates a more practical value of the safe separation distance for hydrogen installations and provides evidence to support communication with authorities and other stakeholders for decision-making.
Selection Criteria and Ranking for Sustainable Hydrogen Production Options
Aug 2022
Publication
This paper aims to holistically study hydrogen production options essential for a sustainable and carbon-free future. This study also outlines the benefits and challenges of hydrogen production methods to provide sustainable alternatives to fossil fuels by meeting the global energy demand and net-zero targets. In this study sixteen hydrogen production methods are selected for sustainability investigation based on seven different criteria. The criteria selected in the comparative evaluation cover various dimensions of hydrogen production in terms of economic technical environmental and thermodynamic aspects for better sustainability. The current study results show that steam methane reforming with carbon capture could provide sustainable hydrogen in the near future while the other technologies’ maturity levels increase and the costs decrease. In the medium- and long-terms photonic and thermal-based hydrogen production methods can be the key to sustainable hydrogen production.
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