Germany
Regime-driven Niches and Institutional Entrepreneurs: Adding Hydrogen to Regional Energy Systems in Germany
Nov 2023
Publication
In recent years production and supply of hydrogen has gained significant attention within the German energy transition. This is due to increasingly urgent pressures to mitigate climate change and geopolitical imperatives to substitute natural gas. Hydrogen is seen as an important cross-sectoral energy carrier serving multiple functions including heat production for industry and households fuel for transportation and energy storage for stabilization of electricity supply. In the context of various funding mechanisms on several administrative levels regional value chains for green hydrogen supply are emerging. To date however few studies analyzing regional hydrogen systems exist. Due to its high projected demand of energy sources for heating industrial processes and mobility Germany appears to be a very relevant research area in this emerging field. Situated within the concept of the multi-level perspective this article examines the way how regional “niches” of green hydrogen evolve and how they are organized. The study takes an evolutionary perspective in analyzing processes of embedding green hydrogen infrastructures in regional energy regimes which entered “re-configuration”-pathways. It argues that the congruence of available resources for renewable electricity established networks of institutional entrepreneurs and access to higher level funding are conditions which put incumbent regime-actors in favorable positions to implement green hydrogen niches. Conversely the embedding of green hydrogen infrastructures in regional energy systems is a case in point of how the attributes of niches in particular technological domains can be used to explain the transition pathway entered by a surrounding energy regime.
Challenges and Opportunities for Hydrogen Production from Microalgae
Nov 2015
Publication
The global population is predicted to increase from ~7.3 billion to over 9 billion people by 2050.Together with rising economic growth this is forecast to result in a 50% increase in fueldemand which will have to be met while reducing carbon dioxide (CO 2 ) emissions by 50–80%to maintain social political energy and climate security. This tension between rising fuel demandand the requirement for rapid global decarbonization highlights the need to fast-track thecoordinated development and deployment of efficient cost-effective renewable technologies forthe production of CO 2 neutral energy. Currently only 20% of global energy is provided aselectricity while 80% is provided as fuel. Hydrogen (H 2) is the most advanced CO 2 -free fuel andprovides a ‘common’ energy currency as it can be produced via a range of renewabletechnologies including photovoltaic (PV) wind wave and biological systems such as microalgaeto power the next generation of H 2 fuel cells. Microalgae production systems for carbon-basedfuel (oil and ethanol) are now at the demonstration scale. This review focuses on evaluating thepotential of microalgal technologies for the commercial production of solar-driven H2 fromwater. It summarizes key global technology drivers the potential and theoretical limits ofmicroalgal H2 production systems emerging strategies to engineer next-generation systems andhow these fit into an evolving H 2 economy.
Net Zero Fuel (Mixed Hydrogen and Biofuels) Cement Clinker: Characterisation, Microstructure, and Performance
Oct 2024
Publication
Over 35% of the CO2 associated with cement production comes from operational energy. The cement industry needs alternative fuels to meet its net zero emissions target. This study investigated the influence of hydrogen mixed with biofuels herein designated net zero fuel as an alternative to coal on the clinker quality and performance of cement produced in an industrial cement plant. Scanning electron microscopy X-ray diffraction and nuclear magnetic resonance were coupled to study the clinker mineralogy and polymorphs. Hydration and microstructure development in plain and slag blended cements based on the clinker were compared to commercial cement equivalent. The results revealed a lower alite/belite ratio but a significant proportion of the belite was of the α’H-C2S polymorph. These reacted faster and compensated for the alite/belite ratio. Gel and micro-capillary pores were densified which reduced total porosity and attained comparable strength to the reference plain and blended cement. This study demonstrates that the investigated net zero fuel-produced clinker meets compositional and strength requirements for plain and blended cement providing a feasible pathway for the cement industry to lower its operational carbon significantly.
Does the Public Want Green Hydrogen in Industry? Local and National Acceptance of Methanol and Steel Transitions in Germany
Feb 2025
Publication
Public perceptions might determine the ease of the transition from a fossil-based to a green hydrogen-based production pathway in the industrial sector. The primary objective of this paper is to empirically identify the antecedents of the acceptance of two relevant industrial applications of green hydrogen: green methanol and green steel. The analysis relying on linear regression models utilises survey data from samples of residents near a chemical park and a steel plant (509 and 502 participants respectively) contrasting them with a representative sample of 1502 individuals in Germany. The findings suggest that acceptance of the transitions to green methanol and green steel is high both locally and nationally. In all surveys >59 % of the participants are in favour while the share of those who are opposed to the respective transitions is below 9 %. Key antecedents of acceptance which are conducive in all models relate to individuals’ attitudes towards green hydrogen and perceptions of the legitimacy of the industry actors involved with varying results across legitimacy types. In general the findings were similar across industrial applications and across levels of observation but varied across regions. This study highlights the importance of civil society perceptions and suggests that relationship management efforts aimed at maintaining positive perceptions of industrial hydrogen applications should consider their broader physical and social contexts.
Considering Hydrogen Policies with a Focus on Incentive Compatibility Towards Electricity Grids
Sep 2025
Publication
A lot of countries have recently published updated hydrogen strategies with many of them increasing and renewing their commitment. In parallel corresponding policy mechanisms are increasingly coming into focus with the first ones already having awarded funding contracts to projects and construction being underway. However these policies are usually translated from renewable energy policy without considering the specific risks and uncertainties spillovers and positive externality of operating grid-conducive electrolyzers in electricity grids which are increasingly subjected to electricity supply volatility from renewables. This article details how different aspects of a dedicated hydrogen policy can address the technology’s specific issues from an economic perspective namely funding provision market and technology risk mitigation and the complex relationship with further actors in electricity markets. Results show that compared to renewable energy policy mechanisms need to emphasize the input side more strongly as price risks and intermittency from electricity markets are more prominent than from hydrogen markets. Also it proposes a targeted mechanism to capture the positive externality of mitigating excess electricity in the grid while keeping investment security high. Economic policy should consider such approaches before scaling support and avoiding the design shortcomings experienced with early RE policy.
Repurposing Natural Gas Pipelines for Hydrogen: Limits and Options from a Case Study in Germany
Jul 2024
Publication
We investigate the challenges and options for repurposing existing natural gas pipelines for hydrogen transportation. Challenges of re-purposing are mainly related to safety and due to the risk of hydrogen embrittlement of pipeline steels and the smaller molecular size of the gas. From an economic perspective the lower volumetric energy density of hydrogen compared to natural gas is a challenge. We investigate three pipeline repurposing options in depth: a) no modification to the pipeline but enhanced maintenance b) use of gaseous inhibitors and c) the pipe-in-pipe approach. The levelized costs of transportation of these options are compared for the case of the German Norddeutsche Erdgasleitung (NEL) pipeline. We find a similar cost range for all three options. This indicates that other criteria such as the sunk costs public acceptance and consumer requirements are likely to shape the decision making for gas pipeline repurposing.
Multilateral Governance in a Global Hydrogen Economy: An Overview of Main Actors and Institutions, Key Challenges and Future Pathways
Nov 2024
Publication
This paper explores the current scope and direction of the emerging global governance of hydrogen within the broader context of the energy transition where technological innovation and institutional change intersect. Hydrogen as a critical yet complex energy vector requires coordinated governance efforts to navigate its development effectively. To this end we critically engage with key challenges facing the hydrogen sector and examine how institutional frameworks are addressing these issues. Departing from the broader scholarship on global energy governance we conceptually leverage the socio-technical transition and innovation system liter ature to understand the complexities underpinning the development of the global hydrogen economy. We identify three overarching issue areas pertaining to the nature and role of hydrogen in the global energy system: end-use sector development infrastructure and trade and environmental and socio-economic sustainability. Each of these areas presents distinct challenges to hydrogen’s global governance from stimulating supply and demand to managing geo-economic challenges and establishing comprehensive certification and standards. Through mapping multilateral institutions at the global and regional levels and their main objectives we offer insights into the emerging institutional architecture related to hydrogen and identify potential gaps in current governance. Our findings suggest that while newer hydrogen-specific institutions complement the broader agenda of the main established international organizations the overall global hydrogen structure remains a patchwork of diverse actors and frameworks each addressing hydrogen-related challenges to varying degrees. Our research contributes to a nuanced understanding of global governance in the hydrogen sector and advances scholarly discussions on how institutional and actor dynamics shape the emergence and development of new technologies.
Stability, Change, Formation: Insights into the Media's Role in Shaping Attitudes Toward Green Hydrogen in Germany
Nov 2024
Publication
This study uses a multi-method design to investigate the media’s role in shaping Germans’ attitudes toward green hydrogen. It combines an automatized content analysis of 7649 German newspaper articles published between July 2021 and June 2024 and a three-wave panel survey of the German population conducted between June 2023 and June 2024 with an initial sample of 2701 participants. The findings show that the intensity of media reporting on hydrogen was low compared to other energy-related topics. Nevertheless participants’ assessments of relative topic presence are rather accurate (rho: 0.50–0.80). A considerable number of participants were unable to position themselves toward the potential and challenges of hydrogen (23%–35%). Overall the results indicate that media and communication tend to stabilize or change existing attitudes rather than contribute to the formation or loss of attitudes leading to implications for the communication of relevant stakeholders.
Liquid Hydrogen Pool Evaporation Above Four Different Substrates
Sep 2023
Publication
In the frame of the EC-funded project PRESLHY ten experiments on LH2-pool evaporation above four different substrates have been performed with the POOL-facility on a free field test site. Substrates to be investigated comprised concrete sand water and gravel. Four of the experiments were made with artificial side wind of known direction and known velocity to investigate the influence of side wind on hydrogen evaporation and cloud formation above the LH2-pool. The POOL-facility mainly consists of an insulated stainless-steel box with the dimensions 0.5 x 0.5 x 0.2 m³ that is filled up to half the height (0.1 m) with the respective substrate and LH2. The height of the LH2-pool that forms above the substrate can be determined using the weight of the complete facility which is positioned on a scale. Additionally six thermocouples are located in different heights above the substrate surface to indicate the LH2-level as soon as they are covered with LH2. Further measurement equipment used in the tests comprises temperature measurements inside the substrate and several thermocouples in the unconfined space above the pool where also H2-concentration measurements were performed. Using the sensor information pool evaporation rates for the different substrates were determined. The temperature and concentration measurements above the pool were mainly used to define promising ignition positions for subsequent combustion experiments in which the LH2-spills above the different substrates were ignited.
Numerical Investigations of Hydrogen Release and Dispersion Due to Silane Decomposition in a Ventilated Container
Sep 2023
Publication
In recent years new chemical release agents based on silane are being used in the tire industry. Silane is an inorganic chemical compound consisting of a silicon backbone and hydrogen. Silanes can be thermally decomposed into high-purity silicon and hydrogen. If silane is stored and transported in Intermediate Bulk Containers (IBCs) equipped with safety valves in vented semi-confined spaces such as ISO-Containers hydrogen can be accumulated and become explosive mixture with air. A conservative CFD analysis using the GASFLOW-MPI code has been carried out to assess the hydrogen risk inside the vented containers. Two types of containers with different natural ventilation systems were investigated under various hypothetical accident scenarios. A continuous release of hydrogen due to the chemical decomposition of silane from IBCs was studied as the reference case. The effect of the safety valves on hydrogen accumulation in the container which results in small pulsed releases of hydrogen was investigated. The external effects of the sun and wind on hydrogen distribution and ventilation were also evaluated. The results can provide detailed information on hydrogen dispersion and mixing within the vented enclosures and used to evaluate the hydrogen risks such as flammability. Based on the assumptions used in this study it indicates that the geometry of ventilation openings plays a key role in the efficiency of the indoor air exchange process. In addition the use of safety valves makes it possible to reduce the concentration of hydrogen by volume in air compared to the reference case. The effect of the sun which results in a temperature difference between two container walls allows a strong mixing of hydrogen and air which helps to obtain a concentration lower than both the base case and the case of the pulsed releases. But the best results for the venting process are obtained with the wind that can drive the mixture to the downwind wall vent holes.
Country Risks Analysis for the Development of Green Hydrogen and Synthetic Fuel Sectors in the MENA Region
Nov 2024
Publication
Hydrogen plays a pivotal role in global efforts to decarbonize energy and industrial sectors. The European Union particularly Germany anticipate a significant reliance on hydrogen imports in the medium to long term identifying the Middle East and North Africa (MENA) region as a key potential producer and exporter of green hydrogen and its downstream products. Yet investment risks pose significant challenges to advancing the region’s green hydrogen and synthetic fuel industries. However systematic comparative risk analyses for these sectors across MENA countries remain limited. This study addresses the research gap by conducting a comparative risk assessment for renewable energy and green hydrogen and synthetic fuel development in 17 MENA countries. A comprehensive framework evaluating macro and micro risks was applied along with two contrasting risk scenarios to explore future developments under different risk conditions. The findings reveal that while MENA countries hold promise most face at least moderate risks underscoring the complexity of fostering these industries regionally.
HyPLANT100: Industrialization from Assembly to the Construction Site for Gigawatt Electrolysis
Apr 2024
Publication
The global push for sustainable energy has heightened the demand for green hydrogen which is crucial for decarbonizing heavy industry. However current electrolysis plant capacities are insufficient. This research addresses the challenge through optimizing large-scale electrolysis construction via standardization modularization process optimization and automation. This paper introduces H2Giga a project for mass-producing electrolyzers and HyPLANT100 investigating largescale electrolysis plant structure and construction processes. Modularizing electrolyzers enhances production efficiency and scalability. The integration of AutomationML facilitates seamless information exchange. A digital twin concept enables simulations optimizations and error identification before assembly. While construction site automation provides advantages tasks like connection technologies and handling cables tubes and hoses require pre-assembly. This study identifies key tasks suitable for automation and estimating required components. The Enapter Multicore electrolyzer serves as a case study showcasing robotic technology for tube fittings. In conclusion this research underscores the significance of standardization modularization and automation in boosting the electrolysis production capacity for green hydrogen contributing to ongoing efforts in decarbonizing the industrial sector and advancing the global energy transition.
Advancing Renewable Energy: Strategic Modeling and Optimization of Flywheel and Hydrogen-based Energy System
Sep 2024
Publication
This study introduces a hybrid energy storage system that combines advanced flywheel technology with hydrogen fuel cells and electrolyzers to address the variability inherent in renewable energy sources like solar and wind. Flywheels provide quick energy dispatch to meet peak demand while hydrogen fuel cells offer sustained power over extended periods. The research explores the strategic integration of these technologies within a hybrid photovoltaic (PV)-flywheel‑hydrogen framework aiming to stabilize the power supply. To evaluate the impact of flywheel integration on system sizing and load fluctuations simulations were conducted both before and after the flywheel integration. The inclusion of the flywheel resulted in a more balanced energy production and consumption profile across different seasons notably reducing the required fuel cell capacity from 100 kW to 30 kW. Additionally the integration significantly enhanced system stability enabling the fuel cell and electrolyzer to operate at consistent power during load fluctuations. The system achieved efficiencies of 71.42 % for the PEM electrolyzer and 62.14 % for the PEM fuel cell. However the introduction of the flywheel requires a higher capacity of PV modules and a larger electrolyzer. The overall flywheel's efficiency was impacted by parasitic energy losses resulting in an overall efficiency of 46.41 %. The minimum efficiency observed across various scenarios of the model studied was 3.14 % highlighting the importance of considering these losses in the overall system design. Despite these challenges the hybrid model demonstrated a substantial improvement in the reliability and stability of renewable energy systems effectively bridging short-term and long-term energy storage solutions.
Experimental Study on the Ignition of Hydrogen Containing Atmospheres by Mechanical Impacts
Sep 2023
Publication
In international regulations on explosion protection mechanical friction impact or abrasion is usually named as one of 13 ignition sources that must be avoided in hazardous zones with explosive atmospheres. In different studies it is even identified as one of the most frequent ignition sources in practice. The effectiveness of mechanical impacts as ignition source is dependent from several parameters including the minimum ignition energy of the explosive atmosphere the properties of the material pairing the kinetic impact energy or the impact velocity. By now there is no standard procedure to determine the effectiveness of mechanical impacts as ignition source. In some previous works test procedures with poor reproducibility or undefined kinetic impact energy were applied for this purpose. In other works only homogeneous material pairings were considered. In this work the effectiveness of mechanical impacts with defined and reproducible kinetic impact energy as ignition source for hydrogen containing atmospheres was studied systematically in dependence from the inhomogeneous material pairing considering materials with practical relevance like stainless steel low alloy steel concrete and non-iron-metals. It was found that ignition can be avoided if non-iron metals are used in combination with different metallic materials but in combination with concrete even the impact of non-iron-metals can be an effective ignition source if the kinetic impact energy is not further limited. Moreover the consequence of hydrogen admixture to natural gas on the effectiveness of mechanical impacts as ignition source was studied. In many cases ignition of atmospheres containing natural gas by mechanical impacts is rather unlikely. No influence could be observed for admixtures up to 25% hydrogen and even more. The results are mainly relevant in the context of repurposing the natural gas grid or adding hydrogen to the natural gas grid. Based on the test results it can be evaluated under which circumstances the use of tools made of non-iron-metals or other non-sparking materials can be an effective measure to avoid ignition sources in hazardous zones containing hydrogen for example during maintenance work.
Conceptual Design and Aerostructural Trade-Offs in HydrogenPowered Strut-Braced Wing Aircraft: Insights into Dry and Wet Ultra-High Aspect Ratio Wings
Jan 2025
Publication
Stringent sustainability goals are set for the next generation of aircraft. A promising novel airframe concept is the ultra-high aspect ratio Strut-Braced Wing (SBW) aircraft. Hydrogen-based concepts are active contenders for sustainable propulsion. The study compares a medium-range Liquid Hydrogen (LH2) to a kerosene-based SBW aircraft designed with the same top-level requirements. For both concepts overall design operating costs and emissions are evaluated using the tool SUAVE. Furthermore aerostructural optimizations are performed for the wing mass of SBW aircraft with and without wing-based fuel tanks. Results show that the main difference in the design point definition results from a higher zero-lift drag due to an extended fuselage housing the LH2 tanks with a small reduction in the required wing loading. Structural mass increases of the LH2 aircraft due to additional tanks and fuselage structure are mostly offset by fuel mass savings. While the fuel mass accounts for nearly 25% of the kerosene design’s Maximum Take-Off Mass (MTOM) this reduces to 10% for the LH2 design. The LH2 aircraft has 16% higher operating costs with emission levels reduced to 57–82% of the kerosene aircraft depending on the LH2 production method. For static loads the absence of fuel acting as bending moment relief in the wing results in an increase in wing structural mass. However the inclusion of roll rate requirements causes large wing mass increases for both concepts significantly outweighing dry wing penalties.
Key Influencing Factors on Hydrogen Storage and Transportation Costs: A Systematic Literature Review
Jan 2025
Publication
Cost-effective hydrogen supply chains are crucial for accelerating hydrogen deployment and decarbonizing economies with the storage and transportation sectors representing major challenges. This study presents a systematic literature review of 81 papers to identify and analyze the main influencing factors on hydrogen storage and transportation costs with the aim of improving transparency across the hydrogen supply chain. The review identifies and assesses 25 technical nine economic and two environmental factors highlighting capital expenditure and capacity of storage and transport facilities as the primary drivers of storage and transportation costs. Furthermore transport distance for trucks and ships as well as the discount rate for pipelines are iden tified as additional critical cost-determining factors for the transportation sector.
A Perspective on Low-Temperature Water Electrolysis - Challenges in Alkaline and Acidic Technology
Dec 2017
Publication
Water electrolysis is considered as an important technology for an increased renewable energy penetration. This perspective on low-temperature water electrolysis joins the dots between the interdisciplinary fields of fundamental science describing physicochemical processes engineering for the targeted design of cell components and the development of operation strategies. Within this aim the mechanisms of ion conduction gas diffusion corrosion and electrocatalysis are reviewed and their influence on the optimum design of separators electrocatalysts electrodes and other cell components are discussed. Electrocatalysts for the water splitting reactions and metals for system components are critically accessed towards their stability and functionality. On the basis of the broad scientific analysis provided challenges for the design of water electrolyzers are elucidated with special regard to the alkaline or acidic media of the electrolyte.
The Geopolitics of Hydrogen, Volume 1: European Strategies in Global Perspective
Jan 2024
Publication
Rainer Quitzow,
Yana Zabanova,
Almudena Nunez,
Ines Bouacida,
Michał Smoleń,
Wojciech Żelisko,
John Szabo,
Ignacio Urbasos,
Gonzalo Escribano,
Andrea Prontera,
Roelof Stam,
Coby van der Linder,
Pier Stapersma,
Stefan Ćetković,
Janek Stockburger,
Jon Birger Skjærseth,
Per Ove Eikeland,
Tor Håkon Jackson Inderberg and
Mari Lie Larsen
Chapters:<br/>♦ Introduction by Rainer Quitzow and Yana Zabanova<br/>♦ The EU in the Global Hydrogen Race: Bringing Together Climate Action Energy Security and Industrial Policy by Yana Zabanova<br/>♦ Germany’s Hydrogen Strategy: Securing Industrial Leadership in a Carbon–Neutral Economy by Almudena Nunez and Rainer Quitzow<br/>♦ France’s Hydrogen Strategy: Focusing on Domestic Hydrogen Production to Decarbonise Industry and Mobility by Ines Bouacida<br/>♦ International Dimension of the Polish Hydrogen Strategy. Conditions and Potential for Future Development by Michał Smoleń and Wojciech Żelisko<br/>♦ Hydrogen Affairs in Hungary’s Politically Confined Ambition byJohn Szabo<br/>♦ Spain’s Hydrogen Ambition: Between Reindustrialisation and Export-Led Energy Integration with the EU by Ignacio Urbasos and Gonzalo Escribano<br/>♦ Italian Hydrogen Policy: Drivers Constraints and Recent Developments by Andrea Prontera<br/>♦ Hydrogen Policy in the Netherlands: Laying the Foundations for a Scalable Hydrogen Value Chain by Roelof Stam Coby van der Linde and Pier Stapersma<br/>♦ Hydrogen Strategy of Sweden: Unpacking the Multiple Drivers and Potential Barriers to Hydrogen Development by Stefan Ćetković and Janek Stockburger<br/>♦ Norway’s Hydrogen Strategy: Unveiling Green Opportunities and Blue Export Ambitions by Jon Birger Skjærseth Per Ove Eikeland Tor Håkon Jackson Inderberg and Mari Lie Larsen<br/>♦ The Geopolitics of Hydrogen in Europe: The Interplay between EU and Member State Policies by Rainer Quitzow and Yana Zabanova
Numerical Investigation and Simulation of Hydrogen Blending into Natural Gas Combustion
Aug 2024
Publication
This study reviews existing simulation models and describes a selected model for analysing combustion dynamics in hydrogen and natural gas mixtures specifically within non-ferrous melting furnaces. The primary objectives are to compare the combustion characteristics of these two energy carriers and assess the impact of hydrogen integration on furnace operation and efficiency. Using computational fluid dynamics (CFD) simulations incorporating actual furnace geometries and a detailed combustion and NOx emission prediction model this research aims to accurately quantify the effects of hydrogen blending. Experimental tests on furnaces using only natural gas confirmed the validity of these simulations. By providing precise predictions for temperature distribution and NOx emissions this approach reduces the need for extensive laboratory testing facilitates broader exploration of design modifications accelerates the design process and ultimately lowers product development costs.
New Development Paths through Green Hydrogen? An Ex-ante Assessment of Structure and Agency in Chile and Namibia
Jan 2025
Publication
Many developing countries seek to participate in the emerging global green hydrogen industry not only as exporters of green hydrogen and its derivatives to Europe and the Far East but also to use it for their own energy security and green transition. They hope that new development paths will lead to late-comer industrialisation. This article assesses corresponding prospects in Chile and Namibia two countries that pursue particularly ambitious plans on green hydrogen. To better understand the chances for path creation ex ante the authors draft an innovative framework that refers to context factors – that is structure – and three types of transformative agency. Against the backdrop of information from secondary sources and a series of expert interviews they uncover sound institutional reforms and initiatives of place-based leadership to promote the green hydrogen industry. However Chile and Namibia lack Schumpeterian entrepreneurship. It therefore remains to be seen whether new development paths will be inclusive contributing to in-country development. Typical downsides of extractive industries in resource peripheries might occur.
Exhaust Gas Aftertreatment to Minimize Nox Emissions from Hydrogen-fueled Internal Combustion Engines
Oct 2023
Publication
Hydrogen-fueled internal combustion engines are a promising CO2-free and zero-impact emission alternative to battery or fuel cell electric powertrains. Advantages include long service life robustness against fuel impurities and a strong infrastructural base with existing production lines and workshop stations. In order to make hydrogen engines harmless in terms of pollutant emissions as well NOX emissions at the tailpipe must be reduced as low as the zero-impact emission level. Here the application of selective catalytic reduction (SCR) catalysts is a promising solution that can be rapidly adopted from conventional diesel engines. This paper therefore investigates the influences of the hydrogen concentration in the raw exhaust gas of the NO2/NOX ratio and of the space velocity on the performance of two different SCR technologies. The results show that both types of SCR copper-zeolite and vanadium-based have their advantages and drawbacks. Copper-based SCR catalysts have an early light-off temperature and reach maximum efficiencies of up to >99%. On the other hand vanadium systems promise almost no secondary N2O emissions. As a result we combined both approaches to create a superior solution with high efficiency and lowest secondary emissions.
The Market Introduction of Hydrogen Focussing on Bus Refueling
Dec 2023
Publication
Public transport plays a prominent role with respect to mitigating transport-related environmental effects by improving passenger transport efficiency and the quality of life in cities. Batteries and fuel cells are at the forefront of the technological shift to zero-emission powertrains. Within the scope of the German-funded project BIC H2 corresponding systems analysis research focuses on the market introduction of fuel cell–electric buses in the Rhine–Ruhr Metropolitan Region through 2035. This study presents the related methods and major outcomes of this techno-economic research which spans spatially-resolved hydrogen demand modeling of all relevant sectors to hydrogen refueling stations and upstream infrastructure modeling to scenario-based analyses. The latter builds upon an empirical study supporting the development of the Hydrogen Roadmap of the State of North Rhine–Westphalia (NRW). Our results show that the demand in NRW alone is expected to account for one third of total German hydrogen use. Hydrogen bus refueling could substantially support market introduction during its early phases. In the long term however hydrogen demand in industry is significantly higher compared to that in the transport sector. Furthermore spatial analysis identifies regions with pronounced hydrogen demands that could therefore be candidates for initial infrastructure investments. With the Cologne area showing the highest hydrogen demand levels such regions can offer particularly high infrastructure utilization e.g. for bus refueling. On the infrastructure side trailers for transporting gaseous hydrogen to refueling stations are the most favorable option through 2035. Pipelines would be the preferred solution soon after 2035 due to increased hydrogen demand. If effectively deployed converted natural gas pipelines would be the most cost-effective option even earlier.
How to Connect Energy Islands: Trade-offs Between Hydrogen and Electricity Infrastructure
Apr 2023
Publication
In light of offshore wind expansions in the North and Baltic Seas in Europe further ideas on using offshore space for renewable-based energy generation have evolved. One of the concepts is that of energy islands which entails the placement of energy conversion and storage equipment near offshore wind farms. Offshore placement of electrolysers will cause interdependence between the availability of electricity for hydrogen production and for power transmission to shore. This paper investigates the trade-offs between integrating energy islands via electricity versus hydrogen infrastructure. We set up a combined capacity expansion and electricity dispatch model to assess the role of electrolysers and electricity cables given the availability of renewable energy from the islands. We find that the electricity system benefits more from connecting close-to-shore wind farms via power cables. In turn electrolysis is more valuable for far-away energy islands as it avoids expensive long-distance cable infrastructure. We also find that capacity investment in electrolysers is sensitive to hydrogen prices but less to carbon prices. The onshore network and congestion caused by increased activity close to shore influence the sizing and siting of electrolysers.
Hydrogen Behavior and Mitigation Measures: State of Knowledge and Database from Nuclear Community
Sep 2023
Publication
Hydrogen has become a key enabler for decarbonization as countries pledge to reach net zero carbon emissions by 2050. With hydrogen infrastructure expanding rapidly beyond its established applications there is a requirement for robust safety practices solutions and regulations. Since the 1980s considerable efforts have been undertaken by the nuclear community to address hydrogen safety issues because in severe accidents of water-cooled nuclear reactors a large amount of hydrogen can be produced from the oxidation of metallic components with steam. As evidenced in the Fukushima accident hydrogen combustion can cause severe damage to reactor building structures promoting the release of radioactive fission products to the environment. A number of large-scale experiments were conducted in the framework of national and international projects to understand the hydrogen dispersion and combustion behaviour under postulated accidental conditions. Empirical engineering models and numerical codes were developed and validated for safety analysis. Hydrogen recombiners known as Passive Autocatalytic Recombiner (PAR) were developed and have been widely installed in nuclear containments to mitigate hydrogen risk. Complementary actions and strategies were established as part of severe accident management guidelines to prevent or limit the consequences of hydrogen explosions. In addition hydrogen monitoring systems were developed and implemented in nuclear power plants. The experience and knowledge gained from the nuclear community on hydrogen safety is valuable and applicable for other industries involving hydrogen production transport storage and use.
Technology Transfer from Fuel Processing for Fuel Cells to Fuel Synthesis from Hydrogen and Carbon Dioxide
Aug 2023
Publication
Improving the energy efficiency of existing technologies such as the on-board power supply of trucks ships and aircraft is an important endeavor for reducing primary energy consumption. The approach consists of using fuel cell technology in conjunction with hydrogen production from liquid fuels. However the energy transition with the goal of complete climate-neutrality requires technological changes in the use of hydrogen produced from renewable energy via electrolysis. Synthetic fuels are an important building block for drive systems that will continue to require liquid energy carriers in the future due to their range. This study addresses the question of whether technical devices that were developed for the generation of hydrogen from liquid fuels for fuel cells to generate electricity are now suitable for the reverse process chain or can play an important role in it. The new process chain produces hydrogen from sustainable electricity combining it with carbon dioxide to create a synthetic liquid fuel.
Design Investigation of Potential Long-Range Hydrogen Combustion Blended Wing Body Aircraft with Future Technologies
Jun 2023
Publication
Present work investigates the potential of a long-range commercial blended wing body configuration powered by hydrogen combustion engines with future airframe and propulsion technologies. Future technologies include advanced materials load alleviation techniques boundary layer ingestion and ultra-high bypass ratio engines. The hydrogen combustion configuration was compared to the configuration powered by kerosene with respect to geometric properties performance characteristics energy demand equivalent CO2 emissions and Direct Operating Costs. In addition technology sensitivity studies were performed to assess the potential influence of each technology on the configuration. A multi-fidelity sizing methodology using low- and mid-fidelity methods for rapid configuration sizing was created to assess the configuration and perform robust analyses and multi-disciplinary optimizations. To assess potential uncertainties of the fidelity of aerodynamic analysis tools high-fidelity aerodynamic analysis and optimization framework MACHAero was used for additional verification. Comparison of hydrogen and kerosene blended wing body aircraft showed a potential reduction of equivalent CO2 emission by 15% and 81% for blue and green hydrogen compared to the kerosene blended wing body and by 44% and 88% with respect to a conventional B777-300ER aircraft. Advancements in future technologies also significantly affect the geometric layout of aircraft. Boundary layer ingestion and ultra-high bypass ratio engines demonstrated the highest potential for fuel reduction although both technologies conflict with each other. However operating costs of hydrogen aircraft could establish a significant problem if pessimistic and base hydrogen price scenarios are achieved for blue and green hydrogen respectively. Finally configurational problems featured by classical blended wing body aircraft are magnified for the hydrogen case due to the significant volume requirements to store hydrogen fuel.
Challenges of Industrial-Scale Testing Infrastructure for Green Hydrogen Technologies
Apr 2023
Publication
Green hydrogen is set to become the energy carrier of the future provided that production technologies such as electrolysis and solar water splitting can be scaled to global dimensions. Testing these hydrogen technologies on the MW scale requires the development of dedicated new test facilities for which there is no precedent. This perspective highlights the challenges to be met on the path to implementing a test facility for large-scale water electrolysis photoelectrochemical and photocatalytic water splitting and aims to serve as a much-needed blueprint for future test facilities based on the authors’ own experience in establishing the Hydrogen Lab Leuna. Key aspects to be considered are the electricity and utility requirements of the devices under testing the analysis of the produced H2 and O2 and the safety regulations for handling large quantities of H2 . Choosing the right location is crucial not only for meeting these device requirements but also for improving financial viability through supplying affordable electricity and providing a remunerated H2 sink to offset the testing costs. Due to their lower TRL and requirement for a light source large-scale photocatalysis and photoelectrochemistry testing are less developed and the requirements are currently less predictable.
Outlook and Challenges for Hydrogen Storage in Nanoporous Materials
Feb 2016
Publication
Darren P. Broom,
Colin Webb,
Katherine Hurst,
P. A. Parilla,
Thomas Gennett,
C. M. Brown,
Renju Zacharia,
E. Tylianakis,
E. Klontzas,
George E. Froudakis,
Th. A. Steriotis,
Pantelis N. Trikalitis,
Donald L. Anton,
B. Hardy,
David A. Tamburello,
Claudio Corgnale,
B. A. van Hassel,
D. Cossement,
Richard Chahine and
Michael Hirscher
Considerable progress has been made recently in the use of nanoporous materials for hydrogen storage. In this article the current status of the field and future challenges are discussed ranging from important open fundamental questions such as the density and volume of the adsorbed phase and its relationship to overall storage capacity to the development of new functional materials and complete storage system design. With regard to fundamentals the use of neutron scattering to study adsorbed H2 suitable adsorption isotherm equations and the accurate computational modelling and simulation of H2 adsorption are discussed. The new materials covered include flexible metal–organic frameworks core–shell materials and porous organic cage compounds. The article concludes with a discussion of the experimental investigation of real adsorptive hydrogen storage tanks the improvement in the thermal conductivity of storage beds and new storage system concepts and designs.
Towards Climate-neutral Aviation: Assessment of Maintenance Requirements for Airborne Hydrogen Storage and Distribution Systems
Apr 2023
Publication
Airlines are faced with the challenge of reducing their environmental footprint in an effort to push for climate-neutral initiatives that comply with international regulations. In the past the aviation industry has followed the approach of incremental improvement of fuel efficiency while simultaneously experiencing significant growth in annual air traffic. With the increase in air traffic negating any reduction in Greenhouse Gas (GHG) emissions more disruptive technologies such as hydrogen-based onboard power generation are required to reduce the environmental impact of airline operations. However despite initial euphoria and first conceptual studies for hydrogen-powered aircraft several decades ago there still has been no mass adoption to this day. Besides the challenges of a suitable ground infrastructure this can partly be attributed to uncertainties with the associated maintenance requirements and the expected operating costs to demonstrate the economic viability of this technology. With this study we address this knowledge gap by estimating changes towards scheduled maintenance activities for an airborne hydrogen storage and distribution system. In particular we develop a detailed system design for a hydrogen-powered fuel-cell-based auxiliary power generation and perform a comparative analysis with an Airbus A320 legacy system. That analysis allows us to (a) identify changes for the expected maintenance effort to enhance subsequent techno-economic assessments (b) identify implications of specific design assumptions with corresponding maintenance activities while ensuring regulatory compliance and (c) describe the impact on the resulting task execution. The thoroughly examined interactions between system design and subsequent maintenance requirements of this study can support practitioners in the development of prospective hydrogen-powered aircraft. In particular it allows the inclusion of maintenance implications in early design stages of corresponding system architectures. Furthermore since the presented methodology is transferable to different design solutions it provides a blueprint for alternative operating concepts such as the complete substitution of kerosene by hydrogen to power the main engines.
Synthetic Fuels in the German Industry Sector Depending on Climate Protection Level
Aug 2021
Publication
Especially the electrification of the industry sector is highly complex and challenging mainly due to process-specific requirements. In this context there are several industrial processes where the direct and indirect use of electricity is subject to technical restrictions. In order to achieve the national climate goals the fossil energy consumption remaining after the implementation of efficiency and sufficiency measures as well as direct electrification has to be substituted through hydrogen and synthetic gaseous liquid and solid hydrocarbons. As the main research object the role of synthetic fuels in industrial transformation paths is investigated and analyzed by combining individual greenhouse gas abatement measures within the Sector Model Industry. Sector Model Industry is an energy consumption model that performs discrete deterministic energy and emission dynamic calculations with a time horizon up to 2050 at macroeconomic level. The results indicate that the use of synthetic fuels can be expected with a high level of climate protection. The industrial CO2 target in the model makes it necessary to replace CO2 -intensive fossil with renewable fuels. The model uses a total of 163 TWh of synthetic fuels in the climate protection scenario and thus achieves an 88% decrease in CO2 emissions in 2050 compared to 1990. This means that the GHG abatement achieved in industry is within the range of the targeted CO2 mitigation of the overall system in Germany of between 80 and 95% in 2050 compared to 1990. Due to technical restrictions the model mainly uses synthetic methane instead of hydrogen (134 TWh). The results show that despite high costs synthetic fuels are crucial for defossilization as a fall back option in the industrial scenario considering high climate ambition. The scenario does not include hydrogen technologies for heat supply. Accordingly the climate protection scenario uses hydrogen only in the steel industry for the direct reduction of iron (21 TWh). 8 TWh of synthetic oil substitute the same amount of fossil oil in the climate protection scenario. A further analysis conducted on the basis of the model results shows that transformation in the energy system and the use of smart ideas concepts and technologies are a basic prerequisite for enabling the holistic defossilisation of industry. The findings in the research can contribute to the cost-efficient use of synthetic fuels in industry and thus serve as a basis for political decision making. Moreover the results may have a practical relevance not only serving as a solid comparison base for the outcome of other studies but also as input data for further simulation of energy system transformation paths.
The Role of Hydrogen for the Defossilization of the German Chemical Industry
Apr 2023
Publication
Within the European Green Deal the European industry is summoned to transform towards a green and circular economy to reduce CO2-emissions and reach climate goals. Special focus is on the chemical industry to boost recycling processes for plastics exploit resource efficiency potentials and switch to a completely renewable feedstock (defossilization). Despite common understanding that drastic changes have to take place it is yet unknown how the industrial transformation should be accomplished. This work explains how a cost-optimal defossilization of the chemical industry in the context of national greenhouse gas (GHG) mitigation strategies look like. The central part of this investigation is based on a national energy system model to optimize the future energy system design of Germany as a case study for a highly industrialized country. A replacement of fossil-based feedstocks by renewable feedstocks leads to a significant increase in hydrogen demand by þ40% compared to a reference scenario. The resulting demand of hydrogen-based energy carriers including the demand for renewable raw materials must be produced domestically or imported. This leads to cumulative additional costs of the transformation that are 32% higher than those of a reference scenario without defossilization of the industry. Fischer-Tropsch synthesis and the methanol-to-olefins route can be identified as key technologies for the defossilization of the chemical industry.
Hydrogen Related Accidents and Lesson Learned from Events Reported in the East Continental Asia
Sep 2023
Publication
Hydrogen as an energy carrier plays an important role in carbon neutrality and energy transition. Hydrogen is the lightest element with a density of only 0.08375 kg/m3 in gaseous form at standard temperature and pressure (STP); as a result hydrogen is usually stored and transported in a highly compressed form. It is prone to leakage and has a very low ignition energy of 0.017 mJ. Safety remains a challenge in the use of hydrogen as an energy source. This paper examines approximately 20 hydrogen-related accidents in China over a 20-year period focusing on the root causes consequences of the accidents and responses to them. These accidents occurred in the production storage transport and application of hydrogen with different causes in different locations and resulting in losses at different scales. Some statistical evaluations were conducted to learn lessons from the accidents. The main objective of this paper is (i) to retrieve a set of hydrogen related incidents from a region which is under-represented in incident repositories (ii) to contribute to a generalised lesson learned from them and (iii) to assist the definition of realistic scenarios for commonly occurring hydrogen accidents.
What Does the Public Know About Technological Solutions for Achieving Carbon Neutrality? Citizens' Knowledge of Energy Transition and the Role of Media
Aug 2023
Publication
The present study explores the relation between media use and knowledge in the context of the energy transition. To identify relevant knowledge categories we relied on the expertise of an interdisciplinary research team. Based on this expertise we identified awareness-knowledge of changes in the energy system and principles-knowledge of hydrogen as important knowledge categories. With data obtained from a nationwide online survey of the German-speaking population (n = 2025) conducted in August 2021 we examined the level of knowledge concerning both categories in the German population. Furthermore we studied its associations with exposure to journalistic media and direct communication from non-media actors (e.g. scientists). Our results revealed a considerable lack of knowledge for both categories. Considering the media variables we found only weak and in some cases even negative relations with the use of journalistic media or other actors that spread information online. However we found comparably strong associations between both knowledge categories and the control variables of sex education and personal interest. We use these results to open up a general discussion of the role of the media in knowledge acquisition processes.
AMHYCO Project - Advances in H2/CO Combustion, Recombination and Containment Modelling
Sep 2023
Publication
During a severe accident in a nuclear power plant one of the potential threats to the containment is the occurrence of energetic combustion events. In modern plants Severe Accident Management Guidelines (SAMG) as well as dedicated mitigation hardware are in place to minimize/mitigate this combustion risk and thus avoid the release of radioactive material into the environment. Advancements in SAMGs are in the focus of AMHYCO an EU-funded Horizon 2020 project officially launched on October 1st 2020. The project consortium consists of 12 organizations (from six European countries and one from Canada) and is coordinated by the Universidad Politécnica de Madrid (UPM). The progress made in the first two years of the AMHYCO project is here presented. A comprehensive bibliographic review has been conducted providing a common foundation to build the knowledge gained during the project. After an extensive set of accident transients simulated both for phases occurring inside and outside the reactor pressure vessel a set of challenging sequences from the combustion risk perspective for different power plant types were identified. At the same time three generic containment models for the three considered reactor designs have been created to provide the full containment analysis simulations with lumped parameter models 3-dimensional containment codes and CFD codes. In order to further consolidate the model base combustion experiments and performance tests on passive auto-catalytic recombiners under explosion prone H2/CO atmospheres were performed at CNRS (France) and FZJ (Germany). Finally it is worth saying that the experimental data and engineering models generated from the AMHYCO project are useful for other industries outside the nuclear one.
Assessment of the Green Hydrogen Value Chain in Cases of the Local Industry in Chile Applying an Optimization Model
May 2024
Publication
This study assessed the feasibility of integrating a green hydrogen value chain into the local industry examining two case studies by comparing four scenarios. The optimization focused on generating electricity from stationary renewable sources such as solar or through Power Purchase Agreements to produce sufficient hydrogen in electrolyzers. Current demand profiles renewable participation targets electricity supply sources levelized costs of energy and hydrogen and technology options were considered. The most cost-effective scenario showed a levelized cost of energy of 0.032 and 0.05 US$/kWh and a hydrogen cost below 1.0 US$/kgH2 for cases 1 and 2 respectively. A sensitivity analysis highlighted the critical influence of fuel cell technology on cost modification underscoring the importance of focusing cost reduction strategies on these technologies to enhance the economic viability of the green hydrogen value chain. Specifically a high sensitivity towards reducing the levelized costs of energy and hydrogen in the port sector with adjustments in fuel cell technology costs was identified indicating the need for specific policies and supports to facilitate their adoption.
European Hydrogen Train the Trainer Framework for Responders: Outcomes of the Hyresponder Project
Sep 2023
Publication
Síle Brennan,
Didier Bouix,
Christian Brauner,
Dominic Davis,
Natalie DeBacker,
Alexander Dyck,
André Vagner Gaathaug,
César García Hernández,
Laurence Grand-Clement,
Etienne Havret,
Deborah Houssin-Agbomson,
Petr Kupka,
Laurent Lecomte,
Eric Maranne,
Vladimir V. Molkov,
Pippa Steele,
Adolfo Pinilla,
Paola Russo and
Gerhard Schoepf
HyResponder is a European Hydrogen Train the Trainer programme for responders. This paper describes the key outputs of the project and the steps taken to develop and implement a long-term sustainable train the trainer programme in hydrogen safety for responders across Europe and beyond. This FCH2 JU (now Clean Hydrogen Joint Undertaking) funded project has built on the successful outcomes of the previous HyResponse project. HyResponder has developed further and updated educational operational and virtual reality training for trainers of responders to reflect the state-of-the-art in hydrogen safety including liquid hydrogen and expand the programme across Europe and specifically within the 10 countries represented directly within the project consortium: Austria Belgium the Czech Republic France Germany Italy Norway Spain Switzerland and the United Kingdom. For the first time four levels of educational materials from fire fighter through to specialist have been developed. The digital training resources are available on the e-Platform (https://hyresponder.eu/e-platform/). The revised European Emergency Response Guide is now available to all stakeholders. The resources are intended to be used to support national training programs. They are available in 8 languages: Czech Dutch English French German Italian Norwegian and Spanish. Through the HyResponder activities trainers from across Europe have undertaken joint actions which are in turn being used to inform the delivery of regional and national training both within and beyond the project. The established pan-European network of trainers is shaping the future in the important for inherently safer deployment of hydrogen systems and infrastructure across Europe and enhancing the reach and impact of the programme.
The Impact of the Russian War against Ukraine on the German Hydrogen Discourse
Jan 2024
Publication
This contribution delves into the transformative effects of the Russian–Ukrainian war on the discourse surrounding German hydrogen. Employing structural topical modeling (STM) on a vast dataset of 2192 newspaper articles spanning from 2019 to 2022 it aims to uncover thematic shifts attributed to the Russian invasion of Ukraine. The onset of the war in February 2022 triggered a significant pivot in the discourse shifting it from sustainability and climate-change mitigation to the securing of energy supplies through new partnerships particularly in response to Russia’s unreliability. Germany started exploring alternative energy trading partners like Canada and Australia emphasizing green hydrogen development. The study illustrates how external shocks can expedite the uptake of new technologies. The adoption of the “H2 readiness” concept for LNG terminals contributes to the successful implementation of green hydrogen. In summary the Russian–Ukrainian war profoundly impacted the German hydrogen discourse shifting the focus from sustainability to energy supply security underscoring the interconnectedness of energy security and sustainability in Germany’s hydrogen policy.
Exploring the State-of-operation of Proton Exchange Membrane Electrolyzers
Dec 2024
Publication
Proton exchange membrane electrolytic cells (PEMECs) have the potential to provide green Hydrogen as a sustainable energy source. PEMEC has already been applied at an industrially relevant scale. However it still faces challenges regarding reliability and durability especially in long-term operation. This review emphasizes the need for standardizing the cell configuration the testing protocols and the evaluation procedures to attain the optimum operation settings and eventually precisely evaluating the degradation rate. Potential physicochemical and electrical operational health indicators are described to identify the degradation of a distinct cell component in a running PEMEC. The reliable evaluation of degradation rate via operational health indicators with a robust supervisory system under stringent operating conditions is likely to diagnose the degradation mechanism. By developing incremental empirical degradation models via mapping a correlation between the history of proposed operational health indicators the instantaneous degradation rate can be quantified. This approach in turn enables us to determine the state-of-operation of an electrolyzer during service thereby benchmarking the durability of PEMEC. Finally with the target of scaling up and fulfilling the commercial demands for PEMEC the significance and literature contributions regarding operation management and prog nostics are expressed.
A Rigorous Optimization Method for Long-term Multi-stage Investment Planning: Integration of Hydrogen into a Decentralized Multi-energy System
Dec 2024
Publication
Thoroughly assessing future energy systems requires examining both their end states and the paths leading to them. Employing dynamic investment or multi-stage optimization models is crucial for this analysis. However solving these optimization problems becomes increasingly challenging due to their long time horizons – often spanning several decades – and their dynamic nature. While simplifications like aggregations are often used to expedite solving procedures they introduce higher uncertainty into the results and might lead to suboptimal solutions compared to non-simplified models. Against this background this paper presents a rigorous optimization method tailored for multi-stage optimization problems in long-term energy system planning. By dividing the solution algorithm into a design and operational optimization step the proposed method efficiently finds feasible solutions for the non-simplified optimization problem with simultaneous quality proof. Applied to a real-life energy system of a waste treatment plant in Germany the method significantly outperforms a benchmark solver by reducing the computational time to find the first feasible solution from more than two weeks to less than one hour. Furthermore it exhibits greater robustness compared to a conventional long-term optimization approach and yields solutions closer to the optimum. Overall this method offers decision-makers computationally efficient and reliable information for planning investment decisions in energy systems.
Green Hydrogen Production and Its Land Tenure Consequences in Africa: An Interpretive Review
Sep 2023
Publication
Globally a green hydrogen economy rush is underway and many companies investors governments and environmentalists consider it as an energy source that could foster the global energy transition. The enormous potential for hydrogen production for domestic use and export places Africa in the spotlight in the green hydrogen economy discourse. This discourse remains unsettled regarding how natural resources such as land and water can be sustainably utilized for such a resource-intensive project and what implications this would have. This review argues that green hydrogen production (GHP) in Africa has consequences where land resources (and their associated natural resources) are concerned. It discusses the current trends in GHP in Africa and the possibilities for reducing any potential pressures it may put on land and other resource use on the continent. The approach of the review is interpretive and hinges on answering three questions concerning the what why and how of GHP and its land consequences in Africa. The review is based on 41 studies identified from Google Scholar and sources identified via snowballed recommendations from experts. The GHP implications identified relate to land and water use mining-related land stress and environmental ecological and land-related socioeconomic consequences. The paper concludes that GHP may not foster the global energy transition as is being opined by many renewable energy enthusiasts but rather could help foster this transition as part of a greener energy mix. It notes that African countries that have the potential for GHP require the institutionalization of or a change in their existing approaches to land-related energy governance systems in order to achieve success.
Modeling of Tube Deformation and Failure under Conditions of Hydrogen Detonation
Sep 2023
Publication
In case of accidental conditions involving high-speed hydrogen combustion the considerable pressure and thermal loads could result in substantial deformation and/or destruction of the industrial appliances. Accounting of such effects in the safety analysis with CFD tools can provide critical information on the design and construction of the sensitive appliances’ elements. The current paper presents the development and the implementation of a new 3D-technique which makes possible to perform simulations of the gas-dynamic processes simultaneously with adaptation of the geometry of complex configurations. Using the data obtained in the experiments on the flame acceleration and DDT in the tubes of industrial arrangements performed in MPA and KIT the authors performed a series of the combustion simulations corresponding to the experimental conditions. The combustion gas-dynamics was simulated using COM3D code and the tube wall material behavior was modelled using finite-element code ABAQUS - © Dassault Systèmes with real-time data exchange between the codes. Obtained numerical results demonstrated good agreement with the observed experimental data on both pressure dynamics and tube deformation history.
Unconfined Hydrogen Detonations: Experiments, Modelling, Scaling
Sep 2023
Publication
A series of unconfined hydrogen detonation bench-mark experiments are analyzed with respect to CFD code validation and safety measures development. 1-Dimensional in-house code COM1D was applied for validation against experimental data for unconfined detonation of a hemispherical envelope of about 3- and 5-m radius with hydrogen-air mixtures from 20 to 30% hydrogen in air. The code demonstrates a very good agreement with experimental data and allows an adequate simulation of the unconfined hydrogen detonation. All calculated data were scaled in Sachs coordinates to compare with experimental data and to approximate the data for practical evaluation of safety distances. Numerical experiments with different hydrogen inventories from 50 g to 50 kg and different sizes of the cloud from 1 to 2 m radius of the same amount of hydrogen 50g were carried out to clarify the problem of energy of gaseous explosion responsible for the strength of blast wave. Additionally a comparison of hydrogen-air explosion pressure with blast wave properties from the hypothetical cloud of hot compressed combustion products (P=Picc; T=Ticc) and simply a hot air of the same initial pressure and temperature as combustion products showed very good agreement of shock wave strength at far distances beyond the cloud. This confirms the governing role of energy of combustion on blast wave propagation and its ability to scale the strength of blast waves. The dynamics of the explosion process and combustion product expansion were also analyzed experimentally and numerically to evaluate the dimension of the heat radiation zone and heat flux from combustion products. To demonstrate the capability of tested COM1D code the modeling and analysis of high-pressure hydrogen tanks rupture at 350 and 700 bar were conducted to investigate blast wave strength and evaluate the safety distances.
Grid-supported Electrolytic Hydrogen Production: Cost of Climate Impact Using Dynamic Emission Factors
Aug 2023
Publication
Hydrogen production based on a combination of intermittent renewables and grid electricity is a promising approach for reducing emissions in hard-to-decarbonise sectors at lower costs. However for such a configuration to provide climate benefits it is crucial to ensure that the grid electricity consumed in the process is derived from low-carbon sources. This paper examined the use of hourly grid emission factors (EFs) to more accurately determine the short-term climate impact of dynamically operated electrolysers. A model of the interconnected northern European electricity system was developed and used to calculate average grid-mix and marginal EFs for the four bidding zones in Sweden. Operating a 10 MW electrolyser using a combination of onshore wind and grid electricity was found to decrease the levelised cost of hydrogen (LCOH) to 2.40–3.63 €/kgH2 compared with 4.68 €/kgH2 for wind-only operation. A trade-off between LCOH and short-term climate impact was revealed as specific marginal emissions could exceed 20 kgCO2eq/kgH2 at minimum LCOH. Both an emission-minimising operating strategy and an increased wind-to-electrolyser ratio was found to manage this trade-off by enabling simultaneous cost and emission reductions lowering the marginal carbon abatement cost (CAC) from 276.8 €/tCO2eq for wind-only operation to a minimum of 222.7 and 119.3 €/tCO2eq respectively. Both EF and LCOH variations were also identified between the bidding zones but with no notable impact on the marginal CAC. When using average grid-mix emission factors the climate impact was low and the CAC could be reduced to 71.3–200.0 €/tCO2eq. In relation to proposed EU policy it was demonstrated that abiding by hourly renewable temporal matching principles could ensure low marginal emissions at current levels of fossil fuels in the electricity mix.
Subcooled Liquid Hydrogen Technology for Heavy-Duty Trucks
Jan 2024
Publication
Subcooled liquid hydrogen (sLH2) is an onboard storage as well as a hydrogen refueling technology that is currently being developed by Daimler Truck and Linde to boost the mileage of heavy-duty trucks while also improving performance and reducing the complexity of hydrogen refueling stations. In this article the key technical aspects advantages challenges and future developments of sLH2 at vehicle and infrastructure levels will be explored and highlighted.
Life Cycle Costing Approaches of Fuel Cell and Hydrogen Systems: A Literature Review
Apr 2023
Publication
Hydrogen is a versatile energy carrier which can be produced from variety of feedstocks stored and transported in various forms for multi-functional end-uses in transportation energy and manufacturing sectors. Several regional national and supra-national climate policy frameworks emphasize the need value and importance of Fuel cell and Hydrogen (FCH) technologies for deep and sector-wide decarbonization. Despite these multi-faceted advantages familiar and proven FCH technologies such as alkaline electrolysis and proton-exchange membrane fuel cell (PEMFC) often face economic technical and societal barriers to mass-market adoption. There is no single unified standardized and globally harmonized normative definition of costs. Nevertheless the discussion and debates surrounding plausible candidates and/or constituents integral for assessing the economics and value proposition of status-quo as well as developmental FCH technologies are steadily increasing—Life Cycle Costing (LCC) being one of them if not the most important outcome of such exercises.<br/>To that end this review article seeks to improve our collective understanding of LCC of FCH technologies by scrutinizing close to a few hundred publications drawn from representative databases—SCOPUS and Web of Science encompassing several tens of technologies for production and select transportation storage and end-user utilization cases. This comprehensive review forms part of and serves as the basis for the Clean Hydrogen Partnership funded SH2E project whose ultimate goal is the methodical development a formal set of principles and guardrails for evaluating the economic environmental and social impacts of FCH technologies. Additionally the SH2E projects will also facilitate the proper comparison of different FCH technologies whilst reconciling range of technologies methodologies modelling assumptions and parameterization found in existing literature.
The Industry Transformation from Fossil Fuels to Hydrogen will Reorganize Value Chains: Big Picture and Case Studies for Germany
Jan 2024
Publication
In many industries low-carbon hydrogen will substitute fossil fuels in the course of the transformation to climate neutrality. This paper contributes to understanding this transformation. This paper provides an overview of energy- and emission-intensive industry sectors with great potential to defossilize their production processes with hydrogen. An assessment of future hydrogen demand for various defossilization strategies in Germany that rely on hydrogen as a feedstock or as an energy carrier to a different extent in the sectors steel chemicals cement lime glass as well as pulp and paper is carried out. Results indicate that aggregate industrial hydrogen demand in those industries would range between 197 TWh and 298 TWh if production did not relocate abroad for any industry sector. The range for hydrogen demand is mainly due to differences in the extent of hydrogen utilization as compared to alternative transformation paths for example based on electrification. The attractiveness of production abroad is then assessed based on the prospective comparative cost advantage of relocating parts of the value chain to excellent production sites for low-carbon hydrogen. Case studies are provided for the steel industry as well as the chemical industry with ethylene production through methanol and the production of urea on the basis of ammonia. The energy cost of the respective value chains in Germany is then compared to the case of value chains partly located in regions with excellent conditions for renewable energies and hydrogen production. The results illustrate that at least for some processes – as ammonia production – relocation to those favorable regions may occur due to substantial comparative cost advantages.
Deep Learning for Wind and Solar Energy Forecasting in Hydrogen Production
Feb 2024
Publication
This research delineates a pivotal advancement in the domain of sustainable energy systems with a focused emphasis on the integration of renewable energy sources—predominantly wind and solar power—into the hydrogen production paradigm. At the core of this scientific endeavor is the formulation and implementation of a deep-learning-based framework for short-term localized weather forecasting specifically designed to enhance the efficiency of hydrogen production derived from renewable energy sources. The study presents a comprehensive evaluation of the efficacy of fully connected neural networks (FCNs) and convolutional neural networks (CNNs) within the realm of deep learning aimed at refining the accuracy of renewable energy forecasts. These methodologies have demonstrated remarkable proficiency in navigating the inherent complexities and variabilities associated with renewable energy systems thereby significantly improving the reliability and precision of predictions pertaining to energy output. The cornerstone of this investigation is the deployment of an artificial intelligence (AI)-driven weather forecasting system which meticulously analyzes data procured from 25 distinct weather monitoring stations across Latvia. This system is specifically tailored to deliver short-term (1 h ahead) forecasts employing a comprehensive sensor fusion approach to accurately predicting wind and solar power outputs. A major finding of this research is the achievement of a mean squared error (MSE) of 1.36 in the forecasting model underscoring the potential of this approach in optimizing renewable energy utilization for hydrogen production. Furthermore the paper elucidates the construction of the forecasting model revealing that the integration of sensor fusion significantly enhances the model’s predictive capabilities by leveraging data from multiple sources to generate a more accurate and robust forecast. The entire codebase developed during this research endeavor has been made available on an open access GIT server.
Numerical Analysis of the Hydrogen-air Mixture Formation Process in a Direct-injection Engine for Off-road Applications
Jun 2024
Publication
Among the different hydrogen premixed combustion concepts direct injection (DI) is one of the most promising for internal combustion engine (ICE) applications. However to fully exploit the benefits of this solution the optimization of the mixture preparation process is a crucial factor. In the present work a study of the hydrogenair mixture formation process in a DI H2-ICE for off-road applications was performed through 3D-CFD simulations. First a sensitivity analysis on the injection timing was carried out to select the optimal injection operating window capable of maximizing mixture homogeneity without a significant volumetric efficiency reduction. Then different spray injector guiding caps were tested to assess their effect on in-cylinder dynamics and mixture characteristics consequently. Finally the impact of swirl intensity on hydrogen distribution has been assessed. The optimization of the combustion chamber geometry has allowed the achievement of significant improvements in terms of mixture homogeneity.
Techno-economic and Environmental Assessment of Renewable Hydrogen Import Routes from Overseas in 2030
Dec 2024
Publication
Converting renewable electricity via water electrolysis into green hydrogen and hydrogen-based products will shape a global trade in power-to-x (PtX) products. The European Union's renewable hydrogen import target of 10 million tonnes by 2030 reflects the urgent need for PtX imports by sea to early high-demand countries like Germany. This study evaluates the cost efficiency and greenhouse gas (GHG) emissions of four hydrogen carrier ship import options considering a reconversion to H2 at the import terminal for a final delivery to offtakers via a H2 pipeline network in 2030. This includes ammonia a liquid organic hydrogen carrier (LOHC) system based on benzyltoluene (BT) and a novel CO2/e-methane and CO2/e-methanol cycle where CO2 is captured at the reconversion plant and then shipped back to the PtX production site in a nearly closed carbon loop. The GHG emission accounting includes well-to-wake emissions of the marine fuels and direct emissions of the carbon capture plant. Two GW-scale case studies reveal the impact of a short and long-distance route from Tunisia and Australia to Germany whereas the specific PtX carriers are either fuelled by its PtX cargo as a renewable marine fuel or by conventional heavy fuel oil (HFO). Ammonia outperforms the other PtX routes as the total hydrogen supply cost range between 5.07 and 7.69 for Australia (low: NH3 HFO high: LOHC HFO) and 4.78–6.21 € per kg H2 for Tunisia (low: NH3 HFO high: CH4 HFO) respectively. The ammonia routes achieve thereby GHG intensities of 31 % and 86 % below the EU threshold of 3.4 kg CO2(e) per kg H2 for renewable hydrogen. LOHC though unless switching to low-emission fuels and the CO2/e-methanol cycle exceed the GHG threshold at shipping distances of 12300 and 16600 km. The hydrogen supply efficiencies vary between 57.9 and 78.8 %LHV (low: CH4 PtX-fuelled high: NH3 HFO) with a PtX marine fuel consumption of up to 15 % LHV for the Australian methanol route whereas high uncertainties remain for the ammonia and methanol reconversion plant efficiencies. The CO2 cyle enables a cost-efficient CO2 supply easing the near-term shortage of climate-neutral CO2 sources at the cost of high GHG emissions for long-distance routes.
Assessing the Implications of Hydrogen Blending on the European Energy System towards 2050
Dec 2023
Publication
With the aim of reducing carbon emissions and seeking independence from Russian gas in the wake of the conflict in Ukraine the use of hydrogen in the European Union is expected to rise in the future. In this regard hydrogen transport via pipeline will become increasingly crucial either through the utilization of existing natural gas infrastructure or the construction of new dedicated hydrogen pipelines. This study investigates the effects of hydrogen blending in existing pipelines on the European energy system by the year 2050 by introducing hydrogen blending sensitivities to the Global Energy System Model (GENeSYS-MOD). Results indicate that hydrogen demand in Europe is inelastic and limited by its high costs and specific use cases with hydrogen production increasing by 0.17% for 100%-blending allowed compared to no blending allowed. The availability of hydrogen blending has been found to impact regional hydrogen production and trade with countries that can utilize existing natural gas pipelines such as Norway experiencing an increase in hydrogen and synthetic gas exports from 44.0 TWh up to 105.9 TWh in 2050 as the proportion of blending increases. Although the influence of blending on the overall production and consumption of hydrogen in Europe is minimal the impacts on the location of production and dependence on imports must be thoroughly evaluated in future planning efforts.
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