Ecuador
Assessing the Feasibility of Hydrogen and Electric Buses for Urban Public Transportation using Rooftop Integrated Photovoltaic Energy in Cuenca Ecuador
Jul 2023
Publication
A main restriction of renewables from intermittent sources is the mismatch between energy resource availability and energy requirements especially when extensive power plants are producing at their highest potential causing huge energy surpluses. In these cases excess power must be stored or curtailed. One alternative is increasing urban solar potential which could be integrated to feed electric buses directly or alternatively through hydrogen (H2 ) as an energy vector. H2 from renewable electricity can be stored and used directly or through fuel cells. This study aims to determine the H2 capability that could be achieved when integrating large-scale photovoltaic (PV) generation in urban areas. This analysis was carried out by determining the PV energy potentially generated by installing PV in Cuenca City downtown (Ecuador). Cuenca is in the process of adopting renewal of the public transport vehicle fleet introducing a new model with an electric tram main network combined with “clean type buses”. The conventional diesel urban transport could be replaced establishing a required vehicle fleet of 475 buses spread over 29 routes emitting 112 tons of CO2 and burning 11175 gallons of diesel daily. Between the main findings we concluded that the electricity that could be produced in the total roof area exceeds the actual demand in the study area by 5.5 times. Taking into account the energy surplus it was determined that the available PV power will cover from 97% to 127% of the total demand necessary to mobilize the city bus fleet. The novelty of this work is the proposal of a combined methodology to find the potential to feed urban transport with urban solar power in cities close to the equatorial line.
Numerical Simulation of Solid Oxide Fuel Cells Comparing Different Electrochemical Kinetics
Mar 2021
Publication
Solid oxide fuel cells (SOFCs) produce electricity with high electrical efficiency and fuel flexibility without pollution for example CO2 NOx SOx and particles. Still numerous issues hindered the large‐scale commercialization of fuel cell at a large scale such as fuel storage mechanical failure catalytic degradation electrode poisoning from fuel and air for example lifetime in relation to cost. Computational fluid dynamics (CFD) couples various physical fields which is vital to reduce the redundant workload required for SOFC development. Modeling of SOFCs includes the coupling of charge transfer electrochemical reactions fluid flow energy transport and species transport. The Butler‐Volmer equation is frequently used to describe the coupling of electrochemical reactions with current density. The most frequently used is the activation‐ and diffusion‐controlled Butler‐Volmer equation. Three different electrode reaction models are examined in the study which is named case 1 case 2 and case 3 respectively. Case 1 is activation controlled while cases 2 and 3 are diffusion‐controlled which take the concentration of redox species into account. It is shown that case 1 gives the highest reaction rate followed by case 2 and case 3. Case 3 gives the lowest reaction rate and thus has a much lower current density and temperature. The change of activation overpotential does not follow the change of current density and temperature at the interface of the anode and electrolyte and interface of cathode and electrolyte which demonstrates the non‐linearity of the model. This study provides a reference to build electrochemical models of SOFCs and gives a deep understanding of the involved electrochemistry.
Opportunities for Low-carbon Generation and Storage Technologies to Decarbonise the Future Power System
Feb 2023
Publication
Alternatives to cope with the challenges of high shares of renewable electricity in power systems have been addressed from different approaches such as energy storage and low-carbon technologies. However no model has previously considered integrating these technologies under stability requirements and different climate conditions. In this study we include this approach to analyse the role of new technologies to decarbonise the power system. The Spanish power system is modelled to provide insights for future applications in other regions. After including storage and low-carbon technologies (currently available and under development) batteries and hydrogen fuel cells have low penetration and the derived emission reduction is negligible in all scenarios. Compressed air storage would have a limited role in the short term but its performance improves in the long term. Flexible generation technologies based on hydrogen turbines and long-duration storage would allow the greatest decarbonisation providing stability and covering up to 11–14 % of demand in the short and long term. The hydrogen storage requirement is equivalent to 18 days of average demand (well below the theoretical storage potential in the region). When these solutions are considered decarbonising the electricity system (achieving Paris targets) is possible without a significant increase in system costs (< € 114/MWh).
Integration of Water Electrolysis Facilities in Power Grids: A Case Study in Northern Germany
Mar 2022
Publication
This work presents a study of the effects that integration of electrolysis facilities for Power-to-X processes have on the power grid. The novel simulation setup combines a high-resolution grid optimization model and a detailed scheduling model for alkaline water electrolysis. The utilization and congestion of power lines in northern Germany is investigated by setting different installed capacities and production strategies of the electrolysis facility. For electrolysis capacities up to 300 MW (~50 ktH2/a) local impacts on the grid are observed while higher capacities cause supra-regional impacts. Thereby impacts are defined as deviations from the average line utilization greater than 5%. In addition the minimum line congestion is determined to coincide with the dailyconstrained production strategy of the electrolysis facility. Our result show a good compromise for the integrated grid-facility operation with minimum production cost and reduced impact on the grid.
Design and Development of a Catalytic Fixed-Bed Reactor for Gasification of Banana Biomass in Hydrogen Production
Apr 2022
Publication
Hydrogen produced from biomass is an alternative energy source to fossil fuels. In this study hydrogen production by gasification of the banana plant is proposed. A fixed-bed catalytic reactor was designed considering fluidization conditions and a height/diameter ratio of 3/1. Experimentation was carried out under the following conditions: 368 ◦C atmospheric pressure 11.75 g of residual mass of the banana (pseudo-stem) an average particle diameter of 1.84 mm and superheated water vapor as a gasifying agent. Gasification reactions were performed using a catalyzed and uncatalyzed medium to compare the effectiveness of each case. The catalyst was Ni/Al2O3 synthesized by coprecipitation. The gas mixture produced from the reaction was continuously condensed to form a two-phase liquid–gas system. The synthesis gas was passed through a silica gel filter and analyzed online by gas chromatography. To conclude the results of this study show production of 178 mg of synthesis gas for every 1 g of biomass and the selectivity of hydrogen to be 51.8 mol% when a Ni 2.5% w/w catalyst was used. The amount of CO2 was halved and CO was reduced from 3.87% to 0% in molar percentage. Lastly a simulation of the distribution of temperatures inside the furnace was developed; the modeled behavior is in agreement with experimental observations.
Pathways to 100% Renewable Energy in Island Systems: A Systematic Review of Challenges, Solutions Strategies, and Success Cases
May 2025
Publication
The transition to 100% renewable energy systems is critical for achieving global sustainability and reducing dependence on fossil fuels. Island power systems due to their geographical isolation limited interconnectivity and reliance on imported fuels face unique challenges in this transition. These systems’ vulnerability to supply–demand imbalances voltage instability and frequency deviations necessitates tailored strategies for achieving grid stability. This study conducts a systematic review of the technical and operational challenges associated with transitioning island energy systems to fully renewable generation following the Preferred Reporting Items for Systematic Reviews and MetaAnalyses (PRISMA) methodology. Out of 991 identified studies 81 high-quality articles were selected focusing on key aspects such as grid stability energy storage technologies and advanced control strategies. The review highlights the importance of energy storage solutions like battery energy storage systems hydrogen storage pumped hydro storage and flywheels in enhancing grid resilience and supporting frequency and voltage regulation. Advanced control strategies including grid-forming and grid-following inverters as well as digital twins and predictive analytics emerged as effective in maintaining grid efficiency. Real-world case studies from islands such as El Hierro Hawai’i and Nusa Penida illustrate successful strategies and best practices emphasizing the role of supportive policies and community engagement. While the findings demonstrate that fully renewable island systems are technically and economically feasible challenges remain including regulatory financial and policy barriers.
Nanomaterials and Hydrogen Production: A Comprehensive Review of Clean Energy Strategies, Costs, and Environmental Implications
Aug 2025
Publication
An increasing demand for energy coupled with rising pollution levels is driving the search for environmentally clean alternative energy resources to replace fossil fuels. Hydrogen has emerged as a promising clean energy carrier and raw material for various applications. However its environmental benefits depend on sustainable production methods. The rapid development of nanomaterials (NMs) has opened new avenues for the conversion and utilization of renewable energy (RE). NMs are becoming increasingly important in addressing challenges related to hydrogen (H₂) generation. This review provides an overview of current advancements in H₂ production from biomass via thermochemical (TC) and biological (BL) processes including associated costs and explores the applications of nanomaterials in these methods. Research indicates that biological hydrogen (BL-H₂) production remains costly. The challenges associated with the TC conversion process are examined along with potential strategies for improvement. Finally the technical and economic obstacles that must be overcome before hydrogen can be widely adopted as a fuel are discussed.
Decarbonizing Insular Energy Systems: A Literature Review of Practical Strategies for Replacing Fossil Fuels with Renewable Energy Sources
Feb 2025
Publication
The reliance on fossil fuels for electricity production in insular regions creates critical environmental economic and logistical challenges particularly for ecologically fragile islands. Transitioning to renewable energy is essential to mitigate these impacts enhance energy security and preserve unique ecosystems. This systematic review addresses key research questions: what practical strategies have proven effective in reducing fossil fuel dependency in island contexts and what barriers hinder their widespread adoption? By applying the PRISMA methodology this study examines a decade (2014–2024) of research on renewable energy systems highlighting successful initiatives such as the integration of solar and wind systems in Hawaii energy storage advancements in La Graciosa hybrid renewable grids in the Galápagos Islands and others. Specific barriers include high upfront costs regulatory challenges and technical limitations such as grid instability due to renewable energy intermittency. This review contributes by synthesizing lessons from diverse case studies and identifying innovative approaches like hydrogen storage predictive control systems and community-driven renewable projects. The findings offer actionable insights for policymakers and researchers to accelerate the transition towards sustainable energy systems in island environments.
A Review of Gas Phase Inhibition of Gaseous Hydrogen Embrittlement in Pipeline Steels
Feb 2024
Publication
The addition of small amounts of certain gases such as O2 CO and SO2 may mitigate hydrogen embrittlement in high-pressure gas transmission pipelines that transport hydrogen. To practically implement such inhibition in gas transmission pipelines a comprehensive understanding and quantification of this effect are essential. This review examines the impact of various added gases to hydrogen including typical odorants on gaseous hydrogen embrittlement of steels and evaluates their inhibition effectiveness. O2 CO and SO2 were found to be effective inhibitors of hydrogen embrittlement. Yet the results in the literature have not always been consistent partly because of the diverse range of mechanical tests and their parameters. The absence of systematic studies hinders the evaluation of the feasibility of using gas phase inhibitors for controlling gaseous hydrogen embrittlement. A method to quantify the effectiveness of gas phase inhibition is proposed using gas phase permeation studies.
Technical Review of Commercial LT-PEMFC Technologies: Performance, Applications and Challenges
Sep 2025
Publication
This manuscript presents a comprehensive technical review of low-temperature proton exchange membrane fuel cells (LT-PEMFCs) focusing on their performance applications and current challenges within commercial contexts. LT-PEMFCs have reached commercial deployment in light-duty vehicles buses trains heavy-duty trucks stationary combined heat and power units and early maritime platforms. This review consolidates datasheetbased specifications and reconstructed performance parameters from leading manufacturers complemented by qualitative evidence from large-scale deployments in Japan and China to provide the first cross-sectoral benchmarking of LT-PEMFC systems. The analysis is structured around the key performance indicators (KPIs) of the Clean Hydrogen Joint Undertaking and the U.S. Department of Energy which define quantitative targets for 2024 and 2030. Results show that while several light-duty and bus platforms already meet or approach KPI compliance for hydrogen consumption and efficiency other sectors such as heavy-duty stationary and maritime remain below target ranges due to integration constraints and limited transparency in datasheet reporting. The study further highlights divergences between laboratory-reported stack metrics and commercial module specifications demonstrating the need for harmonized definitions of volumetric power density efficiency at rated power and durability. By situating catalogue-only and prototype systems within the technological pipeline the review clarifies how near-term developments may close performance gaps and reduce platinum dependency while also acknowledging the economic and infrastructural dimensions that condition future adoption. This includes recent advances in PGM-free catalysts alloyed and core–shell architectures and ionomer-free electrodes which complement low-PGM approaches in reducing material cost and supply risk. The contribution lies in delivering a transparent and replicable framework that not only maps the current state of LT-PEMFC commercialization but also provides directionality for research policy and industrial innovation on the pathway to 2030 deployment objectives. This represents the first systematic cross-sectoral benchmarking of LTPEMFCs that integrates datasheet-derived and reconstructed specifications with DOE and CHJU KPI frameworks providing both quantitative visualizations and a replicable methodology that clarifies current achievements while indicating where targeted innovation is needed to reach 2030 objectives.
An Overview of Photocatalyst Eco-design and Development for Green Hydrogen Production
Feb 2024
Publication
Photocatalysis emerged as a promising alternative to address fossil fuel scarcity and the limitations of other clean energy sources. Photocatalysis enables hydrogen production via water splitting using photocatalysts and light irradiation which can be stored and utilized across various applications. Photocatalysis has exhibited significant improvements and promising yields in hydrogen production surpassing its initial stages. The current photocatalyst market offers diverse materials with unique characteristics and continuous evolution is observed in their synthesis methods. This contribution aims to compile recent literature on advancements in photocatalysts for hydrogen production with particular emphasis on photocatalyst type hydrogen production performance and market trends.
A Review of Influence of Hydrogen on Fracture Toughness and Mechanical Properties of Gas Transmission Pipeline Steels
Jan 2025
Publication
The existing gas transmission pipeline network can be a convenient and cost-effective way to transport hydrogen. However hydrogen can cause hydrogen embrittlement (HE) of the steels used in pipeline construction. HE is typically manifested as a reduction in fracture toughness and ductility. To ensure structural integrity it is thus important to understand the fracture toughness of pipeline steels in hydrogen gas at pipeline pressures. This paper reviews (i) the influence of hydrogen on the fracture toughness of pipeline steels and (ii) the phenomena that occurs during fracture toughness tests of pipeline steel in air and hydrogen. Also reviewed are (i) the in fluence of hydrogen on tensile properties and (ii) the diffusion and solubility of hydrogen in pipeline steels under conditions relevant to hydrogen transport in gas transmission pipelines.
Analysis for the Implementation of Surplus Hydropower for Green Hydrogen Production in Ecuador
Dec 2024
Publication
This study investigates the feasibility of utilizing surplus hydropower from Ecuador’s major hydroelectric plants to produce green hydrogen a clean energy source that can be used to meet a large percentage of energy needs. Given Ecuador’s significant hydropower infrastructure this approach leverages untapped energy resources for hydrogen production with potential impacts on decarbonization strategies. A Pareto analysis identified five key hydroelectric plants that contribute the most to the national surplus. Using historical data from 2019 to 2023 a stochastic model was applied to estimate future surplus availability through 2030. The findings indicate that although Ecuador’s surplus hydropower peaked in 2021 the general trend shows a decline suggesting an urgent need to capitalize on these resources efficiently. The results indicate a projected annual surplus of hydroelectric energy in Ecuador ranging from 7475 to 3445 GWh over the next five years which could be utilized for green hydrogen production. Ecuador thus has promising potential to become a green hydrogen producer enhancing both regional energy security and carbon reduction goals. The reduction in energy availability for hydrogen production is attributed to the increasing energy demand and variable climatic conditions.
Performance Analysis of Hybrid Solar/H2/Battery Renewable Energy System for Residential Electrification
Mar 2019
Publication
Due to the privileged location of Ecuador in terms of solar radiation the analysis and use of renewable energy system (RES) using solar energy has been of great interest during the last years. At the same time the supply support of RES in terms of direct current (DC) can be faced by using fuel cell (FC) systems which can give to the systems fully autonomy from fossil fuels. The aim of this paper is to propose the design of a hybrid photovoltaic-fuel cell-battery (PV-FC-B) system to supply the required electrical energy for residential use in the city of Guayaquil. The feasibility analysis constitutive elements of the system and adjusted variables are computed and presented using a computational tool. The results evidence that this system is not economically viable since the cost of energy (COE) in Ecuador is low compared to the COE of the proposed system. However a more detailed analysis considering the inherent benefits of no emission of pollutant gases is required to have a complete outlook.
Laboratory Studies on Underground H2 Storage: Bibliometric Analysis and Review of Current Knowledge
Dec 2024
Publication
: The global demand for energy and the need to mitigate climate change require a shift from traditional fossil fuels to sustainable and renewable energy alternatives. Hydrogen is recognized as a significant component for achieving a carbon-neutral economy. This comprehensive review examines the underground hydrogen storage and particularly laboratory-scale studies related to rock– hydrogen interaction exploring current knowledge. Using bibliometric analysis of data from the Scopus and Web of Science databases this study reveals an exponential increase in scientific publications post-2015 which accounts for approximately 85.26% of total research output in this field and the relevance of laboratory experiments to understand the physicochemical interactions of hydrogen with geological formations. Processes in underground hydrogen storage are controlled by a set of multi-scale parameters including solid properties (permeability porosity composition and geomechanical properties) and fluid properties (liquid and gas density viscosity etc.) together with fluid–fluid and solid–fluid interactions (controlled by solubility wettability chemical reactions etc.). Laboratory experiments aim to characterize these parameters and their evolution simulating real-world storage conditions to enhance the reliability and applicability of findings. The review emphasizes the need to expand research efforts globally to comprehensively address the currently existing issues and knowledge gaps.
Green Hydrogen Production—Fidelity in Simulation Models for Technical–Economic Analysis
Nov 2024
Publication
Green hydrogen production is a sustainable energy solution with great potential offering advantages such as adaptability storage capacity and ease of transport. However there are challenges such as high energy consumption production costs demand and regulation which hinder its largescale adoption. This study explores the role of simulation models in optimizing the technical and economic aspects of green hydrogen production. The proposed system which integrates photovoltaic and energy storage technologies significantly reduces the grid dependency of the electrolyzer achieving an energy self-consumption of 64 kWh per kilogram of hydrogen produced. By replacing the high-fidelity model of the electrolyzer with a reduced-order model it is possible to minimize the computational effort and simulation times for different step configurations. These findings offer relevant information to improve the economic viability and energy efficiency in green hydrogen production. This facilitates decision-making at a local level by implementing strategies to achieve a sustainable energy transition.
Experimental and Numerical Analysis of Hydrogen-Induced Effects in ASTM A131 and A36 Steels for Naval Fuel Systems
Oct 2025
Publication
Hydrogen embrittlement (HE) can degrade the mechanical integrity of steel pipes increasing failure risks in naval fuel systems. This study assesses HE effects on ASTM A131 and A36 steels through tensile testing and numerical modeling. Tests conducted with varying exposure times to hydrogen revealed that A131 outperformed A36 in terms of mechanical strength. However both materials experienced property degradation after six hours. After nine hours a transient increase in strength occurred due to temporary microstructural hardening though the overall trend remained a decline. The maximum reductions in ultimate tensile strength and toughness were 19% and 47% for A131 and 39% and 61% for A36 respectively. Additionally microstructural analysis revealed the presence of inclusions intergranular decohesion and micro-crack in specimens exposed for longer periods. Finally a combined GTN-PLNIH numerical model was implemented demonstrating its effectiveness in predicting the mechanical behavior of structures exposed to hydrogen.
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