Qatar
Look-ahead Scheduling of Energy-Water Nexus Integrated with Power2X Conversion Technologies under Multiple Uncertainties
Aug 2023
Publication
Co-optimizing energy and water resources in a microgrid can increase efficiency and improve economic performance. Energy-water storage (EWS) devices are crucial components of a high-efficient energy-water microgrid (EWMG). The state of charge (SoC) at the end of the first day of operation is one of the most significant variables in EWS devices since it is used as a parameter to indicate the starting SoC for the second day which influences the operating cost for the second day. Hence this paper examines the benefits and applicability of a lookahead optimization strategy for an EWMG integrated with multi-type energy conversion technologies and multienergy demand response to supply various energy-water demands related to electric/hydrogen vehicles and commercial/residential buildings with the lowest cost for two consecutive days. In addition a hybrid info-gap/robust optimization technique is applied to cover uncertainties in photovoltaic power and electricity prices as a tri-level optimization framework without generating scenarios and using the probability distribution functions. Duality theory is also used to convert the problem into a single-level MILP so that it can be solved by CPLEX. According to the findings the implemented energy-water storage systems and look-ahead strategy accounted for respectively 4.03% and 0.43% reduction in the total cost.
Developing Hydrogen Strategies for Fossil Fuel Exporting Countries Under Uncertainty: The Case of Qatar
Mar 2025
Publication
The economies of fossil fuel exporters are threatened by global efforts to transition away from using unabated fossil fuels. Producing clean hydrogen for export or domestic use in manufacturing provides a potentially major opportunity to continue exploiting their fossil fuel resources. However the substantial uncertainties affecting the future of clean hydrogen make developing hydrogen strategies complex. This paper characterizes such uncertainties and conducts an initial assessment of possible investment risks and critical decisions associated with different strategies in the case of Qatar a leading exporter of natural gas. We find that strategies mostly focused on using clean hydrogen domestically to produce clean commodities are relatively low risk; inversely becoming a leading exporter of clean hydrogen substantially increases investment risks. Also irrespective of the strategy higher investment is required in the early years suggesting that once a strategy is chosen changing path may prove difficult.
Current and Future Role of Natural Gas Supply Chains in the Transition to a Low-Carbon Hydrogen Economy: A Comprehensive Review on Integrated Natural Gas Supply Chain Optimisation Models
Nov 2023
Publication
Natural gas is the most growing fossil fuel due to its environmental advantages. For the economical transportation of natural gas to distant markets physical (i.e. liquefaction and compression) or chemical (i.e. direct and indirect) monetisation options must be considered to reduce volume and meet the demand of different markets. Planning natural gas supply chains is a complex problem in today’s turbulent markets especially considering the uncertainties associated with final market demand and competition with emerging renewable and hydrogen energies. This review study evaluates the latest research on mathematical programming (i.e. MILP and MINLP) as a decisionmaking tool for designing and planning natural gas supply chains under different planning horizons. The first part of this study assesses the status of existing natural gas infrastructures by addressing readily available natural monetisation options quantitative tools for selecting monetisation options and single-state and multistate natural gas supply chain optimisation models. The second part investigates hydrogen as a potential energy carrier for integration with natural gas supply chains carbon capture utilisation and storage technologies. This integration is foreseen to decarbonise systems diversify the product portfolio and fill the gap between current supply chains and the future market need of cleaner energy commodities. Since natural gas markets are turbulent and hydrogen energy has the potential to replace fossil fuels in the future addressing stochastic conditions and demand uncertainty is vital to hedge against risks through designing a responsive supply chain in the project’s early design stages. Hence hydrogen supply chain optimisation studies and the latest works on hydrogen–natural gas supply chain optimisation were reviewed under deterministic and stochastic conditions. Only quantitative mathematical models for supply chain optimisation including linear and nonlinear programming models were considered in this study to evaluate the effectiveness of each proposed approach.
Alternative Fuels in Sustainable Logistics—Applications, Challenges, and Solutions
Sep 2024
Publication
Logistics is becoming more cost competitive while customers and regulatory bodies pressure businesses to disclose their carbon footprints creating interest in alternative fuels as a decarbonization strategy. This paper provides a thematic review of the role of alternative fuels in sustainable air land and sea logistics their challenges and potential mitigations. Through an extensive literature survey we determined that biofuels synthetic kerosene natural gas ammonia alcohols hydrogen and electricity are the primary alternative fuels of interest in terms of environmental sustainability and techno-economic feasibility. In air logistics synthetic kerosene from hydrogenated esters and fatty acids is the most promising route due to its high technical maturity although it is limited by biomass sourcing. Electrical vehicles are favorable in road logistics due to cheaper green power and efficient vehicle designs although they are constrained by recharging infrastructure deployment. In sea logistics liquified natural gas is advantageous owing to its supply chain maturity but it is limited by methane slip control and storage requirements. Overall our examination indicates that alternative fuels will play a pivotal role in the logistics networks of the future.
Advances in Photothermal Catalysts for Solar-driven Hydrogen Production
Nov 2024
Publication
Hydrogen is increasingly recognized as a pivotal energy storage solution and a transformative alternative to conventional energy sources. This review summarizes the evolving landscape of global H2 production and consumption markets focusing on the crucial role of photothermal catalysts (PTCs) in driving Hydrogen evolution reactions (HER) particularly with regards to oxide selenide and telluride-based PTCs. Within this exploration the mechanisms of PTCs take center stage elucidating the intricacies of light absorption localized heating and catalytic activation. Essential optimization parameters ranging from temperature and irradiance to catalyst composition and pH are detailed for their paramount role in enhancing catalytic efficiency. This work comprehensively explores photothermal catalysts (PTCs) for hydrogen production by assessing their synthesis techniques and highlighting the current research gaps particularly in optimizing catalytic stability light absorption and scalability. The energy-efficient nature of oxide selenide and telluride-based PTCs makes them prime candidates for sustainable H2 production when compared to traditional materials. By analyzing a range of materials we summarize key performance metrics including hydrogen evolution rates ranging from 0.47 mmolh− 1 g− 1 for Ti@TiO2 to 22.50 mmolh− 1 g− 1 for Mn0.2Cd0.8S/NiSe2. The review concludes with a strategic roadmap aimed at enhancing PTC performance to meet the growing demand for renewable hydrogen as well as a critical literature review addressing challenges and prospects in deploying PTCs.
Hydrogen Energy Systems: Technologies, Trends, and Future Prospects
May 2024
Publication
This review critically examines hydrogen energy systems highlighting their capacity to transform the global energy framework and mitigate climate change. Hydrogen showcases a high energy density of 120 MJ/kg providing a robust alternative to fossil fuels. Adoption at scale could decrease global CO2 emissions by up to 830 million tonnes annually. Despite its potential the expansion of hydrogen technology is curtailed by the inefficiency of current electrolysis methods and high production costs. Presently electrolysis efficiencies range between 60 % and 80 % with hydrogen production costs around $5 per kilogram. Strategic advancements are necessary to reduce these costs below $2 per kilogram and push efficiencies above 80 %. Additionally hydrogen storage poses its own challenges requiring conditions of up to 700 bar or temperatures below −253 °C. These storage conditions necessitate the development of advanced materials and infrastructure improvements. The findings of this study emphasize the need for comprehensive strategic planning and interdisciplinary efforts to maximize hydrogen's role as a sustainable energy source. Enhancing the economic viability and market integration of hydrogen will depend critically on overcoming these technological and infrastructural challenges supported by robust regulatory frameworks. This comprehensive approach will ensure that hydrogen energy can significantly contribute to a sustainable and low-carbon future.
Optimizing Post-production Alternate Hydrogen Supply Chain Pathways - An Integrated TEA and LCA Approach
Dec 2024
Publication
This study presents a comprehensive techno-economic assessment (TEA) of alternative hydrogen supply chain (HSC) pathways with a focus on the conditioning transportation and reconditioning stages. The pathways assessed include compressed hydrogen liquefied hydrogen and ammonia as a hydrogen carrier. A distinctive feature of this study is its consideration of a broad range of operational capacities and transportation distances facility economies of scale and multiple vessel capacities. The TEA is complemented by a life cycle assessment (LCA) to incorporate environmental impacts ensuring a holistic analysis of economic and environmental tradeoffs. The results reveal that the compressed hydrogen pathway is optimal for short distances and low-demand scenarios with levelized costs of hydrogen (LCOH) ranging from $1.11/kg to $6.91/kg. Liquefied hydrogen shows economic competitiveness for medium distances with LCOH between $1.43/kg and $3.84/kg. Ammonia emerges as the most cost-effective for longer distances and higher demand levels with LCOH between $1.61/kg and $3.80/kg. However the LCA analysis revealed that the ammonia pathway incurs higher emissions particularly during the ammonia synthesis and cracking processes making it less promising from an integrated perspective. This integration of LCA results into the TEA framework provides a comprehensive view of each pathway accounting for both economic and environmental factors. This study provides a robust framework for guiding decision-makers in the development of an effective hydrogen supply chain integrating both economic and environmental considerations.
Feasibility Study on the Provision of Electricity and Hydrogen for Domestic Purposes in the South of Iran using Grid-connected Renewable Energy Plants
Dec 2018
Publication
This work presents a feasibility study on the provision of electricity and hydrogen with renewable grid connected and off-the-grid systems for Bandar Abbas City in the south of Iran. The software HOMER Pro® has been used to perform the analysis. A techno-enviro-economic study comparing a hybrid system consisting of the grid/wind turbine and solar cell is done. The wind turbine is analyzed using four types of commercially available vertical axis wind turbines (VAWTs). According to the literature review no similar study has been performed so far on the feasibility of using VAWTs and also no work exists on the use of a hybrid system in the studied area. The results indicated that the lowest price of providing the required hydrogen was $0.496 which was achieved using the main grid. Also the lowest price of the electricity generated was $1.55 which was obtained through using EOLO VAWT in the main grid/wind turbine/solar cell scenario. Also the results suggested that the highest rate of preventing CO2 emission which was also the lowest rate of using the national grid with 3484 kg/year was associated with EOLO wind turbines where only 4% of the required electricity was generated by the national grid.
Numerical Investigation of the Potential of Using Hydrogen as an Alternative Fuel in an Industrial Burner
Dec 2024
Publication
This study investigates hydrogen and hydrogen-methane mixtures as alternative fuels for industrial burners focusing on combustion dynamics flame stability and emissions. CFD simulations in ANSYS Fluent utilized the RANS framework with the k-ε turbulence model and the mixture fraction/PDF approach. Supporting Python scripts and Cantera-based kinetic modeling employing the GRI-Mech 3.0 mechanism and Zeldovich pathways analyzed equivalence ratios (Φ) adiabatic flame temperatures (Tad) and NOx formation mechanisms. Results revealed non-linear temperature trends with a 50 % hydrogen blend yielding the lowest peak temperature (1880 K) and a 75 % hydrogen blend achieving optimal performance balancing peak temperatures (~1900 K) reduced NOx emissions (5.39 × 10-6) and near-zero CO2 emissions (0.137) though flame stability was impacted by rich mixtures. Pure hydrogen combustion produced the highest peak temperature (2080 K) and NOx emissions (3.82 × 10-5) highlighting the need for NOx mitigation strategies. Mass flow rate (MFR) adjustments and excess air variation significantly influenced emissions with a 25 % MFR increase reducing NOx to 2.8 × 10-5 while higher excess air (e.g. 30 %) raised NOx under lean conditions. Statistical analysis identified Φ hydrogen content (H2%) and flame stability as key factors with 50 %–75 % hydrogen blends minimizing emissions and optimizing performance emphasizing hydrogen’s potential with controlled MFR and air adjustments.
A Review on Underground Gas Storage Systems: Natural Gas, Hydrogen and Carbon Sequestration
May 2023
Publication
The concept of underground gas storage is based on the natural capacity of geological formations such as aquifers depleted oil and gas reservoirs and salt caverns to store gases. Underground storage systems can be used to inject and store natural gas (NG) or hydrogen which can be withdrawn for transport to end-users or for use in industrial processes. Geological formations can additionally be used to securely contain harmful gases such as carbon dioxide deep underground by means of carbon capture and sequestration technologies. This paper defines and discusses underground gas storage highlighting commercial and pilot projects and the behavior of different gases (i.e. CH4 H2 and CO2) when stored underground as well as associated modeling investigations. For underground NG/H2 storage the maintenance of optimal subsurface conditions for efficient gas storage necessitates the use of a cushion gas. Cushion gas is injected before the injection of the working gas (NG/H2). The behavior of cushion gas varies based on the type of gas injected. Underground NG and H2 storage systems operate similarly. However compared to NG storage several challenges could be faced during H2 storage due to its low molecular mass. Underground NG storage is widely recognized and utilized as a reference for subsurface H2 storage systems. Furthermore this paper defines and briefly discusses carbon capture and sequestration underground. Most reported studies investigated the operating and cushion gas mixture. The mixture of operating and cushion gas was studied to explore how it could affect the recovered gas quality from the reservoir. The cushion gas was shown to influence the H2 capacity. By understanding and studying the different underground system technologies future directions for better management and successful operation of such systems are thereby highlighted.
It Is Not the Same Green: A Comparative LCA Study of Green Hydrogen Supply Network Pathways
Jul 2024
Publication
Green hydrogen (H2 ) a promising clean energy source garnering increasing attention worldwide can be derived through various pathways resulting in differing levels of greenhouse gas emissions. Notably Green H2 production can utilize different methods such as integrating standard photovoltaic panels thermal photovoltaic or concentrated photovoltaic thermal collectors with electrolyzers. Furthermore it can be conditioned to different states or carriers including liquefied H2 compressed H2 ammonia and methanol and stored and transported using various methods. This paper employs the Life Cycle Assessment methodology to compare 18 different green hydrogen pathways and provide recommendations for greening the hydrogen supply chain. The findings indicate that the production pathway utilizing concentrated photovoltaic thermal panels for electricity generation and hydrogen compression in the conditioning and transportation stages exhibits the lowest environmental impact emitting only 2.67 kg of CO2 per kg of H2 .
Comparative Study of LNG, Liquid Hydrogen ,and Liquid Ammonia Post-release Evaporation and Dispersion During Bunkering
Apr 2024
Publication
The use of alternative fuels is a primary means for decarbonising the maritime industry. Liquefied natural gas (LNG) liquid hydrogen (LH2) and liquid ammonia (LNH3) are liquified gases among the alternative fuels. The safety risks associated with these fuels differ from traditional fuels. In addition to their low-temperature hazards the flammability of LNG and LH2 and the high toxicity of LNH3 present challenges in fuel handlings due to their high likelihood of fuel release during bunkering. This study aims at drawing extensive comparisons of the evaporation and vapour dispersion behaviours for the three fuels after release accidents during bunkering and discuss their safety issues. The study involved the release event of the three fuels on the main deck area of a reference bulk carrier with a deadweight of 208000 tonnes. Two release scenarios were considered: Scenario 1 involved a release of 0.3 m3 of fuel and Scenario 2 involved a release of 100 kg of fuel. An empirical equation was used to calculate the fuel evaporation process and the Computational Fluid Dynamic (CFD) code FDS was employed to simulate the dispersion of vapour clouds. The obtained results reveal that LH2 has the highest evaporation rate followed by LNG and LNH3. The vapour clouds of LNG and LNH3 spread along the main deck surface while the LH2 vapour cloud exhibits upward dispersion. The flammable vapour clouds of LNG and LH2 remain within the main deck area whereas the toxic gas cloud of LNH3 disperses towards the shore and spreads near the ground on the shore side. Based on the dispersion behaviours the hazards of LNG and LH2 are com parable while LNH3 poses significantly higher hazards. In terms of hazard mitigations effective water curtain systems can suppress the vapour dispersion.
Techno-economic Analysis of Stand-alone Hybrid PV-Hydrogen-Based Plug-in Electric Vehicle Charging Station
Sep 2024
Publication
The increase in the feasibility of hydrogen-based generation makes it a promising addition to the realm of renewable energies that are being employed to address the issue of electric vehicle charging. This paper presents technical and an economical approach to evaluate a newer off-grid hybrid PV-hydrogen energy-based recharging station in the city of Jamshoro Pakistan to meet the everyday charging needs of plug-in electric vehicles. The concept is designed and simulated by employing HOMER software. Hybrid PV-hydrogen and PV-hydrogenbattery are the two different scenarios that are carried out and compared based on their both technical as well as financial standpoints. The simulation results are evident that the hybrid PV- hydrogen-battery energy system has much more financial and economic benefits as compared with the PV-hydrogen energy system. Moreover it is also seen that costs of energy from earlier from hybrid PV-hydrogen-battery is more appealing i.e. 0.358 $/kWh from 0.412 $/kWh cost of energy from hybrid PV-hydrogen. The power produced by the hybrid PV- hydrogen - battery energy for the daily load demand of 1700 kWh /day consists of two powers produced independently by the PV and fuel cells of 87.4 % and 12.6 % respectively.
A Comprehensive Review of Hydrogen Safety through a Metadata Analysis Framework
Feb 2025
Publication
Hydrogen is widely recognized as a promising clean energy carrier but its highly flammable and explosive nature presents significant safety challenges in its production storage transportation and usage. Addressing these challenges is critical for the successful integration of hydrogen into global energy systems aligning with the United Nations’ sustainable development goals to support the transition to a low-carbon future. This study aims to provide a comprehensive review of hydrogen safety through a metadata analysis framework focusing on risks challenges mitigation strategies and regulations for safe handling. Previous reviews have largely addressed general hydrogen safety concerns but none have systematically evaluated the issue from a data-driven perspective. This review fills that gap by analyzing research trends root causes of hydrogen’s unsafe handling such as its low molecular density broad flammability range and high permeability and exploring solutions such as chemical additives and gaseous inhibitors to improve safety. Utilizing bibliometric techniques and scientific mapping tools this study synthesizes extensive research spanning from 2000 to 2024 visualizing the evolution of hydrogen safety research and identifying critical areas for future inquiry. The findings contribute valuable insights into the safe deployment of hydrogen technologies offering recommendations for future research and regulatory advancements to mitigate risks and ensure hydrogen’s role in a sustainable energy future.
Planning Energy Hubs with Hydrogen and Battery Storage for Flexible Ramping Market Participation
Oct 2025
Publication
The integration of renewable resources with advanced storage technologies is critical for sustainable energy systems. In this paper a planning framework for an energy hub incorporating hydrogen and renewable energy systems is developed with the objective of minimizing operational costs while participating in flexible ramping product (FRP) markets. The energy hub is designed to utilize a hybrid storage system comprising multi-type battery energy storage (BESS) accounting for diverse chemistries and degradation behaviors and hydrogen storage (HS) to meet concurrent electric and hydrogen demands. To address uncertainties in renewable generation and market prices a stochastic optimization model is developed to determine the optimal investment capacities while optimizing operational decisions under uncertainty using scenario-based stochastic programming. Financial risks associated with price and renewable variability are mitigated through the Conditional Value-at-Risk (CVaR) metric. Case studies demonstrate that hybrid storage systems including both BESS and HS can reduce total costs by 23.62% compared to single-storage configurations that rely solely on BESS. Based on the results BESS participates more in providing flexible ramp-up services while HS plays a major role in providing flexible ramp-down services. The results emphasize the critical role of co-optimized hydrogen and multi-type BESS in enhancing grid flexibility and economic viability.
Technoeconomic analysis of Hydrogen Versus Natural Gas Considering Safety Hazards and Energy Efficiency Indicators
Aug 2025
Publication
Hydrogen (H2) is emerging as a key alternative to fossil fuels in the global energy transition. This study presents a comparative techno-economic analysis of H2 and natural gas (NG) focusing on safety hazards energy output CO2 emissions and cost-effectiveness aspects. Our analysis showed that compared to NG and other highly flammable gases like acetylene (C2 H2) and propane (C3 H8) H2 has a higher hazard potential due to factors such as its wide flammability range low ignition energy and high flame speed. In terms of energy output 1 kg of NG produces 48.60 MJ while conversion to liquefied natural gas (LNG) grey H2 and blue H2 reduces energy output to 45.96 MJ 35.45 MJ and 31.21 MJ respectively. Similarly while unconverted NG emits 2.72 kg of CO2 per kg emissions increase to 3.12 kg for LNG and 3.32 kg for grey H2. However blue H2 significantly reduces CO2 emissions to 1.05 kg per kg due to carbon capture and storage. From an economic perspective producing 1 kg of NG yields a profit of $0.011. Converting NG to grey H2 is most profitable yielding a net profit of $0.609 per kg of NG while blue H2 despite higher production costs remains viable with a profit of $0.390 per kg of NG. LNG conversion also shows profitability with $0.061 per kg of NG. This analysis highlights the trade-offs between energy efficiency environmental impact and economic viability providing valuable insights for stakeholders formulating hydrogen and LNG implementation strategies.
Preliminary Feasibility Study of Using Hydrogen as a Fuel for an Aquaculture Vessel in Tasmania, Australia
Oct 2025
Publication
Decarbonising aquaculture support vessels is pivotal to reducing greenhouse gas (GHG) emissions across both the aquaculture and maritime sectors. This study evaluates the technical and economic feasibility of deploying hydrogen as a marine fuel for a 14.95 m net cleaning vessel (NCV) operating in Tasmania Australia. The analysis retains the vessel’s original layout and subdivision to enable a like-for-like comparison between conventional diesel and hydrogen-based systems. Two options are evaluated: (i) replacing both the main propulsion engines and auxiliary generator sets with hydrogen-based systems— either proton exchange membrane fuel cells (PEMFCs) or internal combustion engines (ICEs); and (ii) replacing only the diesel generator sets with hydrogen power systems. The assessment covers system sizing onboard hydrogen storage integration operational constraints lifecycle cost and GHG abatement. Option (i) is constrained by the sizes and weights of PEMFC systems and hydrogen-fuelled ICEs rendering full conversion unfeasible within current spatial and technological limits. Option (ii) is technically feasible: sixteen 700 bar cylinders (131.2 kg H2 total) meet one day of onboard power demand for net-cleaning operations with bunkering via swap-and-go skids at the berth. The annualised total cost of ownership for the PEMFC systems is 1.98 times that of diesel generator sets while enabling annual CO2 reductions of 433 t. The findings provide a practical decarbonisation pathway for small- to medium-sized service vessels in niche maritime sectors such as aquaculture while clarifying near-term trade-offs between cost and emissions.
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