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Chemical Utilization of Hydrogen from Fluctuating Energy Sources- Catalytic Transfer Hydrogenation from Charged Liquid Organic Hydrogen Carrier Systems

Abstract

Liquid Organic Hydrogen Carrier (LOHC) systems offer a very attractive way for storing and distributing hydrogen from electrolysis using excess energies from solar or wind power plants. In this contribution, an alternative, high-value utilization of such hydrogen is proposed namely its use in steady-state chemical hydrogenation processes. We here demonstrate that the hydrogen-rich form of the LOHC system dibenzyltoluene/perhydro-dibenzyltoluene can be directly applied as sole source of hydrogen in the hydrogenation of toluene, a model reaction for large-scale technical hydrogenations. Equilibrium experiments using perhydro-dibenzyltoluene and toluene in a ratio of 1:3 (thus in a stoichiometric ratio with respect to H2) yield conversions above 60%, corresponding to an equilibrium constant significantly higher than 1 under the applied conditions (270 °C).

Countries: Germany
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/content/journal1241
2015-11-07
2022-08-10
http://instance.metastore.ingenta.com/content/journal1241
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