Production & Supply Chain
Feasibility Study of "CO2 Free Hydrogen Chain" Utilizing Australian Brown Coal Linked with CCS
Nov 2012
Publication
We had investigated feasible measures to reduce CO2 emission and came to conclusion that introduction of new fuel such as hydrogen with near zero CO2 emission is required for achieving Japan’s commitment of 80% CO2 reduction by 2050. Under this background we are proposing and aiming to realize “CO2 free hydrogen chain” utilizing Australian brown coal linked with CCS. In this chain hydrogen produced from brown coal is liquefied and transported to Japan by liquid hydrogen carrier. We have conducted feasibility study of commercial scale “CO2 free hydrogen chain” whose result shows the chain is technically and economically feasible.
Techno-economic Assessment of Blue and Green Ammonia as Energy Carriers in a Low-carbon Future
Feb 2022
Publication
Ammonia is an industrial chemical and the basic building block for the fertilizer industry. Lately attention has shifted towards using ammonia as a carbon-free energy vector due to the ease of transportation and storage in liquid state at − 33 ◦C and atmospheric pressure. This study evaluates the prospects of blue and green ammonia as future energy carriers; specifically the gas switching reforming (GSR) concept for H2 and N2 co-production from natural gas with inherent CO2 capture (blue) and H2 generation through an optimized value chain of wind and solar power electrolysers cryogenic N2 supply and various options for energy storage (green). These longer term concepts are benchmarked against conventional technologies integrating CO2 capture: the Kellogg Braun & Root (KBR) Purifier process and the Linde Ammonia Concept (LAC). All modelled plants utilize the same ammonia synthesis loop for a consistent comparison. A cash flow analysis showed that the GSR concept achieved an attractive levelized cost of ammonia (LCOA) of 332.1 €/ton relative to 385.1–385.9 €/ton for the conventional plants at European energy prices (6.5 €/GJ natural gas and 60 €/MWh electricity). Optimal technology integration for green ammonia using technology costs representative of 2050 was considerably more expensive: 484.7–772.1 €/ton when varying the location from Saudi Arabia to Germany. Furthermore the LCOA of the GSR technology drops to 192.7 €/ton when benefitting from low Saudi Arabian energy costs (2 €/GJ natural gas and 40 €/MWh electricity). This cost difference between green and blue ammonia remained robust in sensitivity analyses where input energy cost (natural gas or wind/solar power) was the most influential parameter. Given its low production costs and the techno-economic feasibility of international ammonia trade advanced blue ammonia production from GSR offers an attractive pathway for natural gas exporting regions to contribute to global decarbonization.
Towards Net-zero Compatible Hydrogen from Steam Reformation - Techno-economic Analysis of Process Design Options
Dec 2022
Publication
Increased consumption of low-carbon hydrogen is prominent in the decarbonisation strategies of many jurisdictions. Yet prior studies assessing the current most prevalent production method steam reformation of natural gas (SRNG) have not sufficiently evaluated how process design decisions affect life cycle greenhouse gas (GHG) emissions. This techno-economic case study assesses cradle-to-gate emissions of hydrogen produced from SRNG with CO2 capture and storage (CCS) in British Columbia Canada. Four process configurations with amine-based CCS using existing technology and novel process designs are evaluated. We find that cradle-to-gate GHG emission intensity ranges from 0.7 to 2.7 kgCO2e/kgH2 – significantly lower than previous studies of SRNG with CCS and similar to the range of published estimates for hydrogen produced from renewable-powered electrolysis. The levelized cost of hydrogen (LCOH) in this study (US$1.1–1.3/kgH2) is significantly lower than published estimates for renewable-powered electrolysis.
Opportunities for Flexible Electricity Loads such as Hydrogen Production from Curtailed Generation
Jun 2021
Publication
Variable low-cost low-carbon electricity that would otherwise be curtailed may provide a substantial economic opportunity for entities that can flexibly adapt their electricity consumption. We used historical hourly weather data over the contiguous U.S. to model the characteristics of least-cost electricity systems dominated by variable renewable generation that powered firm and flexible electricity demands (loads). Scenarios evaluated included variable wind and solar power battery storage and dispatchable natural gas with carbon capture and storage with electrolytic hydrogen representing a prototypical flexible load. When flexible loads were small excess generation capacity was available during most hours allowing flexible loads to operate at high capacity factors. Expanding the flexible loads allowed the least-cost systems to more fully utilize the generation capacity built to supply firm loads and thus reduced the average cost of delivered electricity. The macro-scale energy model indicated that variable renewable electricity systems optimized to supply firm loads at current costs could supply 25% or more additional flexible load with minimal capacity expansion while resulting in reduced average electricity costs (10% or less capacity expansion and 10% to 20% reduction in costs in our modeled scenarios). These results indicate that adding flexible loads to electricity systems will likely allow more full utilization of generation assets across a wide range of system architectures thus providing new energy services with infrastructure that is already needed to supply firm electricity loads.
Photocatalytic Hydrogen Evolution from Biomass Conversion
Feb 2021
Publication
Biomass has incredible potential as an alternative to fossil fuels for energy production that is sustainable for the future of humanity. Hydrogen evolution from photocatalytic biomass conversion not only produces valuable carbon-free energy in the form of molecular hydrogen but also provides an avenue of production for industrially relevant biomass products. This photocatalytic conversion can be realized with efficient sustainable reaction materials (biomass) and inexhaustible sunlight as the only energy inputs. Reported herein is a general strategy and mechanism for photocatalytic hydrogen evolution from biomass and biomass-derived substrates (including ethanol glycerol formic acid glucose and polysaccharides). Recent advancements in the synthesis and fundamental physical/mechanistic studies of novel photocatalysts for hydrogen evolution from biomass conversion are summarized. Also summarized are recent advancements in hydrogen evolution efciency regarding biomass and biomass-derived substrates. Special emphasis is given to methods that utilize unprocessed biomass as a substrate or synthetic photocatalyst material as the development of such will incur greater benefts towards a sustainable route for the evolution of hydrogen and production of chemical feedstocks.
Techno-economic Evaluation of Medium Scale Power to Hydrogen to Combined Heat and Power Generation Systems
Jun 2022
Publication
The European Hydrogen Strategy and the new « Fit for 55 » package indicate the urgent need for the alignment of policy with the European Green Deal and European Union (EU) climate law for the decarbonization of the energy system and the use of hydrogen towards 2030 and 2050. The increasing carbon prices in EU Emission Trading System (ETS) as well as the lack of dispatchable thermal power generation as part of the Coal exit are expected to enhance the role of Combined Heat and Power (CHP) in the future energy system. In the present work the use of renewable hydrogen for the decarbonization of CHP plants is investigated for various fossil fuel substitution ratios and the impact of the overall efficiency the reduction of direct emissions and the carbon footprint of heat and power generation are reported. The analysis provides insights on efficient and decarbonized cogeneration linking the power with the heat sector via renewable hydrogen production and use. The levelized cost of hydrogen production as well as the levelized cost of electricity in the power to hydrogen to combined heat and power system are analyzed for various natural gas substitution scenarios as well as current and future projections of EU ETS carbon prices.
A Comprehensive Study on Production of Methanol from Wind Energy
Apr 2022
Publication
Methanol is a promising new alternative fuel that emits significantly less carbon dioxide than gasoline. Traditionally methanol was produced by gasifying natural gas and coal. Syn-Gas is created by converting coal and natural gas. After that the Syn-Gas is converted to methanol. Alternative renewable energy-to-methanol conversion processes have been extensively researched in recent years due to the traditional methanol production process’s high carbon footprint. Using an electrolysis cell wind energy can electrolyze water to produce hydrogen. Carbon dioxide is a gas that can be captured from the atmosphere and industrial processes. Carbon dioxide and hydrogen are combusted in a reactor to produce methanol and water; the products are then separated using a distillation column. Although this route is promising it has significant cost and efficiency issues due to the low efficiency of the electrolysis cells and high manufacturing costs. Additionally carbon dioxide capture is an expensive process. Despite these constraints it is still preferable to store excess wind energy in the form of methanol rather than sending it directly to the grid. This process is significantly more carbon-efficient and resource-efficient than conventional processes. Researchers have proposed and/or simulated a variety of wind power methods for methanol processes. This paper discusses these processes. The feasibility of wind energy for methanol production and its future potential is also discussed in this paper.
Technical Failures in Green Hydrogen Production and Reliability Engineering Responses: Insights from Database Analysis and a Literature Review
Nov 2024
Publication
Green hydrogen represents a promising solution for renewable energy application and carbon footprint reduc tion. However its production through renewable energy powered water electrolysis is hindered by significant cost arising from repair maintenance and economic losses due to unexpected downtimes. Although reliability engineering is highly effective in addressing such issues there is limited research on its application in the hydrogen field. To present the state-of-the-art research this study aims to explore the potential of reducing these events through reliability engineering a widely adopted approach in various industries. For this purpose it examines past accidents occurred in water electrolysis plants from the hydrogen incident and accident database (HIAD 2.1). Besides a literature review is performed to analyze the state-of-the-art application of reliability engineering techniques such as failure analysis reliability assessment and reliability-centered maintenance in the hydrogen sector and similar industries. The study highlights the contributions and potentials of reliability engineering for efficient and stable green hydrogen production while also discussing the gaps in applying this approach. The unique challenges posed by hydrogen’s physical properties and innovative technologies in water electrolysis plants necessitate advancement and specialized approaches for reliability engineering.
Decarbonization of Natural Gas Systems in the EU - Costs, Barriers, and Constraints of Hydrogen Production with a Case Study in Portugal
Jul 2022
Publication
The European Union (EU) imports a large amount of natural gas and the injection of renewable hydrogen (H2) into the natural gas systems could help decarbonize the sector. The new geopolitical and energy market situation demands urgent actions in the clean energy transition and energy independence from fossil fuels. This paper aims to investigate techno-economic analysis barriers and constraints in the EU policies/frameworks that affect natural gas decarbonization. First the study examines the levelized cost of hydrogen production (LCOH). The LCOH is evaluated for blue and grey hydrogen i.e. Steam Methane Reforming (SMR) natural gas as the feed stock with and without carbon capture and green hydrogen (three type electrolyzers with electricity from the grid solar and wind) for the years 2020 2030 and 2050. Second the study evaluates the current policies and framework based on a SWOT (Strength Weakness Opportunities and Weakness) analysis which includes a PEST (Political Economic Social and Technological) macro-economic factor assessment with a case study in Portugal. The results show that the cheapest production costs continue to be dominated by grey hydrogen (1.33 €/kg.H2) and blue hydrogen (1.68 €/kg.H2) in comparison to green hydrogen (4.65 €/kg.H2 and 3.54 €/kg.H2) from grid electricity and solar power in the PEM - Polymer Electrolyte Membrane for the year 2020 respectively. The costs are expected to decrease to 4.03 €/kg.H2 (grid-electricity) and 2.49 €/kg.H2 (solar – electricity) in 2030. The LCOH of the green grid-electricity and solar/wind-powered Alkaline Electrolyzer (ALK) and Solid Oxide Electrolyzer Cell (SOEC) are also expected to decrease in the time-span from 2020 to 2050. A sensitivity analysis shows that investments costs electricity price the efficiency of electrolyzers and carbon tax (for SMR) could play a key role in reducing LCOH thereby making the economic competitiveness of hydrogen production. The key barriers are costs amendments in rules/regulations institutions and market creation public perception provisions of incentives and constraints in creating market demand.
Internal Model Control for Onboard Methanol-Reforming Hydrogen Production Systems
Jan 2025
Publication
Methanol reforming is considered to be one of the most promising hydrogen production technologies for hydrogen fuel cells. It is expected to solve the problem of hydrogen storage and transportation because of its high hydrogen production rate low cost and good safety. However the strong nonlinearity and slow response of the pressure and temperature subsystems pose challenges to the tracking control of the methanol reforming hydrogen production system. In this paper two internal model-based temperature and pressure controllers are proposed in which the temperature is adjusted by controlling the air flow and the pressure is adjusted by controlling the opening of the backpressure valve. Firstly a lumped parameter model of the methanol reforming hydrogen production system is constructed using MATLAB/Simulink® (produced by MathWorks in Natick Massachusetts USA). In addition the transfer function model of the system is obtained by system identification at the equilibrium point and the internal model controller is further designed. The simulation results show that the control method achieves the robustness of the system and the temperature and pressure of the reforming reactor can quickly and accurately track the target value when the load changes. Small-load step tests indicate stable tracking of the temperature and pressure for the reforming reactor without steady-state errors. Under large-temperature step signal testing the response time for the reforming temperature is about 148 s while the large-pressure step signal test shows that the response time for the reforming pressure is about 8 s. Compared to the PID controller the internal model controller exhibits faster response zero steady-state error and no overshoot. The results show that the internal model control method has strong robustness and dynamic characteristics.
An Overview of Low-carbon Hydrogen Production via Water Splitting Driven by Piezoelectric and Pyroelectric Catalysis
Jun 2024
Publication
The focus on sustainable energy sources is intensifying as they present a viable alternative to conventional fossil fuels. The emergence of clean and renewable hydrogen fuel marks a significant technological shift toward decarbonizing the environment. Harnessing mechanical and thermal energy through piezoelectric and pyroelectric catalysis has emerged as an effective strategy for producing hydrogen and contributing to reducing dependence on carbon-based fuels. In this regard this review presents recent advances in piezoelectric and pyroelectric catalysis induced by mechanical and thermal excitations respectively towards hydrogen generation via the water splitting process. A thorough description of the fundamental principles underlying the piezoelectric and pyroelectric effects is provided complemented by an analysis of the catalytic processes induced by these effects. Subsequently these effects are examined to propose the prerequisites needed for such catalysts to achieve water splitting reaction and hydrogen generation. Special attention is devoted to identifying the various strategies adopted to enhance hydrogen production in order to provide new paths for increased efficiency.
Development of a Hydrophobic Coating for the Porous Gas Diffusion Layer in a PEM-based Electrochemical Hydrogen Pump to Mitigate Anode Flooding
Jan 2019
Publication
Anode flooding is one of the critical issues in developing a proton exchange membrane (PEM)-based electrochemical hydrogen pump. Improving the hydrophobicity of the gas diffusion layer (GDL) has been studied as an approach to mitigating anode flooding in electrochemical pumps. A mixture of Nafion™ and oxidized carbon nanotubes (O-CNT) has been applied to the porous gas diffusion medium in the hydrogen pump cell. The coating renders the GDL hydrophobic with an effective contact angle of 130°. Electrochemical pump testing has shown that with the help of the coating the flood-recovery performance of the hydrogen pump was greatly improved. A hydrogen pump cell with an uncoated GDL was not able to recover from a flooded state while a hydrogen pump cell with a coated GDL was able to recover its performance in about 100 s.
Network Evolutionary Game Analysis of Coal-to-Hydrogen CCUS Technology Dissemination in Carbon Trading Market
Jan 2025
Publication
Integrating coal-to-hydrogen production with Carbon Capture Utilization and Storage (CCUS) is essential for reducing greenhouse gas emissions and facilitating a shift towards a more sustainable energy paradigm. This paper explores the diffusion of CCUS technology within the coal-to-hydrogen sector against the dynamic backdrop of the carbon trading market. An evolutionary game-theoretic approach is utilized within a smallworld network framework to analyze the spread of CCUS technology among coal-tohydrogen enterprises. The simulation reveals that current market dynamics along with technological market and policy-related uncertainties do not robustly encourage the adoption of CCUS. As the carbon trading market continues to mature carbon prices become a significant factor influencing the diffusion of CCUS technology in coal-to-hydrogen processes. Furthermore investment costs hydrogen market prices and governmental policies are identified as pivotal elements in the propagation of CCUS technology. This study contributes valuable insights into the sustainable development of the hydrogen industry and the broader implications for low-carbon energy transition strategies.
Marine Renewable-Driven Green Hydrogen Production Toward a Sustainable Solution and a Low-carbon Future in Morocco
May 2024
Publication
Oceanic energy sources notably offshore wind and wave power present a significant opportunity to generate green hydrogen through water electrolysis. This approach allows for offshore hydrogen production which can be efficiently transported through existing pipelines and stored in various forms offering a versatile solution to tackle the intermittency of renewable energy sources and potentially revolutionize the entire electrical grid infrastructure. This research focusses on assessing the technical and economic feasibility of this method in six strategic coastal regions in Morocco: Laayoune Agadir Essaouira Eljadida Casablanca and Larache. Our proposed system integrates offshore wind turbines oscillating water column wave energy converters and PEM electrolyzers to meet energy demands while aligning with global sustainability objectives. Significant electricity production estimates are observed across these regions ranging from 14 MW to 20 MW. Additionally encouraging annual estimates of hydrogen production varying between 20 and 40 tonnes for specific locations showcase the potential of this approach. The system’s performance demonstrates promising efficiency rates ranging from 13% to 18% while maintaining competitive production costs. These findings underscore the ability of oceanic energy-driven green hydrogen to diversify Morocco’s energy portfolio bolster water resilience and foster sustainable development. Ultimately this research lays the groundwork for comprehensive energy policies and substantial infrastructure investments positioning Morocco on a trajectory towards a decarbonized future powered by innovative and clean technologies.
Decentralized Hydrogen-oxygen Co-production via Electrolysis for Large Hospitals with Integrated Hydrogen Refuelling Station
Jan 2025
Publication
In the pursuit of greener and more self-sufficient healthcare operations this study presents an integrated eco nomic and environmental analysis of on-site co-production of oxygen and hydrogen through proton exchange membrane electrolysis specifically designed for the Santa Maria Hospital in Lisbon Portugal. The proposed system aims to meet the hospital’s oxygen demand while simultaneously producing hydrogen for use in fuel cell electric vehicles such as ambulances. A 1.5 MW PEM electrolyser is found to be sufficient to meet the hospital’s O2 needs while generating hydrogen at a levelized cost of hydrogen of 4.6 €/kgH2. When considering the implementation costs of an on-site hydrogen refueling station an O2 drying and storage unit as well as the avoided costs in bulk liquid O2 purchases the break-even point for the sale of H2 at the refueling stations is 2.4 €/kgH2. Apart from the economic benefits that could be achieved by selling the produced H2 above this price the environmental analysis showed that 1874 tons of CO2 emissions per year could be avoided by the imple mentation of the concept proposed here. This integrated system not only contributes to the hospital’s energy independence but also serves as a model for sustainable solutions in the healthcare sector with significant environmental and financial benefits.
Hydrogen Production Towards a Carbon-free Economy: A Comprehensive Thermodynamic Analysis
Jan 2025
Publication
Sustainable hydrogen production is key to achieving zero-emission targets and a hydrogen-based economy. Hydrogen production methods vary in terms of resource technology and system efficiency. This work analyzes the thermodynamics of fourteen hydrogen production pathways using Gibbs free energy minimization to examine the effects of pressure (1–60 bar) temperature (100–1000 ◦C) and feed composition using reactant conversion and product selectivity as key indicators of reaction performance. The impact of simultaneous reactions on hydrogen production is also discussed. From the results full conversion (100 %) independent of parameter variations at 1 bar pressure was observed for biomass gasification and steam reforming of glycerol methanol ethanol and bio-oil reactions. However H2 selectivity in all tested reactions except for NH3 dissociation and the splitting of water and H2S is greatly affected by side reactions. Finally the thermodynamic results of all reactions are compared and validated with published experiments followed by an evaluation of the challenges and opportunities in hydrogen production. The study provides optimal reaction parameters and a comprehensive comparison of H2 production processes aiding in designing and developing processes based on regional resource availability. Additionally it highlights the potential for both local and remote hydrogen production pathways from various renewable energy sources.
Everything About Hydrogen Podcast: Nuclear-enabled Hydrogen at Port of Belledune
Jul 2024
Publication
The team sits down with Rishi Jain to discuss Cross River’s marquee wind hydro nuclear hydrogen ammonia project in the revitalized heavy industrial Port of Belledune New Brunswick Canada.
The podcast can be found on their website.
The podcast can be found on their website.
Recent Progress in Seawater Electrolysis for Hydrogen Evolution by Transition Metal Phosphides
Dec 2021
Publication
The electrocatalytic seawater splitting has become an important and necessary way for large-scale hydrogen production with challenges ahead. In this review a brief introduction to the reaction mechanism of seawater electrocatalytic process is first provided including the cathodic hydrogen evolution reaction and the anodic oxygen evolution reaction as well as the competitive chloride evolution reaction. Recent progress in transition metal phosphides-based catalysts for seawater electrolysis such as phosphorus doped transition metals binary metal phosphides and structural engineering are then evaluated and discussed. Finally the challenges and opportunities of transition metal phosphides are proposed and discussed.
A High-performance Capillary-fed Electrolysis Cell Promises More Cost-competitive Renewable Hydrogen
Mar 2022
Publication
Renewable or green hydrogen will play a critical role in the decarbonisation of hard-to-abate sectors and will therefore be important in limiting global warming. However renewable hydrogen is not cost-competitive with fossil fuels due to the moderate energy efficiency and high capital costs of traditional water electrolysers. Here a unique concept of water electrolysis is introduced wherein water is supplied to hydrogen- and oxygen-evolving electrodes via capillary-induced transport along a porous inter-electrode separator leading to inherently bubble-free operation at the electrodes. An alkaline capillary-fed electrolysis cell of this type demonstrates water electrolysis performance exceeding commercial electrolysis cells with a cell voltage at 0.5 A cm−2 and 85 °C of only 1.51 V equating to 98% energy efficiency with an energy consumption of 40.4 kWh/kg hydrogen (vs. ~47.5 kWh/kg in commercial electrolysis cells). High energy efficiency combined with the promise of a simplified balance-ofplant brings cost-competitive renewable hydrogen closer to reality.
Review of Next Generation Hydrogen Production from Offshore Wind Using Water Electrolysis
Dec 2023
Publication
Hydrogen produced using renewable energy from offshore wind provides a versatile method of energy storage and power-to-gas concepts. However few dedicated floating offshore electrolyser facilities currently exist and therefore conditions of the offshore environment on hydrogen production cost and efficiency remain uncertain. Therefore this review focuses on the conversion of electrical energy to hydrogen using water electrolysis located in offshore areas. The challenges associated with the remote locations fluctuating power and harsh conditions are highlighted and recommendations for future electrolysis system designs are suggested. The latest research in polymer electrolyte membrane alkaline and membraneless electrolysis are evaluated in order to understand their capital costs efficiency and current research status for achieving scaled manufacturing to the GW scale required in the next three decades. Operating fundamentals that govern the performance of each device are investigated and future recommendations of research specifically for the integration of water electrolysers with offshore wind turbines is presented.
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