China, People’s Republic
Experimental Investigation of Hydrogen Production Performance of PEM Electrolyze
Jul 2025
Publication
As global awareness of environmental protection increases hydrogen is seen as a promising solution due to its high energy density and zero-emission combustion. The PEM electrolyze combined with renewable energy power generation is an effective method to solve the problem of hydrogen production. The market competitiveness of PEM electrolyte will be enhanced in the future and the equipment cost can be reduced by 35.8%. The fast dynamic response performance of PEM electrolyzes especially during start-up and shutdown affects system flexibility and stability. The 190 Nm3/h test platform is established to study the fast dynamic response performance considering the cold startup thermal start-up and shutdown behaviors. The results shown that the 190 Nm³/h PEM electrolyze required 6340 s to achieve cold start-up 1100 s to achieve thermal start-up and 855 s to complete shutdown. When operating stably the temperature fluctuation of the PEM remains below 5 °C demonstrating the excellent temperature control performance. However during cold start-up and shutdown the concentrations of hydrogen and oxygen fluctuate significantly which can easily lead to a decrease in system performance. These findings provide guidance for optimizing the design and operating parameters of PEM Electrolyze systems.
Energy Storage in the Energy Transition and Blue Economy: Challenges, Innovations, Future Perspectives, and Educational Pathways
Sep 2025
Publication
Transitioning to renewable energy is vital to achieving decarbonization at the global level but energy storage is still a major challenge. This review discusses the role of energy storage in the energy transition and the blue economy focusing on technological development challenges and directions. Effective storage is vital for balancing intermittent renewable energy sources like wind solar and marine energy with the power grid. The development of battery technologies hydrogen storage pumped hydro storage and emerging technologies like sodium-ion and metal-air batteries is discussed for their potential for large-scale deployment. Shortages in critical raw materials environmental impact energy loss and costs are some of the challenges to large-scale deployment. The blue economy promises opportunities for offshore energy storage notably through ocean thermal energy conversion (OTEC) and compressed air energy storage (CAES). Moreover the capacity of datadriven optimization and artificial intelligence to enhance storage efficiency is discussed. Policy interventions and economic incentives are necessary to spur the development and deployment of sustainable energy storage technology. Education and workforce training are also important in cultivating future researchers engineers and policymakers with the ability to drive energy innovation. Merging sustainability training with an interdisciplinary approach can potentially establish an efficient workforce that is capable of addressing energy issues. Future work needs to focus on higher energy density efficiency recyclability and cost-effectiveness of the storage technologies without sacrificing their environmental sustainability. The study underlines the need for converging technological economic and educational approaches to enable a sustainable and resilient energy future.
Day-Ahead Dispatch Optimization of an Integrated Hydrogen–Electric System Considering PEMEL/PEMFC Lifespan Degradation and Fuzzy-Weighted Dynamic Pricing
Sep 2025
Publication
Integrated Hydrogen–Energy Systems (IHES) have attracted widespread attention; however distributed energy sources such as photovoltaics (PV) and wind turbines (WT) within these systems exhibit significant uncertainty and intermittency posing key challenges to scheduling complexity and system instability. As a core mechanism for the integrated operation of IHES electricity price regulation can promote the absorption of renewable energy optimize resource allocation and enhance operational economy. Nevertheless uncertainties in IHES hinder the formulation of accurate electricity prices which easily lead to delays in scheduling responses and an increase in cumulative operating costs. To address these issues this study develops lifespan models for Proton Exchange Membrane Electrolyzers (PEMELs) and Proton Exchange Membrane Fuel Cells (PEMFCs) constructs dynamic equations for the demand side and response side and proposes a fuzzy-weighted dynamic pricing strategy. Simulation results show that compared with fixed pricing the proposed dynamic pricing strategy reduces economic indicators by an average of 15.3% effectively alleviates energy imbalance and optimizes the energy supply of components. Additionally it reduces the lifespan degradation of PEMELs by 21.59% and increases the utilization rate of PEMFCs by 54.8%.
Research on Hydrogen Leakage Risk Control Methods in Deck Compartments of Hydrogen Fuel Cell-Powered Ships Based on CFD Simulation and Ventilation Optimization
Oct 2025
Publication
Hydrogen fuel cell vessels represent a vital direction for green shipping but the risk of large-scale hydrogen leakage and diffusion in their enclosed compartments is particularly prominent. To enhance safety a simplified three-dimensional model of the deck-level cabins of the “Water-Go-Round” passenger ship was established using SolidWorks (2023) software. Based on a hydrogen leakage and diffusion model the effects of leakage location leakage aperture and initial ambient temperature on the diffusion patterns and distribution of hydrogen within the cabins were investigated using FLUENT software. The results show that leak location significantly affects diffusion direction with hydrogen leaking from the compartment ceiling diffusing horizontally much faster than from the floor. When leakage occurs at the compartment ceiling hydrogen can reach a maximum horizontal diffusion distance of up to 5.04 m within 540 s; the larger the leak aperture the faster the diffusion with a 10 mm aperture exhibiting a 40% larger diffusion range than a 6 mm aperture at 720 s. The study provides a theoretical basis for the safety design and risk prevention of hydrogen fuel cell vessels.
Operational Optimization of Electricity–Hydrogen Coupling Systems Based on Reversible Solid Oxide Cells
Sep 2025
Publication
To effectively address the issues of curtailed wind and photovoltaic (PV) power caused by the high proportion of renewable energy integration and to promote the clean and lowcarbon transformation of the energy system this paper proposes a “chemical–mechanical” dual-pathway synergistic mechanism for the reversible solid oxide cell (RSOC) and flywheel energy storage system (FESS) electricity–hydrogen hybrid system. This mechanism aims to address both short-term and long-term energy storage fluctuations thereby minimizing economic costs and curtailed wind and PV power. This synergistic mechanism is applied to regulate system operations under varying wind and PV power output and electricity–hydrogen load fluctuations across different seasons thereby enhancing the power generation system’s ability to integrate wind and PV energy. An economic operation model is then established with the objective of minimizing the economic costs of the electricity–hydrogen hybrid system incorporating RSOC and FESS. Finally taking a large-scale new energy industrial park in the northwest region as an example case studies of different schemes were conducted on the MATLAB platform. Simulation results demonstrate that the reversible solid oxide cell (RSOC) system—integrated with a FESS and operating under the dual-path coordination mechanism—achieves a 14.32% reduction in wind and solar curtailment costs and a 1.16% decrease in total system costs. Furthermore this hybrid system exhibits excellent adaptability to the dynamic fluctuations in electricity– hydrogen energy demand which is accompanied by a 5.41% reduction in the output of gas turbine units. Notably it also maintains strong adaptability under extreme weather conditions with particular effectiveness in scenarios characterized by PV power shortage.
Sustainable Transition Pathways for Steel Manufacturing: Low-Carbon Steelmaking Technologies in Enterprises
Jun 2025
Publication
Amid escalating global climate crises and the urgent imperative to meet the Paris Agreement’s carbon neutrality targets the steel industry—a leading contributor to global greenhouse gas emissions—confronts unprecedented challenges in driving sustainable industrial transformation through innovative low-carbon steelmaking technologies. This paper examines decarbonization technologies across three stages (source process and end-of-pipe) for two dominant steel production routes: the long process (BF-BOF) and the short process (EAF). For the BF-BOF route carbon reduction at the source stage is achieved through high-proportion pellet charging in the blast furnace and high scrap ratio utilization; at the process stage carbon control is optimized via bottom-blowing O2-CO2-CaO composite injection in the converter; and at the end-of-pipe stage CO2 recycling and carbon capture are employed to achieve deep decarbonization. In contrast the EAF route establishes a low-carbon production system by relying on green and efficient electric arc furnaces and hydrogen-based shaft furnaces. At the source stage energy consumption is reduced through the use of green electricity and advanced equipment; during the process stage precision smelting is realized through intelligent control systems; and at the end-of-pipe stage a closed-loop is achieved by combining cascade waste heat recovery and steel slag resource utilization. Across both process routes hydrogen-based direct reduction and green power-driven EAF technology demonstrate significant emission reduction potential providing key technical support for the low-carbon transformation of the steel industry. Comparative analysis of industrial applications reveals varying emission reduction efficiencies economic viability and implementation challenges across different technical pathways. The study concludes that deep decarbonization of the steel industry requires coordinated policy incentives technological innovation and industrial chain collaboration. Accelerating large-scale adoption of low-carbon metallurgical technologies through these synergistic efforts will drive the global steel sector toward sustainable development goals. This study provides a systematic evaluation of current low-carbon steelmaking technologies and outlines practical implementation strategies contributing to the industry’s decarbonization efforts.
Exploring the Gas Permeability of Type IV Hydrogen Storage Cylinder Liners: Research and Applications
Jul 2025
Publication
As hydrogen fuel cell vehicles gain momentum as crucial zero-emission transportation solutions the urgency to address hydrogen permeability through the polymer liner becomes paramount for ensuring the safety efficiency and longevity of Type IV hydrogen storage tanks. This paper synthesizes existing research findings analyzes the influence of different materials and structures on gas permeability elucidates the dissolution and diffusion mechanisms of hydrogen in plastic liners and discusses their engineering applications. We focus on measurement methods influencing factors and improvement strategies for liner gas permeability. Additionally we explore the prospects of Type IV hydrogen storage tanks in fields such as automotive aerospace and energy storage industries. Through this comprehensive review of liner gas permeability critical insights are provided to guide the development of efficient and safe hydrogen storage and transportation systems. These insights are vital for advancing the widespread application of hydrogen energy technology and fostering sustainable energy development significantly contributing to efforts aimed at enhancing the performance and safety of Type IV hydrogen storage tanks.
Double-Layer Optimal Configuration of Wind–Solar-Storage for Multi-Microgrid with Electricity–Hydrogen Coupling
Oct 2025
Publication
To address the collaborative optimization challenge in multi-microgrid systems with significant renewable energy integration this study presents a dual-layer optimization model incorporating power-hydrogen coupling. Firstly a hydrogen energy system coupling framework including photovoltaics storage batteries and electrolysis hydrogen production/fuel cells was constructed at the architecture level to realize the flexible conversion of multiple energy forms. From a modeling perspective the upper-layer optimization aims to minimize lifecycle costs by determining the optimal sizing of distributed PV systems battery storage hydrogen tanks fuel cells and electrolyzers within the microgrid. At the lower level a distributed optimization framework facilitates energy sharing (both electrical and hydrogen-based) across microgrids. This operational layer maximizes yearly system revenue while considering all energy transactions—both inter-microgrid and grid-to-microgrid exchanges. The resulting operational boundaries feed into the upper-layer capacity optimization with the optimal equipment configuration emerging from the iterative convergence of both layers. Finally the actual microgrid in a certain area is taken as an example to verify the effectiveness of the proposed method.
Stimulating Efficiency for Proton Exchange Membrane Water Splitting Electrolyzers: From Material Design to Electrode Engineering
Jun 2025
Publication
Proton exchange membrane water electrolyzers (PEMWEs) are a promising technology for large-scale hydrogen production yet their industrial deployment is hindered by the harsh acidic conditions and sluggish oxygen evolution reaction (OER) kinetics. This review provides a comprehensive analysis of recent advances in iridium-based electrocatalysts (IBEs) emphasizing novel optimization strategies to enhance both catalytic activity and durability. Specifically we critically examine the mechanistic insights into OER under acidic conditions revealing key degradation pathways of Ir species. We further highlight innovative approaches for IBE design including (i) morphology and support engineering to improve stability (ii) structure and phase modulation to enhance catalytic efficiency and (iii) electronic structure tuning for optimizing interactions with reaction intermediates. Additionally we assess emerging electrode engineering strategies and explore the potential of non-precious metal-based alternatives. Finally we propose future research directions focusing on rational catalyst design mechanistic clarity and scalable fabrication for industrial applications. By integrating these insights this review provides a strategic framework for advancing PEMWE technology through highly efficient and durable OER catalysts.
Hydrogen Production Power Supply with Low Current Ripple Based on Virtual Impedance Technology Suitable for Offshore Wind–Solar–Storage System
Oct 2025
Publication
Hydrogen production from water electrolysis can not only reduce greenhouse gas emissions but also has abundant raw materials which is one of the ideal ways to produce hydrogen from new energy. The hydrogen production power supply is the core component of the new energy electrolytic water hydrogen production device and its characteristics have a significant impact on the efficiency and purity of hydrogen production and the service life of the electrolytic cell. In essence the DC/DC converter provides the large current required for hydrogen production. For the converter its input still needs the support of a DC power supply. Given the maturity and technical characteristics of new energy power generation integrating energy storage into offshore energy systems enables stable power supply. This configuration not only mitigates energy fluctuations from renewable sources but also further reduces electrolysis costs providing a feasible pathway for large-scale commercialization of green hydrogen production. First this paper performs a simulation analysis on the wind–solar hybrid energy storage power generation system to demonstrate that the wind–solar–storage system can provide stable power support. It places particular emphasis on the significance of hydrogen production power supply design—this focus stems primarily from the fact that electrolyzers impose specific requirements on high operating current levels and low current ripple which exert a direct impact on the electrolyzer’s service life hydrogen production efficiency and operational safety. To suppress the current ripple induced by high switching frequency and high output current traditional approaches typically involve increasing the output inductor. However this method substantially increases the volume and weight of the device reduces the rate of current change and ultimately results in a degradation of the system’s dynamic response performance. To this end this paper focuses on developing a virtual impedance control technology aiming to reduce the ripple amplitude while avoiding an increase in the filter inductor. Owing to constraints in current experimental conditions this research temporarily relies on simulation data. Specifically a programmable power supply is employed to simulate the voltage output of the wind–solar–storage hybrid system thereby bringing the simulation as close as possible to the actual operating conditions of the wind–solar–storage hydrogen production system. The experimental results demonstrate that the proposed method can effectively suppress the ripple amplitude maintain high operating efficiency and ultimately meet the expected research objectives. That makes it particularly suitable as a high-quality power supply for offshore hydrogen production systems that have strict requirements on volume and weight.
Highly Selective Production of ‘‘Jadeite Hydrogen” from the Catalytic Decomposition of Diesel
Mar 2025
Publication
Clean hydrogen (H2) is highly desirable for the sustainable development of society in the era of carbon neutrality. However the current capability of water electrolysis and steam methane (CH4) reforming to produce green and blue H2 is very limited mainly due to the high production cost difficult scale-up technology or operational risk. Here we propose the direct catalytic decomposition of diesel using a nano-Fe-based catalyst to produce the so-called ‘‘jadeite H2” while simultaneously fixing the carbon from the diesel in the form of carbon nanotubes (CNTs). Efforts are made to understand the suppression mechanism of the CH4 byproduct such as by tuning the catalyst type space velocity and reaction time. The optimal green index (GI)—that is the molar ratio of H2/carbon in a gaseous state—of the proposed technology exceeds 42 which is far higher than those of any previously reported chemical vapor deposition (CVD) method. Moreover the carbon footprint (CFP) of the proposed technology is far lower than those of grey H2 blue H2 and other dehydrogenation technologies. Compared with most of the technologies mentioned above the energy consumption (per mole of H2) and reactor amplification of the proposed technology validate its high efficiency and great practical feasibility.
Pathways to Environmental Sustainability through Energy Efficiency: A Strategic Next Energy Vision for Sustainable Development by 2050
Oct 2025
Publication
As the global push for carbon neutrality accelerates energy efficiency has become essential for sustainable development especially for nations like Nigeria that face rising energy demands and significant environmental challenges. This study explores how integrating energy efficiency with carbon neutrality can support Nigeria’s strategic energy goals while offering global lessons for other countries facing similar challenges focusing on key sectors including industry transport and power generation. The study systematically examines the impacts of renewable energy (RE) technologies like solar wind and hydropower—alongside policy reforms technological innovations and demand-side management strategies to advance energy efficiency in Nigeria. Key findings include the identification of strategic policy frameworks technological solutions and the transformative role of green hydrogen in decarbonizing hard-to-electrify sectors. The study also emphasizes the importance of international climate finance decentralized RE systems like solar mini-grids for improving energy access and economic opportunities for job creation in the RE sector. Furthermore it highlights the need for behavioral changes community engagement and consistent policy implementation to address infrastructure gaps and drive energy efficiency goals. The novelty of this research lies in its scenario-based analysis of Nigeria’s low-carbon transition detailing both the opportunities and challenges such as policy inconsistencies infrastructure deficits and financial constraints. The findings stress the importance of international collaboration technological advancements and targeted investments to overcome these challenges. By offering actionable insights and strategic recommendations this study provides a roadmap for policymakers industry stakeholders and researchers to drive Nigeria towards a sustainable carbon-neutral future by 2050.
QDQN-ThermoNet: A Quantum-driven Dual Depp Q-network Framework for Intelligent Thermal Regulation in Solid-state and Hydrogen Fuel Cell Systems of Future Electric Vehicles
Oct 2025
Publication
This paper presents QDQN-ThermoNet a novel Quantum-Driven Dual Deep Q-Network framework for intelligent thermal regulation in next-generation electric vehicles with hybrid energy systems. Our approach introduces a dual-agent architecture where a classical DQN governs solid-state battery thermal management while a quantumenhanced DQN regulates proton exchange membrane fuel cell dynamics both sharing a unified quantumenhanced experience replay buffer to facilitate cross-system information transfer. Hardware-in-the-Loop validation across diverse operational scenarios demonstrates significant performance improvements compared to classical methods including enhanced thermal stability (95.1 % vs. 82.3 %) faster thermal response (2.1 s vs. 4.7 s) reduced overheating events (0.3 vs. 3.2) and superior energy efficiency (22.4 % energy savings). The quantum-enhanced components deliver 38.7 % greater sample efficiency and maintain robust performance under sparse data conditions (33.9 % improvement) while material-adaptive control strategies leveraging MXeneenhanced phase change materials achieve a 50.3 % reduction in peak temperature rise during transients. Component lifetime analysis reveals a 33.2 % extension in battery service life through optimized thermal management. These results establish QDQN-ThermoNet as a significant advancement in AI-driven thermal management for future electric vehicle platforms effectively addressing the complex challenges of coordinating thermal regulation across divergent energy sources with different optimal operating temperatures.
A Deep Neural Network-Based Approach for Optimizing Ammonia–Hydrogen Combustion Mechanism
Nov 2025
Publication
Ammonia is a highly promising zero-carbon fuel for engines. However it exhibits high ignition energy slow flame propagation and severe pollutant emissions so it is usually burned in combination with highly reactive fuels such as hydrogen. An accurate understanding and modeling of ammonia–hydrogen combustion is of fundamental and practical significance to its application. Deep Neural Networks (DNNs) demonstrate significant potential in autonomously learning the interactions between high-dimensional inputs. This study proposed a deep neural network-based method for optimizing chemical reaction mechanism parameters producing an optimized mechanism file as the final output. The novelty lies in two aspects: first it systematically compares three DNN structures (Multilayer perceptron (MLP) Convolutional Neural Network and Residual Regression Neural Network (ResNet)) with other machine learning models (generalized linear regression (GLR) support vector machine (SVM) random forest (RF)) to identify the most effective structure for mapping combustion-related variables; second it develops a ResNet-based surrogate model for ammonia–hydrogen mechanism optimization. For the test set (20% of the total dataset) the ResNet outperformed all other ML models and empirical correlations achieving a coefficient of determination (R2 ) of 0.9923 and root mean square error (RMSE) of 135. The surrogate model uses the trained ResNet to optimize mechanism parameters based on a Stagni mechanism by mapping the initial conditions to experimental IDT. The results show that the optimized mechanism improves the prediction accuracy on laminar flame speed (LFS) by approximately 36.6% compared to the original mechanism. This method while initially applied to the optimization of an ammonia–hydrogen combustion mechanism can potentially be adapted to optimize mechanisms for other fuels.
Analysis of Exergy Flow and CCUS Carbon Reduction Potential in Coal Gasification Hydrogen Production Technology in China
Nov 2025
Publication
Coal constitutes China’s most significant resource endowment at present. Utilizing coal resources for hydrogen production represents an early-stage pathway for China’s hydrogen production industry. The analysis of energy quality and carbon emissions in coal gasification-based hydrogen production holds practical significance. This paper integrates the exergy analysis methodology into the traditional LCA framework to evaluate the exergy and carbon emission scales of coal gasification-based hydrogen production in China considering the technical conditions of CCUS. This paper found that the life cycle exergic efficiency of the whole chain of gasification-based hydrogen production in China is accounted to be 38.8%. By analyzing the causes of exergic loss and energy varieties it was found that the temperature difference between the reaction of coal gasification and CO conversion unit and the pressure difference due to the compressor driven by the electricity consumption of the compression process in the variable pressure adsorption unit are the main causes of exergic loss. Corresponding countermeasures were suggested. Regarding decarbonization strategies the CCUS process can reduce CO2 emissions across the life cycle of coal gasification-based hydrogen production by 48%. This study provides an academic basis for medium-to-long-term forecasting and roadmap design of China’s hydrogen production structure.
Dual S-Scheme Heterojunction Nanocomposite-chrge Transport for Photocatalytic Green Energy Production and Environmental Implementations - Where to Go?
Sep 2025
Publication
Dating back to more than one century ago the photocatalysis process has demonstrated great promise in addressing environmental problems and the energy crisis. Nevertheless some single or binary composite materials cannot meet the requirements of large-scale implementations owing to their limited photocatalytic efficiencies. Since 2021 dual S-scheme heterojunctionbased nanocomposites have been undertaken as highly efficient photoactive materials for green energy production and environmental applications in order to overcome limitations faced in traditional photocatalysts. Herein state-of-the-art protocols designed for the synthesis of dual S-scheme heterojunctions are described. How the combined three semiconductors in dual S-scheme heterojunctions can benefit from one another to achieve high energy production and efficient oxidative removal of various pollutants is deeply explained. Photocatalytic reaction mechanisms by paying special attention to the creation of Fermi levels (Ef ) and charge carriers transfer between the three semiconductors in dual S-scheme heterojunctions are discussed. An entire section has been dedicated to some examples of preparation and applications of double S-scheme heterojunction-based nanocomposites for several photocatalytic applications such as soluble pollutants photodegradation bacteria disinfection artificial photosynthesis H2 generation H2O2 production CO2 reduction and ammonia synthesis. Lastly the current challenges of dual S-scheme heterojunctions are presented and future research directions are presented. To sum up dual S-scheme heterojunction nanocomposites are promising photocatalytic materials in the pursuit of sustainable energy production and environmental remediation. In the future dual S-scheme heterojunctions are highly recommended for photoreactors engineering instead of single or binary photocatalysts to drive forward photocatalysis processes for practical green energy production and environmental protection.
Sustainable Power System Transition Pathways: Regional Decarbonisation and Resource Conservation Aided by Small Modular Reactors
Oct 2025
Publication
Clean energy technologies offer promising pathways for low-carbon transitions yet their feasibility remains uncertain particularly in rapidly developing regions. This study develops a Factorial Multi-Stochastic Optimization-driven Equilibrium (FMOE) model to assess the economic and environmental impacts of clean power deployment. Using Small Modular Reactors (SMRs) in Guangdong China as a case study the model reveals that SMRs can reduce system costs and alleviate GDP losses supporting provincial-level Nationally Determined Contributions (NDCs). If offshore wind capital costs fall to 40 % of SMRs’ SMR deployment may no longer be necessary after 2030. Otherwise SMRs could supply 22 % of capacity by 2040. The FMOE model provides a robust adaptable framework for evaluating emerging technologies under uncertainty and supports sustainable power planning across diverse regional contexts. This study offers valuable insights into the resource and economic implications of clean energy strategies contributing to global carbon neutrality and efficient energy system design.
Coordinated Control Strategy for Island Power Generation System with Photovoltaic, Hydrogen-Fueled Gas Turbine and Hybrid Energy Storage
Oct 2025
Publication
Marine and island power systems usually incorporate various forms of energy supply which poses challenges to the coordinated control of the system under diverse irregular and complex load operation modes. To improve the stability and self-sufficiency of island-isolated microgrids with high penetration of renewable energy this study proposes a coordinated control strategy for an island microgrid with PV HGT and HESS combining primary power allocation via low-pass filtering with a fuzzy logic-based secondary correction. The fuzzy controller dynamically adjusts power distribution based on the states of charge of the battery and supercapacitor following a set of predefined rules. A comprehensive system model is developed in Matlab R2023b integrating PV generation an electrolyzer HGT and a battery–supercapacitor HESS. Simulation results across four operational cases demonstrate that the proposed strategy reduces DC bus voltage fluctuations to a maximum of 4.71% (compared to 5.63% without correction) with stability improvements between 0.96% and 1.55%. The HESS avoids overcharging and over-discharging by initiating priority charging at low SOC levels thereby extending service life. This work provides a scalable control framework for enhancing the resilience of marine and island microgrids with high renewable energy penetration.
Unlocking Hydrogen Carrier Potential of the Yangtze River in China
Oct 2025
Publication
The Yangtze River as the world’s largest clean energy corridor links key economic regions and plays a crucial role in inland waterway transportation. However few studies have comprehensively evaluated the potential of the Yangtze River for cross-regional hydrogen transport. Here we develop a comprehensive integrated power and hydrogen supply chain (IPHSC) optimization model to evaluate the potential of cross-regional hydrogen transport via the Yangtze River. The IPHSC optimization model covers the entire hydrogen production-storage-transportation-utilization chain through cross-sector modeling of energy transportation water scheduling and environmental protection. Results show that in the 2060 carbon neutrality scenario the deployment of 62.2 kilotons of 574 differentiated liquid hydrogen (LH2) carrier ships could enable the transportation of 5018 kilotons (1512 million ton-km) of hydrogen annually meeting nearly 20% of the total electrolytic hydrogen demand across eight riverine provinces. Unlike west-to-east electricity transmission in China the central Yangtze River region is expected to become the main hub for hydrogen exports in the future. Compared with alternative methods such as transmission lines or pipelines LH2 carrier ships offer the lowest energy supply costs at 3 US cents/kWh for electricity and 5 US cents/kWh for hydrogen. Additionally a full-parameter attribution analysis of over 40 factors is conducted to assess variations in supply costs. Our study offers a thorough evaluation of the feasibility and economic benefits of hydrogen transportation via inland waterways providing a comprehensive multi-sectoral coupling assessment framework for regions with well-established inland waterway networks such as Europe and the United States.
Methanol Steam Reforming with Samarium-stabilized Copper Sites for Efficient Hydrogen Production
Nov 2025
Publication
The rational design of Cu-based catalysts with tailored interfacial structures and electronic states remains challenging yet essential for advancing hydrogen production via methanol steam reforming (MSR). Here we developed a samarium-mediated strategy to construct a 30Sm-CuAl catalyst. The introduction of Sm promotes Cu dispersion and induces strong metal-support interactions resulting in the formation of Sm2O3- encapsulated Cu nanoparticles enriched with Cu+ -O-Sm interfaces. The optimized 30Sm-CuAl demonstrates exceptional MSR performance achieving a hydrogen production rate of 1126 mmol gcat− 1 h− 1 at 250◦C. Mechanistic studies revealed that the reaction follows the formate pathway in xSm-CuAl with formate accumulation identified as the primary reason for the deactivation of 30Sm-CuAl. Dynamic regeneration of 30SmCuAl through redox treatment restores its activity thereby enabling cyclic operation. These findings provide insights into rare-earth oxide regulation of Cu-based catalysts and lay the foundation for targeted resolution of formate intermediate accumulation to enhance MSR stability.
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