Germany
Distribution of Relaxation Times Analysis of High-temperature PEM Fuel Cell Impedance Spectra
Feb 2017
Publication
In this study Distribution of Relaxation Times (DRT) was successfully demonstrated in the analysis of the impedance spectra of High-Temperature Polymer Electrolyte Membrane Fuel Cells (HT-PEMFC) doped with phosphoric acid. Electrochemical impedance spectroscopy (EIS) was performed and the quality of the recorded spectra was verified by Kramers-Kronig relations. DRT was then applied to the measured spectra and polarization losses were separated on the basis of their typical time constants. The main features of the distribution function were assigned to the cell’s polarization processes by selecting appropriate experimental conditions. DRT can be used to identify individual internal HT-PEMFC fuel cell phenomena without any a-priori knowledge about the physics of the system. This method has the potential to further improve EIS spectra interpretation with either equivalent circuits or physical models.
Decarbonization of Long-Haul Heavy-Duty Truck Transport: Technologies, Life Cycle Emissions, and Costs
Feb 2025
Publication
Decarbonizing long-haul heavy-duty transport in Europe focuses on batteryelectric trucks with high-power chargers or electric road systems and fuel-cell-electric vehicles with hydrogen refueling stations. We present a comparative life cycle assessment and total cost of ownership analysis of these technologies for 20% of Germany’s heavy-duty long-haul transport alongside internal combustion engine vehicles. The results show that fuel cell vehicles with on-site hydrogen have the highest life cycle emissions (65 Mt CO2e) followed by internal combustion engine vehicles (55 Mt CO2e). Battery-electric vehicles using electric road systems achieve the lowest emissions (21 Mt CO2e) and the lowest costs (EUR 45 billion). In contrast fuel cell vehicles with on-site hydrogen have the highest costs (EUR 69 billion). Operational costs dominate total expenses making them a compelling target for subsidies. The choice between battery and fuel cell technologies depends on the ratio of vehicles to infrastructure transport performance and range. Fuel cell trucks are better suited for remote areas due to their longer range while integrating electric road systems with high-power charging could offer synergies. Recent advancements in battery and fuel cell durability further highlight the potential of both technologies in heavy-duty transport. This study provides insights for policymakers and industry stakeholders in the shift towards sustainable transport. The greenhouse gas emission savings from adopting battery-electric trucks are 54% in our high-power charging scenario and 62% in the electric road system scenario in comparison to the reference scenario with diesel trucks.
Breakthrough Position and Trajectory of Sustainable Energy Technology
Jan 2025
Publication
This research aims to determine the position and the breakthrough trajectory of sustainable energy technologies. Fine-grained insights into these breakthrough positions and trajectories are limited. This research seeks to fill this gap by analyzing sustainable energy technologies’ breakthrough positions and trajectories in terms of development application and upscaling. To this end the breakthrough positions and trajectories of seven sustainable energy technologies i.e. hydrogen from seawater electrolysis hydrogen airplanes inland floating photovoltaics redox flow batteries hydrogen energy for grid balancing hydrogen fuel cell electric vehicles and smart sustainable energy houses are analyzed. This is guided by an extensively researched and literature-based model that visualizes and describes these technologies’ experimentation and demonstration stages. This research identifies where these technologies are located in their breakthrough trajectory in terms of the development phase (prototyping production process and organization and niche market creation and sales) experiment and demonstration stage (technical organizational and market) the form of collaboration (public–private private–public and private) physical location (university and company laboratories production sites and marketplaces) and scale-up type (demonstrative and first-order and second-order transformative). For scientists this research offers the opportunity to further refine the features of sustainable energy technologies’ developmental positions and trajectories at a detailed level. For practitioners it provides insights that help to determine investments in various sustainable energy technologies.
Hydrogen-ready Power Plants: Optimizing Pathways to a Decarbonized Energy System in Germany
Jun 2025
Publication
The integration of hydrogen technologies is widely regarded as a transformative step in the energy transition. Recently the German government unveiled a Power Plant Strategy to promote H2-Ready Combined-Cycle Gas Turbines (H2-CCGT) which are intended to initially run on natural gas and transition to green hydrogen by 2040 at the latest. This study assesses the role of H2-Ready power plants in a low-carbon transition and explores plausible pathways using a capacity expansion model for Germany. This topic is particularly relevant for other countries aiming to deploy a large share of renewables and considering H2-CCGT as a flexible backup solution to ensure system flexibility and achieve deep decarbonization. Our results indicate that H2-CCGT enhance system flexibility and significantly alleviate the investments need for additional flexibility and renewable generation capacity and reduce renewable-energy curtailment by more than 35 %. Moreover our results also demonstrate that allowing hydrogen in CCGT does not entirely reduce the need for fossil fueled power plants as hydrogen becomes economically viable only with deep decarbonization or direct subsidies. We show that policy interventions can alter the transition pathways for achieving a decarbonized energy system. Our research challenges a prevailing narrative that financial support for hydrogen is needed to ensure a cost-efficient system decarbonization. More straightforward market-based policy instruments such as intensified CO2 pricing or regulatory frameworks such as earlier mandatory hydrogen shifts in H2-CCGT prove more efficient at cutting emissions and costs.
Assessing the Feasibility of a Green Hydrogen Economy in Selected African Regions with Composite Indicators
Jan 2025
Publication
This study offers a comprehensive analysis of the feasibility of green hydrogen economies in Western and Southern African regions focusing on the ECOWAS and SADC countries. Utilizing a novel approach based on composite indicators the research evaluates the potential readiness and overall feasibility of green hydrogen production and export across these regions. The study incorporates various factors including the technical potential of renewable energy sources water resource availability energy security and existing infrastructure for transport and export. Country-specific analyses reveal unique insights into the diverse potential of nations like South Africa Lesotho Ghana Nigeria Angola and Namibia each with its unique strengths and challenges in the context of green hydrogen. The research findings underscore the complexity of developing green hydrogen economies highlighting the need for nuanced region-specific approaches that consider technical socioeconomic geopolitical and environmental factors. The paper concludes that cooperation and integration between countries in the regions may be crucial for the success of a future green hydrogen economy
Energy Asset Stranding in Resource-rich Developing Countries and the Just Transition - A Framework to Push Research Frontiers
Jun 2024
Publication
Climate policy will inevitably lead to the stranding of fossil energy assets such as production and transport assets for coal oil and natural gas. Resourcerich developing countries are particularly aected as they have a higher risk of asset stranding due to strong fossil dependencies and wider societal consequences beyond revenue disruption. However there is only little academic and political awareness of the challenge to manage the asset stranding in these countries as research on transition risk like asset stranding is still in its infancy. We provide a research framework to identify wider societal consequences of fossil asset stranding. We apply it to a case study of Nigeria. Analyzing dierent policy measures we argue that compensation payments come with implementation challenges. Instead of one policy alone to address asset stranding a problem-oriented mix of policies is needed. Renewable hydrogen and just energy transition partnerships can be a contribution to economic development and SDGs. However they can only unfold their potential if fair benefit sharing and an improvement to the typical institutional problems in resource-rich countries such as the lack of rule of law are achieved. We conclude with presenting a future research agenda for the global community and acade
Hydrogen Storage with Gravel and Pipes in Lakes and Reservoirs
Sep 2024
Publication
Climate change is projected to have substantial economic social and environmental impacts worldwide. Currently the leading solutions for hydrogen storage are in salt caverns and depleted natural gas reservoirs. However the required geological formations are limited to certain regions. To increase alternatives for hydrogen storage this paper proposes storing hydrogen in pipes filled with gravel in lakes hydropower and pumped hydro storage reservoirs. Hydrogen is insoluble in water non-toxic and does not threaten aquatic life. Results show the levelized cost of hydrogen storage to be 0.17 USD kg−1 at 200 m depth which is competitive with other large scale hydrogen storage options. Storing hydrogen in lakes hydropower and pumped hydro storage reservoirs increases the alternatives for storing hydrogen and might support the development of a hydrogen economy in the future. The global potential for hydrogen storage in reservoirs and lakes is 3 and 12 PWh respectively. Hydrogen storage in lakes and reservoirs can support the development of a hydrogen economy in the future by providing abundant and cheap hydrogen storage.
Tracing the Research Pulse: A Bibliometric Analysis and Systematic Review of Hydrogen Production Through Gasification
Jun 2025
Publication
Clean hydrogen is expected to play a crucial role in the future decarbonized energy mix. This places the gasification of biomass as a critical conversion pathway for hydrogen production owing to its carbon neutrality. However there is limited research on the direction of the body of literature on this subject matter. Utilising the Bibliometrix package R this paper conducts a systematic review and bibliometric analysis of the literature on gasification-derived hydrogen production over the previous three decades. The results show a decade-wise spike in hydrogen research mostly contributed by China the United States and Europe whereas the scientific contribution of Africa on the topic is limited with less than 6% of the continent’s research output on the subject matter sponsored by African institutions. The current trend of the research is geared towards alignment with the Paris Agreement through feedstock diversification to include renewable sources such as biomass and municipal solid waste and decarbonising the gasification process through carbon-capture technologies. This review reveals a gap in the experimental evaluation of heterogenous organic municipal solid waste for hydrogen production through gasification within the African context. The study provides an incentive for policy actors and researchers to advance the green hydrogen economy in Africa.
Cost and Competitiveness of Green Hydrogen and the Effects of the European Union Regulatory Framework
May 2024
Publication
By passing the delegated acts supplementing the revised Renewable Energy Directive the European Commission has recently set a regulatory benchmark for the classifcation of green hydrogen in the European Union. Controversial reactions to the restricted power purchase for electrolyser operation refect the need for more clarity about the efects of the delegated acts on the cost and the renewable characteristics of green hydrogen. To resolve this controversy we compare diferent power purchase scenarios considering major uncertainty factors such as electricity prices and the availability of renewables in various European locations. We show that the permission for unrestricted electricity mix usage does not necessarily lead to an emission intensity increase partially debilitating concerns by the European Commission and could notably decrease green hydrogen production cost. Furthermore our results indicate that the transitional regulations adopted to support a green hydrogen production ramp-up can result in similar cost reductions and ensure high renewable electricity usage.
Hydrogen Economy Index - A Comparative Assessment of the Political and Economic Perspective in the MENA Region for a Clean Hydrogen Economy
Jan 2025
Publication
The ongoing discourse on the transition to a hydrogen-based economy and the lessons learned from visions such as the Desertec concept emphasise the necessity for a nuanced approach to the development of metrics to assess a country’s hydrogen readiness. In addition to economic criteria such as investment incentives factors including law and order governance performance geography infrastructure and renewable energy production potential significantly impact a location’s attractiveness. To transparently evaluate sites using multiple criteria defined in the PESTEL framework this article aims to analyse quantify and compare the development of a sustainable hydrogen economy in 18 Middle East and North African states. The index-based assessment integrates criteria across three dimensions offering a comprehensive perspective on regional challenges and opportunities striking for policymakers and investors. The results show that the highest-ranked countries belong to the Gulf Cooperation Council followed by North African countries.
Emission Reduction Potential of Hydrogen-Powered Aviation Between Airports in Proximity of Seaports
Jul 2025
Publication
Green hydrogen will play a crucial role in the future of emission reduction in air traffic in the long-term as it will completely eliminate CO2 emissions and significantly reduce other pollutants such as contrails and nitrogen oxides. Hydrogen offers a promising alternative to kerosene for short- and medium-haul flights particularly through direct combustion and hydrogen fuel cell technology in new aircraft concepts. Against the background of the immense capital-intensive infrastructure adjustments that are required at airports for this purpose and the simultaneously high future hydrogen demand for the shipping industry this paper analyses the emission savings potential in Europe if airports near seaports would switch to hydrogen-powered flight connections.
Modelling the Non-adiabatic Blowdown of Pressurised Cryogenic Hydrogen Storage Tank
Sep 2023
Publication
This paper describes a model of hydrogen blowdown dynamics for storage tanks needed for hydrogen safety engineering to accurately represent incident scenarios. Heat transfer through a tank wall affects the temperature and pressure dynamics inside the storage vessel and therefore the characteristics of the resulting hydrogen jet in case of loss of containment. Available non-adiabatic blowdown models are validated only against experiments on hydrogen storages at ambient temperature. Effect of heat transfer for cryo-compressed hydrogen can be more significant due to a larger temperature difference between the stored hydrogen and surrounding atmosphere especially in case of failure of equipment insulation. Previous work by the authors demonstrated that the heat transfer through a discharge pipe wall can significantly affect the mass flow rate of cryogenic hydrogen releases. To the authors’ knowledge thoroughly validated models of non-adiabatic blowdown dynamics for cryo-compressed hydrogen are currently missing. The present work further develops the non-adiabatic blowdown model at ambient temperature using the under-expanded jet theory developed at Ulster University to expand it to cryo-compressed hydrogen storages. The non-ideal behaviour of cryo-compressed hydrogen is accounted through the high-accuracy Helmholtz energy formulations. The developed model includes effect of heat transfer at both the tank and discharge pipe wall. The model is thoroughly validated against sixteen tests performed by Pro-Science on blowdown of hydrogen storage tanks with initial pressure 0.5-20 MPa and temperature 80-310 K through release nozzle of diameter 0.5-4.0 mm. The model well reproduces the experimental pressure and temperature dynamics during the entire blowdown duration.
Electrification or Hydrogen? The Challenge of Decarbonizing Industrial (High-Temperature) Process Heat
Oct 2024
Publication
The decarbonization of industrial process heat is one of the bigger challenges of the global energy transition. Process heating accounts for about 20% of final energy demand in Germany and the situation is similar in other industrialized nations around the globe. Process heating is indispensable in the manufacturing processes of products and materials encountered every day ranging from food beverages paper and textiles to metals ceramics glass and cement. At the same time process heating is also responsible for significant greenhouse gas emissions as it is heavily dependent on fossil fuels such as natural gas and coal. Thus process heating needs to be decarbonized. This review article explores the challenges of decarbonizing industrial process heat and then discusses two of the most promising options the use of electric heating technologies and the substitution of fossil fuels with low-carbon hydrogen in more detail. Both energy carriers have their specific benefits and drawbacks that have to be considered in the context of industrial decarbonization but also in terms of necessary energy infrastructures. The focus is on high-temperature process heat (>400 ◦C) in energy-intensive basic materials industries with examples from the metal and glass industries. Given the heterogeneity of industrial process heating both electricity and hydrogen will likely be the most prominent energy carriers for decarbonized high-temperature process heat each with their respective advantages and disadvantages.
Germany's Power-to-X Policy for Climate-neutral Transport
Nov 2024
Publication
Germany aligned with the European Union has set important targets for decreasing greenhouse gas emissions by 65% by 2030 and achieving climate neutrality by 2045. In this context Power-to-X fuels have emerged as promising solutions for defossilizing transport modes less suitable for electrification. However a significant challenge in developing Power-to-X fuels is the absence of a well-defined regulatory framework for their production and utilization. Thus this study investigates the regulatory landscapes of the EU and Germany aiming to comprehend objectives support schemes and advancements. A total of 25 legal frameworks from the EU and Germany with direct or indirect effects on Power-to-X fuels were identified. For a detailed and comprehensive policy analysis a qualitative inductive approach based on a coding scheme and policy content analysis was implemented. Findings indicate that several updates in the German and EU regulatory frameworks addressed Power-to-X fuels in the 2010s and 2020s. The RED III the REFuelEU Aviation and the FuelEU Maritime have shown to be turning points for Power-to-X fuels in the EU. In Germany the most relevant policies are the 37. BImSchV the National Hydrogen Strategy and the PtL Roadmap. Key challenges are identified related to the limited coherence among policies supporting the sustainable use of resources for the fuel production.
Underground Hydrogen Storage in Sandstone Reservoirs: Effects of Geochemical Reactivity of Hydrogen on Reservoir Performance
Jan 2025
Publication
Underground hydrogen storage in porous rocks is a promising method to stabilize renewable energy fluctuations. However data on the geochemical reactivity of hydrogen with reservoir rocks and its potential effects on reservoir performance are limited. This study investigates the geochemical reactivity of hydrogen with Bunt sandstein reservoir sandstones from northern Germany collected at a depth of about 2.5 km. Experiments were performed at 100 ◦C and 150 bar hydrogen partial pressure for four weeks examining scenarios with dry hydrogen synthetic saline fluid with hydrogen synthetic saline fluid with helium (as a control) and an oxidation environment (air). We measured permeability porosity magnetic susceptibility and fluid element concentration before and after the experiments. Results showed no significant mineral changes attributed to hydrogen. Mag netic susceptibility indicated no formation of magnetic minerals such as magnetite and pyrrhotite. Minor var iations in permeability and porosity were attributed to anhydrite dissolution from fluid chemistry nonequilibrium. Overall our findings suggest hydrogen interactions with Buntsandstein sandstone (no pyrite content) at temperatures up to 100 ◦C do not risk hydrogen loss or reservoir performance degradation.
Levelised Cost of Hydrogen Production in Northern Africa and Europe in 2050: A Monte Carlo Simulation for Germany, Norway, Spain, Algeria, Morocco, and Egypt
May 2024
Publication
The production of green hydrogen through electrolysis utilizing renewable energies is recognized as a pivotal element in the pursuit of decarbonization. In order to attain cost competitiveness for green hydrogen reasonable generation costs are imperative. To identify cost-effective import partners for Germany given its limited green hydrogen production capabilities this study undertakes an exhaustive techno-economic analysis to determine the potential Levelized Cost of Hydrogen in Germany Norway Spain Algeria Morocco and Egypt for the year 2050 which represents a critical milestone in European decarbonization efforts. Employing a stochastic approach with Monte Carlo simulations the paper marks a significant contribution for projecting future cost ranges acknowledging the multitude of uncertainties inherent in related cost parameters and emphasizing the importance of randomness in these assessments. Country-specific Weighted Average Cost of Capital are calculated in order to create a refined understanding of political and economic influences on cost formation rather than using a uniform value across all investigated nations. Key findings reveal that among the evaluated nations PV-based hydrogen emerges as the most cost-efficient alternative in all countries except Norway with Spain presenting the lowest Levelized Cost of Hydrogen at 1.66 €/kg to 3.12 €/kg followed by Algeria (1.72 €/kg to 3.23 €/kg) and Morocco (1.73 €/kg to 3.28 €/kg). Consequently for economically favorable import options Germany is advised to prioritize PV-based hydrogen imports from these countries. Additionally hydrogen derived from onshore wind in Norway (2.24 €/kg to 3.73 €/kg) offers a feasible import alternative. To ensure supply chain diversity and reduce dependency on a single source a mixed import strategy is advisable. Despite having the lowest electricity cost Egypt shows the highest Levelized Cost of Hydrogen primarily due to a significant Weighted Average Cost of Capital.
What will be the Hydrogen and Power Demands of the Process Industry in a Climate-neutral Germany?
Apr 2024
Publication
The defossilization of industry has far-reaching implications regarding the future demand for hydrogen and other forms of energy. This paper presents and applies a fundamental bottom-up model that relies on techno-economic data of industrial production processes. Its aim is to identify across a range of scenarios the most cost-effective low-carbon options considering a variety of production systems. Subsequently it derives the hydrogen and electricity demand that would result from the implementation of these least-cost low-carbon options in process industries in Germany. Aligning with the German government's target year for achieving climate neutrality this study’s reference year is 2045. The primary contribution lies in analyzing which hydrogen-based and direct electrification solutions would be cost-effective for a range of energy price levels under climate-neutral industrial production and what the resulting hydrogen and electricity demand would be. To this end the methodology of this paper comprises the following steps: selection of the relevant industries (I) definition of conventional reference production systems and their low-carbon options (II) investigation and processing of the techno-economic data of the standardized production systems (III) establishment of a scenario framework (IV) determination of the least-cost low-carbon solution of a conventional reference production system under the scenario assumptions made (V) and estimation of the resulting hydrogen and electricity demand (VI). According to the results the expected industrial hydrogen consumption in 2045 ranges from 255 TWh for higher hydrogen prices in or above the range of onshore wind-based green hydrogen supply costs to up to 542 TWh for very low hydrogen prices corresponding to typical blue hydrogen production costs. Meanwhile the direct electricity consumption of the process industries in the results ranges from 122 TWh for these rather low hydrogen prices to 368 TWh for the higher hydrogen prices in the region of or above the hydrogen supply costs from the electrolysis of energy from an onshore wind farm. Most of the break-even hydrogen prices that are relevant to the choice of low-carbon options are in the range of the benchmark purchase costs for blue hydrogen and green hydrogen produced from offshore wind power which span between €40 per MWh and €97 per MWh.
Comparative Analysis of Hydrogen vs. Methane Pipeline Transport Systems with Integrated Methane Pyrolysis for Low-carbon Hydrogen Supply
Jan 2025
Publication
Establishing a climate-neutral energy system is among the most urgent challenges facing humanity with the natural gas network forming a critical component of energy and commodity infrastructure. The hydrogen economy based on climate-neutral hydrogen which serves as both energy source and raw-material for numerous sectors offers a promising pathway for significant reduction in CO2 emissions. However the lack of an extensive hydrogen infrastructure underscores the need for transitional solutions. Given this infrastructure gap and the urgency to establish a reliable and less emission-intensive commodity network methane pyrolysis (MP) emerges as a promising technology for supporting the transition to a climate-neutral energy system. Within this context this study evaluates the intricacies of long-distance pipeline transport of hydrogen (H2) and methane (CH4) focusing on the placement of MP units. The primary goal is to provide “turquoise hydrogen” produced from natural gas via MP along with solid carbon from distant locations to industrial consumers. Two configurations are assessed: Configuration I represents a centralized supply concept transporting molecular hydrogen while Configuration II delivers methane to consumers for on-site hydrogen production. The reference system covers a transport distance of 500 km extending to 4000 km with recompression stations every 125 km. The transport capacity of the hydrogen pipeline is set at 13 GW with the methane mass flow set to match the equivalent hydrogen output chemically bound in methane. A parameter study examines power requirements and global warming impact (GWI) over various transport distances. For distances between 2000 and 4000 km Configuration II requires less power (Δ = 229.4–443.0 MW) and results in GWI savings of 0.25 to 0.37 kgCO2-eq.kgH2−1 owing primarily to the lower specific energy consumption for methane transport compared to hydrogen. The study concludes that the electricity mix of the exporting and importing regions significantly affects the GWI of hydrogen supply with the MP unit contributing a substantial part (6.92 kgCO2-eq.kgH2−1) to the total GWI. The approach of Configuration I is favorable for regions with a low-GWI electricity supply while Configuration II is better suited for regions where the electricity mixes of both the exporting and importing regions are similar.
Governance of Future-making: Green Hydrogen in Namibia and South Africa
Feb 2025
Publication
The green-hydrogen sector has created considerable expectations in the Global South about export-oriented development and industrial path creation. However whether and how these expectations are really materializing requires further scrutiny. This article develops a conceptual approach that we call governance of futuremaking. Thereby we want to understand how actors try to coordinate their expectations about future economic development in different contexts and across scales over time. We conceptualize the emergence of new regional development trajectories as resulting from the use of governance instruments with an increasing bindingness which reflect the interplay between governance of and by expectations. Based on this approach we analyze and compare green-hydrogen activities in Namibia and South Africa. We find that future-making is becoming more binding in both countries but has not resulted in path creation yet.
Review and Evaluation of Hydrogen and Air Heat Exchangers for Fuel Cell-Powered Electric Aircraft Propulsion
Mar 2025
Publication
Hydrogen fuel cell systems are a viable option for electrified aero engines due to their efficiency and environmental benefits. However integrating these systems presents challenges notably in terms of overall system weight and thermal management. Heat exchangers are crucial for the effective thermal management system of electric propulsion systems in commercial electrified aviation. This paper provides a comprehensive review of various heat exchanger types and evaluates their potential applications within these systems. Selection criteria are established based on the specific requirements for air and hydrogen heat exchangers in electrified aircraft. The study highlights the differences in weighting criteria for these two types of heat exchangers and applies a weighted point rating system to assess their performance. Results indicate that extended surface microchannel and printed circuit heat exchangers exhibit significant promise for aviation applications. The paper also identifies key design challenges and research needs particularly in enhancing net heat dissipation increasing compactness improving reliability and ensuring effective integration with aircraft systems.
Ultrasonic Time-of-flight Measurement of Hydrogen Blending Ratios for Industrial Combustion Applications
Oct 2025
Publication
Hydrogen blending offers significant potential for decarbonizing natural gas-based thermal processes particularly in the steel and cement sectors. Due to its distinct combustion properties compared to natural gas – such as lower minimum air requirements and altered flame speeds – the hydrogen fraction of the fuel must be monitored for combustion control. In this study we present an ultrasonic time-of-flight measurement system for hydrogen concentrations of 0–40% in natural gas. The system is verified with test gas mixtures at laboratory scale and validated in a technical-scale setup using a real blower burner (< 60 kW). We evaluate uncertainty of the hydrogen fraction measurement and analyze the influence of varying natural gas compositions. We show that standard uncertainties below 4% can be achieved without knowledge of the specific natural gas composition. Our results provide insights for measurement system design and support the safe application of hydrogen in thermal systems for industrial processes.
Towards Inclusive Path Transplanation: Local Agency for Green Hydrogen Linkage Creation in Namibia
Aug 2025
Publication
Many countries of the Global South struggle to achieve inclusive growth paths despite investment in the exploitation of rich resources. Resource-based industrialization literature stresses the potential for achieving broader development effects via the development of production linkages with local enterprises. The focus lies on market-driven outsourcing dynamics that foster linkage development such as efficiency location-specific knowledge and technology and scale complexity. However little is known about the opportunity space for both policy making and local firms to create these linkages. To address this issue we incorporate the concept of change agency stemming from the path development literature into the discussion on production linkages to show how both (local) firm agency and system-level agency can achieve linkage creation for inclusive path transplantation. We illustrate the framework by scrutinizing the potential inclusion of solar energy companies in Namibia’s emerging green hydrogen economy. The study finds that while the potential for renewable energy companies in Namibia to participate in the value chain is limited an integrated bundle of measures relying on firm- and system-level agency could address peripheral contextual factors overcome entry barriers and leverage further potential for linkage creation in the solar energy sector: mobilizing the local workforce fostering inter-firm cooperation leveraging local advantages creating knowledge institutions enhancing the regulatory framework upgrading infrastructure and enforcing local content regulations.
Green Energy and Steel Imports Reduce Europe's Net-zero Infrastructure Needs
Jun 2025
Publication
Importing renewable energy to Europe may offer many potential benefits including reduced energy costs lower pressure on infrastructure development and less land use within Europe. However open questions remain: on the achievable cost reductions how much should be imported whether the energy vector should be electricity hydrogen or derivatives like ammonia or steel and their impact on Europe’s infrastructure needs. This study integrates a global energy supply chain model with a European energy system model to explore net-zero emission scenarios with varying import volumes costs and vectors. We find system cost reductions of 1-10% within import cost variations of ± 20% with diminishing returns for larger import volumes and a preference for methanol steel and hydrogen imports. Keeping some domestic power-to-X production is beneficial for integrating variable renewables leveraging local carbon sources and power-to-X waste heat. Our findings highlight the need for coordinating import strategies with infrastructure policy and reveal maneuvering space for incorporating non-cost decision factors.
Country Risk Impacts on Export Costs of Green Hydrogen and its Synthetic Downstream Products from the Middle East and North Africa
May 2025
Publication
Green hydrogen produced from renewable energy sources such as wind and solar is increasingly recognized as a critical enabler of the global energy transition and the decarbonization of industrial and transport sectors. The successful adoption of green hydrogen and its derivatives is closely linked to production costs which can vary substantially between countries depending not only on resource potential but also on country-specific financing conditions. These differences arise from country-specific risk factors that affect the costs of capital ultimately influencing investment decisions. However comprehensive assessments that integrate these risks with future cost projections for renewable energy green hydrogen and its synthetic downstream products are lacking. Using the Middle East and North Africa (MENA) as an example this study introduces a novel approach that allows to incorporate mainly qualitative country-specific investment risks into quantitative analyses such as costpotential and energy modelling. Our methodology calculates weighted average costs of capital (WACC) for 17 MENA countries under different risk scenarios providing a more nuanced assessment compared to traditional models that use uniform cost of capital assumptions. The results indicate significant variations in WACC such as between 4.67% in the United Arab Emirates and 24.84% in Yemen or Syria in the business-as-usual scenario. The incorporation of country-specific capital cost scenarios in quantitative analysis is demonstrated by modelling the cost-potential of Fischer-Tropsch (FT) fuels. The results show that countryspecific investment risks significantly impact costs. For instance by 2050 the starting LCOFs in high-risk scenarios can be up to 180% higher than in lowerrisk contexts. This underlines that while renewable energy potential and its cost are important it are the country-specific risk factors—captured through WACC—that have a greater influence in determining the competitiveness of exports and consequently the overall development of the renewable energy green hydrogen and synthetic fuel sectors.
Synergies Between Green Hydrogen and Renewable Energy in South Africa
Aug 2025
Publication
South Africa has excellent conditions for renewable energy generation making it well placed to produce green hydrogen for both domestic use and export. In building a green hydrogen economy around export markets it will face competition from countries with equivalent or better resources and/or that are located closer to export markets (e.g. in North Africa and the Middle East) or have lower capital costs (developed markets like Australia and Canada). South Africa however has an extensive energy system with unserved electricity demand. The ability to trade electricity with the national grid (feeding into the grid during times of peak dedicated renewable energy supply and extracting from the grid during times of low dedicated renewable energy availability) could reduce the cost of producing green hydrogen by as much as 10–25 %. This paper explores the opportunity for South African green hydrogen producers presented by the electricity supply crisis that has been ongoing since 2007. It highlights the potential for a mutually reinforcing growth cycle between renewable energy and green hydrogen to be established which will contribute not only to the mitigation of greenhouse gas emissions but to the local economy and broader society.
Feasibility of Using Rainwater for Hydrogen Production via Electrolysis: Experimental Evaluation and Ionic Analysis
Oct 2025
Publication
This study evaluates the feasibility of employing rainwater as an alternative feedstock for hydrogen production via electrolysis. While conventional systems typically rely on high-purity water—such as deionized or distilled variants—these can be cost-prohibitive and environmentally intensive. Rainwater being naturally available and minimally treated presents a potential sustainable alternative. In this work a series of comparative experiments was conducted using a proton exchange membrane electrolyzer system operating with both deionized water and rainwater collected from different Austrian locations. The chemical composition of rainwater samples was assessed through inductively coupled plasma ion chromatography and visual rapid tests to identify impurities and ionic profiles. The electrolyzer’s performance was evaluated under equivalent operating conditions. Results indicate that rainwater in some cases yielded comparable or marginally superior efficiency compared to deionized water attributed to its inherent ionic content. The study also examines the operational risks linked to trace contaminants and explores possible strategies for their mitigation.
Modeling Homogeneous, Stratified, and Diffusion Combustion in Hydrogen SI Engines Using the Wiebe Approach
Jun 2025
Publication
The use of hydrogen as a fuel for piston engines enables environmentally friendly and efficient operation. However several challenges arise in the combustion process limiting the development of hydrogen engines. These challenges include abnormal combustion the high burning velocity of hydrogen-enriched mixtures increased nitrogen oxide emissions and others. A rational organization of hydrogen combustion can partially or fully mitigate these issues through the use of advanced methods such as late direct injection charge stratification dual injection jet-guided operation and others. However mathematical models describing hydrogen combustion for these methods are still under development complicating the optimization and refinement of hydrogen engines. Previously we proposed a mathematical model based on Wiebe functions to describe premixed and diffusion combustion as well as relatively slow combustion in lean-mixture zones behind the flame front and near-wall regions. This study further develops the model by accounting for the combined influence of the mixture composition and engine speed mixture stratification and the effects of injection and ignition parameters on premixed and diffusion combustion. Special attention is given to combustion modeling in an engine with single injection and jet-guided operation.
Potential Vulnerability of US Green Hydrogen in a World of Interdependent Networks
Jul 2025
Publication
Green hydrogen is viewed as a promising pathway to future decarbonized energy systems. However hydrogen production depends on a few critical minerals particularly platinum and iridium. Here we examine how the supply of these minerals is subject to vulnerabilities hidden in interdependent global networks of trade and investment. We develop an index to quantify these vulnerabilities for a combination of a target country an investing country an intermediary country and a commodity. Focusing on the US as the target country for the import of platinum and iridium we show how vulnerability-inducing investing countries changed between 2010 and 2019. We find that the UK is consistently among investing countries that can potentially induce US vulnerabilities via intermediary exporters of platinum and iridium with South Africa being the primary intermediary country. Future research includes incorporating geopolitical factors and technological innovations to move the index closer from potential to real-world vulnerabilities.
Understanding the Framing of Hydrogen Technology: A Cross-national Content Analysis of Newspaper Coverage in Germany, Saudi Arabia, UAE, and Egypt
Jul 2025
Publication
Introduction: The implementation of national hydrogen strategies targeting zero-emission goals has sparked public discussions regarding energy and environmental communication. However gaining societal acceptance for hydrogen technology poses a significant challenge in numerous countries. Hence this research investigates the framing of hydrogen technology through a comparative analysis of opinion-leading newspapers in Germany Saudi Arabia the United Arab Emirates and Egypt. Methods: Utilizing a quantitative framing analysis based on Entman’s framing approach this research systematically identifies media frames and comprehend their development through specific frame characteristics. A factor analysis identified six distinct frames: Hydrogen as a Sustainable Energy Solution Benefits of Economic and Political Collaboration Technological and Scientific Challenges Governance Issues and Energy Security Industrial and Climate Solutions and Economic Risk. Results: The findings reveal that newspapers frames vary significantly due to contextual factors such as national hydrogen strategies media systems political ideologies article types and focusing events. Specifically German newspapers display diverse and balanced framing in line with its pluralistic media environment and national emphasis on green hydrogen and energy security while newspapers from MENA countries primarily highlight economic and geopolitical benefits aligned with their national strategies and state-controlled media environments. Additionally the political orientation of newspapers affects the diversity of frames particularly in Germany. Moreover non-opinion articles in Germany exhibit greater framing diversity compared to opinion pieces while in the MENA region the framing remains uniform regardless of article type due to centralized media governance. A notable shift in media framing in Germany was found after a significant geopolitical event which changed the frame from climate mitigation to energy security. Discussion: This study underscores the necessity for theoretical and methodological thoroughness in identifying frames as well as the considerable impact of contextual factors on the media representation of emerging sustainable technologies.
Optimal Control of an Over-actuated Spark-Ignited Hydrogen Engine
Jun 2025
Publication
The spark-ignited (SI) hydrogen combustion engine has the potential to noticeably reduce greenhouse gas emissions from passenger cars. To prevent nitrogen oxide emissions and to increase fuel efficiency and power output complex air paths and operating strategies are utilized. This makes the engine control problem more complex challenging the conventional engine calibration process. This work combines and extends the state-of-the-art in real-time combustion engine modeling and optimal control presenting a novel control concept for the efficient operation of a hydrogen combustion engine. The extensive experimental validation with a 1.5 l three-cylinder hydrogen SI engine and a dynamically operated engine test bench with emission and in-cylinder pressure measurements provides a comprehensible comparison to conventional engine control. The results demonstrate that the proposed optimal control decreased the load tracking errors by a factor of up to 2.8 and increased the engine efficiency during lean operation by up to 10 percent while decreasing the calibration effort compared to conventional engine control.
A Comparative Study of Alternative Polymer Binders for the Hydrogen Evolution Reaction
Aug 2025
Publication
Given the economic industrial and environmental value of green dihydrogen (H2) optimization of water electrolysis as a means of producing H2 is essential. Binders are a crucial component of electrocatalysts yet they remain largely underdeveloped with a significant lack of standardization in the field. Therefore targeted research into the development of alternative binder systems is essential for advancing performance and consistency. Binders essentially act as the key to regulating the electrode (support)–catalyst–electrolyte interfacial junctions and contribute to the overall reactivity of the electrocatalyst assembly. Therefore alternative binders were explored with a focus on cost efficiency and environmental compatibility striving to achieve desirable activity and stability. Herein the alkaline hydrogen evolution reaction (HER) was investigated and the sluggish water dissociation step was targeted. Controlled hydrophilic poly(vinyl alcohol)-based hydrogel binders were designed for this application. Three hydrogel binders were evaluated without incorporated electrocatalysts namely PVA145 PVA145-blend-bPEI1.8 and PVA145-blend-PPy. Interestingly the study revealed that the hydrophilicity of the binders exhibited an enhancing effect on the observed activity resulting in improved performance compared to the commercial binder Nafion™. Notably the PVA145 system stands out with an overpotential of 224 mV at−10 mA·cm−2 (geometric) in 1.0 M KOH compared to the 238 mV exhibited by Nafion™. Inclusion of Pt as active material in PVA145 as binder exhibited a synergistic increase in performance achieving a mass activity of 1.174 A.cm−2.mg−1 Pt in comparison to Nafion™’s 0.344 A.cm−2.mg−1 Pt measured at−150 mV vs RHE. Our research aimed to contribute to the development of cost-effective and efficient binder systems stressing the necessity to challenge the dominance of the commercially available binders.
Process Integration and Exergy-based Assessment of High-temperature Solid Oxide Electrolysis Configurations
Sep 2025
Publication
Solid oxide electrolysis (SOEL) is considered an efficient option for largely emission-free hydrogen production and thus for supporting the decarbonization of the process industry. The thermodynamic advantages of high-temperature operation can be utilized particularly when heat integration from subsequent processes is realized. As the produced hydrogen is usually required at a higher pressure level the operating pressure of the electrolysis is a relevant design parameter. The study compares pressurized and near-atmospheric designs of 126 MW SOEL systems with and without the integration of process heat from a downstream ammonia synthesis and the inefficiencies that occur in the processes. Furthermore process improvements by sweep-air utilization are investigated. Pinch analysis is applied to determine the potential of internal heat recovery and the minimum external heating and cooling demand. It is shown that pressurized SOEL operation does not necessarily decrease the overall power consumption for compression due to the high power requirement of the sweep-air compressor. The exergetic efficiencies of the standalone SOEL processes achieve similar values of = 81 %. Results further show that integrating the heat of reaction from ammonia synthesis can replace almost the entire electrically supplied thermal energy thereby improving the overall exergetic efficiency by up to 3.5 percentage points. However the exergetic efficiency strongly depends on the applied air ratio. The highest exergetic efficiency of 86 % can be achieved by employing sweep-air utilization with an expander. The results demonstrate that integrating downstream process heat and applying sweep-air utilization can significantly enhance overall efficiency and thus reduce external energy requirements.
Increasing Public Acceptance of Fuel Cell Vehicles in Germany: A Perspective on Pioneer Users
Jun 2025
Publication
Fuel cell vehicles (FCVs) represent an intriguing alternative to battery electric vehicles (BEVs). While the acceptance of BEVs has been widely discussed acceptance-based recommendations for promoting adoption of FCVs remain ambiguous. This paper aims to improve our understanding by reporting results from a pioneer study based on the standardized Unified Theory of Acceptance and Use of Technology 2 (UTAUT2). The sample consists of n1 = 258 registered customers of H2mobility in Germany. For effect control another n2 = 294 participant sample was drawn from the baseline population. Data were analyzed using SmartPLS 4 and importance-performance mapping (IPMA). Results demonstrate that FCV acceptance primarily relies on Perceived Usefulness Perceived Conditions and Normative Influence while surprisingly hypotheses involving Perceived Risk and Green Attitude are rejected. Finally a discussion reveals ways to increase the level of public acceptance. Three practical strategies emerge. For future acceptance analyses the authors suggest incorporating the young concept of ‘societal readiness’.
Alternative Fuels in Aero Engine Performance Calculations
Oct 2025
Publication
This paper presents a method for gas turbine performance calculations with alternative fuels with a particular focus on their use in aircraft engines. The effects of various alternative aviation fuels on fuel consumption CO2 emissions and contrail formation are examined in a comparative study. We use the GasTurb performance software and calculate heat release and hot section gas properties using a chemical equilibrium solver. Fuels with complex compositions are included in the calculation via surrogates of a limited number of known species that mimic the relevant properties of the real fuel. An automated method is used for the fuel surrogate formulation. We compare the results of this rigorous approach with the simplified approach of calculating the heat release using an alternative fuel’s heating value while still using the gas properties of conventional Jet A-1. The results show that the latter approach systematically overpredicts fuel consumption by up to 0.2% for aromaticsfree synthetic kerosene (e.g. “biofuels”). Overall aircraft engines running on alternative fuels tend to be more fuel efficient due to their often higher hydrogen contents and thus fuel heating values. We find reductions in fuel consumption of up to 2.8% during cruise when using aromatics-free synthetic kerosene. We further assess how alternative fuels affect contrail formation based on the Schmidt-Appleman criterion. Contrails can form 200 m lower under cruise conditions when burning aromatics-free synthetic kerosene instead of Jet A-1 with identical thrust requirements and under the same atmospheric conditions mainly due to their higher hydrogen content. In summary we present a flexible yet easy-to-use method for studying fuel effects in performance calculations that avoids small but systematic errors by rigorously calculating the heat release and hot section gas properties for each fuel.
Exploring the Potential of Ammonia as a Fuel: Advances in Combustion Understanding and Large-scale Furnace Applications
Sep 2025
Publication
From an environmental standpoint carbon-free energy carriers such as ammonia and hydrogen are essential for future energy systems. However their hightemperature chemical behavior remains insufficiently understood posing challenges for the development and optimization of advanced combustion technologies. Ammonia in particular is globally available and cost-effective especially for energy-intensive industries. The addition of ammonia or hydrogen to methane significantly reduces the accuracy of existing predictive models. Therefore validated and detailed data are urgently needed to enable reliable design and performance predictions. This review highlights the compatibility of ammonia with existing combustion infrastructure facilitating a smoother transition to more sustainable heating methods without the need for entirely new systems. Applications in high-temperature heating processes such as metal processing ceramics and glass production and power generation are of particular interest. This review focuses on the systematic assessment of alternative fuel mixtures comprising ammonia and hydrogen as well as natural gas with particular consideration of existing safety-related parameters and combustion characteristics. Fundamental quantities such as the laminar burning velocity are discussed in the context of their relevance for fuel mixtures and their scalability toward turbulent flame propagation which is of critical importance for industrial burner and reactor design. The influence of fuel composition on ignition limits is examined as these are essential parameters for safety margin definitions and operational boundary conditions. Furthermore flame stability in mixed-fuel systems is addressed to evaluate the practical feasibility and robustness of combustion under varying process conditions. A detailed overview of current diagnostic and analysis methods follows encompassing both pollutant measurement techniques and the detection of key radical species. These diagnostics form the experimental basis for reaction kinetics modeling and mechanism validation. Given the importance of emission formation in combustion systems a dedicated subsection summarizes major emission trends even though a comprehensive treatment would exceed the scope of this review. Thermal radiation effects which are highly relevant for heat transfer and system efficiency in large-scale applications are then reviewed. In parallel current developments in numerical simulation approaches for industrial-scale combustion systems are presented including aspects of model accuracy boundary conditions and computational efficiency. The review also incorporates insights from materials engineering particularly regarding high-temperature material performance corrosion resistance and compatibility with combustion products. Based on these interdisciplinary findings operational strategies for high-temperature furnaces are outlined and selected industrial reference systems are briefly presented. This integrated approach aims to support the design optimization and safe operation of next-generation combustion technologies utilizing carbon-free or low-carbon fuels.
Catalytic Hydrogen Combustion as Heat Source for the Dehydrogenation of Liquid Organic Hydrogen Carriers using a Novel Compact Autothermal Reactor
Sep 2025
Publication
The experimental performance of an autothermal hydrogen release unit comprising a perhydro benzyltoluene (H12-BT) dehydrogenation chamber and a catalytic hydrogen combustion (CHC) chamber in thermal contact is discussed. In detail the applied set-up comprised a multi-tubular CHC heating based on seven parallel tubes with the reactor shell containing a commercial dehydrogenation catalyst. In this way the CHC heated the endothermal LOHC dehydrogenation using a part of the hydrogen generated in the dehydrogenation. The proposed heating concept for autothermal LOHC dehydrogenation offers several advantages over state-of-the-art heating concepts including minimized space consumption high efficiency and zero NOx emissions. During performance tests the process reached a minimum hydrogen combustion fraction of 37 % while the minimum heat requirement for the dehydrogenation reaction for industrial scale plants is 33 %. The reactor orientation (vertical vs horizontal) and the flow configuration (counter-current vs. co-current) showed very little influence on the performance demonstrating the robustness of the proposed reactor design.
The Need for Change: A Roadmap for the Sustainable Transformation of the Chemical Industry
Jun 2025
Publication
The chemical industry faces major challenges worldwide. Since 1950 production has increased 50-fold and is projected to continue growing particularly in Asia. It is one of the most energy- and resource-intensive industries contributing significantly to greenhouse gas emissions and the depletion of finite resources. This development exceeds planetary boundaries and calls for a sustainable transformation of the industry. The key transformation areas are as follows: (1) Non-Fossil Energy Supply: The industry must transition away from fossil fuels. Renewable electricity can replace natural gas while green hydrogen can be used for high-temperature processes. (2) Circularity: Chemical production remains largely linear with most products ending up as waste. Sustainable product design and improved recycling processes are crucial. (3) Non-Fossil Feedstock: To achieve greenhouse gas neutrality oil gas and coal must be replaced by recycling plastics renewable biomaterials or CO2-based processes. (4) Sustainable Chemical Production: Energy and resource savings can be achieved through advancements like catalysis biotechnology microreactors and new separation techniques. (5) Sustainable Chemical Products: Chemicals should be designed to be “Safe and Sustainable by Design” (SSbD) meaning they should not have hazardous properties unless essential to their function. (6) Sufficiency: Beyond efficiency and circularity reducing overall material flows is essential to stay within planetary boundaries. This shift requires political economic and societal efforts. Achieving greenhouse gas neutrality in Europe by 2050 demands swift and decisive action from industry governments and society. The speed of transformation is currently too slow to reach this goal. Science can drive innovation but international agreements are necessary to establish a binding framework for action.
Overcoming Hurdles and Harnessing the Potential of the Hydrogen Transition in Germany
Jun 2025
Publication
Green hydrogen has become a core element of Europe’s energy transition to assist in lowering carbon emissions. However the transition to green hydrogen faces challenges including the cost of production availability of renewable energy sources public opposition and the need for supportive government policies and financial initiatives. While there are other alternatives for producing low-carbon hydrogen for example blue hydrogen German funding favours projects that involve hydrogen production via electrolysis. Beyond climate goals it is anticipated that a green hydrogen industry will create economic benefits and a wide-range of collaborative opportunities with key international partnerships increasing energy security if done appropriately. Germany a leader in green hydrogen technology will need to rely on imports to meet long-term demand due to limited renewable energy capacity. Despite the current obstacles to transitioning to green hydrogen it is felt that ultimately the benefits of this industry and reducing emissions will outweigh the associated costs of production. This study analyses the hydrogen transition in Germany by interviewing 37 European experts guided by the research question: What are the key perceived barriers and opportunities influencing the successful adoption and integration of hydrogen technologies in Germany’s hydrogen transition?
Preliminary Design of Regional Aircraft—Integration of a Fuel Cell-Electric Energy Network in SUAVE
Mar 2025
Publication
To enable climate-neutral aviation improving the energy efficiency of aircraft is essential. The research project Synergies of Highly Integrated Transport Aircraft investigates cross-disciplinary synergies in aircraft and propulsion technologies to achieve energy savings. This study examines a fuel cell electric powered configuration with distributed electric propulsion. For this a reverse-engineered ATR 72-500 serves as a reference model for calibrating the methods and ensuring accurate performance modeling. A baseline configuration featuring a state-of-the-art turboprop engine with the same entry-into-service is also introduced for a meaningful performance comparison. The analysis uses an enhanced version of the Stanford University Aerospace Vehicle Environment (SUAVE) a Python-based aircraft design environment that allows for novel energy network architectures. This paper details the preliminary aircraft design process including calibration presents the resulting aircraft configurations and examines the integration of a fuel cell-electric energy network. The results provide a foundation for higher fidelity studies and performance comparisons offering insights into the trade-offs associated with hydrogen-based propulsion systems. All fundamental equations and methodologies are explicitly presented ensuring transparency clarity and reproducibility. This comprehensive disclosure allows the broader scientific community to utilize and refine these findings facilitating further progress in hydrogen-powered aviation technologies.
Injection Strategies in a Hydrogen SI Engine: Parameter Selection and Comparative Analysis
Oct 2025
Publication
Injection strategies play a crucial role in determining hydrogen engine performance. The diversity of these strategies and the limited number of comparative studies highlight the need for further investigation. This study focuses on the analysis parameter selection and comparison of single early and late direct injection single injection with ignition occurring during injection (the so-called jet-guided operation) and dual injection in a hydrogen spark-ignition engine. The applicability and effectiveness of these injection strategies are assessed using contour maps with ignition timing and start of injection as coordinates representing equal levels of key engine parameters. Based on this approach injection and ignition settings are selected for a range of engine operating modes. Simulations of engine performance under different load conditions are carried out using the selected parameters for each strategy. The results indicate that the highest indicated thermal efficiencies are achieved with single late injection while the lowest occur with dual injection. At the same time both dual injection and jet-guided operation provide advantages in terms of knock suppression peak pressure reduction and reduced nitrogen oxide emissions.
A Proposal of Hydrogen Safety Technology for Decommissioning of the Fukushima Daiichi Nuclear Power Station
Mar 2025
Publication
The safe removal transportation and long-term storage of fuel debris in the decommissioning of Fukushima Daiichi is the biggest challenge facing Japan. In the nuclear power field passive autocatalytic recombiners (PARs) have become established as a technology to prevent hydrogen explosions inside the containment vessel. To utilize PAR as a measure to reduce the concentration of hydrogen generated in the fuel debris storage canister which is currently an issue it is required to perform in a sealed environment with high doses of radiation low temperature and high humidity and there are many challenges different from conventional PAR. A honeycombshaped catalyst based on automotive catalyst technology has been newly designed as a PAR and research has been conducted to solve unique problems such as high dose radiation low temperature high humidity coexistence of hydrogen and low oxygen and catalyst poisons. This paper summarizes the challenges of hydrogen generation in a sealed container the results of research and a guide to how to use the PAR for fuel debris storage canisters.
Who Is in and How? A Comprehensive Study on Stakeholder Perspectives in the Green Hydrogen Sector in Luxembourg
Oct 2025
Publication
Green hydrogen has the potential to contribute to the decarbonization of the fossil fuel industry and its development is expected to increase in the coming years. The social dynamics among the various actors in the green hydrogen sector are studied to understand their public perception. Using the technological innovation system research approach for the stakeholder analysis and the qualitative thematic analysis method for the interviews with experts this study presents an overview of the actors in the green hydrogen sector and their relations in Luxembourg. As a central European country with strategic political and geographic relevance Luxembourg offers a timely case for analyzing public perception before the large-scale implementation of green hydrogen. Observing this early stage allows for future comparative insights as the national hydrogen strategy progresses. Results show high expectations for green hydrogen in mobility and industry but concerns persist over infrastructure costs safety and public awareness. Regional stakeholders demonstrate a strong willingness to collaborate recognizing that local public acceptance still requires effort particularly in areas such as clear and inclusive communication sharing knowledge and fostering trust. These findings provide practical insights for stakeholder engagement strategies and theoretical contributions to the study of social dynamics in sustainability transitions.
Spatial Planning Policies for Export-oriented Green-hydrogen Projects in Chile, Namibia, and South Africa
Jun 2025
Publication
Export-oriented green-hydrogen projects (EOGH2P) are being developed in regions with optimal renewableenergy resources. Their reliance on economies of scale makes them land-intensive and object of spatial planning policies. However the impact of spatial planning on the development of EOGH2P remains underexplored. Drawing on the spatial planning and megaproject literatures the analysis of planning documents and expert interviews this paper analyzes how spatial planning influences the development of EOGH2P in Chile Namibia and South Africa. The three countries have developed different spatial planning approaches for EOGH2Ps and are analyzed by employing a comparative case-study design. Our findings reveal that Namibia pursues a restrictive approach South Africa a facilitative approach whereas Chile is shifting from a market-based to a restrictive approach. The respective approaches reflect different political priorities and stakeholder interests and imply diverse effects on the development of EOGH2Ps in terms of their number size shared infrastructure socioenvironmental impact and acceptance. This study underscores the need for well-designed spatial planning frameworks and provides insights for planners and stakeholders on their potential effects.
Determining the Hydrogen Conversion Rates of a Passive Catalytic Recombiner for Hydrogen Risk Mitigation
May 2025
Publication
Hydrogen can play a key role as short- and long-term energy storage solution in an energy grid with fluctuating renewable sources. In technologies using hydrogen there is always the risk of unintended leakages due to the low density of gaseous hydrogen. The risk becomes specifically high in confined areas where leaking hydrogen could easily mix with air and form flammable gas mixtures. In the maritime transportation large and congested geometries can be subject to accumulation of hydrogen. A mitigation measure for areas where venting is insufficient or even impossible is the installation of catalytic recombiners. The operational behavior can be described with numerical models which are required to optimize the location and to assess the efficiency of the mitigation solution. In the present study we established an experimental procedure in the REKO-4 facility a 5.5 m³ vessel to determine the recombination rate obtained from a recombiner. Based on the experimental data an engineering correlation was developed to be used for simulations in safety assessments.
Simulation of Hydrogen Drying via Adsorption in Offshore Hydrogen Production
Sep 2025
Publication
According to the international standard ISO 14687:2019 for hydrogen fuel quality the maximum allowable concentration of water in hydrogen for use in refueling stations and storage systems must not exceed 5 µmol/mol. Therefore an adsorption purification process following the electrolyzer is necessary. This study numerically investigates the adsorption of water and the corresponding water loading on zeolite 13X BFK based on the mass flows entering the adsorption column from three 5 MW electrolyzers coupled to a 15 MW offshore wind turbine. As the mass flow is influenced by wind speed a direct comparison between realistic wind speeds and adsorption loading is presented. The presented numerical discretization of the model also accounts for perturbations in wind speed and consequently mass flows. In addition adsorption isobars were measured for water on zeolite 13X BFK within the required pressure and temperature range. The measured data was utilized to fit parameters to the Langmuir–Freundlich isotherm.
Providing the Transport Sector in Europe with Fossil Free Energy - A Model-based Analysis under Consideration of the MENA Region
Mar 2025
Publication
For reaching the European greenhouse gas emission targets the phase-in of alternative technologies and energy carriers is crucial for all sectors. For the transport sector synthetic fuels are–next to electromobility–a promising option especially for long-distance shipping and air transport. Within this context the import of synthetic fuels from the Middle East and Northern Africa (MENA) region seems attractive due to low costs for renewable electricity in this region and low transport costs of synthetic fuels at the same time. Against this background this paper analyzes the role of the MENA region in meeting the future synthetic fuel demand in Europe using a cost-optimizing energy supply model. In this model the production storage and transport of electricity hydrogen and synthetic fuels by various technologies in both European and MENA countries in the period up to 2050 are explicitly modeled. Thereby different scenarios are analyzed to depict regional differences in investment risks: a base scenario that does not take into account regional differences in investments risks and three risk scenarios with different developments of regional investment risks. Sensitivity analyses are also carried out to derive conclusions about the robustness of results. Results show that meeting the future synthetic fuel demand in Europe to a large extent by imports from the MENA region can be an attractive option from an economic point of view. If investment risks are incorporated however lower import quotas of synthetic fuels are economically attractive for Europe: the higher generation costs are outweighed by the lower investments risks in Europe to a certain extent. Thereby investment risks outweigh other factors such as transport distance or renewable electricity generation costs in terms of exporting MENA regions and a synthetic fuel import is especially attractive from MENA countries with low investment risks. Concluding within this paper detailed export relations between MENA and EU considering investment risks were modeled for the first time. These model results should be complemented by a more in-depth analysis of the MENA countries including evaluating opportunities for local value chain development sustainability concerns (including social factors) and optimal site selection.
Method for Multi-criteria and Mission-specific Component Dimensioning for Heavy-duty Fuel Cell Trucks
May 2025
Publication
Heavy-duty fuel cell trucks are a promising approach to reduce the CO2 emissions of logistic fleets. Due to their higher powertrain energy density in comparison to battery-electric trucks they are especially suited for long-haul applications while transporting high payloads. Despite these great advantages the fleet integration of such vehicles is made difficult due to high costs and limited performance in thermally critical environmental conditions. These challenges are addressed in the European Union (EU) funded project ESCALATE which aims to demonstrate high-efficiency zero-emission heavy-duty vehicle (zHDV) powertrains that provide a range of 800 km without refueling or recharging. Powertrain components and their corresponding thermal components account for a large part of the production costs. For vehicle users higher costs are only acceptable if a significantly higher benefit can be achieved. Therefore it is important to size these components for the actual vehicle mission to avoid oversizing. In this paper an optimization method which determines the optimum component sizes for a given mission scenario under consideration of multiple criteria (e.g. costs performance and range) is presented.
Investigation on Cooling Effect of Water Sprays on Tunnel Fires of Hydrogen
Sep 2025
Publication
As one of the most promising renewable green energies hydrogen power is a popularly accepted option to drive automobiles. Commercial application of fuel cell vehicles has been started since 2015. More and more hydrogen safety concerns have been considered for years. Tunnels are an important part of traffic infrastructure with a mostly confined feature. A hydrogen leak followed possibly by a hydrogen fire is a potential accident scenario which can be triggered trivially by a car accident while hydrogen-powered vehicles operate in a tunnel. Water spray is recommended traditionally as a mitigation measure against tunnel fires. The interaction between water spray and hydrogen fire is studied by way of numerical simulations. By using the computer program of Fire Dynamics Simulator (FDS) tunnel fires of released hydrogen in different scales are simulated coupled with water droplet injections featured in different droplet sizes or varying mass flow rates. The cooling effect of spray on hot gases of hydrogen fires is apparently observed in the simulations. However in some circumstances the turbulence intensified by the water injection can prompt hydrogen combustion which is a negative side effect of the spray.
A Comprehensive Review of Sustainable Energy Systems in the Context of the German Energy Transition Part 2: Renewable Energy and Storage Technologies
Sep 2025
Publication
As a continuation of part 1 which examined the development status and system foundations of sustainable energy systems (SES) in the context of German energy transition this paper provides a comprehensive review of the core technologies enabling the development of SES. It covers recent advances in photovoltaic (PV) wind energy geo‑ thermal energy hydrogen and energy storage. Key trends include the evolution of high-efficiency solar and wind technologies intelligent control systems sector coupling through hydrogen integration and the diversification of electrochemical and mechanical storage solutions. Together these innovations are fostering a more flexible resil‑ ient and low-carbon energy infrastructure. The review further highlights the importance of system-level integration by linking generation conversion and storage to address the intermittency of renewable energy and support longterm decarbonization goals.
Model Predictive Supervisory Control for Multi-stack Electrolyzers Using Multilinear Modeling
Oct 2025
Publication
Offshore green hydrogen production lacks of flexible and scalable supervisory control approaches for multistack electrolyzers raising the need for extendable and high-performance solutions. This work presents a two-stage nonlinear model predictive control (MPC) method. First an MPC stage generates a discrete on-off electrolyzer switching decision through algebraic relaxation of a Boolean signal. The second MPC stage receives the stack’s on-off operation decision and optimizes hydrogen production. This is a novel approach for solving a mixed-integer nonlinear program (MINP) in multi-stack electrolyzer control applications. In order to realize the MPC the advantages of the implicit multilinear time-invariant (iMTI) model class are exploited for the first time for proton exchange membrane (PEM) electrolyzer models. A modular flexible and scalable framework in MATLAB is built. The tensor based iMTI model in canonical polyadic (CP) decomposed form breaks the curse of dimensionality and enables effective model composition for electrolyzers. Simulation results show an appropriate multilinear model representation of the nonlinear system dynamics in the operation region. A sensitivity analysis identified three numeric factors as decisive for the effectiveness of the MPC approach. The classic rule-based control methods Daisy Chain and Equal serve as reference. Over two weeks and under a wind power input profile the MPC strategy performs better regarding the objective of hydrogen production compared to the Daisy Chain (4.60 %) and Equal (0.43 %) power distribution controllers. As a side effect of the optimization a convergence of the degradation states is observed.
No more items...