Denmark
Low-Carbon Optimal Scheduling Model for Peak Shaving Resources in Multi-Energy Power Systems Considering Large-Scale Access for Electric Vehicles
May 2023
Publication
Aiming at the synergy between a system’s carbon emission reduction demand and the economy of peak shaving operation in the process of optimizing the flexible resource peaking unit portfolio of a multi-energy power system containing large-scale electric vehicles this paper proposes a low-carbon optimal scheduling model for peak shaving resources in multi-energy power systems considering large-scale access for electric vehicles. Firstly the charging and discharging characteristics of electric vehicles were studied and a comprehensive cost model for electric vehicles heat storage and hydrogen storage was established. At the same time the carbon emission characteristics of multienergy power systems and their emission cost models under specific carbon trading mechanisms were established. Secondly the change characteristics of the system’s carbon emissions were studied and a carbon emission cost model of multi-energy power was established considering the carbon emission reduction demand of the system. Then taking the carbon emission of the system and the peak regulating operation costs of traditional units energy storage and new energy unit as optimization objectives the multi-energy power system peak regulation multi-objective optimization scheduling model was established and NSGA-II was used to solve the scheduling model. Finally based on a regional power grid data in Northeast China the improved IEEE 30 node multi-energy power system peak shaving simulation model was built and the simulation analysis verified the feasibility of the optimal scheduling model proposed in this paper.
The Impact of Hydrogen Admixture into Natural Gas on Residential and Commercial Gas Appliances
Jan 2022
Publication
Hydrogen as a carbon-free fuel is commonly expected to play a major role in future energy supply e.g. as an admixture gas in natural gas grids. Which impacts on residential and commercial gas appliances can be expected due to the significantly different physical and chemical properties of hydrogen-enriched natural gas? This paper analyses and discusses blends of hydrogen and natural gas from the perspective of combustion science. The admixture of hydrogen into natural gas changes the properties of the fuel gas. Depending on the combustion system burner design and other boundary conditions these changes may cause higher combustion temperatures and laminar combustion velocities while changing flame positions and shapes are also to be expected. For appliances that are designed for natural gas these effects may cause risk of flashback reduced operational safety material deterioration higher nitrogen oxides emissions (NOx) and efficiency losses. Theoretical considerations and first measurements indicate that the effects of hydrogen admixture on combustion temperatures and the laminar combustion velocities are often largely mitigated by a shift towards higher air excess ratios in the absence of combustion control systems but also that common combustion control technologies may be unable to react properly to the presence of hydrogen in the fuel.
Hydrogen-fueled Car Fire Spread to Adjacent Vehicles in Car Parks
Sep 2019
Publication
Car park fires are known to be dangerous due to the risk of fast fire spread from one car to another. In general no fatalities are recorded in such fires but they may have a great cost in relation to damaged cars and structural repair. A very recent example is the Liverpool multi-storey car park fire from December 31 2017. It destroyed 1400 cars and parts of the building structure collapsed. This questions the validity of current design praxis of car parks. Literature studies assumes a 12 minutes period for the fire spread from one gasoline fuelled car to another. Statistical research and test from the European commission of steel structures states that in an open car park at most 3-4 vehicles are expected to be on fire at the same time.<br/>A number of investigations have been made concerning vehicles performance in car park fires but only a few are concerned with hydrogen-fuelled vehicles (HFV). It is therefore important to investigate how these new vehicles may contribute to potential fire spread scenario. The aim of the paper is to report the outcome of car park fire spread simulations involving common fuelled and hydrogen fuelled cars. The case study is based on a typical car park found in Denmark. The simulation applied numerical models implemented in the Fire Dynamic Simulator (FDS). In particular the focus of the study is on the influence of the parking distance to fire spread to adjacent vehicles in case a TPRD is activated during a car fire. The results help understanding whether different design rules should be envisaged for such structures or how a sufficient safety level can be obtained by ensuring specific parking condition for the hydrogen-fuelled cars.
Magnesium Based Materials for Hydrogen Based Energy Storage: Past, Present and Future
Jan 2019
Publication
Volodymyr A. Yartys,
Mykhaylo V. Lototskyy,
Etsuo Akiba,
Rene Albert,
V. E. Antonov,
Jose-Ramón Ares,
Marcello Baricco,
Natacha Bourgeois,
Craig Buckley,
José Bellosta von Colbe,
Jean-Claude Crivello,
Fermin Cuevas,
Roman V. Denys,
Martin Dornheim,
Michael Felderhoff,
David M. Grant,
Bjørn Christian Hauback,
Terry D. Humphries,
Isaac Jacob,
Petra E. de Jongh,
Jean-Marc Joubert,
Mikhail A. Kuzovnikov,
Michel Latroche,
Mark Paskevicius,
Luca Pasquini,
L. Popilevsky,
Vladimir M. Skripnyuk,
Eugene I. Rabkin,
M. Veronica Sofianos,
Alastair D. Stuart,
Gavin Walker,
Hui Wang,
Colin Webb,
Min Zhu and
Torben R. Jensen
Magnesium hydride owns the largest share of publications on solid materials for hydrogen storage. The “Magnesium group” of international experts contributing to IEA Task 32 “Hydrogen Based Energy Storage” recently published two review papers presenting the activities of the group focused on magnesium hydride based materials and on Mg based compounds for hydrogen and energy storage. This review article not only overviews the latest activities on both fundamental aspects of Mg-based hydrides and their applications but also presents a historic overview on the topic and outlines projected future developments. Particular attention is paid to the theoretical and experimental studies of Mg-H system at extreme pressures kinetics and thermodynamics of the systems based on MgH2 nanostructuring new Mg-based compounds and novel composites and catalysis in the Mg based H storage systems. Finally thermal energy storage and upscaled H storage systems accommodating MgH2 are presented.
Application of Hydrides in Hydrogen Storage and Compression: Achievements, Outlook and Perspectives
Feb 2019
Publication
José Bellosta von Colbe,
Jose-Ramón Ares,
Jussara Barale,
Marcello Baricco,
Craig Buckley,
Giovanni Capurso,
Noris Gallandat,
David M. Grant,
Matylda N. Guzik,
Isaac Jacob,
Emil H. Jensen,
Julian Jepsen,
Thomas Klassen,
Mykhaylo V. Lototskyy,
Kandavel Manickam,
Amelia Montone,
Julian Puszkiel,
Martin Dornheim,
Sabrina Sartori,
Drew Sheppard,
Alastair D. Stuart,
Gavin Walker,
Colin Webb,
Heena Yang,
Volodymyr A. Yartys,
Andreas Züttel and
Torben R. Jensen
Metal hydrides are known as a potential efficient low-risk option for high-density hydrogen storage since the late 1970s. In this paper the present status and the future perspectives of the use of metal hydrides for hydrogen storage are discussed. Since the early 1990s interstitial metal hydrides are known as base materials for Ni – metal hydride rechargeable batteries. For hydrogen storage metal hydride systems have been developed in the 2010s [1] for use in emergency or backup power units i. e. for stationary applications.<br/>With the development and completion of the first submarines of the U212 A series by HDW (now Thyssen Krupp Marine Systems) in 2003 and its export class U214 in 2004 the use of metal hydrides for hydrogen storage in mobile applications has been established with new application fields coming into focus.<br/>In the last decades a huge number of new intermetallic and partially covalent hydrogen absorbing compounds has been identified and partly more partly less extensively characterized.<br/>In addition based on the thermodynamic properties of metal hydrides this class of materials gives the opportunity to develop a new hydrogen compression technology. They allow the direct conversion from thermal energy into the compression of hydrogen gas without the need of any moving parts. Such compressors have been developed and are nowadays commercially available for pressures up to 200 bar. Metal hydride based compressors for higher pressures are under development. Moreover storage systems consisting of the combination of metal hydrides and high-pressure vessels have been proposed as a realistic solution for on-board hydrogen storage on fuel cell vehicles.<br/>In the frame of the “Hydrogen Storage Systems for Mobile and Stationary Applications” Group in the International Energy Agency (IEA) Hydrogen Task 32 “Hydrogen-based energy storage” different compounds have been and will be scaled-up in the near future and tested in the range of 500 g to several hundred kg for use in hydrogen storage applications.
The Role of Effectiveness Factor on the Modeling of Methanol Steam Reforming Over CuO/ZnO/Al2O3 Catalyst in a Multi-tubular Reactor
Jan 2022
Publication
A pseudo-homogeneous model for the methanol steam reforming process was developed based on reaction kinetics over a CuO/ZnO/Al2O3 catalyst and non-adiabatic heat and mass transfer performances in a co-current packed-bed reactor. A Thiele modulus method and an intraparticle distribution method were applied for predicting the effectiveness factors for main reactions and providing insights into the diffusion-reaction process in a cylindrical catalyst pellet. The results of both methods are validated and show good agreements with the experimental data but the intraparticle distribution method provides better predictions. Results indicate that increases in catalyst size and bulk fluid temperature amplify the impact of intraparticle diffusion limitations showing a decrease in effectiveness factors. To satisfy the requirements of a high temperature polymer electrolyte membrane fuel cell stack the optimized operating conditions which bring the methanol and CO concentrations to less than 1% vol in the reformate stream are determined based on the simulation results.
Power-to-fuels Via Solid-oxide Electrolyzer: Operating Window and Techno-economics
May 2019
Publication
Power-to-fuel systems via solid-oxide electrolysis are promising for storing excess renewable electricity by efficient electrolysis of steam (or co-electrolysis of steam and CO2) into hydrogen (or syngas) which can be further converted into synthetic fuels with plant-wise thermal integration. Electrolysis stack performance and durability determine the system design performance and long-term operating strategy; thus solid-oxide electrolyzer based power-to-fuels were investigated from the stack to system levels. At the stack level the data from a 6000-h stack testing under laboratory isothermal conditions were used to calibrate a quasi-2D model which enables to predict practical isothermal stack performance with reasonable accuracy. Feasible stack operating windows meeting various design specifications (e.g. specific syngas composition) were further generated to support the selection of operating points. At the system level with the chosen similar stack operating points various power-to-fuel systems including power-to-hydrogen power-to-methane power-to-methanol (dimethyl ether) and power-to-gasoline were compared techno-economically considering system-level heat integration. Several operating strategies of the stack were compared to address the increase in stack temperature due to degradation. The modeling results show that the system efficiency for producing H2 methane methanol/dimethyl ether and gasoline decreases sequentially from 94% (power-to-H2) to 64% (power-to-gasoline) based on a higher heating value. Co-electrolysis which allows better heat integration can improve the efficiency of the systems with less exothermic fuel-synthesis processes (e.g. methanol/dimethyl ether) but offers limited advantages for power-to-methane and power-to-gasoline systems. In a likely future scenario where the growing amount of electricity from renewable sources results in increasing periods of a negative electricity price solid oxide electrolyser based power-to-fuel systems are highly suitable for levelling the price fluctuations in an economic way.
Economic Evaluation of a Power-to-hydrogen System Providing Frequency Regulation Reserves: A Case Study of Denmark
Mar 2023
Publication
Operating costs are dominant in the hydrogen production of a power-to-hydrogen system. An optimal operational strategy or bidding framework is effective in reducing these costs. However it is still found that the production cost of hydrogen is high. As the electrolysis unit is characterized by high flexibility providing ancillary service to the grid becomes a potential pathway for revenue stacking. Recent research has demonstrated the feasibility of providing such a service but the related economics have not been well evaluated. In this work we propose a comprehensive operation model to enable participation in the day-head balancing and reserve markets. Three types of reserves are considered by using different operational constraints. Based on the proposed operation framework we assess the economic performance of a power-to-hydrogen system in Denmark using plentiful actual market data. The results reveal that providing frequency containment reserve and automatic frequency restoration reserve efficiently raises the operational contribution margins. In parallel by investing in the cash flows net present value and break-even hydrogen prices we conclude that providing reserves makes the power-to-hydrogen project more profitable in the studied period and region.
The Socio-technical Dynamics of Net-zero Industrial Megaprojects: Outside-in and Inside-out Analyses of the Humber Industrial Cluster
Feb 2023
Publication
Although energy-intensive industries are often seen as ‘hard-to-decarbonise’ net-zero megaprojects for industrial clusters promise to improve the technical and economic feasibility of hydrogen fuel switching and carbon capture and storage (CCS). Mobilising insights from the megaproject literature this paper analyses the dynamics of an ambitious first-of-kind net-zero megaproject in the Humber industrial cluster in the United Kingdom which includes CCS and hydrogen infrastructure systems industrial fuel switching CO2 capture green and blue hydrogen production and hydrogen storage. To analyse the dynamics of this emerging megaproject the article uses a socio-technical system lens to focus on developments in technology actors and institutions. Synthesising multiple megaproject literature insights the paper develops a comprehensive framework that addresses both aggregate (‘outside-in’) developments and the endogenous (‘inside-out’) experiences and activities regarding three specific challenges: technical system integration actor coordination and institutional alignment. Drawing on an original dataset involving expert interviews (N = 46) site visits (N = 7) and document analysis the ‘outside-in’ analysis finds that the Humber megaproject has progressed rapidly from outline visions to specific technical designs enacted by new coalitions and driven by strengthening policy targets and financial support schemes. The complementary ‘inside-out’ analysis however also finds 12 alignment challenges that can delay or derail materialisation of the plans. While policies are essential aggregate drivers institutional misalignments presently also prevent project-actors from finalising design and investment decisions. Our analysis also finds important tensions between the project's high-pace delivery focus (to meet government targets) and allowing sufficient time for pilot projects learning-by-doing and design iterations.
THyGA - Test Report on Mitigation Solutions for Residential Natural Gas Appliances Not Designed for Hydrogen Admixture
Apr 2023
Publication
This report from the WP5 “Mitigation” provides information and test results regarding perturbations that hydrogen could cause to gas appliances when blended to natural gas especially on anatural draught for exhaust fumes or acidity for the condensates. The important topic of on-site adjustment is also studied with test results on alternative technologies and proposals of mitigation approaches.
THyGA - Long Term Effect of H2 on Appliances Tested
May 2023
Publication
The goals of the long-term tests were to see the impact of blends of hydrogen and natural gas on the technical condition of the appliances and their performance after several hours of operation. To do so they were run through an accelerated test program amounting to more than 3000 testing hours for the boilers and more than 2500 testing hours for the cookers. The percentage of hydrogen in the test gas was 30% by volume. Three boilers and two cookers were tested by DGC and two boilers by GWI. This report describes the test protocol the results and analysis on the seven appliances tested.
Hydrogen Deep Ocean Link: A Global Sustainable Interconnected Energy Grid
Mar 2022
Publication
The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. This paper analyses an innovative proposal for the creation of hydrogen ocean links. It intends to fill existing gaps in the creation of a hydrogen economy with the increase in flexibility and viability for hydrogen production consumption compression storage and transportation. The main concept behind the proposals presented in this paper consists of using the fact that the pressure in the deep sea is very high which allows a thin and cheap HDPE tank to store and transport large amounts of pressurized hydrogen in the deep sea. This is performed by replacing seawater with pressurized hydrogen and maintaining the pressure in the pipes similar to the outside pressure. Hydrogen Deep Ocean Link has the potential of increasing the interconnectivity of different regional energy grids into a global sustainable interconnected energy system.
Hydrogen Deep Ocean Link: A Global Sustainable Interconnected Energy Grid<br/><br/><br/>
Mar 2022
Publication
The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. This paper analyses an innovative proposal for the creation of hydrogen ocean links. It intends to fill existing gaps in the creation of a hydrogen economy with the increase in flexibility and viability for hydrogen production consumption compression storage and transportation. The main concept behind the proposals presented in this paper consists of using the fact that the pressure in the deep sea is very high which allows a thin and cheap HDPE tank to store and transport large amounts of pressurized hydrogen in the deep sea. This is performed by replacing seawater with pressurized hydrogen and maintaining the pressure in the pipes similar to the outside pressure. Hydrogen Deep Ocean Link has the potential of increasing the interconnectivity of different regional energy grids into a global sustainable interconnected energy system.
THyGA - Intermediate Report on the Test of Technologies by Segment – Impact of the Different H2 Concentrations on Safety, Efficiency, Emissions and Correct Operation
Jan 2022
Publication
This report is the very first version of the document that will present the THyGA short-term test. These tests are carried out to observe how appliances react in the short term (few minutes to few hours) on different H2NG mixtures and long-term test are observing behaviour over several weeks. The analysis is based on the test of about 20 appliances only and is not yet covering extensively all the segments of the project. However most of the aspects of the testing are included in the present version that shall be considered as a draft working document to prepare the final report. We have tried to incorporate all aspects that are important to us but there may be more aspects and more analyses that could be added and will be added in the light of the comments and corrections we will gather after the dissemination of the document.
Optimal Operation of the Hydrogen-based Energy Management System with P2X Demand Response and Ammonia Plant
Jul 2021
Publication
Hydrogen production is the key in utilizing an excess renewable energy. Many studies and projects looked at the energy management systems (EMSs) that allow to couple hydrogen production with renewable generation. In the majority of these studies however hydrogen demand is either produced for powering fuel cells or sold to the external hydrogen market. Hydrogen demand from actual industrial plants is rarely considered. In this paper we propose an EMS based on the industrial cluster of GreenLab Skive (GLS) that can minimize the system’s operational cost or maximize its green hydrogen production. EMS utilizes a conventional and P2X demand response (DR) flexibility from electrolysis plant hydrogen storage tank electric battery and hydrogen-consuming plants to design the optimal schedule with maximized benefits. A potential addition to the existing components at GLS - an ammonia plant is modelled to identify its P2X potential and assess the economic viability of its construction. The results show a potential reduction of 51.5–61.6% for the total operational cost of the system and an increase of the share of green hydrogen by 10.4–37.6% due to EMS operation.
Regional Uptake of Direct Reduction Iron Production Using Hydrogen Under Climate Policy
Nov 2022
Publication
The need to reduce CO2 emissions to zero by 2050 has meant an increasing focus on high emitting industrial sectors such as steel. However significant uncertainties remain as to the rate of technology diffusion across steel production pathways in different regions and how this might impact on climate ambition. Informed by empirical analysis of historical transitions this paper presents modelling on the regional deployment of Direction Reduction Iron using hydrogen (DRI-H2). We find that DRI-H2 can play a leading role in the decarbonisation of the sector leading to near-zero emissions by 2070. Regional spillovers from early to late adopting regions can speed up the rate of deployment of DRI-H2 leading to lower cumulative emissions and system costs. Without such effects cumulative emissions are 13% higher than if spillovers are assumed and approximately 15% and 20% higher in China and India respectively. Given the estimates of DRI-H2 cost-effectiveness relative to other primary production technologies we also find that costs increase in the absence of regional spillovers. However other factors can also have impacts on deployment emission reductions and costs including the composition of the early adopter group material efficiency improvements and scrap recycling rates. For the sector to achieve decarbonisation key regions will need to continue to invest in low carbon steel projects recognising their broader global benefit and look to develop and strengthen policy coordination on technologies such as DRI-H2.
Assessing Fluctuating Wind to Hydrogen Production via Long-term Testing of Solid Oxide Electrolysis Stacks
Mar 2024
Publication
The Danish government plans two energy islands to collect offshore wind power for power distribution and green fuel production. Wind power is often criticized for lacking stability which challenges downstream fuel synthesis processes. Solid oxide electrolysis cells (SOEC) are promising for green hydrogen production on a commercial scale but the impact of fluctuating power on SOEC remains uncertain. This paper explores the feasibility of a Wind-SOEC coupled system by conducting a 2104-h durability test with the state-of-the-art Topsoe TSP-1 stack. Three periods of steady operation and two periods of dynamic operation were conducted. Wind power fluctuation was simulated during the dynamic period and two control strategies were used to handle it. The constant flow (CF) and constant conversion (CC) strategies maintain the feedstock flow rate and conversion ratio of steamto‑hydrogen respectively. Compared to steady operation the stack shows no signs of additional degradation in dynamic operation. Thus the TSP-1 stack has been proven robust and flexible enough to handle fluctuating wind power supplies under both operation strategies. Further stack performance during dynamic periods was compared and analyzed by removing degradation effects. Accordingly SOEC stacks with CC control will consume less external heat than CF to maintain a heat balance. Nevertheless SOEC systems with CF and CC control strategies may have different efficiency or hydrogen production costs. Tech-economic analyses will be needed to investigate control strategies at the system level.
Power-to-X in Energy Hubs: A Danish Case Study of Renewable Fuel Production
Feb 2023
Publication
The European Commission recently proposed requirements for the production of renewable fuels as these are required to decarbonize the hard-to-electrify parts of the industrial and heavy transport sectors. Power-to-X (P2X) energy hubs enable efficient synergies between energy infrastructures production facilities and storage options. In this study we explore the optimal operation of an energy hub by leveraging the flexibility of P2X including hydrogen methanol and ammonia synthesizers by analyzing potential revenue streams such as the day-ahead and ancillary services markets. We propose EnerHub2X a mixed-integer linear program that maximizes the hub’s profit based on current market prices considering the technical constraints of P2X such as unit commitment and non-linear efficiencies. We investigate a representative Danish energy hub and find that without price incentives it mainly sells renewable electricity and produces compressed hydrogen. A sufficient amount of renewable ammonia and methanol is only produced by adding a price premium of about 50% (0.16 e/kg) to the conventional fuel prices. To utilize production efficiently on-site renewable energy sources and P2X must be carefully aligned. We show that renewable power purchase agreements can provide flexibility while complying with the rules set by the European Commission.
Day-ahead Economic Optimization Scheduling Model for Electricity–hydrogen Collaboration Market
Aug 2022
Publication
This paper presents a day-ahead economic optimization scheduling model for Regional Electricity–Hydrogen Integrated Energy System (REHIES) with high penetration of renewable energies. The electricity–hydrogen coupling devices are modelled with energy storage units and Insensitive Electrical Load (ISEL). The proposed objective function is able to capture the maximum benefits for REHIES in terms of economic benefits and can be summarized as a Quadratic Programming (QP) problem. The simulation verification is performed by MATLAB/CPLEX solver. The simulation results show that the proposed optimization model adapts the market requirement by contributing flexible collaboration between electricity and hydrogen. Also the translational properties of ISEL can implement higher economic profits and more effective utilization of renewable energy.
Low-carbon and Cost-efficient Hydrogen Optimisation through a Grid-connected Electrolyser: The Case of GreenLab Skive
Nov 2022
Publication
Power-to-X technologies are a promising means to achieve Denmark’s carbon emission reduction targets. Water electrolysis can potentially generate carbon-neutral fuels if powered with renewable electricity. However the high variability of renewable sources threatens the Power-to-X plant’s cost-efficiency instead favouring high and constant operation rates. Therefore a diversified electricity supply is often an option to maximise the load factor of the Power-to-X systems. This paper analyses the impact of using different power sources on the cost of production and the carbon intensity of hydrogen produced by a Power-to-X system. GreenLab Skive the world’s first industrial facility with Power-to-X integrated into an industrial symbiosis network has been used as a case study. Results show that the wind/PV/grid-connected electrolyser for hydrogen and electricity production can reduce operational costs and emissions saving 30.6 × 107 kgCO2 and having a Net Present Value twice higher than a grid-connected electrolyser. In addition the carbon emission coefficient for this configuration is 3.5 × 10− 2 kgH2/kgCO2 against 7.0 gH2/gCO2 produced by Steam Methane Reforming. A sensitivity analysis detects the optimal capacity ratio between the renewables and the electrolyser. A plateau is reached for carbon emission performances suggesting a wind/grid-connected electrolyser setup with a wind farm three times the size of the electrolyser. Results demonstrate that hydrogen cost is not competitive yet with the electricity suggesting an investment cost reduction but can be competitive with the current hydrogen price if the wind capacity is less than three times the electrolyser capacity.
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