Egypt

The depletion of fossil fuel reserves has resulted from their application in the industrial and energy sectors. As a result substantial efforts have been dedicated to fostering the shift from fossil fuels to renewable energy sources via technological advancements in industrial processes. Microalgae can be used to produce biofuels such as biodiesel hydrogen and bioethanol. Microalgae are particularly suitable for hydrogen production due to their rapid growth rate ability to thrive in diverse habitats ability to resolve conflicts between fuel and food pro duction and capacity to capture and utilize atmospheric carbon dioxide. Therefore microalgae-based bio hydrogen production has attracted significant attention as a clean and sustainable fuel to achieve carbon neutrality and sustainability in nature. To this end the review paper emphasizes recent information related to microalgae-based biohydrogen production mechanisms of sustainable hydrogen production factors affecting biohydrogen production by microalgae bioreactor design and hydrogen production advanced strategies to improve efficiency of biohydrogen production by microalgae along with bottlenecks and perspectives to over come the challenges. This review aims to collate advances and new knowledge emerged in recent years for microalgae-based biohydrogen production and promote the adoption of biohydrogen as an alternative to con ventional hydrocarbon biofuels thereby expediting the carbon neutrality target that is most advantageous to the environment.

In this study the electrolysis of water by using ammonium chloride (NH4Cl) as an electrolyte was investigated for the production of hydrogen gas. The assembled electrochemical cell consists mainly of twenty-one stainless-steel electrodes and a direct current from a battery ammonium chloride solution. In the electrolysis process hydrogen and oxygen are developed at the same time and collected as a mixture to be used as a fuel. This study explores a technic regarding the matching of oxyhydrogen (HHO) electrolyzers with photovoltaic (PV) systems to make HHO gas. The primary objective of the present research is to enable the electrolyzer to operate independently of other energy origins functioning as a complete unit powered solely by PV. Moreover the impact of using PWM on cell operation was investigated. The experimental data was collected at various time intervals NH4Cl concentrations. Additionally the hydrogen unit consists of two cells with a shared positive pole fixed between them. Some undesirable anodic reaction affects the efficiency of hydrogen gas production because of the corrosion of anode to ferrous hydroxide (Fe(OH)2). Polyphosphate Inhibitor was used to minimize the corrosion reaction of anode and keep the efficiency of hydrogen gas flow. The optimal concentration of 3M for ammonium chloride was identified balancing a gas flow rate of 772 ml/min with minimal anode corrosion. Without PWM conversion efficiency ranges between 93% and 96%. Therefore PWM increased conversion efficiency by approximately 5% leading to a corresponding increase in hydrogen gas production.

This study tested a cogeneration (desalination/hydrogen production) system with natural and black sand as sensible heat storage considering the thermal efficiencies environmental impact water quality cost aspects and hydrogen generation rate. The black sand-modified distiller attained the highest water production of 4645 mL more than the conventional distiller by 1595 mL. It also offered better energy and exergy efficiencies of 45.26% and 3.72% respectively compared to 32.10% and 2.19% for the conventional one. Both modified distillers showed impressive improvements in water quality by significant reductions in total dissolved solids (TDS) from 29300 mg/L to 60–61 mg/L. Moreover the black sand-modified still reduced chemical oxygen demand (COD) to 135 mg/L. The production cost was minimized by using black sand to 0.0111$/L higher than one-fifth in the case of the lab-based distiller. Regarding hydrogen production the highest rate was obtained using distilled water from a labbased distiller of 0.742 gH₂/hr with an energy efficiency of 11.00%; however it was not much higher than the case of black sand-modified still (0.736 gH₂/hr production rate and 10.91% efficiency). Moreover the black sand-modified still showed the highest annual exergy output of 70.4 kWh/year with a significant annual decarbonization of 1.69 ton-CO2.

Hydrogen energy storage systems (HESS) are increasingly recognised for their role in sustainable energy ap plications though their performance depends on efficient power electronic converter (PEC) interfaces. In this paper a multiport-isolated DC-DC converter characterised by enhanced power density reduced component count and minimal conversion stages is implemented for HESS applications. However the high-frequency multiwinding transformer in this converter introduces cross-coupling effects complicating control and result ing in large power deviations from nominal values due to step changes on other ports which adversely impact system performance. To address this issue a novel model reference-based decoupling control technique is pro posed to minimise the error between the actual plant output and an ideal decoupling reference model which represents the cross-coupling term. This model reference-based decoupling control is further extended into a hybrid decoupling control technique by integrating a decoupling matrix achieving more robust decoupling across a wider operating region. The hybrid decoupling technique mathematically ensures an improved control performance with the cross-coupling term minimised through a proportional-derivative controller. The proposed hybrid decoupling controller achieves a maximum power deviation.

The primary motivation of the present study is to mitigate the severe impact of ongoing energy resource shortages while offering clean and sustainable energy carriers such as hydrogen and ammonia. The present system mainly encompasses water splitting and the Haber-Bosch (HB) processes for green hydrogen and ammonia synthesis using solar and wind power respectively. Pointwise quantification analyses are conducted to quantify the power hydrogen and ammonia as well as the economic parameters specifically the levelized cost of energy (LCOE) levelized cost of hydrogen (LCOH) and levelized cost of ammonia (LCOA). This analysis is based on meteorological data from three sites in Egypt considering the specific water and nitrogen requirements for hydrogen and ammonia synthesis respectively. Furthermore carbon dioxide mitigation from solar and wind systems is estimated. These respective sites are Jarjoub on the coastlines of the Mediterranean Sea and Ain Sokhna and Jabal Al-Zait on the coastlines of the Red Sea. The results indicate that the lowest values of LCOE LCOH and LCOA are 12.58 $/MWh 1.91 $/kg H2 and 396.1 $/Ton NH3 respectively which were attained using solar resources at Ain Sokhna geographical site at the Red Sea. Besides Jarjoub which is located in the Mediterranean Sea could attain LCOH of 2.15 $/kg which is still a promising option due to its export potential to Europe. However the use of wind resources is incompetent for solar counterparts in the respective sites; their potential application in Egypt is still promising. The results demonstrate that Jabal Al-Zait stands as a favorable location for green power hydrogen and ammonia synthesis using wind resources which has LCOE LCOH and LCOA of 23.67 $/MWh 2.75 $/kg H2 and 547.8 $/Ton NH3 respectively.

This paper presents a novel energy management strategy (EMS) to control a wind-hydrogen microgrid which includes a wind turbine paired with a hydrogen-based energy storage system (HESS) i.e. hydrogen production storage and re-electrification facilities and a local load. This complies with the mini-grid use case as per the IEA-HIA Task 24 Final Report where three different use cases and configurations of wind farms paired with HESS are proposed in order to promote the integration of wind energy into the grid. Hydrogen production surpluses by wind generation are stored and used to provide a demand-side management solution for energy supply to the local and contractual loads both in the grid-islanded and connected modes with corresponding different control objectives. The EMS is based on a hierarchical model predictive control (MPC) in which long-term and short-term operations are addressed. The long-term operations are managed by a high-level MPC in which power production by wind generation and load demand forecasts are considered in combination with day-ahead market participation. Accordingly the hydrogen production and re-electrification are scheduled so as to jointly track the load demand maximize the revenue through electricity market participation and minimize the HESS operating costs. Instead the management of the short-term operations is entrusted to a low-level MPC which compensates for any deviations of the actual conditions from the forecasts and refines the power production so as to address the real-time market participation and the short time-scale equipment dynamics and constraints. Both levels also take into account operation requirements and devices’ operating ranges through appropriate constraints. The mathematical modeling relies on the mixed-logic dynamic (MLD) framework so that the various logic states and corresponding continuous dynamics of the HESS are considered. This results in a mixed-integer linear program which is solved numerically. The effectiveness of the controller is analyzed by simulations which are carried out using wind forecasts and spot prices of a wind farm in center-south of Italy.

The global need for energy has risen sharply recently. A global shift to clean energy is urgently needed to avoid catastrophic climate impacts. Hydrogen (H2) has emerged as a potential alternative energy source with near-net-zero emissions. In the African continent for sustainable access to clean energy and the transition away from fossil fuels this paper presents a new approach through which waste energy can produce green hydrogen from biomass. Bio-based hydrogen employing organic waste and biomass is recommended using biological (anaerobic digestion and fermentation) processes for scalable cheaper and low-carbon hydrogen. By reviewing all methods for producing green hydrogen dark fermentation can be applied in developed and developing countries without putting pressure on natural resources such as freshwater and rare metals the primary feedstocks used in producing green hydrogen by electrolysis. It can be expanded to produce medium- and long-term green hydrogen without relying heavily on energy sources or building expensive infrastructure. Implementing the dark fermentation process can support poor communities in producing green hydrogen as an energy source regardless of political and tribal conflicts unlike other methods that require political stability. In addition this approach does not require the approval of new legislation. Such processes can ensure the minimization of waste and greenhouse gases. To achieve cost reduction in hydrogen production by 2030 governments should develop a strategy to expand the use of dark fermentation reactors and utilize hot water from various industrial processes (waste energy recovery from hot wastewater).

Ammonia a molecule that is gaining more interest as a fueling vector has been considered as a candidate to power transport produce energy and support heating applications for decades. However the particular characteristics of the molecule always made it a chemical with low if any benefit once compared to conventional fossil fuels. Still the current need to decarbonize our economy makes the search of new methods crucial to use chemicals such as ammonia that can be produced and employed without incurring in the emission of carbon oxides. Therefore current efforts in this field are leading scientists industries and governments to seriously invest efforts in the development of holistic solutions capable of making ammonia a viable fuel for the transition toward a clean future. On that basis this review has approached the subject gathering inputs from scientists actively working on the topic. The review starts from the importance of ammonia as an energy vector moving through all of the steps in the production distribution utilization safety legal considerations and economic aspects of the use of such a molecule to support the future energy mix. Fundamentals of combustion and practical cases for the recovery of energy of ammonia are also addressed thus providing a complete view of what potentially could become a vector of crucial importance to the mitigation of carbon emissions. Different from other works this review seeks to provide a holistic perspective of ammonia as a chemical that presents benefits and constraints for storing energy from sustainable sources. State-of-the-art knowledge provided by academics actively engaged with the topic at various fronts also enables a clear vision of the progress in each of the branches of ammonia as an energy carrier. Further the fundamental boundaries of the use of the molecule are expanded to real technical issues for all potential technologies capable of using it for energy purposes legal barriers that will be faced to achieve its deployment safety and environmental considerations that impose a critical aspect for acceptance and wellbeing and economic implications for the use of ammonia across all aspects approached for the production and implementation of this chemical as a fueling source. Herein this work sets the principles research practicalities and future views of a transition toward a future where ammonia will be a major energy player.

Developing a green energy strategy for municipalities requires creating a framework to support the local production storage and use of renewable energy and green hydrogen. This framework should cover essential components for small-scale applications including energy sources infrastructure potential uses policy backing and collaborative partnerships. It is deployed as a small-scale renewable and green hydrogen unit in a municipality or building demands meticulous planning and considering multiple elements. Municipality can promote renewable energy and green hydrogen by adopting policies such as providing financial incentives like property tax reductions grants and subsidies for solar wind and hydrogen initiatives. They can also streamline approval processes for renewable energy installations invest in hydrogen refueling stations and community energy projects and collaborate with provinces and neighboring municipalities to develop hydrogen corridors and large-scale renewable projects. Renewable energy and clean hydrogen have significant potential to enhance sustainability in the transportation building and mining sectors by replacing fossil fuels. In Canada where heating accounts for 80% of building energy use blending hydrogen with LPG can reduce emissions. This study proposes a comprehensive approach integrating renewable energy and green hydrogen to support small-scale applications. The study examines many scenarios in a building as a case study focusing on economic and greenhouse gas (GHG) emission impacts. The optimum scenario uses a hybrid renewable energy system to meet two distinct electrical needs with 53% designated for lighting and 10% for equipment with annual saving CAD$ 87026.33. The second scenario explores utilizing a hydrogen-LPG blend as fuel for thermal loads covering 40% and 60% of the total demand respectively. This approach reduces greenhouse gas emissions from 540 to 324 tCO2/year resulting in an annual savings of CAD$ 251406. This innovative approach demonstrates the transformative potential of renewable energy and green hydrogen in enhancing energy efficiency and sustainability across sectors including transportation buildings and mining.

This paper investigates innovative solutions to enhance the performance and lifespan of standalone photovoltaic (PV)-based microgrids with a particular emphasis on off-grid communities. A major challenge in these systems is the limited lifespan of batteries. To overcome this issue researchers have created hybrid energy storage systems (HESS) along with advanced power management strategies. This study introduces innovative multi-level HESS approaches and a related energy management strategy designed to alleviate the charge/discharge stress on batteries. Comprehensive Matlab Simulink models of various HESS topologies within standalone PV microgrids are utilized to evaluate system performance under diverse weather conditions and load profiles for rural site. The findings reveal that the proposed HESS significantly extends battery life expectancy compared to existing solutions. Furthermore the paper presents a novel energy management strategy based on the Reduced Fractional Gradient Descent (RFGD) algorithm optimization tailored for hybrid systems that include photovoltaic fuel cell battery and supercapacitor components. This strategy aims to minimize hydrogen consumption of Fuel Cells (FCs) thereby supporting the production of green ammonia for local industrial use. The RFGD algorithm is selected for its minimal user-defined parameters and high convergence efficiency. The proposed method is compared with other algorithms such as the Lyrebird Optimization Algorithm (LOA) and Osprey Optimization Algorithm (OOA). The RFGD algorithm exhibits superior accuracy in optimizing energy management achieving a 15% reduction in hydrogen consumption. Its efficiency is evident from the reduced computational time compared to conventional algorithms. Although minor losses in computational resources were observed they were substantially lower than those associated with traditional optimization techniques. Overall the RFGD algorithm offers a robust and efficient solution for enhancing the performance of hybrid energy systems.