Ireland
A Physics Constrained Methodology for the Life Cycle Assessment of Sustainable Aviation Fuel Production
May 2024
Publication
Feedstock-to-fuel conversion or “Fuel Production” is a major contributor to greenhouse gas (GHG) emissions in life cycle assessment (LCA) of sustainable aviation fuels (SAF) from wastes. Here we construct and demonstrate an original mass and energy conserved chemically rigorous LCA methodology for the production of Hydroprocessed Esters and Fatty Acids-Synthetic Paraffinic Kerosene (HEFA-SPK) from Used Cooking Oil (UCO). This study proposes and demonstrates the use of; (i) the chemical composition of the UCO (ii) the ASTM properties of HEFA-SPK and (iii) the elemental mass and energy conserved reaction mechanism which converts one to the other as physical constraints for the specific LCA of any UCO derived HEFA-SPK. With application of these constraints the emissions embodied in UCO HEFA-SPK Fuel Production is found to range from 4.2 to 15.7 gCO2e/MJSAF depending on the renewability of the energy and hydrogen utilized. Imposition of (i)-(iii) as modelling constraints derives a HEFA-SPK yield of 49 mass% a priori. This finding aligns with experimental literature but brings attention to the higher yield estimations of 70–81% observed in current LCA tools. We show that this impacts the end LCA significantly as it adjusts allocation of emissions. A replication study of CORSIA’s (10.5 gCO2e/MJSAF) default core LCA value for Fuel Production quantifies the increase at +5.3 gCO2e/MJSAF or 15.8 gCO2e/MJSAF as total for Fuel Production. As the embodied emissions are significantly dependent on the specifics of the scenario assessed we highlight reporting a definitive GHG intensity for any UCO derived HEFA-SPK as generic will be inaccurate to an extent.
A Flexible Techno-economic Analysis Tool for Regional Hydrogen Hubs - A Case Study for Ireland
Apr 2023
Publication
The increasing urgency with which climate change must be addressed has led to an unprecedented level of interest in hydrogen as a clean energy carrier. Much of the analysis of hydrogen until this point has focused predominantly on hydrogen production. This paper aims to address this by developing a flexible techno-economic analysis (TEA) tool that can be used to evaluate the potential of future scenarios where hydrogen is produced stored and distributed within a region. The tool takes a full year of hourly data for renewables availability and dispatch down (the sum of curtailment and constraint) wholesale electricity market prices and hydrogen demand as well as other user-defined inputs and sizes electrolyser capacity in order to minimise cost. The model is applied to a number of case studies on the island of Ireland which includes Ireland and Northern Ireland. For the scenarios analysed the overall LCOH ranges from V2.75e3.95/kgH2. Higher costs for scenarios without access to geological storage indicate the importance of cost-effective storage to allow flexible hydrogen production to reduce electricity costs whilst consistently meeting a set demand.
Dual Fuel-based Multi-Energy System for Australian Renewable Energy Zones at Country Scale
Jul 2025
Publication
This paper aims to optimize dual-fuel facilitated off-/on-grid multi-energy systems (MESs) for different renewable energy zones (REZs) in Australia. The main objective is to develop a novel MES with the main feature of green hydrogen production and blended natural gas utilization for remote households. The proposed optimal system produces green hydrogen of 5343 kg/yr via proton exchange membrane (PEM) electrolyzer and blends it with natural gas. It involves 20 % hydrogen and 80 % natural gas in the overall volume of the blending process. This study contributes by performing optimal sizing of the components economic-energy-environmental and performance analyses to examine the most feasible solution for each REZ. The results indicate that the optimal system in North Queensland REZ has the lowest levelized cost of energy (LCE) of 1.28 A$/kWh and 0.1003 A $/kWh and the net present cost (NPC) of A$0.311 million and A$0.219 million for off-grid and on-grid configurations. The optimal on-grid system has 95.27 % less carbon emissions than the natural gas-fueled combustion energy system.
Thermodynamic Modelling and Optimisation of a Green Hydrogen-blended Syngas-fueled Integrated PV-SOFC System
Sep 2023
Publication
Developing an effective energy transition roadmap is crucial in the face of global commitments to achieve net zero emissions. While renewable power generation systems are expanding challenges such as curtailments and grid constraints can lead to energy loss. To address this surplus electricity can be converted into green hydrogen serving as a key component in the energy transition. This research explores the use of renewable solar energy for powering a proton exchange membrane electrolyser to produce green hydrogen while a downdraft gasifier fed by municipal solid waste generates hydrogen-enriched syngas. The blended fuel is then used to feed a Solid Oxide Fuel Cell (SOFC) system. The study investigates the impact of hydrogen content on the performance of the fuel cell-based power plant from thermodynamics and exergoeconomic perspectives. Multiobjective optimisation using a genetic algorithm identifies optimal operating conditions for the system. Results show that blending hydrogen with syngas increases combined heat and power efficiency by up to 3% but also raises remarkably the unit product cost and reduces carbon dioxide emissions. Therefore the optimal values for hydrogen content current density temperatures and other parameters are determined. These findings contribute to the design and operation of an efficient and sustainable energy generation system.
Techno-economic Optimization of Green HydrogenProduction from Curtailed Power in Ireland: Impact of Future Future Renewable Energy Installations, Weather Variability, and Grid Constraints
Jul 2025
Publication
To improve the economic viability of renewable (green) hydrogen production excess renewable energy which cannot be input to the electricity grid (curtailed power) can be utilized. While several models have attempted to optimize hydrogen production using curtailed power several factors must be considered in greater detail including the impacts of future renewable energy capacity weather variability and electricity grid constraints. This study aims to explore these aspects through an integrated model performing a techno-economic assessment and size optimization in order to achieve the minimum levelized cost of hydrogen (LCOH). Based on the Irish case optimizing the production of hydrogen from curtailed power results in a minimum LCOH of 1.20–9.39 €/kg. To maximize variable renewable energy penetration in the grid while allowing for low-cost hydrogen production from curtailed power it is suggested to focus on grid improvements while ensuring rapid commissioning of offshore wind installations leading to a LCOH of 1.26–2.44 €/kg.
Hydrogen from Offshore Wind: Investor Perspective on the Profitability of a Hybrid System Including for Curtailment
Mar 2020
Publication
Accommodating renewables on the electricity grid may hinder development opportunities for offshore wind farms (OWFs) as they begin to experience significant curtailment or constraint. However there is potential to combine investment in OWFs with Power-to-Gas (PtG) converting electricity to hydrogen via electrolysis for an alternative/complementary revenue. Using historic wind speed and simulated system marginal costs data this work models the electricity generated and potential revenues of a 504 MW OWF. Three configurations are analysed; (1) all electricity is sold to the grid (2) all electricity is converted to hydrogen and sold and (3) a hybrid system where power is converted to hydrogen when curtailment occurs and/or when the system marginal cost is low with the effect of curtailment analysed in each scenario. These represent the status quo a potential future configuration and an innovative business model respectively. The willingness of an investor to build PtG are determined by changes to the net present value (NPV) of a project. Results suggest that configuration (1) is most profitable and that curtailment mitigation alone is not sufficient to secure investment in PtG. By acting as an artificial floor in the electricity price a hybrid configuration (3) is promising and increases NPV for all hydrogen values greater than €4.2/kgH2. Hybrid system attractiveness increases with curtailment only if the hydrogen value is significantly above the levelised cost of €3.77/kgH2. In order for an investor to choose to pursue configuration (2) the offshore wind farm would have to anticipate 8.5% curtailment and be able to receive €4.5/kgH2 or 25% curtailment and receive €4/kgH2. The capital costs and discount rates are the most sensitive parameters and ambitious combinations of technology improvements could produce a levelised cost of €3/kgH2.
Tourist Preferences for Fuel Cell Vehicle Rental: Going Green with Hydrogen on the Island of Tenerife
Mar 2023
Publication
Using a discrete choice experiment (DCE) a survey of international tourists on the island of Tenerife is conducted to examine preferences for fuel cell vehicle (FCV) rental while on vacation. Survey respondents were generally supportive of FCVs and willing to hire one as part of their trip but for most individuals this is contingent on an adequate fuel station infrastructure. A latent class model was used to identify three distinct groups; one of which potentially represent early adopters e they have a high willingness-to-pay (WTP) for green hydrogen and are more likely to accept a low number of fuel stations but it could be challenging to convince them to use FCVs if they are not run on green hydrogen.
Is One Year Enough? The Impact of Availability of Wind Data on Optimal Wind-to-hydrogen System Design
Mar 2025
Publication
Decreasing prices of renewable energy sources (RES) like wind and solar in recent years have led to numerous studies on the optimal design of RES for hydrogen production in an off-grid system. RES are intermittent and vary from year to year. Yet most of the studies still consider only a random single weather year for system design often ignoring the impact of input weather data on system design and its performance. This study evaluates for a gaseous hydrogen system the impact of input weather data on optimal system design system reliability and system costs. Random single-year averaged and multiple years of weather data from 1994 to 2021 are considered. Further multiple years of weather data are considered using a novel method of near-optimal solutions and a maximum of near-optimal solutions. The results show that using the maximum of near-optimal solutions method improves system reliability by as much as 96 % when used in other weather years. The system costs are reduced to 0.1 €/kgH2 in other weather years at the expense of an oversized system design. Meanwhile a wind-to-hydrogen system (WHS) designed using randomly selected single-year weather data results in a significantly undersized system with lower reliability (3.5 %) and higher cost variability (up to 4.7 €/kgH2) in other weather years. On the other hand averaging the weather data smoothens the weather fluctuations and always results in a WHS design with lower reliability and higher cost variability than a WHS designed using multi-year weather data values. The results reveal that the size of input weather dataset significantly impacts the system design and its performance. The maximum of near-optimal solutions method proposed in this study provided significantly lower computational time with improved system performance (reliability and cost variability) in comparison to solving the WHS using multiple years of weather data outright.
Techno-economic Analysis of Green Hydrogen Storage in Salt Caverns: Evaluating Cycling Effects and Cavern Scaling on the Levelized Cost of Hydrogen Storage in Ireland's Power-to-X Landscape
Sep 2025
Publication
This paper examines the techno-economic feasibility of utilising salt caverns for large-scale hydrogen storage in Ireland leveraging wind energy and proton exchange membrane (PEM) electrolysers. The analysis focuses on optimising the integration of wind power with hydrogen production and storage addressing key challenges such as energy curtailment grid transmission constraints and renewable energy intermittency. Findings highlight significant economic considerations with a single hydrogen storage cavern requiring an initial investment of approximately €240 million where geological site preparation and compressor systems constitute the largest cost components. Annual operational expenses (OPEX) are estimated at €4.6 million largely due to compressor energy consumption and cooling requirements. The study emphasizes the critical impact of electrolyser scale on economic viability. Small-scale systems such as a 20 MW PEM electrolyser are economically unfeasible with a levelised cost of hydrogen (LCOH) of around €10/kg and filling times extending up to 2.5 years. However scaling up to a 200 MW PEM electrolyser dramatically improves cost efficiency lowering the LCOH to approximately €0.83/kg and reducing filling times to just 90 days. This research provides a comprehensive framework for hydrogen storage development offering key insights for policymakers and industry stakeholders to drive the renewable energy transition and enhance energy security through cost-effective and sustainable storage solutions.
Policy Supports for the Deployment of Solar Fuels: Islands as Test-beds for a Rapid Green Transition
May 2023
Publication
Coastal areas particularly islands are especially vulnerable to climate change due to their geographic and climate conditions. Reaching decarbonisation targets is a long process which will require radical changes and ‘out of the box’ thinking. In this context islands have become laboratories for the green transition by providing spaces for exploring possibilities and alternatives. Here we explore how hydrogen (H2) energy technologies can be a critical ally for island production of renewable electricity in part by providing a storage solution. However given the abundance of sunlight on many islands we also note the huge potential for a more profound engagement between renewables and hydrogen technologies via the co-generation of ‘green hydrogen’ using solar fuels technology. Solar hydrogen is a clean energy carrier produced by the direct or indirect use of solar irradiation for water-splitting processes such as photovoltaic systems coupled with electrolysers and photoelectrochemical cells. While this technology is fast emerging we question to what extent sufficient policy support exists for such initiatives and how they could be scaled up. We report on a case study of a pilot H2 plant in the Canary Islands and we offer recommendations on early-stage policy implications for hydrogen and other solar fuels in an island setting. The paper draws on the literature on islands as policy laboratories and the multi-level perspective on energy transitions. We argue that particular attention needs to be given to discrete issues such as research and planning and better synchronising between emerging local technology niches the various regulatory regimes for energy together with global trends.
Integration of Underground Green Hydrogen Storage in Hybrid Energy Generation
May 2024
Publication
One of the major challenges in harnessing energy from renewable sources like wind and solar is their intermittent nature. Energy production from these sources can vary based on weather conditions and time of day making it essential to store surplus energy for later use when there is a shortfall. Energy storage systems play a crucial role in addressing this intermittency issue and ensuring a stable and reliable energy supply. Green hydrogen sourced from renewables emerges as a promising solution to meet the rising demand for sustainable energy addressing the depletion of fossil fuels and environmental crises. In the present study underground hydrogen storage in various geological formations (aquifers depleted hydrocarbon reservoirs salt caverns) is examined emphasizing the need for a detailed geological analysis and addressing potential hazards. The paper discusses challenges associated with underground hydrogen storage including the requirement for extensive studies to understand hydrogen interactions with microorganisms. It underscores the importance of the issue with a focus on reviewing the the various past and present hydrogen storage projects and sites as well as reviewing the modeling studies in this field. The paper also emphasizes the importance of incorporating hybrid energy systems into hydrogen storage to overcome limitations associated with standalone hydrogen storage systems. It further explores the past and future integrations of underground storage of green hydrogen within this dynamic energy landscape.
A Techno-economic Analysis of Global Renewable Hydrogen Value Chains
Jul 2024
Publication
Many countries especially those with a high energy demand but insufficient renewable resources are currently investigating the role that imported low carbon hydrogen may play in meeting future energy requirements and emission reduction targets. A future hydrogen economy is uncertain and predicated on reduced price of hydrogen delivered to customers. Current hydrogen production steam reforming of natural gas or coal gasification is co-located to its end-use as a chemical feedstock. Large-scale multi-source value chains of hydrogen needed to support its use for energy are still at concept phase. This research investigates the combination of technical and economic factors which will determine the viability and competitiveness of two competing large scale renewable hydrogen value chains via ammonia and liquid hydrogen. Using a techno-economic model an evaluation of whether green hydrogen exports to Germany from countries with low-cost renewable electricity production but high-costs of storage distribution and transport will be economically competitive with domestic renewable hydrogen production is conducted. The model developed in Python calculates costs and energy losses for each step in the value chain. This includes production from an optimised combination of solar and/or wind generation capacity optimised storage requirements conversion to ammonia or liquid hydrogen distribution shipping and reconversion. The model can easily be applied to any scenario by changing the inputs and was used to compare export from Chile Namibia and Morocco with production in Germany using a 1 GW electrolyser and 2030 cost scenario in each case.
An Assessment of Decarbonisation Pathways for Intercontinental Deep-sea Shipping Using Power-to-X Fuels
Aug 2024
Publication
Shipping corridors act as the arteries of the global economy. The maritime shipping sector is also a major source of greenhouse gas emissions accounting for 2.9% of the global total. The international nature of the shipping sector combined with issues surrounding the use of battery technology means that these emissions are considered difficult to eliminate. This work explores the transition to renewable fuels by examining the use of electrofuels (in the form of liquid hydrogen methane methanol ammonia and Fischer-Tropsch fuel) to decarbonise large container ships from a technical economic and environmental perspective. For an equivalent range to current fossil fuel vessels the cargo capacity of vessels powered by electrofuels decreases by between 3% and 16% depending on the fuel of choice due to the lower energy density compared with conventional marine fuels. If vessel operators are willing to sacrifice range cargo space can be preserved by downsizing onboard energy storage which necessitates more frequent refuelling. For a realistic green hydrogen cost of €3.5/kg (10.5 €c/kWh) in 2030 the use of electrofuels in the shipping sector results in an increase in the total cost of ownership of between 124% and 731% with liquid hydrogen in an internal combustion engine being the most expensive and methanol in an internal combustion engine resulting in the lowest cost increase. Despite this we find that the increased transportation costs of some consumer goods to be relatively small adding for example less than €3.27 to the cost of a laptop. In general fuels which do not require cryogenic storage and can be used in internal combustion engines result in the lowest cost increases. For policymakers reducing the environmental impact of the shipping sector is a key priority. The use of liquid hydrogen which results in the largest cost increase offers a 70% reduction in GHG emissions for an electricity carbon intensity of 80 gCO2e/ kWh which is the greatest reduction of all fuels assessed in this work. A minimum carbon price of €400/tCO2 is required to allow these fuels to reach parity with conventional shipping operations. To meet European Union emissions reductions targets electricity with an emissions intensity below 40 gCO2e/kWh is required which suggests that for electrofuels to be truly sustainable direct connection with a source of renewable electricity is required.
Green Hydrogen Integration in Aluminium Recycling: Techno-economic Analysis Towards Sustainability Transition in the Expanding Aluminium Market
Feb 2024
Publication
The use of aluminum-based products is widespread and growing particularly in industries such as automotive food packaging and construction. Obtaining aluminum is expensive and energy-intensive making the recycling of existing products essential for economic and environmental viability. This work explores the potential of using green hydrogen as a replacement for natural gas in the smelting and refining furnaces in aluminum recycling facilities. The adoption of green hydrogen has the potential to curtail approximately 4.54 Ktons/year of CO2 emissions rendering it a sustainable and economically advantageous solution. The work evaluates the economic viability of a case study through assessing the Net Present Value (NPV) and the Internal Rate of Return (IRR). Furthermore it is employed single- and multi-parameter sensitivity analyses to obtain insight on the most relevant conditions to achieve economic viability. Results demonstrate that integrating on-site green hydrogen generation yields a favorable NPV of €57370 an IRR of 9.83% and a 19.63-year payback period. The primary factors influencing NPV are the initial electricity consumption stack and the H2 price.
Innovative Aircraft Propulsive Configurations: Technology Evaluation and Operations in the SIENA Project
Mar 2025
Publication
In this paper developed in the context of the Clean Sky 2 project SIENA (Scalability Investigation of hybrid-Electric concepts for Next-generation Aircraft) an extensive analysis is carried out to identify and accelerate the development of innovative propulsion technologies and architectures that can be scaled across five aircraft categories from small General Aviation airplanes to long-range airliners. The assessed propulsive architectures consider various components such as batteries and fuel cells to provide electricity as well as electric motors and jet engines to provide thrust combined to find feasible aircraft architectures that satisfy certification constraints and deliver the required performance. The results provide a comprehensive analysis of the impact of key technology performance indicators on aircraft performance. They also highlight technology switching points as well as the potential for scaling up technologies from smaller to larger aircraft based on different hypotheses and assumptions concerning the upcoming technological advancements of components crucial for the decarbonization of aviation. Given the considered scenarios the common denominator of the obtained results is hydrogen as the main energy source. The presented work shows that for the underlying models and technology assumptions hydrogen can be efficiently used by fuel cells for propulsive and system power for smaller aircraft (General Aviation commuter and regional) typically driven by propellers. For short- to long-range jet aircraft direct combustion of hydrogen combined with a fuel cell to power the on-board subsystems appears favorable. The results are obtained for two different temporal scenarios 2030 and 2050 and are assessed using Payload-Range Energy Efficiency as the key performance indicator. Naturally introducing such innovative architectures will face a lack of applicable regulation which could hamper a smooth entry into service. These regulatory gaps are assessed detailing the level of maturity in current regulations for the different technologies and aircraft categories.
Above-ground Hydrogen Storage: A State-of-the-art Review
Oct 2024
Publication
Hydrogen is increasingly recognized as a clean energy alternative offering effective storage solutions for widespread adoption. Advancements in storage electrolysis and fuel cell technologies position hydrogen as a pathway toward cleaner more efficient and resilient energy solutions across various sectors. However challenges like infrastructure development cost-effectiveness and system integration must be addressed. This review comprehensively examines above-ground hydrogen storage technologies and their applications. It highlights the importance of established hydrogen fuel cell infrastructure particularly in gaseous and LH2 systems. The review favors material-based storage for medium- and long-term needs addressing challenges like adverse thermodynamics and kinetics for metal hydrides. It explores hydrogen storage applications in mobile and stationary sectors including fuel-cell electric vehicles aviation maritime power generation systems off-grid stations power backups and combined renewable energy systems. The paper underscores hydrogen’s potential to revolutionize stationary applications and co-generation systems highlighting its significant role in future energy landscapes.
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