Italy

The aviation industry is facing challenges related to its environmental impact and thus the pressing need to develop aircraft technologies aligned with the society climate goals. Hydrogen is emerging as a potential clean fuel for aviation as it offers several advantages in terms of supply potential and weight specific energy. One of the key factors enabling the use of H2 in aviation is the development of reliable and safe storage technologies to be integrated into aircraft design. This work provides an overview of the technologies currently being investigated or developed for the storage of hydrogen within the aircraft which would enable the use of hydrogen as a sustainable fuel for aviation with emphasis on tanks material and structural aspects. The requirements dictated by the need of integrating the fuel system within existing or ex-novo aircraft architectures are discussed. Both the storage of gaseous and liquid hydrogen are considered and the main challenges related to the presence of either high internal pressures or cryogenic conditions are explored in the background of recent literature. The materials employed for the manufacturing of hydrogen tanks are overviewed. The need to improve the storage tanks efficiency is emphasized and issues such as thermal insulation and hydrogen embrittlement are covered as well as the reference to the main structural health monitoring strategies. Recent projects dealing with the development of onboard tanks for aviation are eventually listed and briefly reviewed. Finally considerations on the tank layout deemed more realistic and achievable in the near future are discussed.

The goal of achieving a zero-emission energy system by 2050 requires accurate energy planning to minimise the overall cost of the energy transition. Long-term energy models based on cost-optimal solutions are extremely dependent on the cost forecasts of different technologies. However such forecasts are inherently uncertain. The aim of the present work is to identify a cost-optimal pathway for the Italian energy system decarbonisation and assess how renewable cost scenarios can affect the optimal solution. The analysis has been carried out with the H2RES model a single-objective optimisation algorithm based on Linear Programming. Different cost scenarios for photovoltaics on-shore and off-shore wind power and lithium-ion batteries are simulated. Results indicate that a 100% renewable energy system in Italy is technically feasible. Power-to-X technologies are crucial for balancing purposes enabling a share of non-dispatchable generation higher than 90%. Renewable cost scenarios affect the energy mix however both on-shore and off-shore wind saturate the maximum capacity potential in almost all scenarios. Cost forecasts for lithium-ion batteries have a significant impact on their optimal capacity and the role of hydrogen. Indeed as battery costs rise fuel cells emerge as the main solution for balancing services. This study emphasises the importance of conducting cost sensitivity analyses in long-term energy planning. Such analyses can help to determine how changes in cost forecasts may affect the optimal strategies for decarbonising national energy systems.

Green hydrogen production and storage are vital in mitigating carbon emissions and sustainable transition. However the high investment cost and management requirements are the bottleneck of utilizing hybrid hydrogen-based systems in microgrids. Given the necessity of cost-effective and optimal design of these systems the present study examines techno-economic feasibility of integrating hybrid hydrogen-based systems into an outdoor test facility. With this perspective several solar-driven hybrid scenarios are introduced at two energy storage levels namely the battery and hydrogen energy storage systems including the high-pressure gaseous hydrogen and metal hydride storage tanks. Dynamic simulations are carried out to address subtle interactions in components of the hybrid system by establishing a TRNSYS model coupled to a Fortran code simulating the metal hydride storage system. The OpenStudio-EnergyPlus plugin is used to simulate the building load validate against experimental data according to the measured data and monitored operating conditions. Aimed at enabling efficient integration of energy storage systems a techno-enviro-economic optimization algorithm is developed to simultaneously minimize the levelized cost of the electricity and maximize the CO2 mitigation in each proposed hybrid scenario. The results indicate that integrating the gaseous hydrogen and metal hydride storages into the photovoltaic-alone scenario enhances 22.6% and 14.4% of the annual renewable factor. Accordingly the inclusion of battery system to these hybrid scenarios gives a 30.4% and 20.3 % boost to the renewable factor value respectively. Although the inclusion of battery energy storage into the hybrid systems increases the renewable factor the results imply that it reduces the hydrogen production rate via electrolysis. The optimized values of the levelized cost of electricity and CO2 emission for different scenarios vary in the range of 0.376–0.789 $/kWh and 6.57–9.75 ton respectively. The multi-criteria optimizations improve the levelized cost of electricity and CO2 emission by up to 46.2% and 11.3% with respect to their preliminary design.

Hydrogen refueling stations (HRSs) are key infrastructures rapidly spreading out to support the deployment of fuel cell electric vehicles for several mobility purposes. The research interest in these energy systems is increasing focusing on different research branches: research on innovation on equipment and technology proposal and development of station layout and research aiming to provide experimental data sets for perfor mance investigation. The present manuscript aims to present an overview of the most recent literature on hydrogen stations by presenting the technological status of the system at the global level and their research enhancement on the involved components and processes. After the review of the mentioned aspects this paper will present the already existing layouts and the potential configurations of such infrastructures considering several options of the delivery routes the end-user destination and hydrogen storage thermodynamic status whether liquid or gaseous.

The European Commission through the REPowerEU plan and the “Fit for 55” package aims to reduce fossil fuel dependence and greenhouse gas emissions by promoting electric and fuel cell hybrid electric vehicles (EV-FCHEVs). The transition to this mobility model requires energy systems that are able to provide both electricity and hydrogen while reducing the reliance of residential buildings on the national grid. This study analyses a poly-generative (PG) system composed of a Solid Oxide Fuel Cell (SOFC) fed by biomethane a Photovoltaic (PV) system and a Proton Exchange Membrane Electrolyser (PEME) with electric vehicles used as dynamic storage units. The assessment is based on simulation tools developed for the main components and applied to four representative seasonal days in Rende (Italy) considering different daily travel ranges of a 30-vehicle fleet. Results show that the PG system provides about 27 kW of electricity 14.6 kW of heat and 3.11 kg of hydrogen in winter spring and autumn and about 26 kW 14 kW and 3.11 kg in summer; it fully covers the building’s electrical demand in summer and hot water demand in all seasons. The integration of EV batteries reduces grid dependence improves renewable self-consumption and allows for the continuous and efficient operation of both the SOFC and PEME demonstrating the potential of the proposed system to support the green transition.

Underground hydrogen storage (UHS) in depleted oil and gas fields is pivotal for balancing large-scale renewable-energy systems yet the wettability of reservoir rocks in contact with hydrogen after decades of Enhanced Oil Recovery (EOR) operations remains poorly quantified. This work experimentally investigates how two common EOR legacies cationic surfactant (city-trimethyl-ammonium bromide CTAB) and supercritical carbon dioxide (SC–CO2) flooding alter rock–water–Hydrogen (H2) wettability in carbonate formations. Contact angles were measured on dolomite and limestone rock slabs at 30–75 ◦C and 3.4–17.2 MPa using a high-pressure captive-bubble cell. Crude-oil aging shifted clean dolomite from strongly water-wet (θ ~ 28–29◦) to intermediate-wet (θ ≈ 84◦). Subsequent immersion in dilute CTAB solutions (0.5–2 wt %) fully reversed this effect restoring or surpassing the original water-wetness (θ ≈ 21–28◦). Limestone samples exposed to SC-CO2 at 60–80 ◦C became more hydrophilic (θ ≈ 18–30◦) relative to untreated controls; moderate carbonate dissolution (≤6 × 103 ppm Ca2+) produced the most significant improvement in water-wetness whereas severe dissolution yielded diminishing returns. These findings show that many mature reservoirs are already water-wet (post-CO2) or can be easily re-wetted (via residual CTAB). Across all scenarios sample wettability showed little sensitivity to pressure but higher temperature consistently promoted stronger water-wetness. Future work should include dynamic core-flooding experiments with realistic reservoir.

In this paper developed in the context of the Clean Sky 2 project SIENA (Scalability Investigation of hybrid-Electric concepts for Next-generation Aircraft) an extensive analysis is carried out to identify and accelerate the development of innovative propulsion technologies and architectures that can be scaled across five aircraft categories from small General Aviation airplanes to long-range airliners. The assessed propulsive architectures consider various components such as batteries and fuel cells to provide electricity as well as electric motors and jet engines to provide thrust combined to find feasible aircraft architectures that satisfy certification constraints and deliver the required performance. The results provide a comprehensive analysis of the impact of key technology performance indicators on aircraft performance. They also highlight technology switching points as well as the potential for scaling up technologies from smaller to larger aircraft based on different hypotheses and assumptions concerning the upcoming technological advancements of components crucial for the decarbonization of aviation. Given the considered scenarios the common denominator of the obtained results is hydrogen as the main energy source. The presented work shows that for the underlying models and technology assumptions hydrogen can be efficiently used by fuel cells for propulsive and system power for smaller aircraft (General Aviation commuter and regional) typically driven by propellers. For short- to long-range jet aircraft direct combustion of hydrogen combined with a fuel cell to power the on-board subsystems appears favorable. The results are obtained for two different temporal scenarios 2030 and 2050 and are assessed using Payload-Range Energy Efficiency as the key performance indicator. Naturally introducing such innovative architectures will face a lack of applicable regulation which could hamper a smooth entry into service. These regulatory gaps are assessed detailing the level of maturity in current regulations for the different technologies and aircraft categories.

Hydrogen is considered a key alternative to fossil fuels in the broader context of ecological transition. Repurposing natural gas pipelines for hydrogen transport is one of the challenges of this approach. However hydrogen can diffuse into metallic lattices leading to hydrogen embrittlement (HE). For this reason typically ductile materials can experience unexpected brittle fractures and it is therefore necessary to assess the HE propensity of the current pipeline network to ensure its fitness for hydrogen transport. This study examines the relationship between the microstructure of the circumferential weld joint in X52 pipeline steel and hydrogen concentration introduced electrolytically. Base material heat affected zone and fused zone were subjected to 1800 3600 7200 and 14400 s of continuous charging with a current density J = − 10 mA/cm2 in an acid solution. Results showed that the fusion zone absorbed the most hydrogen across all charging times while the base material absorbed more hydrogen than the heat-affected zone due to the presence of non-metallic inclusions. Fracture toughness was assessed using single edge notch tension specimens (SENT) in air and electrolytic hydrogen. Results indicate that the base material is particularly vulnerable to hydrogen environments exhibiting the greatest reduction in toughness when exposed to hydrogen compared to air.

Hydrogen-based technologies prominently fuel cells are emerging as strategic solutions for decarbonization. They offer an efficient and clean alternative to fossil fuels for electricity generation making a tangible contribution to the European Green Deal climate objectives. The primary issue is the production and transportation of hydrogen. An on-site hydrogen production system that includes CO2 capture could be a viable solution. The proposed power system integrates an internal combustion engine (ICE) with a steam methane reformer (SMR) equipped with a CO2 capture and energy storage system to produce “blue hydrogen”. The hydrogen fuels a high-temperature polymer electrolyte membrane (HTPEM) fuel cell. A battery pack incorporated into the system manages rapid fluctuations in electrical load ensuring stability and continuity of supply and enabling the fuel cell to operate at a fixed point under nominal conditions. This hybrid system utilizes natural gas as its primary source reducing climate-altering emissions and representing an efficient and sustainable solution. The simulation was conducted in two distinct environments: Thermoflex code for the integration of the engine reformer and CO2 capture system; and Matlab/Simulink for fuel cell and battery pack sizing and dynamic system behavior analysis in response to user-demanded load variations with particular attention to energy flow management within the simulated electrical grid. The main results show an overall efficiency of the power system of 39.9% with a 33.5% reduction in CO2 emissions compared to traditional systems based solely on internal combustion engines.

This study explores the design and feasibility of a novel fuel cell-powered wind farm for residential electricity hydrogen/oxygen production and cooling/heating via a compression chiller. Wind turbine energy powers Proton Exchange Membrane (PEM) electrolyzers and a compression chiller unit. The proposed system was modeled using EES thermodynamic software and its economic viability was assessed. A case study across seven Italian regions with varying wind potentials evaluated the system’s feasibility in diverse weather conditions. Multi-objective optimization using Response Surface Methodology (RSM) determined the number of wind turbines as optimum number of electrolyzers & fuel cell units. Optimization results indicated that 37 wind turbines 1 fuel cell unit and 2 electrolyzer units yielded an exergy efficiency of 27.98 % and a cost rate of 619.9 $/h. TOPSIS analysis suggested 32 wind turbines 2 electrolyzers and 2 reverse osmosis units as an alternative configuration. Further twelve different scenarios were examined to enhance the distribution of wind farmgenerated electricity among the grid electrolyzers and reverse osmosis systems. revealing that directing 25 % to reverse osmosis 20 % to electrolyzers and 55 % to grid sales was optimal. Performance analysis across seven Italian cities (Turin Bologna Florence Palermo Genoa Milan and Rome) identified Genoa Palermo and Bologna as the most suitable locations due to favorable wind conditions. Implementing the system in Genoa the optimal site could produce 28435 MWh of electricity annually prevent 5801 tons of CO2 emissions (equivalent to 139218 $). Moreover selling this clean electricity to the grid could meet the annual clean electricity needs of approximately 5770 people in Italy

This study aimed to investigate the effectiveness of dark fermentation in biohydrogen production from agro-industrial wastes including apple pomace brewer’s grains molasses and potato powder subjected to different pretreatment methods. The experiments were conducted at a laboratory scale using 1000 cm3 anaerobic reactors at a temperature of 35 ◦C and anaerobic sludge as the inoculum. The highest yield of hydrogen was obtained from pre-treated apple pomace (101 cm3/g VS). Molasses a less complex substrate compared to the other raw materials produced 25% more hydrogen yield following pretreatment. Methanogens are sensitive to high temperatures and low-pH conditions. Nevertheless methane constituted 1–6% of the total biogas under these conditions. The key factor was appropriate treatment of the inoculum to limit competition from methanogens. Increasing the inoculum dose from 150 cm3/dm3 to 250 cm3/dm3 had no further effect on biogas production. The physicochemical parameters and VFA data confirmed the stability and usefulness of activated sludge as a source of microbial cultures for H2 production via dark fermentation.

From an environmental standpoint carbon-free energy carriers such as ammonia and hydrogen are essential for future energy systems. However their hightemperature chemical behavior remains insufficiently understood posing challenges for the development and optimization of advanced combustion technologies. Ammonia in particular is globally available and cost-effective especially for energy-intensive industries. The addition of ammonia or hydrogen to methane significantly reduces the accuracy of existing predictive models. Therefore validated and detailed data are urgently needed to enable reliable design and performance predictions. This review highlights the compatibility of ammonia with existing combustion infrastructure facilitating a smoother transition to more sustainable heating methods without the need for entirely new systems. Applications in high-temperature heating processes such as metal processing ceramics and glass production and power generation are of particular interest. This review focuses on the systematic assessment of alternative fuel mixtures comprising ammonia and hydrogen as well as natural gas with particular consideration of existing safety-related parameters and combustion characteristics. Fundamental quantities such as the laminar burning velocity are discussed in the context of their relevance for fuel mixtures and their scalability toward turbulent flame propagation which is of critical importance for industrial burner and reactor design. The influence of fuel composition on ignition limits is examined as these are essential parameters for safety margin definitions and operational boundary conditions. Furthermore flame stability in mixed-fuel systems is addressed to evaluate the practical feasibility and robustness of combustion under varying process conditions. A detailed overview of current diagnostic and analysis methods follows encompassing both pollutant measurement techniques and the detection of key radical species. These diagnostics form the experimental basis for reaction kinetics modeling and mechanism validation. Given the importance of emission formation in combustion systems a dedicated subsection summarizes major emission trends even though a comprehensive treatment would exceed the scope of this review. Thermal radiation effects which are highly relevant for heat transfer and system efficiency in large-scale applications are then reviewed. In parallel current developments in numerical simulation approaches for industrial-scale combustion systems are presented including aspects of model accuracy boundary conditions and computational efficiency. The review also incorporates insights from materials engineering particularly regarding high-temperature material performance corrosion resistance and compatibility with combustion products. Based on these interdisciplinary findings operational strategies for high-temperature furnaces are outlined and selected industrial reference systems are briefly presented. This integrated approach aims to support the design optimization and safe operation of next-generation combustion technologies utilizing carbon-free or low-carbon fuels.

Underground Hydrogen Storage (UHS) is a promising solution to maximize the use of hydrogen as an energy carrier. This study presents a standardized methodology for assessing UHS quality by introducing the Underground Hydrogen Storage Suitability Index (UHSSI) which integrates three sub-indices: the Caprock Potential Index (CPI) the Reservoir Quality Index (RQI) and the Site Potential Index (SPI). Parameters such as porosity permeability lithology caprock thickness depth temperature and salinity are evaluated and ranked from 0 (unsuitable) to 5 (excellent). The methodology was validated using data from six worldwide sites including salt caverns and aquifers. Sites like Moss Bluff Clemens Dome and Spindletop (USA) scored highly while Teesside (UK) Lobodice (Czech Republic) and Beynes (France) were classified as unsuitable due to shallow depths and microbial activity. A software tool the UHSSI Calculator was developed to automate site evaluations. This approach offers a cost-effective tool for preliminary screening and supports the safer development of UHS.

This paper explores cleaner and techno-economically viable solutions to provide electricity heat and cooling using green hydrogen (H2) and green ammonia (NH3) across the entire decarbonized value chain. We propose integrating a 100% hydrogen-fueled internal combustion engine (e.g. Jenbacher JMS 420) as a stationary backup solution and comparing its performance with other backup technologies. While electrochemical storage systems or battery energy storage systems (BESSs) offer fast and reliable short-term energy buffering they lack flexibility in relocation and typically involve higher costs for extended backup durations. Through five case studies we highlight that renewable-based energy supply requires additional capacity to bridge longer periods of undersupply. Our results indicate that for cost reasons battery–electric solutions alone are not economically feasible for longterm backup. Instead a more effective system combines both battery and hydrogen storage where batteries address daily fluctuations and hydrogen engines handle seasonal surpluses. Despite lower overall efficiency gas engines offer favorable investment and operating costs in backup applications with low annual operating hours. Furthermore the inherent fuel flexibility of combustion engines eventually will allow green ammonia-based backup systems particularly as advancements in small-scale thermal cracking become commercially available. Future studies will address CO2 credit recognition carbon taxes and regulatory constraints in developing more effective dispatch and master-planning solutions.

The ongoing digitalization of energy infrastructure is a crucial enabler for improving efficiency reliability and sustainability in gas distribution networks especially in the context of decarbonization and the integration of alternative energy carriers (e.g. renewable gases including biogas green hydrogen). This study presents the development and application of a Digital Twin framework for a real-world gas distribution network developed using open-source tools. The proposed methodology covers the entire digital lifecycle: from data acquisition through smart meters and GIS mapping to 3D modelling and simulation using tools such as QGIS FreeCAD and GasNetSim. Consumption data are collected processed and harmonized via Python-based workflows hourly simulations of network operation including pressure flow rate and gas quality indicators like the Wobbe Index. Results demonstrate the effectiveness of the Digital Twin in accurately replicating real network behavior and supporting scenario analyses for the introduction of greener energy vectors such as hydrogen or biomethane. The case study highlights the flexibility and transparency of the workflow as well as the critical importance of data quality and availability. The framework provides a robust basis for advanced network management optimization and planning offering practical tools to support the energy transition in the gas sector.

This study assesses the feasibility and profitability of marine hybrid clusters combining wave energy converters (WECs) and offshore wind turbines (OWTs) to power households and marine aquaculture. Researchers analyzed two coastal sites: La Serena Chile with high and consistent wave energy resources and Ensenada Mexico with moderate and more variable wave power. Two WEC technologies Wave Dragon (WD) and Pelamis (PEL) were evaluated alongside lithium-ion battery storage and green hydrogen production for surplus energy storage. Results show that La Serena’s high wave power (26.05 kW/m) requires less hybridization than Ensenada’s (13.88 kW/m). The WD device in La Serena achieved the highest energy production while PEL arrays in Ensenada were more effective. The PEL-OWT cluster proved the most cost-effective in Ensenada whereas the WD-OWT performed better in La Serena. Supplying electricity for seaweed aquaculture particularly in La Serena proves more profitable than for households. Ensenada’s clusters generate more surplus electricity suitable for the electricity market or hydrogen conversion. This study emphasizes the importance of tailoring emerging WEC systems to local conditions optimizing hybridization strategies and integrating consolidated industries such as aquaculture to enhance both economic and environmental benefits.

Hydrogen is increasingly recognized as a key energy vector for achieving deep decarbonization across urban and industrial sectors. Supporting global efforts to reduce greenhouse gas (GHG) emissions and achieve the Sustainable Development Goals (SDGs) it is essential to understand the multi-sectoral role of the hydrogen value chain spanning production storage and end-use applications with particular emphasis on smart city systems and industrial processes. Green hydrogen production technologies including alkaline water electrolysis (AWE) proton exchange membrane (PEM) electrolysis anion exchange membrane (AEM) electrolysis and solid oxide electrolysis cells (SOECs) are evaluated in terms of efficiency scalability and integration potential. Storage pathways are examined across physical storage (compressed gas cryo-compressed and liquid hydrogen) material-based storage (solid-state absorption in metal hydrides and chemical carriers such as LOHCs and ammonia) and geological storage (salt caverns depleted gas reservoirs and deep saline aquifers) highlighting their suitability for urban and industrial contexts. In the smart city domain hydrogen is analyzed as an enabler of zero-emission transportation low-carbon residential and commercial heating and renewable-integrated smart grids with long-duration storage capabilities. System-level studies demonstrate that coordinated integration of these applications can deliver higher overall energy efficiency deeper reductions in life-cycle GHG emissions and improved resilience of urban energy systems compared with sector-specific approaches. Policy frameworks safety standards and digitalization strategies are reviewed to illustrate how hydrogen infrastructure can be embedded into interconnected urban energy systems. Furthermore industrial applications focus on hydrogen’s potential to decarbonize energy-intensive processes and enable sector coupling between electricity heat and manufacturing. The environmental implications of hydrogen deployment are also considered including resource efficiency life-cycle emissions and ecosystem impacts. In contrast to reviews addressing isolated aspects of hydrogen technologies this study synthesizes technological infrastructural and policy dimensions integrating insights from over 400 studies to highlight the multifaceted role of hydrogen in sustainable urban development and industrial decarbonization and the added benefits achievable through coordinated cross-sector deployment strategies.

The urgent need to mitigate climate change and reduce greenhouse gas emissions has accelerated the search for sustainable and scalable energy carriers. Among the different alternatives ammonia stands out as a promising carbon-free fuel thanks to its high energy density efficient storage and compatibility with existing infrastructure. Moreover it can be produced through sustainable green processes. However its application in internal combustion engines is limited by several challenges including low reactivity narrow flammability limits and high ignition energy. These factors can compromise combustion efficiency and contribute to increased unburned ammonia emissions. To address these limitations hydrogen has emerged as a complementary fuel in dual-fuel configurations with ammonia. Hydrogen’s high reactivity enhances flame stability ignition characteristics and combustion efficiency while reducing emissions of unburned ammonia. This review examines the current status of dual-fuel ammonia and hydrogen combustion strategies in internal combustion engines and summarizes the experimental results. It highlights the potential of dual-fuel systems to optimize engine performance and minimize emissions. It identifies key challenges knowledge gaps and future research directions to support the development and widespread adoption of ammonia–hydrogen dual-fuel technologies.

In recent years governments have promoted the shift to low-emission transport systems with electric and hydrogen vehicles emerging as key alternatives for greener urban mobility. Evaluating zero- or near-zero tailpipe solutions requires a Lifecycle Assessment (LCA) approach accounting for emissions from energy production components and vehicle manufacturing. Such studies mainly address Greenhouse Gas (GHG) emissions while other pollutants are often overlooked. This study compares the Human Toxicity Potential (HTP) of Battery Electric Vehicles (BEVs) Fuel Cell Vehicles (FCVs) Hydrogen Internal Combustion Engine Vehicles (H2ICEVs) and hybrid H2ICEVs for public transport in the European Union. Current and future scenarios (2024 2030 2050) are examined considering evolving energy mixes and manufacturing impacts. Results underline that BEVs are characterized by the highest HTP in 2024 and that this trend is maintained even in future scenarios. As for hydrogen-based powertrains they show lower HTPs similar among them. This work underlines that current efforts must be intensified especially for BEVs to further limit harmful emissions from the mobility sector.

The decarbonization of remote energy systems presents both technical and economic challenges due to their dependance on fossil fuels and the variability of renewable energy sources. This study introduces a Two-Stage Stochastic Programming approach to optimize Hybrid Renewable Energy Systems under uncertainty in renewable energy production. The methodology is applied to the island of Pantelleria aiming to minimize Total Annualized Costs and CO2 emissions using an ε-constraint approach. Results show that within the set of optimized configurations stricter CO2 emissions constraints increase costs due to the need for oversized components to ensure supply reliability. Nevertheless even the zeroemissions scenario offers significant economic benefits compared to the current diesel-based system. Total Annualized Costs are reduced from 15.5 M€ to 8.10 M€ in the deterministic case and to 9.37 M€ in the stochastic one. The additional cost in the stochastic configuration is offset by improved reliability ensuring demand is met under all scenarios. A sensitivity analysis on electricity demand reveals the necessity of further larger components leading to a 27.0% cost increase in a fully renewable scenario with stochastic optimization for a 10% demand increase. These findings highlight the importance of stochastic optimization in designing cost-effective off-grid renewable energy systems.

In the pursuit of zero-emission mobility hydrogen represents a promising fuel for internal combustion engines. However its low volumetric energy density poses challenges especially for high-performance applications where compactness and lightweight design are crucial. This study investigates the feasibility of an innovative hydrogen-fueled two-stroke opposed-piston (2S-OP) engine targeting a specific power of 130 kW/L and an indicated thermal efficiency above 40%. A detailed 3D-CFD analysis is conducted to evaluate mixture formation combustion behavior abnormal combustion and water injection as a mitigation strategy. Innovative ring-shaped multi-point injection systems with several designs are tested demonstrating the impact of injector channels’ orientation on the final mixture distribution. The combustion analysis shows that a dual-spark configuration ensures faster combustion compared to a single-spark system with a 27.5% reduction in 10% to 90% combustion duration. Pre-ignition is identified as the main limiting factor strongly linked to mixture stratification and high temperatures. To suppress it water injection is proposed. A 55% evaporation efficiency of the water mass injected lowers the in-cylinder temperature and delays pre-ignition onset. Overall the study provides key design guidelines for future high-performance hydrogen-fueled 2S-OP engines.

The transition toward environmentally friendly steelmaking using hydrogen direct reduced iron as feed material in electric arc furnaces will eventually require process adjustments due to changes in the pellet properties when compared to e.g. blast furnace pellets. To this end the melting of hydrogen direct reduced iron pellets with 68 and 100% reduction degrees and Fe content of 67.24% was investigated in a laboratory-scale electric arc furnace. The presence of iron oxide-rich slag had a significant effect on the arc movement on the melt and an inhibiting effect on iron evaporation. The melting was monitored with video recording and optical emission spectroscopy. The videos were used to monitor the melting behavior whereas optical emissions revealed iron gangue elements and hydrogen from the pellets radiating in the plasma. Furthermore the flow of the melt is well seen in the videos as well as the movement of slag droplets on the melt surface. After the experiments the metal had silica-rich inclusions whereas slag had mostly penetrated into the crucible. The most notable differences in melting behavior can be attributed to the iron oxide-rich slag its interaction with the arc and penetration into the crucible and how it affects the arc movement and heat transfer.