Italy
Wetting of the Microporous Layer at the Cathode of an Anion Exchange Membrane Water Electrolyzer
Aug 2025
Publication
Water management is crucial for the performance of anion exchange membrane water electrolyzers (AEM-WEs) to maintain membrane hydration and enable phase separation between hydrogen gas and liquid water. Therefore careful material selection for the anode and cathode is essential to enhance reactant/product transport and optimize water management under ‘dry cathode’ conditions. This study investigates the wetting characteristics of two commercially available porous transport layers (PTLs) used in AEM-WE: carbon paper and carbon paper with a microporous layer (MPL). Wettability was measured under static quasi-static and dynamic conditions to assess the effect of water and electrolytes (NaOH KOH K2CO3) across concentrations (up to 1 M) and operational temperatures (20 °C to 92 °C). Carbon paper exhibits mild hydrophobicity (advancing contact angles of ∼120° however with receding contact angle ∼0°) whereas carbon paper with MPL demonstrates superhydrophobicity (advancing and receding contact angles >145° and low contact angle hysteresis) maintaining a stable Cassie-Baxter wetting state. Dynamic wetting experiments confirmed the robustness of the superhydrophobicity in carbon paper with MPL facilitating phase separation between hydrogen gas and liquid water. The presence of supporting electrolytes did not significantly affect wettability and the materials retained hydrophobic properties across different temperatures. These findings highlight the importance of MPLs in optimizing water transport and gas rejection within AEM-WEs ensuring efficient and stable operation under “dry cathode” conditions. These PTLs (with and without the addition of the MPL) were integrated into AEM-WE and polarization curves were run. Preliminary data in a specific condition suggested the presence of the MPL within the PTL enhance AEM-WE performance.
Techno-Economic Analysis of Marine Hybrid Clusters for Use in Chile and Mexico
Oct 2025
Publication
This study assesses the feasibility and profitability of marine hybrid clusters combining wave energy converters (WECs) and offshore wind turbines (OWTs) to power households and marine aquaculture. Researchers analyzed two coastal sites: La Serena Chile with high and consistent wave energy resources and Ensenada Mexico with moderate and more variable wave power. Two WEC technologies Wave Dragon (WD) and Pelamis (PEL) were evaluated alongside lithium-ion battery storage and green hydrogen production for surplus energy storage. Results show that La Serena’s high wave power (26.05 kW/m) requires less hybridization than Ensenada’s (13.88 kW/m). The WD device in La Serena achieved the highest energy production while PEL arrays in Ensenada were more effective. The PEL-OWT cluster proved the most cost-effective in Ensenada whereas the WD-OWT performed better in La Serena. Supplying electricity for seaweed aquaculture particularly in La Serena proves more profitable than for households. Ensenada’s clusters generate more surplus electricity suitable for the electricity market or hydrogen conversion. This study emphasizes the importance of tailoring emerging WEC systems to local conditions optimizing hybridization strategies and integrating consolidated industries such as aquaculture to enhance both economic and environmental benefits.
e-REFORMER for Sustainable Hydrogen Production: Enhancing Efficiency in the Steam Methane Reforming Process
Aug 2025
Publication
Electrifying heat supply in chemical processes offers a strategic pathway to reduce CO2 emissions associated with fossil fuel combustion. This study investigates the retrofit of an existing terrace-wall Steam Methane Reformer (SMR) in an ammonia plant by replacing fuel-fired burners with electric resistance heaters in the radiant section. The proposed e-REFORMER concept is applied to a real-world case producing hydrogen-rich syngas at 29000 Nm3 /h with simulation and energy analysis performed using Aspen HYSYS®. The results show that electric heating reduces total thermal input by 3.78 % lowers direct flue gas CO2 emissions by 91.56 % and improves furnace thermal efficiency from 85.6 % to 88.9 % (+3.3 %). The existing furnace design and convection heat recovery system are largely preserved maintaining process integration and plant operability. While the case study reflects a medium-scale plant the methodology applies to larger facilities and supports integration with decarbonised power grids and Carbon Capture Utilisation and Storage (CCUS) technologies. This work advances current literature by addressing full-system integration of electrification within hydrogen and ammonia production chains offering a viable pathway to improve energy efficiency and reduce industrial emissions.
Hydrogen Energy Systems for Decarbonizing Smart Cities and Industrial Applications: A Review
Oct 2025
Publication
Hydrogen is increasingly recognized as a key energy vector for achieving deep decarbonization across urban and industrial sectors. Supporting global efforts to reduce greenhouse gas (GHG) emissions and achieve the Sustainable Development Goals (SDGs) it is essential to understand the multi-sectoral role of the hydrogen value chain spanning production storage and end-use applications with particular emphasis on smart city systems and industrial processes. Green hydrogen production technologies including alkaline water electrolysis (AWE) proton exchange membrane (PEM) electrolysis anion exchange membrane (AEM) electrolysis and solid oxide electrolysis cells (SOECs) are evaluated in terms of efficiency scalability and integration potential. Storage pathways are examined across physical storage (compressed gas cryo-compressed and liquid hydrogen) material-based storage (solid-state absorption in metal hydrides and chemical carriers such as LOHCs and ammonia) and geological storage (salt caverns depleted gas reservoirs and deep saline aquifers) highlighting their suitability for urban and industrial contexts. In the smart city domain hydrogen is analyzed as an enabler of zero-emission transportation low-carbon residential and commercial heating and renewable-integrated smart grids with long-duration storage capabilities. System-level studies demonstrate that coordinated integration of these applications can deliver higher overall energy efficiency deeper reductions in life-cycle GHG emissions and improved resilience of urban energy systems compared with sector-specific approaches. Policy frameworks safety standards and digitalization strategies are reviewed to illustrate how hydrogen infrastructure can be embedded into interconnected urban energy systems. Furthermore industrial applications focus on hydrogen’s potential to decarbonize energy-intensive processes and enable sector coupling between electricity heat and manufacturing. The environmental implications of hydrogen deployment are also considered including resource efficiency life-cycle emissions and ecosystem impacts. In contrast to reviews addressing isolated aspects of hydrogen technologies this study synthesizes technological infrastructural and policy dimensions integrating insights from over 400 studies to highlight the multifaceted role of hydrogen in sustainable urban development and industrial decarbonization and the added benefits achievable through coordinated cross-sector deployment strategies.
Hydrogen Cargo Bikes as a Data-driven Solution for Last-mile Decarbonization
Oct 2025
Publication
The growing demand for low-emission urban freight has intensified efficiency challenges in lastmile delivery especially in dense city centres. This study assesses hydrogen-powered cargo bikes as a scalable zero-emission alternative to fossil fuel vans and battery-electric cargo bikes. Using real-world logistics data from Rome we apply simulation models including Monte Carlo cost analysis Artificial Intelligence driven routing K-means station placement and fleet scaling. Results show hydrogen bikes deliver 15% more parcels daily than electric counterparts reduce refuelling detours by 31.4% and lower per-trip fuel use by 32%. They can cut up to 120 metric tons of CO2 annually per 100-bike fleet. While battery-electric cargo bikes remain optimal for short trips hydrogen bikes offer superior uptime range and rapid refuelling—ideal for highfrequency mid-distance logistics. Under supportive pricing and infrastructure hydrogen cargo bikes represent a resilient and sustainable solution for decarbonizing last-mile delivery in city areas.
Ammonia–Hydrogen Dual-Fuel Combustion: Strategies for Optimizing Performance and Reducing Emissions in Internal Combustion Engines
Jun 2025
Publication
The urgent need to mitigate climate change and reduce greenhouse gas emissions has accelerated the search for sustainable and scalable energy carriers. Among the different alternatives ammonia stands out as a promising carbon-free fuel thanks to its high energy density efficient storage and compatibility with existing infrastructure. Moreover it can be produced through sustainable green processes. However its application in internal combustion engines is limited by several challenges including low reactivity narrow flammability limits and high ignition energy. These factors can compromise combustion efficiency and contribute to increased unburned ammonia emissions. To address these limitations hydrogen has emerged as a complementary fuel in dual-fuel configurations with ammonia. Hydrogen’s high reactivity enhances flame stability ignition characteristics and combustion efficiency while reducing emissions of unburned ammonia. This review examines the current status of dual-fuel ammonia and hydrogen combustion strategies in internal combustion engines and summarizes the experimental results. It highlights the potential of dual-fuel systems to optimize engine performance and minimize emissions. It identifies key challenges knowledge gaps and future research directions to support the development and widespread adoption of ammonia–hydrogen dual-fuel technologies.
Green Hydrogen in the Alps: Mapping Local Stakeholders Perspectives and Identifying Opportunities for Decarbonization
Jun 2025
Publication
The effects of climate change and reliance on fossil fuels in the Alps highlight the need for energy sufficiency improved efficiency and renewable energy deployment to support decarbonization goals. Hydrogen has gained attention as a versatile zero-emission energy carrier with the potential to drive cleaner energy solutions and sustainable tourism in Alpine regions. This study shares findings from a hydrogen survey conducted within the Interreg Alpine Space AMETHyST project which included questionnaires and roundtable discussions across Alpine territories. The survey explored hydrogen’s role in decarbonizing the Alps gathering insights from local stakeholders about their knowledge expertise needs and targets for hydrogen solutions. It also mapped existing hydrogen initiatives. Results revealed strong interest in hydrogen implementation with many territories eager to launch projects. However high investment and operational costs along with associated risks are key barriers. The absence of clear local hydrogen strategies and of a comprehensive regulatory framework also poses significant challenges. Incentivization schemes could facilitate initiatives and foster local hydrogen economies. The most promising application areas for hydrogen in the Alps are private and public mobility sectors. The residential sector particularly in tourist accommodations also presents potential. Regardless of specific uses developing renewable energy capacity and infrastructure is essential to create green hydrogen ecosystems that can store excess renewable energy from intermittent sources for later use.
Human Toxicity Potential: A Lifecycle Evaluation in Current and Future Frameworks for Hydrogen-Based and Battery Electric Buses in the European Union
Sep 2025
Publication
In recent years governments have promoted the shift to low-emission transport systems with electric and hydrogen vehicles emerging as key alternatives for greener urban mobility. Evaluating zero- or near-zero tailpipe solutions requires a Lifecycle Assessment (LCA) approach accounting for emissions from energy production components and vehicle manufacturing. Such studies mainly address Greenhouse Gas (GHG) emissions while other pollutants are often overlooked. This study compares the Human Toxicity Potential (HTP) of Battery Electric Vehicles (BEVs) Fuel Cell Vehicles (FCVs) Hydrogen Internal Combustion Engine Vehicles (H2ICEVs) and hybrid H2ICEVs for public transport in the European Union. Current and future scenarios (2024 2030 2050) are examined considering evolving energy mixes and manufacturing impacts. Results underline that BEVs are characterized by the highest HTP in 2024 and that this trend is maintained even in future scenarios. As for hydrogen-based powertrains they show lower HTPs similar among them. This work underlines that current efforts must be intensified especially for BEVs to further limit harmful emissions from the mobility sector.
The Green Transition in Commercial Aviation
Aug 2025
Publication
This paper provides a comprehensive review of novel aviation technologies analyzing the advancements and challenges associated with the transition to sustainable air transport. The study explores three key pillars: unconventional aerodynamic configurations novel propulsion systems and advanced materials. Unconventional airframe architectures such as box-wing blended-wing-body and truss-braced wings demonstrate potential for improved aerostructural efficiency and reduced fuel consumption compared to traditional tube-and-wing designs. Aeropropulsive innovations as distributed propulsion boundary layer ingestion and advanced turbofan configurations are also promising in this regard. Significant progress in propulsion technologies including hybrid-electric hydrogen and extensive use of sustainable aviation fuels (SAF) plays a pivotal role in reducing air transport greenhouse gas emissions. However energy storage limitations and infrastructure constraints remain critical challenges and hence in the near future SAF could represent the most feasible solution. The introduction of advanced lightweight materials could further enhance aircraft overall performance. The results presented and discussed in this paper show that there is no a unique solution to the problem of the sustainability of air transport but a combination of all the novel technologies is necessary to achieve the ambitious environmental goals for the air transport of the future.
Designing Off-grid Hybrid Renewable Energy Systems under Uncertainty: A Two-Stage Stochastic Programming Approach
Aug 2025
Publication
The decarbonization of remote energy systems presents both technical and economic challenges due to their dependance on fossil fuels and the variability of renewable energy sources. This study introduces a Two-Stage Stochastic Programming approach to optimize Hybrid Renewable Energy Systems under uncertainty in renewable energy production. The methodology is applied to the island of Pantelleria aiming to minimize Total Annualized Costs and CO2 emissions using an ε-constraint approach. Results show that within the set of optimized configurations stricter CO2 emissions constraints increase costs due to the need for oversized components to ensure supply reliability. Nevertheless even the zeroemissions scenario offers significant economic benefits compared to the current diesel-based system. Total Annualized Costs are reduced from 15.5 M€ to 8.10 M€ in the deterministic case and to 9.37 M€ in the stochastic one. The additional cost in the stochastic configuration is offset by improved reliability ensuring demand is met under all scenarios. A sensitivity analysis on electricity demand reveals the necessity of further larger components leading to a 27.0% cost increase in a fully renewable scenario with stochastic optimization for a 10% demand increase. These findings highlight the importance of stochastic optimization in designing cost-effective off-grid renewable energy systems.
Synergistic Coupling of Waste Heat and Power to Gas via PEM Electrolysis for District Heating Applications
Sep 2025
Publication
This work explores the integration of Proton Exchange Membrane (PEM) electrolysis waste heat with district heating networks (DHN) aiming to enhance the overall energy efficiency and economic viability of hydrogen production systems. PEM electrolysers generate substantial amounts of low-temperature waste heat during operation which is often dissipated and left unutilised. By recovering such thermal energy and selling it to district heating systems a synergistic energy pathway that supports both green hydrogen production and sustainable urban heating can be achieved. The study investigates how the electrolyser’s operating temperature ranging between 50 and 80 ◦C influences both hydrogen production and thermal energy availability exploring trade-offs between electrical efficiency and heat recovery potential. Furthermore the study evaluates the compatibility of the recovered heat with common heat emission systems such as radiators fan coils and radiant floors. Results indicate that valorising waste heat can enhance the overall system performance by reducing the electrolyser’s specific energy consumption and its levelized cost of hydrogen (LCOH) while supplying carbon-free thermal energy for the end users. This integrated approach contributes to the broader goal of sector coupling offering a pathway toward more resilient flexible and resource-efficient energy systems.
High-Performance Two-Stroke Opposed-Piston Hydrogen Engine: Numerical Study on Injection Strategies, Spark Positioning and Water Injection to Mitigate Pre-Ignition
Sep 2025
Publication
In the pursuit of zero-emission mobility hydrogen represents a promising fuel for internal combustion engines. However its low volumetric energy density poses challenges especially for high-performance applications where compactness and lightweight design are crucial. This study investigates the feasibility of an innovative hydrogen-fueled two-stroke opposed-piston (2S-OP) engine targeting a specific power of 130 kW/L and an indicated thermal efficiency above 40%. A detailed 3D-CFD analysis is conducted to evaluate mixture formation combustion behavior abnormal combustion and water injection as a mitigation strategy. Innovative ring-shaped multi-point injection systems with several designs are tested demonstrating the impact of injector channels’ orientation on the final mixture distribution. The combustion analysis shows that a dual-spark configuration ensures faster combustion compared to a single-spark system with a 27.5% reduction in 10% to 90% combustion duration. Pre-ignition is identified as the main limiting factor strongly linked to mixture stratification and high temperatures. To suppress it water injection is proposed. A 55% evaporation efficiency of the water mass injected lowers the in-cylinder temperature and delays pre-ignition onset. Overall the study provides key design guidelines for future high-performance hydrogen-fueled 2S-OP engines.
Development of a MILP Optimization Framework to Design Grid-connected Microgrids: Enhancing Operational Synergy Among Wind, Solar, Batteries, and Hydrogen Storage
Sep 2025
Publication
By integrating Renewable Energy Sources (RES) and storage devices Hybrid Energy Systems (HESs) represent a promising solution for decarbonizing isolated and remote communities. Proper sizing and management of systems comprising a variety of components requires however more advanced methods than conventional energy systems. This study proposes a novel Mixed Integer Linear Programming (MILP) framework for the simultaneous design of a grid-connected HES supported by renewable generators. Unlike the standard design approach based on parametric dispatch strategies this framework simultaneously optimizes the energy management of each system configuration under analysis. The novel approach is applied to size a combination of Li-Ion batteries an alkaline electrolyzer H2 tanks and a PEM fuel cell to maximize the NPV of a system including a wind turbine and a photovoltaic field. Managing thousands of variables at the same time the framework simultaneously optimizes how all components are used to fulfill the load and balance the input/export of power within a limited electrical network. Results show that the combination of BESS and H2 can provide for both the need for short- and long-term energy storage and that the MILP optimization can effectively allocate the energy flows and produce 558 k€ of revenues per year 15.5% of the initial investment cost of 3.6 M€. The investment cost of the system is recovered in six years and presents an NPV of 5.51 M€ after 20 years. Results from the proposed method are also compared to common approaches based on rule-based parametric dispatch strategies demonstrating the superiority of MILP for the design and management of complex HESs.
Hydrogen Direct Reduced Iron Melting in an Electric Arc Furnace: Benefits of In Situ Monitoring
Oct 2025
Publication
The transition toward environmentally friendly steelmaking using hydrogen direct reduced iron as feed material in electric arc furnaces will eventually require process adjustments due to changes in the pellet properties when compared to e.g. blast furnace pellets. To this end the melting of hydrogen direct reduced iron pellets with 68 and 100% reduction degrees and Fe content of 67.24% was investigated in a laboratory-scale electric arc furnace. The presence of iron oxide-rich slag had a significant effect on the arc movement on the melt and an inhibiting effect on iron evaporation. The melting was monitored with video recording and optical emission spectroscopy. The videos were used to monitor the melting behavior whereas optical emissions revealed iron gangue elements and hydrogen from the pellets radiating in the plasma. Furthermore the flow of the melt is well seen in the videos as well as the movement of slag droplets on the melt surface. After the experiments the metal had silica-rich inclusions whereas slag had mostly penetrated into the crucible. The most notable differences in melting behavior can be attributed to the iron oxide-rich slag its interaction with the arc and penetration into the crucible and how it affects the arc movement and heat transfer.
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