Japan

Australia has clear aspirations to become a major global exporter of hydrogen as a replacement for fossil fuels and as part of the drive to reduce CO2 emissions as set out in the National Hydrogen Strategy released in 2019 jointly by the federal and state governments. In 2021 the Australian Energy Market Operator specified a grid forecast scenario for the first time entitled “hydrogen superpower”. Not only does Australia hope to capitalise on the emerging demand for zero-carbon hydrogen in places like Japan and South Korea by establishing a new export industry but it also needs to mitigate the built-in carbon risk of its export revenue from coal and LNG as major customers such as Japan and South Korea move to decarbonise their energy systems. This places hydrogen at the nexus of energy climate change mitigation and economic growth with implications for energy security. Much of the published literature on this topic concentrates on the details of what being a major hydrogen exporter will look like and what steps will need to be taken to achieve it. However there appears to be a gap in the study of the implications for Australia’s domestic energy system in terms of energy security and export economic vulnerability. The objective of this paper is to develop a conceptual framework for the implications of becoming a major hydrogen exporter on Australia’s energy system. Various green hydrogen export scenarios for Australia were compared and the most recent and comprehensive was selected as the basis for further examination for domestic energy system impacts. In this scenario 248.5 GW of new renewable electricity generation capacity was estimated to be required by 2050 to produce the additional 867 TWh required for an electrolyser output of 2088 PJ of green hydrogen for export which will comprise 55.9% of Australia’s total electricity demand at that time. The characteristics of comparative export-oriented resources and their interactions with the domestic economy and energy system are then examined through the lens of the resource curse hypothesis and the LNG and aluminium industries. These existing resource export frameworks are reviewed for applicability of specific factors to export-oriented green hydrogen production with applicable factors then compiled into a novel conceptual framework for exporter domestic implications from large-scale exports of green hydrogen. The green hydrogen export superpower (2050) scenario is then quantitatively assessed using the established indicators for energy exporter vulnerability and domestic energy security comparing it to Australia’s 2019 energy exports profile. This assessment finds that in almost all factors exporter vulnerability is reduced and domestic energy security is enhanced by the transition from fossil fuel exports to green hydrogen with the exception of an increase in exposure of the domestic energy system to international market forces.

Social risk is a comprehensive concept that considers not only internal/external physical risks but also risks (which are multiple varied and diverse) associated with social activity. It should be considered from diverse perspectives and requires a comprehensive evaluation framework that takes into account the synergistic impact of each element on others rather than evaluating each risk individually. Social risk assessment is an approach that is not limited to internal system risk from an engineering perspective but also considers the stakeholders development stage and societal readiness and resilience to change. This study aimed to introduce a social risk approach to assess the public safety of large-scale hydrogen systems. Guidelines for comprehensive social risk assessment were developed to conduct appropriate risk assessments for advanced science and technology activities with high uncertainties to predict major impacts on society before an accident occurs and to take measures to mitigate the damage and to ensure good governance are in place to facilitate emergency response and recovery in addition to preventive measures. In a case study this approach was applied to a hydrogen refueling station in Japan and risk-based multidisciplinary approaches were introduced. These approaches can be an effective supporting tool for social implementation with respect to large-scale hydrogen systems such as liquefied hydrogen storage tanks. The guidelines for social risk assessment of large-scale hydrogen systems are under the International Energy Agency Technology Collaboration Program Hydrogen Safety Task 43. This study presents potential case studies of social risk assessment for large-scale hydrogen systems for future.

The shipping industry is currently the sixth largest contributor to global emissions responsible for one billion tons of greenhouse gas emissions. Urgent action is needed to achieve carbon neutrality in the shipping industry for sustainability. In this paper we use natural language processing techniques to analyze policies announcements and position papers from national and international organizations related to the decarbonization of shipping. In particular we perform the analysis using a novel matrix-based corpus and a fine-tuned machine learning model BERTopic. Our research suggests that the top four priorities for decarbonizing shipping are preventing emissions from methane leaks promoting non-carbon-based hydrogen implementing reusable modular containers to reduce packaging waste in container shipping and protecting Arctic biodiversity while promoting the Arctic shipping route to reduce costs. Our study highlights the validity of NLP techniques in quantitatively extracting critical information related to the decarbonization of the shipping industry.

Hydrogen recombination catalyst is useful tool for reducing hydrogen in closed area. The catalyst is known to be poisoned under wet condition in long time use. The study is focused on the behavior of pre-oxidized Pd nanoparticle as the hard-used catalyst in high humidity environment by comparison of alumina and titanium oxide supports using in situ X-ray absorption spectroscopy technique. The reduction of surface oxide layer of Pd/TiO2 was promoted by water during hydrogen recombination although the reduction reaction of Pd/Al2O3 was inhibited by water.

This study investigates the techno-economic feasibility of a Power-to-X (PtX) system by integrating solarpowered hydrogen electrolysis with carbon capture and Fischer-Tropsch (FT) synthesis processes for e-fuel production in Basra Iraq. To this aim a comprehensive modeling framework is developed to cover the detailed simulation of E-fuel production along with the system cost analysis. The proposed PtX system is supposed to be located near the Hartha power plant which is one of the main sources of electricity in the Basra region allowing for the utilization of captured CO2 from the power plant’s exhaust gas. The PtX plant design shows significant potential producing 2.44 tonnes of (C12-C20) hydrocarbons and 3.36 tonnes of (C21-C40) heavy oils annually. This is achieved by utilizing 7.5 and 74.2 tonnes per year of hydrogen generated from solar electrolysis and captured CO2 respectively. A cash flow analysis covering 25 years shows that an E-fuel market price of $10 per liter is needed to achieve a positive cash flow within 15 years. The study also indicates that implementing a $200 per tonne carbon tax improves the economic feasibility of the project by allowing for earlier positive cash flows from 6 years and a quicker break-even point at the current E-fuel market price of $2 per liter with a NPV of $ 464 million. Sensitivity analysis reveals that higher carbon taxes and e-fuel prices enhance profitability by reducing payback periods and increasing the NPV. However an increase in hydrogen production costs introduces substantial risk with higher costs decreasing economic viability. The feasibility assessment suggests that despite the substantial initial investment needed for various system components the long-term advantages include reduced CO2 emissions and the potential for Iraq to emerge as a leader in renewable fuel production. Stable policies robust carbon taxes and cost-efficient hydrogen production are essential for the successful implementation of PtX project.

The hydrogen compatibility of two X65 pipeline steels for transport of hydrogen gas is investigated through microstructural characterization hydrogen permeation measurements and fracture mechanical testing. The investigated materials are a quenched and tempered pipeline steel with a fine-grained homogeneously distributed ferrite-bainite microstructure and hot rolled pipeline steel with a ferrite-pearlite banded microstructure. All tests are performed both under electrochemical and gaseous hydrogen charging conditions. A correlation between electrochemical hydrogen charging and gaseous charging is determined. The results point to inherent differences in the interaction between hydrogen and the two material microstructures. Further research is needed to unveil the influence of material microstructure on hydrogen embrittlement.

Protonic solid oxide electrolysis cells are pivotal for environmentally sustainable hydrogen production via water splitting but suffer from efficiency losses due to partial hole conductivity. Here we introduce a device architecture based on a hydride-ion (H− )/proton (H+ ) bipolar electrolyte which exploits electrochemical rectification at a heteroionic interface to overcome this limitation. The perovskite-type BaZr0.5In0.5O2.75 electrolyte undergoes an in situ transformation under electrolysis conditions forming an H+ -conducting hydrate layer adjacent to the anode and an H− -conducting oxyhydride layer near the cathode governed by competitive thermodynamic equilibria of hydration and hydrogenation. This bipolar configuration enables high Faradaic currents through the superior H− ion conductivity of the oxyhydride phase stabilized by cathodic potentials while facilitating continuous H+ /H− interconversion at the interface. Furthermore electrochemical hydrogenation generates an electron-depleted interfacial layer that effectively suppresses hole conduction. Consequently the cells achieve efficiencies of ∼95% at 1.0 A cm− 2 surpassing conventional H+ unipolar designs.

The safe removal transportation and long-term storage of fuel debris in the decommissioning of Fukushima Daiichi is the biggest challenge facing Japan. In the nuclear power field passive autocatalytic recombiners (PARs) have become established as a technology to prevent hydrogen explosions inside the containment vessel. To utilize PAR as a measure to reduce the concentration of hydrogen generated in the fuel debris storage canister which is currently an issue it is required to perform in a sealed environment with high doses of radiation low temperature and high humidity and there are many challenges different from conventional PAR. A honeycombshaped catalyst based on automotive catalyst technology has been newly designed as a PAR and research has been conducted to solve unique problems such as high dose radiation low temperature high humidity coexistence of hydrogen and low oxygen and catalyst poisons. This paper summarizes the challenges of hydrogen generation in a sealed container the results of research and a guide to how to use the PAR for fuel debris storage canisters.

Natural hydrogen is generated via serpentinization radiolysis and organic metagenesis in geological settings. After expulsion from the source and along its upward migration path the free gas may encounter hydratebearing sediments. To simulate this natural scenario CH4 hydrate and CH4 + C3H8 hydrate were synthesized at 5.0 MPa and exposed to a hydrogen-containing gas mixture. In-situ Raman spectroscopic measurements demonstrated the incorporation of H2 molecules into the hydrate phase even at a partial pressure of 0.5 MPa. Exsitu Raman spectroscopic characterization of hydrates formed from a CH4 + H2 gas mixture at 5.0 MPa confirmed the H2 inclusion within the large cavities of structure I. The results show that the interactions between H2 and the natural gas hydrate phase range from the incorporation of H2 molecules into the hydrate phase to the rapid dissociation of the gas hydrate depending on thermodynamic conditions and H2 concentration in the coexisting gas phase.

This study presents a techno-economic framework for assessing the potential of utilizing hybrid renewable energy sources (wind and solar) to produce green hydrogen with a specific focus on Australia. The model’s objective is to equip decision-makers in the green hydrogen industry with a reliable methodology to assess the availability of renewable resources for cost-effective hydrogen production. To enhance the credibility of the analysis the model integrates 10 min on-ground solar and wind data uses a high-resolution power dispatch simulation and considers electrolyzer operational thresholds. This study concentrates on five locations in Australia and employs high-frequency resource data to quantify wind and solar availability. A precise simulation of power dispatch for a large off-grid plant has been developed to analyze the PV/wind ratio element capacities and cost variables. The results indicate that the locations where wind turbines can produce cost-effective hydrogen are limited due to the high capital investment which renders wind farms uneconomical for hydrogen production. Our findings show that only one location—Edithburgh South Australia—under a 50% solar–50% wind scenario achieves a hydrogen production cost of 10.3 ¢USD/Nm3 which is lower than the 100% solar scenario. In the other four locations the 100% solar scenario proves to be the most cost-effective for green hydrogen production. This study suggests that precise and comprehensive resource assessment is crucial for developing hydrogen production plants that generate low-cost green hydrogen.