United States
Magnesium-Based Hydrogen Storage Alloys: Advances, Strategies, and Future Outlook for Clean Energy Applications
May 2024
Publication
Magnesium-based hydrogen storage alloys have attracted significant attention as promising materials for solid-state hydrogen storage due to their high hydrogen storage capacity abundant reserves low cost and reversibility. However the widespread application of these alloys is hindered by several challenges including slow hydrogen absorption/desorption kinetics high thermodynamic stability of magnesium hydride and limited cycle life. This comprehensive review provides an in-depth overview of the recent advances in magnesium-based hydrogen storage alloys covering their fundamental properties synthesis methods modification strategies hydrogen storage performance and potential applications. The review discusses the thermodynamic and kinetic properties of magnesium-based alloys as well as the effects of alloying nanostructuring and surface modification on their hydrogen storage performance. The hydrogen absorption/desorption properties of different magnesium-based alloy systems are compared and the influence of various modification strategies on these properties is examined. The review also explores the potential applications of magnesium-based hydrogen storage alloys including mobile and stationary hydrogen storage rechargeable batteries and thermal energy storage. Finally the current challenges and future research directions in this field are discussed highlighting the need for fundamental understanding of hydrogen storage mechanisms development of novel alloy compositions optimization of modification strategies integration of magnesium-based alloys into hydrogen storage systems and collaboration between academia and industry.
Designing an Inherently Safe H2 Infrastructure: Combining Analytical, Experimental, and Numerical Investigations to Optimize H2 Refuelling Stations Safety by Passive Mitigation
Sep 2023
Publication
Natural ventilation is a well-known passive mitigation method to limit hydrogen build-up in confined spaces in case of accidental release [1-3]. In most cases a basic design of H2 infrastructure is adopted and vents installed for natural ventilation are adjusted according to safety targets and constraints of the considered structure. With the growing H2 mobility market the demand for H2 refueling infrastructure in our urban environment is on the rise. In order to meet both safety requirements and societal acceptance the design of such infrastructure is becoming more important. In this study a novel design concept is proposed for the hydrogen refueling station (HRS) by modifying physical structure while keeping safety consideration as the top priority of the concept. In this collaborative project between Air Liquide and the University of Delaware an extensive evaluation was performed on new structures of the processing container and dispenser of HRS by integrating safety protocols via passive means. Through a SWOT analysis combined with the most relevant approaches including analytical engineering models numerical simulations [4] and dedicated experimental trials an optimized design was obtained and its safety enhancement was fully evaluated. A small-scale processing container and an almost full-scale dispenser were built and tested to validate the design concepts by simulating accidental H2 release scenarios and assessing the associated consequences in terms of accumulation and potential flammable volumes formation. A conical dispenser and a V-shaped roof-top processing container which were easy to build and implement were designed and tested for this proof-of-concept study. This unique methodology from conception fundamental analysis investigation and validation through experimental design execution and evaluation is fully described in this study.
Fuel Cell Vehicle Hydrogen Emissions Testing
Sep 2023
Publication
The NREL Hydrogen Sensor Laboratory is comprised of researchers dedicated to furthering hydrogen sensor technology and detection methodology. NREL has teamed up with researchers at Environment and Climate Change Canada (ECCC) and Transport Canada (TC) to conduct research to quantify hydrogen emissions from Fuel Cell Electric Vehicles (FCEV). Test protocols will have a large effect on monitoring and regulating the hydrogen emissions from FCEVs. How emissions are tested will play an important role when understanding the safety and environmental implications of using FCEVs. NREL Sensor Laboratory personnel have partnered with other entities to conduct multiple variations of emissions testing for FCEVs. This experimentation includes testing different models of FCEVs under various driving conditions while monitoring the hydrogen concentration of the exhaust using several different test methods and apparatus. Researchers look to support regulatory bodies by providing useful data that can support more consistent and relevant safety and environmental standards. We plan to present on the current test methods and results from recent emissions measurements at ECCC.
Hydrogen and the Global Energy Transition—Path to Sustainability and Adoption across All Economic Sectors
Feb 2024
Publication
This perspective article delves into the critical role of hydrogen as a sustainable energy carrier in the context of the ongoing global energy transition. Hydrogen with its potential to decarbonize various sectors has emerged as a key player in achieving decarbonization and energy sustainability goals. This article provides an overview of the current state of hydrogen technology its production methods and its applications across diverse industries. By exploring the challenges and opportunities associated with hydrogen integration we aim to shed light on the pathways toward achieving a sustainable hydrogen economy. Additionally the article underscores the need for collaborative efforts among policymakers industries and researchers to overcome existing hurdles and unlock the full potential of hydrogen in the transition to a low-carbon future. Through a balanced analysis of the present landscape and future prospects this perspective article aims to contribute valuable insights to the discourse surrounding hydrogen’s role in the global energy transition.
Energy Transition Technology Comes With New Process Safety Challenges and Risks
Jul 2023
Publication
This paper intends to give an impression of new technologies and processes that are in development for application to achieve decarbonization and about which less or no experience on associated hazards exists in the process industry. More or less an exception is hydrogen technology because its hazards are relatively known and there is industry experience in handling it safely but problems will arise when it is produced stored and distributed on a large scale. So when its use spreads to communities and it becomes as common as natural gas now measures to control the risks will be needed. And even with hydrogen surprise findings have been shown lately e.g. its BLEVE behavior when in a liquified form stored in a vessel heated externally. Substitutes for hydrogen are not without hazard concern either. The paper will further consider the hazards of energy storage in batteries and the problems to get those hazards under control. Relatively much attention will be paid to the electrification of the process industry. Many new processes are being researched which given green energy will be beneficial to reduce greenhouse gases and enhance sustainability but of which hazards are rather unknown. Therefore as last chapter the developments with respect to the concept of hazard identification and scenario definition will be considered in quite detail. Improvements in that respect are also being possible due to the digitization of the industry and the availability of data and considering the entire life cycle all facilitated by the data model standard ISO 15926 with the scope of integration of life-cycle data for process plants including oil and gas production facilities. Conclusion is that the new technologies and processes entail new process and personal hazards and that much effort is going into renewal but safety analyses are scarce. Right in a period of process renewal attention should be focused on possibilities to implement inherently safer design.
An Exploration of Safety Measures in Hydrogen Refueling Stations: Delving into Hydrogen Equipment and Technical Performance
Feb 2024
Publication
The present paper offers a thorough examination of the safety measures enforced at hydrogen filling stations emphasizing their crucial significance in the wider endeavor to advocate for hydrogen as a sustainable and reliable substitute for conventional fuels. The analysis reveals a wide range of crucial safety aspects in hydrogen refueling stations including regulated hydrogen dispensing leak detection accurate hydrogen flow measurement emergency shutdown systems fire-suppression mechanisms hydrogen distribution and pressure management and appropriate hydrogen storage and cooling for secure refueling operations. The paper therefore explores several aspects including the sophisticated architecture of hydrogen dispensers reliable leak-detection systems emergency shut-off mechanisms and the implementation of fire-suppression tactics. Furthermore it emphasizes that the safety and effectiveness of hydrogen filling stations are closely connected to the accuracy in the creation and upkeep of hydrogen dispensers. It highlights the need for materials and systems that can endure severe circumstances of elevated pressure and temperature while maintaining safety. The use of sophisticated leak-detection technology is crucial for rapidly detecting and reducing possible threats therefore improving the overall safety of these facilities. Moreover the research elucidates the complexities of emergency shut-off systems and fire-suppression tactics. These components are crucial not just for promptly managing hazards but also for maintaining the station’s structural soundness in unanticipated circumstances. In addition the study provides observations about recent technical progress in the industry. These advances effectively tackle current safety obstacles and provide the foundation for future breakthroughs in hydrogen fueling infrastructure. The integration of cutting-edge technology and materials together with the development of upgraded safety measures suggests a positive trajectory towards improved efficiency dependability and safety in hydrogen refueling stations.
Helping the Climate by Replacing Liquefied Natural Gas with Liquefied Hydrogen or Ammonia?
Apr 2024
Publication
The war in Ukraine caused Europe to more than double its imports of liquefied natural gas (LNG) in only one year. In addition imported LNG remains a crucial source of energy for resource-poor countries such as Japan where LNG imports satisfy about a quarter of the country’s primary energy demand. However an increasing number of countries are formulating stringent decarbonization plans. Liquefied hydrogen and liquefied ammonia coupled with carbon capture and storage (LH2-CCS LNH3-CCS) are emerging as the front runners in the search for low-carbon alternatives to LNG. Yet little is currently known about the full environmental profile of LH2-CCS and LNH3-CCS because several characteristics of the two alternatives have only been analyzed in isolation in previous work. Here we show that the potential of these fuels to reduce greenhouse gas (GHG) emissions throughout the supply chain is highly uncertain. Our best estimate is that LH2-CCS and LNH3-CCS can reduce GHG emissions by 25%–61% relative to LNG assuming a 100 year global warming potential. However directly coupling LNG with CCS would lead to substantial GHG reductions on the order of 74%. Further under certain conditions emissions from LH2-CCS and LNH3-CCS could exceed those of LNG by up to 44%. These results question the suitability of LH2-CCS and LNH3-CCS for stringent decarbonization purposes.
The Role of Hydrogen in the Energy Transition of the Oil and Gas Industry
May 2024
Publication
Hydrogen primarily produced from steam methane reforming plays a crucial role in oil refining and provides a solution for the oil and gas industry's long-term energy transition by reducing CO2 emissions. This paper examines hydrogen’s role in this transition. Firstly experiences from oil and gas exploration including in-situ gasification can be leveraged for hydrogen production from subsurface natural hydrogen reservoirs. The produced hydrogen can serve as fuel for generating steam and heat for thermal oil recovery. Secondly hydrogen can be blended into gas for pipeline transportation and used as an alternative fuel for oil and gas hauling trucks. Additionally hydrogen can be stored underground in depleted gas fields. Lastly oilfield water can be utilized for hydrogen production using geothermal energy from subsurface oil and gas fields. Scaling up hydrogen production faces challenges such as shared use of oil and gas infrastructures increased carbon tax for promoting blue hydrogen and the introduction of financial incentives for hydrogen production and consumption hydrogen leakage prevention and detection.
Leakage Rates of Hydrogen-methane Gas Blends under Varying Pressure Conditions
Nov 2024
Publication
Integration of hydrogen into the existing natural gas infrastructure is considered a potential pathway that can accelerate the incorporation of hydrogen into the energy sector. While blending renewable hydrogen with natural gas offers advantages such as reduced carbon intensity and the ability to utilize existing infrastructure for hydrogen storage and transportation there are several concerns including leakage and associated issues. Un derstanding the behavior of hydrogen blended with natural gas in the existing infrastructure is crucial to ensure safe and efficient integration. In this study the leakage rates of mixtures of hydrogen and methane at different molar concentrations (5% 10% 20% and 50% hydrogen) through both precision machined orifices and com mon pipe fitting threads were investigated. The experiments showed that the leakage rates of these mixtures increased as the hydrogen content increased; however gas chromatography (GC) analysis showed that hydrogen did not leak preferentially at a greater rate than methane. The results indicate that mixing hydrogen with methane can increase the volume of gas leakage under the same pressure conditions. These findings suggest that mixing hydrogen with natural gas may result in increased volumetric flow rate of gas leaks but hydrogen alone does not leak preferentially to methane.
Simple Energy Model for Hydrogen Fuel Cell Vehicles: Model Development and Testing
Dec 2024
Publication
Hydrogen fuel cell vehicles (HFCVs) are a promising technology for reducing vehicle emissions and improving energy efficiency. Due to the ongoing evolution of this technology there is limited comprehensive research and documentation regarding the energy modeling of HFCVs. To address this gap the paper develops a simple HFCV energy consumption model using new fuel cell efficiency estimation methods. Our HFCV energy model leverages real-time vehicle speed acceleration and roadway grade data to determine instantaneous power exertion for the computation of hydrogen fuel consumption battery energy usage and overall energy consumption. The results suggest that the model’s forecasts align well with real-world data demonstrating average error rates of 0.0% and −0.1% for fuel cell energy and total energy consumption across all four cycles. However it is observed that the error rate for the UDDS drive cycle can be as high as 13.1%. Moreover the study confirms the reliability of the proposed model through validation with independent data. The findings indicate that the model precisely predicts energy consumption with an error rate of 6.7% for fuel cell estimation and 0.2% for total energy estimation compared to empirical data. Furthermore the model is compared to FASTSim which was developed by the National Renewable Energy Laboratory (NREL) and the difference between the two models is found to be around 2.5%. Additionally instantaneous battery state of charge (SOC) predictions from the model closely match observed instantaneous SOC measurements highlighting the model’s effectiveness in estimating real-time changes in the battery SOC. The study investigates the energy impact of various intersection controls to assess the applicability of the proposed energy model. The proposed HFCV energy model offers a practical versatile alternative leveraging simplicity without compromising accuracy. Its simplified structure reduces computational requirements making it ideal for real-time applications smartphone apps in-vehicle systems and transportation simulation tools while maintaining accuracy and addressing limitations of more complex models.
Hydrogen Equipment Enclosure Risk Reduction through Earlier Detection of Component Failures
Sep 2023
Publication
Hydrogen component reliability and the hazard associated with failure rates is a critical area of research for the successful implementation and growth of hydrogen technology across the globe. The research team has partnered to quantify system risk reduction through earlier detection of hydrogen component failures. A model of hydrogen dispersion in a hydrogen equipment enclosure has been developed utilizing experimentally quantified hydrogen component leak rates as inputs. This model provides insight into the impact of hydrogen safety sensors and ventilation on the flammable mass within a hydrogen equipment enclosure. This model also demonstrates the change in safety sensor response time due to detector placement under various leak scenarios. The team looks to improve overall hydrogen system safety through an improved understanding of hydrogen component reliability and risk mitigation methods. This collaboration fits under the work program of IEA Hydrogen Task 43 Subtask E Hydrogen System Safety.
Everything About Hydrogen Podcast: "Stat of the Union" with EAH Hosts
May 2024
Publication
This week’s episode is a discussion between EAH hosts Patrick Molloy Alicia Eastman and Chris Jackson. The team cover the current status of hydrogen regulation innovation financing markets and consolidation. Hanging over most conversations in the decarbonization or future fuels space is the perpetual question: When will investors actually step up with significant capital to help companies make it through the development desert instead of letting promising companies languish in the double dunes of despair? There has been a lot of talk but not a lot of action. Listen to the team unpack recent developments and hopes for the future.
The podcast can be found on their website.
The podcast can be found on their website.
Enabling Large-scale Enhanced Hydrogen Production in Deep Underground Coal Gasification in the Context of a Hydrogen Economy
Dec 2024
Publication
Underground coal gasification (UCG) is an emerging clean energy technology with significant potential for enhanced hydrogen production especially when coupled with water injection. Previous lab-scale studies have explored this potential but the mechanisms driving water-assisted hydrogen enhancement in large-scale deep UCG settings remain unclear. This study addresses this gap using numerical simulations of a large-scale deep coal model designed for hydrogen-oriented UCG. We investigated single-point and multipoint water injection stra tegies to optimize hydrogen production. Additionally we developed a retractable water injection technique to ensure sustained hydrogen output and effective cavity control. Our results indicate that the water–gas shift re action is crucial for increasing hydrogen production. Multipoint injection has been proven to be more effective than single-point injection increasing hydrogen production by 11% with an equal amount of steam. The introduction of retractable injection allows for continuous and efficient hydrogen generation with daily hydrogen production rates of approximately five times that of a conventional injection scheme and an increase in cumulative hydrogen production of approximately 105% over the same time period. Importantly the mul tipoint injection method also helped limit vertical cavity growth mitigating the risk of aquifer contamination. These findings support the potential of UCG as a low-carbon energy source in the transition to a hydrogen economy
Multiperiod Modeling and Optimization of Hydrogen-Based Dense Energy Carrier Supply Chains
Feb 2024
Publication
The production of hydrogen-based dense energy carriers (DECs) has been proposed as a combined solution for the storage and dispatch of power generated through intermittent renewables. Frameworks that model and optimize the production storage and dispatch of generated energy are important for data-driven decision making in the energy systems space. The proposed multiperiod framework considers the evolution of technology costs under different levels of promotion through research and targeted policies using the year 2021 as a baseline. Furthermore carbon credits are included as proposed by the 45Q tax amendment for the capture sequestration and utilization of carbon. The implementation of the mixed-integer linear programming (MILP) framework is illustrated through computational case studies to meet set hydrogen demands. The trade-offs between different technology pathways and contributions to system expenditure are elucidated and promising configurations and technology niches are identified. It is found that while carbon credits can subsidize carbon capture utilization and sequestration (CCUS) pathways substantial reductions in the cost of novel processes are needed to compete with extant technology pathways. Further research and policy push can reduce the levelized cost of hydrogen (LCOH) by upwards of 2 USD/kg.
IEA TCP Task 43 - Subtask Safety Distances: State of the Art
Sep 2023
Publication
The large deployment of hydrogen technologies for new applications such as heat power mobility and other emerging industrial utilizations is essential to meet targets for CO2 reduction. This will lead to an increase in the number of hydrogen installations nearby local populations that will handle hydrogen technologies. Local regulations differ and provide different safety and/or separation distances in different geographies. The purpose of this work is to give an insight on different methodologies and recommendations developed for hydrogen (mainly) risk management and consequences assessment of accidental scenarios. The first objective is to review available methodologies and to identify the divergent points on the methodology. For this purpose a survey has been launched to obtain the needed inputs from the subtask participants. The current work presents the outcomes of this survey highlighting the gaps and suggesting the prioritization of the actions to take to bridge these gaps.
Modeling the Global Annual Carbon Footprint for the Transportation Sector and a Path to Sustainability
Jun 2023
Publication
The transportation industry’s transition to carbon neutrality is essential for addressing sustainability concerns. This study details a model for calculating the carbon footprint of the transportation sector as it progresses towards carbon neutrality. The model aims to support policymakers in estimating the potential impact of various decisions regarding transportation technology and infrastructure. It accounts for energy demand technological advancements and infrastructure upgrades as they relate to each transportation market: passenger vehicles commercial vehicles aircraft watercraft and trains. A technology roadmap underlies this model outlining anticipated advancements in batteries hydrogen storage biofuels renewable grid electricity and carbon capture and sequestration. By estimating the demand and the technologies that comprise each transportation market the model estimates carbon emissions. Results indicate that based on the technology roadmap carbon neutrality can be achieved by 2070 for the transportation sector. Furthermore the model found that carbon neutrality can still be achieved with slippage in the technology development schedule; however delays in infrastructure updates will delay carbon neutrality while resulting in a substantial increase in the cumulative carbon footprint of the transportation sector.
Advancements in Hydrogen Energy Systems: A Review of Levelized Costs, Financial Incentives and Technological Innovations
Apr 2024
Publication
Hydrogen energy systems (HES) are increasingly recognized as pivotal in cutting global carbon dioxide (CO2) emissions especially in transportation power generation and industrial sectors. This paper offers a comprehensive review of HES emphasizing their diverse applications and economic viability. By 2030 hydrogen energy is expected to revolutionize various sectors significantly impacting CO2 abatement and energy demand. In electricity and power generation hydrogen could reduce CO2 emissions by 50–100 million tons annually requiring 10–20 million tons of hydrogen and an investment of $50–100 billion underscoring its role in grid stabilization. Additionally in the heating sector hydrogen could facilitate a CO2 abatement of 30–50 million tons. We examine the levelized cost of hydrogen (LCOH) production influenced by factors like production methods efficiency and infrastructure. While steam methane reforming is cost-effective it poses a larger environmental impact compared to electrolysis. The global life-cycle cost of hydrogen production decreases as production scales up with current costs ranging from $1–3 per kg for fossil-based sources to $3.4–7.5 per kg for electrolysis using low-emission electricity. These costs are projected to decrease especially for electrolytic hydrogen in regions with abundant solar energy. However despite the technical feasibility of decarbonization high production costs still pose challenges. A systematic and effective transition to a hydrogen economy requires comprehensive policy and financial support mechanisms including incentives subsidies tax measures and funding for research and development of pilot projects. Additionally the paper discusses hydrogen's role in advanced storage technologies such as hydrides and Japan's ENE-FARM solution for residential energy emphasizing the need for strategic investments across the hydrogen value chain to enhance HES competitiveness reduce LCOH and advance the learning rates of hydrogen production technologies.
Multi-year Energy Performance Data for an Electrolysis-based Hydrogen Refueling Station
Apr 2023
Publication
Financing sizing operating or upgrading a hydrogen refueling station (HRS) is challenging and may be complex much more so in today's rapidly changing and growing hydrogen industry. There is a significant information gap regarding experimental hydrogen station activities. A high-level perspective on such data and information may facilitate the transition between present and future HRS operations. To address the need for such high-level perspective this paper presents a comprehensive data set on the performance of the California State University Los Angeles Hydrogen Research and Fueling Facility based on multi-year operational data. The analysis of over 4500 refueling events and over 8800 kg of hydrogen dispensed as well as the operation of the facility electrolyzer and of both storage and refueling compressors from 2016 to 2020 reveals a comprehensive picture of HRS energy performance and the identification of useful key performance indicators. In 2016 the station's energy efficiency was 25% but in 2017 and the first three quarters of 2018 it dropped to 15%. Station-specific energy consumption increased during these quarters. The 2020 first quarter energy consumption was between 70 and 80 kWh/kg. At this time the energy efficiency of the station reached 40%.<br/>This research is based on an unprecedented and unique dataset of an HRS operating under real-world conditions with an approach that can be informative for modeling the performance of other stations providing a dataset that HRS designers operators and investors may utilize to make data-driven choices regarding HRS components and their specs and size as well as operating strategies.
Everything About Hydrogen Podcast: Mobilizing Capital in Green Hydrogen
Apr 2023
Publication
Continuing from previous episodes about encouraging global investment in green hydrogen Patrick Molloy and Alicia Eastman speak with Ignacio de Calonje Chief Investment Officer IFC Global Infrastructure. Ignacio breaks down the role of the IFC and its relationship with other Multilateral Development Banks (MDBs) to encourage decarbonization and bespoke solutions for the Global South.
The podcast can be found on their website.
The podcast can be found on their website.
Hydrogen-powered Aircraft: Fundamental Concepts, Key Technologies, and Environmental Impacts
Sep 2024
Publication
Civil aviation provides an essential transportation network that connects the world and supports global economic growth. To maintain these benefits while meeting environmental goals next-generation aircraft must have drastically reduced climate impacts. Hydrogen-powered aircraft have the potential to fly existing routes with no carbon emissions and reduce or eliminate other emissions. This paper is a comprehensive guide to hydrogen-powered aircraft that explains the fundamental physics and reviews current technologies. We discuss the impact of these technologies on aircraft design cost certification and environment. In the long term hydrogen aircraft appear to be the most compelling alternative to today’s kerosene-powered aircraft. Using hydrogen also enables novel technologies such as fuel cells and superconducting electronics which could lead to aircraft concepts that are not feasible with kerosene. Hydrogen-powered aircraft are technologically feasible but require significant research and development. Lightweight liquid hydrogen tanks and their integration with the airframe is one of the critical technologies. Fuel cells can eliminate in-flight emissions but must become lighter more powerful and more durable to make large fuel cell-powered transport aircraft feasible. Hydrogen turbofans already have these desirable characteristics but produce some emissions albeit much less damaging than kerosene turbofans. Beyond airframe and propulsion technologies the viability of hydrogen aircraft hinges on low-cost green hydrogen production which requires massive investments in the energy infrastructure.
Hydrogen Storage Minimisation under Industrial Flexibility Constraints: A Techno-economic Analysis of Off-grid Green Ammonia Production
Feb 2025
Publication
Electrifying ammonia production using renewable energy (RE) and water electrolysis is a critical step in the worldwide transition from fossil fuels to alternative energy sources. However the common requirement that the ammonia reactor operate at a steady production level harms the system’s economic feasibility due to the large hydrogen and battery storage required to overcome RE variability. In this study we examine the sensitivity of the plant storage capacity requirement to the flexibility of the ammonia reactor. We examine two aspects of ammonia reactor flexibility: ramping rate flexibility and the range of operation (turndown flexibility). We develop a storage dispatch and ammonia reactor scheduling optimization which computes the minimum storage requirement given a RE generation profile and set of reactor flexibility parameters. We optimize across a sweep of flexibility parameters for two locations in the United States. We find that turndown flexibility is the most important while ramping flexibility has little effect on the overall storage requirement. Further we see that seasonal variability in the RE generation profile is the primary driver of high storage capacity requirement. We find that with a turndown flexibility of 60% of the ammonia plants rated capacity which is understood to be achievable with existing ammonia reactor technology the storage capacity was reduced by 84 % in one of the locations we examined which resulted in a 22% decrease in the levelized cost of ammonia with pipe-based hydrogen storage.
Review of Electrofuel Feasibility - Cost and Environmental Impact
Jun 2022
Publication
Electrofuels fuels produced from electricity water and carbon or nitrogen are of interest as substitutes for fossil fuels in all energy and chemical sectors. This paper focuses on electrofuels for transportation where some can be used in existing vehicle/vessel/aircraft fleets and fueling infrastructure. The aim of this study is to review publications on electrofuels and summarize costs and environmental performance. A special case denoted as bio-electrofuels involves hydrogen supplementing existing biomethane production (e.g. anaerobic digestion) to generate additional or different fuels. We use costs identified in the literature to calculate harmonized production costs for a range of electrofuels and bio-electrofuels. Results from the harmonized calculations show that bio-electrofuels generally have lower costs than electrofuels produced using captured carbon. Lowest costs are found for liquefied bio-electro-methane bio-electro-methanol and bio-electro-dimethyl ether. The highest cost is for electro-jet fuel. All analyzed fuels have the potential for long-term production costs in the range 90–160 € MWh−1 . Dominant factors impacting production costs are electrolyzer and electricity costs the latter connected to capacity factors (CFs) and cost for hydrogen storage. Electrofuel production costs also depend on regional conditions for renewable electricity generation which are analyzed in sensitivity analyses using corresponding CFs in four European regions. Results show a production cost range for electro-methanol of 76–118 € MWh−1 depending on scenario and region assuming an electrolyzer CAPEX of 300–450 € kWelec −1 and CFs of 45%–65%. Lowest production costs are found in regions with good conditions for renewable electricity such as Ireland and western Spain. The choice of system boundary has a large impact on the environmental assessments. The literature is not consistent regarding the environmental impact from different CO2 sources. The literature however points to the fact that renewable energy sources are required to achieve low global warming impact over the electrofuel life cycle.
Recent Developments in Sensor Technologies for Enabling the Hydrogen Economy
Dec 2023
Publication
Efforts to create a sustainable hydrogen economy are gaining momentum as governments all over the world are investing in hydrogen production storage distribution and delivery technologies to develop a hydrogen infrastructure. This involves transporting hydrogen in gaseous or liquid form or using carrier gases such as methane ammonia or mixtures of methane and hydrogen. Hydrogen is a colorless odorless gas and can easily leak into the atmosphere leading to economic loss and safety concerns. Therefore deployment of robust low-cost sensors for various scenarios involving hydrogen is of paramount importance. Here we review some recent developments in hydrogen sensors for applications such as leak detection safety process monitoring in production transport and use scenarios. The status of methane and ammonia sensors is covered due to their important role in hydrogen production and transportation using existing natural gas and ammonia infrastructure. This review further provides an overview of existing commercial hydrogen sensors and also addresses the potential for hydrogen as an interferent gas for currently used sensors. This review can help developers and users make informed decisions about how to drive hydrogen sensor technology forward and to incorporate hydrogen sensors into the various hydrogen deployment projects in the coming decade.
Agrivoltaics, Opportunities for Hydrogen Generation, and Market Developments
Feb 2025
Publication
To achieve deep decarbonization renewable energy generation must be substantially increased. The technologies with the lowest levelized cost of electricity (LCOE) are land-based photovoltaics (PVs) and wind energy. Agri-PVs offer the potential for dual land use combining energy generation with agricultural activities. However the costs of agri-PVs are higher than those of ground-mounted PV. To enhance the competitiveness of agri-PV we investigate the synergies between agri-PVs and hydrogen electrolysis through process simulation. Additionally we analyse current technological developments in agri-PVs based on a market analysis of start-up companies. Our results indicate that the levelized cost of hydrogen (LCOH) can be comparable for agri-PVs and ground-mounted PVs due to the somewhat smoother electricity generation for the same installed capacity. The market analysis reveals the emergence of a technology ecosystem that integrates agri-PVs with next-generation agricultural technologies such as sensors robotics and artificial intelligence (AI) agents along with localized electricity generation forecasting. The integrated agri-PV and hydrogen generation system has significant global scaling potential for renewable energy generation. Furthermore it positively impacts local economies and energy resilience may reduce water scarcity in agriculture and leverages advancements in AI robotics PV and hydrogen generation technologies.
Quantitative Risk Assessment of Hydrogen Releases in a Hydrogen Fueling Station with Liquid Hydrogen Storage
Feb 2025
Publication
Quantitative Risk Assessments (QRA) is an important tool for enabling safe deployment of hydrogen technologies and is increasingly embedded in the permitting process. Following the framework developed in our companion paper we conducted a detailed QRA on the uncontrolled releases from a high-capacity hydrogen fueling station with liquid hydrogen (LH2) storage. We characterized gaseous and liquid hydrogen releases determined the causal pathways that led to them and the frequency of the potential hazardous outcomes. These hazardous scenarios were modeled to estimate their potential harm on station users. The analysis results reveal that the total frequency for a major hydrogen release is 1.48 × 10− 2 times per station-year. However considering the control barriers in the station the expected frequency of ignition events is reduced to 1.35 × 10− 5 ignition per stationyear. The expected fatality risk is within the tolerable limit for hydrogen fueling stations but still remains higher than that of conventional gasoline stations. The most severe scenario identified involves a high-pressure GH2 release leading to a jet fire with jet flames reaching up to 15 m in length. The most probable sources of GH2 releases are from the gaseous hydrogen filters while for LH2 releases cryogenic pumps are the primary contributors. To improve the accuracy of QRAs for LH2 systems we identified critical gaps including the need for improved reliability data that must be addressed.
Advancing Hydrogen Gas Utilization in Industrial Boilers: Impacts on Critical Boiler Components, Mitigation Measures, and Future Perspectives
Sep 2024
Publication
This review sets out to investigate the detrimental impacts of hydrogen gas (H2 ) on critical boiler components and provide appropriate state-of-the-art mitigation measures and future research directions to advance its use in industrial boiler operations. Specifically the study focused on hydrogen embrittlement (HE) and high-temperature hydrogen attack (HTHA) and their effects on boiler components. The study provided a fundamental understanding of the evolution of these damage mechanisms in materials and their potential impact on critical boiler components in different operational contexts. Subsequently the review highlighted general and specific mitigation measures hydrogen-compatible materials (such as single-crystal PWA 1480E Inconel 625 and Hastelloy X) and hydrogen barrier coatings (such as TiAlN) for mitigating potential hydrogen-induced damages in critical boiler components. This study also identified strategic material selection approaches and advanced approaches based on computational modeling (such as phase-field modeling) and data-driven machine learning models that could be leveraged to mitigate potential equipment failures due to HE and HTHA under elevated H2 conditions. Finally future research directions were outlined to facilitate future implementation of mitigation measures material selection studies and advanced approaches to promote the extensive and sustainable use of H2 in industrial boiler operations.
Net-Zero Greenhouse Gas Emission Electrified Aircraft Propulsion for Large Commercial Transport
Sep 2024
Publication
Until recently electrified aircraft propulsion (EAP) technology development has been driven by the dual objectives of reducing greenhouse gas (GHG) emissions and addressing the depletion of fossil fuels. However the increasing severity of climate change posing a significant threat to all life forms has resulted in the global consensus of achieving net-zero GHG emissions by 2050. This major shift has alerted the aviation electrification industry to consider the following: What is the clear path forward for EAP technology development to support the net-zero GHG goals for large commercial transport aviation? The purpose of this paper is to answer this question. After identifying four types of GHG emissions that should be used as metrics to measure the effectiveness of each technology for GHG reduction the paper presents three significant categories of GHG reduction efforts regarding the engine evaluates the potential of EAP technologies within each category as well as combinations of technologies among the different categories using the identified metrics and thus determines the path forward to support the net-zero GHG objective. Specifically the paper underscores the need for the aviation electrification industry to adapt adjust and integrate its EAP technology development into the emerging new engine classes. These innovations and collaborations are crucial to accelerate net-zero GHG efforts effectively.
Near-term Infrastructure Rollout and Investment Strategies for Net-zero Hydrogen Supply Chains
Feb 2024
Publication
Low-carbon hydrogen plays a key role in European industrial decarbonization strategies. This work investigates the cost-optimal planning of European low-carbon hydrogen supply chains in the near term (2025–2035) comparing several hydrogen production technologies and considering multiple spatial scales. We focus on mature hydrogen production technologies: steam methane reforming of natural gas biomethane reforming biomass gasification and water electrolysis. The analysis includes carbon capture and storage for natural gas and biomass-derived hydrogen. We formulate and solve a linear optimization model that determines the costoptimal type size and location of hydrogen production and transport technologies in compliance with selected carbon emission targets including the EU fit for 55 target and an ambitious net-zero emissions target for 2035. Existing steam methane reforming capacities are considered and optimal carbon and biomass networks are designed. Findings identify biomass-based hydrogen production as the most cost-efficient hydrogen technology. Carbon capture and storage is installed to achieve net-zero carbon emissions while electrolysis remains costdisadvantageous and is deployed on a limited scale across all considered sensitivity scenarios. Our analysis highlights the importance of spatial resolution revealing that national perspectives underestimate costs by neglecting domestic transport needs and regional resource constraints emphasizing the necessity for highly decarbonized infrastructure designs aligned with renewable resource availabilities.
Very Low-cost Wireless Hydrogen Leak Detection for Hydrogen Infrastructure
Sep 2023
Publication
A unique hydrogen leak detection strategy is the use of powerless indicator wraps for fittings and other pneumatic elements within a hydrogen facility. One transduction mechanism of such indicators is a color change that is induced by a reaction between a pigment and released hydrogen. This is an effective way to detect hydrogen leaks and to identify their source before they become a safety event however this technology requires visual (manual) inspection to identify a color change or leak. One improvement in this strategy would be to improve the communication of the visual response to an end-user. Element One (E1) has previously developed and introduced DetecTape® a self-fusing silicone non-reversible hydrogen leak detecting tape for application to potential leak sites in hydrogen piping valves and fittings and it has been successfully commercialized with excellent feedback. Element One’s sensors can be fabricated using either pigments or thin films which both change color and conductivity. Neither change requires an external power source. The conductivity change may be communicated as a wireless transmission such as passive radio frequency identification devices (RFID) to an appropriate receiving system where it may be remotely monitored to achieve higher levels of safety and reliability at low cost. Element One will report on its recent progress in the commercial development of remotely monitored hydrogen leak detection using several wireless protocols including passive RFID.
Everything About Hydrogen Podcast: State of the Union with the Everything About Hydrogen Team
Dec 2024
Publication
Back by popular demand Christopher Jackson Alicia Eastman and Patrick Molloy speak about the industry highlights and lowlights expectations for 2025 and what we can do to improve outcomes across the board. Equal parts sweepingly generalist and mind numbing minutiae create the perfect pundit cocktail. Wallow in the bad news and celebrate the bright sides together.
The podcast can be found on their website.
The podcast can be found on their website.
Exploratory Numerical Study of Liquid Hydrogen Hazards
Sep 2023
Publication
Hydrogen is one of a handful of new low carbon solutions that will be critical for the transition to net zero. The upscaling of production and applications entails that hydrogen is likely to be stored in liquid phase (LH2) at cryogenic conditions to increase its energy density. Widespread LH2 use as an alternative fuel will require significant infrastructure upgrades to accommodate increased bulk transport storage and delivery. However current LH2 bulk storage separation distances are based on subjective expert recommendations rather than experimental observations or physical models. Experimental studies of large-scale LH2 release are challenging and costly. The existing large-scale tests are scarce and numerical studies are a viable option to investigate the existing knowledge gaps. Controlled or accidental releases of LH2 for hydrogen refueling infrastructure would result in high momentum two-phase jets or formation of liquid pools depending on release conditions. Both release scenarios lead to a flammable/explosive cloud posing a safety issue to the public.<br/>The manuscript reports exploratory study to numerically determine the safety zone resulting from cryogenic hydrogen releases related to LH2 storage and refueling using the in-house HyFOAM solver further modified for gaseous hydrogen releases at cryogenic conditions and the subsequent atmospheric dispersion and ignition within the platform of OpenFOAM V8.0. The current version of the solver neglects the flashing process by assuming that the temperature of the stored LH2 is equal to the boiling point at the atmospheric condition. Numerical simulations of dispersion and subsequent ignition of LH2 release scenarios with respect to different release orientations release rates release temperatures and weather conditions were performed. Both hydrogen concentration and temperature fields were predicted and the boundary of zones within the flammability limit was also defined. The study also considered the sensitivities of the consequences to the release orientation wind speed ambient temperature and release content etc. The effect of different barrier walls on the deflagration were also evaluated by changing the height and location.
Mining Nontraditional Water Sources for a Distributed Hydrogen Economy
Jul 2022
Publication
Securing decarbonized economies for energy and commodities will requireabundant and widely available green H2. Ubiquitous wastewaters and nontraditional watersources could potentially feed water electrolyzers to produce this green hydrogen withoutcompeting with drinking water sources. Herein we show that the energy and costs of treatingnontraditional water sources such as municipal wastewater industrial and resource extractionwastewater and seawater are negligible with respect to those for water electrolysis. We alsoillustrate that the potential hydrogen energy that could be mined from these sources is vast.Based on these findings we evaluate the implications of small-scale distributed waterelectrolysis using disperse nontraditional water sources. Techno-economic analysis and lifecycle analysis reveal that the significant contribution of H2 transportation to costs and CO2emissions results in an optimal levelized cost of hydrogen at small- to moderate-scale waterelectrolyzer size. The implications of utilizing nontraditional water sources and decentralizedor stranded renewable energy for distributed water electrolysis are highlighted for severalhydrogen energy storage and chemical feedstock applications. Finally we discuss challengesand opportunities for mining H2 from nontraditional water sources to achieve resilient and sustainable economies for water andenergy.
Life-cycle Assessment and Cost Analysis of Hydrogen Production via Aluminium-seawater Reactions
Jun 2025
Publication
Presented is an evaluation of the carbon footprint and costs associated with hydrogen production via the aluminum-water reaction (AWR) identifying an optimized scenario that achieves 1.45 kgCO2 equiv per kg of hydrogen produced. U.S.-based data are used to compare results with conventional production methods and to assess hydrogen use in fuel-cell passenger vehicles. In the optimized scenario major contributors include the use of recycled aluminum (0.38 kgCO2 equiv) aluminum processing (0.45 kgCO2 equiv) and alloy activator recovery (0.57 kgCO2 equiv). A cost analysis estimates hydrogen production at $9.2/kg when using scrap aluminum alloy recovery and recycling thermal energy aligning with current green hydrogen prices. Reselling reaction byproducts such as boehmite could generate revenue 5.6 times greater than input costs enhancing economic feasibility. The cradle-to-grave assessment suggests that aluminum fuel as an energy carrier for hydrogen distribution and fuel cell vehicle applications offers a low-emission and economically viable pathway for clean energy deployment.
Modeling the Impact of Hydrogen Embrittlement on the Fracture Toughness of Low-Carbon Steel Using a Machine Learning Approach
May 2025
Publication
This study aims to advance the understanding of hydrogen embrittlement (HE) in low-carbon and low-alloy steels by developing a predictive framework for assessing fracture toughness (FT) a critical parameter for mitigating HE in hydrogen infrastructure. A machine learning (ML) model was constructed by analyzing data from relevant literature to evaluate the fracture toughness of steels exposed to hydrogen environments. Seven ML modeling techniques were initially considered with four selected for detailed evaluation based on predictive accuracy. The chosen modeling techniques were k-nearest neighbors (KNN) random forest (RF) gradient boosting (GB) and decision tree regression (DT). The selected models were further evaluated for their predictive accuracy and reliability and the best model was used to perform parametric studies to investigate the impact of relevant parameters on FT. According to the results the KNN model demonstrated reliable predictive performance supported by high R-squared values and low error metrics. Among the variables considered hydrogen pressure and yield strength emerged as the most influential with hydrogen pressure alone accounting for 32% of the variation in FT. The model revealed a distinct trend in FT behavior showing a significant decline at low hydrogen pressures (0–6.9 MPa) and a plateau at higher pressures (>8 MPa) indicating a saturation point. Alloying element contents specifically those of carbon and phosphorus also played a notable role in FT prediction. Additionally the study confirmed that low concentrations of oxygen (
Environmental Life-cycle Analysis of Hydrogen Technology in the United States
Oct 2024
Publication
Hydrogen is a zero-carbon energy carrier with potential to decarbonize industrial and transportation sectors but its life-cycle greenhouse gas (GHG) emissions depend on its energy supply chain and carbon management measures (e.g. carbon capture and storage). Global support for clean hydrogen production and use has recently intensified. In the United States Congress passed several laws that incentivize the production and use of renewable and low-carbon hydrogen such as the Bipartisan Infrastructure Law (BIL) in 2021 and the Inflation Reduction Act (IRA) in 2022 which provides tax credits of up to $3/kg depending on the carbon intensity of the produced hydrogen. A comprehensive life-cycle accounting of GHG emissions associated with hydrogen production is needed to determine the carbon intensity of hydrogen throughout its value chain. In the United States Argonne’s R&D GREET® (Greenhouse Gases Regulated emissions and Energy use in Technologies) model has been widely used for hydrogen carbon intensity calculations. This paper describes the major hydrogen technology pathways considered in the United States and provides data sources and carbon intensity results for each of the hydrogen production and delivery pathways using consistent system boundaries and most recent technology performance and supply chain data.
Stratified Hydrogen Combustion with Various Mixing Processes
Aug 2025
Publication
Hydrogen is recognized as a key alternative fuel for mitigating greenhouse-gas emissions owing to its high fuel efficiency and carbon-free combustion. In the stratified charge combustion (SCC) mode ensuring optimal air-fuel mixing in the combustion chamber is crucial because the local equivalence ratio has a dominant influence on combustion characteristics. Therefore this study aims to build a detailed understanding of stratified hydrogen combustion under various local equivalence ratios. Laser-induced breakdown spectroscopy (LIBS) was used to measure the local equivalence ratios in hydrogen jets at different mixture-formation times (MFTs) and laserignition points (LIPs). The results showed that shorter MFTs induced highly stratified mixtures with elevated local equivalence ratios exceeding 2.0 enhancing the laminar flame speed and maximizing the conversion of chemical energy into pressure gain resulting in a representative total heat release over three times higher compared to longer MFTs. Furthermore ignition near the injector tip produced leaner mixtures with equivalence ratios around 0.3 whereas downstream LIPs generated peak local equivalence ratios around 2.0 facilitating rapid flame propagation and increased heat release by 25 %.
Carbon Neutrality in Malaysia and Kuala Lumpur: Insights from Stakeholder-driven Integrated Assessment Modelling
Apr 2024
Publication
Introduction: Several cities in Malaysia have established plans to reduce their CO2 emissions in addition to Malaysia submitting a Nationally Determined Contribution to reduce its carbon intensity (against GDP) by 45% in 2030 compared to 2005. Meeting these emissions reduction goals will require ajoint effort between governments industries and corporations at different scales and across sectors.<br/>Methods: In collaboration with national and sub-national stakeholders we developed and used a global integrated assessment model to explore emissions mitigation pathways in Malaysia and Kuala Lumpur. Guided by current climate action plans we created a suite of scenarios to reflect uncertainties in policy ambition level of adoption and implementation for reaching carbon neutrality. Through iterative engagement with all parties we refined the scenarios and focus of the analysis to best meet the stakeholders’ needs.<br/>Results: We found that Malaysia can reduce its carbon intensity and reach carbon neutrality by 2050 and that action in Kuala Lumpur can play a significant role. Decarbonization of the power sector paired with extensive electrification energy efficiency improvements in buildings transportation and industry and the use of advanced technologies such as hydrogen and carbon capture and storage will be Major drivers to mitigate emissions with carbon dioxide removal strategies being key to eliminate residual emissions.<br/>Discussion: Our results suggest a hopeful future for Malaysia’s ability to meet its climate goals recognizing that there may be technological social and financial challenges along the way. This study highlights the participatory process in which stakeholders contributed to the development of the model and guided the analysis as well as insights into Malaysia’s decarbonization potential and the role of multilevel governance.
Laboratory Evaluation of Cyclic Underground Hydrogen Storage in the Temblor Sandstone of the San Joaquin Basin, California
Jun 2025
Publication
Underground Hydrogen Storage (UHS) in depleted oil and gas reservoirs could provide a cost-effective solution to balance seasonal fluctuations in renewable energy generation. However data and knowledge on UHS at subsurface conditions are limited so it is difficult to estimate how effective this type of storage could be. In this study we perform high pressure experiment to measure the effectiveness of cyclic hydrogen (H2) storage in a specimen of Temblor sandstone retrieved from the San Joaquin Basin of California. Our experiment mimics reservoir pressure conditions to measure H2-brine relative permeability and fluid-rock interactions over the course of ten charging and discharging cycles. Initial gas breakthrough occurred at 15 % to 25 % H2 saturation in the specimen with 3 % NaCl brine as the resident fluid. Continuing injecting to 4 pore volumes (PV) of H2 yielded an asymptotic H2 saturation of 38 % to 41 % a level often referred to as the irreducible gas saturation based on two-phase flow. The boundary condition in this study mimics the near wellbore region which experiences bidirectional H2 flow. This bi-directional flow led to evaporative drying of the specimen resulting in 94 % H2 saturation at the end of 10th cycle. This indicates that cyclic flow and evaporative drying can lead to more efficient reservoir storage where a larger fraction of the reservoir porosity is usable to store H2. The produced gas stream consisted of H2 mixed with 8 % to 22 % H2O indicating formation dry-out by evaporation. Meanwhile produced water chemistry indicated calcite and silicate dissolution with calcite sourced from fossil fragments. This led to a loss of cementation and weakened the rock sample. Combined our results indicate dry-out compaction increased H2 saturation rock weakening and permeability loss during cyclic UHS. Overall we anticipate that the combined effects should lead to higher than anticipated UHS storage efficiency per volume of sandstone reservoir rock.
Machine Learning Applications in Gray, Blue, and Green Hydrogen Production: A Comprehensive Review
May 2025
Publication
Hydrogen is increasingly recognized as a key contributor to a low-carbon energy future and machine learning (ML) is emerging as a valuable tool to optimize hydrogen production processes. This review presents a comprehensive analysis of ML applications across various hydrogen production pathways including gray blue and green hydrogen with additional insights into pink turquoise white and black/brown hydrogen. A total of 51 peer-reviewed studies published between 2012 and 2025 were systematically reviewed. Among these green hydrogen—particularly via water electrolysis and biomass gasification—received the most attention reflecting its central role in decarbonization strategies. ML algorithms such as artificial neural networks (ANNs) random forest (RF) and gradient boosting regression (GBR) have been widely applied to predict hydrogen yield optimize operational conditions reduce emissions and improve process efficiency. Despite promising results real-world deployment remains limited due to data sparsity model integration challenges and economic barriers. Nonetheless this review identifies significant opportunities for ML to accelerate innovation across the hydrogen value chain. By highlighting trends key methodologies and current gaps this study offers strategic guidance for future research and development in intelligent hydrogen systems aimed at achieving sustainable and cost-effective energy solutions.
Comparative Analysis of Hydrogen-Ammonia Blends and Jet Fuels in Gas Turbine Combustors Using Well-stirred Reactor Models
Jun 2025
Publication
This study compares hydrogen ammonia-hydrogen fuel blends and Jet-A2 fuel in gas turbine combustors using a well-stirred reactor model and validated MATLAB library H2ools to assess flame temperature pollutant generation combustion stability and thermal efficiency. The aim is to address a significant deficiency in existing research which frequently lacks standardized turbine-related comparisons among new zero-carbon fuels. Quantitative data indicate that pure hydrogen attains the maximum adiabatic flame temperature (2552 Kelvin) laminar flame speed (7.73 meters per second) and heat generation (9.02 × 1010 watts per cubic meter) while also demonstrating increased nitrogen oxide emissions (up to 6400 parts per million). Jet-A2 exhibits reduced flame temperatures (2429 Kelvin) and minimal nitrogen oxide emissions (1308 parts per million) whereas a 50% ammonia-hydrogen blend yields the maximum nitrogen oxide output (7022 parts per million) attributable to the nitrogen content in ammonia. Hydrogen generates the minimal nitrogen oxide emissions per unit of energy output—approximately 0.1 grams per kilowatt-hour at a residence time of five milliseconds. This study integrates reactor-level study with a high-fidelity modeling tool providing insights for combustor design fuel selection and emissions control strategies in low-carbon aircraft and power systems.
Diverse Decarbonization Pathways under Near Cost-optimal Futures
Sep 2024
Publication
Energy system optimization models offer insights into energy and emissions futures through least-cost optimization. However real-world energy systems often deviate from deterministic scenarios necessitating rigorous uncertainty exploration in macro-energy system modeling. This study uses modeling techniques to generate diverse near cost-optimal net-zero CO2 pathways for the United States’ energy system. Our findings reveal consistent trends across these pathways including rapid expansion of solar and wind power generation substantial petroleum use reductions near elimination of coal combustion and increased end-use electrification. We also observe varying deployment levels for natural gas hydrogen direct air capture of CO2 and synthetic fuels. Notably carbon-captured coal and synthetic fuels exhibit high adoption rates but only in select decarbonization pathways. By analyzing technology adoption correlations we uncover interconnected technologies. These results demonstrate that diverse pathways for decarbonization exist at comparable system-level costs and provide insights into technology portfolios that enable near cost-optimal net-zero CO2 futures.
Thermoeconomic Analysis of a Integrated Membrane Reactor and Carbon Dioxide Capture System Producing Decarbonized Hydrogen
Jan 2025
Publication
In this study a novel thermo-economic analysis on a membrane reactor adopted to generate hydrogen coupled to a carbon-dioxide capture system is proposed. Exergy destruction fuel and environmental as well as pur chased equipment costs have been accounted to estimate the cost of hydrogen production in the aforementioned integrated plant. It has been found that the integration of the CO2 capture system with the membrane reactor is responsible for the reduction of the hydrogen production cost by 12 % due to the decrease in environmental penalty cost. In addition the effects of operating parameters (steam-to-carbo ratio and biogas temperature) on the hydrogen production cost are investigated. Hence this work demonstrates that the latter can be decreased by approximately 2 $/kgH2 when steam to carbon ratio increases from 1.5 to 4. The analyses reveal that steam-tocarbo ratio increases exergy destruction cost affecting consequently also the hydrogen production cost. How ever from a thermodynamic point of view it enhances the hydrogen production in the membrane reactor mutually lowering the hydrogen production cost. It has been also estimated that a decrease in the biogas inlet temperature from 450 to 400◦C can reduce the hydrogen production cost by 7 %. This study demonstrates that the fuel cost is a major economic parameter affecting commercialization of hydrogen production while exergy destruction and environmental costs are also significant factors in determining the hydrogen production cost.
Innovative Strategies for Combining Solar and Wind Energy with Green Hydrogen Systems
Oct 2024
Publication
The integration of wind and solar energy with green hydrogen technologies represents an innovative approach toward achieving sustainable energy solutions. This review examines state-ofthe-art strategies for synthesizing renewable energy sources aimed at improving the efficiency of hydrogen (H2 ) generation storage and utilization. The complementary characteristics of solar and wind energy where solar power typically peaks during daylight hours while wind energy becomes more accessible at night or during overcast conditions facilitate more reliable and stable hydrogen production. Quantitatively hybrid systems can realize a reduction in the levelized cost of hydrogen (LCOH) ranging from EUR 3.5 to EUR 8.9 per kilogram thereby maximizing the use of renewable resources but also minimizing the overall H2 production and infrastructure costs. Furthermore advancements such as enhanced electrolysis technologies with overall efficiencies rising from 6% in 2008 to over 20% in the near future illustrate significant progress in this domain. The review also addresses operational challenges including intermittency and scalability and introduces system topologies that enhance both efficiency and performance. However it is essential to consider these challenges carefully because they can significantly impact the overall effectiveness of hydrogen production systems. By providing a comprehensive assessment of these hybrid systems (which are gaining traction) this study highlights their potential to address the increasing global energy demands. However it also aims to support the transition toward a carbon-neutral future. This potential is significant because it aligns with both environmental goals and energy requirements. Although challenges remain the promise of these systems is evident.
Research Goals for Minimizing the Cost of CO2 Capture when Using Steam Methane Reforming for Hydrogen Production
Nov 2024
Publication
This paper presents a techno-economic assessment of adding state-of-the-art solvent-based CO2 capture technologies to greenfield steam methane reforming (SMR)-based H2 production plants and quantifies the impacts of improvements in CO2 capture technology. Current conventional capture technologies are reviewed and future technologies in intermediate and long-term scenarios are analyzed. The results show that adding significantly more efficient solvent-based capture technologies leads to an equivalent rate of natural gas consumption as that of a conventional SMR plant without capture despite capturing most of the CO2 and producing the same amount of H2. Overall improvements in reboiler duty and reductions in capital costs can significantly reduce the cost of H2 production and cost of capture. Particularly the reboiler duty of pre-combustion capture and the capital cost of post-combustion capture have the greatest impact. Based on the results research goals are suggested. Solvent development is recommended—particularly pre-combustion solvents—for reducing the reboiler duties and process schemes to reduce the capital costs. Costlier but more efficient solvents can be considered. A sensitivity analysis using natural gas price shows that technological improvements can reduce the impacts of high natural gas prices. The degree of economic feasibility of CO2 capture increases with improvements to the capture technology.
Progress in Carbon Capture and Impurities Removal for High Purity Hydrogen Production from Biomass Thermochemical Conversion
Nov 2024
Publication
Renewable hydrogen production from biomass thermochemical conversion is an emerging technology to reduce fossil fuel consumptions and carbon emissions. Biomass-derived hydrogen can be produced by pyrolysis gasification alkaline thermal treatment etc. However the removal of impurities from biomass thermochemical conversion products to improve hydrogen purity is currently technical bottleneck. It is important to assess and investigate the types and properties of impurities the difficulty of separation and the impact on downstream utilization of hydrogen in the biomass-derived hydrogen production process. The key objectives of this comprehensive review are: (1) to reveal the current status and necessity of developing biomass-derived hydrogen production; (2) to evaluate the types devices and impurities distribution of biomass thermochemical conversion; (3) to explore the formation pathways and removal technologies of typical impurities of tar CO2 sulfides and nitrides in hydrogen production process; and (4) to propose future insights on the separation technologies of typical impurities to promote the gradual substitution of biomass-derived hydrogen for fossil-derived energy.
Hydrogen and Fuel Cell Technology: Progress, Challenges, and Future Directions
Sep 2012
Publication
The Department of Energy’s (DOE) hydrogen and fuel cell activities are presented focussing on key targets and progress. Recent results on the cost durability and performance of fuel cells are discussed along with the status of hydrogen-related technologies and cross-cutting activities. DOE has deployed fuel cells in key early markets including backup power and forklifts. Recent analyses show that fuel cell electric vehicles (FCEVs) are among the most promising options to reduce greenhouse gas emissions and petroleum use. Preliminary analysis also indicates that the total cost of ownership of FCEVs will be comparable to other advanced vehicle and fuel options.
Roadmap to Reach Global Net Zero Emissions for Developing Regions by 2085
Jan 2025
Publication
As climate change intensifies determining a developing region’s role in achieving net-zero emissions worldwide is crucial. However regional efforts considering historical emissions remain underexplored. Here we assess energy system changes technology adoption and investments needed for developing regions including five major- and minor-emitting nations. Our analysis using an integrated assessment model shows a large gap in regional efforts toward global net-zero emissions stemming from the necessary shift of energy systems to low-carbon resources. The use of new technologies like electric vehicles hydrogen and carbon capture varies by region with the highest adoption required between 2020 and 2030. Financing this shift needs an average gross domestic product (GDP) investment rise of 0.464% in minor-emitting regions and up to 2.1% in major-emitting regions by 2085. Our results could guide policies and support setting quantifiable targets for developing nations. The findings are key to facilitating strategic technology use and finance mobilization to achieve a carbon-neutral future.
Enhancing Safety and Operation of Hydrogen Fueling Stations: A Model-based Method for Complex Failure Scenario Analysis
Jun 2025
Publication
As a zero-emission fuel hydrogen provides a promising solution with significant potential to meet the increasing demand for clean energy alternatives. Hydrogen fueling stations are essential infrastructure for the commercialization of hydrogen fuel cells but the flammability of hydrogen poses safety challenges throughout its lifecycle. Past incidents highlight the need for robust risk assessments starting with comprehensive hazard identification and failure scenario analysis.<br/>This paper proposes using Multilevel Flow Modelling (MFM) a functional modeling method integrated with reasoning capability to support safety evaluations. MFM enables the structured representation of system functions and supports tasks such as fault diagnosis and hazard analysis. Previously applied in nuclear offshore and chemical systems MFM is here used to model a liquid hydrogen fueling station. This paper demonstrates that a developed MFM model identifies failure scenarios related to hydrogen leaks overpressure and operational reliability issues.<br/>This paper conducts a comparison between MFM and traditional methods FMEA and FTA and demonstrates MFM's strength in handling the key challenges rooted from complex failure interactions. Results suggest MFM is complementary to traditional methods and can enhance risk assessments. MFM also contributes to digitalization in safety assessment and monitoring systems ultimately improving hydrogen fueling station reliability and safety.
Low-temperature Water Electrolysis: Fundamentals, Progress, and New Strategies
May 2022
Publication
Water electrolysis is a promising technology for sustainable energy conversion and storage of intermittent and fluctuating renewable energy sources and production of high-purity hydrogen for fuel cells and various industrial applications. Low-temperature electrochemical water splitting technologies include alkaline proton exchange membrane and anion exchange membrane water electrolyses which normally consist of two coupled half reactions: the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Despite the advances over decades formidable challenges still exist and hinder the practical application of large-scale energy-efficient and economically viable water electrolysis including large energy penalty sluggish kinetics high cost of precious metal based electrocatalysts possible H2/O2 gas crossover difficulty in storage and distribution of H2. Herein we first briefly introduce the fundamentals of water electrolysis summarize the recommended standardized electrochemical characterization protocols and demonstrate the metrics and key performance indicators that are used to evaluate the performances of HER and OER electrocatalysts and electrolyser cells. Then we present six new strategies to mitigate the technical challenges in conventional water electrolysis. These emerging strategies for disruptive innovation of water electrolysis technology include overall water electrolysis based on bifunctional nonprecious electrocatalysts (or pre-catalysts) magnetic field-assisted water electrolysis decoupled water electrolysis hybrid water electrolysis acid/alkaline asymmetric electrolyte electrolysis and tandem water electrolysis. Finally the remaining challenges perspectives and future directions are discussed. This review will provide guidance and inspire more endeavours to deepen the mechanistic understanding and advance the development of water electrolysis.
Everything About Hydrogen Podcast: Resilience
Jul 2023
Publication
The EAH team discuss Nataliya’s plan for a green Ukraine including working with the current government on the Hydrogen Road Map. We also get another example of incredible Ukrainian resilience and discuss its importance for the current and future energy system.
The podcast can be found on their website.
The podcast can be found on their website.
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