United States
Repurposing Pipelines for Hydrogen: Legal and Policy Considerations
Nov 2022
Publication
As the world looks to implement the Energy Transition repurposing existing fossil fuel infrastructure to produce or distribute “clean” energy will be critical. The most promising is using natural gas pipelines for moving hydrogen. This is the cheapest and fastest method of transport and reducing the cost of transporting hydrogen is a key step in making it economically viable. However while there are technical challenges the greater challenge is in the legal arena. This paper seeks to outline the numerous legal — treaty statutory and contractual — and regulatory obstacles to repurposing natural gas pipelines for hydrogen transport. Gas pipelines exist in a complex microclimate of international public and private law and domestic law and contracts. Ownership is often layered and tangled; financing doubly so; and myriad state interests compound the private interests including national security concerns energy supply imperatives and geopolitical balance. State aid — investment subsidies and tax breaks — may encumber the project with additional legal obligations. And the contracts that control the development of a pipeline project may inject further legal complexity such as dispute mediation procedures and fora and applicable law. This paper seeks to map all the likely areas of future conflict or difficulty so that work on developing the requisite legal regime and remedies to permit use of natural gas pipelines for hydrogen transport can begin now. For policy and lawmakers as well as the private sector evaluating these known unknowns is a good starting point for reconsidering legislation regulation contracts and project risk in preparation for the future probability of hydrogen pipelines.
Risk of the Hydrogen Economy for Atmospheric Methane
Dec 2022
Publication
Hydrogen (H2) is expected to play a crucial role in reducing greenhouse gas emissions. However hydrogen losses to the atmosphere impact atmospheric chemistry including positive feedback on methane (CH4) the second most important greenhouse gas. Here we investigate through a minimalist model the response of atmospheric methane to fossil fuel displacement by hydrogen. We find that CH4 concentration may increase or decrease depending on the amount of hydrogen lost to the atmosphere and the methane emissions associated with hydrogen production. Green H2 can mitigate atmospheric methane if hydrogen losses throughout the value chain are below 9 ± 3%. Blue H2 can reduce methane emissions only if methane losses are below 1%. We address and discuss the main uncertainties in our results and the implications for the decarbonization of the energy sector.
Fission Battery Markets and Economic Requirements
Oct 2022
Publication
Fission Batteries (FBs) are nuclear reactors for customers with heat demands less than 250 MWt—replacing oil and natural gas in a low-carbon economy. Individual FBs would have outputs between 5 and 30 MWt. The small FB size has two major benefits: (1) the possibility of mass production and (2) ease of transport and leasing with return of used FBs to factory for refurbishing and reuse. Comparatively these two features are lacking in larger conventional reactors. Larger reactors are not transportable and thus can’t obtain the manufacturing economics possible with mass production or the operational advantages of returning the FB to the factory after use. Leasing places the regulatory maintenance and fuel-cycle burden on the leasing company that is minimized by large-fleet operations of identical units. The markets and economic requirements for FBs were examined. The primary existing markets are industrial biofuels off-grid electricity and container ships. Two major future markets were identified—advanced biofuels and hydrogen. In a low-carbon world the competitive price range for heat is $20–50/MWh ($6–15/million BTU) and $70–115/MWh for non-grid electricity. The primary competition in these sectors is likely to be biofuels and hydrogen produced using alternative energy sources—grid electricity is non-competitive. Larger users of energy have alternative low-carbon energy choices including modular nuclear reactors and fossil fuels with carbon capture and sequestration (CCS).
Challenges Toward Achieving a Successful Hydrogen Economy in the US: Potential End-use and Infrastructure Analysis to the Year 2100
Jul 2022
Publication
Fossil fuels continue to exacerbate climate change due to large carbon emissions resulting from their use across a number of sectors. An energy transition away from fossil fuels seems inevitable and energy sources such as renewables and hydrogen may provide a low carbon alternative for the future energy system particularly in large emitting nations such as the United States. This research quantifies and maps potential hydrogen fuel distribution pathways for the continental US reflecting technological changes barriers to deployment and end-use-cases from 2020 to 2100 clarifying the potential role of hydrogen in the US energy transition. The methodology consists of two parts a linear optimization of the global energy system constrained by carbon reduction targets and system cost followed by a projection of hydrogen infrastructure development. Key findings include the emergence of trade pattern diversification with a greater variety of end-uses associated with imported fuels and greater annual hydrogen consumption over time. Further sensitivity analysis identified the influence of complementary technologies including nuclear power and carbon capture and storage technologies. We conclude that hydrogen penetration into the US energy system is economically viable and can contribute toward achieving Paris Agreement and more aggressive carbon reduction targets in the future.
The Hydrogen Economy and Jobs of the Future
Nov 2018
Publication
Growth in the hydrogen and fuel cell industries will lead to vast new employment opportunities and these will be created in a wide variety of industries skills tasks and earnings. Many of these jobs do not currently exist and do not have occupational titles defined in official classifications. In addition many of these jobs require different skills and education than current jobs and training requirements must be assessed so that this rapidly growing part of the economy has a sufficient supply of trained and qualified workers. We discuss the current hydrogen economy and technologies. We then identify by occupational titles the new jobs that will be created in the expanding hydrogen/fuel cell economy estimate the average US salary for each job identify the minimum educational attainment required to gain entry into that occupation and specify the recommended university degree for the advanced educational requirements. We provide recommendations for further research.
Hydrogen Storage Assessment in Depleted Oil Reservoir and Saline Aquifer
Oct 2022
Publication
Hydrogen (H2 ) is an attractive energy carrier to move store and deliver energy in a form that can be easily used. Field proven technology for underground hydrogen storage (UHS) is essential for a successful hydrogen economy. Options for this are manmade caverns salt domes/caverns saline aquifers and depleted oil/gas fields where large quantities of gaseous hydrogen have been stored in caverns for many years. The key requirements intrinsic of a porous rock formation for seasonal storage of hydrogen are: adequate capacity ability to contain H2 capability to inject/extract high volumes of H2 and a reliable caprock to prevent leakage. We have carefully evaluated a commercial non-isothermal compositional gas reservoir simulator and its suitability for hydrogen storage and withdrawal from saline aquifers and depleted oil/gas reservoirs. We have successfully calibrated the gas equation of state model against published laboratory H2 density and viscosity data as a function of pressure and temperature. Comparisons between the H2 natural gas and CO2 storage in real field models were also performed. Our numerical models demonstrated more lateral spread of the H2 when compared to CO2 and natural gas with a need for special containment in H2 projects. It was also observed that the experience with CO2 and natural gas storage cannot be simply replicated with H2 .
Hydrogen Production from Water Electrolysis: Role of Catalysts
Feb 2021
Publication
As a promising substitute for fossil fuels hydrogen has emerged as a clean and renewable energy. A key challenge is the efcient production of hydrogen to meet the commercial-scale demand of hydrogen. Water splitting electrolysis is a promising pathway to achieve the efcient hydrogen production in terms of energy conversion and storage in which catalysis or electrocatalysis plays a critical role. The development of active stable and low-cost catalysts or electrocatalysts is an essential prerequisite for achieving the desired electrocatalytic hydrogen production from water splitting for practical use which constitutes the central focus of this review. It will start with an introduction of the water splitting performance evaluation of various electrocatalysts in terms of activity stability and efciency. This will be followed by outlining current knowledge on the two half-cell reactions hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in terms of reaction mechanisms in alkaline and acidic media. Recent advances in the design and preparation of nanostructured noble-metal and non-noble metal-based electrocatalysts will be dis‑ cussed. New strategies and insights in exploring the synergistic structure morphology composition and active sites of the nanostructured electrocatalysts for increasing the electrocatalytic activity and stability in HER and OER will be highlighted. Finally future challenges and perspectives in the design of active and robust electrocatalysts for HER and OER towards efcient production of hydrogen from water splitting electrolysis will also be outlined.
A Study into Proton Exchange Membrane Fuel Cell Power and Voltage Prediction using Artificial Neural Network
Sep 2022
Publication
Polymer Electrolyte Membrane fuel cell (PEMFC) uses hydrogen as fuel to generate electricity and by-product water at relatively low operating temperatures which is environmentally friendly. Since PEMFC performance characteristics are inherently nonlinear and related predicting the best performance for the different operating conditions is essential to improve the system’s efficiency. Thus modeling using artificial neural networks (ANN) to predict its performance can significantly improve the capabilities of handling multi-variable nonlinear performance of the PEMFC. This paper predicts the electrical performance of a PEMFC stack under various operating conditions. The four input terms for the 5 W PEMFC include anode and cathode pressures and flow rates. The model performances are based on ANN using two different learning algorithms to estimate the stack voltage and power. The models have shown consistently to be comparable to the experimental data. All models with at least five hidden neurons have coefficients of determination of 0.95 or higher. Meanwhile the PEMFC voltage and power models have mean squared errors of less than 1 × 10−3 V and 1 × 10−3 W respectively. Therefore the model results demonstrate the potential use of ANN into the implementation of such models to predict the steady state behavior of the PEMFC system (not limited to polarization curves) for different operating conditions and help in the optimization process for achieving the best performance of the system.
Everything About Hydrogen Podcast: Using Hydrogen to Decarbonise Steel Manufacturing
Mar 2022
Publication
Hydrogen could be used in many hard-to-decarbonize sectors. Foremost amongst them is the steel manufacturing industry. On this episode of EAH we speak with Dr. Martin Pei Executive Vice President and CTO of SSAB and the first Chairman of the Board for Hybrit Development AB. SSAB is a global steel company with a leading position in high-strength steels and related services. Together with their partners LKAB and Vattenfall SSAB are making a unique joint effort to change the Swedish iron and steel industry fundamentally. With HYBRIT technology SSAB aims to be the first steel company in the world to bring fossil-free steel to the market already in 2026 and largely eliminate carbon dioxide emissions from the company's own operations as soon as 2030.
The podcast can be found on their website.
The podcast can be found on their website.
Experimental Investigation of Stress Corrosion on Supercritical CO2 Transportation Pipelines Against Leakage for CCUS Applications
Nov 2022
Publication
Carbon Capture Utilization and Storage (CCUS) is one of the key technologies that will determine how humans address global climate change. For captured CO2 in order to avoid the complications associated with two-phase flow most carbon steel pipelines are operated in the supercritical state on a large scale. A pipeline has clear Stress Corrosion Cracking (SCC) sensitivity under the action of stress and corrosion medium which will generally cause serious consequences. In this study X70 steel was selected to simulate an environment in the process of supercritical CO2 transportation by using high-temperature high-pressure Slow Strain Rate Tensile (SSRT) tests and high-temperature high-pressure electrochemical test devices with different O2 and SO2 contents. Studies have shown that 200 ppm SO2 shows a clear SCC sensitivity tendency which is obvious when the SO2 content reaches 600 ppm. The SCC sensitivity increases with the increase of SO2 concentration but the increase amplitude decreases. With the help of advanced microscopic characterization techniques such as scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) through the analysis of fracture and side morphology the stress corrosion mechanism of a supercritical CO2 pipeline containing SO2 and O2 impurities was obtained by hydrogen embrittlement fracture characteristics. With the increase of SO2 content the content of Fe element decreases and the corrosion increases demonstrating that SO2 plays a leading role in electrochemical corrosion. This study further strengthens the theoretical basis of stress corrosion of supercritical CO2 pipelines plays an important role in preventing leakage of supercritical CO2 pipelines and will provide guidance for the industrial application of CCUS.
Everything About Hydrogen Podcast: Decarbonizing Steel and Industrial Manufacturing
May 2022
Publication
H2 Green Steel was founded in 2020 with the aim to build a large-scale green steel production in northern Sweden. H2 Green Steel is on a mission to undertake the global steel industry’s greatest ever technological shift. By 2024 H2 Green Steel will be in production at their Boden site and by 2030 will produce five million tonnes of green steel annually. Vargas co-founder and a major shareholder in Northvolt is also H2 Green Steel’s founder and largest shareholder. The EAH team speaks with Kajsa Ryttberg-Wallgren head of the Hydrogen Business Unit at H2 Green Steel.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Global Energy Majors in the Hydrogen Space
Jul 2022
Publication
On today’s episode of Everything About Hydrogen we are speaking with Paul Bogers Vice President for Hydrogen at Shell. As a company Shell needs no introduction but the company’s work and investments in the hydrogen space make it a global leader in the energy transition especially when it comes to the hydrogen component. Paul is amongst the executives at Shell that are working to bring their hydrogen vision to fruition and it is great to have him with us on the show today.
The podcast can be found on their website
The podcast can be found on their website
Time-phased Geospatial Siting Analysis for Renewable Hydrogen Production Facilities under a Billion-kilogram-scale Build-out using California as an Example
Jun 2022
Publication
For renewable hydrogen to be a significant part of the future decarbonized energy and transportation sectors a rapid and massive build-out of hydrogen production facilities will be needed. This paper describes a geospatial modeling approach to identifying the optimal locations for renewable hydrogen fuel production throughout the state of California based on least-cost generation and transport. This is accomplished by (1) estimating and projecting California renewable hydrogen demand scenarios through the year 2050 (2) identifying feedstock locations (3) excluding areas not suitable for development and (4) selecting optimal site locations using commercial geospatial modeling software. The findings indicate that there is a need for hundreds of new renewable hydrogen production facilities in the decades preceding the year 2050. In selecting sites for development feedstock availability by technology type is the driving factor."
Can Industrial-Scale Solar Hydrogen Supplied from Commodity Technologies Be Cost Competitive by 2030?
Sep 2020
Publication
Expanding decarbonization efforts beyond the power sector are contingent on cost-effective production of energy carriers like H2 with near-zero life-cycle carbon emissions. Here we assess the levelized cost of continuous H2 supply (95% availability) at industrial-scale quantities (100 tonnes/day) in 2030 from integrating commodity technologies for solar photovoltaics electrolysis and energy storage. Our approach relies on modeling the least-cost plant design and operation that optimize component sizes while adhering to hourly solar availability production requirements and component inter-temporal operating constraints. We apply the model to study H2 production costs spanning the continental United States and through extensive sensitivity analysis explore system configurations that can achieve $2.5/kg levelized costs or less for a range of plausible 2030 technology projections at high-irradiance locations. Notably we identify potential sites and system configurations where PV-electrolytic H2 could substitute natural gas-derived H2 at avoided CO2 costs (%$120/ton) similar to the cost of deploying carbon capture and sequestration.
Adapted Tube Cleaning Practices to Reduce Particulate Contamination at Hydrogen Fueling Stations
Sep 2017
Publication
The higher rate of component failure and downtime during initial operation in hydrogen stations is not well understood. The National Renewable Energy Laboratory (NREL) has been collecting failed components from retail and research hydrogen fuelling stations in California and Colorado and analyzing them using an optical zoom and scanning electron microscope. The results show stainless steel metal particulate contamination. While it is difficult to definitively know the origin of the contaminants a possible source of the metal particulates is improper tube cleaning practices. To understand the impact of different cleaning procedures NREL performed an experiment to quantify the particulates introduced from newly cut tubes. The process of tube cutting threading and bevelling which is performed most often during station fabrication is shown to introduce metal contaminants and thus is an area that could benefit from improved cleaning practices. This paper shows how these particulates can be reduced which could prevent station downtime and costly repair. These results are from the initial phase of a project in which NREL intends to further investigate the sources of particulate contamination in hydrogen stations.
Effect of Wind on Cryogenic Hydrogen Dispersion from Vent Stacks
Sep 2021
Publication
Liquid hydrogen vent stacks often release hydrogen for example due to pressure relief from an underutilized tank boiling off hydrogen or after hydrogen delivery and transfer (trucks often depressurize through the tank vent stack to meet pressure regulations for on-road transport).<br/>A rapid release of cryogenic hydrogen through a vent stack will condense moisture from the entrained air forming a visible cloud. It is often assumed that the extent of the cold hydrogen is concurrent with the cloud. In this work a laser-based Raman scattering diagnostic was used to map out the hydrogen location during a series of vent stack release experiments. A description of the diagnostic instrument is given followed by a comparison of hydrogen signals to the visible cloud for releases through a liquid hydrogen vent stack. A liquid hydrogen pump was used to vary the flowrate of hydrogen through the vent stack and tests were performed under low and high wind conditions as well as low and high humidity conditions. The hydrogen was observed only where the condensed moisture was located regardless of the humidity level or wind. These measurements are being used to validate models such as those included in Sanda’s HyRAM toolkit and inform safety codes and standards.
The Renewable Hydrogen–Methane (RHYME) Transportation Fuel: A Practical First Step in the Realization of the Hydrogen Economy
Feb 2022
Publication
The permanent introduction of green hydrogen into the energy economy would require that a discriminating selection be made of its use in the sectors where its value is optimal in terms of relative cost and life cycle reduction in carbon dioxide emissions. Consequently hydrogen can be used as an energy storage medium when intermittent wind and solar power exceed certain penetration in the grid likely above 40% and in road transportation right away to begin displacing gasoline and diesel fuels. To this end the proposed approach is to utilize current technologies represented by PHEV in light-duty and HEV in heavy-duty vehicles where a high-performance internal combustion engine is used with a fuel comprised of 15–20% green hydrogen and 85–89% green methane depending on vehicle type. This fuel designated as RHYME takes advantage of the best attributes of hydrogen and methane results in lower life cycle carbon dioxide emissions than BEVs or FCEVs and offers a cost-effective and pragmatic approach both locally as well as globally in establishing hydrogen as part of the energy economy over the next ten to thirty years.
Boosting Photocatalytic Hydrogen Production from Water by Photothermally Induced Biphase Systems
Feb 2021
Publication
Solar-driven hydrogen production from water using particulate photocatalysts is considered the most economical and effective approach to produce hydrogen fuel with little environmental concern. However the efficiency of hydrogen production from water in particulate photocatalysis systems is still low. Here we propose an efficient biphase photocatalytic system composed of integrated photothermal–photocatalytic materials that use charred wood substrates to convert liquid water to water steam simultaneously splitting hydrogen under light illumination without additional energy. The photothermal–photocatalytic system exhibits biphase interfaces of photothermally-generated steam/photocatalyst/hydrogen which significantly reduce the interface barrier and drastically lower the transport resistance of the hydrogen gas by nearly two orders of magnitude. In this work an impressive hydrogen production rate up to 220.74 μmol h−1 cm−2 in the particulate photocatalytic systems has been achieved based on the wood/CoO system demonstrating that the photothermal–photocatalytic biphase system is cost-effective and greatly advantageous for practical applications.
Role of Hydrogen in a Low-Carbon Electric Power System: A Case Study
Jan 2021
Publication
The European Union set a 2050 decarbonization target in the Paris Agreement to reduce carbon emissions by 90–95% relative to 1990 emission levels. The path toward achieving those deep decarbonization targets can take various shapes but will surely include a portfolio of economy-wide low-carbon energy technologies/options. The growth of the intermittent renewable power sources in the grid mix has helped reduce the carbon footprint of the electric power sector. Under the need for decarbonizing the electric power sector we simulated a low-carbon power system. We investigated the role of hydrogen for future electric power systems under current cost projections. The model optimizes the power generation mix economically for a given carbon constraint. The generation mix consists of intermittent renewable power sources (solar and wind) and dispatchable gas turbine and combined cycle units fuelled by natural gas with carbon capture and sequestration as well as hydrogen. We created several scenarios with battery storage options pumped hydro hydrogen storage and demand-side response (DSR). The results show that energy storage replaces power generation and pumped hydro entirely replaces battery storage under given conditions. The availability of pumped hydro storage and demand-side response reduced the total cost as well as the combination of solar photovoltaic and pumped hydro storage. Demand-side response reduces relatively costly dispatchable power generation reduces annual power generation halves the shadow carbon price and is a viable alternative to energy storage. The carbon constrain defines the generation mix and initializes the integration of hydrogen (H2). Although the model rates power to gas with hydrogen as not economically viable in this power system under the given conditions and assumptions hydrogen is important for hard-to-abate sectors and enables sector coupling in a real energy system. This study discusses the potential for hydrogen beyond this model approach and shows the differences between cost optimization models and real-world feasibility.
A Manganese Hydride Molecular Sieve for Practical Hydrogen Storage Under Ambient Conditions
Dec 2018
Publication
A viable hydrogen economy has thus far been hampered by the lack of an inexpensive and convenient hydrogen storage solution meeting all requirements especially in the areas of long hauls and delivery infrastructure. Current approaches require high pressure and/or complex heat management systems to achieve acceptable storage densities. Herein we present a manganese hydride molecular sieve that can be readily synthesized from inexpensive precursors and demonstrates a reversible excess adsorption performance of 10.5 wt% and 197 kgH2 m-3 at 120 bar at ambient temperature with no loss of activity after 54 cycles. Inelastic neutron scattering and computational studies confirm Kubas binding as the principal mechanism. The thermodynamically neutral adsorption process allows for a simple system without the need for heat management using moderate pressure as a toggle. A storage material with these properties will allow the DOE system targets for storage and delivery to be achieved providing a practical alternative to incumbents such as 700 bar systems which generally provide volumetric storage values of 40 kgH2 m-3 or less while retaining advantages over batteries such as fill time and energy density. Reasonable estimates for production costs and loss of performance due to system implementation project total energy storage costs roughly 5 times cheaper than those for 700 bar tanks potentially opening doors for increased adoption of hydrogen as an energy vector.
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