United States
Magnesium-Based Hydrogen Storage Alloys: Advances, Strategies, and Future Outlook for Clean Energy Applications
May 2024
Publication
Magnesium-based hydrogen storage alloys have attracted significant attention as promising materials for solid-state hydrogen storage due to their high hydrogen storage capacity abundant reserves low cost and reversibility. However the widespread application of these alloys is hindered by several challenges including slow hydrogen absorption/desorption kinetics high thermodynamic stability of magnesium hydride and limited cycle life. This comprehensive review provides an in-depth overview of the recent advances in magnesium-based hydrogen storage alloys covering their fundamental properties synthesis methods modification strategies hydrogen storage performance and potential applications. The review discusses the thermodynamic and kinetic properties of magnesium-based alloys as well as the effects of alloying nanostructuring and surface modification on their hydrogen storage performance. The hydrogen absorption/desorption properties of different magnesium-based alloy systems are compared and the influence of various modification strategies on these properties is examined. The review also explores the potential applications of magnesium-based hydrogen storage alloys including mobile and stationary hydrogen storage rechargeable batteries and thermal energy storage. Finally the current challenges and future research directions in this field are discussed highlighting the need for fundamental understanding of hydrogen storage mechanisms development of novel alloy compositions optimization of modification strategies integration of magnesium-based alloys into hydrogen storage systems and collaboration between academia and industry.
Designing an Inherently Safe H2 Infrastructure: Combining Analytical, Experimental, and Numerical Investigations to Optimize H2 Refuelling Stations Safety by Passive Mitigation
Sep 2023
Publication
Natural ventilation is a well-known passive mitigation method to limit hydrogen build-up in confined spaces in case of accidental release [1-3]. In most cases a basic design of H2 infrastructure is adopted and vents installed for natural ventilation are adjusted according to safety targets and constraints of the considered structure. With the growing H2 mobility market the demand for H2 refueling infrastructure in our urban environment is on the rise. In order to meet both safety requirements and societal acceptance the design of such infrastructure is becoming more important. In this study a novel design concept is proposed for the hydrogen refueling station (HRS) by modifying physical structure while keeping safety consideration as the top priority of the concept. In this collaborative project between Air Liquide and the University of Delaware an extensive evaluation was performed on new structures of the processing container and dispenser of HRS by integrating safety protocols via passive means. Through a SWOT analysis combined with the most relevant approaches including analytical engineering models numerical simulations [4] and dedicated experimental trials an optimized design was obtained and its safety enhancement was fully evaluated. A small-scale processing container and an almost full-scale dispenser were built and tested to validate the design concepts by simulating accidental H2 release scenarios and assessing the associated consequences in terms of accumulation and potential flammable volumes formation. A conical dispenser and a V-shaped roof-top processing container which were easy to build and implement were designed and tested for this proof-of-concept study. This unique methodology from conception fundamental analysis investigation and validation through experimental design execution and evaluation is fully described in this study.
Fuel Cell Vehicle Hydrogen Emissions Testing
Sep 2023
Publication
The NREL Hydrogen Sensor Laboratory is comprised of researchers dedicated to furthering hydrogen sensor technology and detection methodology. NREL has teamed up with researchers at Environment and Climate Change Canada (ECCC) and Transport Canada (TC) to conduct research to quantify hydrogen emissions from Fuel Cell Electric Vehicles (FCEV). Test protocols will have a large effect on monitoring and regulating the hydrogen emissions from FCEVs. How emissions are tested will play an important role when understanding the safety and environmental implications of using FCEVs. NREL Sensor Laboratory personnel have partnered with other entities to conduct multiple variations of emissions testing for FCEVs. This experimentation includes testing different models of FCEVs under various driving conditions while monitoring the hydrogen concentration of the exhaust using several different test methods and apparatus. Researchers look to support regulatory bodies by providing useful data that can support more consistent and relevant safety and environmental standards. We plan to present on the current test methods and results from recent emissions measurements at ECCC.
Hydrogen and the Global Energy Transition—Path to Sustainability and Adoption across All Economic Sectors
Feb 2024
Publication
This perspective article delves into the critical role of hydrogen as a sustainable energy carrier in the context of the ongoing global energy transition. Hydrogen with its potential to decarbonize various sectors has emerged as a key player in achieving decarbonization and energy sustainability goals. This article provides an overview of the current state of hydrogen technology its production methods and its applications across diverse industries. By exploring the challenges and opportunities associated with hydrogen integration we aim to shed light on the pathways toward achieving a sustainable hydrogen economy. Additionally the article underscores the need for collaborative efforts among policymakers industries and researchers to overcome existing hurdles and unlock the full potential of hydrogen in the transition to a low-carbon future. Through a balanced analysis of the present landscape and future prospects this perspective article aims to contribute valuable insights to the discourse surrounding hydrogen’s role in the global energy transition.
Energy Transition Technology Comes With New Process Safety Challenges and Risks
Jul 2023
Publication
This paper intends to give an impression of new technologies and processes that are in development for application to achieve decarbonization and about which less or no experience on associated hazards exists in the process industry. More or less an exception is hydrogen technology because its hazards are relatively known and there is industry experience in handling it safely but problems will arise when it is produced stored and distributed on a large scale. So when its use spreads to communities and it becomes as common as natural gas now measures to control the risks will be needed. And even with hydrogen surprise findings have been shown lately e.g. its BLEVE behavior when in a liquified form stored in a vessel heated externally. Substitutes for hydrogen are not without hazard concern either. The paper will further consider the hazards of energy storage in batteries and the problems to get those hazards under control. Relatively much attention will be paid to the electrification of the process industry. Many new processes are being researched which given green energy will be beneficial to reduce greenhouse gases and enhance sustainability but of which hazards are rather unknown. Therefore as last chapter the developments with respect to the concept of hazard identification and scenario definition will be considered in quite detail. Improvements in that respect are also being possible due to the digitization of the industry and the availability of data and considering the entire life cycle all facilitated by the data model standard ISO 15926 with the scope of integration of life-cycle data for process plants including oil and gas production facilities. Conclusion is that the new technologies and processes entail new process and personal hazards and that much effort is going into renewal but safety analyses are scarce. Right in a period of process renewal attention should be focused on possibilities to implement inherently safer design.
An Exploration of Safety Measures in Hydrogen Refueling Stations: Delving into Hydrogen Equipment and Technical Performance
Feb 2024
Publication
The present paper offers a thorough examination of the safety measures enforced at hydrogen filling stations emphasizing their crucial significance in the wider endeavor to advocate for hydrogen as a sustainable and reliable substitute for conventional fuels. The analysis reveals a wide range of crucial safety aspects in hydrogen refueling stations including regulated hydrogen dispensing leak detection accurate hydrogen flow measurement emergency shutdown systems fire-suppression mechanisms hydrogen distribution and pressure management and appropriate hydrogen storage and cooling for secure refueling operations. The paper therefore explores several aspects including the sophisticated architecture of hydrogen dispensers reliable leak-detection systems emergency shut-off mechanisms and the implementation of fire-suppression tactics. Furthermore it emphasizes that the safety and effectiveness of hydrogen filling stations are closely connected to the accuracy in the creation and upkeep of hydrogen dispensers. It highlights the need for materials and systems that can endure severe circumstances of elevated pressure and temperature while maintaining safety. The use of sophisticated leak-detection technology is crucial for rapidly detecting and reducing possible threats therefore improving the overall safety of these facilities. Moreover the research elucidates the complexities of emergency shut-off systems and fire-suppression tactics. These components are crucial not just for promptly managing hazards but also for maintaining the station’s structural soundness in unanticipated circumstances. In addition the study provides observations about recent technical progress in the industry. These advances effectively tackle current safety obstacles and provide the foundation for future breakthroughs in hydrogen fueling infrastructure. The integration of cutting-edge technology and materials together with the development of upgraded safety measures suggests a positive trajectory towards improved efficiency dependability and safety in hydrogen refueling stations.
Helping the Climate by Replacing Liquefied Natural Gas with Liquefied Hydrogen or Ammonia?
Apr 2024
Publication
The war in Ukraine caused Europe to more than double its imports of liquefied natural gas (LNG) in only one year. In addition imported LNG remains a crucial source of energy for resource-poor countries such as Japan where LNG imports satisfy about a quarter of the country’s primary energy demand. However an increasing number of countries are formulating stringent decarbonization plans. Liquefied hydrogen and liquefied ammonia coupled with carbon capture and storage (LH2-CCS LNH3-CCS) are emerging as the front runners in the search for low-carbon alternatives to LNG. Yet little is currently known about the full environmental profile of LH2-CCS and LNH3-CCS because several characteristics of the two alternatives have only been analyzed in isolation in previous work. Here we show that the potential of these fuels to reduce greenhouse gas (GHG) emissions throughout the supply chain is highly uncertain. Our best estimate is that LH2-CCS and LNH3-CCS can reduce GHG emissions by 25%–61% relative to LNG assuming a 100 year global warming potential. However directly coupling LNG with CCS would lead to substantial GHG reductions on the order of 74%. Further under certain conditions emissions from LH2-CCS and LNH3-CCS could exceed those of LNG by up to 44%. These results question the suitability of LH2-CCS and LNH3-CCS for stringent decarbonization purposes.
The Role of Hydrogen in the Energy Transition of the Oil and Gas Industry
May 2024
Publication
Hydrogen primarily produced from steam methane reforming plays a crucial role in oil refining and provides a solution for the oil and gas industry's long-term energy transition by reducing CO2 emissions. This paper examines hydrogen’s role in this transition. Firstly experiences from oil and gas exploration including in-situ gasification can be leveraged for hydrogen production from subsurface natural hydrogen reservoirs. The produced hydrogen can serve as fuel for generating steam and heat for thermal oil recovery. Secondly hydrogen can be blended into gas for pipeline transportation and used as an alternative fuel for oil and gas hauling trucks. Additionally hydrogen can be stored underground in depleted gas fields. Lastly oilfield water can be utilized for hydrogen production using geothermal energy from subsurface oil and gas fields. Scaling up hydrogen production faces challenges such as shared use of oil and gas infrastructures increased carbon tax for promoting blue hydrogen and the introduction of financial incentives for hydrogen production and consumption hydrogen leakage prevention and detection.
Leakage Rates of Hydrogen-methane Gas Blends under Varying Pressure Conditions
Nov 2024
Publication
Integration of hydrogen into the existing natural gas infrastructure is considered a potential pathway that can accelerate the incorporation of hydrogen into the energy sector. While blending renewable hydrogen with natural gas offers advantages such as reduced carbon intensity and the ability to utilize existing infrastructure for hydrogen storage and transportation there are several concerns including leakage and associated issues. Un derstanding the behavior of hydrogen blended with natural gas in the existing infrastructure is crucial to ensure safe and efficient integration. In this study the leakage rates of mixtures of hydrogen and methane at different molar concentrations (5% 10% 20% and 50% hydrogen) through both precision machined orifices and com mon pipe fitting threads were investigated. The experiments showed that the leakage rates of these mixtures increased as the hydrogen content increased; however gas chromatography (GC) analysis showed that hydrogen did not leak preferentially at a greater rate than methane. The results indicate that mixing hydrogen with methane can increase the volume of gas leakage under the same pressure conditions. These findings suggest that mixing hydrogen with natural gas may result in increased volumetric flow rate of gas leaks but hydrogen alone does not leak preferentially to methane.
Simple Energy Model for Hydrogen Fuel Cell Vehicles: Model Development and Testing
Dec 2024
Publication
Hydrogen fuel cell vehicles (HFCVs) are a promising technology for reducing vehicle emissions and improving energy efficiency. Due to the ongoing evolution of this technology there is limited comprehensive research and documentation regarding the energy modeling of HFCVs. To address this gap the paper develops a simple HFCV energy consumption model using new fuel cell efficiency estimation methods. Our HFCV energy model leverages real-time vehicle speed acceleration and roadway grade data to determine instantaneous power exertion for the computation of hydrogen fuel consumption battery energy usage and overall energy consumption. The results suggest that the model’s forecasts align well with real-world data demonstrating average error rates of 0.0% and −0.1% for fuel cell energy and total energy consumption across all four cycles. However it is observed that the error rate for the UDDS drive cycle can be as high as 13.1%. Moreover the study confirms the reliability of the proposed model through validation with independent data. The findings indicate that the model precisely predicts energy consumption with an error rate of 6.7% for fuel cell estimation and 0.2% for total energy estimation compared to empirical data. Furthermore the model is compared to FASTSim which was developed by the National Renewable Energy Laboratory (NREL) and the difference between the two models is found to be around 2.5%. Additionally instantaneous battery state of charge (SOC) predictions from the model closely match observed instantaneous SOC measurements highlighting the model’s effectiveness in estimating real-time changes in the battery SOC. The study investigates the energy impact of various intersection controls to assess the applicability of the proposed energy model. The proposed HFCV energy model offers a practical versatile alternative leveraging simplicity without compromising accuracy. Its simplified structure reduces computational requirements making it ideal for real-time applications smartphone apps in-vehicle systems and transportation simulation tools while maintaining accuracy and addressing limitations of more complex models.
Hydrogen Equipment Enclosure Risk Reduction through Earlier Detection of Component Failures
Sep 2023
Publication
Hydrogen component reliability and the hazard associated with failure rates is a critical area of research for the successful implementation and growth of hydrogen technology across the globe. The research team has partnered to quantify system risk reduction through earlier detection of hydrogen component failures. A model of hydrogen dispersion in a hydrogen equipment enclosure has been developed utilizing experimentally quantified hydrogen component leak rates as inputs. This model provides insight into the impact of hydrogen safety sensors and ventilation on the flammable mass within a hydrogen equipment enclosure. This model also demonstrates the change in safety sensor response time due to detector placement under various leak scenarios. The team looks to improve overall hydrogen system safety through an improved understanding of hydrogen component reliability and risk mitigation methods. This collaboration fits under the work program of IEA Hydrogen Task 43 Subtask E Hydrogen System Safety.
Everything About Hydrogen Podcast: "Stat of the Union" with EAH Hosts
May 2024
Publication
This week’s episode is a discussion between EAH hosts Patrick Molloy Alicia Eastman and Chris Jackson. The team cover the current status of hydrogen regulation innovation financing markets and consolidation. Hanging over most conversations in the decarbonization or future fuels space is the perpetual question: When will investors actually step up with significant capital to help companies make it through the development desert instead of letting promising companies languish in the double dunes of despair? There has been a lot of talk but not a lot of action. Listen to the team unpack recent developments and hopes for the future.
The podcast can be found on their website.
The podcast can be found on their website.
Enabling Large-scale Enhanced Hydrogen Production in Deep Underground Coal Gasification in the Context of a Hydrogen Economy
Dec 2024
Publication
Underground coal gasification (UCG) is an emerging clean energy technology with significant potential for enhanced hydrogen production especially when coupled with water injection. Previous lab-scale studies have explored this potential but the mechanisms driving water-assisted hydrogen enhancement in large-scale deep UCG settings remain unclear. This study addresses this gap using numerical simulations of a large-scale deep coal model designed for hydrogen-oriented UCG. We investigated single-point and multipoint water injection stra tegies to optimize hydrogen production. Additionally we developed a retractable water injection technique to ensure sustained hydrogen output and effective cavity control. Our results indicate that the water–gas shift re action is crucial for increasing hydrogen production. Multipoint injection has been proven to be more effective than single-point injection increasing hydrogen production by 11% with an equal amount of steam. The introduction of retractable injection allows for continuous and efficient hydrogen generation with daily hydrogen production rates of approximately five times that of a conventional injection scheme and an increase in cumulative hydrogen production of approximately 105% over the same time period. Importantly the mul tipoint injection method also helped limit vertical cavity growth mitigating the risk of aquifer contamination. These findings support the potential of UCG as a low-carbon energy source in the transition to a hydrogen economy
Multiperiod Modeling and Optimization of Hydrogen-Based Dense Energy Carrier Supply Chains
Feb 2024
Publication
The production of hydrogen-based dense energy carriers (DECs) has been proposed as a combined solution for the storage and dispatch of power generated through intermittent renewables. Frameworks that model and optimize the production storage and dispatch of generated energy are important for data-driven decision making in the energy systems space. The proposed multiperiod framework considers the evolution of technology costs under different levels of promotion through research and targeted policies using the year 2021 as a baseline. Furthermore carbon credits are included as proposed by the 45Q tax amendment for the capture sequestration and utilization of carbon. The implementation of the mixed-integer linear programming (MILP) framework is illustrated through computational case studies to meet set hydrogen demands. The trade-offs between different technology pathways and contributions to system expenditure are elucidated and promising configurations and technology niches are identified. It is found that while carbon credits can subsidize carbon capture utilization and sequestration (CCUS) pathways substantial reductions in the cost of novel processes are needed to compete with extant technology pathways. Further research and policy push can reduce the levelized cost of hydrogen (LCOH) by upwards of 2 USD/kg.
IEA TCP Task 43 - Subtask Safety Distances: State of the Art
Sep 2023
Publication
The large deployment of hydrogen technologies for new applications such as heat power mobility and other emerging industrial utilizations is essential to meet targets for CO2 reduction. This will lead to an increase in the number of hydrogen installations nearby local populations that will handle hydrogen technologies. Local regulations differ and provide different safety and/or separation distances in different geographies. The purpose of this work is to give an insight on different methodologies and recommendations developed for hydrogen (mainly) risk management and consequences assessment of accidental scenarios. The first objective is to review available methodologies and to identify the divergent points on the methodology. For this purpose a survey has been launched to obtain the needed inputs from the subtask participants. The current work presents the outcomes of this survey highlighting the gaps and suggesting the prioritization of the actions to take to bridge these gaps.
Modeling the Global Annual Carbon Footprint for the Transportation Sector and a Path to Sustainability
Jun 2023
Publication
The transportation industry’s transition to carbon neutrality is essential for addressing sustainability concerns. This study details a model for calculating the carbon footprint of the transportation sector as it progresses towards carbon neutrality. The model aims to support policymakers in estimating the potential impact of various decisions regarding transportation technology and infrastructure. It accounts for energy demand technological advancements and infrastructure upgrades as they relate to each transportation market: passenger vehicles commercial vehicles aircraft watercraft and trains. A technology roadmap underlies this model outlining anticipated advancements in batteries hydrogen storage biofuels renewable grid electricity and carbon capture and sequestration. By estimating the demand and the technologies that comprise each transportation market the model estimates carbon emissions. Results indicate that based on the technology roadmap carbon neutrality can be achieved by 2070 for the transportation sector. Furthermore the model found that carbon neutrality can still be achieved with slippage in the technology development schedule; however delays in infrastructure updates will delay carbon neutrality while resulting in a substantial increase in the cumulative carbon footprint of the transportation sector.
Advancements in Hydrogen Energy Systems: A Review of Levelized Costs, Financial Incentives and Technological Innovations
Apr 2024
Publication
Hydrogen energy systems (HES) are increasingly recognized as pivotal in cutting global carbon dioxide (CO2) emissions especially in transportation power generation and industrial sectors. This paper offers a comprehensive review of HES emphasizing their diverse applications and economic viability. By 2030 hydrogen energy is expected to revolutionize various sectors significantly impacting CO2 abatement and energy demand. In electricity and power generation hydrogen could reduce CO2 emissions by 50–100 million tons annually requiring 10–20 million tons of hydrogen and an investment of $50–100 billion underscoring its role in grid stabilization. Additionally in the heating sector hydrogen could facilitate a CO2 abatement of 30–50 million tons. We examine the levelized cost of hydrogen (LCOH) production influenced by factors like production methods efficiency and infrastructure. While steam methane reforming is cost-effective it poses a larger environmental impact compared to electrolysis. The global life-cycle cost of hydrogen production decreases as production scales up with current costs ranging from $1–3 per kg for fossil-based sources to $3.4–7.5 per kg for electrolysis using low-emission electricity. These costs are projected to decrease especially for electrolytic hydrogen in regions with abundant solar energy. However despite the technical feasibility of decarbonization high production costs still pose challenges. A systematic and effective transition to a hydrogen economy requires comprehensive policy and financial support mechanisms including incentives subsidies tax measures and funding for research and development of pilot projects. Additionally the paper discusses hydrogen's role in advanced storage technologies such as hydrides and Japan's ENE-FARM solution for residential energy emphasizing the need for strategic investments across the hydrogen value chain to enhance HES competitiveness reduce LCOH and advance the learning rates of hydrogen production technologies.
Multi-year Energy Performance Data for an Electrolysis-based Hydrogen Refueling Station
Apr 2023
Publication
Financing sizing operating or upgrading a hydrogen refueling station (HRS) is challenging and may be complex much more so in today's rapidly changing and growing hydrogen industry. There is a significant information gap regarding experimental hydrogen station activities. A high-level perspective on such data and information may facilitate the transition between present and future HRS operations. To address the need for such high-level perspective this paper presents a comprehensive data set on the performance of the California State University Los Angeles Hydrogen Research and Fueling Facility based on multi-year operational data. The analysis of over 4500 refueling events and over 8800 kg of hydrogen dispensed as well as the operation of the facility electrolyzer and of both storage and refueling compressors from 2016 to 2020 reveals a comprehensive picture of HRS energy performance and the identification of useful key performance indicators. In 2016 the station's energy efficiency was 25% but in 2017 and the first three quarters of 2018 it dropped to 15%. Station-specific energy consumption increased during these quarters. The 2020 first quarter energy consumption was between 70 and 80 kWh/kg. At this time the energy efficiency of the station reached 40%.<br/>This research is based on an unprecedented and unique dataset of an HRS operating under real-world conditions with an approach that can be informative for modeling the performance of other stations providing a dataset that HRS designers operators and investors may utilize to make data-driven choices regarding HRS components and their specs and size as well as operating strategies.
Everything About Hydrogen Podcast: Mobilizing Capital in Green Hydrogen
Apr 2023
Publication
Continuing from previous episodes about encouraging global investment in green hydrogen Patrick Molloy and Alicia Eastman speak with Ignacio de Calonje Chief Investment Officer IFC Global Infrastructure. Ignacio breaks down the role of the IFC and its relationship with other Multilateral Development Banks (MDBs) to encourage decarbonization and bespoke solutions for the Global South.
The podcast can be found on their website.
The podcast can be found on their website.
Hydrogen-powered Aircraft: Fundamental Concepts, Key Technologies, and Environmental Impacts
Sep 2024
Publication
Civil aviation provides an essential transportation network that connects the world and supports global economic growth. To maintain these benefits while meeting environmental goals next-generation aircraft must have drastically reduced climate impacts. Hydrogen-powered aircraft have the potential to fly existing routes with no carbon emissions and reduce or eliminate other emissions. This paper is a comprehensive guide to hydrogen-powered aircraft that explains the fundamental physics and reviews current technologies. We discuss the impact of these technologies on aircraft design cost certification and environment. In the long term hydrogen aircraft appear to be the most compelling alternative to today’s kerosene-powered aircraft. Using hydrogen also enables novel technologies such as fuel cells and superconducting electronics which could lead to aircraft concepts that are not feasible with kerosene. Hydrogen-powered aircraft are technologically feasible but require significant research and development. Lightweight liquid hydrogen tanks and their integration with the airframe is one of the critical technologies. Fuel cells can eliminate in-flight emissions but must become lighter more powerful and more durable to make large fuel cell-powered transport aircraft feasible. Hydrogen turbofans already have these desirable characteristics but produce some emissions albeit much less damaging than kerosene turbofans. Beyond airframe and propulsion technologies the viability of hydrogen aircraft hinges on low-cost green hydrogen production which requires massive investments in the energy infrastructure.
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