Production & Supply Chain
The Effects of Light Energy Fields on the Molecular and Electrochemical Dynamics During Water Electrolysis
Aug 2025
Publication
Hydrogen will be an integral component for the transition to sustainable energy generation and storage due to its favourable characteristics and versatility in its application. This research provides a greater understanding of the potential light energy has to increase water electrolysis efficiency by examining the effects that light energy fields have on the molecular and electrochemical dynamics during electrolysis. The results indicate that light energy increased efficiency by ~10% while enhancing the molecular dynamics regardless of application. The application of a line laser generated the highest gains in efficiency with a maximum of ~15%. Furthermore the application of a line laser with a linear magnetic field resulted in a synergistic effect which generated higher increases in molecular dynamics as well as an ~18% increase in efficiency and a ~58% increase in hydrogen gas production. As such the application of light energy fields presents a promising method for enhancing water’s molecular dynamics and electrolysis efficiency.
Synergistic Sizing and Energy Management Strategy of Combined Offshore Wind with Solar Floating PV System for Green Hydrogen and Electricity Co-Production Using Multi-Objective Dung Beetle Optimization
Feb 2025
Publication
This study comprehensively analyzes an integrated renewable energy system complementing offshore wind turbines (OWT) and floating solar photovoltaic (FPV) technology designed for producing electric power and green hydrogen. The research explores the technical feasibility techno-economic performance and optimal sizing of the system components. The system integrates OWT farms FPV arrays water electrolyzer and hydrogen storage tank to minimize the levelized cost of energy (LCOE) loss of power supply probability (LPSP) and excess energy. A novel optimization approach Dung Beetle Optimization (DBO) algorithm is utilized and compared with the Grey Wolf Optimizer (GWO) for performance validation. To ensure the robustness of the proposed DBO algorithm it is thoroughly tested on two system configurations: a standalone OWT hydrogen production system and a hybrid FPV/OWT hydrogen production system. The results showed that the DBO algorithm outperforms the GWO algorithm in terms of system efficiency cost-effectiveness and reliability. The optimization findings reveal that the FPV/OWT hybrid system optimized with the DBO algorithm leads to a more cost-effective configuration with the OWT component contributing 45.96% of the total costs. Moreover the optimized FPV/OWT system achieves a lower levelized cost of energy (LCOE) of 0.5797 $/kWh compared to 0.8190 $/kWh for the standalone OWT system. Furthermore the hybrid FPV/OWT system maintains a levelized cost of hydrogen (COH) of 1.205 $/kg making it a competitive option for large-scale hydrogen production. Conclusively the findings demonstrate the technical feasibility and economic viability of the designated hybrid system for sustainable off-grid rural electrification and hydrogen production offering a robust solution to meet future energy demands.
Off-Design Analysis of Power-to-Gas System Based on Solid-Oxide Electrolysis with Nominal Power of 25 kW
Mar 2025
Publication
The deployment of large installed power capacities from intermittent renewable energy sources requires balancing to ensure the steady and safe operation of the electrical grid. New methods of energy storage are essential to store excess electrical power when energy is not needed and later use it during high-demand periods both in the short and long term. Power-to-Gas (P2G) is an energy storage solution that uses electric power produced from renewables to generate gas fuels such as hydrogen which can be stored for later use. Hydrogen produced in this manner can be utilized in energy storage systems and in transportation as fuel for cars trams trains or buses. Currently most hydrogen is produced from fossil fuels. Solid-oxide electrolysis (SOE) offers a method to produce clean hydrogen without harmful emissions being the most efficient of all electrolysis methods. The objective of this work is to determine the optimal operational parameters of an SOE system such as lower heating value (LHV)-based efficiency and total input power based on calculations from a mathematical model. The results are provided for three different operating temperature levels and four different steam utilization ratios. The introductory chapter outlines the motivation and background of this work. The second chapter explains the basics of electrolysis and describes its different types. The third chapter focuses on solid-oxide electrolysis and electrolyzer systems. The fourth chapter details the methodology including the mathematical formulations and software used for simulations. The fifth chapter presents the results of the calculations with conclusions. The final chapter summarizes this work.
A Coordinated Control Strategy for a Coupled Wind Power and Energy Storage System for Hydrogen Production
Apr 2025
Publication
Hydrogen energy as a medium for long-term energy storage needs to ensure the continuous and stable operation of the electrolyzer during the production of green hydrogen using wind energy. In this paper based on the overall model of a wind power hydrogen production system an integrated control strategy aimed at improving the quality of wind power generation smoothing the hydrogen production process and enhancing the stability of the system is proposed. The strategy combines key measures such as the maximum power point tracking control of the wind turbine and the adaptive coordinated control of the electrochemical energy storage system which can not only efficiently utilize the wind resources but also effectively ensure the stability of the bus voltage and the smoothness of the hydrogen production process. The simulation results show that the electrolyzer can operate at full power to produce hydrogen while the energy storage device is charging when wind energy is sufficient; the electrolyzer continuously produces hydrogen according to the wind energy when the wind speed is normal; and the energy storage device will take on the task of maintaining the operation of the electrolyzer when the wind speed is insufficient to ensure the stability and reliability of the system.
Selection of a Green Hydrogen Production Facility Location with a Novel Heuristic Approach
Mar 2025
Publication
The production of green hydrogen the cleanest energy source plays a crucial role in enhancing the efficiency of renewable energy systems by utilizing surplus energy that would otherwise be wasted. With the global shift towards sustainability and the rising adoption of renewable energy sources green hydrogen is gaining significant importance as both an energy carrier and a storage solution. However determining the optimal locations for green hydrogen production facilities remains a complex challenge due to the interplay of technical economic logistical and environmental factors. This study introduces the City Location Evaluation Optimization for Green Hydrogen (CELO_GH) algorithm a novel heuristic approach designed to address this challenge. Unlike conventional multi-criteria decision-making (MCDM) models CELO_GH dynamically evaluates cities by considering renewable energy surplus proximity to industrial hydrogen demand port and pipeline accessibility and economic viability. A case study conducted in Turkey demonstrates the effectiveness of the approach by identifying optimal cities for green hydrogen production based on real-world energy and infrastructure data. The problem was also solved with the genetic algorithm and the results were compared and it was seen that the proposed heuristic provides the lowest cost location selection. A geographically flexible methodology as the proposed algorithm can be applied globally to regions with high renewable energy potential ensuring scalability and adaptability for future energy transition strategies. The results provide valuable insights for policy-makers energy investors and industrial planners aiming to optimize green hydrogen infrastructure while ensuring cost efficiency and sustainability.
Comparative Life Cycle Assessment of Hydrogen Production via Biogas Reforming and Agricultural Residue Gasification
Apr 2025
Publication
Hydrogen (H2) production from biomass has emerged as a promising alternative to fossil-based pathways addressing the global demand for low-carbon energy solutions. This study compares the environmental impacts of two biomass-based H2 production processes biogas reforming and agricultural residue gasification through a life cycle assessment (LCA). Using real-world data from the literature the analysis considered key system boundaries for each process including biogas production reforming and infrastructure for the former and biomass cultivation syngas generation and offgas management for the latter. Environmental impacts were evaluated using SimaPro software (Version 9.4) and the ReCiPe midpoint (H) method. The results revealed that biogas reforming emits approximately 5.047 kg CO2-eq per kg of H2 which is 4.89 times higher than the emissions from agricultural residue gasification (1.30 kg CO2-eq/kg H2) demonstrating the latter’s superior environmental performance. Gasification consumes fewer fossil resources (3.20 vs. 10.42 kg oil-eq) and poses significantly lower risks to human health (1.51 vs. 23.28 kg 14-DCB-eq). Gasification water consumption is markedly higher (5.37 compared to biogas reforming (0.041 m3/kg H2)) which is an important factor to consider for sustainability. These findings highlight gasification as a more sustainable H2 production method and emphasize its potential as an eco-friendly solution. To advance sustainability in energy systems integrating socio-economic studies with LCA is recommended alongside prioritizing agricultural residue gasification for hydrogen production.
Review of Electrochemical Systems for Grid Scale Power Generation and Conversion: Low- and High-Temperature Fuel Cells and Electrolysis Processes
May 2025
Publication
This review paper presents an overview of fuel cell electrochemical systems that can be used for clean large-scale power generation and energy storage as global energy concerns regarding emissions and greenhouse gases escalate. The fundamental thermochemical and operational principles of fuel cell power generation and electrolyzer technologies are discussed with a focus on high-temperature solid oxide fuel cells (SOFCs) and solid oxide electrolysis cells (SOECs) that are best suited for grid scale energy generation. SOFCs and SOECs share similar promising characteristics and have the potential to revolutionize energy conversion and storage due to improved energy efficiency and reduced carbon emissions. Electrochemical and thermodynamic foundations are presented while exploring energy conversion mechanisms electric parameters and efficiency in comparison with conventional power generation systems. Methods of converting hydrocarbon fuels to chemicals that can serve as fuel cell fuels are also presented. Key fuel cell challenges are also discussed including degradation thermal cycling and long-term stability. The latest advancements including in materials selection research design and manufacturing methods are also presented as they are essential for unlocking the full potential of these technologies and achieving a sustainable near zero-emission energy future.
Thermo-economic Analysis of a Novel P2X Polygeneration System for Hydrogen, Ammonia, and Methanol Production with Near-zero Emissions
Jun 2025
Publication
This paper presents a comprehensive thermo-economic analysis of a novel Power-to-X (P2X) polygeneration system designed for the production of hydrogen ammonia and methanol with near-zero CO2 emissions. The system integrates an air separation unit (ASU) a direct oxy-combustor (DOC) powered by natural gas combined with a supercritical carbon dioxide (sCO2) power cycle water electrolyzer (WE) a Haber-Bosch process (HBP) and a methanol production unit (MPU). The system is investigated in four configurations: ASU + DOC-sCO2 (S1) ASU + DOC-sCO2 + WE (S2) ASU + DOC-sCO2 + WE + HBP (S3) and ASU + DOC-sCO2 + WE + HBP + MPU (S4) each contributing to improve energy efficiency and reduced emissions. Simulation results show that the overall system efficiency reaches 56 % improving from 45 % to 56 % across different configurations. The system’s levelized cost of hydrogen (LCOH) decreases significantly from $1.70/kg to $0.80/kg and the levelized cost of electricity (LCOE) decreases from 4.30 ¢/kWh to 3.30 ¢/kWh. CO2 emissions are reduced from 200 gCO2/ MWe to 145 gCO2/MWe with the CO2 reduction rate improving from 89 % to 94 %. These results demonstrate the economic viability and environmental sustainability of the proposed P2X system paving the way for industrial decarbonization and large-scale deployment in future energy infrastructures.
Hydrogen Production in Integration with CCUS: A Realistic Strategy towards Net Zero
Jan 2025
Publication
It is believed that hydrogen will play an essential role in energy transition and achieving the net-zero target by 2050. Currently global hydrogen production mostly relies on processing fossil fuels such as coal and natural gas commonly referred to as grey hydrogen production while releasing substantial amounts of carbon dioxide (CO2). Developing economically and technologically viable pathways for hydrogen production while eliminating CO2 emissions becomes paramount. In this critical review we examine the common grey hydrogen production techniques by analyzing their technical characteristics production efficiency and costs. We further analyze the integration of carbon capture utilization and storage (CCUS) technology establishing the zero-carbon strategy transiting from grey to blue hydrogen production with CO2 capture and either utilized or permanently stored. Today grey hydrogen production exhibits technological diversities with various commercial maturities. Most methods rely on the effectiveness of catalysts necessitating a solution to address catalyst fouling and sintering in practice. Although CCUS captures utilizes or stores CO2 during grey hydrogen production its wide application faces multiple challenges regarding the technological complexity cost and environmental benefits. It is urgent to develop technologically mature low-cost and low-energy-consumption CCUS technology implementing extensive large-scale integrated pilot projects.
Green Hydrogen Potential Assessment in Ghana: Application of PEM Electrolysis Process and Geospatial-multi-criteria Approach
Sep 2023
Publication
With green hydrogen gaining traction as a viable sustainable energyoption the present study explores the potential of producing greenhydrogen from wind and solar energy in Ghana. The study combinedthe use of geospatial multi-criteria approach and PEM electrolysisprocess to estimate the geographical and technical potential of theselected two renewable resources. The study also included anassessment of potential areas for grid integration. Technologyspecifications of a monocrystalline solar PV module and 1 MW windturbine module were applied. Results of the assessment show thatabout 85% of the total land area in the country is available for greenhydrogen projects. Technically capacities of ∼14196.21 Mt of greenhydrogen using solar and ∼10123.36 Mt/year from wind energy can beproduced annually in the country. It was also observed that someregions especially regions in the northern part of the country eventhough showed the most favourable locations for solar-based greenhydrogen projects with technical potential of over 1500 Mt/year theseregions may not qualify for a grid connected system based on thecurrent electrification policy of the country due to the regions’ lowpopulation density and distance from the power grid network threshold.
Development of a Novel Biomass-Wind Energy System for Clean Hydrogen Production along with Other Useful Products for a Residential Community
Jan 2025
Publication
The study presents the development of a novel integrated wind-biomass energy system designed for sustainable urban development leveraging municipality waste and wind power energy sources. This innovative system is capable of producing multiple forms of energy including electricity cooling heat and hydrogen addressing the diverse energy needs of urban communities. It integrates advanced thermodynamic cycles like Kalina and water electrolysis via an alkaline electrolyzer. In addition the system uniquely combines power and refrigeration while utilizing landfills as an energy source. The designed system is thermodynamically modeled using the Engineering Equation Solver and process wise simulated by the Aspen Plus software to ensure better performance. By integrating advanced thermodynamic cycles such as the Kalina and combined power and refrigeration system the overall system is designed to maximize the utilization of biomass energy content and enhances overall performance. The thermodynamic analysis results reveal that the system achieved remarkable results with an energy efficiency of 67.60% and an exergy efficiency of 59.7% demonstrating its tangible performance compared to other standalone energy systems. The refrigeration system itself achieves an energetic COP of 5.41 and an exergetic COP of 1.7. Additionally the system's hydrogen production facilitated by an alkaline electrolyzer reaches a rate of 5.38 kg/h highlighting its potential to contribute to clean hydrogen energy solutions. Moreover the exergo-environmental assessment shows that the system is environmentally friendly. The cost assessment shows that the system reaches profitability in 7 years and demonstrates growth achieving a substantial NPV of 192.39 million by 30 years highlighting its long-term financial viability.
Blue Hydrogen can be Low-Carbon, A Techno-Economic-Environmental Analysis
Oct 2025
Publication
Hydrogen produced through natural gas reforming with carbon capture and storage (blue H2) is expected to supply up to 30 % of global low-carbon hydrogen by 2030. However wide variability in reported findings creates uncertainty about its future role. To address this the present techno-economic-environmental study from a lifecycle perspective evaluates whether blue hydrogen can meet carbon footprint thresholds (3 and 3.4 kg CO2 eq./ kg H2) required to qualify as low-carbon hydrogen. Several configurations of either chemical absorption or lowtemperature CO2 separation techniques integrated with auto-thermal reforming are modeled. Results show that low-temperature separation can achieve comparable or even superior energetic performance to conventional capture methods with cold gas and overall efficiencies reaching up to 80 % and 78 % respectively. The economic analysis estimates the levelized cost of blue hydrogen at 3.5–4 €/kg under 2024 EU average nonhousehold consumer natural gas and electricity prices and 2.4–2.8 €/kg under Italy’s 2024 wholesale prices. From an environmental standpoint life-cycle assessment indicates an average carbon footprint of 2.5 kg CO2 eq./ kg H2 assuming photovoltaic electricity for auxiliary power and excluding more carbon-intensive natural gas supply chains. The findings highlight that partial electrification of the CO2 separation unit use of renewable electricity and maximizing capture rates are key factors essential for producing compliant blue H2. Furthermore adopting ultra-low-emission natural gas supply chains could reduce blue H2′s carbon footprint to the level of green H2 suggesting that the introduction of certificate-of-origin schemes for natural gas can guarantee blue H2 with minimal emissions.
Advancing the Hydrogen Production Economy: A Comprehensive Review of Technologies, Sustainability, and Future Prospects
Jun 2024
Publication
The transition to a hydrogen-based economy presents a promising solution to the challenges posed by unsus tainable energy systems and reliance on fossil fuels. This comprehensive review explores various hydrogen production methods emphasizing their technological advancements sustainability implications and future prospects. Beginning with an overview of hydrogen’s significance as a clean energy carrier the review examines key production methods such as Steam Methane Reforming Electrolysis (Proton Exchange Membrane alkaline solid oxide) Biomass Gasification Photoelectrochemical Water Splitting and Thermochemical Processes. Each method is scrutinized for its efficiency environmental impact and scalability providing valuable insights into their roles in advancing the hydrogen economy. The review highlights the transformative potential of hydrogen production to replace fossil fuels due to its ability to store renewable energy long-term and its zero emissions. It also discusses potential technological advancements including high-efficiency solid-state electrolysis and advanced catalysts for water splitting highlighting avenues for innovation in hydrogen production. Additionally policy recommendations aimed at promoting the hydrogen economy and fostering collaboration between academia industry and governments are elucidated. Through a detailed analysis of hydrogen production technologies and future prospects this review contributes to shaping the trajectory of sustainable energy sys tems advancing the adoption of hydrogen as a key energy vector and underscoring the importance of alternative and sustainable energy sources.
Optimizing Hydrogen Production from Wastewater-derived Sewage Sludge via Alkali-catalyzed Supercritical Water Gasification
Sep 2025
Publication
The increasing global wastewater generation and reliance on fossil fuels for energy production necessitate sustainable treatment and energy recovery solutions. This study explores supercritical water gasification (SCWG) of sewage sludge from municipal wastewater as a hydrogen production pathway focusing on the role of alkali catalysts (KOH K₂CO₃ Na₂CO₃). The effects of temperature (450–550◦C) reaction time (5–30 min) and catalyst type on gas yield and efficiency were analyzed. At 550◦C the highest carbon efficiency (61 %) gas efficiency (69 %) and hydrogen yield (41 mol/kg) were observed. After 30 min the gas composition reached H₂ (58 %) CO₂ (26 %) CH₄ (11.7 %) and CO (4 %). Among catalysts Na₂CO₃ exhibited superior H₂ yield (29 mol/kg) carbon efficiency (58 %) and gas efficiency (51 %). This study highlights SCWG as a viable technology for hydrogen-rich gas production contributing to sustainable energy solutions and wastewater valorization.
Production of Green Hydrogen from Sewage Sludge/Algae in Agriculture Diesel Engine: Performance Evaluation
Jan 2024
Publication
Alternative fuel opportunities can satisfy energy security and reduce carbon emissions. In this regard the hydrogen fuel is derived from the source of environmental pollutants like sewage and algae wastewater through hydrothermal gasification technique using a KOH catalyst with varied gasification process parameters of duration and temperature of 6–30 min and 500-800 ◦C. The novelty of the work is to identify the optimum gasification process parameter for obtaining the maximum hydrogen yield using a KOH catalyst as an alternative fuel for agricultural engine applications. Influences of gasification processing time and temperature on H2 selectivity Carbon gasification efficiency (CE) Lower heating value (LHV) Hydrogen yield potential (HYP) and gasification efficiency (GE) were studied. Its results showed that the gasifier operated at 800 ◦C for 30 min offering maximum hydrogen yield (26 mol/kg) and gasification efficiency (58 %). The synthesized H2 was an alternative fuel blended with diesel fuel/TiO2 nanoparticles. It was experimentally studied using an internal combustion engine. Influences of H2 on engine perfor mance like brake-specific fuel consumption brake thermal efficiency and emission performances were measured and compared with diesel fuel. The results showed that DH20T has the least (420g/kWh) brake-specific fuel consumption (BSFC) and superior brake thermal efficiency of about 25.2 %. The emission results revealed that the DH20T blend showed the NOX value increased by almost 10.97 % compared to diesel fuel whereas the CO UHC and smoke values reduced by roughly 31.25 28.34 and 42.35 %. The optimum fuel blend (DH20T) result is rec ommended for agricultural engine applications.
Nanomaterials and Hydrogen Production: A Comprehensive Review of Clean Energy Strategies, Costs, and Environmental Implications
Aug 2025
Publication
An increasing demand for energy coupled with rising pollution levels is driving the search for environmentally clean alternative energy resources to replace fossil fuels. Hydrogen has emerged as a promising clean energy carrier and raw material for various applications. However its environmental benefits depend on sustainable production methods. The rapid development of nanomaterials (NMs) has opened new avenues for the conversion and utilization of renewable energy (RE). NMs are becoming increasingly important in addressing challenges related to hydrogen (H₂) generation. This review provides an overview of current advancements in H₂ production from biomass via thermochemical (TC) and biological (BL) processes including associated costs and explores the applications of nanomaterials in these methods. Research indicates that biological hydrogen (BL-H₂) production remains costly. The challenges associated with the TC conversion process are examined along with potential strategies for improvement. Finally the technical and economic obstacles that must be overcome before hydrogen can be widely adopted as a fuel are discussed.
Analysis of the Sugarcane Biomass Use to Produce Green Hydrogen: Brazilian Case Study
Feb 2025
Publication
Conventional hydrogen production processes which often involve fossil raw materials emit significant amounts of carbon dioxide into the atmosphere. This study critically evaluates the feasibility of using sugarcane biomass as an energy source to produce green hydrogen. In the 2023/2024 harvest Brazil the world’s largest sugarcane producer processed approximately 713.2 million metric tons of sugarcane. This yielded 45.68 million metric tons of sugar and 29.69 billion liters of first-generation ethanol equivalent to approximately 0.0416 liters of ethanol per kilogram of sugarcane. A systematic literature review was conducted using Scopus and Clarivate Analytics Web of Science resulting in the assessment of 335 articles. The study has identified seven potential biohydrogen production methods including two direct approaches from second-generation ethanol and five from integrated bioenergy systems. Experimental data indicate that second-generation ethanol can yield 594 MJ per metric ton of biomass with additional energy recovery from lignin combustion (1705 MJ per metric ton). Moreover advances in electrocatalytic reforming and plasma-driven hydrogen production have demonstrated high conversion efficiencies addressing key technical barriers. The results highlight Brazil’s strategic potential to integrate biohydrogen production within its existing bioenergy infrastructure. By leveraging sugarcane biomass for green hydrogen the country can contribute significantly to the global transition to sustainable energy while enhancing its energy security.
Hydrogen Production Efficiency: A Critical Factor in Integrated Planning of Distributed and Transmission System for Large-scale Centralized Offshore Wind-hydrogen System
Dec 2024
Publication
Green hydrogen plays a pivotal role in decarbonizing our energy system and achieving the Net-Zero Emissions goal by 2050. Offshore wind farms (OWFs) dedicated to green hydrogen production are currently recognized as the most feasible solution for scaling up the production of cost-effective electrolytic hydrogen. However the cost associated with distribution and transmission systems constitute a significant portion of the total cost in the large-scale wind-hydrogen system. This study pioneers the simultaneous optimization of the inter-array cable routing of OWFs and the location and capacity of offshore hydrogen production platforms (OHPPs) aiming to minimize the total cost of distribution and transmission systems. Considering the characteristics of hydrogen production efficiency this paper constructs a novel mathematical model for OHPPs across diverse wind scenarios. Subsequently we formulate the joint planning problem as a relaxed mixed-integer second-order cone programming (MISOCP) model and employ the Benders decomposition algorithm for the solution introducing three valid inequalities to expedite convergence. Through validation on real-world large-scale OWFs we demonstrate the validity and rapid convergence of our approach. Moreover we identify hydrogen production efficiency as a major bottleneck cost factor for the joint planning problem it decreases by 1.01% of total cost for every 1% increase in hydrogen production efficiency.
New Perspectives on Catalytic Hydrogen Production by the Reforming, Partial Oxidation and Decomposition of Methane and Biogas
Sep 2023
Publication
The article provides a short review on catalyst-based processes for the production of hydrogen starting from methane both of fossil origin and from sustainable processes. The three main paths of steam- and dry-reforming partial oxidation and thermo-catalytic decomposition are briefly introduced and compared above all with reference to the latest publications available and to new catalysts which obey the criteria of lower environmental impact and minimize the content of critical raw materials. The novel strategies based on chemical looping with CO2 utilization membrane separation electrical-assisted (plasma and microwave) processes multistage reactors and catalyst patterning are also illustrated as the most promising perspective for CH4 reforming especially on small and medium scale. Although these strategies should only be considered at a limited level of technological readiness research on these topics including catalyst development and process optimization represents the crucial challenge for the scientific community
Renewable Hydrogen from Seafood Shell Waste for Long-term Energy Storage on Islands
Aug 2025
Publication
This study explores the potential of renewable seafood shell waste for sustainable energy conversion and longterm storage particularly for isolated communities. Despite its rich chitin and protein composition seafood shell waste is often neglected. The research evaluates and compares three advanced gasification technologies: biomass gasification plasma gasification and chemical looping to convert seafood shell waste into syngas and H2. The study uses validated Aspen Plus models to optimize feedstock blending ratios and operational parameters. Results show that feedstocks high in lobster and shrimp shells yield higher H2 outputs and improved syngas quality compared to clam-dominated blends. For instance biomass gasification at 1200 ◦C yielded approximately 500 kg/h of H2 from pure lobster or shrimp feeds while plasma gasification at 4500 ◦C achieved yields near 730 kg/ h. Plasma gasification when integrated with fuel cell conversion and heat recovery systems can generate over 10000 kWh during a 6-hour peak period enough to power over 1100 single-detached homes. Its levelized cost of hydrogen (LCOH) varies from $5.72-$8.37/kg H2 making it less expensive than chemical looping and biomass gasification. Plasma gasification also has the lowest global warming potential (GWP) at 6 kg CO2e/kg H2. Combining plasma gasification with carbon capture and storage may reduce GWP to 0.3 kg CO2e/kg H2 and can be further explored. These findings underscore the technical and economic viability of converting seafood shell renewable waste into H2 advancing sustainable energy transitions and supporting net-zero goals.
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