Transmission, Distribution & Storage
Leakage and Diffusion Characteristics of Underground Hydrogen Pipeline
Jun 2023
Publication
Soil corrosion and hydrogen embrittlement are the main factors of hydrogen pipeline failure. The gas escapes diffuses and accumulating in the soil and entering the atmosphere when leak occurs. The mechanism of gas diffusion in buried pipelines is very complicated. Mastering the evolution law of hydrogen leakage diffusion is conducive to quickly locating the leakage point and reducing the loss. The leakage model of the underground hydrogen pipeline is established in this paper. Effect of leakage hole soil type pipeline pressure pipeline diameter on hydrogen leakage diffusion were investigated. The results show that when the hydrogen pipeline leaks the hydrogen concentration increases with the increase of leakage time showing a symmetrical distribution trend. With the pipeline pressure increase hydrogen leakage speed is accelerated and longitudinal diffusion gradually becomes the dominant direction. With the leakage diameter increases hydrogen leakage per unit of time increases sharply. Hydrogen diffuses more easily in sandy soil and diffusion speed concentration and range are higher than that in clay soil. The research content provides a reference and basis for the detection and evaluation of buried hydrogen pipeline leakage.
First Solar Hydrogen Storage in a Private Building in Western Switzerland: Building energy Analysis and Schematic Design
Sep 2019
Publication
Self-sufficiency of buildings with carbon emission reduction can be obtained thanks to the introduction of Photovoltaics systems coupled with Hydrogen seasonal storage. To be self-sufficient over the year the electricity converted to hydrogen by electrolysis during the sunny season can be re-used with the help of fuel cells during the winter season. This article is dealing with the dimensioning methodology of a solar PV hydrogen-electrochemical system for self-sufficient buildings. We introduce the case study of the first private building in western Switzerland that will be equipped with solar hydrogen storage. Calculation results of the dimensioning of the PV system with storage will be presented. The life cycle assessment and the calculations of the environmental indicators GWP and CED will be introduced.
Complex Metal Borohydrides: From Laboratory Oddities to Prime Candidates in Energy Storage Applications
Mar 2022
Publication
Despite being the lightest element in the periodic table hydrogen poses many risks regarding its production storage and transport but it is also the one element promising pollutionfree energy for the planet energy reliability and sustainability. Development of such novel materials conveying a hydrogen source face stringent scrutiny from both a scientific and a safety point of view: they are required to have a high hydrogen wt.% storage capacity must store hydrogen in a safe manner (i.e. by chemically binding it) and should exhibit controlled and preferably rapid absorption–desorption kinetics. Even the most advanced composites today face the difficult task of overcoming the harsh re-hydrogenation conditions (elevated temperature high hydrogen pressure). Traditionally the most utilized materials have been RMH (reactive metal hydrides) and complex metal borohydrides M(BH4 )x (M: main group or transition metal; x: valence of M) often along with metal amides or various additives serving as catalysts (Pd2+ Ti4+ etc.). Through destabilization (kinetic or thermodynamic) M(BH4 )x can effectively lower their dehydrogenation enthalpy providing for a faster reaction occurring at a lower temperature onset. The present review summarizes the recent scientific results on various metal borohydrides aiming to present the current state-of-the-art on such hydrogen storage materials while trying to analyze the pros and cons of each material regarding its thermodynamic and kinetic behavior in hydrogenation studies.
Impact of Local Emergency Demand Response Programs on the Operation of Electricity and Gas Systems
Mar 2022
Publication
With increasing attention to climate change the penetration level of renewable energy sources (RES) in the electricity network is increasing. Due to the intermittency of RES gas‐fired power plants could play a significant role in backing up the RES in order to maintain the supply– demand balance. As a result the interaction between gas and power networks are significantly in‐ creasing. On the other hand due to the increase in peak demand (e.g. electrification of heat) net‐ work operators are willing to execute demand response programs (DRPs) to improve congestion management and reduce costs. In this context modeling and optimal implementation of DRPs in proportion to the demand is one of the main issues for gas and power network operators. In this paper an emergency demand response program (EDRP) is implemented locally to reduce the con‐ gestion of transmission lines and gas pipelines more efficiently. Additionally the effects of optimal implementation of local emergency demand response program (LEDRP) in gas and power networks using linear and non‐linear economic models (power exponential and logarithmic) for EDRP in terms of cost and line congestion and risk of unserved demand are investigated. The most reliable demand response model is the approach that has the least difference between the estimated demand and the actual demand. Furthermore the role of the LEDRP in the case of hydrogen injection instead of natural gas in the gas infrastructure is investigated. The optimal incentives for each bus or node are determined based on the power transfer distribution factor gas transfer distribution factor available electricity or gas transmission capability and combination of unit commitment with the LEDRP in the integrated operation of these networks. According to the results implementing the LEDRP in gas and power networks reduces the total operation cost up to 11% and could facilitate hydrogen injection to the network. The proposed hybrid model is implemented on a 24‐bus IEEE electricity network and a 15‐bus gas network to quantify the role and value of different LEDRP models.
A Novel Approach for Quantifying Hydrogen Embrittlement Using Side-grooved CT Samples
Feb 2022
Publication
Aerospace parts made of high strength steels such as landing gears and helicopter transmissions are often electroplated to satisfy various engineering specifications. However plated parts are occasionnaly rejected because of hydrogen embrittlement and the industry has few means of evaluating quantitatively the actual damage caused by hydrogen. In the present article we developed a novel method to measure the stress intensity threshold for hydrogen embrittlement (Kth) in industrial plating conditions. The method consists in plating side-grooved CT samples in industrial plating baths and measuring Kth with an incremental step loading methodology. We validated the method with a benchmark case known to produce embrittlement (omitted post-plating bake) and we used the method on a test case for which the level of embrittlement was unknown (delayed bake). For the benchmark case we measured a Kth of 49.0 MPa m0.5 for non-baked samples. This value is significantly lower than the fracture toughness of the unplated material which is 63.8 MPa m0.5 . We conclude that this novel combination of geometry and test method is efficient in quantifying hydrogen embrittlement of samples plated in industrial conditions. For the test case the Kth are respectively 57.9 MPa m0.5 and 58.8 MPa m0.5 for samples baked 100 h and 4 h after plating. We conclude that delaying the post-plating bake does not cause hydrogen embrittlement in the studied conditions. Using a finite element hydrogen diffusion analysis we argue that the side grooves on CT samples increase the sensitivity to hydrogen embrittlement in comparison to smooth samples. In smooth samples a zone of plane stress at the surface of the specimen shields hydrogen from penetrating to the center of the specimen a phenomenon which is alleviated with machining side grooves.
Techno-economic Evaluation on a Hybrid Technology for Low Hydrogen Concentration Separation and Purification from Natural Gas Grid
Jul 2020
Publication
Hydrogen can be stored and distributed by injecting into existing natural grids then at the user site separated and used in different applications. The conventional technology for hydrogen separation is pressure swing adsorption (PSA). The recent NREL study showed the extraction cost for separating hydrogen from a 10% H2 stream with a recovery of 80% is around 3.3e8.3 US$/kg. In this document new system configurations for low hydrogen concentration separation from the natural gas grid by combining novel membrane-based hybrid technologies will be described in detail. The focus of the manuscript will be on the description of different configurations for the direct hydrogen separation which comprises a membrane module a vacuum pump and an electrochemical hydrogen compressor. These technological combinations bring substantial synergy effect of one another while improving the total hydrogen recovery purity and total cost of hydrogen. Simulation has been carried out for 17 different configurations; according to the results a configuration of two-stage membrane modules (in series) with a vacuum pump and an electrochemical hydrogen compressor (EHC) shows highest hydrogen purity (99.9997%) for 25 kg/day of hydrogen production for low-pressure grid. However this configuration shows a higher electric consumption (configuration B) due to the additional mechanical compressor between the two-stage membrane modules and the EHC. Whereas when the compressor is excluded and a double skin Pd membrane (PdDS) module is used in a single stage while connected to a vacuum pump (configuration A5) the hydrogen purity (99.92%) slightly decreases yet the power consumption considerably improves (1.53 times lower). Besides to these two complementary configurations the combination of a single membrane module a vacuum pump and the electrochemical compressor has been also carried out (configuration A) and results show that relatively higher purity can be achieved. Based on four master configurations this document presents a different novel hybrid system by integrating two to three technologies for hydrogen purification combined in a way that enhances the strengths of each of them.
Optimal Configuration of the Integrated Charging Station for PV and Hydrogen Storage
Oct 2021
Publication
This paper designs the integrated charging station of PV and hydrogen storage based on the charging station. The energy storage system includes hydrogen energy storage for hydrogen production and the charging station can provide services for electric vehicles and hydrogen vehicles at the same time. To improve the independent energy supply capacity of the hybrid charging station and reduce the cost the components are reasonably configured. To minimize the configuration cost of the integrated charging station and the proportion of power purchase to the demand of the charging station the energy flow strategy of the integrated charging station is designed and the optimal configuration model of optical storage capacity is constructed. The NSGA-II algorithm optimizes the non-inferior Pareto solution set and a fuzzy comprehensive evaluation evaluates the optimal configuration.
Evaluation of Conceptual Electrolysis-based Energy Storage Systems Using Gas Expanders
Feb 2020
Publication
In this study four energy storage systems (Power-to-Gas-to-Power) were analysed that allow electrolysis products to be fully utilized immediately after they are produced. For each option the electrolysis process was supplied with electricity from a wind farm during the off-peak demand periods. In the first two variants the produced hydrogen was directed to a natural gas pipeline while the third and fourth options assumed the use of hydrogen for synthetic natural gas production. All four variants assumed the use of a gas expander powered by high-temperature exhaust gases generated during gas combustion. In the first two options gas was supplied from a natural gas network while synthetic natural gas produced during methanation was used in the other two options. A characteristic feature of all systems was the combustion of gaseous fuels within a ballast-free oxidant atmosphere without nitrogen which is the fundamental component of air in conventional systems. The fifth variant was a reference for the systems equipped with gas expanders and assumed the use of fuel cells for power generation. To evaluate the individual variants the energy storage efficiency was defined and determined and the calculated overall efficiency ranged from 17.08 to 23.79% which may be comparable to fuel cells.
Hydrogen-Assisted Cracking in GMA Welding of High-Strength Structural Steel—A New Look into This Issue at Narrow Groove
Jun 2021
Publication
Modern arc processes such as the modified spray arc (Mod. SA) have been developed for gas metal arc welding of high-strength structural steels with which even narrow weld seams can be welded. High-strength joints are subjected to increasingly stringent requirements in terms of welding processing and the resulting component performance. In the present work this challenge is to be met by clarifying the influences on hydrogen-assisted cracking (HAC) in a high-strength structural steel S960QL. Adapted samples analogous to the self-restraint TEKKEN test are used and analyzed with respect to crack formation microstructure diffusible hydrogen concentration and residual stresses. The variation of the seam opening angle of the test seams is between 30° and 60°. To prevent HAC the effectiveness of a dehydrogenation heat treatment (DHT) from the welding heat is investigated. As a result the weld metals produced at reduced weld opening angle show slightly higher hydrogen concentrations on average. In addition increased micro- as well as macro-crack formation can be observed on these weld metal samples. On all samples without DHT cracks in the root notch occur due to HAC which can be prevented by DHT immediately after welding.
Sizing Hydrogen Energy Storage in Consideration of Demand Response in Highly Renewable Generation Power Systems
May 2018
Publication
From an environment perspective the increased penetration of wind and solar generation in power systems is remarkable. However as the intermittent renewable generation briskly grows electrical grids are experiencing significant discrepancies between supply and demand as a result of limited system flexibility. This paper investigates the optimal sizing and control of the hydrogen energy storage system for increased utilization of renewable generation. Using a Finnish case study a mathematical model is presented to investigate the optimal storage capacity in a renewable power system. In addition the impact of demand response for domestic storage space heating in terms of the optimal sizing of energy storage is discussed. Finally sensitivity analyses are conducted to observe the impact of a small share of controllable baseload production as well as the oversizing of renewable generation in terms of required hydrogen storage size.
A Review of Hydrogen Production and Supply Chain Modeling and Optmization
Jan 2023
Publication
This paper reviews recent optimization models for hydrogen supply chains and production. Optimization is a central component of systematic methodologies to support hydrogen expansion. Hydrogen production is expected to evolve in the coming years to help replace fossil fuels; these high expectations arise from the potential to produce low-carbon hydrogen via electrolysis using electricity generated by renewable sources. However hydrogen is currently mainly used in refinery and industrial operations; therefore physical infrastructures for transmission distribution integration with other energy systems and efficient hydrogen production processes are lacking. Given the potential of hydrogen the greenfield state of infrastructures and the variability of renewable sources systematic methodologies are needed to reach competitive hydrogen prices and design hydrogen supply chains. Future research topics are identified: 1) improved hydrogen demand projections 2) integrated sector modeling 3) improving temporal and spatial resolutions 4) accounting for climate change 5) new methods to address sophisticated models.
AI Agents Envisioning the Future: Forecast-based Operation of Renewable Energy Storage Systems Using Hydrogen with Deep Reinforcement Learning
Feb 2022
Publication
Hydrogen-based energy storage has the potential to compensate for the volatility of renewable power generation in energy systems with a high renewable penetration. The operation of these storage facilities can be optimized using automated energy management systems. This work presents a Reinforcement Learning-based energy management approach in the context of CO2-neutral hydrogen production and storage for an industrial combined heat and power application. The economic performance of the presented approach is compared to a rule-based energy management strategy as a lower benchmark and a Dynamic Programming-based unit commitment as an upper benchmark. The comparative analysis highlights both the potential benefits and drawbacks of the implemented Reinforcement Learning approach. The simulation results indicate a promising potential of Reinforcement Learning-based algorithms for hydrogen production planning outperforming the lower benchmark. Furthermore a novel approach in the scientific literature demonstrates that including energy and price forecasts in the Reinforcement Learning observation space significantly improves optimization results and allows the algorithm to take variable prices into account. An unresolved challenge however is balancing multiple conflicting objectives in a setting with few degrees of freedom. As a result no parameterization of the reward function could be found that fully satisfied all predefined targets highlighting one of the major challenges for Reinforcement Learning -based energy management algorithms to overcome.
The Role of Hydrogen in the Corrosion and Cracking of Steels - A Review
Oct 2021
Publication
In many processes of steel industrial including steel manufacture storage and service hydrogen could be absorbed into metallic materials and the absorbed hydrogen seriously impaired its corrosion resistance. This paper provides a comprehensive review on the effects of hydrogen on passive film anodic dissolution pitting corrosion and stress corrosion cracking and based on the review the mechanism by which hydrogen promotes corrosion of steel and subsequently leads to cracking has been discussed. It is envisaged that hydrogen harms the stability of the passive film and as a result escalates anode’s activation of steel eventually leading to pitting and stress corrosion cracking.
Everything About Hydrogen Podcast: Storage for the Future!
Jan 2022
Publication
For our first episode of 2022 we invited Jørn Helge Dahl Global Director of Sales&Marketing at Hexagon Purus to talk about hydrogen storage with the EAH podcast and to explain the types of solutions available today Hexagon's history and plans for the future alongside some commentary on US hydrogen strategy from the gang.
The podcast can be found on their website
The podcast can be found on their website
A Comparative Study for H2 –CH4 Mixture Wettability in Sandstone Porous Rocks Relevant to Underground Hydrogen Storage
Mar 2022
Publication
Characterizing the wettability of hydrogen (H2 )–methane (CH4 ) mixtures in subsurface reservoirs is the first step towards understanding containment and transport properties for underground hydrogen storage (UHS). In this study we investigate the static contact angles of H2 –CH4 mixtures in contact with brine and Bentheimer sandstone rock using a captive-bubble cell device at different pressures temperatures and brine salinity values. It is found that under the studied conditions H2 and CH4 show comparable wettability behaviour with contact angles ranging between [25◦–45◦ ]; and consequently their mixtures behave similar to the pure gas systems independent of composition pressure temperature and salinity. For the system at rest the acting buoyancy and surface forces allow for theoretical sensitivity analysis for the captive-bubble cell approach to characterize the wettability. Moreover it is theoretically validated that under similar Bond numbers and similar bubble sizes the contact angles of H2 and CH4 bubbles and their mixtures are indeed comparable. Consequently in large-scale subsurface storage systems where buoyancy and capillary are the main acting forces H2 CH4 and their mixtures will have similar wettability characteristics.
Simulation of the Inelastic Deformation of Porous Reservoirs Under Cyclic Loading Relevant for Underground Hydrogen Storage
Dec 2022
Publication
Subsurface geological formations can be utilized to safely store large-scale (TWh) renewable energy in the form of green gases such as hydrogen. Successful implementation of this technology involves estimating feasible storage sites including rigorous mechanical safety analyses. Geological formations are often highly heterogeneous and entail complex nonlinear inelastic rock deformation physics when utilized for cyclic energy storage. In this work we present a novel scalable computational framework to analyse the impact of nonlinear deformation of porous reservoirs under cyclic loading. The proposed methodology includes three diferent time-dependent nonlinear constitutive models to appropriately describe the behavior of sandstone shale rock and salt rock. These constitutive models are studied and benchmarked against both numerical and experimental results in the literature. An implicit time-integration scheme is developed to preserve the stability of the simulation. In order to ensure its scalability the numerical strategy adopts a multiscale fnite element formulation in which coarse scale systems with locally-computed basis functions are constructed and solved. Further the efect of heterogeneity on the results and estimation of deformation is analyzed. Lastly the Bergermeer test case—an active Dutch natural gas storage feld—is studied to investigate the infuence of inelastic deformation on the uplift caused by cyclic injection and production of gas. The present study shows acceptable subsidence predictions in this feld-scale test once the properties of the fnite element representative elementary volumes are tuned with the experimental data.
Machine Learning Approach for Prediction of Hydrogen Environment Embrittlement in Austenitic Steels
Jun 2022
Publication
This study introduces a machine learning approach to predict the effect of alloying elements and test conditions on the hydrogen environment embrittlement (HEE) index of austenitic steels for the first time. The correlation between input features and the HEE index was analyzed with Pearson's correlation coefficient (PCC) and Maximum Information Coefficient (MIC) algorithms. The correlation analysis results identified Ni and Mo as dominant features influencing the HEE index of austenitic steels. Based on the analysis results the performance of the four representative machine learning models as a function of the number of top-ranked features was evaluated: random forest (RF) linear regression (LR) Bayesian ridge (BR) and support vector machine (SVM). Regardless of the type and the number of top-ranking features the RF model had the highest accuracy among various models. The machine learning-based approach is expected to be useful in designing new steels having mechanical properties required for hydrogen applications.
Thermodynamic Performance Comparison of Various Energy Storage Systems from Source-to-electricity for Renewable Energy Resources
Dec 2020
Publication
This study discusses and thermodynamically analyzes several energy storage systems namely; pumped hydro compressed air hot water storage molten salt thermal storage hydrogen ammonia lithium-ion battery Zn-air battery redox flow battery reversible fuel cells supercapacitors and superconducting magnetic storage through the first and second law of thermodynamics. By fixing an electrical output of 100 kW for all systems the energy efficiencies obtained for the considered energy storage methods vary between 10.9% and 74.6% whereas the exergy efficiencies range between 23.1% and 71.9%. The exergy destruction rates are also calculated for each system ranging from 1.640 kW to 356 kW. The highest destruction rate is obtained for the solar-driven molten salt thermal energy storage system since it includes thermal energy conversion via the heliostat field. Furthermore the roundtrip efficiencies for the electrochemical and electromagnetic storage systems are compared with the analyzed systems ranging from 58% to 94%. Renewable sources (solar wind ocean current biomass and geothermal) energy conversion efficiencies are also considered for the final round-trip performances. The molten salt and hot water systems are applicable to solar geothermal and biomass. The highest source-to-electricity efficiency is obtained for the super magnetic storage with 37.6% when using wind ocean current and biomass sources.
On the Bulk Transport of Green Hydrogen at Sea: Comparison Between Submarine Pipeline and Compressed and Liquefied Transport by Ship
Jan 2023
Publication
This paper compares six (6) alternatives for green hydrogen transport at sea. Two (2) alternatives of liquid hydrogen (LH2) by ship two (2) alternatives of compressed hydrogen (cH2) by ship and two (2) alternatives of hydrogen by pipeline. The ship alternatives study having hydrogen storage media at both end terminals to reduce the ships’ time at port or prescinding of them and reduce the immobilized capital. In the case of the pipeline new models are proposed by considering pressure costs. One scenario considers that there are compression stations every 500 km and the other one considers that there are none along the way. These alternatives are assessed under nine different scenarios that combine three distances: 100 km 2500 km and 5000 km; and three export rates of hydrogen 100 kt/y 1 Mt/y and 10 Mt/y. The results show including uncertainty bands that for the 100 km of distance the best alternative is the pipeline. For 2500 km and 100 kt/y the top alternative is cH2 shipping without storage facilities at the port terminals. For 2500 km and 1 Mt/y and for 5000 km and 100 kt/y the best alternatives are cH2 or LH2 shipping. For the remaining scenarios the best alternative is LH2 shipping.
Techno-economic Assessment of Low-carbon Hydrogen Export from Western Canada to Eastern Canada, the USA, the Asia-Pacific, and Europe
Dec 2021
Publication
The use of low-carbon hydrogen is being considered to help decarbonize several jurisdictions around the world. There may be opportunities for energy-exporting countries to supply energy-importing countries with a secure source of low-carbon hydrogen. The study objective is to assess the delivered cost of gaseous hydrogen export from Canada (a fossil-resource rich country) to the Asia-Pacific Europe and inland destinations in North America. There is a data gap on the feasibility of inter-continental export of hydrogen from an energy-producing jurisdiction to energy-consuming jurisdictions. This study is aimed at addressing this gap and includes an assessment of opportunities across the Pacific Ocean and the Atlantic Ocean based on fundamental engineering-based models. Techno-economics were used to determine the delivered cost of hydrogen to these destinations. The modelling considers energy material and capacity-sizing requirements for a five-stage supply chain comprising hydrogen production with carbon capture and storage hydrogen pipeline transportation liquefaction shipping and regasification at the destinations. The results show that the delivered cost of hydrogen to inland destinations in North America is between CAD$4.81/kg and CAD$6.03/kg to the Asia-Pacific from CAD$6.65/kg to CAD$6.99/kg and at least CAD$8.14/kg for exports to Europe. Delivering hydrogen by blending in existing long-distance natural gas pipelines reduced the delivered cost to inland destinations by 17%. Exporting ammonia to the Asia-Pacific provides cost savings of 28% compared to shipping liquified hydrogen. The developed information may be helpful to policymakers in government and the industry in making informed decisions about international trade of low-carbon hydrogen in both energy-exporting and energy-importing jurisdictions globally.
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