Canada
Investigating the Effects of Flow Regime on Hydrogen Transport in Salt Rock
Jun 2025
Publication
Underground hydrogen storage (UHS) in salt caverns is emerging as a promising solution for the transition to a sustainable energy future. However a thorough understanding of hydrogen flow mechanisms through salt rock is essential to ensure safe and efficient storage operations. In this study we conducted hydrogen flow experiments in salt rocks using the pressure pulse decay (PPD) method covering a range of hydrogen pore pressures from 0.4 MPa to 7.5 MPa within the slip and transitional flow regimes (Knudsen numbers between 0.04 and 1.5). The Knudsen numbers were determined by measuring the pore size distribution (PSD) of the salt rock samples and assigning an average pore size to each sample based on the measured PSD. Our results indicate that the intrinsic permeability of the tested salt rock samples ranges from 5 × 10− 21 m2 to 1.0 × 10− 20 m2 . However a significant enhancement in apparent permeability up to 10 times the intrinsic permeability was observed particularly at lower pressures. This permeability enhancement is attributed to the nanoscale pore structure of salt rocks where the mean free path of hydrogen becomes comparable to the pore sizes leading to a shift from slip flow to the transitional flow regime. The results further reveal that the first-order slip model underestimates the apparent permeability in the transitional flow regime despite its satisfactory accuracy in the slip region. Moreover the higher-order slip model demonstrates acceptable accuracy across both the slip and transitional flow regimes.
Hydrogen Storage Systems at Ports for Enhanced Safety and Sustainability: A Review
Sep 2025
Publication
With the increasing demand for clean energy and the global push toward carbon neutrality hydrogen has emerged as a promising alternative fuel. Ports are critical nodes in the hydrogen supply chain that are increasingly being utilized as long-term hydrogen storage hubs. However integrating hydrogen storage systems into port infrastructure presents unique technical environmental and safety challenges. This review systematically examines current technologies used for hydrogen storage in port environments—including compressed gas cryogenic liquid cryocompressed gas ammonia liquid organic hydrogen carriers solid-state hydrides and underground storage. Each technology is evaluated based on performance infrastructure requirements accident risks environmental impact and cost. The study also assesses port-specific infrastructure vulnerabilities under operational stress and climate change conditions and explores strategies for accident prevention emergency response and postincident recovery. A comprehensive framework is proposed to enhance the resilience and safety of hydrogen storage systems at ports. This study offers valuable insights for stakeholders and researchers by addressing technical gaps regulatory challenges and future directions for sustainable and safe hydrogen storage in port facilities
Green Hydrogen Viability in the Transition to a Fully-Renewable Energy Grid
Sep 2025
Publication
With the transition to a fully renewable energy grid arises the need for a green source of stability and baseload support which classical renewable generation such as wind and solar cannot offer due to their uncertain and highly-variable generation. In this paper we study whether green hydrogen can close this gap as a source of supplemental generation and storage. We design a two-stage mixed-integer stochastic optimization model that accounts for uncertainties in renewable generation. Our model considers the investment in renewable plants and hydrogen storage as well as the operational decisions for running the hydrogen storage systems. For the data considered we observe that a fully renewable network driven by green hydrogen has a greater potential to succeed when wind generation is high. In fact the main investment priorities revealed by the model are in wind generation and in liquid hydrogen storage. This long-term storage is more valuable for taking full advantage of hydrogen than shorter-term intraday hydrogen gas storage. In addition we note that the main driver for the potential and profitability of green hydrogen lies in the electricity demand and prices as opposed to those for gas. Our model and the investment solutions proposed are robust with respect to changes in the investment costs. All in all our results show that there is potential for green hydrogen as a source of baseload support in the transition to a fully renewable-powered energy grid.
Case Study of a Greenfield Blue Hydrogen Plant: A Comparative Analysis of Production Methods
Jun 2025
Publication
Blue hydrogen is a key pathway for reducing greenhouse gas emissions while utilizing natural gas with carbon capture and storage (CCS). This study conducts a techno-economic and environmental analysis of a greenfield blue hydrogen plant in Saskatchewan Canada integrating both SMR and ATR technologies. Unlike previous studies that focus mainly on production units this research includes all process and utility systems such as H2 and CO2 compression air separation refrigeration co-generation and gas dehydration. Aspen HYSYS simulations revealed ATR’s energy demand is 10% lower than that of SMR. The hydrogen production cost was USD 3.28/kg for ATR and USD 3.33/kg for SMR while a separate study estimated a USD 2.2/kg cost for design without utilities highlighting the impact of indirect costs. Environmental analysis showed ATR’s lower Global Warming Potential (GWP) compared to SMR reducing its carbon footprint. The results signified the role of utility integration site conditions and process selection in optimizing energy efficiency costs and sustainability.
Exploring the Gas Permeability of Type IV Hydrogen Storage Cylinder Liners: Research and Applications
Jul 2025
Publication
As hydrogen fuel cell vehicles gain momentum as crucial zero-emission transportation solutions the urgency to address hydrogen permeability through the polymer liner becomes paramount for ensuring the safety efficiency and longevity of Type IV hydrogen storage tanks. This paper synthesizes existing research findings analyzes the influence of different materials and structures on gas permeability elucidates the dissolution and diffusion mechanisms of hydrogen in plastic liners and discusses their engineering applications. We focus on measurement methods influencing factors and improvement strategies for liner gas permeability. Additionally we explore the prospects of Type IV hydrogen storage tanks in fields such as automotive aerospace and energy storage industries. Through this comprehensive review of liner gas permeability critical insights are provided to guide the development of efficient and safe hydrogen storage and transportation systems. These insights are vital for advancing the widespread application of hydrogen energy technology and fostering sustainable energy development significantly contributing to efforts aimed at enhancing the performance and safety of Type IV hydrogen storage tanks.
Assessment of Carbon-abatement Pricing to Maximize the Value of Electrolytic Hydrogen in Emissions-intensive Power Sectors
Aug 2025
Publication
Electrolytic hydrogen can support the decarbonization of the power sector. Achieving cost-effective power-to-gas-to-power (PGP) integration through targeted emissions pricing can accelerate the adoption of electrolytic hydrogen in greenhouse gas-intensive power sectors. This study develops a framework for assessing the economic viability of electrolytic hydrogen-based PGP systems in fossil fuel-dependent grids while considering the competing objectives of the electricity system operator a risk-averse investor and the government. Here we show that given the risk-averse investor’s inherent pursuit of profit maximization a break-even carbon abatement cost of at least 57 Canadian Dollars per tonne of CO₂ by 2030 from the government with a shift in electricity market dispatch rules from sole system marginal pricereduction to system-wide emissions reduction is essential to stimulate price discovery for low-cost hydrogen production and contingency reserve provision by the PGP system. This work can help policymakers capture and incentivize the role of electrolytic hydrogen in low-carbon power sector planning.
Advancing Hydrogen Sustainability in Alberta: Life Cycle Sustainability Assessment of Hydrogen Production Pathways
Oct 2025
Publication
This study conducts a Life Cycle Sustainability Assessment (LCSA) of hydrogen production pathways in Alberta Canada evaluating environmental economic and social dimensions. Eight pathways are analyzed: steam methane reforming (SMR) with and without carbon capture and storage (CCS) autothermal reforming (ATR) with and without CCS and with and without grid electricity as well as alkaline electrolysis using grid and wind electricity. While alkaline electrolysis with wind electricity shows the best performance under the climate change and ozone depletion categories ATR + CCS (CO2 capture rate of 91 % no-grid electricity) demonstrates the strongest performance in seven of nine environmental impact categories being the worst performer in none and having the lowest social risks. Economically SMR and ATR without CCS exhibit the lowest levelized cost of hydrogen followed by ATR + CCS (CO2 capture rate of 91 % no-grid electricity). ATR + CCS (CO2 capture rate of 91 % no-grid electricity) emerges as a promising pathway offering an overall balance of sustainability under the current study’s assumptions. The results suggest that a blue hydrogen to electricity scenario where ATR + CCS with 100 % on-site hydrogen-fueled power generation replaces grid electricity may be the most suitable pathway for hydrogen production in Alberta. Key recommendations include optimizing environmental performance in climate change and ozone depletion impacts reducing costs and mitigating social risks in ATR pathways. This LCSA supports policies and investments to advance hydrogen’s role in Alberta’s decarbonization and energy transition.
Development of Newly Designed Biomass-based Electrodes used in Water Electrolysis for Clean Hydrogen Production
Oct 2025
Publication
The conventional electrolysis is recognized as a mature and promising hydrogen (H2) production technology but there is still a strong need for further performance improvement. In this regard achieving an effective H2 evolution reaction at the cathode requires costly catalysts such as platinum and various catalyst-modified electrode materials. Nevertheless these materials are expensive and involve complex production procedures. Due to an increasing interest in deploying biomaterial-based cathodes as potential alternatives to conventional cathode materials we make the focus of this study on such materials and a graphite-loaded bioelectrode is in this regard synthesized for electrolysis application for effective H2 production. The surface morphology and electrochemical activity of the produced biocathode are characterized. Our results show that the H2 production performance of the system improves with the increasing graphite dosage on the biocathode and with the applied voltage ranging from 2 to 6 V. At improved operating conditions the highest H2 production rate of 1000 ppm (8.18 mg/m3 min) is obtained using a 1.5 g graphite-loaded biocathode at an applied voltage of 6 V. Consequently the produced graphite-loaded biocathode can be a promising option for sustainable and effective H2 production with waste minimization owing to its high conductivity low-cost and good stability.
Transient Analysis of Solar Driven Hydrogen Generation System Using Industrial Waste Water
Oct 2025
Publication
This study investigates an integrated solar-powered system for wastewater treatment and hydrogen production combining solar PV a humidification–dehumidification (HDH) system solar thermal collectors and electrolysis. The objective is to evaluate the feasibility of utilizing industrial wastewater for both clean water production and green hydrogen generation. A transient analysis is conducted using TRNSYS and EES software modeling a system designed to process 4000 kg of wastewater daily. The results indicate that the HDH system produces 300 kg of clean water per hour while the electrolyzer generates approximately 66.5 kg of hydrogen per hour. The solar PV system operates under the weather conditions of Kohat Pakistan. This integrated approach demonstrates significant potential for sustainable wastewater treatment and renewable energy production offering a promising solution for industrial applications.
Life Cycle and Economic Viability Assessment of Clean Hydrogen as a Fuel in Corn Drying
Oct 2025
Publication
This study presents a comparative life cycle and economic assessment of using clean hydrogen as a sustainable alternative to natural gas and propane for corn grain drying. The study compares the environmental performance limited to GWP100 and cost-effectiveness of hydrogen from various renewable sources (hydro wind solar) and plasma pyrolysis of natural gas against conventional fossil fuels under two delivery scenarios: pipeline and trucking. A life cycle assessment is conducted using Open LCA to quantify the carbon intensity of each fuel from cradle to combustion at multiple energy requirements based on four burner efficiencies across each scenario. In parallel economic analysis is conducted by calculating the fuel cost required per ton of dried corn grains at each efficiency across both scenarios. The results indicate that green hydrogen consistently outperforms current fuels in terms of emissions but it is generally more expensive at lower burner efficiencies and in trucking scenarios. However the cost competitiveness of green hydrogen improves significantly at higher efficiency and with pipeline infrastructure development it can become more economical when compared to propane. Hydrogen produced via plasma pyrolysis offers high environmental and economic costs due to its electricity and natural gas requirements. Sensitivity analysis further explores the impact of a 50% reduction in hydrogen production and transportation costs revealing that hydrogen could become a viable option for grain drying in both pipeline and trucking scenarios. This study highlights the long-term potential of hydrogen in reducing carbon emissions and offers insights into the economic feasibility of hydrogen adoption in agricultural drying processes. The findings suggest that strategic investments in hydrogen infrastructure could significantly enhance the sustainability of agricultural practices paving the way for a greener future in food production.
Hybrid Renewable Energy Systems for Off-Grid Electrification: A Comprehensive Review of Storage Technologies, Metaheuristic Optimization Approaches and Key Challenges
Nov 2025
Publication
Hybrid Renewable Energy Systems (HRESs) are a practical solution for providing reliable low-carbon electricity to off-grid and remote communities. This review examines the role of energy storage within HRESs by systematically comparing electrochemical mechanical thermal and hydrogen-based technologies in terms of technical performance lifecycle cost operational constraints and environmental impact. We synthesize findings from implemented off-grid projects across multiple countries to evaluate real-world performance metrics including renewable fraction expected energy not supplied (EENS) lifecycle cost and operation & maintenance burdens. Special attention is given to the emerging role of hydrogen as a long-term and cross-sector energy carrier addressing its technical regulatory and financial barriers to widespread deployment. In addition the paper reviews real-world implementations of off-grid HRES in various countries summarizing practical outcomes and lessons for system design and policy. The discussion also includes recent advances in metaheuristic optimization algorithms which have improved planning efficiency system reliability and cost-effectiveness. By combining technological operational and policy perspectives this review identifies current challenges and future directions for developing sustainable resilient and economically viable HRES that can accelerate equitable electrification in remote areas. Finally the review outlines key limitations and future directions calling for more systematic quantitative studies long-term field validation of emerging technologies and the development of intelligent Artificial Intelligence (AI)-driven energy management systems within broader socio-techno-economic frameworks. Overall this work offers concise insights to guide researchers and policymakers in advancing the practical deployment of sustainable and resilient HRES.
Sustainable Power System Transition Pathways: Regional Decarbonisation and Resource Conservation Aided by Small Modular Reactors
Oct 2025
Publication
Clean energy technologies offer promising pathways for low-carbon transitions yet their feasibility remains uncertain particularly in rapidly developing regions. This study develops a Factorial Multi-Stochastic Optimization-driven Equilibrium (FMOE) model to assess the economic and environmental impacts of clean power deployment. Using Small Modular Reactors (SMRs) in Guangdong China as a case study the model reveals that SMRs can reduce system costs and alleviate GDP losses supporting provincial-level Nationally Determined Contributions (NDCs). If offshore wind capital costs fall to 40 % of SMRs’ SMR deployment may no longer be necessary after 2030. Otherwise SMRs could supply 22 % of capacity by 2040. The FMOE model provides a robust adaptable framework for evaluating emerging technologies under uncertainty and supports sustainable power planning across diverse regional contexts. This study offers valuable insights into the resource and economic implications of clean energy strategies contributing to global carbon neutrality and efficient energy system design.
Development of a High-performance Electrolyzer for Efficient Hydrogen Production via Electrode Modification with a Commercial Catalyst
Oct 2025
Publication
A potential strategy to promote the use of clean energy is the development of catalyst-coated cathodic electrodes that are economical effective and sustainable to enhance the generation of hydrogen (H2) through the electrolysis process. This study investigates the unique design and use of stainless steel (SS) coated with a CuNiZnFeOx catalyst as both anode and cathode electrodes in the alkaline electrolysis process. The electrode exhibits an improved electrochemical behavior achieving a current density of 92 mA/cm2 at an applied voltage of 2.5 V with a surface area of 36 cm2 in 1 M KOH electrolyte at 25 ◦C. Furthermore the H2 production is systematically investigated by varying electrolyte concentration applied voltage and temperature. The results demonstrate that H2 production increases significantly with enhanced electrolyte concentration (3102 mL at 2 M KOH) applied voltage (3468 mL at 3.0 V) and temperature (3202 mL at 60 ◦C) over a 300 min electrolysis time. However optimal operating conditions are determined to be 1 M KOH 2.5 V and 25 ◦C balancing performance and energy efficiency. The improved performance is primarily attributed to enhanced ionic conductivity reduced internal resistance and the synergistic catalytic activity of the Cu-integrated NiZnFeOx coating.
Energy Management of Hybrid Energy System Considering a Demand-Side Management Strategy and Hydrogen Storage System
Oct 2025
Publication
A hybrid energy system (HES) integrates various energy resources to attain synchronized energy output. However HES faces significant challenges due to rising energy consumption the expenses of using multiple sources increased emissions due to non-renewable energy resources etc. This study aims to develop an energy management strategy for distribution grids (DGs) by incorporating a hydrogen storage system (HSS) and demand-side management strategy (DSM) through the design of a multi-objective optimization technique. The primary focus is on optimizing operational costs and reducing pollution. These are approached as minimization problems while also addressing the challenge of achieving a high penetration of renewable energy resources framed as a maximization problem. The third objective function is introduced through the implementation of the demand-side management strategy aiming to minimize the energy gap between initial demand and consumption. This DSM strategy is designed around consumers with three types of loads: sheddable loads non-sheddable loads and shiftable loads. To establish a bidirectional communication link between the grid and consumers by utilizing a distribution grid operator (DGO). Additionally the uncertain behavior of wind solar and demand is modeled using probability distribution functions: Weibull for wind PDF beta for solar and Gaussian PDF for demand. To tackle this tri-objective optimization problem this work proposes a hybrid approach that combines well-known techniques namely the non-dominated sorting genetic algorithm II and multi-objective particle swarm optimization (Hybrid-NSGA-II-MOPSO). Simulation results demonstrate the effectiveness of the proposed model in optimizing the tri-objective problem while considering various constraints.
Computational Fluid Dynamic Modeling and Parametric Optimization of Hydrogen Adsorption in Stationary Hydrogen Tanks
Nov 2025
Publication
This study investigates hydrogen storage enhancement through adsorption in porous materials by coupling the Dubinin–Astakhov (D-A) adsorption model with H2 conservation equations (mass momentum and energy). The resulting system of partial differential equations (PDEs) was solved numerically using the finite element method (FEM). Experimental work using activated carbon as an adsorbent was carried out to validate the model. The comparison showed good agreement in terms of temperature distribution average pressure of the system and the amount of adsorbed hydrogen (H2). Further simulations with different adsorbents indicated that compact metal–organic framework 5 (MOF-5) is the most effective material in terms of H2 adsorption. Additionally the pair (273 K 800 s) remains the optimal combination of injection temperature and time. The findings underscore the prospective advantages of optimized MOF-5-based systems for enhanced hydrogen storage. These systems offer increased capacity and safety compared to traditional adsorbents. Subsequent research should investigate multi-objective optimization of material properties and system geometry along with evaluating dynamic cycling performance in practical operating conditions. Additionally experimental validation on MOF-5-based storage prototypes would further reinforce the model’s predictive capabilities for industrial applications.
No more items...