Switzerland
Reversible Solid-oxide Cell Stack Based Power-to-x-to-power Systems: Comparison of Thermodynamic Performance
Jun 2020
Publication
The increasing penetration of variable renewable energies poses new challenges for grid management. The economic feasibility of grid-balancing plants may be limited by low annual operating hours if they work either only for power generation or only for power storage. This issue might be addressed by a dual-function power plant with power-to-x capability which can produce electricity or store excess renewable electricity into chemicals at different periods. Such a plant can be uniquely enabled by a solid-oxide cell stack which can switch between fuel cell and electrolysis with the same stack. This paper investigates the optimal conceptual design of this type of plant represented by power-to-x-to-power process chains with x being hydrogen syngas methane methanol and ammonia concerning the efficiency (on a lower heating value) and power densities. The results show that an increase in current density leads to an increased oxygen flow rate and a decreased reactant utilization at the stack level for its thermal management and an increased power density and a decreased efficiency at the system level. The power-generation efficiency is ranked as methane (65.9%) methanol (60.2%) ammonia (58.2%) hydrogen (58.3%) syngas (53.3%) at 0.4 A/cm2 due to the benefit of heat-to-chemical-energy conversion by chemical reformulating and the deterioration of electrochemical performance by the dilution of hydrogen. The power-storage efficiency is ranked as syngas (80%) hydrogen (74%) methane (72%) methanol (68%) ammonia (66%) at 0.7 A/cm2 mainly due to the benefit of co-electrolysis and the chemical energy loss occurring in the chemical synthesis reactions. The lost chemical energy improves plant-wise heat integration and compensates for its adverse effect on power-storage efficiency. Combining these efficiency numbers of the two modes results in a rank of round-trip efficiency: methane (47.5%)>syngas (43.3%) ≈ hydrogen (42.6%)>methanol (40.7%)>ammonia (38.6%). The pool of plant designs obtained lays the basis for the optimal deployment of this balancing technology for specific applications.
Planetary Boundaries Assessment of Deep Decarbonisation Options for Building Heating in the European Union
Jan 2023
Publication
Building heating is one of the sectors for which multiple decarbonisation options exist and current geopolitical tensions provide urgency to design adequate regional policies. Heat pumps and hydrogen boilers alongside alternative district heating systems are the most promising alternatives. Although a host of city or country-level studies exist it remains controversial what role hydrogen should play for building heating in the European Union compared with electrification and how blue and green hydrogen differ in terms of costs and environmental impacts. This works assesses the optimal technology mix for staying within planetary boundaries and the influence of international cooperation and political restrictions. To perform the analysis a bottom-up optimisation model was developed incorporating life cycle assessment constraints and covering production storage transport of energy and carbon dioxide as well as grid and non-grid connected end-users of heat. It was found that a building heating system within planetary boundaries is feasible through large-scale electrification via heat pumps although at a higher cost than the current system with abatement costs of around 200 €/ton CO2. Increasing interconnector capacity or onshore wind energy is found to be vital to staying within boundaries. A strong trade-off for hydrogen was identified with blue hydrogen being cost-competitive but vastly unsustainable (when applied to heating) and green hydrogen being 2–3 times more expensive than electrification while still transgressing several planetary boundaries. The insights from this work indicate that heat pumps and renewable electricity should be prioritised over hydrogen-based heating in most cases and grid-stability and storage aspects explored further while revealing a need for policy instruments to mitigate increased costs for consumers.
Investigations on Pressure Dependence of Coriolis Mass Flow Meters Used at Hydrogen Refueling Stations
Sep 2020
Publication
In the framework of the ongoing EMPIR JRP 16ENG01 ‘‘Metrology for Hydrogen Vehicles’’ a main task is to investigate the influence of pressure on the measurement accuracy of Coriolis Mass Flow Meters (CFM) used at Hydrogen Refueling Stations (HRS). At a HRS hydrogen is transferred at very high and changing pressures with simultaneously varying flow rates and temperatures. It is clearly very difficult for CFMs to achieve the current legal requirements with respect to mass flow measurement accuracy at these measurement conditions. As a result of the very dynamic filling process it was observed that the accuracy of mass flow measurement at different pressure ranges is not sufficient. At higher pressures it was found that particularly short refueling times cause significant measurement deviations. On this background it may be concluded that pressure has a great impact on the accuracy of mass flow measurement. To gain a deeper understanding of this matter RISE has built a unique high-pressure test facility. With the aid of this newly developed test rig it is possible to calibrate CFMs over a wide pressure and flow range with water or base oils as test medium. The test rig allows calibration measurements under the conditions prevailing at a 70 MPa HRS regarding mass flows (up to 3.6 kg min−1) and pressures (up to 87.5 MPa).
Heat Transfer Analysis of High Pressure Hydrogen Tank Fillings
Jun 2022
Publication
Fast fillings of hydrogen vehicles require proper control of the temperature to ensure the integrity of the storage tanks. This study presents an analysis of heat transfer during filling of a hydrogen tank. A conjugate heat transfer based on energy balance is introduced. The numerical model is validated against fast filling experiments of hydrogen in a Type IV tank by comparing the gas temperature evolution. The impact of filling parameters such as initial temperature inlet nozzle diameter and filling time is then assessed. For the considered Type IV tank the results show that both a higher and lower tank shell thermal conductivity results in lower inner wall peak temperatures. The presented model provides an analytical description of the temperature evolution in the gas and in the tank shell and is thus a useful tool to explore a broad range of parameters e.g. to determine new hydrogen filling protocols.
Polymer Electrolyte Membrane Electrolyzer and Fuel Cell System Characterization for Power System Frequency Control
Mar 2022
Publication
This work focuses on tests for control reserve of a novel Power-to-Gas-to-Power platform based on proton exchange membrane technologies and on pure oxygen instead of air in the re-electrification process. The technologies are intended as a further option to stabilize the power system therefore helping integrating renewable energy into the power system. The tests are based on the pre-qualification tests used by Swissgrid but are not identical in order to capture the maximum dynamics by the plants. The main characteristics identified are the ramping capabilities of ±8% per unit per second for the electrolyzer system and ±33% per unit per second for the fuel cell system. The ramping capabilities are mainly limited by the underlying processes of polymer electrolyte membrane technologies. Additionally the current and projected round-trip efficiencies for Power-to-Gas-to-Power of 39% in 2025 and 48% in 2040 are derived. Furthermore during the successful tests the usage of oxygen in the present Power-to-Gas and Gas-to-Power processes and its influence on the dynamics and the round-trip efficiency was assessed. In consequence fundamental data on the efficiency and the dynamics of the Power-to-Gas-to-Power technologies is presented. This data can serve as basis for prospective assessments on the suitability of the technologies investigated for frequency control in power systems.
Life Cycle Assessment and Economic Analysis of an Innovative Biogas Membrane Reformer for Hydrogen Production
Feb 2019
Publication
This work investigates the environmental and economic performances of a membrane reactor for hydrogen production from raw biogas. Potential benefits of the innovative technology are compared against reference hydrogen production processes based on steam (or autothermal) reforming water gas shift reactors and a pressure swing adsorption unit. Both biogas produced by landfill and anaerobic digestion are considered to evaluate the impact of biogas composition. Starting from the thermodynamic results the environmental analysis is carried out using environmental Life cycle assessment (LCA). Results show that the adoption of the membrane reactor increases the system efficiency by more than 20 percentage points with respect to the reference cases. LCA analysis shows that the innovative BIONICO system performs better than reference systems when biogas becomes a limiting factor for hydrogen production to satisfy market demand as a higher biogas conversion efficiency can potentially substitute more hydrogen produced by fossil fuels (natural gas). However when biogas is not a limiting factor for hydrogen production the innovative system can perform either similar or worse than reference systems as in this case impacts are largely dominated by grid electric energy demand and component use rather than conversion efficiency. Focusing on the economic results hydrogen production cost shows lower value with respect to the reference cases (4 €/kgH2 vs 4.2 €/kgH2) at the same hydrogen delivery pressure of 20 bar. Between landfill and anaerobic digestion cases the latter has the lower costs as a consequence of the higher methane content.
Design of Gravimetric Primary Standards for Field-testing of Hydrogen Refuelling Stations
Apr 2020
Publication
The Federal Institute of Metrology METAS developed a Hydrogen Field Test Standard (HFTS) that can be used for field verification and calibration of hydrogen refuelling stations. The testing method is based on the gravimetric principle. The experimental design of the HFTS as well as the description of the method are presented here.
First Solar Hydrogen Storage in a Private Building in Western Switzerland: Building energy Analysis and Schematic Design
Sep 2019
Publication
Self-sufficiency of buildings with carbon emission reduction can be obtained thanks to the introduction of Photovoltaics systems coupled with Hydrogen seasonal storage. To be self-sufficient over the year the electricity converted to hydrogen by electrolysis during the sunny season can be re-used with the help of fuel cells during the winter season. This article is dealing with the dimensioning methodology of a solar PV hydrogen-electrochemical system for self-sufficient buildings. We introduce the case study of the first private building in western Switzerland that will be equipped with solar hydrogen storage. Calculation results of the dimensioning of the PV system with storage will be presented. The life cycle assessment and the calculations of the environmental indicators GWP and CED will be introduced.
Hydrogen Production on Demand by Redox-mediated Electrocatalysis: A Kinetic Study
Aug 2020
Publication
Producing hydrogen from water using a redox mediator on solid electrocatalyst particles in a reactor offers several advantages over classical electrolysis in terms of safety membrane degradation purity and flexibility. Herein vanadium-mediated hydrogen evolution on a commercial and low-cost Mo2C electrocatalyst is studied through the development of a reaction kinetics model. Based on a proposed mechanistic reaction scheme we established a kinetic rate law dependent on the concentration of V2+ the state-of-charge of the vanadium electrolyte from a vanadium redox flow battery and the amount of available catalytic sites on solid Mo2C. Kinetic experiments in transient conditions reveals a first-order dependence on both the concentration of V2+ and the concentration of catalytic active sites and a power law with an exponential factor of 0.57 was measured on the molar ratio V2+/V3+ i.e. on the electrochemical driving force generated on the Mo2C particles. The kinetic rate law was validated by studying the rate of reaction in steady-state conditions using a specially developed rotating ring-disk device (RRD) methodology. The kinetic model was demonstrated to be a useful tool to predict the hydrogen production via the chemical oxidation of V2+ over Mo2C at low pH (> 1 M H2SO4). For a perspective the model was implemented in a semi-batch reactor. The simulations highlight the optimal state-of-charge (SOC) to carry out the reaction in an efficient way for a given demand in hydrogen.
Life Cycle Assessment Integration into Energy System Models: An Application for Power-to-Methane in the EU
Nov 2019
Publication
As the EU energy system transitions to low carbon the technology choices should consider a broader set of criteria. The use of Life Cycle Assessment (LCA) prevents burden shift across life cycle stages or impact categories while the use of Energy System Models (ESM) allows evaluating alternative policies capacity evolution and covering all the sectors. This study does an ex-post LCA analysis of results from JRC-EU-TIMES and estimates the environmental impact indicators across 18 categories in scenarios that achieve 80–95% CO2 emission reduction by 2050. Results indicate that indirect CO2 emissions can be as large as direct ones for an 80% CO2 reduction target and up to three times as large for 95% CO2 reduction. Impact across most categories decreases by 20–40% as the CO2 emission target becomes stricter. However toxicity related impacts can become 35–100% higher. The integrated framework was also used to evaluate the Power-to-Methane (PtM) system to relate the electricity mix and various CO2 sources to the PtM environmental impact. To be more attractive than natural gas the climate change impact of the electricity used for PtM should be 123–181 gCO2eq/kWh when the CO2 comes from air or biogenic sources and 4–62 gCO2eq/kWh if the CO2 is from fossil fuels. PtM can have an impact up to 10 times larger for impact categories other than climate change. A system without PtM results in ~4% higher climate change impact and 9% higher fossil depletion while having 5–15% lower impact for most of the other categories. This is based on a scenario where 9 parameters favor PtM deployment and establishes the upper bound of the environmental impact PtM can have. Further studies should work towards integrating LCA feedback into ESM and standardizing the methodology.
Deep Decarbonisation Pathways of the Energy System in Times of Unprecedented Uncertainty in the Energy Sector
May 2023
Publication
Unprecedented investments in clean energy technology are required for a net-zero carbon energy system before temperatures breach the Paris Agreement goals. By performing a Monte-Carlo Analysis with the detailed ETSAPTIAM Integrated Assessment Model and by generating 4000 scenarios of the world’s energy system climate and economy we find that the uncertainty surrounding technology costs resource potentials climate sensitivity and the level of decoupling between energy demands and economic growth influence the efficiency of climate policies and accentuate investment risks in clean energy technologies. Contrary to other studies relying on exploring the uncertainty space via model intercomparison we find that the CO2 emissions and CO2 prices vary convexly and nonlinearly with the discount rate and climate sensitivity over time. Accounting for this uncertainty is important for designing climate policies and carbon prices to accelerate the transition. In 70% of the scenarios a 1.5 ◦C temperature overshoot was within this decade calling for immediate policy action. Delaying this action by ten years may result in 2 ◦C mitigation costs being similar to those required to reach the 1.5 ◦C target if started today with an immediate peak in emissions a larger uncertainty in the medium-term horizon and a higher effort for net-zero emissions.
Understanding Degradation Effects of Elevated Temperature Operating Conditions in Polymer Electrolyte Water Electrolyzers
Apr 2021
Publication
The cost of polymer electrolyte water electrolysis (PEWE) is dominated by the price of electricity used to power the water splitting reaction. We present a liquid water fed polymer electrolyte water electrolyzer cell operated at a cell temperature of 100 °C in comparison to a cell operated at state-of-the-art operation temperature of 60 °C over a 300 h constant current period. The hydrogen conversion efficiency increases by up to 5% at elevated temperature and makes green hydrogen cheaper. However temperature is a stress factor that accelerates degradation causes in the cell. The PEWE cell operated at a cell temperature of 100 °C shows a 5 times increased cell voltage loss rate compared to the PEWE cell at 60 °C. The initial performance gain was found to be consumed after a projected operation time of 3500 h. Elevated temperature operation is only viable if a voltage loss rate of less than 5.8 μV h−1 can be attained. The major degradation phenomena that impact performance loss at 100 °C are ohmic (49%) and anode kinetic losses (45%). Damage to components was identified by post-test electron-microscopic analysis of the catalyst coated membrane and measurement of cation content in the drag water. The chemical decomposition of the ionomer increases by a factor of 10 at 100 °C vs 60 °C. Failure by short circuit formation was estimated to be a failure mode after a projected lifetime 3700 h. At elevated temperature and differential pressure operation hydrogen gas cross-over is limiting since a content of 4% hydrogen in oxygen represents the lower explosion limit.
How to Make Climate-neutral Aviation Fly
Jul 2023
Publication
The European aviation sector must substantially reduce climate impacts to reach net-zero goals. This reduction however must not be limited to flight CO2 emissions since such a narrow focus leaves up to 80% of climate impacts unaccounted for. Based on rigorous life-cycle assessment and a time-dependent quantification of non-CO2 climate impacts here we show that from a technological standpoint using electricity-based synthetic jet fuels and compensating climate impacts via direct air carbon capture and storage (DACCS) can enable climate-neutral aviation. However with a continuous increase in air traffic synthetic jet fuel produced with electricity from renewables would exert excessive pressure on economic and natural resources. Alternatively compensating climate impacts of fossil jet fuel via DACCS would require massive CO2 storage volumes and prolong dependence on fossil fuels. Here we demonstrate that a European climate-neutral aviation will fly if air traffic is reduced to limit the scale of the climate impacts to mitigate.
Conditions for Profitable Operation of P2X Energy Hubs to Meet Local Demand Under Energy Market Access
Feb 2023
Publication
This paper analyzes the operation of an energy hub on a community level with an integrated P2X facility and with access to energy markets. In our case P2X allows converting power to hydrogen heat methane or back to power. We consider the energy hub as a large prosumer who can be both a producer and consumer in the markets with the novelty that P2X technology is available. We investigate how such a P2X energy hub trades optimally in the electricity market and satisfies local energy demand under the assumption of a long-term strong climate scenario in year 2050. For numerical analysis a case study of a mountain village in Switzerland is used. One of the main contributions of this paper is to quantify key conditions for profitable operations of such a P2X energy hub. In particular the analysis includes impacts of influencing factors on profits and operational patterns in terms of different degrees of self-sufficiency and different availability of local renewable resources. Moreover the access to real-time wholesale market electricity price signals and a future retail hydrogen market is assessed. The key factors for the successful operation of a P2X energy hub are identified to be sufficient local renewable resources and access to a retail market of hydrogen. The results also show that the P2X operation leads to an increased deployment of local renewables especially in the case of low initial deployment; on the other hand seasonal storage plays a subordinated role. Additionally P2X lowers for the community the wholesale electricity market trading volumes.
Optimal Pathways for the Decarbonisation of the Transport Sector: Trade-offs Between Battery and Hydrogen Technologies Using a Whole Energy System Perspective
Jun 2023
Publication
Several countries have revised their targets in recent years to reach net-zero CO2 emissions across all sectors by 2050 and the transport sector is responsible for a significant share of these emissions. This study compares possible pathways to decarbonise the transport sector through electrification including passenger cars light commercial vehicles and heavy commercial vehicles. To do so we explore 125 scenarios by varying the share of battery and hydrogen-based fuel cell electric vehicles in each of the three categories above independently. We further model the decarbonisation of the industrial hydrogen demand using electrolysers with hydrogen storage. To explore the potential role of electric and hydrogen transport as well as their trade-offs we use GRIMSEL an open-source sector coupling energy system model of Switzerland which includes the residential commercial industrial and transport sectors with four energy carriers namely electricity heat hot water and hydrogen. The total costs are minimised from a social planner perspective. We find that the full electrification of the transport sector could lead on average to a 12% increase in costs by 2050 and 1.3 MtCO2/year which represents a 90% CO2 emissions reduction for the whole sector. Second the transport energy self-sufficiency (i.e. the share of domestic electricity generation in final transport demand) may reach up to 50% for the scenarios with the largest share of battery electric vehicles mainly due to a smaller energy demand than with hydrogen vehicles. Third more than three quarters of the industrial hydrogen production is met by local photovoltaic electricity coupled with battery at minimum costs i.e. green hydrogen. Finally the use of hydrogen as an energy carrier to store electricity over a long period is not cost-optimal.
The Role of Hydrogen for Deep Decarbonization of Energy Systems: A Chilean Case Study
Mar 2023
Publication
In this paper we implement a long-term multi-sectoral energy planning model to evaluate the role of green hydrogen in the energy mix of Chile a country with a high renewable potential under stringent emission reduction objectives in 2050. Our results show that green hydrogen is a cost-effective and environmentally friendly route especially for hard-to-abate sectors such as interprovincial and freight transport. They also suggest a strong synergy of hydrogen with electricity generation from renewable sources. Our numerical simulations show that Chile should (i) start immediately to develop hydrogen production through electrolyzers all along the country (ii) keep investing in wind and solar generation capacities ensuring a low cost hydrogen production and reinforce the power transmission grid to allow nodal hydrogen production (iii) foster the use of electric mobility for cars and local buses and of hydrogen for long-haul trucks and interprovincial buses and (iv) develop seasonal hydrogen storage and hydrogen cells to be exploited for electricity supply especially for the most stringent emission reduction objectives.
Power-to-hydrogen as Seasonal Energy Storage: An Uncertainty Analysis for Optimal Design of Low-carbon Multi-energy Systems
Jun 2020
Publication
This study analyzes the factors leading to the deployment of Power-to-Hydrogen (PtH2) within the optimal design of district-scale Multi-Energy Systems (MES). To this end we utilize an optimization framework based on a mixed integer linear program that selects sizes and operates technologies in the MES to satisfy electric and thermal demands while minimizing annual costs and CO2 emissions. We conduct a comprehensive uncertainty analysis that encompasses the entire set of technology (e.g. cost efficiency lifetime) and context (e.g. economic policy grid carbon footprint) input parameters as well as various climate-referenced districts (e.g. environmental data and energy demands) at a European-scope.
Minimum-emissions MES with large amounts of renewable energy generation and high ratios of seasonal thermal-to-electrical demand optimally achieve zero operational CO2 emissions by utilizing PtH2 seasonally to offset the long-term mismatch between renewable generation and energy demand. PtH2 is only used to abate the last 5–10% emissions and it is installed along with a large battery capacity to maximize renewable self-consumption and completely electrify thermal demand with heat pumps and fuel cells. However this incurs additional cost. Additionally we show that ‘traditional’ MES comprised of renewables and short-term energy storage are able to decrease emissions by 90% with manageable cost increases.
The impact of uncertainty on the optimal system design reveals that the most influential parameter for PtH2 implementation is (1) heat pump efficiency as it is the main competitor in providing renewable-powered heat in winter. Further battery (2) capital cost and (3) lifetime prove to be significant as the competing electrical energy storage technology. In the face of policy uncertainties a CO2 tax shows large potential to reduce emissions in district MES without cost implications. The results illustrate the importance of capturing the dynamics and uncertainties of short- and long-term energy storage technologies for assessing cost and CO2 emissions in optimal MES designs over districts with different geographical scopes.
Minimum-emissions MES with large amounts of renewable energy generation and high ratios of seasonal thermal-to-electrical demand optimally achieve zero operational CO2 emissions by utilizing PtH2 seasonally to offset the long-term mismatch between renewable generation and energy demand. PtH2 is only used to abate the last 5–10% emissions and it is installed along with a large battery capacity to maximize renewable self-consumption and completely electrify thermal demand with heat pumps and fuel cells. However this incurs additional cost. Additionally we show that ‘traditional’ MES comprised of renewables and short-term energy storage are able to decrease emissions by 90% with manageable cost increases.
The impact of uncertainty on the optimal system design reveals that the most influential parameter for PtH2 implementation is (1) heat pump efficiency as it is the main competitor in providing renewable-powered heat in winter. Further battery (2) capital cost and (3) lifetime prove to be significant as the competing electrical energy storage technology. In the face of policy uncertainties a CO2 tax shows large potential to reduce emissions in district MES without cost implications. The results illustrate the importance of capturing the dynamics and uncertainties of short- and long-term energy storage technologies for assessing cost and CO2 emissions in optimal MES designs over districts with different geographical scopes.
Cost Benefits of Optimizing Hydrogen Storage and Methanation Capacities for Power-to-Gas Plants in Dynamic Operation
Oct 2019
Publication
Power-to-Gas technologies offer a promising approach for converting renewable electricity into a molecular form (fuel) to serve the energy demands of non-electric energy applications in all end-use sectors. The technologies have been broadly developed and are at the edge of a mass roll-out. The barriers that Power-to-Gas faces are no longer technical but are foremost regulatory and economic. This study focuses on a Power-to-Gas pathway where electricity is first converted in a water electrolyzer into hydrogen which is then synthetized with carbon dioxide to produce synthetic natural gas. A key aspect of this pathway is that an intermittent electricity supply could be used which could reduce the amount of electricity curtailment from renewable energy generation. Interim storages would then be necessary to decouple the synthesized part from hydrogen production to enable (I) longer continuous operation cycles for the methanation reactor and (II) increased annual full-load hours leading to an overall reduction in gas production costs. This work optimizes a Power-to-Gas plant configuration with respect to the cost benefits using a Monte Carlo-based simulation tool. The results indicate potential cost reductions of up to 17% in synthetic natural gas production by implementing well-balanced components and interim storages. This study also evaluates three different power sources which differ greatly in their optimal system configuration. Results from time-resolved simulations and sensitivity analyses for different plant designs and electricity sources are discussed with respect to technical and economic implications so as to facilitate a plant design process for decision makers.
Non-Precious Electrodes for Practical Alkaline Water Electrolysis
Apr 2019
Publication
Water electrolysis is a promising approach to hydrogen production from renewable energy sources. Alkaline water electrolyzers allow using non-noble and low-cost materials. An analysis of common assumptions and experimental conditions (low concentrations low temperature low current densities and short-term experiments) found in the literature is reported. The steps to estimate the reaction overpotentials for hydrogen and oxygen reactions are reported and discussed. The results of some of the most investigated electrocatalysts namely from the iron group elements (iron nickel and cobalt) and chromium are reported. Past findings and recent progress in the development of efficient anode and cathode materials appropriate for large-scale water electrolysis are presented. The experimental work is done involving the direct-current electrolysis of highly concentrated potassium hydroxide solutions at temperatures between 30 and 100 ◦C which are closer to industrial applications than what is usually found in literature. Stable cell components and a good performance was achieved using Raney nickel as a cathode and stainless steel 316L as an anode by means of a monopolar cell at 75 ◦C which ran for one month at 300 mA cm−2 . Finally the proposed catalysts showed a total kinetic overpotential of about 550 mV at 75 ◦C and 1 A cm−2.
A Review of the MSCA ITN ECOSTORE—Novel Complex Metal Hydrides for Efficient and Compact Storage of Renewable Energy as Hydrogen and Electricity
Mar 2020
Publication
Hydrogen as an energy carrier is very versatile in energy storage applications. Developments in novel sustainable technologies towards a CO2-free society are needed and the exploration of all-solid-state batteries (ASSBs) as well as solid-state hydrogen storage applications based on metal hydrides can provide solutions for such technologies. However there are still many technical challenges for both hydrogen storage material and ASSBs related to designing low-cost materials with low-environmental impact. The current materials considered for all-solid-state batteries should have high conductivities for Na+ Mg2+ and Ca2+ while Al3+-based compounds are often marginalised due to the lack of suitable electrode and electrolyte materials. In hydrogen storage materials the sluggish kinetic behaviour of solid-state hydride materials is one of the key constraints that limit their practical uses. Therefore it is necessary to overcome the kinetic issues of hydride materials before discussing and considering them on the system level. This review summarizes the achievements of the Marie Skłodowska-Curie Actions (MSCA) innovative training network (ITN) ECOSTORE the aim of which was the investigation of different aspects of (complex) metal hydride materials. Advances in battery and hydrogen storage materials for the efficient and compact storage of renewable energy production are discussed.
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