China, People’s Republic
Seawater Membrane Distillation Coupled with Alkaline Water Electrolysis for Hydrogen Production: Parameter Influence and Techno-Economic Analysis
Feb 2025
Publication
The production of green hydrogen requires renewable electricity and a supply of sustainable water. Due to global water scarcity using seawater to produce green hydrogen is particularly important in areas where freshwater resources are scarce. This study establishes a system model to simulate and optimize the integrated technology of seawater desalination by membrane distillation and hydrogen production by alkaline water electrolysis. Technical economics is also performed to evaluate the key factors affecting the economic benefits of the coupling system. The results show that an increase in electrolyzer power and energy efficiency will reduce the amount of pure water. An increase in the heat transfer efficiency of the membrane distillation can cause the breaking of water consumption and production equilibrium requiring a higher electrolyzer power to consume the water produced by membrane distillation. The levelized costs of pure water and hydrogen are US$1.28 per tonne and $1.37/kg H2 respectively. The most important factors affecting the production costs of pure water and hydrogen are electrolyzer power and energy efficiency. When the price of hydrogen rises the project’s revenue increases significantly. The integrated system offers excellent energy efficiency compared to conventional desalination and hydrogen production processes and advantages in terms of environmental protection and resource conservation.
Cost and Competitiveness of Green Hydrogen and the Effects of the European Union Regulatory Framework
May 2024
Publication
By passing the delegated acts supplementing the revised Renewable Energy Directive the European Commission has recently set a regulatory benchmark for the classifcation of green hydrogen in the European Union. Controversial reactions to the restricted power purchase for electrolyser operation refect the need for more clarity about the efects of the delegated acts on the cost and the renewable characteristics of green hydrogen. To resolve this controversy we compare diferent power purchase scenarios considering major uncertainty factors such as electricity prices and the availability of renewables in various European locations. We show that the permission for unrestricted electricity mix usage does not necessarily lead to an emission intensity increase partially debilitating concerns by the European Commission and could notably decrease green hydrogen production cost. Furthermore our results indicate that the transitional regulations adopted to support a green hydrogen production ramp-up can result in similar cost reductions and ensure high renewable electricity usage.
Connotation, Innovation and Vision of "Carbon Neutrality"
Sep 2021
Publication
Global climate change caused by geological processes is one of the main causes of the 5 global mass extinctions in geological history. Human industrialization activities have caused serious damage to the ecosystem the greenhouse effect of atmospheric CO2 has intensified and the living environment is facing threats and challenges. Carbon neutrality is the active action and common goal of mankind in the face of the climate change crisis therefore probing into its theoretical and technological connotation scientific and technological innovation system has far-reaching significance and broad prospects. Studies indicate that (1) Carbon neutrality reflects the theoretical connotations of “energy science” and “carbon neutrality science” including technical connotations of carbon emission reduction zero carbon emission negative carbon emission and carbon trading. (2) Carbon neutrality spawns new industries such as carbon industry centering on CO2 capture utilization and storage (CCUS or CO2 capture and storage CCS) and hydrogen industry centering on green hydrogen. “Gray carbon” and “black carbon” are the two application attributes of CO2. “Carbonþ” “Carbon” and “Carbon¼” are three carbon-neutral products and technologies. (3) China faces three major challenges in achieving the goal of carbon neutrality: first energy transition is large in scale and the cycle is short; Second there are many problems in the process of energy transition such as security uncertainties economic utilization and unpredictable disruptive technologies; Third after transition we may face new key techno-logical “bottlenecks” and “broken chain” of key mineral resources. (4) Based on current knowledge to predict the top 10 disruptive technologies and industries in the energy field: underground coal gasification in-situ conversion process of medium and low-mature shale oil CCUS/CCS hydrogen energy and fuel cells bio-photovoltaic power generation space-based solar power generation optical storage smart micro-grid super energy storage controllable nuclear fusion wisdom energy Internet. Five strategic projects will be implemented including energy conservation and efficiency improvement carbon reduction and sequestration scientific and technological innovation emergency reserve and policy support. (5) In the future different types of energy will have different orientations. Coal will play the role of ensuring the national energy strategy “reserve” and “guarantee the bottom line”. Petroleum will play the role of ensuring national energy security “urgent need” and the “cornerstone” of raw materials in people's livelihood. Natural gas will play the role in ensuring national energy “safety” and “best partner” of new energy. New energy will play the role in ensuring the “replacement” and “main force” of the national energy strategy. (6) Carbon neutrality is a major practice of the green industrial revolution carbon reduction energy revolution and ecological technology revolution which will bring new and profound changes to human society the environment and the economy. (7) Carbon neutrality needs to follow the four principles of “disruptive breakthroughs in technology guarantee of energy security realization of economic feasibility and controllable social stability”. We should rely on technological innovation and management changes to ensure the realization of national energy “independence” and carbon neutrality goal and make China's contribution to the construction of a livable earth green development and ecological civilization.
Dynamic Simulation Optimization of the Hydrogen Liquefaction Process
Jan 2025
Publication
Liquid hydrogen has attracted much attention due to its high energy storage density and suitability for long-distance transportation. An efficient hydrogen liquefaction process is the key to obtaining liquid hydrogen. In an effort to determine the parameter optimization of the hydrogen liquefaction process this paper employed process simulation software Aspen HYSYS to simulate the hydrogen liquefaction process. By establishing a dynamic model of the unit module this study carried out dynamic simulation optimization based on the steady-state process and process parameters of the hydrogen liquefaction process and analyzed the dynamic characteristics of the process. Based on the pressure drop characteristic experiment an equation for the pressure drop in the heat exchanger was proposed. The heat transfer of hydrogen conversion was simulated and analyzed and its accuracy was verified by comparison with the literature. The dynamic simulation of a plate-fin heat exchanger was carried out by coupling heat transfer simulation and the pressure drop experiment. The results show that the increase in inlet temperature (5 C and 10 C) leads to an increase in specific energy consumption (0.65 % and 1.29 % respectively) and a decrease in hydrogen liquefaction rate (0.63 % and 2.88 % respectively). When the inlet pressure decreases by 28.57 % the hydrogen temperature of the whole liquefaction process decreases and the specific energy consumption increases by 52.94 %. The research results are of great significance for improving the operating efficiency of the refrigeration cycle and guiding the actual liquid hydrogen production.
A Novel LH2/GH2/Battery Multi-energy Vehicle Supply Station using 100% Local Wind Energy, Technical, Economic and Environmental Perspectives
Feb 2023
Publication
With the gradual maturity of wind power technology China’s wind power generation has grown rapidly over the recent years. However due to the on-site inconsumable electricity the phenomenon of large-scale “wind curtailment” occurs in some areas. In this paper a novel hybrid hydrogen/electricity refueling station is built near a wind farm and a part of the surplus wind power is used to charge electric trucks and the other part of the surplus power is used to produce “green hydrogen”. According to real-time load changes different amounts of liquid hydrogen and gas hydrogen can be properly coordinated to provide timely energy supply for hydrogen trucks. For a 400 MW wind farm in the western Inner Mongolia China the feasibility of the proposed system has been carried out based on the sensitivity and reliability analysis the static and dynamic economic modeling with an entire life cycle analysis. Compared to the conventional technology the initial investment of the proposed scheme (700.07 M$) decreases by 13.97% and the dynamic payback period (10.93 years) decreases by 25.87%. During the life cycle of the proposed system the accumulative NPV reaches 184.63 M$ which increases by 3.14 times compared to the case by conventional wind technology.
Numerical Simulation of Underexpanded Cryogenic Hydrogen Jets
Sep 2023
Publication
As a clean and renewable energy carrier hydrogen is one of the most promising alternative fuels. Cryogenic compressed hydrogen can achieve high storage density without liquefying hydrogen which has good application prospects. Investigation of the safety problems of cryogenic compressed hydrogen is necessary before massive commercialization. The present study modeled the instantaneous flow field using the Large Eddy Simulation (LES) for cryogenic (50 and 100 K) underexpanded hydrogen jets released from a round nozzle of 1.5 mm diameter at pressures of 0.5-5.0 MPa. The simulation results were compared with the experimental data for validation. The axial and radial concentration and velocity distributions were normalized to show the self-similar characteristics of underexpanded cryogenic jets. The shock structures near the nozzle were quantified to correlate the shock structure sizes to the source pressure and nozzle diameter. The present study on the concentration and velocity distributions of underexpanded cryogenic hydrogen jets is useful for developing safety codes and standards.
A Comprehensive Review on the Power Supply System of Hydrogen Production Electrolyzers for Future Integrated Energy Systems
Feb 2024
Publication
Hydrogen energy is regarded as an ideal solution for addressing climate change issues and an indispensable part of future integrated energy systems. The most environmentally friendly hydrogen production method remains water electrolysis where the electrolyzer constructs the physical interface between electrical energy and hydrogen energy. However few articles have reviewed the electrolyzer from the perspective of power supply topology and control. This review is the first to discuss the positioning of the electrolyzer power supply in the future integrated energy system. The electrolyzer is reviewed from the perspective of the electrolysis method the market and the electrical interface modelling reflecting the requirement of the electrolyzer for power supply. Various electrolyzer power supply topologies are studied and reviewed. Although the most widely used topology in the current hydrogen production industry is still single-stage AC/DC the interleaved parallel LLC topology constructed by wideband gap power semiconductors and controlled by the zero-voltage switching algorithm has broad application prospects because of its advantages of high power density high efficiency fault tolerance and low current ripple. Taking into account the development trend of the EL power supply a hierarchical control framework is proposed as it can manage the operation performance of the power supply itself the electrolyzer the hydrogen energy domain and the entire integrated energy system.
Current Status of Green Hydrogen Production Technology: A Review
Oct 2024
Publication
As a clean energy source hydrogen not only helps to reduce the use of fossil fuels but also promotes the transformation of energy structure and sustainable development. This paper firstly introduces the development status of green hydrogen at home and abroad and then focuses on several advanced green hydrogen production technologies. Then the advantages and shortcomings of different green hydrogen production technologies are compared. Among them the future source of hydrogen tends to be electrolysis water hydrogen production. Finally the challenges and application prospects of the development process of green hydrogen technology are discussed and green hydrogen is expected to become an important part of realizing sustainable global energy development.
Progress in Carbon Capture and Impurities Removal for High Purity Hydrogen Production from Biomass Thermochemical Conversion
Nov 2024
Publication
Renewable hydrogen production from biomass thermochemical conversion is an emerging technology to reduce fossil fuel consumptions and carbon emissions. Biomass-derived hydrogen can be produced by pyrolysis gasification alkaline thermal treatment etc. However the removal of impurities from biomass thermochemical conversion products to improve hydrogen purity is currently technical bottleneck. It is important to assess and investigate the types and properties of impurities the difficulty of separation and the impact on downstream utilization of hydrogen in the biomass-derived hydrogen production process. The key objectives of this comprehensive review are: (1) to reveal the current status and necessity of developing biomass-derived hydrogen production; (2) to evaluate the types devices and impurities distribution of biomass thermochemical conversion; (3) to explore the formation pathways and removal technologies of typical impurities of tar CO2 sulfides and nitrides in hydrogen production process; and (4) to propose future insights on the separation technologies of typical impurities to promote the gradual substitution of biomass-derived hydrogen for fossil-derived energy.
Research on Hydrogen Production System Technology Based on Photovoltaic-Photothermal Coupling Electrolyzer
Dec 2023
Publication
Solar hydrogen production technology is a key technology for building a clean low-carbon safe and efficient energy system. At present the intermittency and volatility of renewable energy have caused a lot of “wind and light.” By combining renewable energy with electrolytic water technology to produce high-purity hydrogen and oxygen which can be converted into electricity the utilization rate of renewable energy can be effectively improved while helping to improve the solar hydrogen production system. This paper summarizes and analyzes the research status and development direction of solar hydrogen production technology from three aspects. Energy supply mode: the role of solar PV systems and PT systems in this technology is analyzed. System control: the key technology and system structure of different types of electrolytic cells are introduced in detail. System economy: the economy and improvement measures of electrolytic cells are analyzed from the perspectives of cost consumption efficiency and durability. Finally the development prospects of solar hydrogen production systems in China are summarized and anticipated. This article reviews the current research status of photovoltaic-photothermal coupled electrolysis cell systems fills the current research gap and provides theoretical reference for the further development of solar hydrogen production systems.
The Impact of Impurity Gases on the Hydrogen Embrittlement Behavior of Pipeline Steel in High-Pressure H2 Environments
May 2024
Publication
The use of hydrogen-blended natural gas presents an efficacious pathway toward the rapid large-scale implementation of hydrogen energy with pipeline transportation being the principal method of conveyance. However pipeline materials are susceptible to hydrogen embrittlement in high-pressure hydrogen environments. Natural gas contains various impurity gases that can either exacerbate or mitigate sensitivity to hydrogen embrittlement. In this study we analyzed the mechanisms through which multiple impurity gases could affect the hydrogen embrittlement behavior of pipeline steel. We examined the effects of O2 and CO2 on the hydrogen embrittlement behavior of L360 pipeline steel through a series of fatigue crack growth tests conducted in various environments. We analyzed the fracture surfaces and assessed the fracture mechanisms involved. We discovered that CO2 promoted the hydrogen embrittlement of the material whereas O2 inhibited it. O2 mitigated the enhancing effect of CO2 when both gases were mixed with hydrogen. As the fatigue crack growth rate increased the influence of impurity gases on the hydrogen embrittlement of the material diminished.
A Study on the Promoting Role of Renewable Hydrogen in the Transformation of Petroleum Refining Pathways
Jun 2024
Publication
The refining industry is shifting from decarbonization to hydrogenation for processing heavy fractions to reduce pollution and improve efficiency. However the carbon footprint of hydrogen production presents significant environmental challenges. This study couples refinery linear programming models with life cycle assessment to evaluate from a long-term perspective the role of low-carbon hydrogen in promoting sustainable and profitable hydrogenation refining practices. Eight hydrogen-production pathways were examined including those based on fossil fuels and renewable energy providing hydrogen for three representative refineries adopting hydrogenation decarbonization and co-processing routes. Learning curves were used to predict future hydrogen cost trends. Currently hydrogenation refineries using fossil fuels benefit from significant cost advantages in hydrogen production demonstrating optimal economic performance. However in the long term with increasing carbon taxes hydrogenation routes will be affected by the high carbon emissions associated with fossil-based hydrogen losing economic advantages compared to decarbonization pathways. With increasing installed capacity and technological advancements low-carbon hydrogen is anticipated to reach cost parity with fossil-based hydrogen before 2060. Coupling renewable hydrogen is expected to yield the most significant economic advantages for hydrogenation refineries in the long term. Renewable hydrogen drives the transition of refining processing routes from a decarbonization-oriented approach to a hydrogenation-oriented paradigm resulting in cleaner refining processes and enhanced competitiveness under emission-reduction pressures.
Data-driven Optimal Scheduling for Underground Space Based Integrated Hydrogen Energy System
Dec 2021
Publication
Integrated hydrogen energy systems (IHESs) have attracted extensive attention in miti-gating climate problems. As a kind of large-scale hydrogen storage device undergroundhydrogen storage (UHS) can be introduced into IHES to balance the seasonal energy mis-match while bringing challenges to optimal operation of IHES due to the complex geolog-ical structure and uncertain hydrodynamics. To address this problem a deep deterministicpolicy gradient (DDPG)-based optimal scheduling method for underground space basedIHES is proposed. The energy management problem is formulated as a Markov decisionprocess to characterize the interaction between environmental states and policy. Based onDDPG theory the actor-critic structure is applied to approximate deterministic policy andactor-value function. Through policy iteration and actor-critic network training the oper-ation of UHS and other energy conversion devices can be adaptively optimised which isdriven by real-time response data instead of accurate system models. Finally the effective-ness of the proposed optimal scheduling method and the benefits of underground spaceare verified through time-domain simulations.
The Progress of Autoignition of High-Pressure Hydrogen Gas Leakage: A Comprehensive Review
Aug 2024
Publication
As a paradigm of clean energy hydrogen is gradually attracting global attention. However its unique characteristics of leakage and autoignition pose significant challenges to the development of high-pressure hydrogen storage technologies. In recent years numerous scholars have made significant progress in the field of high-pressure hydrogen leakage autoignition. This paper based on diffusion ignition theory thoroughly explores the mechanism of high-pressure hydrogen leakage autoignition. It reviews the effects of various factors such as gas properties burst disc rupture conditions tube geometric structure obstacles etc. on shock wave growth patterns and autoignition characteristics. Additionally the development of internal flames and propagation characteristics of external flames after ignition kernels generation are summarized. Finally to promote future development in the field of high-pressure hydrogen energy storage and transportation this paper identifies deficiencies in the current research and proposes key directions for future research.
Review and Prospects of Key Technologies for Integrated Systems in Hydrogen Production from Offshore Superconducting Wind Power
Dec 2024
Publication
Hydrogen production from renewable energy sources is a crucial pathway to achieving the carbon peak target and realizing the vision of carbon neutrality. The hydrogen production from offshore superconducting wind power (HPOSWP) integrated systems as an innovative technology in the renewable energy hydrogen production field holds significant market potential and promising development prospects. This integrated technology based on research into high-temperature superconducting generator (HTSG) characteristics and electrolytic water hydrogen production (EWHP) technology converts offshore wind energy (OWE) into hydrogen energy locally through electrolysis with hydrogen storage being shipped and controlled liquid hydrogen (LH2) circulation ensuring a stable low-temperature environment for the HTSGs’ refrigeration system. However due to the significant instability and intermittency of offshore wind power (OWP) this HPOSWP system can greatly affect the dynamic adaptability of the EWHP system resulting in impure hydrogen production and compromising the safety of the LH2 cooling system and reduce the fitness of the integrated system for wind electricity–hydrogen heat multi-field coupling. This paper provides a comprehensive overview of the fundamental structure and characteristics of this integrated technology and further identifies the key challenges in its application including the dynamic adaptability of electrolytic water hydrogen production technology as well as the need for large-capacity long-duration storage solutions. Additionally this paper explores the future technological direction of this integrated system highlighting the need to overcome the limitations of electrical energy adaptation within the system improve product purity and achieve large-scale applications.
Low-temperature Water Electrolysis: Fundamentals, Progress, and New Strategies
May 2022
Publication
Water electrolysis is a promising technology for sustainable energy conversion and storage of intermittent and fluctuating renewable energy sources and production of high-purity hydrogen for fuel cells and various industrial applications. Low-temperature electrochemical water splitting technologies include alkaline proton exchange membrane and anion exchange membrane water electrolyses which normally consist of two coupled half reactions: the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Despite the advances over decades formidable challenges still exist and hinder the practical application of large-scale energy-efficient and economically viable water electrolysis including large energy penalty sluggish kinetics high cost of precious metal based electrocatalysts possible H2/O2 gas crossover difficulty in storage and distribution of H2. Herein we first briefly introduce the fundamentals of water electrolysis summarize the recommended standardized electrochemical characterization protocols and demonstrate the metrics and key performance indicators that are used to evaluate the performances of HER and OER electrocatalysts and electrolyser cells. Then we present six new strategies to mitigate the technical challenges in conventional water electrolysis. These emerging strategies for disruptive innovation of water electrolysis technology include overall water electrolysis based on bifunctional nonprecious electrocatalysts (or pre-catalysts) magnetic field-assisted water electrolysis decoupled water electrolysis hybrid water electrolysis acid/alkaline asymmetric electrolyte electrolysis and tandem water electrolysis. Finally the remaining challenges perspectives and future directions are discussed. This review will provide guidance and inspire more endeavours to deepen the mechanistic understanding and advance the development of water electrolysis.
Numerical Simulation of Diffusion Characteristics and Hazards in Multi-Hole Leakage from Hydrogen-Blended Natural Gas Pipelines
Aug 2025
Publication
In this study a 3D model is developed to simulate multi-hole leakage scenarios in buried pipelines transporting hydrogen-blended natural gas (HBNG). By introducing three parameters—the First Dangerous Time (FDT) Ground Dangerous Range (GDR) and Farthest Dangerous Distance (FDD)—to characterize the diffusion hazard of the gas mixture this study further analyzes the effects of the number of leakage holes hole spacing hydrogen blending ratio (HBR) and soil porosity on the diffusion hazard of the gas mixture during leakage. Results indicate that gas leakage exhibits three distinct phases: initial independent diffusion followed by an intersecting accelerated diffusion stage and culminating in a unified-source diffusion. Hydrogen exhibits the first two phases whereas methane undergoes all three and dominates the GDR. Concentration gradients for multi-hole leakage demonstrate similarities to single-hole scenarios but multi-hole leakage presents significantly higher hazards. When the inter-hole spacing is small diffusion characteristics converge with those of single-hole leakage. Increasing HBR only affects the gas concentration distribution near the leakage hole with minimal impact on the overall ground danger evolution. Conversely variations in soil porosity substantially impact leakage-induced hazards. The outcomes of this study will support leakage monitoring and emergency management of HBNG pipelines.
A Study on the Thermal Behavior of Series and Parallel Connection Methods in the Process of Hydrogenation of Ship-Borne Hydrogen Storage Cylinder
Feb 2024
Publication
As a subdivision of the hydrogen energy application field ship-borne hydrogen fuel cell systems have certain differences from vehicle or other application scenarios in terms of their structural type safety environmental adaptability and test verification. The connection method of the ship-borne hydrogen storage cylinder (SHSC) is very important for the hydrogen fuel cell ship and the structural parameters of the SHSC are particularly important in the hydrogen refueling process. To ensure the safe and reliable operation of the hydrogen-powered ship research on the filling of the SHSC under different connection modes was carried out during refueling. In our study a thermal flow physical model of the SHSC was established to research the hydrogen refueling process of the series and parallel SHSCs. The influence of series and parallel modes of the SHSCs on the hydrogen refueling process was explored and the evolution law of the internal flow field pressure and temperature of series and parallel SHSCs under different filling parameters was analyzed by numerical simulation. Our results confirmed the superiority of the parallel modular approach in terms of thermal safety during refueling. The results can supply a technical basis for the future development of hydrogen refueling stations and ship-board hydrogenation control algorithms.
Modulating Selectivity and Stability of the Direct Seawater Electrolysis for Sustainable Green Hydrogen Production
Feb 2025
Publication
Direct seawater electrolysis (DSE) has emerged as a compelling route to sustainable hydrogen production leveraging the vast global reserves of seawater. However the inherently complex composition of seawater—laden with halide ions multivalent cations (Mg2+ Ca2+) and organic/biological impurities—presents formidable challenges in maintaining both selectivity and durability. Chief among these obstacles is mitigating chloride corrosion and suppressing chlorine evolution reaction (ClER) at the anode while also preventing the precipitation of magnesium and calcium hydroxides at the cathode. This review consolidates recent advances in material engineering and cell design strategies aimed at controlling undesired side reactions enhancing electrode stability and maximizing energy efficiency in DSE. We first outline the fundamental thermodynamic and kinetic hurdles introduced by Cl⁻ and other impurities. This discussion highlights how these factors accelerate catalyst degradation and drive suboptimal reaction pathways. We then delve into innovative approaches to improve selectivity and durability of DSE—such as engineering protective barrier layers tuning electrolyte interfaces developing corrosion-resistant materials and techniques to minimize Mg/Ca-related precipitations. Finally we explore emerging reactor configurations including asymmetric and membrane-free electrolyzers which address some barriers for DSE commercialization. Collectively these insights provide a framework for designing next-generation DSE systems which can achieve large-scale cost-effective and environmentally benign hydrogen production.
The Recent Progresses of Electrodes and Electrolysers for Seawater Electrolysis
Jan 2024
Publication
The utilization of renewable energy for hydrogen production presents a promising pathway towards achieving carbon neutrality in energy consumption. Water electrolysis utilizing pure water has proven to be a robust technology for clean hydrogen production. Recently seawater electrolysis has emerged as an attractive alternative due to the limitations of deep-sea regions imposed by the transmission capacity of long-distance undersea cables. However seawater electrolysis faces several challenges including the slow kinetics of the oxygen evolution reaction (OER) the competing chlorine evolution reaction (CER) processes electrode degradation caused by chloride ions and the formation of precipitates on the cathode. The electrode and catalyst materials are corroded by the Cl− under long-term operations. Numerous efforts have been made to address these issues arising from impurities in the seawater. This review focuses on recent progress in developing high-performance electrodes and electrolyser designs for efficient seawater electrolysis. Its aim is to provide a systematic and insightful introduction and discussion on seawater electrolysers and electrodes with the hope of promoting the utilization of offshore renewable energy sources through seawater electrolysis.
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