Germany
Anion-exchange Membrane Water Electrolyzers
Apr 2022
Publication
This Review provides an overview of the emerging concepts of catalystsmembranes and membrane electrode assemblies (MEAs) for water electrolyzers with anion-exchange membranes (AEMs) also known as zero-gap alkaline water electrolyzers. Much ofthe recent progress is due to improvements in materials chemistry MEA designs andoptimized operation conditions. Research on anion-exchange polymers (AEPs) has focusedon the cationic head/backbone/side-chain structures and key properties such as ionicconductivity and alkaline stability. Several approaches such as cross-linking microphase andorganic/inorganic composites have been proposed to improve the anion-exchangeperformance and the chemical and mechanical stability of AEMs. Numerous AEMs nowexceed values of 0.1 S/cm (at 60−80 °C) although the stability specifically at temperaturesexceeding 60 °C needs further enhancement. The oxygen evolution reaction (OER) is still alimiting factor. An analysis of thin-layer OER data suggests that NiFe-type catalysts have thehighest activity. There is debate on the active-site mechanism of the NiFe catalysts and their long-term stability needs to beunderstood. Addition of Co to NiFe increases the conductivity of these catalysts. The same analysis for the hydrogen evolutionreaction (HER) shows carbon-supported Pt to be dominating although PtNi alloys and clusters of Ni(OH) 2 on Pt show competitiveactivities. Recent advances in forming and embedding well-dispersed Ru nanoparticles on functionalized high-surface-area carbonsupports show promising HER activities. However the stability of these catalysts under actual AEMWE operating conditions needsto be proven. The field is advancing rapidly but could benefit through the adaptation of new in situ techniques standardizedevaluation protocols for AEMWE conditions and innovative catalyst-structure designs. Nevertheless single AEM water electrolyzercells have been operated for several thousand hours at temperatures and current densities as high as 60 °C and 1 A/cm 2 respectively.
Techno-economic Analysis of Green Hydrogen Supply for a Hydrogen Refueling Station in Germany
Feb 2025
Publication
Green hydrogen is a cornerstone in the global quest for a carbon-neutral future offering transformative potential for decarbonizing transportation. This study investigates its role by assessing the feasibility of a large-scale hydrogen refueling station in Germany focusing on integrating renewable energy sources. A hydrogen demand model with a 10-min time resolution to refuel 30 trucks and 20 vans (1019 kg/day) is combined with a techno-economic optimization model to evaluate a hybrid energy system utilizing wind solar and grid electricity. Scenario-based analysis reveals that Levelized Cost of Hydrogen ranges from 13.92 to 18.12 €/kg primarily influenced by electricity costs. Excess electricity sales can reduce this cost to 13.34–16.92 €/kg. On-site wind energy reduces storage and grid reliance achieving the lowest hydrogen cost. Unlike prior studies this work combines temporally resolved hydrogen demand profiles with comprehensive techno-economic modeling offering unprecedented insights into decentralized green hydrogen systems for heavy-duty transport. By bridging critical gaps in the scalability and economic feasibility of Power-to-Hydrogen systems it provides viable strategies for advancing green hydrogen infrastructure.
Evaluating Cost and Emission Reduction Potentials with Stochastic PPA Portfolio Optimization for Green Hydrogen Production in a Decarbonized Glassworks
Sep 2025
Publication
The decarbonization of heavy industries demands large volumes of green hydrogen. To produce green hydrogen via electrolysis the EU’s Renewable Energy Directive II imposes rules to ensure the use of renewable electricity. Hydrogen producers can use portfolios of power purchase agreements (PPAs) to buy renewable electricity. These portfolios must meet hydrogen demand cost-effectively and battery storage can help by shifting excess renewable generation. However high uncertainty around future electricity prices and demand complicates optimal portfolio design. Current literature lacks comprehensive models that evaluate such portfolio optimization under uncertainty for real-world case studies including battery storage. This work addresses the gap by introducing a stochastic mixed-integer linear programming model tailored to industrial applications. We demonstrate the model using a real-world glass manufacturing site in Germany. Our findings show that portfolio optimization alone can reduce the levelized cost of hydrogen (LCOH) by 6.24% under EU rules. Adding a battery further cuts costs achieving an LCOH of 11.8 e2024 kg−1 . Exploring different temporal matching schemes reveals that weekly matching reduces LCOH by 2 e2024kg−1 while maintaining a high share of renewable energy. The model offers a flexible tool for optimizing PPA portfolios in various industrial settings.
A Review of Hydrogen Storage and Transport Technologies
Mar 2023
Publication
An important component of the deep decarbonization of the worldwide energy system is to build up the large-scale utilization of hydrogen to substitute for fossil fuels in all sectors including industry the electricity sector transportation and heating. Hence apart from reducing hydrogen production costs establishing an efficient and suitable infrastructure for the storage transportation and distribution of hydrogen becomes essential. This article provides a technically detailed overview of the state-of-the-art technologies for hydrogen infrastructure including the physical- and material-based hydrogen storage technologies. Physical-based storage means the storage of hydrogen in its compressed gaseous liquid or supercritical state. Hydrogen storage in the form of liquid-organic hydrogen carriers metal hydrides or power fuels is denoted as material-based storage. Furthermore primary ways to transport hydrogen such as land transportation via trailer and pipeline overseas shipping and some related commercial data are reviewed. As the key results of this article hydrogen storage and transportation technologies are compared with each other. This comparison provides recommendations for building appropriate hydrogen infrastructure systems according to different application scenarios.
The German Scramble for Green Hydrogen in Namibia: Colonial Legacies Revisited?
Feb 2025
Publication
Namibia is positioning itself as a green hydrogen superpower to supply the German market with the muchneeded energy carrier. While the hydrogen hype is marketed as a pathway facilitating the German and Euro pean green transition that is mutually beneficial for African interests social movements and affected commu nities have been denouncing green colonialist tendencies of the hydrogen rush. This paper is centring these claims. Applying a heuristic of green colonialism along the lines of externalisation enactment expansion exclusion and empowerment we highlight colonial tendencies of the hydrogen rush in Namibia. While still in a nascent stadium current developments indicate patterns to transform Southern economies according to Euro pean interest which can then uphold their allegedly superior image as renewable energy pioneers. Our study indicates that the green hydrogen rush resembles a longue dur´ee of (neo)colonial violence: while clinging to old colonial patterns it takes advantage of the post-colonial state and at the same time uses narratives of contemporary multiple crises to advance and legitimise a supposedly green but intrinsically violent transition.
A Novel Design Approach: Increase in Storage and Transport Efficiency for Liquid Hydrogen by Using a Dual Concept Involving a Steel-fiber Composite Tank and Thermal Sprayed Insulating Coatings
Nov 2024
Publication
Wind power-to-gas concepts have a high potential to sustainably cover the increasing demand for hydrogen as an energy carrier and raw material as it has been shown in the past that there is an enormous potential in energy overproduction which currently remains unused due to the shutdown of wind turbines. Thus there is barely experience in maritime production offshore storage and transport of large quantities of liquid hydrogen (LH2) due to the developing market. Instead tank designs refer to heavy standard onshore storage and transport applications with vacuum insulated double wall hulls made from austenitic stainless steel and comparatively high thermal diffusivity and conductivity. This reduces cost effectiveness due to inevitable boil-off and disregards some other requirements such as mechanical and cyclic strength and high corrosion resistance. Hence new concepts for LH2 tanks are required for addressing these issues. Two innovative technical concepts from space travel and high-temperature applications were adopted combined and qualified for use in the wind-power-to-gas scenario. The focus was particularly on the high requirements for transport weight insulation and cryogenic durability. The first concept part consisted of the implementation of FRP (fiber-reinforced plastics)–steel hybrid tanks which have a high potential as a hull for LH2 tanks. However these hybrid tanks are currently only used in the space sector. Questions still arise regarding interactions with coatings production material temperature resilience and design for commercial use. Thermally sprayed thermal barrier coatings (TBC) in turn show promising potential for surfaces subject to high thermal and mechanical stress. However the application is currently limited to use at high temperatures and needed to be extended to the cryogenic temperature range. The research on this second part of the concept thus focused on the validation of standard MCrAlY alloys and innovative (partially) amorphous metal coatings with regard to mechanical-technological and insulating properties in the low temperature range. This article gives an overview regarding the achieved results including manufacturing and measurements on a small tank demonstrator.
Unlocking Hydrogen's Potential: Prediction of Adsorption in Metal-organic Frameworks for Sustainable Energy Storage
Oct 2025
Publication
Accurately predicting hydrogen adsorption behavior is essential to developing efficient materials with storage capacities approaching those of liquid hydrogen and surpassing the performance of conventional compressed gas storage systems. Grand canonical Monte Carlo (GCMC) simulations accurately predict adsorption isotherms but are computationally expensive limiting large-scale material screening. We employ GPU-accelerated threedimensional classical density functional theory (DFT) based on the SAFT-VRQ Mie equation of state with a first-order Feynman–Hibbs correction to model hydrogen adsorption in [Zn(bdc)(ted)0.5] MOF-5 CuBTC and ZIF-8 at 30 K 50 K 77 K and 298 K. Our approach generates adsorption isotherms in seconds compared to hours for GCMC simulations with quantum corrections proving crucial for accurate low-temperature predictions. The results show good agreement with GCMC simulations and available experiments demonstrating classical DFT as a powerful tool for high-throughput material screening and optimizing hydrogen storage applications.
Large-Scale H2 Storage and Transport with Liquid Organic Hydrogen Carrier Technology: Insights into Current Project Developments and the Future Outlook
Jan 2024
Publication
The green hydrogen economy is evolving rapidly accompanied by the need to establish trading routes on a global scale. Currently several technologies arecompeting for a leadership role in future hydrogen value chains. Within thiscontext liquid organic hydrogen carrier (LOHC) technology represents an excellent solution for large-scale storage and safe transportation of hydrogen.This article presents LOHC technology recent progress as well as further potential of this technology with focus on benzyltoluene as the carrier material.Furthermore this contribution offers an insight into previous and ongoingproject development activities led by Hydrogenious LOHC Technologies togetherwith an evaluation of the economic viability and an overview of the regulatory aspects of LOHC technology.
Unlocking Solar and Hydrogen Potentials: A Comparative Analysis of Solar Tracking Systems for South Africa's Energy Transition
Aug 2025
Publication
This study explores the potential of solar tracking technologies to enhance South Africa’s energy transition focusing on their role in supporting green hydrogen production for domestic use and export. Using the Global Energy System Model (GENeSYS-MOD) it evaluates four solar tracking technologies — horizontal axis tilted horizontal axis vertical axis and dual-axis — across six scenarios: tracking and non-tracking versions of a Business-as-Usual (BAU) scenario a 2 ◦C scenario and a high hydrogen demand and export (HighH2) scenario. The results identify horizontal axis tracking as the most cost-effective option followed by tilted horizontal axis tracking which is particularly prominent in the HighH2 scenario. Tracking systems enhance hydrogen production by extending power output and increasing electrolyzer full-load hours. In the HighH2 scenario they reduce hydrogen production costs in 2050 from 1.47 e/kg to 1.34 e/kg and system cost by 0.66% positioning South Africa competitively in the global hydrogen market. By integrating tracking technologies South Africa can align hydrogen production ambitions with renewable energy growth while mitigating grid and financial challenges. The research underscores the need for targeted energy investments and policies to maximize renewable energy and hydrogen potential ensuring a just energy transition that supports export opportunities domestic energy security and equitable socio-economic growth.
Towards Water-conscious Green Hydrogen and Methanol: A Techno-economic Review
Jan 2025
Publication
To enable a sustainable and socially accepted hydrogen and methanol economy it is crucial to prioritize green and water-conscious production. In this review we reveal that there is a significant research gap regarding comprehensive assessments of such production methods. We present an innovative process chain consisting of adsorption-based direct air capture solid oxide electrolysis and methanol synthesis to address this issue. To allow future comprehensive techno-economic assessments we perform a systematic literature review and harmonization of the techno-economic parameters of the process chain’s technologies. Based on the conducted literature review we find that the long-term median specific energy demand of adsorption-based direct air capture is expected to decrease to 204 kWhel/tCO2 and 1257 kWhth/tCO2 while the capture cost is expected to decrease to 162 €2024/tCO2 with a relative high uncertainty. The evaluated sources expect a future increase in system efficiency of solid oxide electrolysis to 80% while the purchase equipment costs are expected to decrease significantly. Finally we demonstrate the feasibility of the process chain from a technoeconomic perspective and show a potential reduction in external heat demand of the DAC unit of up to 34% when integrated in the process chain.
Research Sites of the H2STORE Project and the Relevance of Lithological Variations for Hydrogen Storage at Depths
Sep 2013
Publication
The H2STORE collaborative project investigates potential geohydraulic petrophysical mineralogical microbiological and geochemical interactions induced by the injection of hydrogen into depleted gas reservoirs and CO2- and town gas storage sites. In this context the University of Jena performs mineralogical and geochemical investigations on reservoir and cap rocks to evaluate the relevance of preferential sedimentological features which will control fluid (hydrogen) pathways thus provoking fluid-rock interactions and related variations in porosity and permeability. Thereby reservoir sand- and sealing mudstones of different composition sampled from distinct depths (different: pressure/temperature conditions) of five German locations are analysed. In combination with laboratory experiments the results will enable the characterization of specific mineral reactions at different physico-chemical conditions and geological settings.
Evaluation of the Impact of Gaseous Hydrogen on Pipeline Steels Utilizing Hollow Specimen Technique and μCT
Feb 2024
Publication
The high potential of hydrogen as a key factor on the pathway towards a climate neutral economy leads to rising demand in technical applications where gaseous hydrogen is used. For several metals hydrogen-metal interactions could cause a degradation of the material properties. This is especially valid for low carbon and highstrength structural steels as they are commonly used in natural gas pipelines and analyzed in this work. This work provides an insight to the impact of hydrogen on the mechanical properties of an API 5L X65 pipeline steel tested in 60 bar gaseous hydrogen atmosphere. The analyses were performed using the hollow specimen technique with slow strain rate testing (SSRT). The nature of the crack was visualized thereafter utilizing μCT imaging of the sample pressurized with gaseous hydrogen in comparison to one tested in an inert atmosphere. The combination of the results from non-conventional mechanical testing procedures and nondestructive imaging techniques has shown unambiguously how the exposure to hydrogen under realistic service pressure influences the mechanical properties of the material and the appearance of failure.
Hydrogen Sampling Systems Adapted to Heavy-duty Refuelling Stations' Current and Future Specifications - A Review
Sep 2024
Publication
To meet the new regulation for the deployment of alternative fuels infrastructure which sets targets for electric recharging and hydrogen refuelling infrastructure by 2025 or 2030 a large infrastructure comprising trucksuitable hydrogen refuelling stations will soon be required. However further standardisation is required to support the uptake of hydrogen for heavy-duty transport for Europe’s green energy future. Hydrogen-powered vehicles require pure hydrogen as some contaminants can reduce the performance of the fuel cell even at very low levels. Even if previous projects have paved the way for the development of the European quality infrastructure for hydrogen conformity assessment sampling systems and methods have yet to be developed for heavy-duty hydrogen refuelling stations (HD-HRS). This study reviews different aspects of the sampling of hydrogen at heavy-duty hydrogen refuelling stations for purity assessment with a focus on the current and future specifications and operations at HD-HRS. This study describes the state-of-the art of sampling systems currently under development for use at HD-HRS and highlights a number of aspects which must be taken into consideration to ensure safe and accurate sampling: risk assessment for the whole sampling exercise selection of cylinders methods to prepare cylinders before the sampling filling pressure and venting of the sampling systems.
Projecting Technological Advancement of Electrolyzers and the Impact on the Competitiveness of Hydrogen
Dec 2024
Publication
Green hydrogen has the potential to decarbonize hard-to-abate sectors and processes and should therefore play an important role in the energy system in achieving climate goals. However the main hydrogen supply is still based on fossil fuels and only limited amounts of electrolyzers have been installed. Switching from fossil-based fuel sources to green hydrogen is highly dependent on when and at what price green hydrogen will become available which in turn is dependent on the technological development of electrolyzers. In this paper we apply the experience curve methodology to project the capital expenditure and electrical consumption developments of the three main electrolysis technologies: alkaline proton exchange membrane and solid oxide electrolysis. Based on our calculations we expect that both AEL and PEM will reach similar costs by 2030 of around 300 e per kW and SOEC will remain the most expensive technology with a considerable cost reduction down to 828 e per kW. The electrical consumptions will fall to 4.23 kWh per Nm3 for AEL 3.86 kWh per Nm3 for PEM and 3.05 kWh per Nm3 for SOEC. Based on this technological progress we calculate that the levelized cost of hydrogen will be reduced to 2.43–3.07 e per kg. To reach lower levelized cost of hydrogen notable reductions in electricity (purchase) cost are required.
The Technopolitics of Hydrogen: Arab Gulf States' Pursuit of Significance in a Climate-Constrained World
Nov 2024
Publication
Despite uncertainties surrounding the hydrogen economy’s emergence in terms of technological innovation production storage and transport policy and regulation economic viability and environmental impact coun tries worldwide actively pursue initiatives to engage in this critical energy transition. Politicians analysts and global experts see ‘clean’ hydrogen as the ultimate solution for addressing the climate crisis. This optimism is shared by several major oil and gas-exporting nations which are investing heavily in hydrogen infrastructure to establish themselves as future global hubs. Oman Saudi Arabia and the United Arab Emirates (UAE) are especially well-positioned benefiting from strategic advantages over other hydrogen-producing regions in the Global South. Advocates in these countries view hydrogen as a potential ‘silver bullet’ for sustaining political and economic influence in a world increasingly shaped by climate constraints. Western technology and expertise play a significant role in supporting these efforts. By using various qualitative methods this paper employs and expand the concept of technopolitics to evaluate the role of industrialized nations in endorsing the Gulf states’ authoritarian top-down techno-optimistic approach to their sustainability agenda.
The Integration of Thermal Energy Storage Within Metal Hydride Systems: A Comprehensive Review
Dec 2024
Publication
Hydrogen storage technologies are key enablers for the development of low-emission sustainable energy supply chains primarily due to the versatility of hydrogen as a clean energy carrier. Hydrogen can be utilized in both stationary and mobile power applications and as a lowenvironmental-impact energy source for various industrial sectors provided it is produced from renewable resources. However efficient hydrogen storage remains a significant technical challenge. Conventional storage methods such as compressed and liquefied hydrogen suffer from energy losses and limited gravimetric and volumetric energy densities highlighting the need for innovative storage solutions. One promising approach is hydrogen storage in metal hydrides which offers advantages such as high storage capacities and flexibility in the temperature and pressure conditions required for hydrogen uptake and release depending on the chosen material. However these systems necessitate the careful management of the heat generated and absorbed during hydrogen absorption and desorption processes. Thermal energy storage (TES) systems provide a means to enhance the energy efficiency and cost-effectiveness of metal hydride-based storage by effectively coupling thermal management with hydrogen storage processes. This review introduces metal hydride materials for hydrogen storage focusing on their thermophysical thermodynamic and kinetic properties. Additionally it explores TES materials including sensible latent and thermochemical energy storage options with emphasis on those that operate at temperatures compatible with widely studied hydride systems. A detailed analysis of notable metal hydride–TES coupled systems from the literature is provided. Finally the review assesses potential future developments in the field offering guidance for researchers and engineers in advancing innovative and efficient hydrogen energy systems.
Hydrogen Production from Wastewater: A Comprehensive Review of Conventional and Solar Powered Technologies
Mar 2024
Publication
The need to reduce the carbon footprint of conventional energy sources has made green hydrogen a promising solution for the energy transition. The most environmentally friendly way to produce hydrogen is through water-based production using renewable energy. However the availability of fresh water is limited so switching to wastewater instead of fresh water is the key solution to this problem. In response to this issue the present review reports the main findings of the research studies dealing with the feasibility of hydrogen production from wastewater using various technologies including biological electrochemical and advanced oxidation routes. These methods have been studied in a large number of experiments with the aim of investigating and improving the potential of each method. On the other hand the maturity of solar energy technologies has led researchers to focus on the possibility of harnessing this source and combining it with wastewater treatment techniques for the production of green hydrogen. Therefore the present review pays special attention to solar driven hydrogen production from wastewater by highlighting the potential of several technologies for simultaneous water treatment and green hydrogen production from wastewater. Recent results limitations challenges possible improvements and techno-economic assessments reported by several authors as well as future directions of research and industrial implementation in this field are reported.
Heat and Mass Transfer Modeling of Vacuum Insulated Vessel Storing Cryogenic Liquid in Loss of Vacuum Accident
Sep 2023
Publication
Cryogenic liquid is often stored in a vacuum insulated Dewar vessel for a high efficiency of thermal insulation. Multi-layer insulation (MLI) can be further applied in the double-walled vacuum space to reduce the heat transfer from the environment to the stored cryogenic fluid. However in loss-of-vacuum accident (LOVA) scenarios heat flux across the MLI will raise to orders of magnitudes larger than with an intact vacuum shield. The cryogenic liquid will boil intensively and pressurize the vessel due to the heat ingress. The pressurization endangers the integrity of the vessel and poses an extra catastrophic risk if the vapor is flammable e.g. hydrogen. Therefore safety valves have to be designed and installed appropriately to make sure the pressure is limited to acceptable levels. In this work the dynamic process of the heat and mass transfers in the LOVA scenarios is studied theoretically. The mass deposition - desublimation of gaseous nitrogen on cryogenic surfaces is modeled as it provides the dominant contribution of the thermal load to the cryogenic fluid. The conventional heat convection and radiation are modeled too although they play only secondary roles as realized in the course of the study. The temperature dependent thermal properties of e.g. gaseous and solid nitrogen and stainless steel are used to improve the accuracy of calculation in the cryogenic temperature range. Presented methodology enabling the computation of thermodynamic parameters in the cryogenic storage system during LOVA scenarios provides further support for the future risk assessment and safety system design.
European Hydrogen Train the Trainer Programme for Responders: The Impact of HyResponder on Training Across Europe
Jan 2025
Publication
Síle Brennan,
Christian Brauner,
Dennis Davis,
Natalie DeBacker,
Alexander Dyck,
César García Hernández,
André Vagner Gaathaug,
Petr Kupka,
Laurence Grand-Clement,
Etienne Havret,
Deborah Houssin-Agbomson,
Laurent Lecomte,
Eric Maranne,
Pippa Steele,
Paola Russo,
Adolfo Pinilla,
Gerhard Schoepf,
Tom Van Esbroeck and
Vladimir V. Molkov
The impact of the HyResponder project on the training of responders in 10 European countries is described. An overview is presented of training activities undertaken within the project in Austria Belgium Czech Republic France Germany Italy Norway Spain Switzerland and the United Kingdom. National leads with training expertise are given and the longer-term plans in each region are mentioned. Responders from each region took part in a specially tailored “train the trainer” programme and then delivered training within their regions. A flexible approach to training within the HyResponder network has enabled fit for purpose region appropriate activities to be delivered impacting over 1250 individuals during the project and many more beyond. Teaching and learning materials in hydrogen safety for responders have been made available in 8 languages: English Czech Dutch French German Italian Norwegian Spanish. They are being used to inform training within each of the partner countries. Dedicated national working groups focused on hydrogen safety training for responders have been established in Belgium the Czech Republic Italy and Switzerland.
PyPSA-Earth Sector-coupled: A Global Open-source Multi-energy System Model Showcased for Hydrogen Applications in Countries of the Global South
Jan 2025
Publication
This study presents sector-coupled PyPSA-Earth: a novel global open-source energy system optimization model that incorporates major demand sectors and energy carriers in high spatial and temporal resolution to enable energy transition studies worldwide. The model includes a workflow that automatically downloads and processes the necessary demand supply and transmission data to co-optimize investment and operation of energy systems of countries or regions of Earth. The workflow provides the user with tools to forecast future demand scenarios and allows for custom user-defined data in several aspects. Sector-coupled PyPSA-Earth introduces novelty by offering users a comprehensive methodology to generate readily available sector-coupled data and model of any region worldwide starting from raw and open data sources. The model provides flexibility in terms of spatial and temporal detail allowing the user to tailor it to their specific needs. The capabilities of the model are demonstrated through two showcases for Egypt and Brazil. The Egypt case quantifies the relevant role of PV exceeding 35 GW and electrolysis in Suez and Damietta regions for meeting 16% of the EU hydrogen demand. Complementarily the Brazil case confirms the model’s ability in handling hydrogen planning infrastructure including repurposing of existing gas networks which results in 146 M€ lower costs than building new pipelines. The results prove the suitability of sector-coupled PyPSA-Earth to meet the needs of policymakers developers and scholars in advancing the energy transition. The authors invite the interested individuals and institutions to collaborate in the future developments of the model within PyPSA meets Earth initiative.
Comparative Socio-economic Analysis and Green Transition Perspectives in the Green Hydrogen Economy of Sub-Saharan Africa and South America Countries
Sep 2025
Publication
The global shift toward a green hydrogen economy requires diversifying production beyond the Middle East and North Africa where political logistical and water constraints limit long-term supply. This study provides a comparative socio-economic assessment of Sub-Saharan African and South American countries focusing on their readiness for large-scale green hydrogen development. A Green Economy Index (GEI) was developed integrating political/regulatory efficiency socio-economic status infrastructure and sustainability indicators. In addition public perception was examined through a survey conducted in Nigeria. Results show GEI scores ranging from 0.328 to 0.744 with Germany as the benchmark. Brazil Uruguay and Namibia emerge as the most promising cases due to strong renewable energy potential socio-economic stability and supportive policies though each faces specific challenges such as transport logistics (Brazil and Uruguay) or water scarcity (Namibia). Nigeria demonstrates significant potential but is constrained by weak infrastructure and public safety concerns. Cameroon Angola and Gabon display moderate performance but require policy and investment reforms. By combining macro-level readiness analysis with social acceptance insights the study highlights opportunities and barriers for diversifying global hydrogen supply chains and advancing sustainable energy transitions in emerging regions.
Hydrogen Admixture Effects on Natural Gas-Oxygen Burner for Glass-melting: Flame Imaging, Temperature Profiles, Exhaust Gas Analysis, and False Air Impact
Jan 2025
Publication
An experimental investigation is carried out to evaluate the effect of introducing hydrogen into natural gas flames on the combustion process (different temperature profiles flame locations and burning velocity) in glass melting furnaces. This work considers the fundamental changes in a non-premixed natural gas-oxygen flame (referred to as oxyfuel flame) with varying levels of hydrogen admixtures ranging from 0 to 100 vol%. To facilitate meaningful data comparisons the burner power output is maintained at a constant thermal power of 20 kW during the entire series of tests. At first the flow field of the oxyfuel burner is measured by using laser doppler anemometry (LDA). Then the burner is tested in a multi-segment combustion chamber with optical accesses. A camera system is employed to visually observe the combustion zone capturing signals in both the visible (VIS) and ultraviolet (UV) wavelengths. The chemiluminescence of the OH* radicals could be determined over the entire flame length. Notably the study reveals variations in flame position especially with higher hydrogen concentrations. Furthermore radial and axial flame temperature profiles are recorded at various po sitions. The analysis extends to major exhaust gas components (CO2 NOx O2) at different fuel compositions and multiple equivalence ratios. In addition a study is being carried out to investigate the influence of false air impacts. The obtained results indicate that the flame temperature increases slightly with pure hydrogen. The NOx values in the overall exhaust gas also show an increase with a higher hydrogen admixture. In particular the influence of false air can lead to a significant rise in NOx levels.
A Review of Life Cycle Assessment (LCA) Studies for Hydrogen Production Technologies through Water Electrolysis: Recent Advances
Aug 2024
Publication
Climate change is a major concern for the sustainable development of global energy systems. Hydrogen produced through water electrolysis offers a crucial solution by storing and generating renewable energy with minimal environmental impact thereby reducing carbon emissions in the energy sector. Our research evaluates current hydrogen production technologies such as alkaline water electrolysis (AWE) proton exchange membrane water electrolysis (PEMWE) solid oxide electrolysis (SOEC) and anion exchange membrane water electrolysis (AEMWE). We systematically review life cycle assessments (LCA) for these technologies analyzing their environmental impacts and recent technological advancements. This study fills essential gaps by providing detailed LCAs for emerging technologies and evaluating their scalability and environmental footprints. Our analysis outlines the strengths and weaknesses of each technology guiding future research and assisting stakeholders in making informed decisions about integrating hydrogen production into the global energy mix. Our approach highlights operational efficiencies and potential sustainability enhancements by employing comparative analyses and reviewing advancements in membrane technology and electrocatalysts. A significant finding is that PEMWE when integrated with renewable energy sources offers rapid response capabilities that are vital for adaptive energy systems and reducing carbon footprints.
Strategy Development for Hydrogen-Conversion Businesses in Côte d’Ivoire
Aug 2024
Publication
Côte d’Ivoire has substantially neglected crop residues from farms in rural areas so this study aimed to provide strategies for the sustainable conversion of these products to hydrogen. The use of existing data showed that in the Côte d’Ivoire there were up to 16801306 tons of crop residues from 11 crop types in 2019 from which 1296424.84 tons of hydrogen could potentially be derived via theoretical gasification and dark fermentation approaches. As 907497.39 tons of hydrogen is expected annually the following estimations were derived. The three hydrogen-project implementation scenarios developed indicate that Ivorian industries could be supplied with 9026635 gigajoules of heat alongside 17910 cars and 4732 buses in the transport sector. It was estimated that 817293.95 tons of green ammonia could be supplied to farmers. According to the study 5727992 households could be expected to have access to 1718.40 gigawatts of electricity. Due to these changes in the transport energy industry and agricultural sectors a reduction of 1644722.08 tons of carbon dioxide per year could theoretically be achieved. With these scenarios around 263276.87 tons of hydrogen could be exported to other countries. The conversion of crop residues to hydrogen is a promising opportunity with environmental and socio-economic impacts. Therefore this study requires further extensive research.
Prospective Assessment of Transformation Pathways Toward Low-carbon Steelmaking: Evaluating Economic and Climate Impacts in Germany
Jan 2024
Publication
Due to climate change there is an urgent need to decarbonize high-emission industries. As coal-based operations predominate in primary steelmaking the steel industry offers an exceptionally high potential for reducing greenhouse gas emissions. Alternative processes for almost fully decarbonized primary steelmaking exist but require substantial investments by steelmakers for their implementation while maintaining desired production levels during the transformation periods. In this context the energy carriers required change such that the transformation of the steelmaking processes is deeply intertwined with the transformation of the background system. For the first time we evaluate potential transformation pathways from the steelmakers’ perspective using a prospective life cycle assessment approach. We find that hydrogen may facilitate a reduction of direct emissions by around 96 % compared to conventional steelmaking in 2050. However indirect emissions remain at a high level throughout the transformation period unless the upstream stages of the value chain are transformed accordingly.
Towards the Simulation of Hydrogen Leakage Scenarios in Closed Buildings Using ContainmentFOAM
Sep 2023
Publication
The increase of using hydrogen as a replacement for fossil fuels in power generation and mobility is expected to witness a huge leap in the next decades. However several safety issues arise due to the physical and chemical properties of hydrogen especially its wide range of flammability. In case of Hydrogen leakage in confined areas Hydrogen clouds can accumulate in the space and their concentration can build up quickly to reach the lower flammability limit (LFL) in case of not applying a proper ventilation system. As a part of the Living Lab Energy Campus (LLEC) project at Jülich Research Centre the use of hydrogen mixed with natural gas as a fuel for the central heating system of the campus is being studied. The current research aims to investigate the release dispersion and formation and the spread of a hydrogen cloud inside the central utility building at the campus of Jülich Research Centre in case of hypothetical accidental leakage. Such a leakage is simulated using the opensource containmentFoam package base on OpenFOAM CFD code to numerically simulate the behavior of the air-hydrogen mixture. The critical locations where hydrogen concentrations can reach the LFL values are shown.
Energy Management of Hydrogen Hybrid Electric Vehicles - A Potential Analysis
Jan 2024
Publication
The hydrogen combustion engine (H2 ICE) is known to be able to burn H2 producing no CO2 emissions and extremely low engine-out NOeo emissions. In this work the potential to reduce the NOeo emissions through the implementation of electric hybridization of an H2 ICE-equipped passenger car (H2 -HEV) combined with a dedicated energy management system (EMS) is discussed. Achieving a low H2 consumption and low NOeo emissions are conflicting objectives the trade-off of which depends on the EMS and can be represented as a Pareto front. The dynamic programming algorithm is used to calculate the Pareto-optimal EMS calibrations for various driving missions. Through the utilization of a dedicated energy management calibration H2 -HEVs exhibit the potential to decrease the NOeo x emissions by more than 90% while decreasing the H2 consumption by over 16% compared to a comparable non-hybridized H2 -vehicle. The present paper represents the initial potential analysis suggesting that H2 -HEVs are a viable option towards a CO2 -free mobility with extremely low NOeo emissions.
Subsurface Renewable Energy Storage Capcity for Hydrogen, Methane and Compress Air - A Performance Assessment Study from the North German Basin
Jul 2021
Publication
The transition to renewable energy sources to mitigate climate change will require large-scale energy storage to dampen the fluctuating availability of renewable sources and to ensure a stable energy supply. Energy storage in the geological subsurface can provide capacity and support the cycle times required. This study investigates hydrogen storage methane storage and compressed air energy storage in subsurface porous formations and quantifies potential storage capacities as well as storage rates on a site-specific basis. For part of the North German Basin used as the study area potential storage sites are identified employing a newly developed structural geological model. Energy storage capacities estimated from a volume-based approach are 6510 TWh and 24544 TWh for hydrogen and methane respectively. For a consistent comparison of storage capacities including compressed air energy storage the stored exergy is calculated as 6735 TWh 25795 TWh and 358 TWh for hydrogen methane and compressed air energy storage respectively. Evaluation of storage deliverability indicates that high deliverability rates are found mainly in two of the three storage formations considered. Even accounting for the uncertainty in geological parameters the storage potential for the three considered storage technologies is significantly larger than the predicted demand and suitable storage rates are achievable in all storage formations.
Hydrogen as an Energy Carrier—An Overview over Technology, Status, and Challenges in Germany
Dec 2024
Publication
Hydrogen is set to become an important energy carrier in Germany in the next decades in the country’s quest to reach the target of climate neutrality by 2045. To meet Germany’s potential green hydrogen demand of up to 587 to 1143 TWh by 2045 electrolyser capacities between 7 and 71 GW by 2030 and between 137 to 275 GW by 2050 are required. Presently the capacities for electrolysis are small (around 153 MW) and even with an increase in electrolysis capacity of >1 GW per year Germany will still need to import large quantities of hydrogen to meet its future demand. This work examines the expected green hydrogen demand in different sectors describes the available technologies and highlights the current situation and challenges that need to be addressed in the next years to reach Germany’s climate goals with regard to scaling up production infrastructure development and transport as well as developing the demand for green hydrogen.
Uncertainty Quantification in Hydrogen Tank Exchange: Estimating Maintenance Costs for New Aircraft Concepts
Apr 2024
Publication
The increasing demand for sustainable air mobility has led to the development of innovative aircraft designs necessitating a balance between environmental responsibility and profitability. However despite technological advancements there is still limited understanding of the maintenance implications for hydrogen systems in aviation. The aim of this study is to estimate the maintenance costs of replacing the hydrogen storage system in an aircraft as part of its life cycle costs. To achieve this we compared conventional and hydrogenpowered aircraft. As there is insufficient data for new aircraft concepts typical probabilistic methods are not applicable. However by combining global sensitivity analysis with Dempster–Shafer Theory of Evidence and discrete event simulation it is possible to identify key uncertainties that impact maintenance costs and economic efficiency. This innovative framework offers an early estimate of maintenance costs under uncertainty enhancing understanding and assisting in decision-making when integrating hydrogen storage systems and new aviation technologies.
Perspective on the Development and Integration of Hydrogen Sensors for Fuel Cell Control
Oct 2024
Publication
The measurement of hydrogen concentration in fuel cell systems is an important prerequisite for the development of a control strategy to enhance system performance reduce purge losses and minimize fuel cell aging effects. In this perspective paper the working principles of hydrogen sensors are analyzed and their requirements for hydrogen control in fuel cell systems are critically discussed. The wide measurement range absence of oxygen high humidity and limited space turn out to be most limiting. A perspective on the development of hydrogen sensors based on palladium as a gas-sensitive metal and based on the organic magnetic field effect in organic lightemitting devices is presented. The design of a test chamber where the sensor response can easily be analyzed under fuel cell-like conditions is proposed. This allows the generation of practical knowledge for further sensor development. The presented sensors could be integrated into the end plate to measure the hydrogen concentration at the anode in- and outlet. Further miniaturization is necessary to integrate them into the flow field of the fuel cell to avoid fuel starvation in each single cell. Compressed sensing methods are used for more efficient data analysis. By using a dynamical sensor model control algorithms are applied with high frequency to control the hydrogen concentration the purge process and the recirculation pump.
The Long Term Price Elastic Demand of Hydrogen - A Multi-model Analysis for Germany
May 2024
Publication
Hydrogen and its derivatives are important components to achieve climate policy goals especially in terms of greenhouse gas neutrality. There is an ongoing controversial debate about the applications in which hydrogen and its derivatives should be used and to what extent. Typically the estimation of hydrogen demand relies on scenario-based analyses with varying underlying assumptions and targets. This study establishes a new framework consisting of existing energy system simulation and optimisation models in order to assess the long-term price-elastic demand of hydrogen. The aim of this work is to shift towards an analysis of the hydrogen demand that is primarily driven by its price. This is done for the case of Germany because of the expected high hydrogen demand for the years 2025–2045. 15 wholesale price pathways were established with final prices in 2045 between 56 €/MWh and 182 €/MWh. The results suggest that – if climate targets are to be achieved - even with high hydrogen prices (252 €/MWh in 2030 and 182 €/MWh in 2045) a significant hydrogen demand in the industry sector and the energy conversion sector is expected to emerge (318 TWh). Furthermore the energy conversion sector has a large share of price sensitive hydrogen demand and therefore its demand strongly increases with lower prices. The road transportation sector will only play a small role in terms of hydrogen demand if prices are low. In the decentralised heating for buildings no relevant demand will be seen over the considered price ranges whereas the centralised supply of heat via heat grids increases as prices fall.
The Race Between Hydrogen and Heat Pumps for Space and Water Heating: A Model-based Scenario Analysis
Nov 2023
Publication
This paper analyses different levels and means of the electrification of space and hot water heating using an explorative modelling approach. The analysis provides guidance to the ongoing discussion on favourable pathways for heating buildings and the role of secondary energy carriers such as hydrogen or synthetic fuels. In total 12 different scenarios were modelled with decarbonisation pathways until 2050 which cover all 27 member states of the European Union. Two highly detailed optimisation models were combined to cover the building stock and the upstream energy supply sector. The analysis shows that decarbonisation pathways for space and water heating based on large shares of heat pumps have at least 11% lower system costs in 2050 than pathways with large shares of hydrogen or synthetic fuels. This translates into system cost savings of around €70 bn. Heat pumps are cost-efficient in decentralised systems and in centralised district heating systems. Hence heat pumps should be the favoured option to achieve a cost-optimal solution for heating buildings. Accordingly the paper makes a novel and significant contribution to understanding suitable and cost-efficient decarbonisation pathways for space and hot water heating via electrification. The results of the paper can provide robust guidance for policymakers.
Experimental Characterization of the Operational Behavior of a Catalytic Recombiner for Hydrogen Mitigation
Sep 2023
Publication
One of the significant safety concerns in large-scale storage and transportation of liquefied (cryogenic) hydrogen (LH2) is the formation of flammable hydrogen/air mixtures after leakages during storage or transportation. Especially in maritime transportation hydrogen accumulations could occur within large and congested geometries. The installation of passive auto-catalytic recombiners (PARs) is a suitable mitigation measure for local areas where venting is insufficient or even impossible. Numerical models describing the operational behavior of PARs are required to allow for optimizing the location and assessing the efficiency of the mitigation measure. In the present study the operational behavior of a PAR with a compact design has been experimentally investigated. In order to obtain data for model validation an experimental program has been performed in the REKO-4 facility a 5.5 m³ vessel. The test procedure includes two phases steady-state and dynamic. The results provide insights into the hydrogen recombination rates and catalyst temperatures under different boundary conditions.
Simulations of Hydrogen Dispersion from Fuel Cell Vehicles' Leakages Inside Full-scale Tunnel
Sep 2023
Publication
In this work real scale experiments involving hydrogen dispersion inside a road tunnel have been modelled using the Computational Fluid Dynamics (CFD) methodology. The aim is to assess the performance of the ADREA-HF CFD tool against full-scale tunnel dispersion data resulting from high-pressure hydrogen leakage through Thermal Pressure Relief Device (TPRD) of a vehicle. The assessment was performed with the help of experiments conducted by the French Alternative Energies and Atomic Energy Commission (CEA) in a real inclined tunnel in France. In the experiments helium as hydrogen surrogate has been released from 200 bar storage pressure. Several tests were carried out examining different TPRD sizes and release directions (upwards and downwards). For the CFD evaluation two tests were considered: one with downwards and one with upwards release both through a TPRD with a diameter of 2 mm. The comparison between the CFD results and the experiments shows the good predictive capabilities of the ADREA-HF code that can be used as a safety tool in hydrogen dispersion studies. The comparison reveals some of the strengths and weaknesses of both the CFD and the experiments. It is made clear that CFD can contribute to the design of the experiments and to the interpretation of the experimental results.
Greenhouse Gas Emissions Performance of Electric, Hydrogen and Fossil-Fuelled Freight Trucks with Uncertainty Estimates Using a Probabilistic Life-Cycle Assessment (pLCA)
Jan 2024
Publication
This research conducted a probabilistic life-cycle assessment (pLCA) into the greenhouse gas (GHG) emissions performance of nine combinations of truck size and powertrain technology for a recent past and a future (largely decarbonised) situation in Australia. This study finds that the relative and absolute life-cycle GHG emissions performance strongly depends on the vehicle class powertrain and year of assessment. Life-cycle emission factor distributions vary substantially in their magnitude range and shape. Diesel trucks had lower life-cycle GHG emissions in 2019 than electric trucks (battery hydrogen fuel cell) mainly due to the high carbon-emission intensity of the Australian electricity grid (mainly coal) and hydrogen production (mainly through steam–methane reforming). The picture is however very different for a more decarbonised situation where battery electric trucks in particular provide deep reductions (about 75–85%) in life-cycle GHG emissions. Fuel-cell electric (hydrogen) trucks also provide substantial reductions (about 50–70%) but not as deep as those for battery electric trucks. Moreover hydrogen trucks exhibit the largest uncertainty in emissions performance which reflects the uncertainty and general lack of information for this technology. They therefore carry an elevated risk of not achieving the expected emission reductions. Battery electric trucks show the smallest (absolute) uncertainty which suggests that these trucks are expected to deliver the deepest and most robust emission reductions. Operational emissions (on-road driving and vehicle maintenance combined) dominate life-cycle emissions for all vehicle classes. Vehicle manufacturing and upstream emissions make a relatively small contribution to life-cycle emissions from diesel trucks (
The Impact of Country-specific Investment Risks on the Levelised Costs of Green Hydrogen Production
Jun 2024
Publication
Green hydrogen is central to the global energy transition. This paper introduces a renewable hydrogen production system model that optimizes hydrogen production on a worldwide 50 km × 50 km grid considering country-specific investment risks. Besides the renewable energy’s impact on the hydrogen production system (HPS) design we analyze the effect of country-specific interest rates on the levelized cost of hydrogen (LCOH) production. Over one-third (40.0%) of all cells have an installed solar PV capacity share between 50% and 70% 76.4% have a hybrid (onshore wind and solar PV) configuration. Hydrogen storage is deployed rather than battery storage to balance hydrogen production via electrolysis and hydrogen demand. Hybrid HPSs can significantly reduce the LCOH production compared to non-hybrid designs whereas country-specific interest rates can lead to significant increases diminishing the relative competitiveness of countries with abundant renewable energy resources compared to countries with fewer resources but fewer investment risks.
Comprehensive Techno-economic Assessment of Power Technologies and Synthetic Fuels under Discussion for Ship Applications
Jun 2023
Publication
The decarbonization of the global ship traffic is one of the industry’s greatest challenges for the next decades and will likely only be achieved with the introduction of synthetic fuels. Until now however not one single best technology solution emerged to ideally fit this task. Instead different energy carriers including hydrogen ammonia methanol methane and synthetic diesel are subject of discussion for usage in either internal combustion engines or fuel cells. In order to drive the selection procedure a case study for the year 2030 with all eligible combinations of power technologies and fuels is conducted. The assessment quantifies the technologies’ economic performances for cost-optimized system designs and in dependence of a ship’s mission characteristics. Thereby the influence of trends for electrofuel prices and shipboard volume opportunity costs are examined. Even if gaseous hydrogen is often considered not suitable for large ship applications due to its low volumetric energy density both the comparatively small fuel price and the high efficiency of fuel cells lead to the overall smallest system costs for passages up to 21 days depending on assumed cost parameters. Only for missions longer than seven days fuel cells operating on methanol or ammonia can compete with gaseous hydrogen economically.
Assessment of a Coupled Electricity and Hydrogen Sector in the Texas Energy System in 2050
Oct 2024
Publication
Due to its ability to reduce emissions in the hard-to-abate sectors hydrogen is expected to play a significant role in future energy systems. This study modifies a sector-coupled dynamic modeling framework for electricity and hydrogen by including policy constraints carbon prices and possible hydrogen pathways and applies it to Texas in 2050. The impact of financial policies including the US clean hydrogen production tax credit on required infrastructure and costs are explored. Due to low natural gas prices financial levers are necessary to promote low-carbon hydrogen production as the optimized solution. The Levelized Costs of Hydrogen are found to be $1.50/kg in the base case (primarily via steam methane reformation production) and lie between $2.10 - 3.10/kg when production is via renewable electrolysis. The supporting infrastructure required to supply those volumes of renewable hydrogen is immense. The hydrogen tax credit was found to be enough to drive production via electrolysis.
Socio-technical Imaginaries of Climate-neutral Aviation
May 2024
Publication
Limiting global warming to 1.5 ◦C is crucial to prevent the worst effects of climate change. This entails also the decarbonization of the aviation sector which is considered to be a “hard-to-abate” sector and thus requires special attention regarding its sustainability transition. However transition pathways to a potentially climateneutral aviation sector are unclear with different stakeholders having diverse imaginations of the sector's future. This paper aims to analyze socio-technical imaginaries of climate-neutral aviation as different perceptions of various stakeholders on this issue have not been sufficiently explored so far. In that sense this work contributes to the current scientific debate on socio-technical imaginaries of energy transitions for the first time studying the case of the aviation sector. Drawing on six decarbonization reports composed by different interest groups (e.g. industry academia and environmental associations) three imaginaries were explored following the process of a thematic analysis: rethinking travel and behavioral change (travel innovation) radical modernization and technological progress (fleet innovation) and transition to alternative fuels and renewable energy sources (fuel innovation). The results reveal how different and partly conflicting socio-technical imaginaries are co-produced and how the emergence and enforceability of these imaginaries is influenced by the situatedness of their creators indicating that the sustainability transition of aviation also raises political issues. Essentially as socio-technical imaginaries act as a driver for change policymakers should acknowledge the existence of alternative and counter-hegemonic visions created by actors from civil society settings to take an inclusive and equitable approach to implementing pathways towards climate-neutral aviation.
Pathways to the Hydrogen Economy: A Multidimensional Analysis of the Technological Innovation Systems of Germany and South Korea
Aug 2023
Publication
The global trend towards decarbonization and the demand for energy security have put hydrogen energy into the spotlight of industry politics and societies. Numerous governments worldwide are adopting policies and strategies to facilitate the transition towards hydrogen-based economies. To assess the determinants of such transition this study presents a comparative analysis of the technological innovation systems (TISs) for hydrogen technologies in Germany and South Korea both recognized as global front-runners in advancing and implementing hydrogen-based solutions. By providing a multi-dimensional assessment of pathways to the hydrogen economy our analysis introduces two novel and crucial elements to the TIS analysis: (i) We integrate the concept of ‘quality infrastructure’ given the relevance of safety and quality assurance for technology adoption and social acceptance and (ii) we emphasize the social perspective within the hydrogen TIS. To this end we conducted 24 semi-structured expert interviews applying qualitative open coding to analyze the data. Our results indicate that the hydrogen TISs in both countries have undergone significant developments across various dimensions. However several barriers still hinder the further realization of a hydrogen economy. Based on our findings we propose policy implications that can facilitate informed policy decisions for a successful hydrogen transition.
Hydrogen in the Natural Gas Network—Relevance for Existing Fire Precautions
Jun 2024
Publication
Power-to-gas technology can be used to convert excess power from renewable energies to hydrogen by means of water electrolysis. This hydrogen can serve as “chemical energy storage” and be converted back to electricity or fed into the natural gas grid. In the presented study a leak in a household pipe in a single-family house with a 13 KW heating device was experimentally investigated. An admixture of up to 40% hydrogen was set up to produce a scenario of burning leakage. Due to the outflow and mixing conditions a lifted turbulent diffusion flame was formed. This led to an additional examination point and expanded the aim and novelty of the experimental investigation. In addition to the fire safety experimental simulation of a burning leakage the resulting complex properties of the flame namely the lift-off height flame length shape and thermal radiation have also been investigated. The obtained results of this show clearly that as a consequence of the hydrogen addition the main properties of the flame such as lifting height flame temperature thermal radiation and total heat flux densities along the flame have been changed. To supplement the measurements with thermocouples imaging methods based on the Sobel gradient were used to determine the lifting height and the flame length. In order to analyze the determined values a probability density function was created.
Blue Hydrogen and Industrial Base Products: The Future of Fossil Fuel Exporters in a Net-zero World
May 2022
Publication
Is there a place for today’s fossil fuel exporters in a low-carbon future? This study explores trade channels between energy exporters and importers using a novel electricity-hydrogen-steel energy systems model calibrated to Norway a major natural gas producer and Germany a major energy consumer. Under tight emission constraints Norway can supply Germany with electricity (blue) hydrogen or natural gas with re-import of captured CO2. Alternatively it can use hydrogen to produce steel through direct reduction and supply it to the world market an export route not available to other energy carriers due to high transport costs. Although results show that natural gas imports with CO2 capture in Germany is the least-cost solution avoiding local CO2 handling via imports of blue hydrogen (direct or embodied in steel) involves only moderately higher costs. A robust hydrogen demand would allow Norway to profitably export all its natural gas production as blue hydrogen. However diversification into local steel production as one example of easy-to-export industrial base products offers an effective hedge against the possibility of lower European blue hydrogen demand. Looking beyond Europe the findings of this study are also relevant for the world’s largest energy exporters (e.g. OPEC+) and importers (e.g. developing Asia). Thus it is recommended that large hydrocarbon exporters consider a strategic energy export transition to a diversified mix of blue hydrogen and climate-neutral industrial base products.
Risk Management in a Containerized Metal Hydride Storage System
Sep 2023
Publication
HyCARE project supported by the Clean Hydrogen Partnership of the European Union deals with a prototype of hydrogen storage tank using a solid-state hydrogen carrier. Up to 40 kilograms of hydrogen are stored in twelve tanks at less than 50 barg and less than 100 °C. The innovative design is based on a standard twenty-foot container including twelve TiFe-based metal hydride (MH) hydrogen storage tanks coupled with a thermal energy storage in phase change materials (PCM). This article aims at showing the main risks related to hydrogen storage in a MH system and the safety barriers considered based on HyCARE’s specific risk analysis.<br/>Regarding the TiFe MH material used to store hydrogen experimental tests showed that the exposure of the MH to air or water did not cause spontaneous ignition. Furthermore an explosion within the solid MH cannot propagate due to internal pore size. Additionally in case of leakage the speed of hydrogen desorption from the MH is self-limited which is an important safety characteristic since it reduces the potential consequences from the hydrogen release scenario.<br/>Regarding the integrated system the critical scenarios identified during the risk analysis were: explosion due to release of hydrogen inside or outside the container internal explosion inside MH tanks due to accidental mix of hydrogen and air and asphyxiation due to inert gas accumulation in the container. This identification phase of the risk analysis allowed to pinpoint the most relevant safety barriers already in place and recommend additional ones if needed to further reduce the risk that were later implemented.<br/>The main safety barriers identified were: material and component selection (including the MH selected) safety interlocks safety valves ventilation gas detection and safety distances.<br/>The risk management process based on risk identification and assessment contributed to coherently integrate inherently safe design features and safety barriers.
Benchmark of J55 and X56 Steels on Cracking and Corrosion Effects Under Hydrogen Salt Cavern Boundary Conditions
Feb 2024
Publication
Salt caverns have great potential to store relevant amounts of hydrogen as part of the energy transition. However the durability and suitability of commonly used steels for piping in hydrogen salt caverns is still under research. In this work aging effects focusing on corrosion and cracking patterns of casing steel API 5CT J55 and “H2ready” pipeline steel API 5L X56 were investigated with scanning electron microscopy and energy dispersive X-ray spectroscopy after accelerated stress tests with pressure/temperature cycling under hydrogen salt cavern-like conditions. Compared to dry conditions significant more corrosion by presence of salt ions was detected. However compared to X56 only for J55 an intensification of corrosion and cracking at the surface due to hydrogen atmosphere was revealed. Pronounced surface cracks were observed for J55 over the entire samples. Overall the results strongly suggest that X56 is more resistant than J55 under the conditions of a hydrogen salt cavern.
Renewable Hydrogen in Industrial Production: A Bibliometric Analysis of Current and Future Applications
Dec 2024
Publication
Renewable hydrogen is widely considered a key technology to achieve net zero emissions in industrial production processes. This paper presents a structured bibliometric analysis examining current and future applications of hydrogen as feedstock and fuel across industries quantifying demand for different industrial processes and identifying greenhouse gas emissions reduction potential against the context of current fossil-based practices. The findings highlight significant focus on hydrogen as feedstock for steel ammonia and methanol production and its use in high-to medium-temperature processes and a general emphasis on techno-economic and technological evaluations of hydrogen applications across industries. However gaps exist in research on hydrogen use in sectors like cement glass waste pulp and paper ceramics and aluminum. Additionally the analysis reveals limited attention in the identified literature to hydrogen supply chain efficiencies including conversion and transportation losses as well as geopolitical and raw material challenges. The analysis underscores the need for comprehensive and transparent data to align hydrogen use with decarbonization goals optimize resource allocation and inform policy and investment decisions for strategic deployment of renewable hydrogen.
The Regulatory Framework of Geological Storage of Hydrogen in Salt Caverns
Sep 2023
Publication
A growing share of renewable energy production in the energy supply systems is key to reaching the European political goal of zero CO2 emission in 2050 highlighted in the green deal. Linked to the irregular production of solar and wind energies which have the highest potential for development in Europe massive energy storage solutions are needed as energy buffers. The European project HyPSTER [1] (Hydrogen Pilot STorage for large Ecosystem Replication) granted by the Clean Hydrogen Partnership addresses this topic by demonstrating a cyclic test in an experimental salt cavern filled with hydrogen up to 3 tons using hydrogen that is produced onsite by a 1 MW electrolyser. One specific objective of the project is the assessment of the risks and environmental impacts of cyclic hydrogen storage in salt caverns and providing guidelines for safety regulations and standards. This paper highlights the first outcome of the task WP5.5 of the HyPSTER project addressing the regulatory and normative frameworks for the safety of hydrogen storage in salt caverns from some selected European Countries which is dedicated to defining recommendations for promoting the safe development of this industry within Europe.
QRA of Hydrogen Vehicles in a Road Tunnel
Sep 2023
Publication
Hydrogen energy is recognized by many European governments as an important part of the development to achieve a more sustainable energy infrastructure. Great efforts are spent to build up a hydrogen supply chain to support the increasing number of hydrogen-powered vehicles. Naturally these vehicles will use the common traffic infrastructure. Thus it has to be ensured these infrastructures are capable to withstand the hazards and associated risks that may arise from these new technologies. In order to have an appropriate assessment tool for hydrogen vehicles transport through tunnels a new QRA methodology is developed and presented here. In Europe the PIARC is a very common approach. It is therefore chosen as a starting point for the new methodology. It provides data on traffic statistics accident frequencies tunnel geometries including certain prevention and protection measures. This approach is enhanced by allowing better identification of hazards and their respective sources for hydrogen vehicles. A detailed analysis of the accident scenarios that are unique for hydrogen vehicles hereunder the initiating events severity of collision types that may result in a release of hydrogen gas in a tunnel and the location of such an accident are included. QRA enables the assessment and evaluation of scenarios involving external fires or vehicles that burst into fire because of an accident or other fire sources. Event Tree Analysis is the technique used to estimate the event frequencies. The consequence analysis includes the hazards from blast waves hydrogen jet fires DDT.
The Role of Hydrogen in the Ecological Benefits of Ultra Low Sulphur Diesel Production and Use: An LCA Benchmark
Apr 2019
Publication
Desulphurization of oil-based fuels is common practice to mitigate the ecological burden to ecosystems and human health of SOx emissions. In many countries fuels for vehicles are restricted to 10 ppm sulphur. For marine fuels low sulphur contents are under discussion. The environmental impact of desulphurization processes is however quite high: (1) The main current source for industrial hydrogen is Steam Methane Reforming (SMR) with a rather high level of CO2 emissions (2) the hydrotreating process especially below 150 ppm needs a lot of energy. These two issues lead to three research questions: (a) What is the overall net ecological benefit of the current desulphurization practice? (b) At which sulfphur ppm level in the fuel is the additional ecological burden of desulphurization higher than the additional ecological benefit of less SOx pollution from combustion? (c) To what extent can cleaner hydrogen processes improve the ecological benefit of diesel desulphurization? In this paper we use LCA to analyze the processes of hydrotreatment the recovery of sulphur via amine treating of H2S and three processes of hydrogen production: SMR without Carbon Capture and Sequestration (CCS) SMR with 53% and 90% CCS and water electrolysis with two types of renewable energy. The prevention-based eco-costs system is used for the overall comparison of the ecological burden and the ecological benefit. The ReCiPe system was applied as well but appeared not suitable for such a comparison (other damage-based indicators cannot be applied either). The overall conclusion is that (1) the overall net ecological benefit of hydrogen-based Ultra Low Sulphur Diesel is dependent of local conditions but is remarkably high (2) desulphurization below 10 ppm is beneficial for big cities and (3) cleaner production of hydrogen reduces eco-cost by a factor 1.8–3.4.
50 Shades of Hydrogen: A Perspective on Definitions in Science and Public Communication
Sep 2025
Publication
Discussions about the transition to hydrogen in various applications have become an important topic in recent years. A key factor for an effective transition is public acceptance of hydrogen technologies. However the increase in acceptance depends among other things on individual knowledge about the hydrogen colors and the linked hydrogen production pathways currently under discussion. In communications colors such as green grey and blue are used to distinguish hydrogen sources. With new research additional colors have become necessary. Unfortunately there is no unified definition for the colors. The aim of this perspective is to identify the most frequent hydrogen colors used by scientists and the public derive open definitions and propose a solution to a representation problem. The general use of hydrogen colors in communication and the implications on public acceptance are briefly outlined. We then identified definitions for colors associated with a specific pathway and discussed some discrepancies between science and media use. To make better use of the existing colors more open definitions were formulated. We point out the representation problem with shades of a color and provide a connection between the assigned color and a view-independent RGB color code as proposal. The derived definitions can be used to unify communication in science and public media.
No more items...