Germany
Hydrogen-Assisted Cracking in GMA Welding of High-Strength Structural Steel—A New Look into This Issue at Narrow Groove
Jun 2021
Publication
Modern arc processes such as the modified spray arc (Mod. SA) have been developed for gas metal arc welding of high-strength structural steels with which even narrow weld seams can be welded. High-strength joints are subjected to increasingly stringent requirements in terms of welding processing and the resulting component performance. In the present work this challenge is to be met by clarifying the influences on hydrogen-assisted cracking (HAC) in a high-strength structural steel S960QL. Adapted samples analogous to the self-restraint TEKKEN test are used and analyzed with respect to crack formation microstructure diffusible hydrogen concentration and residual stresses. The variation of the seam opening angle of the test seams is between 30° and 60°. To prevent HAC the effectiveness of a dehydrogenation heat treatment (DHT) from the welding heat is investigated. As a result the weld metals produced at reduced weld opening angle show slightly higher hydrogen concentrations on average. In addition increased micro- as well as macro-crack formation can be observed on these weld metal samples. On all samples without DHT cracks in the root notch occur due to HAC which can be prevented by DHT immediately after welding.
Hydrogen Technology Towards the Solution of Environment-Friendly New Energy Vehicles
Aug 2021
Publication
The popularity of climate neutral new energy vehicles for reduced emissions and improved air quality has been raising great attention for many years. World-wide a strong commitment continues to drive the demand for zero-emission through alternative energy sources and propulsion systems. Despite the fact that 71.27% of hydrogen is produced from natural gas green hydrogen is a promising clean way to contribute to and maintain a climate neutral ecosystem. Thereby reaching CO2 targets for 2030 and beyond requires cross-sectoral changes. However the strong motivation of governments for climate neutrality is challenging many sectors. One of them is the transport sector as it is challenged to find viable all-in solutions that satisfy social economic and sustainable requirements. Currently the use of new energy vehicles operating on green sustainable hydrogen technologies such as batteries or fuel cells has been the focus for reducing the mobility induced emissions. In Europe 50% of the total emissions result from mobility. The following article reviews the background ongoing challenges and potentials of new energy vehicles towards the development of an environmentally friendly hydrogen economy. A change management process mindset has been adapted to discuss the key scientific and commercial challenges for a successful transition.
Decarbonizing the German Industrial Thermal Energy Use with Solar, Hydrogen, and Other Options - Recommendations for the World
Nov 2022
Publication
This paper is based on a position paper of the German Industry Association Concentrated Solar Power e.V. to the German government and discusses options on how to decarbonize the heat demand of the domestic industry. Among other option concentration solar collectors are a suitable option in Germany which has not been expected by many experts. The paper derives requirements that are needed to ensure a quick and sustainable way to decarbonize industrial heat demand. They are considered to also be relevant for many other countries that follow the same ambition to become climate neutral in the next decades. They major statements are: A mix of different renewable energy technologies in conjunction with efficiency measures is needed to ensure a secure climate-friendly and cost-efficient heat supply for the industry; The different technology options for the provision of heat from renewable sources through electrification and through hydrogen can and must be combined and integrated with each other. In this context concentrating solar thermal represents an important part of the hybrid supply portfolio of a decarbonized industry This requires: The definition of an expansion target for process heat and the flanking measures; Ensuring the equivalence of renewable heat renewable electricity and green hydrogen - also as hybrid solutions; The promotion of concentrating solar thermal reference projects as an impetus for market ramp-up in Germany; The launch of an information campaign for heat consumers and the establishment of a pool of consultants.
Setting Thresholds to Define Indifferences and Preferences in PROMETHEE for Life Cycle Sustainability Assessment of European Hydrogen Production
Jun 2021
Publication
The Life Cycle Sustainability Assessment (LCSA) is a proven method for sustainability assessment. However the interpretation phase of an LCSA is challenging because many different single results are obtained. Additionally performing a Multi-Criteria Decision Analysis (MCDA) is one way—not only for LCSA—to gain clarity about how to interpret the results. One common form of MCDAs are outranking methods. For these type of methods it becomes of utmost importance to clarify when results become preferable. Thus thresholds are commonly used to prevent decisions based on results that are actually indifferent between the analyzed options. In this paper a new approach is presented to identify and quantify such thresholds for Preference Ranking Organization METHod for Enrichment Evaluation (PROMETHEE) based on uncertainty of Life Cycle Impact Assessment (LCIA) methods. Common thresholds and this new approach are discussed using a case study on finding a preferred location for sustainable industrial hydrogen production comparing three locations in European countries. The single LCSA results indicated different preferences for the environmental economic and social assessment. The application of PROMETHEE helped to find a clear solution. The comparison of the newly-specified thresholds based on LCIA uncertainty with default thresholds provided important insights of how to interpret the LCSA results regarding industrial hydrogen production.
Development of a Flashback Correlation for Burner-stabilized Hydrogen-air Premixed Flames
Feb 2022
Publication
With a growing need for replacing fossil fuels with cleaner alternatives hydrogen has emerged as a viable candidate for providing heat and power. However stable and safe combustion of hydrogen is not simple and as such a number of key issues have been identified that need to be understood for a safe design of combustion chambers. One such issue is the higher propensity of hydrogen flames to flashback compared to that for methane flames. The flashback problem is coupled with higher burner temperatures that could cause strong thermal stresses in burners and could hinder their performance. In order to systematically investigate flashback in premixed hydrogen-air flames for finding a global flashback criteria in this study we use numerical simulations as a basic tool to study flashback limits of slit burners. Flashback limits are found for varying geometrical parameters and equivalence ratios and the sensitivity of each parameter on the flashback limit and burner temperatures are identified and analyzed. It is shown that the conventional flashback correlation with critical velocity gradient does not collapse the flashback data as it does not take into account stretch induced preferential diffusion effects. A new Karlovitz number definition is introduced with physical insights that collapses the flashback data at all tested conditions in an excellent manner.
AI Agents Envisioning the Future: Forecast-based Operation of Renewable Energy Storage Systems Using Hydrogen with Deep Reinforcement Learning
Feb 2022
Publication
Hydrogen-based energy storage has the potential to compensate for the volatility of renewable power generation in energy systems with a high renewable penetration. The operation of these storage facilities can be optimized using automated energy management systems. This work presents a Reinforcement Learning-based energy management approach in the context of CO2-neutral hydrogen production and storage for an industrial combined heat and power application. The economic performance of the presented approach is compared to a rule-based energy management strategy as a lower benchmark and a Dynamic Programming-based unit commitment as an upper benchmark. The comparative analysis highlights both the potential benefits and drawbacks of the implemented Reinforcement Learning approach. The simulation results indicate a promising potential of Reinforcement Learning-based algorithms for hydrogen production planning outperforming the lower benchmark. Furthermore a novel approach in the scientific literature demonstrates that including energy and price forecasts in the Reinforcement Learning observation space significantly improves optimization results and allows the algorithm to take variable prices into account. An unresolved challenge however is balancing multiple conflicting objectives in a setting with few degrees of freedom. As a result no parameterization of the reward function could be found that fully satisfied all predefined targets highlighting one of the major challenges for Reinforcement Learning -based energy management algorithms to overcome.
Strategies for the Sampling of Hydrogen at Refuelling Stations for Purity Assessment
Aug 2021
Publication
Hydrogen delivered at hydrogen refuelling station must be compliant with requirements stated in different standards which require specialized sampling device and personnel to operate it. Currently different strategies are implemented in different parts of the world and these strategies have already been used to perform 100s of hydrogen fuel sampling in USA EU and Japan. However these strategies have never been compared on a large systematic study. The purpose of this paper is to describe and compare the different strategies for sampling hydrogen at the nozzle and summarize the key aspects of all the existing hydrogen fuel sampling including discussion on material compatibility with the impurities that must be assessed. This review highlights the fact it is currently difficult to evaluate the impact or the difference these strategies would have on the hydrogen fuel quality assessment. Therefore comparative sampling studies are required to evaluate the equivalence between the different sampling strategies. This is the first step to support the standardization of hydrogen fuel sampling and to identify future research and development area for hydrogen fuel sampling.
Is Iridium Demand a Potential Bottleneck in the Realization of Large-Scale PEM Water Electrolysis?
Jul 2021
Publication
Proton exchange membrane water electrolysis (PEMWE) is a key technology for future sustainable energy systems. Proton exchange membrane (PEM) electrolysis cells use iridium one of the scarcest elements on earth as catalyst for the oxygen evolution reaction. In the present study the expected iridium demand and potential bottlenecks in the realization of PEMWE for hydrogen production in the targeted GW a−1 scale are assessed in a model built on three pillars: (i) an in-depth analysis of iridium reserves and mine production (ii) technical prospects for the optimization of PEM water electrolyzers and (iii) PEMWE installation rates for a market ramp-up and maturation model covering 50 years. As a main result two necessary preconditions have been identified to meet the immense future iridium demand: first the dramatic reduction of iridium catalyst loading in PEM electrolysis cells and second the development of a recycling infrastructure for iridium catalysts with technical end-of-life recycling rates of at least 90%.
Hydrogen Supply Chains for Mobility—Environmental and Economic Assessment
May 2018
Publication
Hydrogen mobility is one option for reducing local emissions avoiding greenhouse gas (GHG) emissions and moving away from a mainly oil-based transport system towards a diversification of energy sources. As hydrogen production can be based on a broad variety of technologies already existing or under development a comprehensive assessment of the different supply chains is necessary regarding not only costs but also diverse environmental impacts. Therefore in this paper a broad variety of hydrogen production technologies using different energy sources renewable and fossil are exemplarily assessed with the help of a Life Cycle Assessment and a cost assessment for Germany. As environmental impacts along with the impact category Climate change five more advanced impact categories are assessed. The results show that from an environmental point of view PEM and alkaline electrolysis are characterized by the lowest results in five out of six impact categories. Supply chains using fossil fuels in contrast have the lowest supply costs; this is true e.g. for steam methane reforming. Solar powered hydrogen production shows low impacts during hydrogen production but high impacts for transport and distribution to Germany. There is no single supply chain that is the most promising for every aspect assessed here. Either costs have to be lowered further or supply chains with selected environmental impacts have to be modified.
Nested Decomposition Approach for Dispatch Optimization of Large-Scale, Integrated Electricity, Methane and Hydrogen Infrastructures
Apr 2022
Publication
Energy system integration enables raising operational synergies by coupling the energy infrastructures for electricity methane and hydrogen. However this coupling reinforces the infrastructure interdependencies increasing the need for integrated modeling of these infrastructures. To analyze the cost-efficient sustainable and secure dispatch of applied large-scale energy infrastructures an extensive and non-linear optimization problem needs to be solved. This paper introduces a nested decomposition approach with three stages. The method enables an integrated and full-year consideration of large-scale multi-energy systems in hourly resolution taking into account physical laws of power flows in electricity and gas transmission systems as boundary conditions. For this purpose a zooming technique successively reduces the temporal scope while first increasing the spatial and last the technical resolution. A use case proves the applicability of the presented approach to large-scale energy systems. To this end the model is applied to an integrated European energy system model with a detailed focus on Germany in a challenging transport situation. The use case demonstrates the temporal regional and cross-sectoral interdependencies in the dispatch of integrated energy infrastructures and thus the benefits of the introduced approach.
Sector Coupling and Business Models Towards Sustainability: The Case of the Hydrogen Vehicle Industry
Mar 2022
Publication
The concept of sector coupling has been gaining increased momentum in political discourses during 18 the past few years but it has only recently received the attention of international academics. The 19 private sector is particularly relevant to foster sector coupling through entrepreneurial action – 20 specifically innovative business models for more sustainable technologies are needed to promote a 21 transition towards more sustainability. So far however the literature on business models from a 22 sector coupling perspective is scarce yet strongly emerging. To address the identified research gaps 23 and enhance the current knowledge on the emerging hydrogen vehicle industry and sector coupling 24 this study adopts a qualitative and exploratory research approach and builds on information gained 25 in 103 semi-structured interviews to discuss emerging business models in Germany. In particular 33 26 business cases have been analyzed. Anchoring business model theory to the concept of sector 27 coupling this study identifies 12 business model archetypes in the emerging hydrogen vehicle 28 industry and its value chain. It can be shown that while the market is still emerging and the market 29 players are not defined and are evolving companies are currently engaged in finding their position 30 along the value chain fostering vertical integration and promoting cooperation between the 31 different sectors. While this study is relevant for both the academia and the industry it is particularly 2 32 interesting for policy makers shaping the future of sustainable development specifically considering 33 integrated energy systems.
Cost-effective Technology Choice in a Decarbonized and Diversified Long-haul Truck Transportation Sector: A U.S. Case Study
Dec 2021
Publication
Achieving net-zero emissions by 2050 will require accelerated efforts that include decarbonizing long-haul truck transportation. In this difficult-to-decarbonize low-margin industry economic transparency on technology options is vital for decision makers seeking to eliminate emissions. Battery electric (BET) and hydrogen fuel cell electric trucks (FCET) can represent emission-free alternatives to diesel-powered trucks (DT). Previous studies focus on cost competitiveness in weight-constrained transportation even though logistics research shows that significant shares of transportation are constrained by volume and analyze cost only for selected technologies hence impeding a differentiated market segmentation of future emission-free trucks. In this study the perspective of a rational investor is taken and it is shown that under current conditions in the U.S. BETs outperform FCETs in various long-haul use cases despite charging times and cargo deficits and will further increase their technological competitiveness to DTs. While future energy and fueling prices are decisive for BET competitiveness the analysis reveals that autonomous driving may change the picture in favor of FCETs.
Hydrogen-powered Aviation and its Reliance on Green Hydrogen Infrastructure - Review and Research Gaps
Oct 2021
Publication
Aircraft powered by green hydrogen (H2) are a lever for the aviation sector to reduce the climate impact. Previous research already focused on evaluations of H2 aircraft technology but analyses on infrastructure related cost factors are rarely undertaken. Therefore this paper aims to provide a holistic overview of previous efforts and introduces an approach to assess the importance of a H2 infrastructure for aviation. A short and a medium-range aircraft are modelled and modified for H2 propulsion. Based on these a detailed cost analysis is used to compare both aircraft and infrastructure related direct operating costs (DOC). Overall it is shown that the economy of H2 aviation highly depends on the availability of low-cost green liquid hydrogen (LH2) supply infrastructure. While total DOC might even slightly decrease in a best LH2 cost case total DOC could also increase between 10 and 70% (short-range) and 15e102% (medium-range) due to LH2 costs alone.
An Overview of Promising Alternative Fuels for Road, Rail, Air, and Inland Waterway Transport in Germany
Feb 2022
Publication
To solve the challenge of decarbonizing the transport sector a broad variety of alternative fuels based on different concepts including Power-to-Gas and Power-to-Liquid and propulsion systems have been developed. The current research landscape is investigating either a selection of fuel options or a selection of criteria a comprehensive overview is missing so far. This study aims to close this gap by providing a holistic analysis of existing fuel and drivetrain options spanning production to utilization. For this purpose a case study for Germany is performed considering different vehicle classes in road rail inland waterway and air transport. The evaluated criteria on the production side include technical maturity costs as well as environmental impacts whereas on the utilization side possible blending with existing fossil fuels and the satisfaction of the required mission ranges are evaluated. Overall the fuels and propulsion systems Methanol-to-Gasoline Fischer–Tropsch diesel and kerosene hydrogen battery-electric propulsion HVO DME and natural gas are identified as promising future options. All of these promising fuels could reach near-zero greenhouse gas emissions bounded to some mandatory preconditions. However the current research landscape is characterized by high insecurity with regard to fuel costs depending on the predicted range and length of value chains.
The Evolution and Structure of Ignited High-pressure Cryogenic Hydrogen Jets
Jun 2022
Publication
The anticipated upscaling of hydrogen energy applications will involve the storage and transport of hydrogen at cryogenic conditions. Understanding the potential hazard arising from leaks in high-pressure cryogenic storage is needed to improve hydrogen safety. The manuscript reports a series of numerical simulations with detailed chemistry for the transient evolution of ignited high-pressure cryogenic hydrogen jets. The study aims to gain insight of the ignition processes flame structures and dynamics associated with the transient flame evolution. Numerical simulations were firstly conducted for an unignited jet released under the same cryogenic temperature of 80 K and pressure of 200 bar as the considered ignited jets. The predicted hydrogen concentrations were found to be in good agreement with the experimental measurements. The results informed the subsequent simulations of the ignited jets involving four different ignition locations. The predicted time series snapshots of temperature hydrogen mass fraction and the flame index are analyzed to study the transient evolution and structure of the flame. The results show that a diffusion combustion layer is developed along the outer boundary of the jet and a side diffusion flame is formed for the near-field ignition. For the far-field ignition an envelope flame is observed. The flame structure contains a diffusion flame on the outer edge and a premixed flame inside the jet. Due to the complex interactions between turbulence fuel-air mixing at cryogenic temperature and chemical reactions localized spontaneous ignition and transient flame extinguishment are observed. The predictions also captured the experimentally observed deflagration waves in the far-field ignited jets.
Building the Green Hydrogen Market - Current State and Outlook on Green Hydrogen Demand and Electrolyzer Manufacturing
Jul 2022
Publication
Over the past two years requirements to meet climate targets have been intensified. In addition to the tightening of the climate targets and the demand for net-zero achievement by as early as 2045 there have been discussions on implementing and realizing these goals. Hydrogen has emerged as a promising climate-neutral energy carrier. Thus over the last 1.5 years more than 25 countries have published hydrogen roadmaps. Furthermore various studies by different authorities have been released to support the development of a hydrogen economy. This paper examines published studies and hydrogen country roadmaps as part of a meta-analysis. Furthermore a market analysis of electrolyzer manufacturers is conducted. The prospected demand for green hydrogen from various studies is compared to electrolyzer manufacturing capacities and selected green hydrogen projects to identify potential market ramp-up scenarios and to evaluate if green hydrogen demand forecasts can be filled.
The Role of Renewable Energies, Storage and Sector-Coupling Technologies in the German Energy Sector under Different CO2 Emission Restrictions
Aug 2022
Publication
This study aimed to simulate the sector-coupled energy system of Germany in 2030 with the restriction on CO2 emission levels and to observe how the system evolves with decreasing emissions. Moreover the study presented an analysis of the interconnection between electricity heat and hydrogen and how technologies providing flexibility will react when restricting CO2 emissions levels. This investigation has not yet been carried out with the technologies under consideration in this study. It shows how the energy system behaves under different set boundaries of CO2 emissions and how the costs and technologies change with different emission levels. The study results show that the installed capacities of renewable technologies constantly increase with higher limitations on emissions. However their usage rates decreases with low CO2 emission levels in response to higher curtailed energy. The sector-coupled technologies behave differently in this regard. Heat pumps show similar behaviour while the electrolysers usage rate increases with more renewable energy penetration. The system flexibility is not primarily driven by the hydrogen sector but in low CO2 emission level scenarios the flexibility shifts towards the heating sector and electrical batteries.
Underground Bio-methanation: Concept and Potential
Feb 2020
Publication
As a major part of the energy turn around the European Union and other countries are supporting the development of renewable energy technologies to decrease nuclear and fossil energy production. Therefore efficient use of renewable energy resources is one challenge as they are influenced by environmental conditions and hence the intensity of resources such as wind or solar power fluctuates. To secure constant energy supply suitable energy storage and conversion techniques are required. An upcoming solution is the utilization and storage of hydrogen or hydrogen-rich natural gas in porous formations in the underground. In the past microbial methanation was observed as a side effect during these gas storage operations. The concept of underground bio-methanation arised which uses the microbial metabolism to convert hydrogen and carbon dioxide into methane. The concept consists of injecting gaseous hydrogen and carbon dioxide into an underground structure during energy production peaks which are subsequently partly converted into methane. The resulting methane-rich gas mixture is withdrawn during high energy demand. The concept is comparable to engineered bio-reactors which are already locally integrated into the gas infrastructure. In both technologies the conversion process of hydrogen into methane is driven by hydrogenotrophic methanogenic archaea present in the aqueous phase of the natural underground or above-ground engineered reactor. Nevertheless the porous medium in the underground provides compared to the engineered bio-reactors a larger interface between the gas and aqueous phase caused by the enormous volume in the underground porous media. The following article summarizes the potential and concept of underground methanation and the current state of the art in terms of laboratory investigations and pilot tests. A short system potential analysis shows that an underground bio-reactor with a storage capacity of 850 Mio. Sm3 could deliver methane to more than 600000 households based on a hydrogen production from renewable energies.
The More the Merrier? Actors and Ideas in the Evolution of Germany Hydrogen Policy Discourse
Feb 2023
Publication
Hydrogen has set high hopes for decarbonization due to its flexibility and ability to decarbonize sectors of the economy where direct electrification appears unviable. Broad hydrogen policies have therefore started to emerge. Nevertheless it is still a rather niche technology not integrated or adopted at scale and not regulated through particular policy provisions. The involved stakeholders are thus still rushing to set the agenda over the issue. All this plays out publicly and shapes the public discourse. This paper explores how the composition of stakeholders their positions and the overall discourse structure have developed and accompanied the political agenda-setting in the early public debate on hydrogen in Germany. We use discourse network analysis of media where stakeholders' claims-making is documented and their positions can be tracked over time. The public discourse on hydrogen in Germany shows the expected evolution of statements in connection with the two milestones chosen for the analyses the initiation of the Gas 2030 Dialogue and the publication of the National Hydrogen Strategy. Interestingly the discourse was comparatively feeble in the immediate aftermath of the respective milestones but intensified in a consolidation phase around half a year later. Sequencing the discourse and contextualizing its content relative to political societal and economic conditions in a diachronic way is essential because it helps to avoid misinterpreting the development of stakeholders' standpoints as conflict-driven rather than mere repositioning. Thus we observed no discourse “polarization” even though potentially polarizing issues were already present in the debate.
Green Hydrogen Production and Use in Low- and Middle-income Countries: A Least-cost Geospatial Modelling Approach Applied to Kenya
May 2023
Publication
With the rising threat of climate change green hydrogen is increasingly seen as the high-capacity energy storage and transport medium of the future. This creates an opportunity for low- and middle-income countries to leverage their high renewable energy potential to produce use and export low-cost green hydrogen creating environmental and economic development benefits. While identifying ideal locations for green hydrogen production is critical for countries when defining their green hydrogen strategies there has been a paucity of adequate geospatial planning approaches suitable to low- and middle-income countries. It is essential for these countries to identify green hydrogen production sites which match demand to expected use cases such that their strategies are economically sustainable. This paper therefore develops a novel geospatial cost modelling method to optimize the location of green hydrogen production across different use cases with a focus on suitability to low- and middle-income countries. This method is applied in Kenya to investigate the potential hydrogen supply chain for three use cases: ammonia-based fertilizer freight transport and export. We find hydrogen production costs of e3.7–9.9/kgH2 are currently achievable across Kenya depending on the production location chosen. The cheapest production locations are identified to the south and south-east of Lake Turkana. We show that ammonia produced in Kenya can be cost-competitive given the current energy crisis and that Kenya could export hydrogen to Rotterdam with costs of e7/kgH2 undercutting current market prices regardless of the carrier medium. With expected techno-economic improvements hydrogen production costs across Kenya could drop to e1.8–3.0/kgH2 by 2030.
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