Spain
Solid Oxide Electrolyzers Process Integration: A Comprehensive Review
Aug 2025
Publication
Solid oxide electrolysis (SOEL) has emerged as a promising technology for efficient hydrogen production. Its main advantages lie in the high operating temperatures which enhance thermodynamic efficiency and in the ability to supply part of the required energy in the form of heat. Nevertheless improving the long-term durability of stack materials remains a key challenge. Thermal energy can be supplied by dedicated integration with different industrial processes where the main challenge lies in the elevated stack operating temperature (700–900 ◦C). This review provides a comprehensive analysis of the integration of solid oxide electrolysis cells (SOECs) into different industrial applications. Main processes cover methanol production methane production Power-to-Hydrogen systems or the use of reversible solid oxide electrolysis cell (rSOEC) stacks that can operate in both electrolysis and fuel cell mode. The potential of co-electrolysis to increase process flexibility and broaden application areas is also analyzed. The aim is to provide a comprehensive analysis of the integration strategies identify the main technical and economic challenges and highlight recent developments and future trends in the field. A detailed comparison assessment of the different processes is being discussed in terms of electrical and thermal efficiencies and operating parameters as well as Key Performance Indicators (KPIs) for each process. Technical-economic challenges that are currently a barrier to their implementation in industry are also analyzed.
Green Hydrogen Production—Fidelity in Simulation Models for Technical–Economic Analysis
Nov 2024
Publication
Green hydrogen production is a sustainable energy solution with great potential offering advantages such as adaptability storage capacity and ease of transport. However there are challenges such as high energy consumption production costs demand and regulation which hinder its largescale adoption. This study explores the role of simulation models in optimizing the technical and economic aspects of green hydrogen production. The proposed system which integrates photovoltaic and energy storage technologies significantly reduces the grid dependency of the electrolyzer achieving an energy self-consumption of 64 kWh per kilogram of hydrogen produced. By replacing the high-fidelity model of the electrolyzer with a reduced-order model it is possible to minimize the computational effort and simulation times for different step configurations. These findings offer relevant information to improve the economic viability and energy efficiency in green hydrogen production. This facilitates decision-making at a local level by implementing strategies to achieve a sustainable energy transition.
Green Hydrogen Production by Brewery Spent Grain Valorization Through Gasification and Membrane Seperation Towards Fuel-cell Grade Purity
May 2025
Publication
This study focuses on the potential valorization of brewers’ spent grain (BSG) through gasification for ultra-pure green hydrogen production via membrane separation. First a fundamental physicochemical characterization of BSG samples from two different Spanish brewing industries was conducted revealing high energy content and good reproducibility of elemental composition thus providing great potential for hydrogen generation in the context of circular economy for the brewery industry. The syngas composition reached by BSG gasification has been predicted and main operating conditions optimized to maximize the hydrogen yield (25–75 vol% air-steam mixture ratio GR = 0.75 T = 800 ◦C and P = 5 bar). For gas purification two Pd-membranes were fabricated by ELP-PP onto tubular PSS supports with high reproducibility (Pd-thickness in the range 8.22–8.75 μm) exhibiting an almost complete H2-selectivity good fitting to Sieverts’ law and hydrogen permeate fluxes ranging from 175 to 550 mol m− 2 h− 1 under ideal gas feed composition conditions. The mechanical resistance of membranes was maintained at pressure driving forces up to 10 bar thus highlighting their potential for commercialization and industrial application. Furthermore long-term stability tests up to 75 h indicated promising membrane performance for continuous operation offering valuable insights for stakeholders in the brewery industry to enhance economic growth and environmental sustainability through green hydrogen production from BSG.
On the Identification of Regulatory Gaps for Hydrogen as Maritime Fuel
Feb 2025
Publication
C. Georgopoulou,
C. Di Maria,
G. Di Ilio,
Viviana Cigolotti,
Mariagiovanna Minutillo,
Mosè Rossi,
B.P. Sullivan,
A. Bionda,
Markus Rautanen,
R. Ponzini,
F. Salvadore,
M. Alvarez-Cardozo,
P. Douska,
L. Koukoulopoulos,
G. Psaraftis,
G. Dimopoulos,
T. Wannemacher,
N. Baumann,
K. Mahosl,
M. Tome,
O. Noguero Torres,
F. Oikonomou,
A. Hamalainen,
F. Chillé,
Y. Papagiannopoulos and
N. Sakellaridis
The decarbonization of the maritime sector represents a priority in the energy policy agendas of the majority of Countries worldwide and the International Maritime Organization (IMO) has recently revised its strategy aiming for an ambitious zero-emissions scenario by 2050. In these regards there is a broad consensus on hydrogen as one of the most promising clean energy vectors for maritime transport and a key towards that goal. However to date an international regulatory framework for the use of hydrogen on-board of ships is absent this posing a severe limitation to the adoption of hydrogen technologies in this sector. To cope with this issue this paper presents a preliminary gap assessment analysis for the International Code of Safety for Ship Using Gases or other Low-flashpoint Fuels (IGF Code) with relation to hydrogen as a fuel. The analysis is structured according to the IGF Code chapters and a bottom-up approach is followed to review the code content and assess its relevance to hydrogen. The risks related to hydrogen are accounted for in assessing the gaps and providing a first level set of recommendations for IGF Code updates. By this means this work settles the basis for further research over the identified gaps towards the identification of a final set of recommendations for the IGF Code update.
Environmental, Economic, and Social Impacts of Methane Cracking for Hydrogen Production: A Comprehensive Review
Jul 2025
Publication
Methane cracking (MC) is emerging as a low-carbon hydrogen production technology. This review conducts a comprehensive bibliometric analysis of 46 studies examining the sustainability of MC process. The review employs Life Cycle Assessment (LCA) Life Cycle Cost (LCC) Techno-Economic Analysis (TEA) and Social Life Cycle Assessment (SLCA) methodologies. The findings reveal that LCOH for MC technologies ranges from 0.9 to 6.6 $/kg H2 at the same time GHG emissions span 0.8–14.5 kg CO2eq/kg H2 depending on the specific reactor configurations plant geographical locations and carbon revenues. These results indicate that MC can be competitive with steam methane reforming with carbon capture and electrolysis under certain conditions. However the review identifies significant research gaps including limited comprehensive LCA studies a lack of social impact assessments insufficient environmental impact analysis of molten media catalysts and particulate matter formation in MC processes as well as insufficient analysis of the potential of biomethane cracking.
Energy Valorization Strategies in Rural Renewable Energy Communities: A Path to Social Revitalization and Sustainable Development
May 2025
Publication
Energy communities led by local citizens are vital for achieving the European energy transition goals. This study examines the design of a regional energy community in a rural area of Spain aiming to address the pressing issue of rural depopulation. Seven villages were selected based on criteria such as size energy demand population and proximity to infrastructure. Three energy valorization scenarios generating eight subscenarios were analyzed: (1) self-consumption including direct sale (1A) net billing (1B) and selling to other consumers (1C); (2) battery storage including storing for self-consumption (2A) battery-to-grid (2B) and electric vehicle recharging points (2C); and (3) advanced options such as hydrogen refueling stations (3A) and hydrogen-based fertilizer production (3B). The findings underscore that designing rural energy communities with a focus on social impact—especially in relation to depopulation—requires an innovative approach to both their design and operation. Although none of the scenarios alone can fully reverse depopulation trends or drive systemic change they can significantly mitigate the issue if social impact is embedded as a core principle. For rural energy communities to effectively tackle depopulation strategies such as acting as an energy retailer or aggregating individual villages into a single unified energy community structure are crucial. These approaches align with the primary objective of revitalizing rural communities through the energy transition.
Hydrogen Production through the Integration of Biomass Gasification and Residual Steelmaking Streams
Sep 2025
Publication
As energy systems transition towards greater sustainability green hydrogen is emerging as a clean and flexible solution. This study evaluates the potential of using biomass and residual streams from steelmaking processes as feedstocks for hydrogen production integrating renewable resources and waste utilization to enable sustainable hydrogen generation while supporting industrial decarbonization efforts. The simulated plant includes biomass gasification and syngas upgrading through steam reforming and water-gas shift (WGS) reactors. The results demonstrate the viability of the integrated plant and identify optimal operating conditions for different scenarios: feeding solely biomass or incorporating gases from coke ovens blast furnaces and electric arc furnaces. A syngas upgrading configuration based on a single steam reforming reactor and two WGS reactors operating at different temperatures proves to be the most versatile option for effectively integrating these highly dissimilar feedstocks. Since the process involves stages operating at markedly different temperatures energy integration is feasible contributing to improved overall energy efficiency.
Green Hydrogen Integration in Aluminium Recycling: Techno-economic Analysis Towards Sustainability Transition in the Expanding Aluminium Market
Feb 2024
Publication
The use of aluminum-based products is widespread and growing particularly in industries such as automotive food packaging and construction. Obtaining aluminum is expensive and energy-intensive making the recycling of existing products essential for economic and environmental viability. This work explores the potential of using green hydrogen as a replacement for natural gas in the smelting and refining furnaces in aluminum recycling facilities. The adoption of green hydrogen has the potential to curtail approximately 4.54 Ktons/year of CO2 emissions rendering it a sustainable and economically advantageous solution. The work evaluates the economic viability of a case study through assessing the Net Present Value (NPV) and the Internal Rate of Return (IRR). Furthermore it is employed single- and multi-parameter sensitivity analyses to obtain insight on the most relevant conditions to achieve economic viability. Results demonstrate that integrating on-site green hydrogen generation yields a favorable NPV of €57370 an IRR of 9.83% and a 19.63-year payback period. The primary factors influencing NPV are the initial electricity consumption stack and the H2 price.
Towards Suitable Practices for the Integration of Social Life Cycle Assessment into the Ecodesign Framework of Hydrogen-related Products
Feb 2024
Publication
The hydrogen sector is envisaged as one of the key enablers of the energy transition that the European Union is facing to accomplish its decarbonization targets. However regarding the technologies that enable the deployment of a hydrogen economy a growing concern exists about potential burden-shifting across sustainability dimensions. In this sense social life cycle assessment arises as a promising methodology to evaluate the social implications of hydrogen technologies along their supply chains. In the context of the European projects eGHOST and SH2E this study seeks to advance on key methodological aspects of social life cycle assessment when it comes to guiding the ecodesign of two relevant hydrogen-related products: a 5 kW solid oxide electrolysis cell stack for hydrogen production and a 48 kW proton-exchange membrane fuel cell stack for mobility applications. Based on the social life cycle assessment results for both case studies under alternative approaches the definition of a product-specific supply chain making use of appropriate cut-off criteria was found to be the preferable choice when addressing system boundaries definition. Moreover performing calculations according to the activity variable approach was found to provide valuable results in terms of social hotspots identification to support subsequent decision-making processes on ecodesign while the direct calculation approach is foreseen as a complement to ease the interpretation of social scores. It is concluded that advancements in the formalization of such suitable practices could foster the integration of social metrics into the sustainable-by-design framework of hydrogen-related products.
Hydrogen Production Technologies: From Fossil Fuels toward Renewable Sources. A Mini Review
Oct 2021
Publication
The global economic growth the increase in thepopulation and advances in technology lead to an increment in theglobal primary energy demand. Considering that most of thisenergy is currently supplied by fossil fuels a considerable amountof greenhouse gases are emitted contributing to climate changewhich is the reason why the next European Union bindingagreement is focused on reducing carbon emissions usinghydrogen. This study reviews different technologies for hydrogenproduction using renewable and non-renewable resources.Furthermore a comparative analysis is performed on renewable-based technologies to evaluate which technologies are economically and energetically more promising. The results show howbiomass-based technologies allow for a similar hydrogen yield compared to those obtained with water-based technologies but withhigher energy efficiencies and lower operational costs. More specifically biomass gasification and steam reforming obtained a properbalance between the studied parameters with gasification being the technique that allows for higher hydrogen yields while steamreforming is more energy-efficient. Nevertheless the application of hydrogen as the energy vector of the future requires both the useof renewable feedstocks with a sustainable energy source. This combination would potentially produce green hydrogen whilereducing carbon dioxide emissions limiting global climate change and thus achieving the so-called hydrogen economy.
A Correlation for Turbulent Combustion Speed Accounting for Instabilities and Expansion Speed in a Hydrogen-natural Gas Spark Ignition Engine
Oct 2020
Publication
An analysis of the turbulent premixed combustion speed in an internal combustion engine using natural gas hydrogen and intermediate mixtures as fuels is carried out with different air-fuel ratios and engine speeds. The combustion speed has been calculated by means of a two-zone diagnosis thermodynamic model combined with a geometric model using a spherical flame front hypothesis. 48 operating conditions have been analyzed. At each test point the pressure record of 200 cycles has been processed to calculate the cycle averaged turbulent combustion speed for each flame front radius. An expression of turbulent combustion speed has been established as a function of two parameters: the ratio between turbulence intensity and laminar combustion speed and the second parameter the ratio between the integral spatial scale and the thickness of the laminar flame front increased by instabilities. The conclusion of this initial study is that the position of the flame front has a great influence on the expression to calculate the combustion speed. A unified correlation for all positions of the flame front has been obtained by adding one correction term based on the expansion speed as a turbulence source. This unified correlation is thus valid for all experimental conditions of fuel types air–fuel ratios engine speeds and flame front positions. The correlation can be used in quasi-dimensional predictive models to determine the heat released in an ICE.
Hydrogen Production by Wastewater Alkaline Electro-Oxidation
Aug 2024
Publication
The current work presents the electro-oxidation of olive mill and biodiesel wastewaters in an alkaline medium with the aim of hydrogen production and simultaneous reduction in the organic pollution content. The process is performed at laboratory scale in an own-design single cavity electrolyzer with graphite electrodes and no membrane. The system and the procedures to generate hydrogen under ambient conditions are described. The gas flow generated is analyzed through gas chromatography. The wastewater balance in the liquid electrolyte shows a reduction in the chemical oxygen demand (COD) pointing to a decrease in the organic content. The experimental results confirm the production of hydrogen with different purity levels and the simultaneous reduction in organic contaminants. This wastewater treatment appears as a feasible process to obtain hydrogen at ambient conditions powered with renewable energy sources resulting in a more competitive hydrogen cost.
Influence of Catalytic Support on Hydrogen Production from Glycerol Steam Reforming
Oct 2025
Publication
The use of hydrogen as an energy carrier represents a promising alternative for mitigating climate change. However its practical application requires achieving a high degree of purity throughout the production process. In this study the influence of the type of catalytic support on H2 production via steam glycerol reforming was evaluated with the objective of obtaining syngas with the highest possible H2 concentration. Three types of support were analyzed: two natural materials (zeolite and dolomite) and one metal oxide alumina. Alumina and dolomite were coated with Ni at different loadings while zeolite was only evaluated without Ni. Reforming experiments were carried out at a constant temperature of 850 ◦C with continuous monitoring of H2 CO2 CO and CH4 concentrations. The results showed that zeolite yielded the lowest H2 concentration (51%) mainly due to amorphization at high temperatures and the limited effectiveness of physical adsorption processes. In contrast alumina and dolomite achieved H2 purities of around 70% which increased with Ni loading. The improvement was particularly significant in dolomite owing to its higher porosity and the recarbonation processes of CaO enabling H2 purities of up to 90%.
Macroeconomic and Environmental Impacts of Two Decarbonization Options for the Dutch Steel Industry: Green Relocation Versus Green Hydrogen Imports
Jun 2025
Publication
Decarbonizing the steel industry will require a shift towards renewable energy. However costs and emissions associated with the long-distance transport of renewable energy carriers may incentivize the relocation of steel production closer to renewable energy sources. This “green relocation” would affect regional economic structures and global trade patterns. Nevertheless the macroeconomic and environmental impacts of alternative industry location options remain underexplored. This study compares the impacts on value-added prices and emissions under two options for decarbonizing the Dutch steel industry: importing green hydrogen from Brazil to produce green steel in the Netherlands versus relocating production to Brazil and transporting green steel to the Netherlands. Impacts are analyzed by combining a price and a quantity model within an environmentally extended multiregional input-output (EE-MRIO) framework. Results suggest that the relocation option brings the greatest synergies between climate and economic goals at the global level as it leads to lower production costs smaller price effects and greater emissions reductions. However relocation also results in stronger distributive impacts across global regions. Higher carbon prices would be insufficient to counteract relocation incentives. This calls for policymakers in industrialized countries to systematically consider the possibility of green relocation when designing decarbonization and industrial competitiveness strategies.
Impact of Plastic Composition on the Performance of the Integrated Process of Pyrolysis and Oxidative Steam Reforming for Hydrogen Production
Aug 2025
Publication
The pyrolysis and oxidative steam reforming (P-OSR) of different types of plastics (HDPE PP PET and PS) has been carried out in a two reactor system provided with a conical spouted bed reactor (CSBR) and a fluidized bed reactor (FBR). The effect plastic composition has on the oxidative steam reforming step has been analyzed using two space time values (3.1 gcatalyst min gplastic − 1 and 12.5 gcatalyst min gplastic − 1 ) at a reforming temperature of 700 ◦C S/P ratio of 3 and ER of 0.2 (optimum conditions for autothermal reforming). The different composition of the plastics leads to differences in the yields and compositions of pyrolysis products and consequently in the performance of the oxidative steam reforming step. High conversions (> 97 %) have been achieved by using a space time of 12.5 gcat min gplastic − 1 with H2 production increasing as follows: PET ≪ PS < HDPE ≤ PP. A maximum H2 production of 25.5 wt% has been obtained by using PP which is lower than that obtained in the process of pyrolysis and in line conventional steam reforming (P-SR) of the same feedstock (34.8 wt%). The lowest H2 production (10.5 wt%) has been achieved when PET was used due to the high oxygen content of this plastic. The results obtained in this study prove that P-OSR performs very well with different feedstock thereby confirming the versatility and efficiency of this process to produce a hydrogen-rich gas.
Opportunities for Emission Reduction in the Transformation of Petroleum Refining
Sep 2025
Publication
Crude oil accounts for approximately 40% of global energy consumption and the refining sector is a major contributor to greenhouse gas (GHG) emissions particularly through the production of hard-to-abate fuels such as aviation fuel and fuel oil. This study disaggregates the refinery into its key process units to identify decarbonization opportunities along the entire production chain. Units are categorized into combustion-based processes— including crude and vacuum distillation hydrogen production coking and fluid catalytic cracking—and non-combustion processes which exhibit lower emission intensities. The analysis reveals that GHG emissions can be reduced by up to 60% with currently available technologies without requiring major structural changes. Electrification residual heat recovery renewable hydrogen for desulfurization and process optimization through digital twins are identified as priority measures many of which are also economically viable in the short term. However achieving full decarbonization and alignment with net-zero targets will require the deployment of carbon capture technologies. These results highlight the significant potential for emission reduction in refineries and reinforce their strategic role in enabling the transition toward low-carbon fuels.
Thermochemical Aspects of Substituting Natural Gas by Hydrogen in Blister Copper Deoxidation
Aug 2025
Publication
This study employs computational thermodynamics to evaluate the feasibility of replacing methane with hydrogen as both burner fuel and reductant during blister copper deoxidation aiming to enhance deoxidation efficiency and reduce CO2 emissions. A comprehensive thermodynamic model was developed using FactSage 8.3 for dilute Cu–O and Cu–S–O melts containing trace impurities (Fe Ni Pb Zn) incorporating methane thermal decomposition and temperature-dependent variations in liquid copper density with oxygen and sulfur content. Model parameters were optimized against over 105 deoxidation simulation data points yielding temperature- and composition-dependent expressions for rapid density estimates. Benchmarking against existing literature models demonstrated improved accuracy. Key findings include: (1) increasing impurities contents from electronics waste recycling (Fe Ni Pb Zn) reduces oxygen activity deteriorating the deoxidation efficiency; (2) under global equilibrium methane provides greater reducing power per mole than hydrogen due to full thermal cracking but real-world mass transfer limitations render hydrogen more consistently effective up to 1200 C with methane gas needing to achieve at least 472 C to match hydrogen’s performance; (3) adiabatic flame equilibrium studies show that O2/H2 ratios of 0.5 to 1 yield liquid copper oxygen activities comparable to industrial O2/CH4 ratios of 2 to 3 supporting the direct substitution of methane with hydrogen in oxy-fuel anode furnace burners without compromising metal quality.
Energy Storage in the Energy Transition and Blue Economy: Challenges, Innovations, Future Perspectives, and Educational Pathways
Sep 2025
Publication
Transitioning to renewable energy is vital to achieving decarbonization at the global level but energy storage is still a major challenge. This review discusses the role of energy storage in the energy transition and the blue economy focusing on technological development challenges and directions. Effective storage is vital for balancing intermittent renewable energy sources like wind solar and marine energy with the power grid. The development of battery technologies hydrogen storage pumped hydro storage and emerging technologies like sodium-ion and metal-air batteries is discussed for their potential for large-scale deployment. Shortages in critical raw materials environmental impact energy loss and costs are some of the challenges to large-scale deployment. The blue economy promises opportunities for offshore energy storage notably through ocean thermal energy conversion (OTEC) and compressed air energy storage (CAES). Moreover the capacity of datadriven optimization and artificial intelligence to enhance storage efficiency is discussed. Policy interventions and economic incentives are necessary to spur the development and deployment of sustainable energy storage technology. Education and workforce training are also important in cultivating future researchers engineers and policymakers with the ability to drive energy innovation. Merging sustainability training with an interdisciplinary approach can potentially establish an efficient workforce that is capable of addressing energy issues. Future work needs to focus on higher energy density efficiency recyclability and cost-effectiveness of the storage technologies without sacrificing their environmental sustainability. The study underlines the need for converging technological economic and educational approaches to enable a sustainable and resilient energy future.
Retrofitted Production of Bio-hydrogen. Large-scale Biowaste Valorization via Solar-based Gasification
Aug 2025
Publication
Hydrogen production from gasification of biowaste generates large volumes of CO2 due to endothermic biowaste decomposition. Alternatively the Sun can provide that energy. To evaluate the yield and performance of solarbased gasifiers at country scale a multi-scale approach is required. First the operation of a solar gasifier is analyzed by developing a two-phase model validated and scaled to industrial level. Next the performance and yield of such technology as a function of the radiation received is studied taking Spain as a case study. The results were promising obtaining a syngas rich in H2. However tar and char were not reduced due to insufficient temperature. Scale-up studies revealed energy losses to the environment in the industrial-scale gasifier which suggested the use of segmented heating. In turn diameters no larger than 0.8 m and biomass feeding rates below 0.85 kg/s highlight the deployment of a modular design due to particle size limitations. Finally the large-scale waste valorization showed that the gasifier can only operate in Spain in the summer months. It can run over 180 h/month and more than 250 days/year only in C´ adiz and Santa Cruz de Tenerife which also showed the highest yearly production capacities.
Techno-Economic Analysis of Marine Hybrid Clusters for Use in Chile and Mexico
Oct 2025
Publication
This study assesses the feasibility and profitability of marine hybrid clusters combining wave energy converters (WECs) and offshore wind turbines (OWTs) to power households and marine aquaculture. Researchers analyzed two coastal sites: La Serena Chile with high and consistent wave energy resources and Ensenada Mexico with moderate and more variable wave power. Two WEC technologies Wave Dragon (WD) and Pelamis (PEL) were evaluated alongside lithium-ion battery storage and green hydrogen production for surplus energy storage. Results show that La Serena’s high wave power (26.05 kW/m) requires less hybridization than Ensenada’s (13.88 kW/m). The WD device in La Serena achieved the highest energy production while PEL arrays in Ensenada were more effective. The PEL-OWT cluster proved the most cost-effective in Ensenada whereas the WD-OWT performed better in La Serena. Supplying electricity for seaweed aquaculture particularly in La Serena proves more profitable than for households. Ensenada’s clusters generate more surplus electricity suitable for the electricity market or hydrogen conversion. This study emphasizes the importance of tailoring emerging WEC systems to local conditions optimizing hybridization strategies and integrating consolidated industries such as aquaculture to enhance both economic and environmental benefits.
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