India

Environmental emissions global warming and energy-related concerns have accelerated the advancements in conventional vehicles that primarily use internal combustion engines. Among the existing technologies hydrogen fuel cell electric vehicles and fuel cell hybrid electric vehicles may have minimal contributions to greenhouse gas emissions and thus are the prime choices for environmental concerns. However energy management in fuel cell electric vehicles and fuel cell hybrid electric vehicles is a major challenge. Appropriate control strategies should be used for effective energy management in these vehicles. On the other hand there has been significant progress in artificial intelligence machine learning and designing data-driven intelligent controllers. These techniques have found much attention within the community and state-of-the-art energy management technologies have been developed based on them. This manuscript reviews the application of machine learning and intelligent controllers for prediction control energy management and vehicle to everything (V2X) in hydrogen fuel cell vehicles. The effectiveness of data-driven control and optimization systems are investigated to evolve classify and compare and future trends and directions for sustainability are discussed.

Hydrogen produced from renewable energy sources is clean and sustainable. Biomass gasification has a significant role in the context of hydrogen generation from biomass. Assessment of the performance of biomass gasification process regarding the product gas yield and composition can be performed using mathematical models. Among the different mathematical models thermodynamic equilibrium models are simple and useful tools for the first estimate and preliminary comparison and assessment of gasification process. A stoichiometric thermodynamic equilibrium model is developed here and its performance is validated for steam gasification and air-steam gasification. The model is then used to assess the feasibility of different biomass feedstock for gasification based on hydrogen yield and lower heating value.

Consumption of fossil fuels especially in transport and energy-dependent sectors has led to large greenhouse gas production. Hydrogen is an exciting energy source that can serve our energy purposes and decrease toxic waste production. Decomposition of methane yields hydrogen devoid of COx components thereby aiding as an eco-friendly approach towards large-scale hydrogen production. This review article is focused on hydrogen production through thermocatalytic methane decomposition (TMD) for hydrogen production. The thermodynamics of this approach has been highlighted. Various methods of hydrogen production from fossil fuels and renewable resources were discussed. Methods including steam methane reforming partial oxidation of methane auto thermal reforming direct biomass gasification thermal water splitting methane pyrolysis aqueous reforming and coal gasification have been reported in this article. A detailed overview of the different types of catalysts available the reasons behind their deactivation and their possible regeneration methods were discussed. Finally we presented the challenges and future perspectives for hydrogen production via TMD. This review concluded that among all catalysts nickel ruthenium and platinum-based catalysts show the highest activity and catalytic efficiency and gave carbon-free hydrogen products during the TMD process. However their rapid deactivation at high temperatures still needs the attention of the scientific community.

Hydrogen is a clean fuel and an abundant renewable energy resource. In recent years huge scientific attention has been invested to invent suitable materials for its safe storage. Conducting polymers has been extensively investigated as a potential hydrogen storage and fuel cell membrane due to the low cost ease of synthesis and processability to achieve the desired morphological and microstructural architecture ease of doping and composite formation chemical stability and functional properties. The review presents the recent progress in the direction of material selection modification to achieve appropriate morphology and adsorbent properties chemical and thermal stabilities. Polyaniline is the most explored material for hydrogen storage. Polypyrrole and polythiophene has also been explored to some extent. Activated carbons derived from conducting polymers have shown the highest specific surface area and significant storage. This review also covers recent advances in the field of proton conducting solid polymer electrolyte membranes in fuel cells application. This review focuses on the basic structure synthesis and working mechanisms of the polymer materials and critically discusses their relative merits.

Hydrogen can be recognized as the most plausible fuel for promoting a green environment. Worldwide developed and developing countries have established their hydrogen research investment and policy frameworks. This analysis of 610 peer-reviewed journal articles from the last 50 years provides quantitative and impartial insight into the hydrogen economy. By 2030 academics and business professionals believe that hydrogen will complement other renewable energy (RE) sources in the energy revolution. This study conducts an integrative review by employing software such as Bibliometrix R-tool and VOSviewer on socio-economic consequences of hydrogen energy literature derived from the Scopus database. We observed that most research focuses on multidisciplinary concerns such as generation storage transportation application feasibility and policy development. We also present the conceptual framework derived from in-depth literature analysis as well as the interlinkage of concepts themes and aggregate dimensions to highlight research hotspots and emerging patterns. In the future factors such as green hydrogen generation hydrogen permeation and leakage management efficient storage risk assessment studies blending and techno-economic feasibility shall play a critical role in the socio-economic aspects of hydrogen energy research.  

The shipping industry is a major enabler of globalization trade commerce and human welfare. But it is still heavily served by fossil fuels which make it one of the foremost greenhouse gas emitting sectors operational today. It is also one of the hardest to abate segments of the transport industry. As part of the economy-wide climate change mitigation and adaptation efforts it is necessary to consider a low carbon energy transition for this segment as well. This study examines the potential role of nuclear power and cogeneration towards greening this sector and identifies the associated techno-commercial and policy challenges associated with the transition. Quantitative estimates of the economics and investments associated with some of the possible routes are also presented. Alternatives such as nuclear-powered ships along commercial maritime trading routes ships working on nuclear derived green hydrogen ammonia or other sustainable power fuels will enable not only decarbonization of the shipping industry but also allow further diversification of the nuclear industry through non-electric applications of nuclear power and new sector coupling opportunities. In the run-up to the UNFCCC-COP28 meeting in 2023 in UAE nuclear equipped nations heavily engaged in and dependent on maritime trade and commerce should definitely consider nuclear driven decarbonization of shipping and some of the options presented here as part of their climate action strategies.

Carbon-based nanocomposites have developed as the most promising and emerging materials in nanoscience and technology during the last several years. They are microscopic materials that range in size from 1 to 100 nanometers. They may be distinguished from bulk materials by their size shape increased surface-to-volume ratio and unique physical and chemical characteristics. Carbon nanocomposite matrixes are often created by combining more than two distinct solid phase types. The nanocomposites that were constructed exhibit unique properties such as significantly enhanced toughness mechanical strength and thermal/electrochemical conductivity. As a result of these advantages nanocomposites have been used in a variety of applications including catalysts electrochemical sensors biosensors and energy storage devices among others. This study focuses on the usage of several forms of carbon nanomaterials such as carbon aerogels carbon nanofibers graphene carbon nanotubes and fullerenes in the development of hydrogen fuel cells. These fuel cells have been successfully employed in numerous commercial sectors in recent years notably in the car industry due to their cost-effectiveness eco-friendliness and long-cyclic durability. Further; we discuss the principles reaction mechanisms and cyclic stability of the fuel cells and also new strategies and future challenges related to the development of viable fuel cells.

Blending hydrogen into natural gas pipelines is a recent alternative adopted for hydrogen transportation as a mixture with natural gas. In this paper hydrogen embrittlement of steel pipelines originally designed for natural gas transportation is investigated. Solubility permeation and diffusion phenomena of hydrogen molecules into the crystalline lattice structure of the pipeline material are followed up based on transient evolution of internal pressure applied on the pipeline wall. The transient regime is created through changes of gas demand depending on daily consumptions. As a result the pressure may reach excessive values that lead to the acceleration of hydrogen solubility and its diffusion through the pipeline wall. Furthermore permeation is an important parameter to determine the diffusion amount of hydrogen inside the pipeline wall resulting in the embrittlement of the material. The numerical obtained results have shown that using pipelines designed for natural gas conduction to transport hydrogen is a risky choice. Actually added to overpressure and great fluctuations during transients that may cause fatigue and damage the structure also the latter pressure evolution is likely to induce the diffusion phenomena of hydrogen molecules into the lattice of the structure leading to brittle the pipe material. The numerical simulation reposes on solving partial differential equations describing transient gas flow in pipelines coupled with the diffusion equation for mass transfer. The model is built using the finite elements based software COMSOL Multiphysics considering different cases of pipe material; API X52 (base metal and nutrided) and API X80 steels. Obtained results allowed tracking the evolution with time of hydrogen concentration through the pipeline internal wall based on the pressure variation due to transient gas flow. Such observation permits to estimate the amount of hydrogen diffused in the metal to avoid leakage of this flammable gas. Thus precautions may be taken to prevent explosive risks due to hydrogen embrittlement of steel pipelines among other effects that can lead to alter safe conditions of gas conduction.

Fully decarbonizing global industry is essential to achieving climate stabilization and reaching net zero greenhouse gas emissions by 2050–2070 is necessary to limit global warming to 2 °C. This paper assembles and evaluates technical and policy interventions both on the supply side and on the demand side. It identifies measures that employed together can achieve net zero industrial emissions in the required timeframe. Key supply-side technologies include energy efficiency (especially at the system level) carbon capture electrification and zero-carbon hydrogen as a heat source and chemical feedstock. There are also promising technologies specific to each of the three top-emitting industries: cement iron & steel and chemicals & plastics. These include cement admixtures and alternative chemistries several technological routes for zero-carbon steelmaking and novel chemical catalysts and separation technologies. Crucial demand-side approaches include material-efficient design reductions in material waste substituting low-carbon for high-carbon materials and circular economy interventions (such as improving product longevity reusability ease of refurbishment and recyclability). Strategic well-designed policy can accelerate innovation and provide incentives for technology deployment. High-value policies include carbon pricing with border adjustments or other price signals; robust government support for research development and deployment; and energy efficiency or emissions standards. These core policies should be supported by labeling and government procurement of low-carbon products data collection and disclosure requirements and recycling incentives. In implementing these policies care must be taken to ensure a just transition for displaced workers and affected communities. Similarly decarbonization must complement the human and economic development of low- and middle-income countries.

Hydrogen is widely produced and used for our day-to-day needs. It has also the potential to be used as fuel for industry or can be used as an energy carrier for stationary power. Hydrogen can be produced by different processes like from fossil fuels (Steam methane reforming coal gasification cracking of natural gas); renewable resources (electrolysis wind etc.); nuclear energy (thermochemical water splitting). In this paper few processes have been discussed briefly. Cracking of methane has been given special emphasis in this review for production of hydrogen. There are mainly two types of cracking non-catalytic and catalytic. Catalytic cracking of methane is governed mainly by finding a suitable catalyst; its generation deactivation activation and filament formation for the adsorption of carbon particles (deposited on metal surface); study of metallic support which helps in finding active sites of the catalyst for the reaction to proceed easily. Non-catalytic cracking of methane is mainly based on thermal cracking. Moreover several thermal cracking processes with their reactor configurations have been discussed.