Italy

In this paper we propose an alternative strategy to produce green hydrogen in a more sustainable way than standard water electrolysis where a substantial amount of the electrical energy is wasted in the oxygen evolution quite often simply released in the atmosphere. The HER (hydrogen evolution reaction) is effectively coupled with the oxidation of guaiacol at the anode leading to the simultaneous production of H2 and valuable guaiacol oligomers. Significative points i) a substantial decrease of the potential difference for the HER 0.85 V with guaiacol ii) HER is accompanied by the production of industrially appealing and sustainable guaiacol based oligomers iii) guaiacol oxidation runs efficiently on carbon-based surfaces like graphite and glassy carbon which are cheap and not-strategic materials. Then the electrochemical oxidation mechanism of guaiacol is studied in detail with in-situ EPR measurements and post-electrolysis product characterization: LC-DAD LC-MS and NMR. Experimental results and theoretical calculations suggest that guaiacol polymerization follows a Kane-Maguire mechanism.

A comprehensive literature review highlights how the nature of active metals support materials promoters and synthesis methods influences catalytic performance with particular attention to ruthenium-based catalysts as the current benchmark. Kinetic models are presented to describe the reaction pathway and predict catalyst behavior. Various reactor configurations including fixed-bed membrane catalytic membrane perovskitebased and microreactors are evaluated in terms of their suitability for ammonia decomposition. While ruthenium remains the benchmark catalyst alternative transition metals such as iron nickel and cobalt have also been investigated although they typically require higher operating temperatures (≥500 °C) to achieve comparable conversion levels. At the industrial scale catalyst development must balance performance with cost. Inexpensive and scalable materials (e.g. MgO Al2O3 CaO K Na) and simple preparation techniques (e.g. wet impregnation incipient wetness) may offer lower performance than more advanced systems but are often favored for practical implementation. From a reactor engineering standpoint membrane reactors emerge as the most promising technology for combining catalytic reaction and product separation in a single unit operation. This review provides a critical overview of current advances in ammonia decomposition for hydrogen production offering insights into both catalytic materials and reactor design strategies for sustainable energy applications.

As the need to reduce Greenhouse Gas (GHG) emissions and dependence on fossil fuels grows new vehicle concepts are emerging as sustainable solutions for urban mobility. Beyond evaluating tailpipe emissions indirect emissions associated with energy and hydrogen production as vehicle manufacturing must be accounted offering a holistic Lifecycle Assessment (LCA) perspective. This study compares Battery Electric Vehicles (BEVs) Fuel Cell Vehicles (FCVs) Hydrogen Internal Combustion Engine Vehicles (H2ICEVs) and hybrid H2ICEVs analyzing energy efficiency and GHG emissions in urban environment across the European Union. Future scenarios (2030 2050) are examined as well with evolving energy mixes and manufacturing impacts. Findings show BEVs as the most efficient configuration with the lowest GHG emissions in 2024 while FCVs become the best option in future scenarios due to greener hydrogen production and improved manufacturing. This study emphasizes the need for tailored strategies to achieve sustainable urban mobility providing insights for policymakers and stakeholders.

A tool for parametric finite element modeling and analysis of LH2 tanks for aviation is developed. Passively insulated cryogenic composite sandwich pressure vessels are investigated as they conjugate simplicity effectiveness and lightweight design for aeronautical applications. Several parametric analyses are performed with the aim of gaining both general and case-specific understanding of how particular design choices may impact the tank mechanical and thermal performance. Differently from most of previous studies multiple design choices including tank walls thicknesses constraints for airframe integration strategies as well as the presence position and integration of refuelling cutouts and anti-sloshing bulkheads are considered. The thermo-mechanical analyses are performed considering first a simple reference configuration with the aim of evaluating possible directions for performance enhancement. Results indicate how different design features affect the gravimetric and thermal efficiency of the tank without compromising structural integrity if the walls thicknesses are suitably sized. The effects of different constraints and geometric discontinuities which reflect specific fuselage integration choices must be carefully assessed as they reduce safety margins. Ultimately a vessel model including features necessary for safe operation is presented as it serves as a baseline for further optimization.

Hydrogen is commonly perceived as the key player in the transition towards a low-carbon future. Nevertheless H2 low energy density hinders its easy storage and transportation. To address this issue different alternatives (liquefied hydrogen ammonia and liquid organic hydrogen carriers) are explored as hydrogen vectors. The techno-economic assessment of H2 transport through these carriers is strongly dependent on the basis of design adopted such that it is difficult to draw general conclusions. In this respect this work is aimed at performing a sensitivity analysis on the hypotheses introduced in the layout of H2 value chains. Different scenarios are discussed depending on harbour-to-harbour distances cost of utilities and raw materials and H2 application to the industrial or mobility sector. The most cost-effective carrier is selected for each case-study: NH3 is the most advantageous for industrial sector while LH2 holds promises for mobility. Critical issues are pointed out for future large-scale applications.

Solid oxide electrolysis cells (SOEC) system has potential to offer an efficient green hydrogen production technology. However the significant cost of this technology is related to the high operating temperatures materials and thermal management including the waste heat. Recovering the waste heat can be conducted through techniques to reduce the overall energy consumption. This approach aims to improve accuracy and efficiency by recovering and reusing the heat that would otherwise be lost. In this paper thermal energy models are proposed based on waste heat recovery methodologies to utilize the heat from outlet fluids within the SOEC system. The mathematical methods for calculating thermal energy and energy transfer in SOEC systems have involved the principles of heat transfer. To address this different simplified thermal models are developed in Simulink Matlab R2025b. The obtained results for estimating proper thermal energy for heating incoming fluids and recycled heat are discussed and compared to determine the efficient and potential thermal model for improvement the waste heat recovery.

As highlighted by the recent roadmaps from the European Union and the United States water electrolysis is the most valuable high-intensity technology for producing green hydrogen. Currently two commercial low-temperature water electrolyzer technologies exist: alkaline water electrolyzer (A-WE) and proton-exchange membrane water electrolyzer (PEM-WE). However both have major drawbacks. A-WE shows low productivity and efficiency while PEM-WE uses a significant amount of critical raw materials. Lately the use of anion-exchange membrane water electrolyzers (AEM-WE) has been proposed to overcome the limitations of the current commercial systems. AEM-WE could become the cornerstone to achieve an intense safe and resilient green hydrogen production to fulfill the hydrogen targets to achieve the 2050 decarbonization goals. Here the status of AEM-WE development is discussed with a focus on the most critical aspects for research and highlighting the potential routes for overcoming the remaining issues. The Review closes with the future perspective on the AEM-WE research indicating the targets to be achieved.

The development of hydrogen refueling infrastructure plays a strategic role in enabling the decarbonization of the transport sector especially along major freight and passenger corridors such as the Trans-European Transport Network (TEN-T). Despite the growing interest in hydrogen mobility existing methodologies for the optimal location of hydrogen refueling stations (HRS) remain fragmented and often overlook operational dynamics. Following a review of the existing literature on HRS location models and approaches this study highlights key methodological gaps that hinder effective infrastructure planning. In response a two-stage framework is proposed combining a flow-based location model with a stochastic queueing approach to determine both the optimal placement of HRS and the number of dispensers required at each site. The method is applied to a real segment of the TEN-T network in Northern Italy. The results demonstrate the flexibility of the model in accommodating different hydrogen vehicle penetration scenarios and its utility as a decision-support tool for public authorities and infrastructure planners.

Direct electrification and hydrogen utilization represent two key pathways for decarbonizing the glass industry with their effectiveness subject to adequate furnace design and renewable energy availability. This study presents a techno-economic assessment for optimal solar energy integration in a representative 300 t/d oxyfuel container glass furnace with a specific energy consumption of 4.35 GJ/t. A mixed-integer linear programming formulation is developed to evaluate specific melting costs carbon emissions and renewable energy self-consumption and self-production rates across three scenarios: direct solar coupling battery storage and a hydrogen-based infrastructure. Battery storage achieves the greatest reductions in specific melting costs and emissions whereas hydrogen integration minimizes electricity export to the grid. By incorporating capital investment considerations the study quantifies the cost premiums and capacity requirements under varying decarbonization targets. A combination of 30 MW of solar plant and 9 MW of electric boosting enables the realization of around 30% carbon reduction while increasing total costs by 25%. Deeper decarbonization targets require more advanced systems with batteries emerging as a cost-effective solution. These findings offer critical insights into the economic and environmental trade-offs as well as the technical constraints associated with renewable energy adoption in the glass industry providing a foundation for strategic energy and decarbonization planning.

In this work we present the simulation of a plant for the exploitation of renewable hydrogen (e.g. from biomass gasification) with production of renewable ammonia as hydrogen vector and energy storage medium. The simulation and sizing of all unit operations were performed with Aspen Plus® as software. Vegetable waste biomass is used as raw material for hydrogen production more specifically pine sawdust.<br/>The hydrogen production process is based on a gasification reactor operating at high temperature (700–800 °C) in the presence of a gasifying agent such as air or steam. At the outlet a solid residue (ash) and a certain amount of gas which mainly contains H2 CH4 CO and some impurities (e.g. sulphur or chlorine compounds) are obtained. Subsequently this gas stream is purified and treated in a series of reactors in order to maximize the hydrogen yield. In fact after the removal of the sulphur compounds through an absorption column with MEA (to avoid poisoning of the catalytic processes) 3 reactors are arranged in series: Methane Steam Reforming (MSR) High temperature Water-Gas Shift (HT-WGS) Low temperature Water-Gas Shift (LT-WGS).<br/>In the first MSR reactor methane reacts at 1000 °C in presence of steam and a nickel-based catalyst in order to obtain mainly H2 CO and CO2. Subsequently two steps of WGS are present to convert most of the CO into H2 and CO2. Also these reactions are carried out in the presence of a catalyst and with an excess of water.<br/>All the oxygenated compounds must be carefully eliminated: the remaining traces of CO are methanated while CO2 is removed by a basic scrubbing with MEA (35 wt%) inside an absorption column. The Haber-Bosch synthesis of ammonia was carried out at 200 bar and in a temperature range between 300 and 400 °C using two catalysts: Fe (wustite) and Ru/C.<br/>As overall balance from an hourly flow rate of 1000 kg of dry biomass and 600 kg of nitrogen 550 kg of NH3 at 98.8 wt% were obtained demonstrating the proof of concept of this newly designed process for the production of hydrogen from renewable waste biomass and its transformation into a liquid hydrogen vector to be easily transported and stored.

This study evaluates and compares physical chemical and dual activation methods for preparing activated carbons from spent coffee grounds to optimize their porosity for hydrogen storage. Activation processes including both one-step and two-step chemical and physical methods were investigated incorporating a novel dual activation process that combines chemical and physical activation. The findings indicate that the two-step chemical activation yields superior results producing activated carbons with a high specific surface area of 1680 m2 /g and a micropore volume of 0.616 cm3 /g. These characteristics lead to impressive hydrogen uptake capacities of 2.65 wt% and 3.66 wt% at 77 K under pressures of 1 and 70 bar respectively. The study highlights the potential of spent coffee grounds as a cost-effective precursor for producing high-performance activated carbons.

This paper deals with proton exchange membrane (PEM) electrolyzers directly coupled with a photovoltaic source. It proposes a method to increase the energy delivered to the electrolyzer by reconfiguring the electrical connection of the arrays according to solar radiation. Unlike the design criterion proposed by the literature the suggested approach considers a source obtained by connecting arrays in parallel depending on solar radiation based on a fixed photovoltaic configuration. This method allows for the optimization of the operating point at medium or low solar radiation where the fixed configuration gives poor results. The analysis is performed on a low-power plant (400 W). It is based on a commercial photovoltaic cell whose equivalent model is retrieved from data provided by the manufacturer. An equivalent model of the PEM electrolyzer is also derived. Two comparisons are proposed: the former considers a photovoltaic source designed according to the traditional approach i.e. a fixed configuration; in the latter a DC/DC converter as interface is adopted. The role of the converter is discussed to highlight the pros and cons. The optimal set point of the converter is calculated using an analytical equation that takes into account the electrolyzer model. In the proposed study an increase of 17% 62% and 93% of the delivered energy has been obtained in three characteristic days summer spring/autumn and winter respectively compared to the fixed PV configuration. These results are also better than those achieved using the converter. Results show that the proposed direct coupling technique applied to PEM electrolyzers in low-power plants is a good trade-off between a fixed photovoltaic source configuration and the use of a DC/DC converter.

For centuries fossil fuels have been the primary energy source but their unchecked use has led to significant environmental and economic challenges that now shape the global energy landscape. The combustion of these fuels releases greenhouse gases which are critical contributors to the acceleration of climate change resulting in severe consequences for both the environment and human health. Therefore this article examines the potential of hydrogen as a sustainable alternative energy source capable of mitigating these climate impacts. It explores the properties of hydrogen with particular emphasis on its application in industrial burners and furnaces underscoring its clean combustion and high energy density in comparison to fossil fuels and also examines hydrogen production through thermochemical and electrochemical methods covering green gray blue and turquoise pathways. It discusses storage and transportation challenges highlighting methods like compression liquefaction chemical carriers (e.g. ammonia) and transport via pipelines and vehicles. Hydrogen combustion mechanisms and optimized burner and furnace designs are explored along with the environmental benefits of lower emissions contrasted with economic concerns like production and infrastructure costs. Additionally industrial and energy applications safety concerns and the challenges of large-scale adoption are addressed presenting hydrogen as a promising yet complex alternative to fossil fuels.

In the current context of increasing demand for clean transportation hydrogen usage in internal combustion engines (ICEs) represents a viable solution to abate all engine-out criteria pollutants and almost zeroing CO2 tailpipe emissions. Indeed the wider flammability limits thanks to the higher flame propagation speed and the lower minimum ignition energy compared with conventional fuels extend the stable combustion regime to leaner mixtures thus allowing high thermal efficiency keeping under control the NOX emissions. To fully exploit the potential of hydrogen as a fuel and to avoid undesired abnormal combustion processes a deep characterization of the combustion process is needed. With this aim a 6-cylinder 12.9-L heavy-duty engine was converted from a port-fuel injected compressed natural gas to a direct injected hydrogen spark ignition one. A wide experimental campaign was carried out consisting of several sweeps of relative air-fuel ratios spark advances and injection timings at different engine speeds and loads aiming to define a preliminary engine map. The effect of each calibration parameter at different engine load and speed has been analyzed through the combination of relevant combustion parameters as well as NOX emissions. The results have demonstrated the critical influence of the mixture inhomogeneity when the injection is retarded through the top dead center firing as indicated by the increase in NOX emissions and combustion variability. The analysis of the combustion timing has indicated the dependence of the optimal MFB50 on the relative air-fuel ratio. Lastly the analysis of 200 consecutive cycles for each operating condition has allowed the evaluation of the influence of the main calibration parameters on the cyclic variability thus providing further insights about the lean limit of hydrogen in ICE.

The impact of the HyResponder project on the training of responders in 10 European countries is described. An overview is presented of training activities undertaken within the project in Austria Belgium Czech Republic France Germany Italy Norway Spain Switzerland and the United Kingdom. National leads with training expertise are given and the longer-term plans in each region are mentioned. Responders from each region took part in a specially tailored “train the trainer” programme and then delivered training within their regions. A flexible approach to training within the HyResponder network has enabled fit for purpose region appropriate activities to be delivered impacting over 1250 individuals during the project and many more beyond. Teaching and learning materials in hydrogen safety for responders have been made available in 8 languages: English Czech Dutch French German Italian Norwegian Spanish. They are being used to inform training within each of the partner countries. Dedicated national working groups focused on hydrogen safety training for responders have been established in Belgium the Czech Republic Italy and Switzerland.

This study presents sector-coupled PyPSA-Earth: a novel global open-source energy system optimization model that incorporates major demand sectors and energy carriers in high spatial and temporal resolution to enable energy transition studies worldwide. The model includes a workflow that automatically downloads and processes the necessary demand supply and transmission data to co-optimize investment and operation of energy systems of countries or regions of Earth. The workflow provides the user with tools to forecast future demand scenarios and allows for custom user-defined data in several aspects. Sector-coupled PyPSA-Earth introduces novelty by offering users a comprehensive methodology to generate readily available sector-coupled data and model of any region worldwide starting from raw and open data sources. The model provides flexibility in terms of spatial and temporal detail allowing the user to tailor it to their specific needs. The capabilities of the model are demonstrated through two showcases for Egypt and Brazil. The Egypt case quantifies the relevant role of PV exceeding 35 GW and electrolysis in Suez and Damietta regions for meeting 16% of the EU hydrogen demand. Complementarily the Brazil case confirms the model’s ability in handling hydrogen planning infrastructure including repurposing of existing gas networks which results in 146 M€ lower costs than building new pipelines. The results prove the suitability of sector-coupled PyPSA-Earth to meet the needs of policymakers developers and scholars in advancing the energy transition. The authors invite the interested individuals and institutions to collaborate in the future developments of the model within PyPSA meets Earth initiative.

The coupling of offshore wind energy with hydrogen production involves complex energy flow dynamics and management challenges. This study explores the production of hydrogen through a PEM electrolyzer powered by offshore wind farms and Lithium-ion batteries. A digital twin is developed in Python with the aim of supporting the sizing and carrying out a techno-economic analysis. A controller is designed to manage energy flows on an hourly basis. Three scenarios are analyzed by fixing the electrolyzer capacity to meet a steel plant’s hydrogen demand while exploring different wind farm configurations where the electrolyzer capacity represents 40% 60% and 80% of the wind farm. The layout is optimized to account for the turbine wake. Results reveal that when the electrolyzer capacity is 80% of the wind farm a better energy balance is achieved with 87.5% of the wind production consumed by the electrolyzer. In all scenarios the energy stored is less than 5% highlighting its limitation as a storage solution in this application. LCOE and LCOH differ minimally between scenarios. Saved emissions from wind power reach 268 ktonCO2 /year while those from hydrogen production amount to 520 ktonCO2 /year underlying the importance of hydrogen in hard-to-abate sectors.

Hydrogen leakage in Proton Exchange Membrane (PEM) fuel cells poses critical safety efficiency and operational reliability risks. This study introduces an innovative infrared (IR) thermography-based methodology for detecting and quantifying hydrogen leaks towards the outside of PEM fuel cells. The proposed method leverages the catalytic properties of a membrane electrode assembly (MEA) as an active thermal tracer facilitating real-time visualisation and assessment of hydrogen leaks. Experimental tests were conducted on a single-cell PEM fuel cell equipped with intact and defective gaskets to evaluate the method’s effectiveness. Results indicate that the active tracer generates distinct thermal signatures proportional to the leakage rate overcoming the limitations of hydrogen’s low IR emissivity. Comparative analysis with passive tracers and baseline configurations highlights the active tracer-based approach’s superior positional accuracy and sensitivity. Additionally the method aligns detected thermal anomalies with defect locations validated through pressure distribution maps. This novel non-invasive technique offers precise reliable and scalable solutions for hydrogen leak detection making it suitable for dynamic operational environments and industrial applications. The findings significantly advance hydrogen’s safety diagnostics supporting the broader adoption of hydrogen-based energy systems.

The ecological transition in the transport sector is a major challenge to tackle environmental pollution and European legislation will mandate zero-emission new cars from 2035. To reduce the impact of petrol and diesel vehicles much emphasis is being placed on the potential use of synthetic fuels including electrofuels (e-fuels). This research aims to examine a levelised cost (LCO) analysis of e-fuel production where the energy source is renewable. The energy used in the process is expected to come from a photovoltaic plant and the other steps required to produce e-fuel: direct air capture electrolysis and Fischer-Tropsch process. The results showed that the LCOe-fuel in the baseline scenario is around 3.1 €/l and this value is mainly influenced by the energy production component followed by the hydrogen one. Sensitivity scenario and risk analyses are also conducted to evaluate alternative scenarios and it emerges that in 84% of the cases LCOe-fuel ranges between 2.8 €/l and 3.4 €/l. The findings show that the current cost is not competitive with fossil fuels yet the development of e-fuels supports environmental protection. The concept of pragmatic sustainability incentive policies technology development industrial symbiosis economies of scale and learning economies can reduce this cost by supporting the decarbonisation of the transport sector.

This paper deals with the optimal scheduling of the resources of a renewable energy community whose coordination is aimed at providing flexibility services to the electrical distribution network. The available resources are renewable generation units battery energy storage systems dispatchable loads and power-to-hydrogen systems. The main purposes behind the proposed strategy are enhancement of self-consumption and hydrogen production from local resources and the maximization of the economic benefits derived from both the selling of hydrogen and the subsidies given to the community for the shared energy. The proposed approach is formulated as an economic problem accounting for the perspectives of both community members and the distribution system operator. In more detail a mixed-integer constrained non-linear optimization problem is formulated. Technical constraints related to the resources and the power flows in the electrical grid are considered. Numerical applications allow for verifying the effectiveness of the procedure. The results show that it is possible to increase self-consumption and the production of green hydrogen while providing flexibility services through the exploitation of community resources in terms of active and reactive power support. More specifically the application of the proposed strategy to different case studies showed that daily revenues of up to EUR 1000 for each MW of renewable energy generation installed can be obtained. This value includes the benefit obtained thanks to the provision of flexibility services which contribute about 58% of the total.

This article analyzes a power-to-hydrogen system designed to provide high-temperature heat to hard-to-abate industries. We leverage on a geospatial analysis for wind and solar availability and different industrial demand profiles with the aim to identify the ideal sizing of plant components and the resulting Levelized Cost of Hydrogen (LCOH). We assess the carbon intensity of the produced hydrogen especially when grid electricity is utilized. A methodology is developed to size and optimize the PV and wind energy capacity the electrolyzer unit and hybrid storage by combining compressed hydrogen storage with lithium-ion batteries. The hydrogen demand profile is generated synthetically thus allowing different industrial consumption profiles to be investigated. The LCOH in a baseline scenario ranges from 3.5 to 8.9 €/kg with the lowest values in wind-rich climates. Solar PV only plays a role in locations with high PV full-load hours. It was found that optimal hydrogen storage can cover the users’ demand for 2–3 days. Most of the considered scenarios comply with the emission intensity thresholds set by the EU. A sensitivity analysis reveals that a lower variability of the demand profile is associated with cost savings. An ideally constant demand profile results in a cost reduction of approximately 11 %.

This article discusses possible strategies for decarbonizing the energy systems of an existing port. The approach consists in creating a complete superstructure that includes the use of renewable and fossil energy sources the import or local production of hydrogen vehicles and other equipment powered by Diesel electricity or hydrogen and the associated refuelling and storage units. Two substructures are then identified one including all these options the other considering also the addition of the energy demand of an adjacent steel industry. The goal is to select from each of these two substructures the most cost-effective configurations for 2030 and 2050 that meet the emission targets for those years under different cost scenarios for the energy sources and conversion/storage units obtained from the most reliable forecasts found in the literature. To this end the minimum total cost of all the energy conversion and storage units plus the associated infrastructures is sought by setting up a Mixed Integer Linear Programming optimization problem where integer variables handle the inclusion of the different generation and storage units and their activation in the operational phases. The comprehensive picture of possible solutions set allows identifying which options can most realistically be realized in the years to come in relation to the different assumed cost scenarios. Optimization results related to the scenario projected to 2030 indicate the key role played by Diesel hybrid and electric systems while considering the most stringent or much more stringent scenarios for emissions in 2050 almost all vehicles energy demand and industry hydrogen demand is met by hydrogen imported as ammonia by ship.

Given the global effort to embrace research actions and technology enhancement for the energy transition innovative sustainable systems are needed both for energy production and for those sectors that are responsible for high pollution and CO2 emissions. In this context electrolytic cells and fuel cells in their variety and flexibility are energy systems characterized by high efficiency and important performance guaranteeing a sustainable solution for future energy systems and for the circular economy. The scope of this paper is therefore to present the state of the art of such systems. An overview of the electrolyzers for hydrogen production is presented by detailing the level of applications for their different technologies from low-temperature units to high-temperature units the fuel flexibility the electrolysis and co-electrolysis mode and the potential coupling with renewable sources. Fuel cell-based systems are also presented and their application in the mobility sector is investigated by considering road transport with light-duty and heavy-duty applications and marine transport. A comparison with conventional technologies will be also presented providing some hints on the potential applications of electrolytic cells and fuel cell systems given their important contribution to the sustainable and circular economy.

Green hydrogen is among the most promising energy vectors that may enable the decarbonization of our society. The present study addresses the decarbonization of hard-to-abate sectors via the deployment of sustainable alternatives to current technologies and processes where the complete replacement of fossil fuels is deemed not nearly immediate. In particular the investigated case study tackles the emission reduction potential of steelmaking in the Italian industrial framework via the implementation of dedicated green hydrogen production systems to feed Hydrogen Direct Reduction process the main alternative to the traditional polluting routes towards emissions abatement. Green hydrogen is produced via the coupling of an onshore wind farm with lithium-ion batteries alkaline type electrolyzers and the interaction with the electricity grid. Building on a power generation dataset from a real utility-scale wind farm techno-economic analyses are carried out for a large number of system configurations varying components size and layout to assess its performance on the basis of two main key parameters the levelized cost of hydrogen (LCOH) and the Green Index (GI) the latter presented for the first time in this study. The optimal system design and operation logics are investigated accounting for the necessity of providing a constant mass flow rate of H2 and thus considering the interaction with the electricity network instead of relying solely on RES surplus. In-house-developed models that account for performances degradation over time of different technologies are adapted and used for the case study. The effect of different storage technologies is evaluated via a sensitivity analysis on different components and electricity pricing strategy to understand how to favour green hydrogen penetration in the heavy industry. Furthermore for a better comprehension and contextualization of the proposed solutions their emission-reduction potential is quantified and presented in comparison with the current scenario of EU-27 countries. In the optimal case the emission intensity related to the steel making process can be lowered to 235 kg of CO2 per ton of output steel 88 % less than the traditional route. A higher cost of the process must be accounted resulting in an LCOH of such solutions around 6.5 €/kg.

Remote locations and off-grid regions still rely mainly on diesel generators despite the high operating costs and greenhouse gas emissions. The exploitation of local renewable energy sources (RES) in combination with energy storage technologies can be a promising solution for the sustainable electrification of these areas. The aim of this work is to investigate the potential for decarbonizing remote islands in Norway by installing RES-based energy systems with hydrogen-battery storage. A national scale assessment is presented: first Norwegian islands are characterized and classified according to geographical location number of inhabitants key services and current electrification system. Then 138 suitable installation sites are pinpointed through a multiple-step sorting procedure and finally 10 reference islands are identified as representative case studies. A site-specific methodology is applied to estimate the electrical load profiles of all the selected reference islands. An optimization framework is then developed to determine the optimal system configuration that minimizes the levelized cost of electricity (LCOE) while ensuring a reliable 100% renewable power supply. The LCOE of the RES-based energy systems range from 0.21 to 0.63 €/kWh and a clear linear correlation with the wind farm capacity factor is observed (R2 equal to 0.87). Hydrogen is found to be crucial to prevent the oversizing of the RES generators and batteries and ensure long-term storage capacity. The techno-economic feasibility of alternative electrification strategies is also investigated: the use of diesel generators is not economically viable (0.87–1.04 €/kWh) while the profitability of submarine cable connections is highly dependent on the cable length and the annual electricity consumption (0.14–1.47 €/kWh). Overall the cost-effectiveness of RES-based energy systems for off-grid locations in Northern Europe can be easily assessed using the correlations derived in this analysis.