Kuwait
The Effect of the Temperature and Moisture to the Permeation Properties of PEO-Based Membranes for Carbon-Dioxide Separation
Jun 2021
Publication
An increased demand for energy in recent decades has caused an increase in the emissions of combustion products among which carbon-dioxide is the most harmful. As carbon-dioxide induces negative environmental effects like global warming and the greenhouse effect a decrease of the carbon-dioxide emission has emerged as one of the most urgent tasks in engineering. In this work the possibility for the application of the polymer-based dense mixed matrix membranes for flue gas treatment was tested. The task was to test a potential decrease in the permeability and selectivity of a mixed-matrix membrane in the presence of moisture and at elevated temperature. Membranes are based on two different poly(ethylene oxide)-based polymers filled with two different zeolite powders (ITR and IWS). An additive of detergent type was added to improve the contact properties between the zeolite and polymer matrix. The measurements were performed at three different temperatures (30 60 and 90 °C) under wet conditions with partial pressure of the water equal to the vapor pressure of the water at the given temperature. The permeability of carbon-dioxide hydrogen nitrogen and oxygen was measured and the selectivity of the carbon-dioxide versus other gases was determined. Obtained results have shown that an increase of temperature and partial pressure of the vapor slightly increase both the selectivity and permeability of the synthesized membranes. It was also shown that the addition of the zeolite powder increases the permeability of carbon-dioxide while maintaining the selectivity compared to hydrogen oxygen and nitrogen.
Hydrogen Energy Demand Growth Prediction and Assessment (2021–2050) Using a System Thinking and System Dynamics Approach
Jan 2022
Publication
Adoption of hydrogen energy as an alternative to fossil fuels could be a major step towards decarbonising and fulfilling the needs of the energy sector. Hydrogen can be an ideal alternative for many fields compared with other alternatives. However there are many potential environmental challenges that are not limited to production and distribution systems but they also focus on how hydrogen is used through fuel cells and combustion pathways. The use of hydrogen has received little attention in research and policy which may explain the widely claimed belief that nothing but water is released as a by-product when hydrogen energy is used. We adopt systems thinking and system dynamics approaches to construct a conceptual model for hydrogen energy with a special focus on the pathways of hydrogen use to assess the potential unintended consequences and possible interventions; to highlight the possible growth of hydrogen energy by 2050. The results indicate that the combustion pathway may increase the risk of the adoption of hydrogen as a combustion fuel as it produces NOx which is a key air pollutant that causes environmental deterioration which may limit the application of a combustion pathway if no intervention is made. The results indicate that the potential range of global hydrogen demand is rising ranging from 73 to 158 Mt in 2030 73 to 300 Mt in 2040 and 73 to 568 Mt in 2050 depending on the scenario presented.
Sustainable Aviation—Hydrogen Is the Future
Jan 2022
Publication
As the global search for new methods to combat global warming and climate change continues renewable fuels and hydrogen have emerged as saviours for environmentally polluting industries such as aviation. Sustainable aviation is the goal of the aviation industry today. There is increasing interest in achieving carbon-neutral flight to combat global warming. Hydrogen has proven to be a suitable alternative fuel. It is abundant clean and produces no carbon emissions but only water after use which has the potential to cool the environment. This paper traces the historical growth and future of the aviation and aerospace industry. It examines how hydrogen can be used in the air and on the ground to lower the aviation industry’s impact on the environment. In addition while aircraft are an essential part of the aviation industry other support services add to the overall impact on the environment. Hydrogen can be used to fuel the energy needs of these services. However for hydrogen technology to be accepted and implemented other issues such as government policy education and employability must be addressed. Improvement in the performance and emissions of hydrogen as an alternative energy and fuel has grown in the last decade. However other issues such as the storage and cost and the entire value chain require significant work for hydrogen to be implemented. The international community’s alternative renewable energy and hydrogen roadmaps can provide a long-term blueprint for developing the alternative energy industry. This will inform the private and public sectors so that the industry can adjust its plan accordingly.
Converting Sewage Water into H2 Fuel Gas Using Cu/CuO Nanoporous Photocatalytic Electrodes
Feb 2022
Publication
This work reports on H2 fuel generation from sewage water using Cu/CuO nanoporous (NP) electrodes. This is a novel concept for converting contaminated water into H2 fuel. The preparation of Cu/CuO NP was achieved using a simple thermal combustion process of Cu metallic foil at 550 ◦C for 1 h. The Cu/CuO surface consists of island-like structures with an inter-distance of 100 nm. Each island has a highly porous surface with a pore diameter of about 250 nm. X-ray diffraction (XRD) confirmed the formation of monoclinic Cu/CuO NP material with a crystallite size of 89 nm. The prepared Cu/CuO photoelectrode was applied for H2 generation from sewage water achieving an incident to photon conversion efficiency (IPCE) of 14.6%. Further the effects of light intensity and wavelength on the photoelectrode performance were assessed. The current density (Jph) value increased from 2.17 to 4.7 mA·cm−2 upon raising the light power density from 50 to 100 mW·cm−2 . Moreover the enthalpy (∆H*) and entropy (∆S*) values of Cu/CuO electrode were determined as 9.519 KJ mol−1 and 180.4 JK−1 ·mol−1 respectively. The results obtained in the present study are very promising for solving the problem of energy in far regions by converting sewage water to H2 fuel.
Propulsion of a Hydrogen-fuelled LH2 Tanker Ship
Mar 2022
Publication
This study aims to present a philosophical and quantitative perspective of a propulsion system for a large-scale hydrogen-fuelled liquid-hydrogen (LH2) tanker ship. Established methods are used to evaluate the design and performance of an LH2-carrier propulsion system for JAMILA a ship designed with four cylindrical LH2 tanks bearing a total capacity of ~280000 m3 along with cargo and using the boil-off as propulsion and power fuel. Additionally the ship propulsion system is evaluated based on the ship resistance requirements and a hydrogen-fuelled combined-cycle gas turbine is modelled to achieve the dual objectives of high efficiency and zero-carbon footprint. The required inputs primarily involve the off-design and degraded performance of the gas-turbine topping cycle and the proposed power plant operates with a total output power of 50 M.W. The results reveal that the output power allows ship operation at a great speed even with a degraded engine and adverse ambient conditions.
Economic Analysis of a Zero-carbon Liquefied Hydrogen Tanker Ship
Jun 2022
Publication
The green hydrogen economy is considered one of the sustainable solutions to mitigate climate change. This study provides an economic analysis of a novel liquified hydrogen (LH2) tanker fuelled by hydrogen with a total capacity of ~280000 m3 of liquified hydrogen named ‘JAMILA’. An established economic method was applied to investigate the economic feasibility of the JAMILA ship as a contribution to the future zero-emission target. The systematic economic evaluation determined the net present value of the LH2 tanker internal rate of return payback period and economic value added to support and encourage shipyards and the industrial sector in general. The results indicate that the implementation of the LH2 tanker ship can cover the capital cost of the ship within no more than 2.5 years which represents 8.3% of the assumed 30-year operational life cycle of the project in the best maritime shipping prices conditions and 6 years in the worst-case shipping marine economic conditions. Therefore the assessment of the economic results shows that the LH2 tankers may be a worthwhile contribution to the green hydrogen economy.
Improved Engine Performance and Significantly Reduced Greenhouse Gas Emissions by Fumigating Hydrogen in a Diesel Engine
Oct 2022
Publication
A thermodynamic model was developed for combustion performance and emissions with a reference diesel fuel a 10 vol% methanol blend with 90 vol% diesel a 10 vol% ethanol with 90 vol% diesel and a 4% hydrogen fumigating in the inlet port along with diesel direct injection. The diesel and two alcohol blends (10% methanol–90% diesel and 10% ethanol–90% diesel) was directly injected into the cylinder while hydrogen was fumigated at the inlet port. The model was developed by commercial GT-Suite software. Besides engine performance exergy and energy rates were estimated for the four fuels. Among the four fuels/fuel blends hydrogen fuel (4% fumigated hydrogen) shows the best performance in terms of exergy energy rates specific fuel consumption power and greenhouse gas emissions. Regarding greenhouse gases carbon dioxide was only considered in this investigation as it contributes to a significant detrimental effect on environmental pollution.
Sorption-enhanced Steam Methane Reforming for Combined CO2 Capture and Hydrogen Production: A State-of-the-Art Review
Oct 2021
Publication
The European Commission have just stated that hydrogen would play a major role in the economic recovery of post-COVID-19 EU countries. Hydrogen is recognised as one of the key players in a fossil fuel-free world in decades to come. However commercially practiced pathways to hydrogen production todays are associated with a considerable amount of carbon emissions. The Paris Climate Change Agreement has set out plans for an international commitment to reduce carbon emissions within the forthcoming decades. A sustainable hydrogen future would only be achievable if hydrogen production is “designed” to capture such emissions. Today nearly 98% of global hydrogen production relies on the utilisation of fossil fuels. Among these steam methane reforming (SMR) boasts the biggest share of nearly 3 50% of the global generation. SMR processes correspond to a significant amount of carbon emissions at various points throughout the process. Despite the dark side of the SMR processes they are projected to play a major role in hydrogen production by the first half of this century. This that a sustainable yet clean short/medium-term hydrogen production is only possible by devising a plan to efficiently capture this co-produced carbon as stated in the latest International Energy Agency (IEA) reports. Here we have carried out an in-depth technical review of the processes employed in sorption-enhanced steam methane reforming (SE-SMR) an emerging technology in low-carbon SMR for combined carbon capture and hydrogen production. This paper aims to provide an in-depth review on two key challenging elements of SE-SMR i.e. the advancements in catalysts/adsorbents preparation and current approaches in process synthesis and optimisation including the employment of artificial intelligence in SE-SMR processes. To the best of the authors‟ knowledge there is a clear gap in the literature where the above areas have been scrutinised in a systematic and coherent fashion. The gap is even more pronounced in the application of AI in SE-SMR technologies. As a result this work aims to fill this gap within the scientific literature.
Techno Environmental Assessment of Flettner Rotor as Assistance Propulsion System for LH2 Tanker Ship Fuelled by Hydrogen
Nov 2022
Publication
This study presents a novel design and development of a 280000 m3 liquefied hydrogen tanker ship by implementing a set of 6 Flettner rotors as an assistance propulsion system in conjunction with a combined-cycle gas turbine fuelled by hydrogen as a prime mover. The study includes assessment of the technical and environmental aspects of the developed design. Furthermore an established method was applied to simulate the LH2 tanker in different voyages and conditions to investigate the benefits of harnessing wind energy to assist combined-cycle gas turbine in terms of performance and emission reduction based on engine behaviour for different voyages under loaded and unloaded normal as well as 6 % degraded engine and varying ambient conditions. The results indicate that implementing a set of 6 Flettner rotors for the LH2 tanker ship has the potential to positively impact the performance and lead to environmental benefits. A maximum contribution power of around 1.8 MW was achieved in the winter season owing to high wind speed and favourable wind direction. This power could save approximately 3.6 % of the combined-cycle gas turbine total output power (50 MW) and cause a 3.5 % reduction in NOx emissions.
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