Netherlands
The Many Greenhouse Gas Footprints of Green Hydrogen
Aug 2022
Publication
Green hydrogen could contribute to climate change mitigation but its greenhouse gas footprint varies with electricity source and allocation choices. Using life-cycle assessment we conclude that if electricity comes from additional renewable capacity green hydrogen outperforms fossil-based hydrogen. In the short run alternative uses of renewable electricity likely achieve greater emission reductions.
Prospective LCA of Alkaline and PEM Electrolyser Systems
Nov 2023
Publication
This prospective life cycle assessment (LCA) compares the environmental impacts of alkaline electrolyser (AE) and proton exchange membrane (PEM) electrolyser systems for green hydrogen production with a special focus on the stack components. The study evaluates both baseline and near-future advanced designs considering cradle-to-gate life cycle from material production to operation. The electricity source followed by the stacks are identified as major contributors to environmental impacts. No clear winner emerges between AE and PEM in relation to environmental impacts. The advanced designs show a reduced impact in most categories compared to baseline designs which can mainly be attributed to the increased current density. Advanced green hydrogen production technologies outperform grey and blue hydrogen production technologies in all impact categories except for minerals and metals resource use due to rare earth metals in the stacks. Next to increasing current density decreasing minimal load requirements. improving sustainable mining practices (including waste treatment) and low carbon intensity steel production routes can enhance the environmental performance of electrolyser systems aiding the transition to sustainable hydrogen production.
Alkaline Electrolysis for Green Hydrogen Production: A Novel, Simple Model for Thermo-electrochemical Coupled System Analysis
Dec 2024
Publication
Alkaline water electrolysis (AWE) is the most mature electrochemical technology for hydrogen production from renewable electricity. Thus its mathematical modeling is an important tool to provide new perspectives for the design and optimization of energy storage and decarbonization systems. However current models rely on numerous empirical parameters and neglect variations of temperature and concentration alongside the electrolysis cell which can impact the application and reliability of the simulation results. Thus this study proposes a simple four-parameter semi-empirical model for AWE system analysis which relies on minimal fitting data while providing reliable extrapolation results. In addition the effect of model dimensionality (i.e. 0D 1/2D and 1D) are carefully assessed in the optimization of an AWE system. The results indicate that the proposed model can accurately reproduce literature data from four previous works (R 2 ≥ 0.98) as well as new experimental data. In the system optimization the trade-offs existing in the lye cooling sizing highlight that maintaining a low temperature difference in AWE stacks (76-80°C) leads to higher efficiencies and lower hydrogen costs.
Hydrogen Storage in Depleted Gas Reservoirs with Carbon Dioxide as a Cushion Gas: Exploring a Lateral Gas Seperation Strategy to Reduce Gas Mixing
Jan 2025
Publication
Large-scale H2 storage in depleted hydrocarbon reservoirs offers a practical way to use existing energy infra structure to address renewable energy intermittency. Cushion gases often constitute a large initial investment especially when expensive H2 is used. Cheaper alternatives such as CO2 or in-situ CH4 can reduce costs and in the case of CO2 integrate within carbon capture and storage systems. This study explored cushion and working gas dynamics through numerically modelling a range of storage scenarios in laterally extensive reservoirs – such as those in the Southern North Sea. In all simulations the cushion and working gases were separated laterally to limit contact surface area and therefore mixing. This work provides valuable insights into (i) capacity estima tions of CO2 storage and H2 withdrawal (ii) macro-scale fluid dynamics and (iii) the effects of gas mixing trends on H2 purity. The results underscore key trade-offs between CO2 storage volumes and H2 withdrawal and purity
A Hybrid Robust-stochastic Approach for Optimal Scheduling of Interconnected Hydrogen-based Energy Hubs
Jan 2021
Publication
The energy hub (EH) concept is an efficient way to integrate various energy carriers. Inaddition demand response programmes (DRPs) are complementary to improving anEH's efficiency and increase energy system flexibility. The hydrogen storage system as agreen energy carrier has an essential role in balancing supply and demand preciselysimilar to other storage systems. A hybrid robust‐stochastic approach is applied herein toaddress fluctuations in wind power generation multiple demands and electricity marketprice in a hydrogen‐based smart micro‐energy hub (SMEH) with multi‐energy storagesystems. The proposed hybrid approach enables the operator to manage the existinguncertainties with more flexibility. Also flexible electrical and thermal demands under anintegrated demand response programme (IDRP) are implemented in the proposedSMEH. The optimal scheduling of the hydrogen‐based SMEH problem considering windpower generation and electricity market price fluctuations as well as IDRP is modelledvia a mixed‐integer linear programming problem. Finally the validity and applicability ofthe proposed model are verified through simulation and numerical results.
Determining Onshore or Offshore Hydrogen Storage for Large Offshore Wind Parks: The North Sea Wind Power Hub Case
Aug 2024
Publication
The large-scale integration of renewable energy sources leads to daily and seasonal mismatches between supply and demand and the curtailment of wind power. Hydrogen produced from surplus wind power offers an attractive solution to these challenges. In this paper we consider a large offshore wind park and analyze the need for hydrogen storage at the onshore and offshore sides of a large transportation pipeline that connects the wind park to the mainland. The results show that the pipeline with line pack storage though important for day-to-day fluctuations will not offer sufficient storage capacity to bridge seasonal differences. Furthermore the results show that if the pipeline is sufficiently sized additional storage is only needed on one side of the pipeline which would limit the needed investments. Results show that the policy which determines what part of the wind power is fed into the electricity grid and what part is converted into hydrogen has a significant influence on these seasonal storage needs. Therefore investment decisions for hydrogen systems should be made by considering both the onshore and offshore storage requirements in combination with electricity transport to the mainland.
Hydrogen Sampling Systems Adapted to Heavy-duty Refuelling Stations' Current and Future Specifications - A Review
Sep 2024
Publication
To meet the new regulation for the deployment of alternative fuels infrastructure which sets targets for electric recharging and hydrogen refuelling infrastructure by 2025 or 2030 a large infrastructure comprising trucksuitable hydrogen refuelling stations will soon be required. However further standardisation is required to support the uptake of hydrogen for heavy-duty transport for Europe’s green energy future. Hydrogen-powered vehicles require pure hydrogen as some contaminants can reduce the performance of the fuel cell even at very low levels. Even if previous projects have paved the way for the development of the European quality infrastructure for hydrogen conformity assessment sampling systems and methods have yet to be developed for heavy-duty hydrogen refuelling stations (HD-HRS). This study reviews different aspects of the sampling of hydrogen at heavy-duty hydrogen refuelling stations for purity assessment with a focus on the current and future specifications and operations at HD-HRS. This study describes the state-of-the art of sampling systems currently under development for use at HD-HRS and highlights a number of aspects which must be taken into consideration to ensure safe and accurate sampling: risk assessment for the whole sampling exercise selection of cylinders methods to prepare cylinders before the sampling filling pressure and venting of the sampling systems.
Impact of an Electrode-diaphragm Gap on Diffusive Hydrogen Crossover in Alkaline Water Electrolysis
Oct 2023
Publication
Hydrogen crossover limits the load range of alkaline water electrolyzers hindering their integration with renewable energy. This study examines the impact of the electrode-diaphragm gap on crossover focusing on diffusive transport. Both finite-gap and zero-gap designs employing the state-of-the-art Zirfon UTP Perl 500 and UTP 220 diaphragms were investigated at room temperature and with a 12 wt% KOH electrolyte. Experimental results reveal a relatively high crossover for a zero-gap configuration which corresponds to supersaturation levels at the diaphragm-electrolyte interface of 8–80 with significant fluctuations over time and between experiments due to an imperfect zero-gap design. In contrast a finite-gap (500 μm) has a significantly smaller crossover corresponding to supersaturation levels of 2–4. Introducing a cathode gap strongly decreases crossover unlike an anode gap. Our results suggest that adding a small cathode-gap can significantly decrease gas impurity potentially increase the operating range of alkaline electrolyzers while maintaining good efficiency.
Green Hydrogen Techno-economic Assessments from Simulated and Measured Solar Photovoltaic Power Profiles
Nov 2024
Publication
Studies estimating the production cost of hydrogen-based fuels known as e-fuels often use renewable power profile time series obtained from open-source simulation tools that rely on meteorological reanalysis and satellite data such as Renewables.ninja or PVGIS. These simulated time series contain errors compared to real on-site measured data which are reflected in e-fuels cost estimates plant design and operational performance increasing the risk of inaccurate plant design and business models. Focusing on solar-powered e-fuels this study aims to quantify these errors using high-quality on-site power production data. A state-of-the-art optimization techno-economic model was used to estimate e-fuel production costs by utilizing either simulated or high-quality measured PV power profiles across four sites with different climates. The results indicate that in cloudy climates relying on simulated data instead of measured data can lead to an underestimation of the fuel production costs by 36 % for a hydrogen user requiring a constant supply considering an original error of 1.2 % in the annual average capacity factor. The cost underestimation can reach 25 % for a hydrogen user operating between 40 % and 100 % load and 17.5 % for a fully flexible user. For comparison cost differences around 20 % could also result from increasing the electrolyser or PV plant costs by around 55 % which highlights the importance of using high-quality renewable power profiles. To support this an open-source collaborative repository was developed to facilitate the sharing of measured renewable power profiles and provide tools for both time series analysis and green hydrogen techno-economic assessments.
Assessment of Hydrogen Transport Aircraft
Sep 2022
Publication
Zero-carbon-dioxide-emitting hydrogen-powered aircraft have in recent decades come back on the stage as promising protagonists in the fght against global warming. The main cause for the reduced performance of liquid hydrogen aircraft lays in the fuel storage which demands the use of voluminous and heavy tanks. Literature on the topic shows that the optimal fuel storage solution depends on the aircraft range category but most studies disagree on which solution is optimal for each category. The objective of this research was to identify and compare possible solutions to the integration of the hydrogen fuel containment system on regional short/medium- and large passenger aircraft and to understand why and how the optimal tank integration strategy depends on the aircraft category. This objective was pursued by creating a design and analysis framework for CS-25 aircraft capable of appreciating the efects that diferent combinations of tank structure fuselage diameter tank layout shape venting pressure and pressure control generate at aircraft level. Despite that no large diferences among categories were found the following main observations were made: (1) using an integral tank structure was found to be increasingly more benefcial with increasing aircraft range/size. (2) The use of a forward tank in combination with the aft one appeared to be always benefcial in terms of energy consumption. (3) The increase in fuselage diameter is detrimental especially when an extra aisle is not required and a double-deck cabin is not feasible. (4) Direct venting has when done efciently a small positive efect. (5) The optimal venting pressure varies with the aircraft confguration performance and mission. The impact on performance from sizing the tank for missions longer than the harmonic one was also quantifed.
Retrofitted Hydrogen-Electric Propulsion Aircraft: Performance Simulation of Critical Operating Conditions
Jan 2025
Publication
Retrofitting regional turboprop aircraft with hydrogen (H2)-electric powertrains using fuel cell systems (FCSs) has gained interest in the last decade. This type of powertrain eliminates CO2 NOx and fine particle emissions during flight as FCSs only emit water. In this context the “Hydrogen Aircraft Powertrain and Storage Systems” (HAPSS) project targets the development of a H2-electric propulsion system for retrofitting Dash 8- 300 series aircraft. The purpose of the study described in this paper is to analyze the performance of the retrofitted H2-electric aircraft during critical operating conditions. Takeoff as well as climb cruise and go-around performances are addressed. The NLR in-house tool MASS (Mission Aircraft and Systems Simulation) was used for the performance analyses. The results show that the retrofitted H2-electric aircraft has a slightly increased takeoff distance compared to the Dash 8-300 and it requires a maximum rated shaft power of 1.9 MW per propeller. A total rated FCS output power of 3.1 MW is sufficient to satisfy the takeoff requirements at the cost of lower cruise altitude and reduced cruise speed as compared to the Dash 8-300. Furthermore a higher-rated FCS is required to achieve the climb performance required for the typical climb profile of the Dash 8-300.
Will Hydrogen and Synthetic Fuels Energize our Future? Their Role in Europe's Climate-neutral Energy System and Power System Dynamics
Aug 2024
Publication
This study evaluates the technoeconomic impacts of direct and indirect electrification on the EU's net-zero emissions target by 2050. By linking the JRC-EU-TIMES long-term energy system model with PLEXOS hourly resolution power system model this research offers a detailed analysis of the interactions between electricity hydrogen and synthetic fuel demand production technologies and their effects on the power sector. It highlights the importance of high temporal resolution power system analysis to capture the synergistic effects of these components often overlooked in isolated studies. Results indicate that direct electrification increases significantly and unimpacted by biomass CCS and nuclear energy assumptions. However indirect electrification in the form of hydrogen varies significantly between 1400 and 2200 TWhH2 by 2050. Synthetic fuels are essential for sector coupling making up 6–12% of total energy consumption by 2050 with the power sector supplying most hydrogen and CO2 for their production. Varying levels of indirect electrification impact electrolysers renewable energy and firm capacities. Higher indirect electrification increases electrolyser capacity factors by 8% leading to more renewable energy curtailment but improves system reliability by reducing 11 TWh unserved energy and increasing flexibility options. These insights inform EU energy policies stressing the need for a balanced approach to electrification biomass use and CCS to achieve a sustainable and reliable net-zero energy system by 2050. We also explore limitations and sensitivities.
Using Hydro-Pneumatic Energy Storage for Improving Offshore Wind-Driven Green Hydrogen Production—A Preliminary Feasibility Study in the Central Mediterranean Sea
Aug 2025
Publication
This paper presents a preliminary feasibility study for integrating hydro-pneumatic energy storage (HPES) with off-grid offshore wind turbines and green hydrogen production facilities—a concept termed HydroGenEration (HGE). This study compares the performance of this innovative concept system with an off-grid direct wind-to-hydrogen plant concept without energy storage both under central Mediterranean wind conditions. Numerical simulations were conducted at high temporal resolution capturing 10-min fluctuations of open field measured wind speeds at an equivalent offshore wind turbine (WT) hub height over a full 1-year seasonal cycle. Key findings demonstrate that the HPES system of choice namely the Floating Liquid Piston Accumulator with Sea Water under Compression (FLASC) system significantly reduces Proton Exchange Membrane (PEM) electrolyser (PEMEL) On/Off cycling (with a 66% reduction in On/Off events) while maintaining hydrogen production levels despite the integration of the energy storage system which has a projected round-trip efficiency of 75%. The FLASC-integrated HGE solution also marginally reduces renewable energy curtailment by approximately 0.3% during the 12-month timeframe. Economic analysis reveals that while the FLASC HPES system does introduce an additional capital cost into the energy chain it still yields substantial operational savings exceeding EUR 3 million annually through extended PEM electrolyser lifetime and improved operational efficiency. The Levelized Cost of Hydrogen (LCOH) for the FLASC-integrated HGE system which is estimated to be EUR 18.83/kg proves more economical than a direct wind-to-hydrogen approach with a levelized cost of EUR 21.09/kg of H2 produced. This result was achieved through more efficient utilisation of wind energy interfaced with energy storage as it mitigated the natural intermittency of the wind and increased the lifecycle of the equipment especially that of the PEM electrolysers. Three scenario models were created to project future costs. As electrolyser technologies advance cost reductions would be expected and this was one of the scenarios envisaged for the future. These scenarios reinforce the technical and economic viability of the HGE concept for offshore green hydrogen production particularly in the Mediterranean and in regions having similar moderate wind resources and deeper seas for offshore hybrid sustainable energy systems.
A Systematic Review of Predictive, Optimization, and Smart Control Strategies for Hydrogen-based Building Heating Systems
Nov 2024
Publication
The use of energy in the built environment contributes to over one-third of the world’s carbon emissions. To reduce that effect two primary solutions can be adopted i.e. (i) renovation of old buildings and (ii) increasing the renewable energy penetration. This review paper focuses on the latter. Renewable energy sources typically have an intermittent nature. In other words it is not guaranteed that these sources can be harnessed on demand. Thus complement solutions should be considered to use renewable energy sources efficiently. Hydrogen is recognized as a potential solution. It can be used to store excess energy or be directly exploited to generate thermal energy. Throughout this review various research papers focusing on hydrogen-based heating systems were reviewed analyzed and classified from different perspectives. Subsequently articles related to machine learning models optimization algorithms and smart control systems along with their applications in building energy management were reviewed to outline their potential contributions to reducing energy use lowering carbon emissions and improving thermal comfort for occupants. Furthermore research gaps in the use of these smart strategies in residential hydrogen heating systems were thoroughly identified and discussed. The presented findings indicate that the semi-decentralized hydrogen-based heating systems hold significant potential. First these systems can control the thermal demand of neighboring homes through local substations; second they can reduce reliance on power and gas grids. Furthermore the model predictive control and reinforcement learning approaches outperform other control systems ensuring energy comfort and cost-effective energy bills for residential buildings.
Comprehensive Review of Geomechanics of Underground Hydrogen Storage in Depleted Reservoirs and Salt Caverns
Sep 2023
Publication
Hydrogen is a promising energy carrier for a low-carbon future energy system as it can be stored on a megaton scale (equivalent to TWh of energy) in subsurface reservoirs. However safe and efficient underground hydrogen storage requires a thorough understanding of the geomechanics of the host rock under fluid pressure fluctuations. In this context we summarize the current state of knowledge regarding geomechanics relevant to carbon dioxide and natural gas storage in salt caverns and depleted reservoirs. We further elaborate on how this knowledge can be applied to underground hydrogen storage. The primary focus lies on the mechanical response of rocks under cyclic hydrogen injection and production fault reactivation the impact of hydrogen on rock properties and other associated risks and challenges. In addition we discuss wellbore integrity from the perspective of underground hydrogen storage. The paper provides insights into the history of energy storage laboratory scale experiments and analytical and simulation studies at the field scale. We also emphasize the current knowledge gaps and the necessity to enhance our understanding of the geomechanical aspects of hydrogen storage. This involves developing predictive models coupled with laboratory scale and field-scale testing along with benchmarking methodologies.
A Novel Sustainable Approach for Site Selection of Underground Hydrogen Storage in Poland Using Deep Learning
Jul 2024
Publication
This research investigates the potential of using bedded salt formations for underground hydrogen storage. We present a novel artificial intelligence framework that employs spatial data analysis and multi-criteria decision-making to pinpoint the most appropriate sites for hydrogen storage in salt caverns. This methodology incorporates a comprehensive platform enhanced by a deep learning algorithm specifically a convolutional neural network (CNN) to generate suitability maps for rock salt deposits for hydrogen storage. The efficacy of the CNN algorithm was assessed using metrics such as Mean Absolute Error (MAE) Mean Squared Error (MSE) Root Mean Square Error (RMSE) and the Correlation Coefficient (R2 ) with comparisons made to a real-world dataset. The CNN model showed outstanding performance with an R2 of 0.96 MSE of 1.97 MAE of 1.003 and RMSE of 1.4. This novel approach leverages advanced deep learning techniques to offer a unique framework for assessing the viability of underground hydrogen storage. It presents a significant advancement in the field offering valuable insights for a wide range of stakeholders and facilitating the identification of ideal sites for hydrogen storage facilities thereby supporting informed decisionmaking and sustainable energy infrastructure development.
Hydrogen Storage Solutions for Residential Heating: A Thermodynamic and Economic Analysis with Scale-up Potential
Jul 2024
Publication
The study presents a thermodynamic and economic assessment of different hydrogen storage solutions for heating purposes powered by PV panels of a 10-apartment residential building in Milan and it focuses on compressed hydrogen liquid hydrogen and metal hydride. The technical assessment involves using Python to code thermodynamic models to address technical and thermodynamic performances. The economic analysis evaluates the CAPEX the ROI and the cost per unit of stored hydrogen and energy. The study aims to provide an accurate assessment of the thermodynamic and economic indicators of three of the storage methods introduced in the literature review pointing out the one with the best techno-economic performance for further development and research. The performed analysis shows that compressed hydrogen represents the best alternative but its cost is still too high for small residential applications. Applying the technology to a big system case would enable the solution making it economically feasible.
Impact of Experimentally Measured Relative Permeability Hysteresis on Reservoir-scale Performance of Undergound Hydrogen Storage (UHS)
Jan 2024
Publication
Underground Hydrogen Storage (UHS) is an emerging large-scale energy storage technology. Researchers are investigating its feasibility and performance including its injectivity productivity and storage capacity through numerical simulations. However several ad-hoc relative permeability and capillary pressure functions have been used in the literature with no direct link to the underlying physics of the hydrogen storage and production process. Recent relative permeability measurements for the hydrogen-brine system show very low hydrogen relative permeability and strong liquid phase hysteresis very different to what has been observed for other fluid systems for the same rock type. This raises the concern as to what extend the existing studies in the literature are able to reliably quantify the feasibility of the potential storage projects. In this study we investigate how experimentally measured hydrogen-brine relative permeability hysteresis affects the performance of UHS projects through numerical reservoir simulations. Relative permeability data measured during a hydrogen-water core-flooding experiment within ADMIRE project is used to design a relative permeability hysteresis model. Next numerical simulation for a UHS project in a generic braided-fluvial water-gas reservoir is performed using this hysteresis model. A performance assessment is carried out for several UHS scenarios with different drainage relative permeability curves hysteresis model coefficients and injection/production rates. Our results show that both gas and liquid relative permeability hysteresis play an important role in UHS irrespective of injection/production rate. Ignoring gas hysteresis may cause up to 338% of uncertainty on cumulative hydrogen production as it has negative effects on injectivity and productivity due to the resulting limited variation range of gas saturation and pressure during cyclic operations. In contrast hysteresis in the liquid phase relative permeability resolves this issue to some extent by improving the displacement of the liquid phase. Finally implementing relative permeability curves from other fluid systems during UHS performance assessment will cause uncertainty in terms of gas saturation and up to 141% underestimation on cumulative hydrogen production. These observations illustrate the importance of using relative permeability curves characteristic of hydrogen-brine system for assessing the UHS performances.
Modelling of Hydrogen Dispersion with Effects
Sep 2023
Publication
The paper shows the latest developments of Gexcon’s consequence modelling software EFFECTS with validation based on hydrogen experimental data for different storage conditions and scenarios including liquid hydrogen two-phase jet releases. The effect of atmospheric turbulence on the dispersion and potential worst-case scenarios of hydrogen which are very different from heavy gas releases are discussed. Beside validation for gaseous hydrogen releases a validation study for pressurised liquid hydrogen jet releases including a sensitivity analysis is performed and the results are compared with experimental data.
Benchmark of J55 and X56 Steels on Cracking and Corrosion Effects Under Hydrogen Salt Cavern Boundary Conditions
Feb 2024
Publication
Salt caverns have great potential to store relevant amounts of hydrogen as part of the energy transition. However the durability and suitability of commonly used steels for piping in hydrogen salt caverns is still under research. In this work aging effects focusing on corrosion and cracking patterns of casing steel API 5CT J55 and “H2ready” pipeline steel API 5L X56 were investigated with scanning electron microscopy and energy dispersive X-ray spectroscopy after accelerated stress tests with pressure/temperature cycling under hydrogen salt cavern-like conditions. Compared to dry conditions significant more corrosion by presence of salt ions was detected. However compared to X56 only for J55 an intensification of corrosion and cracking at the surface due to hydrogen atmosphere was revealed. Pronounced surface cracks were observed for J55 over the entire samples. Overall the results strongly suggest that X56 is more resistant than J55 under the conditions of a hydrogen salt cavern.
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