Saudi Arabia
Hydrogen Effect on the Cyclic Behavior of a Superelastic NiTi Archwire
Mar 2019
Publication
In this work we are interested in examining the strain rate effect on the mechanical behavior of Ni–Ti superelastic wires after hydrogen charging and ageing for 24 h. Specimens underwent 50 cycles of loading-unloading reaching an imposed deformation of 7.6%. During loading strain rates from 10−4 s−1 to 10−2 s−1 were achieved. With a strain rate of 10−2 s−1 the specimens were charged by hydrogen for 6 h and aged for one day showed a superelastic behavior marked by an increase in the residual deformation as a function of the number of cycles. In contrast after a few number of cycles with a strain rate of 10−4 s−1 the Ni-Ti alloy archwire specimens fractured in a brittle manner during the martensite transformation stage. The thermal desorption analysis showed that for immersed specimens the desorption peak of hydrogen appeared at 320 °C. However after annealing the charged specimens by hydrogen at 400 °C for 1 h an embrittlement took place at the last cycles for the lower strain rates of 10−4 s−1. The present study suggests that the embrittlement can be due to the development of an internal stress in the subsurface of the parent phase during hydrogen charging and due to the creation of cracks and local zones of plasticity after desorption.
Geopolitics of the Energy Transformation: The Hydrogen Factor
Jan 2022
Publication
As countries around the world rally behind net zero targets hydrogen is increasingly seen as a missing piece of the energy transformation puzzle to decarbonise harder-to-abate sectors. The possible pathway on which hydrogen might evolve still involves many uncertainties. With the growing momentum to establish a global hydrogen market comes the need for a deeper understanding of its broader effects including geopolitical aspects. IRENA has carried out an in-depth analysis of the geopolitics of hydrogen as part of the work of the Collaborative Framework on the Geopolitics of Energy Transformation (CF-GET). The report builds on IRENA’s substantial body of work in hydrogen and benefits from a wide range of expert input in the fields of energy and geopolitics.
This report considers whether and how hydrogen may disrupt future energy systems reflecting on many of the key themes discussed in the Global Commission’s report A New World – The Geopolitics of the Energy Transformation. The analysis offers insights into how countries and stakeholders can navigate the uncertainties and shape the development of hydrogen markets and outlines policy considerations to help mitigate the geopolitical risks and capitalise on opportunities. Some of the key findings of the report include:
This report considers whether and how hydrogen may disrupt future energy systems reflecting on many of the key themes discussed in the Global Commission’s report A New World – The Geopolitics of the Energy Transformation. The analysis offers insights into how countries and stakeholders can navigate the uncertainties and shape the development of hydrogen markets and outlines policy considerations to help mitigate the geopolitical risks and capitalise on opportunities. Some of the key findings of the report include:
- Hydrogen is part of a much bigger energy transition picture and its development and deployment strategies should not be considered in isolation.
- Setting the right priorities for hydrogen use will be essential for its rapid scale-up and long-term contribution to decarbonisation efforts.
- The 2020s could become the era of a big race for technology leadership as costs are likely to fall sharply with learning and scaling-up of needed infrastructure. Equipment manufacturing offers an opportunity to capture value in the coming years and decades.
- Hydrogen trade and investment flows will spawn new patterns of interdependence and bring shifts in bilateral relations.
- Countries with an abundance of low-cost renewable power could become producers of green hydrogen with commensurate geoeconomic and geopolitical consequences.
- Hydrogen could be an attractive avenue for fossil fuel exporters to help diversify their economies and develop new export industries.
- Supporting the advancement of renewable energy and green hydrogen in developing countries is critical for decarbonising the energy system and can contribute to global equity and stability.
- International co-operation will be necessary to devise a transparent hydrogen market with coherent standards and norms that contribute to climate change efforts meaningfully.
A Pathway to Decarbonise the Shipping Sector by 2050
Oct 2021
Publication
Urgent action is needed to accelerate the pace of the global energy transition and the decarbonisation of the global economy. International shipping is a key sector of the economy as much as 90% of worldwide trade is transacted via ocean going vessels. The sector is also one of the most challenging to decarbonise.
In this context A Pathway to Decarbonise the Shipping Sector by 2050 by the International Renewable Energy Agency (IRENA) analyses the technology readiness of the renewable fuels suitable for international shipping. This report also explores the options and actions needed to progress towards a decarbonised maritime shipping sector by 2050 and seeks to identify a realistic mitigation pathway to reach the climate goal of limiting global temperature rise to 1.5°C and bringing CO2 emissions closer to net zero by mid-century.
Key messages:
In this context A Pathway to Decarbonise the Shipping Sector by 2050 by the International Renewable Energy Agency (IRENA) analyses the technology readiness of the renewable fuels suitable for international shipping. This report also explores the options and actions needed to progress towards a decarbonised maritime shipping sector by 2050 and seeks to identify a realistic mitigation pathway to reach the climate goal of limiting global temperature rise to 1.5°C and bringing CO2 emissions closer to net zero by mid-century.
Key messages:
- The sector’s decarbonisation strategy must involve a combination of energy efficiency and renewable fuels. Starting now the active adoption of energy efficiency measures will be critical to reduce energy demand and thus CO2 emissions in the immediate term.
- In the short term advanced biofuels will play a key role in the reduction of CO2 emissions. In the medium and long-term green hydrogen-based fuels are set to be the backbone for the sector’s decarbonisation.
- Renewable e-ammonia will play a pivotal role; where 183 million tonnes of renewable ammonia for international shipping alone will be needed by 2050 - a comparable amount to today’s ammonia global production.
- While renewable fuels production costs are currently high in the next decades renewable fuels will become cost competitive and can shield the shipping sector from the volatility that characterises the fossil fuels market.
- Taking early action is vital. Sector decarbonisation can be accelerated and ambition raised beyond the climate goals by fostering investment in the production of renewable fuels. Stakeholders need to develop broader business models and establish strategic partnerships involving energy-intensive industries as well as power suppliers and the petrochemical sector.
A Thorough Economic Evaluation by Implementing Solar/Wind Energies for Hydrogen Production: A Case Study
Jan 2022
Publication
A technical–economic assessment was carried out in this study to determine the possibilities for wind and solar power generation in Afghanistan’s Helmand province. The results showed that most of the province has a solar irradiance of over 400 W/m2 and also showed that wind and solar power generated in the province can be up to twice as cheap as the official price of renewable power in Afghanistan. The most suitable site for solar and hydrogen production was found to be Laškar Gah where solar and hydrogen can be produced at a cost of 0.066 $/kWh and 2.1496 $/kg-H ¯ 2 respectively. In terms of wind power production and hydrogen production from wind the most suitable site was Sang¯ın where wind power and hydrogen could be produced at costs of 0.057 $/kWh and 1.4527 $/kg-H2 respectively. Despite the high potential of wind and solar energy in the Helmand province the most suitable place in this region to produce hydrogen from wind/solar energy was evaluated from technical economic and environmental perspectives with the Multi-Criteria DecisionMaking (MCDM) method. The Stepwise Weight Assessment Ratio Analysis (SWARA) method was used for weighting criteria and the Weighted Aggregated Sum Product Assessment (WASPAS) method was used to prioritize locations. The results show that Sang¯ın is the most suitable place for the construction of a wind hydrogen power plant and Laškar Gah is the most suitable place for the ¯ construction of a solar hydrogen power plant.
Development and Mechanistic Studies of Ternary Nanocomposites for Hydrogen Production from Water Splitting to Yield Sustainable/Green Energy and Environmental Remediation
Mar 2022
Publication
Photocatalysts lead vitally to water purifications and decarbonise environment each by wastewater treatment and hydrogen (H2 ) production as a renewable energy source from waterphotolysis. This work deals with the photocatalytic degradation of ciprofloxacin (CIP) and H2 production by novel silver-nanoparticle (AgNPs) based ternary-nanocomposites of thiolated reducegraphene oxide graphitic carbon nitride (AgNPs-S-rGO2%@g-C3N4 ) material. Herein the optimised balanced ratio of thiolated reduce-graphene oxide in prepared ternary-nanocomposites played matchlessly to enhance activity by increasing the charge carriers’ movements via slowing down charge-recombination ratios. Reduced graphene oxide (rGO) >2 wt.% or < 10 nm. Therefore AgNPs-S-rGO2%@g-C3N4 has 3772.5 µmolg−1 h −1 H2 production which is 6.43-fold higher than g-C3N4 having cyclic stability of 96% even after four consecutive cycles. The proposed mechanism for AgNPs-S-rGO2%@g-C3N4 revealed that the photo-excited electrons in the conduction-band of g-C3N4 react with the adhered water moieties to generate H2 .
A Smart Strategy for Sizing of Hybrid Renewable Energy System to Supply Remote Loads in Saudi Arabia
Oct 2021
Publication
The use of hybrid renewable energy systems (HRES) has become the best option for supplying electricity to sites remote from the central power system because of its sustainability environmental friendliness and its low cost of energy compared to many conventional sources such as diesel generators. Due to the intermittent nature of renewable energy resources there is a need however for an energy storage system (ESS) to store the surplus energy and feed the energy deficit. Most renewable sources used battery storage systems (BSS) a green hydrogen storage system (GHSS) and a diesel generator as a backup for these sources. Batteries are very expensive and have a very short lifetime and GHSS have a very expensive initial cost and many security issues. In this paper a system consisting of wind turbines and a photovoltaic (PV) array with a pumped hydro energy storage (PHES) system as the main energy storage to replace the expensive and short lifetime batteries is proposed. The proposed system is built to feed a remote area called Dumah Aljandal in the north of Saudi Arabia. A smart grid is used via a novel demand response strategy (DRS) with a dynamic tariff to reduce the size of the components and it reduces the cost of energy compared to a flat tariff. The use of the PHES with smart DRS reduced the cost of energy by 34.2% and 41.1% compared to the use of BSS and GHSS as an ESS respectively. Moreover the use of 100% green energy sources will avoid the emission of an estimated 2.5 million tons of greenhouse gases every year. The proposed system will use a novel optimization algorithm called the gradually reduced particles of particle swarm optimization (GRP-PSO) algorithm to enhance the exploration and exploitation during the searching iterations. The GRP-PSO reduces the convergence time to 58% compared to the average convergence time of 10 optimization algorithms used for comparison. A sensitivity analysis study is introduced in this paper in which the effect of ±20% change in wind speed and solar irradiance are selected and the system showed a low effect of these resources on the Levelized cost of energy of the HRES. These outstanding results proved the superiority of using a pumped-storage system with a dynamic tariff demand response strategy compared to the other energy storage systems with flat-rate tariffs.
Intelligent Natural Gas and Hydrogen Pipeline Dispatching Using the Coupled Thermodynamics-Informed Neural Network and Compressor Boolean Neural Network
Feb 2022
Publication
Natural gas pipelines have attracted increasing attention in the energy industry thanks to the current demand for green energy and the advantages of pipeline transportation. A novel deep learning method is proposed in this paper using a coupled network structure incorporating the thermodynamics-informed neural network and the compressor Boolean neural network to incorporate both functions of pipeline transportation safety check and energy supply predictions. The deep learning model is uniformed for the coupled network structure and the prediction efficiency and accuracy are validated by a number of numerical tests simulating various engineering scenarios including hydrogen gas pipelines. The trained model can provide dispatchers with suggestions about the number of phases existing during the transportation as an index showing safety while the effects of operation temperature pressure and compositional purity are investigated to suggest the optimized productions.
Converting Sewage Water into H2 Fuel Gas Using Cu/CuO Nanoporous Photocatalytic Electrodes
Feb 2022
Publication
This work reports on H2 fuel generation from sewage water using Cu/CuO nanoporous (NP) electrodes. This is a novel concept for converting contaminated water into H2 fuel. The preparation of Cu/CuO NP was achieved using a simple thermal combustion process of Cu metallic foil at 550 ◦C for 1 h. The Cu/CuO surface consists of island-like structures with an inter-distance of 100 nm. Each island has a highly porous surface with a pore diameter of about 250 nm. X-ray diffraction (XRD) confirmed the formation of monoclinic Cu/CuO NP material with a crystallite size of 89 nm. The prepared Cu/CuO photoelectrode was applied for H2 generation from sewage water achieving an incident to photon conversion efficiency (IPCE) of 14.6%. Further the effects of light intensity and wavelength on the photoelectrode performance were assessed. The current density (Jph) value increased from 2.17 to 4.7 mA·cm−2 upon raising the light power density from 50 to 100 mW·cm−2 . Moreover the enthalpy (∆H*) and entropy (∆S*) values of Cu/CuO electrode were determined as 9.519 KJ mol−1 and 180.4 JK−1 ·mol−1 respectively. The results obtained in the present study are very promising for solving the problem of energy in far regions by converting sewage water to H2 fuel.
Catalytic and Photocatalytic Electrospun Nanofibers for Hydrogen Generation from Ammonia Borane Complex: A Review
Jul 2021
Publication
Hydrogen (H2) is a promising renewable energy source that can replace fossil fuels since it can solve several environmental and economic issues. However the widespread usage of H2 is constrained by its storage and safety issues. Many researchers consider solid materials with an excellent capacity for H2 storage and generation as the solution for most H2-related issues. Among solid materials ammonia borane (abbreviated hereafter as AB) is considered one of the best hydrogen storage materials due to its extraordinary H2 content and small density. However the process must be conducted in the presence of efficient catalysts to obtain a reasonable amount of generated H2. Electrospun nanofibrous catalysts are a new class of efficient catalysts that involves the usage of polymers. Here a comprehensive review of the ceramic-supported electrospun NF catalysts for AB hydrolysis is presented with a special focus on catalytic and photolytic performance and preparation steps. Photocatalytic AB hydrolysis was discussed in detail due to its importance and promising results. AB photocatalytic hydrolysis mechanisms under light were also explained. Electrospun catalysts show excellent activity for AB hydrolysis with good recyclability. Kinetics studies show that the AB hydrolysis reaction is independent of AB concentration and the first-order reaction of NF catalysts.
An Optimization-Based Model for A Hybrid Photovoltaic-Hydrogen Storage System for Agricultural Operations in Saudi Arabia
Apr 2023
Publication
Renewable energy technologies and resources particularly solar photovoltaic systems provide cost-effective and environmentally friendly solutions for meeting the demand for electricity. The design of such systems is a critical task as it has a significant impact on the overall cost of the system. In this paper a mixed-integer linear programming-based model is proposed for designing an integrated photovoltaic-hydrogen renewable energy system to minimize total life costs for one of Saudi Arabia’s most important fields a greenhouse farm. The aim of the proposed system is to determine the number of photovoltaic (PV) modules the amount of hydrogen accumulated over time and the number of hydrogen tanks. In addition binary decision variables are used to describe either-or decisions on hydrogen tank charging and discharging. To solve the developed model an exact approach embedded in the general algebraic modeling System (GAMS) software was utilized. The model was validated using a farm consisting of 20 greenhouses a worker-housing area and a water desalination station with hourly energy demand. The findings revealed that 1094 PV panels and 1554 hydrogen storage tanks are required to meet the farm’s load demand. In addition the results indicated that the annual energy cost is $228234 with a levelized cost of energy (LCOE) of 0.12 $/kWh. On the other hand the proposed model reduced the carbon dioxide emissions to 882 tons per year. These findings demonstrated the viability of integrating an electrolyzer fuel cell and hydrogen tank storage with a renewable energy system; nevertheless the cost of energy produced remains high due to the high capital cost. Moreover the findings indicated that hydrogen technology can be used as an energy storage solution when the production of renewable energy systems is variable as well as in other applications such as the industrial residential and transportation sectors. Furthermore the results revealed the feasibility of employing renewable energy as a source of energy for agricultural operations.
Portable Prototype of Hydrogen Fuel Cells for Educational Training
Jan 2023
Publication
This paper presents an experimental prototype of hydrogen fuel cells suitable for training engineering students. The presented system is designed to teach students the V-I characteristics of the fuel cells and how to record the V-I characteristics curve in the case of a single or multiple fuel cells. The prototype contains a compact electrolyzer to produce hydrogen and oxygen to the fuel cell. The fuel cell generates electricity to supply power to various types of loads. The paper also illustrates how to calculate the efficiency of fuel cells in series and parallel modes of operation. In the series mode of operation it is mathematically proven that the efficiency is higher at lower currents. Still the fuel cell operating area is required where the power is the highest. According to experimental results the efficiency in the case of series connection is approximately 25% while in parallel operation mode the efficiency is about 50%. Thus a parallel connection is recommended in the high current applications because the efficiency is higher than the one resulted from series connection. As explained later in the study plan several other experiments can be performed using this educational kit.
Advances in Hydrogen Production from Natural Gas Reforming
Jun 2021
Publication
Steam natural gas reforming is the preferred technique presently used to produce hydrogen. Proposed in 1932 the technique is very well established but still subjected to perfections. Herein first the improvements being sought in catalysts and processes are reviewed and then the advantage of replacing the energy supply from burning fuels with concentrated solar energy is discussed. It is especially this advance that may drastically reduce the economic and environmental cost of hydrogen production. Steam reforming can be easily integrated into concentrated solar with thermal storage for continuous hydrogen production.
Design and Implementation of an Intelligent Energy Management System for Smart Home Utilizing a Multi-agent System
Jul 2022
Publication
Green Hydrogen Microgrid System has been selected as a source of clean and renewable alternative energy because it is undergoing a global revolution and has been identified as a source of clean energy that may aid the country in achieving net-zero emissions in the coming years. The study proposes an innovative Microgrid Renewable hybrid system to achieve these targets. The proposed hybrid renewable energy system combines a photovoltaic generator (PVG) a fuel cell (FC) a supercapacitor (SC) and a home vehicle power supply (V2H) to provide energy for a predefined demand. The proposed architecture is connected to the grid and is highly dependent on solar energy during peak periods. During the night or shading period it uses FC as a backup power source. The SC assists the FC with high charge power. SC performs this way during load transients or quick load changes. A multi-agent system (MAS) was used to build a real energy management system (RT-HEMS) for intelligent coordination between components (MAS). The scheduling algorithm reduces energy consumption by managing the required automation devices without the need for additional network power. It will meet household energy requirements regardless of weather conditions including bright cloudy or rainy conditions. Implementation and discussion of the RT-HEMS ensures that the GHS is functioning properly and that the charge request is satisfied.
Techno-Economic Evaluation of Hydrogen Production via Gasification of Vacuum Residue Integrated with Dry Methane Reforming
Dec 2021
Publication
The continuous rise of global carbon emissions demands the utilization of fossil fuels in a sustainable way. Owing to various forms of emissions our environment conditions might be affected necessitating more focus of scientists and researchers to upgrade oil processing to more efficient manner. Gasification is a potential technology that can convert fossil fuels to produce clean and environmentally friendly hydrogen fuel in an economical manner. Therefore this study analyzed and examined it critically. In this study two different routes for the production of high-purity hydrogen from vacuum residue while minimizing the carbon emissions were proposed. The first route (Case I) studied the gasification of heavy vacuum residue (VR) in series with dry methane reforming (DMR). The second route studied the gasification of VR in parallel integration with DMR (Case II). After investigating both processes a brief comparison was made between the two routes of hydrogen production in terms of their CO2 emissions energy efficiency energy consumption and environmental and economic impacts. In this study the two vacuum-residue-to-hydrogen (VRTH) processes were simulated using Aspen Plus for a hydrogen production capacity of 50 t/h with 99.9 wt.% purity. The results showed that Case II offered a process energy efficiency of 57.8% which was slightly higher than that of Case I. The unit cost of the hydrogen product for Case II was USD 15.95 per metric ton of hydrogen which was almost 9% lower than that of Case I. In terms of the environmental analysis both cases had comparably low carbon emissions of around 8.3 kg of CO2/kg of hydrogen produced; with such high purity the hydrogen could be used for production of other products further downstream or for industrial applications.
Hydrogen Production Methods Based on Solar and Wind Energy: A Review
Jan 2023
Publication
Several research works have investigated the direct supply of renewable electricity to electrolysis particularly from photovoltaic (PV) and wind generator (WG) systems. Hydrogen (H2 ) production based on solar energy is considered to be the newest solution for sustainable energy. Different technologies based on solar energy which allow hydrogen production are presented to study their benefits and inconveniences. The technology of water decomposition based on renewable energy sources to produce hydrogen can be achieved by different processes (photochemical systems; photocatalysis systems photo-electrolysis systems bio-photolysis systems thermolysis systems thermochemical cycles steam electrolysis hybrid processes and concentrated solar energy systems). A comparison of the different methods for hydrogen production based on PV and WG systems was given in this study. A comparative study of different types of electrolyzers was also presented and discussed. Finally an economic assessment of green hydrogen production is given. The hydrogen production cost depends on several factors such as renewable energy sources electrolysis type weather conditions installation cost and the productivity of hydrogen per day. PV/H2 and wind/H2 systems are both suitable in remote and arid areas. Minimum maintenance is required and a power cycle is not needed to produce electricity. The concentrated CSP/H2 system needs a power cycle. The hydrogen production cost is higher if using wind/H2 rather than PV/H2 . The green energy sources are useful for multiple applications such as hydrogen production cooling systems heating and water desalination.
Optimal Energy Management for Hydrogen Economy in a Hybrid Electric Vehicle
Feb 2023
Publication
Fuel cell hybrid electric vehicles (FCEVs) are mainly electrified by the fuel cell (FC) system. As a supplementary power source a battery or supercapacitor (SC) is employed (besides the FC) to enhance the power response due to the slow dynamics of the FC. Indeed the performance of the hybrid power system mainly depends on the required power distribution manner among the sources which is managed by the energy management strategy (EMS). This paper considers an FCEV based on the proton exchange membrane FC (PEMFC)/battery/SC. The energy management strategy is designed to ensure optimum power distribution between the sources considering hydrogen consumption. Its main objective is to meet the electric motor’s required power with economic hydrogen consumption and better electrical efficiency. The proposed EMS combines the external energy maximization strategy (EEMS) and the bald eagle search algorithm (BES). Simulation tests for the Extra-Urban Driving Cycle (EUDC) and New European Driving Cycle (NEDC) profiles were performed. The test is supposed to be performed in typical conditions t = 25 ◦C on a flat road without no wind effect. In addition this strategy was compared with the state machine control strategy classic PI and equivalent consumption minimization strategy. In terms of optimization the proposed approach was compared with the original EEMS particle swarm optimization (PSO)-based EEMS and equilibrium optimizer (EO)-based EEMS. The results confirm the ability of the proposed strategy to reduce fuel consumption and enhance system efficiency. This strategy provides 26.36% for NEDC and 11.35% for EUDC fuel-saving and efficiency enhancement by 6.74% for NEDC and 36.19% for EUDC.
Wettability of Shale–brine–H2 System and H2-brine Interfacial Tension for Assessment of the Sealing Capacities of Shale Formations During Underground Hydrogen Storage
Jul 2022
Publication
Replacement of fossil fuels with clean hydrogen has been recognized as the most feasible approach of implementing CO2-free hydrogen economy globally. However large-scale storage of hydrogen is a critical component of hydrogen economy value chain because hydrogen is the lightest molecule and has moderately low volumetric energy content. To achieve successful storage of buoyant hydrogen at the subsurface and convenient withdrawal during the period of critical energy demand the integrity of the underground storage rock and overlying seal (caprock) must be assured. Presently there is paucity of information on hydrogen wettability of shale and the interfacial properties of H2/brine system. In this research contact angles of shale/H2/brine system and hydrogen/brine interfacial tension (IFT) were measured using Krüss drop shape analyzer (DSA 100) at 50 ◦C and varying pressure (14.7–1000 psi). A modified form of sessile drop approach was used for the contact angles measurement whereas the H2- brine IFT was measured through the pendant drop method. H2-brine IFT values decreased slightly with increasing pressure ranging between 63.68◦ at 14.7 psia and 51.29◦ at 1000 psia. The Eagle-ford shale with moderate total organic carbon (TOC) of 3.83% attained fully hydrogen-wet (contact angle of 99.9◦ ) and intermediate-wet condition (contact angle of 89.7◦ ) at 14.7 psi and 200 psi respectively. Likewise the Wolf-camp shale with low TOC (0.30%) attained weakly water-wet conditions with contact angles of 58.8◦ and 62.9◦ at 14.7 psi and 200 psi respectively. The maximum height of hydrogen that can be securely trapped by the Wolf-camp shale was approximately 325 meters whereas the value was merely 100 meters for the Eagle-ford shale. Results of this study will aid in assessment of hydrogen storage capacity of organic-rich shale (adsorption trapping) as well as evaluation of the sealing potentials of low TOC shale (caprock) during underground hydrogen storage.
Maximizing Green Hydrogen Production from Water Electrocatalysis: Modeling and Optimization
Mar 2023
Publication
The use of green hydrogen as a fuel source for marine applications has the potential to significantly reduce the carbon footprint of the industry. The development of a sustainable and cost-effective method for producing green hydrogen has gained a lot of attention. Water electrolysis is the best and most environmentally friendly method for producing green hydrogen-based renewable energy. Therefore identifying the ideal operating parameters of the water electrolysis process is critical to hydrogen production. Three controlling factors must be appropriately identified to boost hydrogen generation namely electrolysis time (min) electric voltage (V) and catalyst amount (µg). The proposed methodology contains the following two phases: modeling and optimization. Initially a robust model of the water electrolysis process in terms of controlling factors was established using an adaptive neuro-fuzzy inference system (ANFIS) based on the experimental dataset. After that a modern pelican optimization algorithm (POA) was employed to identify the ideal parameters of electrolysis duration electric voltage and catalyst amount to enhance hydrogen production. Compared to the measured datasets and response surface methodology (RSM) the integration of ANFIS and POA improved the generated hydrogen by around 1.3% and 1.7% respectively. Overall this study highlights the potential of ANFIS modeling and optimal parameter identification in optimizing the performance of solar-powered water electrocatalysis systems for green hydrogen production in marine applications. This research could pave the way for the more widespread adoption of this technology in the marine industry which would help to reduce the industry’s carbon footprint and promote sustainability.
Industrial Waste Gases as a Resource for Sustainable Hydrogen Production: Resource Availability, Production Potential, Challenges, and Prospects
May 2024
Publication
Industrial sectors pivotal for the economic prosperity of nations rely heavily on affordable reliable and environmentally friendly energy sources. Industries like iron and steel oil refineries and coal-fired power plants while instrumental to national economies are also the most significant contributors to waste gases that contain substantial volumes of carbon monoxide (CO). CO can be converted to a highly efficient and carbon free fuel hydrogen (H2) through a well-known water gas shift reaction. However the untapped potential of H2 from waste industrial streams is yet to be explored. This is the first article that investigates the potential of H2 production from industrial waste gases. The available resource (i.e. CO) and its H2 production potential are estimated. The article also provides insights into the principal challenges and potential avenues for long-term adoption. The results showed that 249.14 MTPY of CO are available to produce 17.44 MTPY of H2 annually. This suggests a significant potential for H2 production from waste gases to revolutionize industrial waste management and contribute significantly towards Sustainable Development Goals 7 9 and 13ensuring access to affordable reliable sustainable and modern energy for all and taking decisive climate action respectively.
A Review of Hydrogen Production and Supply Chain Modeling and Optmization
Jan 2023
Publication
This paper reviews recent optimization models for hydrogen supply chains and production. Optimization is a central component of systematic methodologies to support hydrogen expansion. Hydrogen production is expected to evolve in the coming years to help replace fossil fuels; these high expectations arise from the potential to produce low-carbon hydrogen via electrolysis using electricity generated by renewable sources. However hydrogen is currently mainly used in refinery and industrial operations; therefore physical infrastructures for transmission distribution integration with other energy systems and efficient hydrogen production processes are lacking. Given the potential of hydrogen the greenfield state of infrastructures and the variability of renewable sources systematic methodologies are needed to reach competitive hydrogen prices and design hydrogen supply chains. Future research topics are identified: 1) improved hydrogen demand projections 2) integrated sector modeling 3) improving temporal and spatial resolutions 4) accounting for climate change 5) new methods to address sophisticated models.
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