Saudi Arabia
Numerical Investigation of Combustion, Performance, and Emission Attributes of Premixed Ammonia-hydrogen/air Flames within a Swirl Burners of a Gas Turbine
Oct 2025
Publication
This study investigates numerically combustion attributes and NOx formation of premixed ammonia-hydrogen/air flames within a swirl burner of a gas turbine considering various conditions of hydrogen fraction (HF: 0 % 5 % 30 % 40 % and 50 %) equivalence ratio (φ: 0.85 1.0 and 1.2) and mixture inlet temperature (Tin: 400–600 K). The results illustrate that flame temperature increases with hydrogen addition from 1958 K for pure ammonia to 2253 K at 50 % HF. Raising the inlet temperature from 400 K to 600 K markedly enhances combustion intensity resulting in an increase of the Damköhler number (Da) from 117 to 287. NOx levels rise from ∼1800 ppm (0 % HF) to ∼7500 ppm (50 % HF) and peak at 8243 ppm under lean conditions (φ = 0.85). Individual NO N2O and NO2 emissions also reach maxima at φ = 0.85 with values of 5870 ppm 2364 ppm and 10 ppm respectively decreasing significantly under richer conditions (2547 ppm 1245 ppm and 5 ppm at φ = 1.2). These results contribute to advancing low-carbon fuel technologies and highlight the viability of ammonia-hydrogen co-firing as a pathway toward sustainable gas turbine operation.
Hybrid Wind–Solar–Fuel Cell–Battery Power System with PI Control for Low-Emission Marine Vessels in Saudi Arabia
Nov 2025
Publication
The maritime industry is under increasing pressure to reduce greenhouse gas emissions especially in countries such as Saudi Arabia that are actively working to transition to cleaner energy. In this paper a new hybrid shipboard power system which incorporates wind turbines solar photovoltaic (PV) panels proton-exchange membrane fuel cells (PEMFCs) and a battery energy storage system (BESS) together for propulsion and hotel load services is proposed. A multi-loop Energy Management System (EMS) based on proportional–integral control (PI) is developed to coordinate the interconnections of the power sources in real time. In contrast to the widely reported model predictive or artificial intelligence optimization schemes the PI-derived EMS achieves similar power stability and hydrogen utilization efficiency with significantly reduced computational overhead and full marine suitability. By taking advantage of the high solar irradiance and coastal wind resources in Saudi Arabia the proposed configuration provides continuous near-zeroemission operation. Simulation results show that the PEMFC accounts for about 90% of the total energy demand the BESS (±0.4 MW 2 MWh) accounts for about 3% and the stationary renewables account for about 7% which reduces the demand for hydro-gas to about 160 kg. The DC-bus voltage is kept within ±5% of its nominal value of 750 V and the battery state of charge (SOC) is kept within 20% to 80%. Sensitivity analyses show that by varying renewable input by ±20% diesel consumption is ±5%. These results demonstrate the system’s ability to meet International Maritime Organization (IMO) emission targets by delivering stable near-zero-emission operation while achieving high hydrogen efficiency and grid stability with minimal computational cost. Consequently the proposed system presents a realistic certifiable and regionally optimized roadmap for next-generation hybrid PEMFC–battery–renewable marine power systems in Saudi Arabian coastal operations.
An Empirical Study of Kingdom of Saudi Arabia Citizens' Intentions about the Adoption of Hydrogen Fuel Cell Vehicles
Oct 2025
Publication
A comprehensive understanding of consumer preferences and demand factors is essential for successfully implementing demand-side strategies for alternative energy solutions such as hydrogen. This study aims to identify the key determinants influencing the adoption propensity for Hydrogen fuel cell vehicles (HFCVs) in the Kingdom of Saudi Arabia (KSA). Developing a conceptual framework to organise the key factors influencing consumers’ decisions to adopt or reject this technology. Using data from an online survey of 384 prospective customers we employed structural equation modelling (SEM) via Smart-PLS 4.1 to analyze consumer intent. The findings reveal that perceived benefits barriers opinions and governmental initiatives have a significant impact on the likelihood of HFCV adoption. The study emphasises the significance of collaborative efforts among key stakeholders including manufacturers hydrogen producers research institutions and financial entities in addressing challenges and advancing the development of the hydrogen transportation ecosystem in KSA. Financial incentives and subsidies such as purchasing subsidies awareness and reduced registration costs for HFCVs may be instituted.
Thermal Energy Integration and Optimization in a Biomass-fueled Multi-generation System for Power, Hydrogen, and Freshwater Production
Nov 2025
Publication
This work investigates a biomass-driven multi-generation system designed for simultaneous power freshwater and hydrogen production addressing the interlinked energy-waterenvironment nexus. The configuration integrates Brayton supercritical carbon dioxide (SCO2) organic Rankine cycle (ORC) and thermoelectric generator (TEG) subsystems to maximize utilization of biomass-derived syngas. The recovered energy drives a reverse osmosis (RO) desalination unit for freshwater production and an alkaline electrolyzer for hydrogen generation followed by two-stage compression for storage. Under baseline conditions the system generates 1.99 MW of electricity 9.38 kg/h of hydrogen and 88.6 m3 /h of freshwater with an overall exergetic efficiency of 20.25 % emissions intensity of 0.85 kg/kWh and a payback period of 5.87 years. The Brayton cycle accounts for 49.3 % of the total cost rate while the gasifier exhibits the highest exergy destruction at 46 %. Sensitivity analyses show that varying biomass moisture content (10–30 %) and operating temperatures (700–900 ◦C) significantly influence system performance. Using a data-driven optimization framework that combines artificial neural networks (ANN) and a genetic algorithm (GA) the system’s exergetic efficiency improves to 21.76 % freshwater output rises to 90.96 m3 /h and emissions intensity decreases to 0.877 kg/kWh. Additionally optimization reduces the total cost rate by 2.71 % leading to a payback period of 5.4 years and enhances the system’s overall performance by 12.64 %.
Circular Bioenergy Pathway for Sustainable Hydrogen Production with Carbon Capture: Technical, Economic & Environmental Assessment
Nov 2025
Publication
The accelerating global demand for hydrogen is pushing for renewable and waste derived hydrogen production processes where date palm waste (DPW) has been identified as an available and unexploited agricultural residue that has the potential to be a sustainable source of hydrogen. The current work focuses on developing and evaluating four different process configurations in terms of energy environment and economics for producing hydrogen from DPW using Aspen Plus® simulation tool. Case 1 represents the standalone DPW gasification with CO₂ capture via methanol absorption Case 2 represents the DPW gasification with CaO-based chemical looping for CO₂ capture Case 3 represents the DPW gasification integrated with steam methane reforming (SMR) and methanol-based CO₂ capture and Case 4 represents the DPW gasification integrated with SMR and CaO-based CO₂ capture. Each case was evaluated in terms of syngas composition hydrogen production lower heating value CO₂ captured utility demand process efficiency and H2 production cost. Hydrogen production ranged from 974.55 t/year (Case 1) and 988.83 t/year (Case 2) to 2032.32 t/year (Case 3) and 2048.61 t/year (Case 4). CO₂ capture was also more effective in Case 4 (16929.49 t/year) compared to Case 1 (7676.30 t/year). Process efficiency improved from 33 % in Case 1 to 47 % in Case 2 and from 32 % in Case 3 to further to 55 % in Case 4. Economically Case 1 offered the highest hydrogen production cost ($5.03/kg) followed by Case 2 ($4.77/kg) while Case 3 and Case 4 achieved significantly lower production costs of $2.89/kg and $2.69/kg respectively.
A Comprehensive Review of Influence of Critical Parameters on Wettability of Rock-hydrogen-brine Systems: Implications for Underground Hydrogen Storage
Oct 2025
Publication
The rock wettability is one of the most critical parameters that influences rock storage potential trapping and H2 withdrawal rate during Underground hydrogen storage (UHS). However the existing review articles on wettability of H2-brine-rock systems do not provide detailed information on complexities introduced by reservoir wettability influencing parameters such as high pressure temperature salinity conditions micro-biotic effects cushion gases and organic acids relevant to subsurface environments. Therefore a comprehensive review of existing research on various parameters influencing rock wettability during UHS and residual trapping of H2 was conducted in this study. Literature that provides insight into molecular-level interaction through machine learning and molecular dynamic (MD) simulations and role of surface-active chemicals such as nanoparticles surfactants and wastewater chemicals were also reviewed. The review suggested that UHS could be feasible in clean geo-storage formations but the presence of rock surface contaminants at higher storage depth and microbial effects should be accounted for to prevent over-estimation of the rock storage potentials. The H2 wettability of storage/caprocks and associated risks of UHS projects could be higher in rocks with high proportion of carbonate minerals organic-rich shale and basalt with high plagioclase minerals content. However treatment of rock surfaces with nanofluids surfactants methylene blue and methyl orange has proven to alter the rock wettability from H2-wet towards water-wet. Research results on effect of rock wettability on residually trapped hydrogen and snap-off effects during UHS are contradictory thus further studies would be required in this area. The review generally concludes that rock wettability plays prominent role on H2 storage due to the frequency and cyclic loading of UHS hence it is vital to evaluate the effects of all possible wettability influencing parameters for successful designs and implementation of UHS projects.
Optical Investigation and combustion Analysis of Stratified Ammonia-hydrogen Pre-chamber Engine with Variable Injection Timing
Oct 2025
Publication
This study presents an experimental investigation of a direct injection ammonia-fuelled engine using hydrogen pre-chamber jet ignition. All tests have been conducted in an optically accessible combustion chamber that is installed in the head of a single-cylinder engine. The effect of ammonia injection timing on ignition and combustion characteristics was investigated with the timing varied from 165 CAD BTDC to 40 CAD BTDC. The experiments were conducted with a fixed spark timing of 14 CAD BTDC while ammonia injection duration was adjusted to maintain a main chamber global equivalence ratio of 0.6. Two pre-chamber nozzle configurations a single-hole and a multi-hole were tested. The results show that the later NH3 injection timing (40 CAD BTDC) significantly improved combustion with a peak in-cylinder pressure of 80 bar measured compared to a peak in-cylinder pressure of 50 bar with earlier injection (165 CAD BTDC). This study indicates the importance of optimising ammonia injection timing in order to enhance combustion stability and efficiency. The hydrogen pre-chamber jet ignition combined with a late ammonia injection is a promising approach for addressing the combustion challenges of ammonia as a zero-carbon fuel for maritime applications.
Production Technology of Blue Hydrogen with Low CO2 Emissions
Oct 2025
Publication
Blue hydrogen technology generated from natural gas through carbon capture and storage (CCS) technology is a promising solution to mitigate greenhouse gas emissions and meet the growing demand for clean energy. To improve the sustainability of blue hydrogen it is crucial to explore alternative feedstocks production methods and improve the efficiency and economics of carbon capture storage and utilization strategies. Two established technologies for hydrogen synthesis are Steam Methane Reforming (SMR) and Autothermal Reforming (ATR). The choice between SMR and ATR depends on project specifics including the infrastructure energy availability environmental goals and economic considerations. ATR-based facilities typically generate hydrogen at a lower cost than SMR-based facilities except in cases where electricity prices are elevated or the facility has reduced capacity. Both SMR and ATR are methods used for hydrogen production from methane but ATR offers an advantage in minimizing CO2 emissions per unit of hydrogen generated due to its enhanced energy efficiency and unique process characteristics. ATR provides enhanced utility and flexibility regarding energy sources due to its autothermal characteristics potentially facilitating integration with renewable energy sources. However SMR is easier to run but may lack flexibility compared to ATR necessitating meticulous management. Capital expenditures for SMR and ATR hydrogen reactors are similar at the lower end of the capacity spectrum but when plant capacity exceeds this threshold the capital costs of SMR-based hydrogen production surpass those of ATR-based facilities. The less profitably scaled-up SMR relative to the ATR reactor contributes to the cost disparity. Additionally individual train capacity constraints for SMR CO2 removal units and PSA units increase the expenses of the SMR-based hydrogen facility significantly.
Economic Hydrogen Production by Water Splitting with Different Catalysts and Temperatures under Thermal and Gamma Radiation-thermal Processes
Nov 2025
Publication
This article describes hydrogen production via water splitting because of high green energy demand globally. The amounts of hydrogen produced with zirconium in thermal processes at 473 K and radiation-thermal processes at 473 K and 773K were 1.55 x 1018 2.2 x 1018 and 4.1 x 1018 molecules/g. These amounts on aluminum and stainless steel were 1.05 x 1018 1.95 x 1018 and 3.0 x 1018 molecules/g; and 0.30 x 1018 1.27 x 1018 and 2.6 x 1018 molecules/g. A comparison was carried out and the order of hydrogen production was zirconium > aluminum > stainless steel. The activation energy in radiation-thermal and thermal processes were 14.2 and 65.0 kJ/mol (Zr) 12.05 and 63.1 kJ/mol (Al) and 11.16 and 61.52 kJ/mol (SS). The mechanisms of water splitting were developed and described for future use. The described methods are scalable and can be transferred to a pilot scale.
Direct Injection Hydrogen Combustion under Leaner Conditions in an Optical Engine using Optical/Laser Diagnostics
Nov 2025
Publication
Hydrogen’s increasing potential as an alternative fuel for heavy-duty transport has led to the conversion of conventional diesel compression-ignition engines to spark-ignition hydrogen operation. Hydrogen’s broad flammability range enables leaner operation achieving both higher engine efficiency and near-zero emissions. In particular direct injection hydrogen combustion improves volumetric efficiency and reduces problems including pre-ignition and knock related to hydrogen port-fuel injection. In the present work we performed an optical investigation of direct injection (DI) hydrogen combustion under leaner mixture conditions. The study was conducted using a heavy-duty optical diesel engine modified for spark-ignition operation. Bottom-view natural flame luminosity and OH-PLIF imaging were conducted along with in-cylinder pressure measurements. Experiments were conducted at three air-excess ratios (3 3.4 and 3.8) with spark timings (ST) varied from − 15 ◦CA aTDC to − 30 ◦CA aTDC. Hydrogen injection ended at − 30 ◦CA aTDC with the start of injection adjusted accordingly to achieve the desired lambda conditions. The maximum IMEPg corresponded to the lowest COV of the IMEPg indicating optimal spark timing for lean DI hydrogen combustion. The optimized spark timing for λ = 3 λ = 3.4 and λ = 3.8 were occurred at − 25 ◦CA aTDC − 25 ◦CA aTDC and − 30 ◦CA aTDC respectively. The corresponding COV of IMEPg values were below 5 % indicating stable combustion. The flame kernel first initiates at the spark plug and then propagates toward the piston’s outer boundary however the flame propagation does not remain as a continuous front unlike port-fuel injected hydrogen combustion. The effect of fuel stratification is evident in combustion luminosity and OH-PLIF images showing pockets of varying intensity within the combustion chamber. Natural flame luminosity images reveal incomplete flame coverage and asymmetric combustion emphasizing the need for metal engine experiments to further quantify the unburned hydrogen and associated combustion losses.
Enhancing Green Hydrogen Forecasting with a Spatio-temporal Graph Convolutional Network Optimized by the Ninja Algorithm
Nov 2025
Publication
In light of increased international efforts to combat climate change sustainable infrastructure is shifting toward green hydrogen produced through renewable-powered electrolysis. Still it is challenging to forecast the production of green hydrogen because environmental and system factors are variable both in time and space. We introduce a new system that utilizes a Spatio-Temporal Graph Convolutional Network (STGCN) and a novel algorithm the Ninja Optimization Algorithm (NiOA) to address this issue. Using the framework binary NiOA performs feature selection while continuous NiOA optimizes both the model architecture and the number of variables in the data simultaneously. It is clear from the research that forecasting results have shown significant improvement. The STGCN model achieved an R2 of 0.8769 and an MSE of 0.00375 whereas the STGCN with NiOA reached an R2 of 0.9815 and an MSE of only 7.48 × 10−8. Due to these improvements adaptive metaheuristics show even greater promise in delivering more accurate forecasting and reduced computational requirements for addressing critical environmental issues. The suggested strategy can be followed repeatedly providing a solid framework for the effective modeling of renewable energy systems and making green hydrogen projects more dependable.
Competition and Equilibrium in Future Global Renewable Hydrogen Trade: A Game-theoretic Analysis
Nov 2025
Publication
Global renewable hydrogen trade is expected to play a key role in decarbonizing future energy systems. Yet hydrogen exporters may deviate from perfectly competitive behaviour to influence prices similarly to the existing fossil fuel market with important implications for consumer welfare and the pace of the energy transition. This study develops a global renewable hydrogen trade model that captures potential strategic interactions among exporters using a Stackelberg game-theoretic framework. The model is formulated as an Equilibrium Problem with Equilibrium Constraints (EPEC) and solved under three alternative equilibria: a profitmaximizing Nash equilibrium a cost-minimizing Nash equilibrium and a welfare-maximizing benchmark representing perfect competition. Results indicate that producers may strategically reduce their export quantities by up to 40 % relative to perfect competition to maximize profits. Such behaviour raises prices to a minimum of 4.5 USD/kg in 2050 across major import markets thereby significantly eroding consumer surplus. Strategic behaviour of dominant exporters also shifts trade flows reshaping the global allocation of hydrogen supply. Sensitivity analysis further reveals that financing costs play a key role in shaping strategic producers’ behaviour with lower financing costs helping to reduce prices and stimulate demand. These findings highlight the implications of imperfect competition in global hydrogen trade and suggest that policy measures may be needed to mitigate potential negative consequences.
Heat Recovery Unit Integrated with Biomass Gasification for Producing Hydrogen/Power/Heat Using a Novel Cascaded ORC with Biphenyl/Diphenyl Oxide Mixture; ML Optimsation and Economic Evaluation
Nov 2025
Publication
This work provides a detailed evaluation of a novel biomass-fueled multigeneration system conceived to contribute to the growing emphasis on sustainable energy solutions. The architecture comprises a biomass gasifier an innovative cascaded organic Rankine cycle (CORC) incorporating a high-temperature mixture in the top cycle a proton exchange membrane electrolyzer (PEME) a Brayton cycle and waste heat utilization units all operating together to deliver electricity hydrogen (H2) and thermal output. A comprehensive thermodynamic modeling framework is established to evaluate the system’s performance across various operational scenarios. The framework emphasizes critical metrics including exergy efficiency levelized total emissions (LTE) and payback period (PP). These indicators ensure a holistic assessment of energy exergy economic and environmental considerations. Parametric studies demonstrate that enhancements in biomass mass flow rate and combustion chamber temperature significantly increase power output and H2 production while reducing the payback period underscoring the system’s flexibility and economic feasibility. Furthermore the study employs sophisticated machine learning optimization methods combining artificial neural networks (ANNs) with genetic algorithms (GA) to determine optimal operating conditions with minimal computational effort and maximum efficiency. When evaluated at nominal parameters the system records an exergy efficiency of 23.72 % achieves a PP of 5.61 years and yields an LTE value of 0.34 ton/GJ. However under optimized conditions these values improve to 35.01 % 3.78 years and 0.241 ton/GJ respectively.
State and Disturbance Estimation with Supertwisting Sliding Mode Control for Frequency Regulation in Hydrogen Based Microgrids
Nov 2025
Publication
This study considers the use of an enhanced super-twisting sliding mode control (STSMC) scheme via the incorporation of a hybrid extended state observer (ESO) and a higher order sliding mode observer (HOSMO) state estimation and disturbance observer (DO) based on exponential decay embedded via a tracking element in order to hasten the estimation of disturbance thus improving performance significantly. This scheme is employed to generate single and multiple control signals per agent based on the microgrid’s presented components such as energy storage devices and renewable energy sources (RESs) alongside the harness of a puma optimizer (PO) metaheuristics scheme to optimize each area regulator’s performance. The sliding surface incorporated is chosen based on desired control objectives. Adjusting the constricted area frequency and reducing tie-line power transfer fluctuations are considered the primary goals for frequency regulation in a multi-area power system. Also based on the presented simulations adequate performance in terms of minimum chattering low complexity fast convergence and adequate robustness has been achieved. Using various microgrid peripheral components such as a multi-terminal soft open point (SOP) with a dedicated terminal for hydrogen energy storage alongside the proposed enhanced STSMC the frequency change and power transfer rate of change are maintained within the range of ×10−6 values substantially preserving proper performance compared to other simulated scenarios. In regard to the final simulated case involving SOP the following has been achieved: steady state errors of 2.538×10−6 Hz for ΔF1 3.125×10−6 Hz for ΔF2 and 1.920×10−6 p.u for ΔPtie alongside peak disturbance overshoot reduction in comparison to stochastic case of 99.580% 99.605% and 99.771% for same mentioned elements respectively. Also a reduction in peak disturbance undershoot of 95.589% 99.547% and 99.573% respectively has been achieved. Thus the enhanced STSMC can effectively mitigate frequency fluctuations and tie-line power transfer abnormalities.
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