South Africa
Failure of PEM Water Electrolysis Cells: Case Study Involving Anode Dissolution and Membrane Thinning
Sep 2013
Publication
Polymer electrolyte membrane (PEM) water electrolysis is an efficient and environmental friendly method that can be used for the production of molecular hydrogen of electrolytic grade using zero-carbon power sources such as renewable and nuclear. However market applications are asking for cost reduction and performances improvement. This can be achieved by increasing operating current density and lifetime of operation. Concerning performance safety reliability and durability issues the membrane-electrode assembly (MEA) is the weakest cell component. Most performance losses and most accidents occurring during PEM water electrolysis are usually due to the MEA. The purpose of this communication is to report on some specific degradation mechanisms that have been identified as a potential source of performance loss and membrane failure. An accelerated degradation test has been performed on a MEA by applying galvanostatic pulses. Platinum has been used as electrocatalyst at both anode and cathode in order to accelerate degradation rate by maintaining higher cell voltage and higher anodic potential that otherwise would have occurred if conventional Ir/IrOx catalysts had been used. Experimental evidence of degradation mechanisms have been obtained by post-mortem analysis of the MEA using microscopy and chemical analysis. Details of these degradation processes are presented and discussed.
Testing, Evaluation and Development of Hydrogen Sensors for an Underground Mining Ventilation Test Facility
Sep 2019
Publication
An underground mining ventilation testing facility (VTF) was designed and constructed at the HySA facility at the North-West University South Africa. The purpose was to evaluate risks associated with different hydrogen storage technologies in a confined environment. The work included initial calculations of hydrogen movement in specific spaces and the development of simulation tools to compare these modelled results with experimental work. For this purpose hydrogen sensors that could accurately measure hydrogen concentrations during a controlled hydrogen leak at the VTF were required. Hazardous hydrogen sensors capable of measuring >4% hydrogen are not readily available commercially. Typically hydrogen sensors rated for hazardous environments are designed for safety actions (e.g. activating emergency measures when hydrogen is detected) at concentrations of 8%. (Measuring concentrations higher than this is not required for commercial use hence there is no market for such sensors.) At the VTF it is necessary to be able to measure hydrogen concentrations >4% in order to obtain information on the flammable hydrogen concentrations at specified distances and orientations around a controlled hydrogen leak. Initial experimental work was conducted at low pressures resulting in very low hydrogen concentrations. Commercial available original equipment manufacturer (OEM) hydrogen sensors were capable of measuring 0.2% hydrogen which for the low pressures and gas flows here proved sufficient to enable us to make sensible conclusions. However higher pressures and gas flows are essential in practical use hence higher concentrations of hydrogen need to be measured. A custom sensor was developed by HySA while commercial sensors (OEM) were investigated. This work reports on the testing and evaluation of several hydrogen sensors. Results of initial ventilation tests are presented.
Hydrogen Ventilation Test Facility or Underground Mining and Tunneling
Sep 2019
Publication
One of the focus areas in the heavy-duty transport industry globally is de-carbonization of trucks dozers shovels semi-trucks buses etc. Hydrogen fuel cells (FCs) technology is one considered solution for the industry due to its zero-emissions its MW scalability and capacity to store large amounts of energy for long duration continuous power operation. Underground deep mines is another option for deployment and operation of hydrogen FCs. Benefits include lower emissions improved health comfort and safety as well as reduced operating costs. Underground mining trucks loaders and other machines have power ratings up to 750 kW which proves difficult for battery and tethered electric energy. Hydrogen FCs have the ability to overcome these power and energy storage limitations. The risks and technologies associated with delivering storing and using hydrogen underground first need to be investigated and proven safe. This work presents the design construction and operation of a mining ventilation test facility (VTF) at the North-West University in South Africa that aims to quantify the risk of hydrogen in confined ventilated environments. Initial work has been conducted on measuring concentrations of hydrogen released in the temporary ventilation site and is discussed.
Effects of CO2 sequestration on lipid and biomass productivity in microalgal biomass production
Mar 2017
Publication
The study is focused on the technology and manipulation of production strategies for the cultivation of biomass from four strains of microalgae. Species of microalgae studied are: Chlorella vulgaris Dunaliella Scenedesmus quadricauda and Synechococcus spp. The effects of the rate and amount of CO2 removal from the atmosphere and sequestration with dissolved oxygen on lipid production from accumulated biomass were studied. Also the rate of sequestration of both total and dissolved carbon was investigated. Daily measurements of total organic and inorganic carbon sequestrated optical densities proximate analysis and kinetic parameters of the growing and cultivated microalga were monitored and carried out during the two phases of cultivation: dark and light phases. The values of maximum rate of carbon (IV) oxide removed rmax varied from 11.73 mg L -1 min -1 to 18.84 mg L -1 min -1 from Chlorella vulgaris to Synechoccocus spp. Important parameters such as biomass productivity maximum pH values obtained at cultivation lipid content of the produced biomass and the hydraulic detection time for all four strains of microalgae were considered and presented in comparison and with their individual and collective effects. The ratios of the rate of CO2 absorption constant and the constant for the CO2 desorption rate (k1/k2) occurred highest in Dunaliella suggesting that with a high uptake of CO2 the algal strain is more effective in CO2 CO2 sequestration. The best biomass producer in this study was the C. vulgaris (Xmax = 5400 mg L-1 and Px = 35.1 mg L h -1) where biomass productivity is Px and the maximum cellular concentration is Xmax. C. vulgaris has the highest lipids productivity of 27% while Synechoccocus has the least (11.72%). In general biomass productivity may be inversely related; this fact may be explained by greater metabolic involvement of lipid biosynthesis. This pioneer study may be advanced further to developing models for strategic manipulation and optimisation approach in micro algal biomass cultivation.
HYDRIDE4MOBILITY: An EU HORIZON 2020 Project on Hydrogen Powered Fuel Cell Utility Vehicles Using Metal Hydrides in Hydrogen Storage and Refuelling Systems
Feb 2021
Publication
Volodymyr A. Yartys,
Mykhaylo V. Lototskyy,
Vladimir Linkov,
Sivakumar Pasupathi,
Moegamat Wafeeq Davids,
Gojmir Radica,
Roman V. Denys,
Jon Eriksen,
José Bellosta von Colbe,
Klaus Taube,
Giovanni Capurso,
Martin Dornheim,
Fahmida Smith,
Delisile Mathebula,
Dana Swanepoel,
Suwarno Suwarno and
Ivan Tolj
The goal of the EU Horizon 2020 RISE project 778307 “Hydrogen fuelled utility vehicles and their support systems utilising metal hydrides” (HYDRIDE4MOBILITY) is in addressing critical issues towards a commercial implementation of hydrogen powered forklifts using metal hydride (MH) based hydrogen storage and PEM fuel cells together with the systems for their refuelling at industrial customers facilities. For these applications high specific weight of the metallic hydrides has an added value as it allows counterbalancing of a vehicle with no extra cost. Improving the rates of H2 charge/discharge in MH on the materials and system level simplification of the design and reducing the system cost together with improvement of the efficiency of system “MH store-FC” is in the focus of this work as a joint effort of consortium uniting academic teams and industrial partners from two EU and associated countries Member States (Norway Germany Croatia) and two partner countries (South Africa and Indonesia).<br/>The work within the project is focused on the validation of various efficient and cost-competitive solutions including (i) advanced MH materials for hydrogen storage and compression (ii) advanced MH containers characterised by improved charge-discharge dynamic performance and ability to be mass produced (iii) integrated hydrogen storage and compression/refuelling systems which are developed and tested together with PEM fuel cells during the collaborative efforts of the consortium.<br/>This article gives an overview of HYDRIDE4MOBILITY project focused on the results generated during its first phase (2017–2019).
Research and Development of Hydrogen Carrier Based Solutions for Hydrogen Compression and Storage
Aug 2022
Publication
Martin Dornheim,
Lars Baetcke,
Etsuo Akiba,
Jose-Ramón Ares,
Tom Autrey,
Jussara Barale,
Marcello Baricco,
Kriston Brooks,
Nikolaos Chalkiadakis,
Véronique Charbonnier,
Steven Christensen,
José Bellosta von Colbe,
Mattia Costamagna,
Erika Michela Dematteis,
Jose-Francisco Fernández,
Thomas Gennett,
David Grant,
Tae Wook Heo,
Michael Hirscher,
Katherine Hurst,
Mykhaylo V. Lototskyy,
Oliver Metz,
Paola Rizzi,
Kouji Sakaki,
Sabrina Sartori,
Emmanuel Stamatakis,
Alastair D. Stuart,
Athanasios Stubos,
Gavin Walker,
Colin Webb,
Brandon Wood,
Volodymyr A. Yartys and
Emmanuel Zoulias
Industrial and public interest in hydrogen technologies has risen strongly recently as hydrogen is the ideal means for medium to long term energy storage transport and usage in combination with renewable and green energy supply. In a future energy system the production storage and usage of green hydrogen is a key technology. Hydrogen is and will in future be even more used for industrial production processes as a reduction agent or for the production of synthetic hydrocarbons especially in the chemical industry and in refineries. Under certain conditions material based systems for hydrogen storage and compression offer advantages over the classical systems based on gaseous or liquid hydrogen. This includes in particular lower maintenance costs higher reliability and safety. Hydrogen storage is possible at pressures and temperatures much closer to ambient conditions. Hydrogen compression is possible without any moving parts and only by using waste heat. In this paper we summarize the newest developments of hydrogen carriers for storage and compression and in addition give an overview of the different research activities in this field.
Metal Hydride Hydrogen Compressors
Feb 2014
Publication
Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine – the metal hydride material itself – should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage hydrogen sorption kinetics and effective thermal conductivity) the thermodynamics of the metal–hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimised to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors reduction of slope of the isotherms and hysteresis increase of cycling stability and life time together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation.<br/>The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal–hydrogen systems suitable for the hydrogen compression; and (b) applied aspects including their consideration from the applied thermodynamic viewpoint system design features and performances of the metal hydride compressors and major applications.
Materials for Hydrogen-based Energy Storage - Past, Recent Progress and Future Outlook
Dec 2019
Publication
Michael Hirscher,
Volodymyr A. Yartys,
Marcello Baricco,
José Bellosta von Colbe,
Didier Blanchard,
Robert C. Bowman Jr.,
Darren P. Broom,
Craig Buckley,
Fei Chang,
Ping Chen,
Young Whan Cho,
Jean-Claude Crivello,
Fermin Cuevas,
William I. F. David,
Petra E. de Jongh,
Roman V. Denys,
Martin Dornheim,
Michael Felderhoff,
Yaroslav Filinchuk,
George E. Froudakis,
David M. Grant,
Evan MacA. Gray,
Bjørn Christian Hauback,
Teng He,
Terry D. Humphries,
Torben R. Jensen,
Sangryun Kim,
Yoshitsugu Kojima,
Michel Latroche,
Hai-wen Li,
Mykhaylo V. Lototskyy,
Joshua W. Makepeace,
Kasper T. Møller,
Lubna Naheed,
Peter Ngene,
Dag Noreus,
Magnus Moe Nygård,
Shin-ichi Orimo,
Mark Paskevicius,
Luca Pasquini,
Dorthe B. Ravnsbæk,
M. Veronica Sofianos,
Terrence J. Udovic,
Tejs Vegge,
Gavin Walker,
Colin Webb,
Claudia Weidenthaler and
Claudia Zlotea
Globally the accelerating use of renewable energy sources enabled by increased efficiencies and reduced costs and driven by the need to mitigate the effects of climate change has significantly increased research in the areas of renewable energy production storage distribution and end-use. Central to this discussion is the use of hydrogen as a clean efficient energy vector for energy storage. This review by experts of Task 32 “Hydrogen-based Energy Storage” of the International Energy Agency Hydrogen TCP reports on the development over the last 6 years of hydrogen storage materials methods and techniques including electrochemical and thermal storage systems. An overview is given on the background to the various methods the current state of development and the future prospects. The following areas are covered; porous materials liquid hydrogen carriers complex hydrides intermetallic hydrides electro-chemical storage of energy thermal energy storage hydrogen energy systems and an outlook is presented for future prospects and research on hydrogen-based energy storage
Effect of a Ripple Current on the Efficiency of a PEM Electrolyser
Mar 2021
Publication
The aim of this study was to determine how the efficiency of a proton exchange membrane (PEM) electrolyser is affected by an electric ripple current and the different characteristics of the ripple current (frequency amplitude and waveform). This paper presents the experimental method and measured results used to analyse the effect of ripple currents at various frequencies ripple factors and waveforms on the hydrogen production power consumption and efficiency of a PEM electrolyser. An active laboratory-size PEM electrolysis system was used to investigate the impact of various ripple currents on the efficiency of the system. The results revealed that the average power consumption increases as the ripple factor increases and decreases as the frequency of the ripple increases while the waveform of the applied current has no effect. Furthermore the average hydrogen flow rate is unaffected by the ripple factor frequency or waveform of the applied ripple current.
From Biogas to Hydrogen: A Techno-Economic Study on the Production of Turquoise Hydrogen and Solid Carbons
Sep 2022
Publication
Biogas is a renewable feedstock that can be used to produce hydrogen through the decomposition of biomethane. However the economics of the process are not well studied and understood especially in cases where solid carbons are also produced and which have a detrimental effect on the performance of the catalysts. The scale as well as product diversification of a biogas plant to produce hydrogen and other value-added carbons plays a crucial role in determining the feasibility of biogasto-hydrogen projects. Through a techno-economic study using the discounted cash flow method it has been shown that there are no feasible sizes of plants that can produce hydrogen at the target price of USD 3/kg or lower. However for self-funded anaerobic digestor plants retrofitting modular units for hydrogen production would only make financial sense at biogas production capacities of more than 412 m3/h. A sensitivity analysis has also shown that the cost competitiveness is dependent on the type of carbon formed and low-grade carbon black has a negative effect on economic feasibility. Hydrogen produced from biogas would thus not be able to compete with grey hydrogen production but rather with current green hydrogen production costs.
Challenges in Hydrogen RCS’ Stakeholder Engagement in South Africa
Sep 2019
Publication
There is a great deal of knowledge and experience on the safe handling of hydrogen and the safe operation and management of hydrogen systems in South Africa. This knowledge and experience mostly sits within large gas supply companies and other large producers and consumers of hydrogen. However there appears to be less experience leading to a level of discomfort within regulatory bodies such as provincial and municipal fire departments and the national standards association. This compounded by a national policy of disallowing gas cylinders indoors has resulted in delays and indeed stalling in the process of obtaining permission to operate laboratories such as those of the national hydrogen programme HySA. In an effort to break this impasse two workshops were organised by HySA. The first was held at the CSIR’s facilities in Pretoria in October 2016. The second was held at the campus of the University of the Western Cape in Cape Town in May 2018. Four international experts and local experts in hydrogen regulations codes standards and safety addressed the 50-strong South African audiences via 5-way videoconferencing. This proved to be a very powerful tool to educate the audience and in particular the Tshwane (Pretoria) and Western Cape Fire Departments on the real issues risks and safety of hydrogen. The paper describes the South African Hydrogen RCS landscape the organisation and running of the workshops and the outputs achieved.
The Use of Metal Hydrides in Fuel Cell Applications
Feb 2017
Publication
This paper reviews state-of-the-art developments in hydrogen energy systems which integrate fuel cells with metal hydride-based hydrogen storage. The 187 reference papers included in this review provide an overview of all major publications in the field as well as recent work by several of the authors of the review. The review contains four parts. The first part gives an overview of the existing types of fuel cells and outlines the potential of using metal hydride stores as a source of hydrogen fuel. The second part of the review considers the suitability and optimisation of different metal hydrides based on their energy efficient thermal integration with fuel cells. The performances of metal hydrides are considered from the viewpoint of the reversible heat driven interaction of the metal hydrides with gaseous H2. Efficiencies of hydrogen and heat exchange in hydrogen stores to control H2 charge/discharge flow rates are the focus of the third section of the review and are considered together with metal hydride – fuel cell system integration issues and the corresponding engineering solutions. Finally the last section of the review describes specific hydrogen-fuelled systems presented in the available reference data.
An Overview of the Classification, Production and Utilization of Biofuels for Internal Combustion Engine Applications
Sep 2021
Publication
Biofuel a cost-effective safe and environmentally benign fuel produced from renewable sources has been accepted as a sustainable replacement and a panacea for the damaging effects of the exploration for and consumption of fossil-based fuels. The current work examines the classification generation and utilization of biofuels particularly in internal combustion engine (ICE) applications. Biofuels are classified according to their physical state technology maturity the generation of feedstock and the generation of products. The methods of production and the advantages of the application of biogas bioalcohol and hydrogen in spark ignition engines as well as biodiesel Fischer– Tropsch fuel and dimethyl ether in compression ignition engines in terms of engine performance and emission are highlighted. The generation of biofuels from waste helps in waste minimization proper waste disposal and sanitation. The utilization of biofuels in ICEs improves engine performance and mitigates the emission of poisonous gases. There is a need for appropriate policy frameworks to promote commercial production and seamless deployment of these biofuels for transportation applications with a view to guaranteeing energy security.
Can Africa Serve Europe with Hydrogen Energy from Its Renewables?—Assessing the Economics of Shipping Hydrogen and Hydrogen Carriers to Europe from Different Parts of the Continent
Apr 2023
Publication
There exists no single optimal way for transporting hydrogen and other hydrogen carriers from one port to the other globally. Its delivery depends on several factors such as the quantity distance economics and the availability of the required infrastructure for its transportation. Europe has a strategy to invest in the production of green hydrogen in Africa to meet its needs. This study assessed the economic viability of shipping liquefied hydrogen (LH2 ) and hydrogen carriers to Germany from six African countries that have been identified as countries with great potential in the production of hydrogen. The results obtained suggest that the shipping of LH2 to Europe (Germany) will cost between 0.47 and 1.55 USD/kg H2 depending on the distance of travel for the ship. Similarly the transportation of hydrogen carriers could range from 0.19 to 0.55 USD/kg H2 for ammonia 0.25 to 0.77 USD/kg H2 for LNG 0.24 to 0.73 USD/kg H2 for methanol and 0.43 to 1.28 USD/kg H2 for liquid organic hydrogen carriers (LOHCs). Ammonia was found to be the ideal hydrogen carrier since it recorded the least transportation cost. A sensitivity analysis conducted indicates that an increase in the economic life by 5 years could averagely decrease the cost of LNG by some 13.9% NH3 by 13.2% methanol by 7.9% LOHC by 8.03% and LH2 by 12.41% under a constant distance of 6470 nautical miles. The study concludes with a suggestion that if both foreign and local participation in the development of the hydrogen market is increased in Africa the continent could supply LH2 and other hydrogen carriers to Europe at a cheaper price using clean fuel.
Magnesium Based Materials for Hydrogen Based Energy Storage: Past, Present and Future
Jan 2019
Publication
Volodymyr A. Yartys,
Mykhaylo V. Lototskyy,
Etsuo Akiba,
Rene Albert,
V. E. Antonov,
Jose-Ramón Ares,
Marcello Baricco,
Natacha Bourgeois,
Craig Buckley,
José Bellosta von Colbe,
Jean-Claude Crivello,
Fermin Cuevas,
Roman V. Denys,
Martin Dornheim,
Michael Felderhoff,
David M. Grant,
Bjørn Christian Hauback,
Terry D. Humphries,
Isaac Jacob,
Petra E. de Jongh,
Jean-Marc Joubert,
Mikhail A. Kuzovnikov,
Michel Latroche,
Mark Paskevicius,
Luca Pasquini,
L. Popilevsky,
Vladimir M. Skripnyuk,
Eugene I. Rabkin,
M. Veronica Sofianos,
Alastair D. Stuart,
Gavin Walker,
Hui Wang,
Colin Webb,
Min Zhu and
Torben R. Jensen
Magnesium hydride owns the largest share of publications on solid materials for hydrogen storage. The “Magnesium group” of international experts contributing to IEA Task 32 “Hydrogen Based Energy Storage” recently published two review papers presenting the activities of the group focused on magnesium hydride based materials and on Mg based compounds for hydrogen and energy storage. This review article not only overviews the latest activities on both fundamental aspects of Mg-based hydrides and their applications but also presents a historic overview on the topic and outlines projected future developments. Particular attention is paid to the theoretical and experimental studies of Mg-H system at extreme pressures kinetics and thermodynamics of the systems based on MgH2 nanostructuring new Mg-based compounds and novel composites and catalysis in the Mg based H storage systems. Finally thermal energy storage and upscaled H storage systems accommodating MgH2 are presented.
Application of Hydrides in Hydrogen Storage and Compression: Achievements, Outlook and Perspectives
Feb 2019
Publication
José Bellosta von Colbe,
Jose-Ramón Ares,
Jussara Barale,
Marcello Baricco,
Craig Buckley,
Giovanni Capurso,
Noris Gallandat,
David M. Grant,
Matylda N. Guzik,
Isaac Jacob,
Emil H. Jensen,
Julian Jepsen,
Thomas Klassen,
Mykhaylo V. Lototskyy,
Kandavel Manickam,
Amelia Montone,
Julian Puszkiel,
Martin Dornheim,
Sabrina Sartori,
Drew Sheppard,
Alastair D. Stuart,
Gavin Walker,
Colin Webb,
Heena Yang,
Volodymyr A. Yartys,
Andreas Züttel and
Torben R. Jensen
Metal hydrides are known as a potential efficient low-risk option for high-density hydrogen storage since the late 1970s. In this paper the present status and the future perspectives of the use of metal hydrides for hydrogen storage are discussed. Since the early 1990s interstitial metal hydrides are known as base materials for Ni – metal hydride rechargeable batteries. For hydrogen storage metal hydride systems have been developed in the 2010s [1] for use in emergency or backup power units i. e. for stationary applications.<br/>With the development and completion of the first submarines of the U212 A series by HDW (now Thyssen Krupp Marine Systems) in 2003 and its export class U214 in 2004 the use of metal hydrides for hydrogen storage in mobile applications has been established with new application fields coming into focus.<br/>In the last decades a huge number of new intermetallic and partially covalent hydrogen absorbing compounds has been identified and partly more partly less extensively characterized.<br/>In addition based on the thermodynamic properties of metal hydrides this class of materials gives the opportunity to develop a new hydrogen compression technology. They allow the direct conversion from thermal energy into the compression of hydrogen gas without the need of any moving parts. Such compressors have been developed and are nowadays commercially available for pressures up to 200 bar. Metal hydride based compressors for higher pressures are under development. Moreover storage systems consisting of the combination of metal hydrides and high-pressure vessels have been proposed as a realistic solution for on-board hydrogen storage on fuel cell vehicles.<br/>In the frame of the “Hydrogen Storage Systems for Mobile and Stationary Applications” Group in the International Energy Agency (IEA) Hydrogen Task 32 “Hydrogen-based energy storage” different compounds have been and will be scaled-up in the near future and tested in the range of 500 g to several hundred kg for use in hydrogen storage applications.
Hybrid Hydrogen PEM Fuel Cell and Batteries Without DC–DC Converter
Sep 2013
Publication
Concerns about greenhouse gases as well as the price and security of oil supply have acted as a spur to sustainable automobile development. The hydrogen fuel cells electric vehicle (HFCEV) is generally recognised by leading automobile manufacturers and scientists as one of the optimum technologies for long-term future low carbon vehicle. In a typical HFCEV power train a DC–DC converter is required to balance the voltage difference between the fuel cells (FCs) stack and batteries. However research shows that a considerable amount of energy generated by the hydrogen FCs stack is deplete during this conversion process as heat. This experiment aims to improve the power train efficiency by eliminating the DC–DC converter by finding the best combination of FC stack and batteries matching the size and capacity of the electrical components.
Emerging Borophene Two-dimensional Nanmaterials for Hydrogen Storage
May 2023
Publication
The growing demand for energy and the need to reduce the carbon footprint has made green hydrogen a promising alternative to traditional fossil fuels. Green hydrogen is produced using renewable energy sources making it a sustainable and environmentally friendly energy source. Solid-state hydrogen storage aims to store hydrogen in a solid matrix offering potential advantages such as higher safety and improved energy density compared to traditional storage methods such as compressed gas or liquid hydrogen. However the development of efficient and economically viable solid-state storage materials is still a challenge and research continues in this field. Borophene is a two-dimensional material that offers potential as an intermediate hydrogen storage material due to its moderate binding energy and reversible behavior. Its unique geometry and electronic properties also allow for higher hydrogen adsorption capacity than metal-based complex hydrides surpassing the goals set by the U.S. Department of Energy. Borophene has shown great potential for hydrogen storage but it is still not practical for commercial use. In this review borophene nanomaterials chemical and physical properties are discussed related to hydrogen storage and binding energy. The importance of borophene for hydrogen storage the challenges it faces and its future prospects are also being discussed.
Forecasting Hydrogen Vehicle Refuelling for Sustainable Transportation: A Light Gradient-Boosting Machine Model
May 2024
Publication
Efficiently predicting and understanding refuelling patterns in the context of HFVs is paramount for optimising fuelling processes infrastructure planning and facilitating vehicle operation. This study evaluates several supervised machine learning methodologies for predicting the refuelling behaviour of HFVs. The LightGBM model emerged as the most effective predictive model due to its ability to handle time series and seasonal data. The selected model integrates various input variables encompassing refuelling metrics day of the week and weather conditions (e.g. temperature precipitation) to capture intricate patterns and relationships within the data set. Empirical testing and validation against real-world refuelling data underscore the efficacy of the LightGBM model demonstrating a minimal deviation from actual data given limited data and thereby showcasing its potential to offer valuable insights to fuelling station operators vehicle manufacturers and policymakers. Overall this study highlights the potential of sustainable predictive modelling for optimising fuelling processes infrastructure planning and facilitating vehicle operation in the context of HFVs.
Scaling Factors for Channel Width Variations in Tree-like Flow Field Patterns for Polymer Electrolyte Membrane Fuel Cells - An Experimental Study
Apr 2021
Publication
To have a uniform distribution of reactants is an advantage to a fuel cell. We report results for such a distributor with tree-like flow field plates (FFP). Numerical simulations have shown that the width scaling parameters of tree-like patterns in FFPs used in polymer electrolyte membrane fuel cells (PEMFC) reduces the viscous dissipation in the channels. In this study experimental investigations were conducted on a 2-layer FF plate possessing a tree-like FF pattern which was CNC milled on high-quality graphite. Three FF designs of different width scaling parameters were employed. I–V curves power curves and impedance spectra were generated at 70% 60% and 50% relative humidity (25 cm2 active area) and compared to those obtained from a conventional 1-channel serpentine FF. It was found that the FF design with a width scaling factor of 0.917 in the inlet and 0.925 in the outlet pattern exhibited the best peak power out of the three designs (only 11% - 0.08 W/cm2 lower than reference serpentine FF). Results showed that a reduction of the viscous dissipation in the flow pattern was not directly linked to a PEMFC performance increase. It was found that water accumulation together with a slight increase in single PEMFC resistance were the main reasons for the reduced power density. As further improvements a reduction of the number of branching generation levels and width scaling factor were recommended.
Hydrogen Separation and Purification from Various Gas Mixtures by Means of Electrochemical Membrane Technology in the Temperature Range 100–160 ◦C
Apr 2021
Publication
This paper reports on an experimental evaluation of the hydrogen separation performance in a proton exchange membrane system with Pt-Co/C as the anode electrocatalyst. The recovery of hydrogen from H2/CO2 H2/CH4 and H2/NH3 gas mixtures were determined in the temperature range of 100–160 ◦C. The effects of both the impurity concentration and cell temperature on the separation performance of the cell and membrane were further examined. The electrochemical properties and performance of the cell were determined by means of polarization curves limiting current density open-circuit voltage hydrogen permeability hydrogen selectivity hydrogen purity and cell efficiencies (current voltage and power efficiencies) as performance parameters. High purity hydrogen (>99.9%) was obtained from a low purity feed (20% H2 ) after hydrogen was separated from H2/CH4 mixtures. Hydrogen purities of 98–99.5% and 96–99.5% were achieved for 10% and 50% CO2 in the feed respectively. Moreover the use of proton exchange membranes for electrochemical hydrogen separation was unsuccessful in separating hydrogen-rich streams containing NH3 ; the membrane underwent irreversible damage.
Optimization and Sustainability of Gasohol/hydrogen Blends for Operative Spark Ignition Engine Utilization and Green Environment
Aug 2022
Publication
One of the many technical benefits of green diesel (GD) is its ability to be oxygenated lubricated and adopted in diesel engines without requiring hardware modifications. The inability of GD to reduce exhaust tail emissions and its poor performance in endurance tests have spurred researchers to look for new clean fuels. Improving gasohol/hydrogen blend (GHB) spark ignition is critical to its long-term viability and accurate demand forecasting. This study employed the Response Surface Methodology (RSM) to identify the appropriate GHB and engine speed (ES) for efficient performance and lower emissions in a GHB engine. The RSM model output variables included brake specific fuel consumption (BSFC) brake thermal efficiency (BTE) hydrocarbon (HC) carbon dioxide (CO2) and carbon monoxide (CO) while the input variables included ES and GHB. The Analysis of Variance-assisted RSM revealed that the most affected responses are BSFC and BTE. Based on the desirability criteria the best values for the GHB and the ES were determined to be 20% and 1500 rpm respectively while the validation between experimental and numerical results was calculated to be 4.82. As a result the RSM is a useful tool for predicting the optimal GHB and ES for optimizing spark-ignition engine characteristics and ensuring benign environment.
Optimal Hybrid Renewable Energy System: A Comparative Study of Wind/Hydrogen/Fuel-Cell and Wind/Battery Storage
Dec 2020
Publication
This paper performs a technoeconomic comparison of two hybrid renewable energy supplies (HRES) for a specific location in Ghana and suggests the optimal solution in terms of cost energy generation capacity and emissions. (e two HRES considered in this paper were wind/hydrogen/fuel-cell and wind/battery storage respectively. (e necessity of this study was derived from the rise and expansion of hybrid renewable energy supply in a decentralised network. (e readiness to embrace these new technologies is apparently high but the best combination for a selected location that brings optimum benefits is not obvious and demands serious technical knowledge of their technical and economic models. In the methodology an analytical model of energy generation by the various RE sources was first established and data were collected about a rural-urban community in Doderkope Ghana to test the models. HOMER software was used to design the two hybrid systems based on the same load profiles and results were compared. It turns out that the HRES 1 (wind/hydrogen/fuel-cell) had the lowest net present cost (NPC) and levelized cost of electricity (COE) over the project life span of 25 years. (e energy reserve with the HRES 2 (wind/battery storage) was huge compared to that with the HRES 1 about 270% bigger. Furthermore with respect to the emissions the HRES 2 was environmentally friendlier than the HRES 1. Even though the battery storage seems to be more cost-effective than the hydrogen fuel cell technology the latter presents some merits regarding system capacity and emission that deserve greater attention as the world looks into more sustainable energy storage systems.
A Review of the Optimization Strategies and Methods Used to Locate Hydrogen Fuel Refueling Stations
Feb 2023
Publication
Increasing sales of conventional fuel-based vehicles are leading to an increase in carbon emissions which are dangerous to the environment. To reduce these conventional fuel-based vehicles must be replaced with alternative fuel vehicles such as hydrogen-fueled. Hydrogen can fuel vehicles with near-zero greenhouse gas emissions. However to increase the penetration of such alternative fuel vehicles there needs to be adequate infrastructure specifically refueling infrastructure in place. This paper presents a comprehensive review of the different optimization strategies and methods used in the location of hydrogen refueling stations. The findings of the review in this paper show that there are various methods which can be used to optimally locate refueling stations the most popular being the p-median and flow-capture location models. It is also evident from the review that there are limited studies that consider location strategies of hydrogen refueling stations within a rural setting; most studies are focused on urban locations due to the high probability of penetration into these areas. Furthermore it is apparent that there is still a need to incorporate factors such as the safety elements of hydrogen refueling station construction and for risk assessments to provide more robust realistic solutions for the optimal location of hydrogen refueling stations. Hence the methods reviewed in this paper can be used and expanded upon to create useful and accurate models for a hydrogen refueling network. Furthermore this paper will assist future studies to achieve an understanding of the extant studies on hydrogen refueling station and their optimal location strategies.
Exploring Economic Expansion of Green Hydrogen Production in South Africa
Jan 2025
Publication
Hydrogen is a crucial energy carrier for the Clean Energy Sustainable Development Goals and the just transition to low/zero-carbon energy. As a top CO2-emitting country hydrogen (especially green hydrogen) production in South Africa has gained momentum due to the availability of resources such as solar energy land wind energy platinum group metals (as catalysts for electrolysers) and water. However the demand for green hydrogen in South Africa is insignificant which implies that the majority of the production must be exported. Despite the positive developments there are unclear matters such as dependence on the national electricity grid for green hydrogen production and the cost of transporting it to Asian and European markets. Hence this study aims to explore opportunities for economic expansion for sustainable production transportation storage and utilisation of green hydrogen produced in South Africa. This paper uses a thematic literature review methodology. The key findings are that the available renewable energy sources incentivizing the green economy carbon taxation and increasing the demand for green hydrogen in South Africa and Africa could decrease the cost of hydrogen from 3.54 to 1.40 €/kgH2 and thus stimulate its production usage and export. The appeal of green hydrogen lies in diversifying products to green hydrogen as an energy carrier clean electricity synthetic fuels green ammonia and methanol green fertilizers and green steel production with the principal purpose of significant energy decarbonisation and economic and foreign earnings. These findings are expected to drive the African hydrogen revolution in agreement with the AU 2063 agenda.
Analysing the Prospects of Grid-connected Green Hydrogen Production in Predominantly Fossil-based Countries - A Case Study of South Africa
Aug 2024
Publication
Importing substantial amount of green hydrogen from countries like South Africa which have abundant solar and wind potentials to replace fossil fuels has attracted interest in developed regions. This study analyses South African strategies for improving and decarbonizing the power sector while also producing hydrogen for export. These strategies include the Integrated Resource Plan the Transmission Development Plan Just Energy Transition and Hydrogen Society Roadmap for grid connected hydrogen production in 2030. Results based on an hourly resolution optimisation in Plexos indicate that annual grid-connected hydrogen production of 500 kt can lead to a 20–25% increase in the cost of electricity in scenarios with lower renewable energy penetration due to South African emission constraints by 2030. While the price of electricity is still in acceptable range and the price of hydrogen can be competitive on the international market (2–3 USD/kgH2 for production) the emission factor of this hydrogen is higher than the one of grey hydrogen ranging from 13 to 24 kgCO2/kgh2. When attempting to reach emission factors based on EU directives the three policy roadmaps become unfeasible and free capacity expansion results in significant sixteen-fold increase of wind and seven-fold increase in solar installations compared to 2023 levels by 2030 in South Africa.
Process Integration of Hydrogen Production Using Steam Gasification and Water-Gas Shift Reactions: A Case of Response Surface Method and Machine Learning Techniques
May 2024
Publication
An equilibrium-based steady-state simulator model that predicts and optimizes hydrogen production from steam gasification ofbiomass is developed using ASPEN Plus software and artificial intelligence techniques. Corn cob’s chemical composition wascharacterized to ensure the biomass used as a gasifier and with potential for production of hydrogen. Artificial intelligence is usedto examine the effects of the significant input variables on response variables such as hydrogen mole fraction and hydrogen energycontent. Optimizing the steam-gasification process using response surface methodology (RSM) considering a variety of biomass-steam ratios was carried out to achieve the best results. Hydrogen yield and the impact of main operating parameters wereconsidered. A maximum hydrogen concentration is found in the gasifier and water-gas shift (WGS) reactor at the highest steam-to-biomass (S/B) ratio and the lowest WGS reaction temperature while the gasification temperature has an optimum value. ANFISwas used to predict hydrogen of mole fraction 0.5045 with the input parameters of S/B ratio of 2.449 and reactor pressure andtemperature of 1 bar and 848°C respectively. With the steam-gasification model operating at temperature (850°C) pressure (1 bar)and S/B ratio of 2.0 an ASPEN simulator achieved a maximum of 0.5862 mole fraction of hydrogen while RSM gave an increaseof 19.0% optimum hydrogen produced over the ANFIS prediction with the input parameters of S/B ratio of 1.053 and reactorpressure and temperature of 1 bar and 850°C respectively. Varying the gasifier temperature and S/B ratio have on the other handa crucial effect on the gasification process with artificial intelligence as a unique tool for process evaluation prediction andoptimization to increase a significant impact on the products especially hydrogen.
Recent Advances in Membrane-based Electrochemical Hydrogen Separation: A Review
Feb 2021
Publication
In this paper an overview of commercial hydrogen separation technologies is given. These technologies are discussed and compared—with a detailed discussion on membrane-based technologies. An emerging and promising novel hydrogen separation technology namely electrochemical hydrogen separation (EHS) is reviewed in detail. EHS has many advantages over conventional separation systems (e.g. it is not energy intensive it is environmentally-friendly with near-zero pollutants it is known for its silent operation and the greatest advantage simultaneous compression and purification can be achieved in a one-step operation). Therefore the focus of this review is to survey open literature and research conducted to date on EHS. Current technological advances in the field of EHS that have been made are highlighted. In the conclusion literature gaps and aspects of electrochemical hydrogen separation that require further research are also highlighted. Currently the cost factor lack of adequate understanding of the degradation mechanisms related to this technology and the fact that certain aspects of this technology are as yet unexplored (e.g. simultaneous hydrogen separation and compression) all hinder its widespread application. In future research some attention could be given to the aforementioned factors and emerging technologies such as ceramic proton conductors and solid acids.
Review on the Thermal Neutrality of Application-orientated Liquid Organic Hydrogen Carrier for Hydrogen Energy Storage and Delivery
Aug 2023
Publication
The depletion and overuse of fossil fuels present formidable challenge to energy supply system and environment. The human society is in great need of clean renewable and sustainable energy which can guarantee the long-term utilization without leading to escalation of greenhouse effect. Hydrogen as an extraordinary secondary energy is capable of realizing the target of environmental protection and transferring the intermittent primary energy to the application terminal while its nature of low volumetric energy density and volatility need suitable storage method and proper carrier. In this context liquid organic hydrogen carrier (LOHC) among a series of storage methods such as compressed and liquefied hydrogen provokes a considerable amount of research interest since it is proven to be a suitable carrier for hydrogen with safety and stability. However the dehydrogenation of hydrogen-rich LOHC materials is an endothermic process and needs large energy consumption which hampers the scale up of the LOHC system. The heat issue is thus essential to be addressed for fulfilling the potential of LOHC. In this work several strategies of heat intensification and management for LOHC system including the microwave irradiation circulation of exhaust heat and direct LOHC fuel cell are summarized and analyzed to provide suggestions and directions for future research.
Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal Plasma
Sep 2023
Publication
Liquid hydrogen carriers will soon play a significant role in transporting energy. The key factors that are considered when assessing the applicability of ammonia cracking in large-scale projects are as follows: high energy density easy storage and distribution the simplicity of the overall process and a low or zero-carbon footprint. Thermal systems used for recovering H2 from ammonia require a reaction unit and catalyst that operates at a high temperature (550–800 ◦C) for the complete conversion of ammonia which has a negative effect on the economics of the process. A non-thermal plasma (NTP) solution is the answer to this problem. Ammonia becomes a reliable hydrogen carrier and in combination with NTP offers the high conversion of the dehydrogenation process at a relatively low temperature so that zero-carbon pure hydrogen can be transported over long distances. This paper provides a critical overview of ammonia decomposition systems that focus on non-thermal methods especially under plasma conditions. The review shows that the process has various positive aspects and is an innovative process that has only been reported to a limited extent.
Techno-economic Investigation of Hybrid Peaker Plant and Hydrogen Refuelling Station
Sep 2023
Publication
The power and transport sectors are responsible for significant emissions of greenhouse gases. Therefore it is imperative that substantial efforts are directed towards the decarbonisation of these industries. This study establishes a combined-solar-wind system's economic and technical practicality for producing hydrogen for an onsite hydrogen refuelling station (HRS) and electricity to meet peak demand. To minimise the levelised cost of electricity and maximise the system's reliability at different commercial locations in South Africa the dual-objective optimisation sizing is carried out using Mixed Integer Quadratic Constrained Programming (MICQP) model and was executed with an Advanced Multi-dimensional Modelling System (AIMMS) [61] [62]. The levelised costs of electricity and hydrogen at Johannesburg Pretoria and Cape Town for 2 MW grid export benchmark are 74.2 $/MWh/5.85 $/kg 76.3 $/MWh/5.97 $/kg and 50 $/MWh/4.45 $/kg respectively. The CO₂ equivalent emissions (tonnes) are 54000 55800 59000 and the corresponding carbon taxes ($) avoided for the locations are 432100 446200 and 472000 for Johannesburg Pretoria and Cape Town respectively. The results of the framework show that it can be adopted as a viable and fossil-free replacement for conventional peaking generators.
Optimal Design of Hydrogen-based Storage with a Hybrid Renewable energy System Considering Economic and Environmental Uncertainties
Dec 2023
Publication
Hydrogen and electricity derived from renewable sources present feasible alternative energy options for the decarbonisation of the transportation and power sectors. This study presents the utilisation of hydrogen generated from solar and wind energy resources as a clean fuel for mobility and backup storage for stationary applications under economic and environmental uncertainties. This is achieved by developing a detailed technoeconomic model of an integrated system consisting of a hydrogen refuelling station and an electric power generation system using Mixed Integer Quadratic Constrained Programming (MIQCP) which is further relaxed to Mixed Integer Linear Programming (MILP). The model is implemented in the Advanced Interactive Multidi mensional Modelling Software (AIMMS) and considering the inherent uncertainties in the wind resource solar resource costs and discount rate the total cost of the three configurations (Hybrid PV-Wind Standalone PV and Standalone wind energy system) was minimised using robust optimisation technique and the corresponding optimal sizes of the components levelised cost of energy (LCOE) excess energy greenhouse emission avoided and carbon tax were evaluated. The levelised cost of the deterministic optimisation solution for all the config uration ranges between 0.0702 $/kWh to 0.0786 $/kWh while the levelised cost of the robust optimisation solution ranges between 0.07188 $/kWh to 0.1125 $/kWh. The proposed integration has the advantages of affordable hydrogen and electricity prices minimisation of carbon emissions and grid export of excess energy.
The UAE Net-Zero Strategy—Aspirations, Achievements and Lessons for the MENA Region
Aug 2025
Publication
The Middle East and North Africa region has not played a major role in climate action so far and several countries depend economically on fossil fuel exports. However this is a region with vast solar energy resources which can be exploited affordably for power generation and hydrogen production at scale to eventually reach carbon neutrality. In this paper we elaborate on the case of the United Arab Emirates and explore the aspirations and feasibility of its net-zero by 2050 target. While we affirm the concept per se we also highlight the technological complexity and economic dimensions that accompany such transformation. We expect the UAE’s electricity demand to triple between today and 2050 and the annual green hydrogen production is expected to reach 3.5 Mt accounting for over 40% of the electricity consumption. Green hydrogen will provide power-to-fuel solutions for aviation maritime transport and hard-to-abate industries. At the same time electrification will intensify—most importantly in road transport and low-temperature heat demands. The UAE can meet its future electricity demands primarily with solar power followed by natural gas power plants with carbon capture utilization and storage while the role of nuclear power in the long term is unclear at this stage.
Energy Advancements and Integration Strategies in Hydrogen and Battery Storage for Renewable Energy Systems
Mar 2025
Publication
The long term and large-scale energy storage operations require quick response time and round-trip efficiency which is not feasible with conventional battery systems. To address this issue while endorsing high energy density long term storage and grid adaptability the hydrogen energy storage (HES) is preferred. This proposed work makes a comprehensive review on HES while synthesizing recent research on energy storage technologies and integration into renewable energy (RE) applications. The proposed research also identifies critical challenges related to system optimization energy management strategies and economic viability while featuring emerging technologies like artificial intelligence (AI) and machine learning (ML) for energy management. The proposed survey also discusses key advancements in battery technologies (lithium-ion Ni-Cd Ni/MH and flow batteries) which are examined alongside innovations in HES methods. The proposed survey utilizes an extensive list of publications to date in the open literature to canvass and portray various developments in this area.
Characterization of Perfluoro Sulfonic Acid Membranes for Potential Electrolytic Hydrogen Production and Fuel Cell Applications for Local and Global Green Hydrogen Economy
Aug 2025
Publication
Fuel cells have become a fundamental technology in the development of clean energy systems playing a vital role in the global shift toward a low-carbon future. With the growing need for sustainable hydrogen production perfluoro sulfonic acid (PFSA) ionomer membranes play a critical role in optimizing green hydrogen technologies and fuel cells. This study aims to investigate the effects of different environmental and solvent treatments on the chemical and physical properties of Nafion N−115 membranes to evaluate their suitability for both hydrogen production in proton exchange membrane (PEM) electrolyzers and hydrogen utilization in fuel cells supporting integrated applications in the local and global green hydrogen economy. To achieve this Nafion N−115 membranes were partially dissolved in various solvent mixtures including ethanol/isopropanol (EI) isopropanol/water (IW) dimethylformamide/N-methyl-2-pyrrolidone (DN) and ethanol/methanol/isopropanol (EMI) evaluated under water immersion and thermal stress and characterized for chemical stability mechanical strength water uptake and proton conductivity using advanced electrochemical and spectroscopic techniques. The results demonstrated that the EMI-treated membrane showed the highest proton conductivity and maintained its structural integrity making it the most promising for hydrogen electrolysis applications. Conversely the DN-treated membrane exhibited reduced stability and lower conductivity due to solvent-induced degradation. This study highlights the potential of EMI as an optimal solvent mixture for enhancing PFSA membranes performance in green hydrogen production contributing to the advancement of sustainable energy solutions.
Advancing the Hydrogen Production Economy: A Comprehensive Review of Technologies, Sustainability, and Future Prospects
Jun 2024
Publication
The transition to a hydrogen-based economy presents a promising solution to the challenges posed by unsus tainable energy systems and reliance on fossil fuels. This comprehensive review explores various hydrogen production methods emphasizing their technological advancements sustainability implications and future prospects. Beginning with an overview of hydrogen’s significance as a clean energy carrier the review examines key production methods such as Steam Methane Reforming Electrolysis (Proton Exchange Membrane alkaline solid oxide) Biomass Gasification Photoelectrochemical Water Splitting and Thermochemical Processes. Each method is scrutinized for its efficiency environmental impact and scalability providing valuable insights into their roles in advancing the hydrogen economy. The review highlights the transformative potential of hydrogen production to replace fossil fuels due to its ability to store renewable energy long-term and its zero emissions. It also discusses potential technological advancements including high-efficiency solid-state electrolysis and advanced catalysts for water splitting highlighting avenues for innovation in hydrogen production. Additionally policy recommendations aimed at promoting the hydrogen economy and fostering collaboration between academia industry and governments are elucidated. Through a detailed analysis of hydrogen production technologies and future prospects this review contributes to shaping the trajectory of sustainable energy sys tems advancing the adoption of hydrogen as a key energy vector and underscoring the importance of alternative and sustainable energy sources.
Optimizing Hydrogen Production from Wastewater-derived Sewage Sludge via Alkali-catalyzed Supercritical Water Gasification
Sep 2025
Publication
The increasing global wastewater generation and reliance on fossil fuels for energy production necessitate sustainable treatment and energy recovery solutions. This study explores supercritical water gasification (SCWG) of sewage sludge from municipal wastewater as a hydrogen production pathway focusing on the role of alkali catalysts (KOH K₂CO₃ Na₂CO₃). The effects of temperature (450–550◦C) reaction time (5–30 min) and catalyst type on gas yield and efficiency were analyzed. At 550◦C the highest carbon efficiency (61 %) gas efficiency (69 %) and hydrogen yield (41 mol/kg) were observed. After 30 min the gas composition reached H₂ (58 %) CO₂ (26 %) CH₄ (11.7 %) and CO (4 %). Among catalysts Na₂CO₃ exhibited superior H₂ yield (29 mol/kg) carbon efficiency (58 %) and gas efficiency (51 %). This study highlights SCWG as a viable technology for hydrogen-rich gas production contributing to sustainable energy solutions and wastewater valorization.
On the Relationship Between Pressure Collapse Rate and Nusselt Number During Sloshing in Cryogenic Liquid Hydrogen Tanks
Oct 2025
Publication
Pressure collapse in sloshing cryogenic liquid hydrogen tanks is a challenge for existing models which often diverge from experimental data. This paper presents a novel lumped-parameter model that overcomes these limitations. Based on a control volume analysis our approach simplifies the complex non-equilibrium physics into a single dimensionless ordinary differential equation governing the liquid’s temperature. We demonstrate this evolution is controlled by one key parameter: the interfacial Nusselt number (). A method for estimating directly from pressure data is also provided. Validated against literature data the model predicts final tank temperatures with deviation of 0.88K (<5% relative error) from measurements thereby explaining the associated pressure collapse. Furthermore our analysis reveals that the Nusselt number varies significantly during a single sloshing event—with calculated values ranging from a peak of 5.81 × 105 down to 7.58 × 103—reflecting the transient nature of the phenomenon.
Hydrogen Economy and Climate Change: Additive Manufacturing in Perspective
Oct 2025
Publication
The hydrogen economy stands at the forefront of the global energy transition and additive manufacturing (AM) is increasingly recognized as a critical enabler of this transformation. AM offers unique capabilities for improving the performance and durability of hydrogen energy components through rapid prototyping topology optimization functional integration of cooling channels and the fabrication of intricate hierarchical structured pores with precisely controlled connectivity. These features facilitate efficient heat and mass transfer thereby improving hydrogen production storage and utilization efficiency. Furthermore AM’s multi-material and functionally graded printing capability holds promise for producing components with tailored properties to mitigate hydrogen embrittlement significantly extending operational lifespan. Collectively these advances suggest that AM could lower manufacturing costs for hydrogen-related systems while improving performance and reliability. However the current literature provides limited evidence on the integrated techno-economic advantages of AM in hydrogen applications posing a significant barrier to large-scale industrial adoption. At present the technological readiness level (TRL) of AM-based hydrogen components is estimated to be 4–5 reflecting laboratory-scale progress but underscoring the need for further development validation and industrial-scale demonstration before commercialization can be realized.
Aromatic Liquid Organic Hydrogen Carriers for Hydrogen Storage and Release
Apr 2023
Publication
Hydrogen production from renewable energy sources has the potential to significantly reduce the carbon footprint of critical economic sectors that rely heavily on fossil fuels. Liquid organic hydrogen carrier (LOHC) technology has the capability to overcome the limitations associated with conventional hydrogen storage technologies. To date dibenzyltoluene and benzyltoluene are the benchmark LOHC molecules due to the unique hydrogen storage properties. However the reaction temperature for dehydrogenation reaction is high and catalysts need to be further developed so that efficient release of hydrogen can be realized. Exploration of various catalyst preparation methods such as supercritical carbon-dioxide deposition the selection on support material with relevant textural and chemical properties and optimization of catalyst modifiers are rewarding approaches of improving the catalyst performance. In addition to this the lowering of the dehydrogenation temperature by employing electrochemical methods and reactive distillation approaches are strategies that will make the LOHC technology competitive.
A Systematic Review of Energy Recovery and Regeneration Systems in Hydrogen-Powered Vehicles for Deployment in Developing Nations
Aug 2025
Publication
Improving the efficiency and range of hydrogen-powered electric vehicles (HPEVs) is essential for their global adoption especially in developing countries with limited resources. This study systematically evaluates regenerative braking and suspension systems in HPEVs and proposes a deployment-focused framework tailored to the needs of developing nations. A comprehensive search was performed across multiple databases to identify relevant studies. The selected studies are screened assessed for quality and analyzed based on predefined criteria. The data is synthesized and interpreted to identify patterns gaps and conclusions. The findings show that regeneration systems such as regenerative braking and regenerative suspension are the most effective energy recovery systems in most electric and hydrogen-powered vehicles. Although the regenerative braking system (RBS) offers higher energy efficiency gains that enhance cost-effectiveness despite its high initial investment the regenerative suspension system (RSS) involves increased complexity. Still it offers comparatively efficient energy recovery particularly in developing countries with patchy road infrastructure. The gaps highlighted in this review will aid researchers and vehicle manufacturers in designing optimizing developing and commercializing HPEVs for deployment in developing countries.
Analysis of Equipment Failures as a Contributor to Hydrogen Refuelling Stations Incidents
Oct 2025
Publication
Hydrogen is a sustainable clean source of energy and a viable alternative to carbon-based fossil fuels. To support the transport sector’s transition from fossil fuels to hydrogen a hydrogen refuelling station network is being developed to refuel hydrogen-powered vehicles. However hydrogen’s inherent properties present a significant safety challenge and there have been several hydrogen incidents noted with severe impacts to people and assets reported from operational hydrogen refuelling stations worldwide. This paper presents the outcome of an analysis of hydrogen incidents that occurred at hydrogen refuelling stations. For this purpose the HIAD 2.1 and H2tool.org databases were used for the collection of hydrogen incidents. Forty-five incidents were reviewed and analysed to determine the frequent equipment failures in the hydrogen refuelling stations and the underlying causes. This study adopted a mixed research approach for the analysis of the incidents in the hydrogen refuelling stations. The analysis reveals that storage tank failures accounted for 40% of total reported incidents hydrogen dispenser failures accounted for 33% compressors accounted for 11% valves accounted for 9% and pipeline failures accounted for 7%. To enable the safe operation of hydrogen refuelling stations hazards must be understood effective barriers implemented and learning from past incidents incorporated into safety protocols to prevent future incidents.
Risk Assessment Framework for Green Hydrogen Megaprojects: Balancing Climate Goals with Project Viability
Dec 2024
Publication
Green hydrogen presents a promising solution for decarbonisation but its widespread adoption faces significant challenges. To meet Europe’s 2030 targets a 250-fold increase in electrolyser capacity is required necessitating an investment of €170-240 billion. This involves constructing 20-40 pioneering megaprojects each with a 1-5 GW capacity. Historically pioneering energy projects have seen capital costs double or triple from initial estimates with over 50% failing to meet production goals at startup due to new technology introductions site-specific characteristics and project complexity. Additionally megaprojects costing more than €1 billion frequently succumb to the "iron law" which states they are often over budget take longer than anticipated and yield fewer benefits than expected mainly because key players consistently underestimate costs and risks. Pursuing multiple pioneering megaprojects simultaneously restricts opportunities for iterative learning which raises risks related to untested technologies and infrastructure demands. This vision paper introduces a novel risk assessment framework that combines insights from pioneering and megaprojects with technology readiness evaluations and comparative CO2 reduction analyses to tackle these challenges. The framework aims to guide investment decisions and risk mitigation strategies such as staged scaling and limiting the introduction of new technology. The analysis highlights that using green ammonia for fertiliser production can reduce CO2 emissions by 51 tons of CO2 per ton of hydrogen significantly outperforming hydrogen use in transportation and heating. This structured approach considers risks and environmental benefits while promoting equitable risk distribution between developed and developing nations.
Optimization of Green Hydrogen Production via Direct Seawater Electrolysis Powered by Hybrid PV-Wind Energy: Response Surface Methodology
Oct 2025
Publication
This study explored the optimization of green hydrogen production via seawater electrolysis powered by a hybrid photovoltaic (PV)-wind system in KwaZulu-Natal South Africa. A Box–Behnken Design (BBD) adapted from Response Surface Methodology (RSM) was utilized to address the synergistic effect of key operational factors on the integration of renewable energy for green hydrogen production and its economic viability. Addressing critical gaps in renewable energy integration the research evaluated the feasibility of direct seawater electrolysis and hybrid renewable systems alongside their techno-economic viability to support South Africa’s transition from a coal-dependent energy system. Key variables including electrolyzer efficiency wind and PV capacity and financial parameters were analyzed to optimize performance metrics such as the Levelized Cost of Hydrogen (LCOH) Net Present Cost (NPC) and annual hydrogen production. At 95% confidence level with regression coefficient (R2 > 0.99) and statistical significance (p < 0.05) optimal conditions of electricity efficiency of 95% a wind-turbine capacity of 4960 kW a capital investment of $40001 operational costs of $40000 per year a project lifetime of 29 years a nominal discount rate of 8.9% and a generic PV capacity of 29 kW resulted in a predictive LCOH of 0.124$/kg H2 with a yearly production of 355071 kg. Within the scope of this study with the goal of minimizing the cost of production the lowest LCOH observed can be attributed to the architecture of the power ratios (Wind/PV cells) at high energy efficiency (95%) without the cost of desalination of the seawater energy storage and transportation. Electrolyzer efficiency emerged as the most influential factor while financial parameters significantly affected the cost-related responses. The findings underscore the technical and economic viability of hybrid renewable-powered seawater electrolysis as a sustainable pathway for South Africa’s transition away from coal-based energy systems.
Techno-economic Evaluation of Retrofitting Power-to-methanol: Grid-connected Energy Arbitrage vs Standalone Renewable Energy
Aug 2025
Publication
The power-to-methanol (PtMeOH) will play a crucial role as a form of renewable chemical energy storage. In this paper PtMeOH techno-economics are assessed using the promising configuration from the previous work (Mbatha et al. [1]). This study evaluated the effect of parameters such as the CO2 emission tax electricity price and CAPEX reduction on the product methanol economic parity with respect to a reference case. Superior to previous economic studies a scenario where an existing methanol synthesis infrastructure is 100 % retrofitted with the promising electrolyser is assessed in terms of its economics and the associated economic parity. The volatile South African electricity market is considered as a case study. The sensitivity of the PtMeOH and green H2 profitability are checked. Grid-connected and standalone renewable energy PtMeOH scenarios are assessed. Foremost generalisable effect trends of these parameters on the net present value (NPV) and the levelized cost of methanol(LCOMeOH) and H2 (LCOH2) are discussed. The results show that economic parity of H2 (LCOH2 = current selling price = 4.06 €/kg) can be reached with an electricity price of 30 €/MWh and 70 % of the CAPEX. While the LCOMeOH will still be above 2 €/kg at 80 % of the CAPEX and electricity price of 20 €/MWh. This indicates that even if the CAPEX reduces to 20 % of its original in this study and the electricity price reduces to about 20 €/MWh the LCOMEOH will still not reach economic parity (LCOMeOH > current selling price = 0.44 €/kg). The results show that to make the retrofitted plant with a minimum of 20 years of life span profitable a feasible reduction in the electricity price to below 10 €/MWh along with favourable incentives such as CO2 credit and reduction in CAPEX particularly that of the electrolyser and treatment of the PtMeOH as a multiproduct plant will be required.
HYDRIDE4MOBILITY: An EU Project on Hydrogen Powered Forklift using Metal Hydrides for Hydrogen Storage and H2 Compression
Jan 2025
Publication
Volodymyr A. Yartys,
Mykhaylo V. Lototskyy,
Ivan Tolj,
José Bellosta von Colbe,
Roman V. Denys,
Moegamat Wafeeq Davids,
S. Nyallang Nyamsi,
Dana Swanepoel,
V.V. Berezovets,
I.Yu. Zavaliy,
Suwarno Suwarno,
I.J. Puszkiel,
Julian Jepsen,
Inês Abreu Ferreira,
Claudio Pistidda,
Yuanyuan Shang,
Sivakumar Pasupathi and
Vladimir Linkov
The EU Horizon2020 RISE project 778307 “Hydrogen fuelled utility and their support systems utilising metal hydrides” (HYDRIDE4MOBILITY) worked on the commercialization of hydrogen powered forklifts using metal hydride (MH) based hydrogen stores. The project consortium joined forces of 9 academic and industrial partners from 4 countries. The work program included a) Development of the materials for hydrogen storage and compression; b) Theoretical modelling and optimisation of the materials performance and system integration; c) Advanced fibre reinforced composite cylinder systems for H2 storage and compression; d) System validation. Materials development was focused on i) Zr/Ti-based Laves type high entropy alloys; ii) Mg-rich composite materials; iii) REMNiSn intermetallics; iv) Mg based materials for the hydrolysis process; v) Cost-efficient alloys. For the optimized AB2±x alloys the Zr/Ti content was optimized at A = Zr78-88Ti12–22 while B=Ni10Mn5.83VFe. These alloys provided a) Low hysteresis of hydrogen absorption-desorption; b) Excellent kinetics of charge and discharge; c) Tailored thermodynamics; d) Long cycle life. Zr0.85Ti0.15TM2 alloy provided a reversible H storage and electrochemical capacity of 1.6 wt% H and 450 mAh/g. The tanks development targeted: i) High efficiency of heat and hydrogen exchange; ii) Reduction of the weight and increasing the working H2 pressure; iii) Modelling testing and optimizing the H2 stores with fast performance. The system for power generation was validated at the Implats plant in a fuel cell powered forklift with on-board MH hydrogen storage and on-site H2 refuelling. The outcome on the HYDRIDE4MOBILITY project (2017–2024) (http://hydride4mobility.fesb.unist. hr) was presented in 58 publications.
Investigating the Investments Required to Transition New Zealand’s Heavy-Duty Vehicles to Hydrogen
Mar 2021
Publication
Reducing greenhouse gas emissions in the transport sector is known to be an important contribution to climate change mitigation. Some parts of the transport sector are particularly difficult to decarbonize; this includes the heavy-duty vehicle sector which is considered one of the “hardto-abate” sectors of the economy. Transitioning from diesel trucks to hydrogen fuel cell trucks has been identified as a potential way to decarbonize the sector. However the current and future costs and efficiencies of the enabling technologies remain unclear. In light of these uncertainties this paper investigates the investments required to decarbonize New Zealand’s heavy-duty vehicle sector with green hydrogen. By combining system dynamics modelling literature and hydrogen transition modelling literature a customized methodology is developed for modelling hydrogen transitions with system dynamics modelling. Results are presented in terms of the investments required to purchase the hydrogen production capacity and the investments required to supply electricity to the hydrogen production systems. Production capacity investments are found to range between 1.59 and 2.58 billion New Zealand Dollars and marginal electricity investments are found to range between 4.14 and 7.65 billion New Zealand Dollars. These investments represent scenarios in which 71% to 90% of the heavy-duty vehicle fleet are replaced with fuel cell trucks by 2050. The wide range of these findings reflects the large uncertainties in estimates of how hydrogen technologies will develop over the course of the next thirty years. Policy recommendations are drawn from these results and a clear opportunity for future work is outlined. Most notably the results from this study should be compared with research investigating the investments required to decarbonize the heavy-duty vehicle sectors with alternative technologies such as battery-electric trucks biodiesel and catenary systems. Such a comparison would ensure that the most cost effective decarbonization strategy is employed.
Catalysis as a Driver for Sustainable Technologies in Africa - A Perspective by the Catalysis Institute at the University of Cape Town
Mar 2023
Publication
One of the biggest global challenges we are facing today is the provision of affordable green and sustainable energy to a growing population. Enshrined in multiple United Nation Sustainable Development Goals – Goal 7: Affordable and Clean Energy; Goal 11: Sustainable Cities and Communities; Goal 12: Responsible Consumption and Production and Goal 13: Climate Action – as well as at the core of the Paris Agreement it is our task as scientists and engineers to develop innovative technologies that satisfy society’s needs while pivoting away from the use of fossil resources. This is a mammoth task with an ambitious timeline. The global development of the industrial sector as we know it is solely based on the exploitation of energy-rich fossil fuels that remain cost-competitive today. However a gradual change from a market driven to a policy-driven transition allows alternative technologies to make inroads and find applications. One of the most prominently discussed approaches is the Power-to-X (PtX) process envelope. It describes a series of catalytic conversions using only renewable energy water and captured CO2 to produce green hydrogen liquid hydrocarbon fuels and chemicals. Especially for sectors that are difficult or impossible to decarbonise such processes that effectively defossilising the production of energy and goods represent an important solution. The Catalysis Institute at the University of Cape Town (herein/after referred to as the Catalysis Institute) builds on decades of experience in the individual catalytic processes combined in the PtX concept. In collaboration with our global partners we are therefore able to develop technologies for the full value chain considering interdependencies and develop solutions for the African and indeed global society.
Advances in Hydrogen-Powered Trains: A Brief Report
Sep 2023
Publication
The majority of rail vehicles worldwide use diesel as a primary fuel source. Diesel engine carbon emissions harm the environment and human health. Although railway electrification can reduce emissions it is not always the most economical option especially on routes with low vehicle demand. As a result interest in hydrogen-powered trains as a way to reduce greenhouse gas (GHG) emissions has steadily grown in recent years. In this paper we discuss advancements made in hydrogen-powered freight and commuter trains as well as the technology used in some aspects of hydrogen-powered vehicles. It was observed that hydrogen-powered trains are already in use in Europe and Asia unlike most developing countries in Africa. Commuter trains have received most of the research and development (R&D) attention but interest in hydrogen-powered freight trains has recently picked up momentum. Despite the availability and use of gray and blue hydrogen green hydrogen is still the preferred fuel for decarbonizing the rail transport sector.
Production of Hydrogen Energy from Graphene-based Catalytic Technologies
Jul 2025
Publication
This comprehensive review aims at investigating graphene-based technologies in boosting hydrogen production via three methods including electrocatalysis photocatalysis and plasma-assisted reforming. Graphene stands out as an excellent catalytic material due to its exceptional attributes which include large surface area exceptional electrical and thermal conductivity adjustable electronic properties and outstanding mechanical strength. The research explores graphene’s contributions to hydrogen evolution through three main strategies including lowering energy barriers escalation of active sites and enhanced electrical charge transport. The study also focuses on graphene’s performance when functionalized with metal catalysts and heteroatoms enhancing its capability in charge separation and absorption of light during photocatalysis. The application of plasma to graphene improves catalytic reaction in hydrogen production with improved resistance to energy consumption. Large-scale industrial adoption of this technology remains restricted in terms production cost synthesis scalability and environmental safety issues. The research suggests an outlook for enhancing production technologies improving process sustainability and tackling scale-up technology to boost graphene’s incorporation into green and effective hydrogen energy production.
No more items...