Institution of Gas Engineers & Managers

The concept of techno-economic pathways is used to investigate the potential implementation of CO2 abatement measures over time towards zero-emission steelmaking in Sweden. The following mitigation measures are investigated and combined in three pathways: top gas recycling blast furnace (TGRBF); carbon capture and storage (CCS); substitution of pulverized coal injection (PCI) with biomass; hydrogen direct reduction of iron ore (H-DR); and electric arc furnace (EAF) where fossil fuels are replaced with biomass. The results show that CCS in combination with biomass substitution in the blast furnace and a replacement primary steel production plant with EAF with biomass (Pathway 1) yield CO2 emission reductions of 83% in 2045 compared to CO2 emissions with current steel process configurations. Electrification of the primary steel production in terms of H-DR/EAF process (Pathway 2) could result in almost fossil-free steel production and Sweden could achieve a 10% reduction in total CO2 emissions. Finally (Pathway 3) we show that increased production of hot briquetted iron pellets (HBI) could lead to decarbonization of the steel industry outside Sweden assuming that the exported HBI will be converted via EAF and the receiving country has a decarbonized power sector.

After a tank has been exposed to crash violence or an external fire it might in some situations be judged dangerous to move the vessel due to the risk of a sudden tank rupture. Therefore Swedish rescue services have a long history of using rifles to penetrate and therefore depressurize the vessels. In this paper some first steps on providing guidance on the selection of ammunition and required stand back distance are presented. The results indicate that a stand back distance on the order of 100 m is required and that the standard 7.62 Ball should only be used for composite CNG-tanks while stronger ammunitions are needed for steel and composite hydrogen tanks. However more research is required to provide a more solid scientific underpinning of the tactic guidance.

In the present study Reynolds-Averaged Navier-Stokes simulations together with a novel flamelet generated manifold (FGM) hybrid combustion model incorporating preferential diffusion effects is utilised for the investigation of a hydrogen-blended diesel-hydrogen dual-fuel engine combustion process with high hydrogen energy share. The FGM hybrid combustion model was developed by coupling laminar flamelet databases obtained from diffusion flamelets and premixed flamelets. The model employed three control variables namely mixture fraction reaction progress variable and enthalpy. The preferential diffusion effects were included in the laminar flamelet calculations and in the diffusion terms in the transport equations of the control variables. The resulting model is then validated against an experimental diesel-hydrogen dual-fuel combustion engine. The results show that the FGM hybrid combustion model incorporating preferential diffusion effects in the flame chemistry and transport equations yields better predictions with good accuracy for the in-cylinder characteristics. The inclusion of preferential diffusion effects in the flame chemistry and transport equations was found to predict well several characteristics of the diesel-hydrogen dual-fuel combustion process: 1) ignition delay 2) start and end of combustion 3) faster flame propagation and quicker burning rate of hydrogen 4) high temperature combustion due to highly reactive nature of hydrogen radicals 5) peak values of the heat release rate due to high temperature combustion of the partially premixed pilot fuel spray with entrained hydrogen/air and then background hydrogen-air premixed mixture. The comparison between diesel-hydrogen dual-fuel combustion and diesel only combustion shows early start of combustion longer ignition delay time higher flame temperature and NOx emissions for dual-fuel combustion compared to diesel only combustion.

The use of hydrogen as energy carrier in a low emission microturbine could be an interesting option for renewable energy storage distributed generation and combined heat & power. However the hydrogen using in gas turbine is limited by the NOx emissions and the difficulty to operate safely. CFD simulations represent a powerful and mature tool to perform detailed 3-D investigation for the development of a prototype before carrying out an experimental analysis. This paper describes the CFD supported redesign of the Turbec T100 microturbine combustion chamber natural gas-fired to allow the operation on 100% hydrogen.

A potential method of storing and transporting hydrogen safely in a cost-effective and practical way involves the utilization of molecules that contain hydrogen in their structure such as ammonia. Because of its high hydrogen content and carbon-free molecular structure as well as the maturity of related technology (easy liquefaction) ammonia has gained attention as a “hydrogen carrier” for the generation of energy. Unfortunately hydrogen production from ammonia requires an efficient catalyst to achieve high conversion at low reaction temperatures. Recently very attractive results have been obtained with low-surface-area materials. This review paper is focused on summarizing and comparing recent advances in novel economic and active catalysts for this reaction paying particular attention to materials with low surface area such as silicon carbide (SiC) and perovskites (ABO3 structure). The effects of the supports the active phase and the addition of promoters in such low-porosity materials have been analyzed in detail. Advances in adequate catalytic systems (including support and active metal) benefit the perspective of ammonia as a hydrogen carrier for the decarbonization of the energy sector and accelerate the “hydrogen economy”.

A thermodynamic model was developed for combustion performance and emissions with a reference diesel fuel a 10 vol% methanol blend with 90 vol% diesel a 10 vol% ethanol with 90 vol% diesel and a 4% hydrogen fumigating in the inlet port along with diesel direct injection. The diesel and two alcohol blends (10% methanol–90% diesel and 10% ethanol–90% diesel) was directly injected into the cylinder while hydrogen was fumigated at the inlet port. The model was developed by commercial GT-Suite software. Besides engine performance exergy and energy rates were estimated for the four fuels. Among the four fuels/fuel blends hydrogen fuel (4% fumigated hydrogen) shows the best performance in terms of exergy energy rates specific fuel consumption power and greenhouse gas emissions. Regarding greenhouse gases carbon dioxide was only considered in this investigation as it contributes to a significant detrimental effect on environmental pollution.

The development of hydropower industry is progressing rapidly in China and the installed capacity and power generation are increasing year by year. However due to factors such as transmission channels and power grid peaking capacity hydropower consumption in some areas is facing greater pressure. As an excellent medium for energy interconnection hydrogen energy can play an important role in promoting hydropower consumption. This paper introduces the current status and trends of hydrogen energy development in major developed countries and China and analyzes the current status of China’s hydropower abandoned water. Based on the production of hydrogen using surplus hydropower in the Dadu River Basin in Sichuan an integrated energy network research plan including hydropower electrolytic hydrogen production storage and transportation hydrogen refueling and hydrogen-powered vehicles is proposed. At the same time the development concept of hydrogen energy industry including hydrogen energy source economy hydrogen energy industry ecosphere and hydrogen energy sky road in western Sichuan is also proposed.

Recent advances in technologies for the decentralized islanded ammonia economy are reviewed with an emphasis on feasibility for long-term practical implementation. The emphasis in this review is on storage systems in the size range of 1–10 MW. Alternatives for hydrogen production nitrogen production ammonia synthesis ammonia separation ammonia storage and ammonia combustion are compared and evaluated. A conceptual process design based on the optimization of temperature and pressure levels of existing and recently proposed technologies is presented for an islanded ammonia energy system. This process design consists of wind turbines and solar panels for electricity generation a battery for short-term energy storage an electrolyzer for hydrogen production a pressure swing adsorption unit for nitrogen production a novel ruthenium-based catalyst for ammonia synthesis a supported metal halide for ammonia separation and storage and an ammonia fueled proton-conducting solid oxide fuel cell for electricity generation. In a generic location in northern Europe it is possible to operate the islanded energy system at a round-trip efficiency of 61% and at a cost of about 0.30–0.35 € kWh−1 .

In the present scenario much importance has been provided to hydrogen energy systems (HES) in the energy sector because of their clean and green behavior during utilization. The developments of novel techniques and materials have focused on overcoming the practical difficulties in the HES (production storage and utilization). Comparatively considerable attention needs to be provided in the hydrogen storage systems (HSS) because of physical-based storage (compressed gas cold/cryo compressed and liquid) issues such as low gravimetric/volumetric density storage conditions/parameters and safety. In material-based HSS a high amount of hydrogen can be effectively stored in materials via physical or chemical bonds. In different hydride materials Mg-based hydrides (Mg–H) showed considerable benefits such as low density hydrogen uptake and reversibility. However the inferior sorption kinetics and severe oxidation/contamination at exposure to air limit its benefits. There are numerous kinds of efforts like the inclusion of catalysts that have been made for Mg–H to alter the thermodynamic-related issues. Still those efforts do not overcome the oxidation/contamination-related issues. The developments of Mg–H encapsulated by gas-selective polymers can effectively and positively influence hydrogen sorption kinetics and prevent the Mg–H from contaminating (air and moisture). In this review the impact of different polymers (carboxymethyl cellulose polystyrene polyimide polypyrrole polyvinylpyrrolidone polyvinylidene fluoride polymethylpentene and poly(methyl methacrylate)) with Mg–H systems has been systematically reviewed. In polymer-encapsulated Mg–H the polymers act as a barrier for the reaction between Mg–H and O2/H2O selectively allowing the H2 gas and preventing the aggregation of hydride nanoparticles. Thus the H2 uptake amount and sorption kinetics improved considerably in Mg–H.

The combination of offshore wind and green hydrogen provides major opportunities for job creation economic growth and regional regeneration as well as attracting inward investment alongside delivering the emission reductions needed to achieve climate neutrality. In order to get to Net Zero emissions in 2050 the UK is likely to need a minimum of 75GW of offshore wind (OSW) and modelling of the energy system indicates that hydrogen will play a major role in integrating the high levels of OSW on the electricity grid.<br/><br/>Some of the key findings from report are listed below:<br/><br/>The UK has vast resources of offshore wind with the potential for over 600GW in UK waters and potentially up to 1000GW. This is well above the he figure of 75-100GW likely to be needed for UK electricity generation by 2050.<br/>The universities in the UK provide the underpinning science and engineering for electrolysers fuel cells and hydrogen and are home to world-leading capability in these areas.<br/>In order to achieve cost reduction and growing a significant manufacturing and export industry it will be crucial to develop green hydrogen in the next 5 years<br/>By 2050 green hydrogen can be cheaper than blue hydrogen. With accelerated deployment green hydrogen costs can be competitive with blue hydrogen by the eary 2030s.<br/>The combination of additional OSW deployment and electrolyser manufacture alone could generate over 120000 new jobs. These are are expected to be based mainly in manufacturing OSW-related activity shipping and mobility<br/>By 2050 it is estimated that the cumulative gross value added (GVA) from supply of electrolysers and additional OSW farm could be up to £320bn where the majority will come from exports of electrolysers to overseas markets.<br/>The report also calls for immediate government intervention and a new national strategy to support the creation of supply and demand in the new industry.<br/><br/>This study was jointly supported by the Offshore Wind Industry Council (OWIC) and ORE Catapult.