Institution of Gas Engineers & Managers
Progress and Prospects of Reversible Solid Oxide Fuel Cell Materials
Dec 2021
Publication
Reversible solid oxide fuel cell (RSOFC) is an energy device that flexibly interchanges between electrical and chemical energy according to people’s life and production needs. The development of cell materials affects the stability and cost of the cell but also restricts its market-oriented development. After decades of research by scientists a lot of achievements and progress have been made on RSOFC materials. According to the composition and requirements of each component of RSOFC this article summarizes the research progress based on materials and discusses the merits and demerits of current cell materials in electrochemical performance. According to the efficiency of different materials in solid oxide fuel cell (SOFC mode) and solid oxide electrolyzer (SOEC mode) the challenges encountered by RSOFC in the operation are evaluated and the future development of RSOFC materials is boldly prospected.
An Environmentally Sustainable Energy Management Strategy for Marine Hybrid Propulsion
Jan 2025
Publication
Integrating electric technologies such as battery energy storage systems and electric propulsion has become an appealing option for reducing fuel consumption and emissions in the transportation sector making these technologies increasingly popular for research and industrial application in the maritime sector. In addition hydrogen is a promising technology for reducing emissions although hydrogen production technologies significantly influence the overall impact of hydrogen-powered systems. This paper proposes an optimizationbased strategy to minimize the environmental impact of a hybrid propulsion system over a given load profile while furthermore considering the environmental impact resulting from the hydrogen production chain. The propulsion system includes diesel generators hydrogen-powered fuel cells batteries and electric motors; mathematical models and assumptions are discussed in detail. The paper applies the proposed strategy and compares different hybrid solutions considering equivalent CO2 emissions discussing a test case applied to a short-range ferry operating in a marine protected area an area particularly sensitive to the problem of atmospheric emissions. The results demonstrate that the proposed strategy can reduce greenhouse gas emissions by up to 73% compared to a conventional mechanical propulsion system.
Sensitivity Analysis of the Methanation Process in Underground Hydrogen Storage: A Case Study in Upper Austria
Jan 2025
Publication
Underground hydrogen storage (UHS) has attracted increasing attention as a promising technology for the largescale storage of renewable energy resources and the decarbonization of energy systems. This study aimed to identify critical parameters influencing UHS performance particularly the role of hydrogen conversion via in situ methanation and hydrogen recovery during production cycles. The main focus is the Lehen field in Upper Austria where a pilot hydrogen storage project was conducted under the leadership of RAG Austria AG. A layered reservoir model was developed on the basis of well-log data to simulate the field trials that occurred in 2016. A sensitivity analysis was performed with the one-parameter-at-a-time (OPAAT) method and the response surface methodology (RSM) to evaluate the impacts of different parameters on hydrogen methanation and hydrogen recovery. The RSM results indicate the activation energy as the most influential factor on methanation that accounts for ~20000 moles variation in generated methane significantly higher than the 6000 moles variance observed in OPAAT. However initial CO2 content contributes up to 15000 moles of methane gener ation as per RSM whereas OPAAT results in a larger impact of up to 32000 moles. These discrepancies demonstrate the limitations of isolated parameter analyses like OPAAT which may not accurately capture the complex interactions between factors influencing the methanation process. This research provides valuable in sights for optimizing UHS performance by emphasizing the influence of reservoir parameters on storage effi ciency. In addition a robust workflow for conducting comprehensive sensitivity analyses of UHS systems is established. By understanding these key factors the potential and predictability of large-scale UHS systems can be significantly improved.
A Perspective on the Decarbonization of the Metals Industry
Nov 2024
Publication
The decarbonization of the metals industry is a major challenge for the energy transition. Metals are indeed essential elements in the expansion of renewable energy installations worldwide but they also represent a relevant source of carbon emissions. Therefore metals producers need to carefully shift their technologies towards less carbon intensive routes. After ranking all the metals in terms of world production volume and total estimated carbon emissions the three most relevant ones have been selected: steel aluminum and chromium. Concentrating the rest of the analysis on them several production processes are available for implementing the decarbonization step but none of them is currently capable of overcoming the challenge alone and being compatible with the 1.5°C trajectory. In this perspective the main production routes are reviewed and proper combinations of proven or emerging technologies are streamlined with the aim to provide an industrially feasible approach to curb the carbon emissions from the metals industry.
Decentralized Hydrogen-oxygen Co-production via Electrolysis for Large Hospitals with Integrated Hydrogen Refuelling Station
Jan 2025
Publication
In the pursuit of greener and more self-sufficient healthcare operations this study presents an integrated eco nomic and environmental analysis of on-site co-production of oxygen and hydrogen through proton exchange membrane electrolysis specifically designed for the Santa Maria Hospital in Lisbon Portugal. The proposed system aims to meet the hospital’s oxygen demand while simultaneously producing hydrogen for use in fuel cell electric vehicles such as ambulances. A 1.5 MW PEM electrolyser is found to be sufficient to meet the hospital’s O2 needs while generating hydrogen at a levelized cost of hydrogen of 4.6 €/kgH2. When considering the implementation costs of an on-site hydrogen refueling station an O2 drying and storage unit as well as the avoided costs in bulk liquid O2 purchases the break-even point for the sale of H2 at the refueling stations is 2.4 €/kgH2. Apart from the economic benefits that could be achieved by selling the produced H2 above this price the environmental analysis showed that 1874 tons of CO2 emissions per year could be avoided by the imple mentation of the concept proposed here. This integrated system not only contributes to the hospital’s energy independence but also serves as a model for sustainable solutions in the healthcare sector with significant environmental and financial benefits.
Hydrogen Production Towards a Carbon-free Economy: A Comprehensive Thermodynamic Analysis
Jan 2025
Publication
Sustainable hydrogen production is key to achieving zero-emission targets and a hydrogen-based economy. Hydrogen production methods vary in terms of resource technology and system efficiency. This work analyzes the thermodynamics of fourteen hydrogen production pathways using Gibbs free energy minimization to examine the effects of pressure (1–60 bar) temperature (100–1000 ◦C) and feed composition using reactant conversion and product selectivity as key indicators of reaction performance. The impact of simultaneous reactions on hydrogen production is also discussed. From the results full conversion (100 %) independent of parameter variations at 1 bar pressure was observed for biomass gasification and steam reforming of glycerol methanol ethanol and bio-oil reactions. However H2 selectivity in all tested reactions except for NH3 dissociation and the splitting of water and H2S is greatly affected by side reactions. Finally the thermodynamic results of all reactions are compared and validated with published experiments followed by an evaluation of the challenges and opportunities in hydrogen production. The study provides optimal reaction parameters and a comprehensive comparison of H2 production processes aiding in designing and developing processes based on regional resource availability. Additionally it highlights the potential for both local and remote hydrogen production pathways from various renewable energy sources.
Everything About Hydrogen Podcast: Nuclear-enabled Hydrogen at Port of Belledune
Jul 2024
Publication
The team sits down with Rishi Jain to discuss Cross River’s marquee wind hydro nuclear hydrogen ammonia project in the revitalized heavy industrial Port of Belledune New Brunswick Canada.
The podcast can be found on their website.
The podcast can be found on their website.
Recent Progress in Seawater Electrolysis for Hydrogen Evolution by Transition Metal Phosphides
Dec 2021
Publication
The electrocatalytic seawater splitting has become an important and necessary way for large-scale hydrogen production with challenges ahead. In this review a brief introduction to the reaction mechanism of seawater electrocatalytic process is first provided including the cathodic hydrogen evolution reaction and the anodic oxygen evolution reaction as well as the competitive chloride evolution reaction. Recent progress in transition metal phosphides-based catalysts for seawater electrolysis such as phosphorus doped transition metals binary metal phosphides and structural engineering are then evaluated and discussed. Finally the challenges and opportunities of transition metal phosphides are proposed and discussed.
Assessment of Selected Alternative Fuels for Spanish Navy Ships According to Multi-Criteria Decision Analysis
Dec 2023
Publication
Climate change and environmental degradation are growing concerns in today’s society which has led to greater awareness and responsibility regarding the need to adopt sustainable practices. The European Union has established the goal of achieving climate neutrality by 2050 which implies a significant reduction in greenhouse gas emissions in all sectors. To achieve this goal renewable energies the circular economy and energy efficiency are being promoted. A major source of emissions is the use of fossil fuels in different types of ships (from transport ships to those used by national navies). Among these it highlights the growing interest of the defense sector in trying to reduce these emissions. The Spanish Ministry of Defense is also involved in this effort and is taking steps to reduce the carbon footprint in military operations and improve sustainability in equipment acquisition and maintenance. The objective of this study is to identify the most promising alternative fuel among those under development for possible implementation on Spanish Navy ships in order to reduce greenhouse gas emissions and improve its capabilities. To achieve this a multi-criteria decision-making method will be used to determine the most viable fuel option. The data provided by the officers of the Spanish Navy is of great importance thanks to their long careers in front of the ships. The analysis revealed that hydrogen was the most suitable fuel with the highest priority ahead of LNG and scored the highest in most of the sections of the officials’ ratings. These fuels are less polluting and would allow a significant reduction in emissions during the navigation of ships. However a further study would also have to be carried out on the costs of adapting to their use and the safety of their use.
Multi-Temporal Energy Management Strategy for Fuel Cell Ships Considering Power Source Lifespan Decay Synergy
Dec 2024
Publication
With increasingly stringent maritime environmental regulations hybrid fuel cell ships have garnered significant attention due to their advantages in low emissions and high efficiency. However challenges related to the coordinated control of multi-energy systems and fuel cell degradation remain significant barriers to their practical implementation. This paper proposes an innovative multi-timescale energy management strategy that focuses on optimizing the lifespan decay synergy of fuel cells and lithium batteries. The study designs an attention-based CNN-LSTM hybrid model for power prediction and constructs a twostage optimization framework: The first stage employs Model Predictive Control (MPC) for long-term power planning to optimize equivalent hydrogen consumption while the second stage focuses on real-time power allocation considering both power source degradation and system operational efficiency. The simulation results demonstrate that compared to single-layer MPC and the Equivalent Consumption Minimization Strategy (ECMS) the proposed method exhibits significant advantages in reducing single-voyage costs minimizing differences in power source degradation rates and alleviating power source stress. The overall performance of this strategy approaches the global optimal solution obtained through Dynamic Programming comprehensively validating its superiority in simultaneously optimizing system economics and durability.
The Effect of Defueling Rate on the Temperature Evolution of On-board Hydrogen Tanks
Jul 2015
Publication
During the driving of a fuel cell car the expansion of the hydrogen along the emptying of the high pressure storage tank produces a cooling of the gas. The hydrogen vessel can experience a fast depressurization during acceleration or under an emergency release. This can result on the one hand in exceeding the low safety temperature limit of 40 C inside the on-board compressed hydrogen tank and on the other hand in the cooling of its walls. In the present paper defueling experiments of two different types of on-board hydrogen tanks (Type III and Type IV) have been performed in all the range of expected defueling rates. The lowest temperatures have been found on the bottom part of the Type IV tank in very fast defuelings. For average driving conditions in both types of vessels the inside gas temperature gets closer to that of the walls and the tank would arrive to the refuelling station at a temperature significantly lower than the ambient temperature.
Green Energy Revolution and Substitution of Hydrocarbons with Hydrogen: Distribution Network Infrastructure Materials
Dec 2023
Publication
Global warming is an accepted fact of life on Earth posing grave consequences in the form of weather patterns with life-threatening outcomes for inhabitants and their cultures especially those of island countries. These wild and unpredictable weather patterns have persuaded authorities governments and industrial leaders to adapt a range of solutions to combat the temperature rise on Earth. One such solution is to abandon fossil fuels (hydrocarbons) for energy generation and employ renewable energy sources or at least use energy sources that do not generate greenhouse gases. One such energy carrier is hydrogen which is expected to slowly replace natural gas and will soon be pumped into the energy distribution pipeline network. Since the current energy distribution network was designed for hydrocarbons its use for hydrogen may pose some threat to the safety of urban society. This is the first time an overview article has examined the replacement of hydrocarbons by hydrogen from a totally different angle by incorporating material science viewpoints. This article discusses hydrogen properties and warns about the issue of hydrogen embrittlement in the current pipeline network if hydrogen is to be pumped through the current energy distribution network i.e. pipelines. It is recommended that sufficient study and research be planned and carried out to ensure the safety of using the current energy distribution network for hydrogen distribution and to set the necessary standards and procedures for future design and construction.
Multi-functional Hybrid Energy System for Zero-energy Residential Buildings: Integrating Hydrogen Production and Renewable Energy Solutions
Jan 2025
Publication
The increasing global residential energy demand causes carbon emissions and ecological impacts necessitating cleaner efficient solutions. This study presents an innovative hybrid energy system integrating wind power and gas turbines for a four-story 16-unit residential building. The system generates electricity heating cooling and hydrogen using a Proton Exchange Membrane electrolyzer and a compression chiller. Integrating the electrolyzer enables hydrogen production and demonstrates hydrogen’s potential as a versatile clean energy carrier for systems contributing to advancements in hydrogen utilization. Simulations with Engineering Equation Solver software coupled with neural network-based multi-objective optimization fine-tuned parameters such as gas turbine efficiency wind turbine count and gas turbine inlet temperature to enhance exergy efficiency and reduce operational costs. The optimized system achieves an energy efficiency of 33.69% and an exergy efficiency of 36.95% and operates at $446.04 per hour demonstrating economic viability. It produces 51061 MWh annually exceeding the building’s energy demands and allowing surplus energy use elsewhere. BEopt simulations confirm the system meets residential needs by providing 2.52 GWh of electricity 3.36 GWh of heating and 5.11 GWh of cooling annually. This system also generates 10 kg of hydrogen per hour and achieves a CO₂ reduction of 10416 tons/year. The wind farm (25 turbines) provides most of the energy at 396.7 dollars per hour while the gas turbine operates at 80% efficiency. By addressing the challenges of intermittent renewable energy in residential Zero-Energy Buildings this research offers a scalable and environmentally friendly solution contributing to sustainable urban living and advancing hydrogen energy applications.
Advancing Hydrogen: A Closer Look at Implementation Factors, Current Status and Future Potential
Dec 2023
Publication
This review article provides a comprehensive analysis of the hydrogen landscape outlining the imperative for enhanced hydrogen production implementation and utilisation. It places the question of how to accelerate hydrogen adoption within the broader context of sustainable energy transitions and international commitments to reduce carbon emissions. It discusses influencing factors and policies for best practices in hydrogen energy application. Through an in-depth exploration of key factors affecting hydrogen implementation this study provides insights into the complex interplay of both technical and logistical factors. It also discusses the challenges of planning constructing infrastructure and overcoming geographical constraints in the transition to hydrogen-based energy systems. The drive to achieve net-zero carbon emissions is contingent on accelerating clean hydrogen development with blue and green hydrogen poised to complement traditional fuels. Public–private partnerships are emerging as catalysts for the commercialisation of hydrogen and fuel-cell technologies fostering hydrogen demonstration projects worldwide. The anticipated integration of clean hydrogen into various sectors in the coming years signifies its importance as a complementary energy source although specific applications across industries remain undefined. The paper provides a good reference on the gradual integration of hydrogen into the energy landscape marking a significant step forward toward a cleaner greener future.
Transitioning to a Renewable Hydrogen System: Optimal Infrastructure for Self-sufficient Hydrogen Supply in Austria by 2030
Aug 2024
Publication
In this study we employ an optimization model to optimally design a self-sufficient independent of any imports and exports hydrogen infrastructure for Austria by 2030. Our approach integrates key hydrogen technologies within a detailed spatial investment and operation model – coupled with a European scale electricity market model. We focus on optimizing diverse infrastructure componentsincluding trailers pipelines electrolyzers and storages to meet Austria's projected hydrogen demand. To accurately estimate this demand in hourly resolution we combine existing hydrogen strategies and projections to account for developments in various industrial sectors consider demand driven by the transport sector and integrate hydrogen demand arising from its use in gas-powered plants. Accounting for the inherent uncertainty linked to such projections we run the analysis for two complementary scenarios. Our approach addresses the challenges of integrating large quantities of renewable hydrogen into a future energy system by recognizing the critical role of domestic production in the early market stages. The main contribution of this work is to address the gap in optimizing hydrogen infrastructure for effective integration of domestic renewable hydrogen production in Austria by 2030 considering sector coupling potentials optimal electrolyzer placement and the design of local hydrogen networks.
A High-performance Capillary-fed Electrolysis Cell Promises More Cost-competitive Renewable Hydrogen
Mar 2022
Publication
Renewable or green hydrogen will play a critical role in the decarbonisation of hard-to-abate sectors and will therefore be important in limiting global warming. However renewable hydrogen is not cost-competitive with fossil fuels due to the moderate energy efficiency and high capital costs of traditional water electrolysers. Here a unique concept of water electrolysis is introduced wherein water is supplied to hydrogen- and oxygen-evolving electrodes via capillary-induced transport along a porous inter-electrode separator leading to inherently bubble-free operation at the electrodes. An alkaline capillary-fed electrolysis cell of this type demonstrates water electrolysis performance exceeding commercial electrolysis cells with a cell voltage at 0.5 A cm−2 and 85 °C of only 1.51 V equating to 98% energy efficiency with an energy consumption of 40.4 kWh/kg hydrogen (vs. ~47.5 kWh/kg in commercial electrolysis cells). High energy efficiency combined with the promise of a simplified balance-ofplant brings cost-competitive renewable hydrogen closer to reality.
Understanding Costs in Hydrogen Infrastructure Networks: A Multi-stage Approach for Spatially-aware Pipeline Design
Jan 2025
Publication
The emergence and design of hydrogen transport infrastructures are crucial steps towards the development of a hydrogen economy. However pipeline routing remains underdeveloped in hydrogen infrastructure design models despite its significant impact on the resultant cost and network configuration. Many previous studies assume uniform cost surfaces on which pipelines are designed. Studies that consider a variable cost surface focus on designing candidate networks rather than bespoke routes for a given infrastructure. This study proposes a novel multi-stage approach based on a graph-based Steiner tree with Obstacles Genetic Algorithm (StObGA) to route pipelines on a complex cost surface for multi-source multi-sink hydrogen networks. The application of StObGA results in cost savings of 20–40% compared to alternative graph-based methods that assume uniform cost surfaces. Furthermore this publication presents an in-depth methodological comparative analysis of different pipeline routing and sizing methods used in the literature and discusses their impact. Finally we demonstrate how this model can generate design variations and provide practical insights to inform industry and policymakers.
Review of Next Generation Hydrogen Production from Offshore Wind Using Water Electrolysis
Dec 2023
Publication
Hydrogen produced using renewable energy from offshore wind provides a versatile method of energy storage and power-to-gas concepts. However few dedicated floating offshore electrolyser facilities currently exist and therefore conditions of the offshore environment on hydrogen production cost and efficiency remain uncertain. Therefore this review focuses on the conversion of electrical energy to hydrogen using water electrolysis located in offshore areas. The challenges associated with the remote locations fluctuating power and harsh conditions are highlighted and recommendations for future electrolysis system designs are suggested. The latest research in polymer electrolyte membrane alkaline and membraneless electrolysis are evaluated in order to understand their capital costs efficiency and current research status for achieving scaled manufacturing to the GW scale required in the next three decades. Operating fundamentals that govern the performance of each device are investigated and future recommendations of research specifically for the integration of water electrolysers with offshore wind turbines is presented.
Optimal Sizing of Renewable Energy Storage: A Techno-economic Analysis of Hydrogen, Battery and Hybrid Systems Considering Degradation and Seasonal Storage
Feb 2023
Publication
Energy storage is essential to address the intermittent issues of renewable energy systems thereby enhancing system stability and reliability. This paper presents the design and operation optimisation of hydrogen/battery/ hybrid energy storage systems considering component degradation and energy cost volatility. The study ex amines a real-world case study which is a grid-connected warehouse located in a tropical climate zone with a photovoltaic solar system. An accurate and robust Multi-Objective Modified Firefly Algorithm (MOMFA) is proposed for the optimal design and operation of the energy storage systems of the case study. To further demonstrate the robustness and versatility of the optimisation method another synthetic case is tested for a location in a temperate climate zone that has a high seasonal mismatch. The modelling results show that the system in the tropical zone always provides a superior return when compared to a similar system in the temperate zone due to abundant solar resources. When comparing battery-only and hydrogen-only systems battery systems perform better than hydrogen systems in many situations with a higher self-sufficient ratio and net present value. However if there is high seasonal variation and a high requirement for using renewable energy (the penetration of renewable energy is >80 %) using hydrogen for energy storage is more beneficial. Furthermore the hybrid system (i.e. combining battery and hydrogen) outperforms battery-only and hydrogenonly systems. This is attributed to the complementary combination of hydrogen which can be used as a longterm energy storage option and battery which is utilised as a short-term option. This study also shows that storing hydrogen in a long-term strategy can lower component degradation enhance efficiency and increase the total economic performance of hydrogen and hybrid storage systems. The developed optimisation method and findings of this study can support the implementation of energy storage systems for renewable energy.
Maximizing H2 Production from a Combination of Catalytic Partial Oxidation of CH4 and Water Gas Shift Reaction
Jan 2025
Publication
A single-bed and dual-bed catalyst system was studied to maximize H2 production from the combination of partial oxidation of CH4 and water gas shift reaction. In addition the different types of catalysts including Ni Cu Ni-Re and Cu-Re supported on gadolinium-doped ceria (GDC) were investigated under different operating conditions of temperature (400–650 ◦C). Over Ni-based catalysts methane can easily dissociate on a Ni surface to give hydrogen and carbon species. Then carbon species react with lattice oxygen of ceria-based material to form CO. The addition of Re to Ni/GDC enhances CH4 dissociation on the Ni surface and increases oxygen storage capacity in the catalyst thus promoting carbon elimination. In addition the results showed that a dual-bed catalyst system exhibited catalytic activity better than a single-bed catalyst system. The dual-bed catalyst system by the combination of 1%Re4%Ni/GDC as a partial oxidation catalyst and 1%Re4%Cu/GDC as a water gas shift catalyst provided the highest CH4 conversion and H2 yield. An addition of Re onto Ni/GDC and Cu/GDC caused an increase in catalytic performance because Re addition could improve the catalyst reducibility and increase metal surface area as more of their surface active sites are exposed to reactants.
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