Publications
Economic Performance of Combined Solid Oxide Fuel Cell System with Carbon Capture and Storage with Methanolation and Methanation by Green Hydrogen
Feb 2025
Publication
In addition to the promotion of pumped storage and electricity storage batteries the minimum use of inexpensive thermal power generation for the regulation of power in Japan and other countries is being considered as a supply-demand stabilization device with the expected widespread introduction of renewable energy by 2050. Therefore this study analyzed the economics related to the introduction of solid oxide fuel cell combined cycle using liquefied natural gas as a regulating power. The commercialization of recovered CO2 has been investigated for reducing the overall system operating costs. This study investigated a combined solid oxide fuel cell CO2 utilization system that employed green hydrogen methanolation and methanation to facilitate the use of the CO2 captured by the system. CO2 was separated from the exhaust gas of the system captured stored and used through methanation and methanolation. Consequently the synthesized methane was used for solid oxide fuel cell power generation and the synthesized methanol was sold. The discounted cash flow method was employed to evaluate the economic performance of the proposed system. At a unit price of 0.7–0.9 USD/kWh for electricity sold rated outputs of 1250 and 390 MW for solid oxide fuel cell combined cycle and photovoltaics respectively carbon capture and storage equipment cost of 800 USD/kWh and discount rate of 0.3 % the simple integrated payback period was obtained as 9 years whereas the dynamic payback period was 11–30 years. Consequently the economic feasibility of the proposed system was demonstrated.
Towards Hydrogen-powered Electric Aircraft: Physics-informed Machine Learning Based Multi-domain Modelling and Real-time Digital Twin Emulation on FPGA
Mar 2025
Publication
In response to environmental concerns related to carbon and nitrogen emissions hydrogen-powered aircraft (HPA) are poised for significant development over the coming decades driven by advances in power electronics technology. However HPA systems present complex multi-domain challenges encompassing electrical hydraulic mechanical and chemical disciplines necessitating efficient modeling and robust validation platforms. This paper introduces a physics-informed machine learning (PIML) approach for multi-domain HPA system modeling enhanced by hardware accelerated parallel hardware emulation to construct a real-time digital twin. It delves into the physical analysis of various HPA subsystems whose equations form the basis for both traditional numerical solution methods like Euler’s and Runge-Kutta methods (RKM) as well as the physics-informed neural networks (PINN) components developed herein. By comparing physics-feature neural networks (PFNN) and PINN with conventional neural network strategies this paper elucidates their advantages and limitations in practical applications. The final implementation on the Xilinx® UltraScale+™ VCU128 FPGA platform showcases the PIML method’s high efficiency accuracy data independence and adherence to established physical laws demonstrating its potential for advancing real-time multi-domain HPA emulation.
Fuel Cell Electric Vehicle Hydrogen Consumption and Battery Cycle Optimization Using Bald Eagle Search Algorithm
Sep 2024
Publication
In this study the Bald Eagle Search Algorithm performed hydrogen consumption and battery cycle optimization of a fuel cell electric vehicle. To save time and cost the digital vehicle model created in Matlab/Simulink and validated with real-world driving data is the main platform of the optimization study. The digital vehicle model was run with the minimum and maximum battery charge states determined by the Bald Eagle Search Algorithm and hydrogen consumption and battery cycle values were obtained. By using the algorithm and digital vehicle model together hydrogen consumption was minimized and range was increased. It was aimed to extend the life of the parts by considering the battery cycle. At the same time the number of battery packs was included in the optimization and its effect on consumption was investigated. According to the study results the total hydrogen consumption of the fuel cell electric vehicle decreased by 57.8% in the hybrid driving condition 23.3% with two battery packs and 36.27% with three battery packs in the constant speed driving condition.
Review of Reforming Processes for the Production of Green Hydrogen from Landfill Gas
Dec 2024
Publication
The growing challenges of climate change the depletion of fossil fuel reserves and the urgent need for carbon-neutral energy solutions have intensified the focus on renewable energy. In this perspective the generation of green hydrogen from renewable sources like biogas/landfill gas (LFG) offers an intriguing option providing the dual benefits of a sustainable hydrogen supply and enhanced waste management through energy innovation and valorization. Thus this review explores the production of green hydrogen from biogas/LFG through four conventional reforming processes specifically dry methane reforming (DMR) steam methane reforming (SMR) partial oxidation reforming (POX) and autothermal reforming (ATR) focusing on their mechanisms operating parameters and the role of catalysts in hydrogen production. This review further delves into both the environmental aspects specifically GWP (CO2 eq·kg−1 H2) emissions and the economic aspects of these processes examining their efficiency and impact. Additionally this review also explores hydrogen purification in biogas/LFG reforming and its integration into the CO2 capture utilization and storage roadmap for net-negative emissions. Lastly this review highlights future research directions focusing on improving SMR and DMR biogas/LFG reforming technologies through simulation and modeling to enhance hydrogen production efficiency thereby advancing understanding and informing future research and policy initiatives for sustainable energy solutions.
Exhaust Gas Aftertreatment to Minimize Nox Emissions from Hydrogen-fueled Internal Combustion Engines
Oct 2023
Publication
Hydrogen-fueled internal combustion engines are a promising CO2-free and zero-impact emission alternative to battery or fuel cell electric powertrains. Advantages include long service life robustness against fuel impurities and a strong infrastructural base with existing production lines and workshop stations. In order to make hydrogen engines harmless in terms of pollutant emissions as well NOX emissions at the tailpipe must be reduced as low as the zero-impact emission level. Here the application of selective catalytic reduction (SCR) catalysts is a promising solution that can be rapidly adopted from conventional diesel engines. This paper therefore investigates the influences of the hydrogen concentration in the raw exhaust gas of the NO2/NOX ratio and of the space velocity on the performance of two different SCR technologies. The results show that both types of SCR copper-zeolite and vanadium-based have their advantages and drawbacks. Copper-based SCR catalysts have an early light-off temperature and reach maximum efficiencies of up to >99%. On the other hand vanadium systems promise almost no secondary N2O emissions. As a result we combined both approaches to create a superior solution with high efficiency and lowest secondary emissions.
Eye-readable Sensors for Intuitive Hydrogen Monitoring
Apr 2024
Publication
Hydrogen energy is a cornerstone of the future climate-neutral economy. Yet as undetected leaks easily generate dangerous atmospheres sensing systems must timely detect accumulated hydrogen to prevent ignitions and explosions. Eye-readable sensors (ERSs) displaying intuitive readouts promise to guarantee safe use and universal access to hydrogen-based technology. This review highlights the impact of reversible ERSs in hydrogen moni toring to contextualize their current and potential applicability. First sensing mechanisms for gasochromic tungsten oxide films and switchable metal hydrides are critically overviewed. Then pivotal strategies targeting real-time monitorization indoors and permanent leak recording outdoors are presented along with standard hydrogen leakage scenarios elucidating opportunities for ERSs. Finally important challenges and desirable userfriendly concepts are discussed with the purpose of narrowing the gap between this class of sensors and the forthcoming hydrogen society.
Diffusive Mixing Between Hydrogen and Carbon Dioxide: Implications for Underground Hydrogen Storage
Feb 2025
Publication
The diffusive process between hydrogen (H2) and cushion gas affects the purity of H2 stored in the subsurface porous media. It is essential to understand the diffusive mass transfer and its impact on the migration of H2. Carbon dioxide (CO2) serves as a promising option for cushion gas. However due to experimental challenges there has been limited research conducted to quantify the diffusion between H2 and CO2 under reservoir conditions. For the first time we quantitatively measured the horizontal diffusive process between H2 and CO2 without convection interference in a high-pressure optical cell. The Raman spectroscopy is used to monitor the diffusive process in real-time and the diffusion coefficient is determined based on the measured concentration profiles. We showed that the Fick’s second law with a constant diffusion coefficient describes adequately the observed diffusive process. The resulting diffusion coefficient scales linearly with the reciprocal viscosity of CO2. Based on the measured diffusion coefficient we conducted a numerical study at field-scale. Results suggest that the dispersive mixing plays a role in the purity of produced H2.
Optimal Integration of Hybrid Renewable Energy Systems for Decarbonized Urban Electrification and Hydrogen Mobility
Aug 2024
Publication
This study addresses cost-optimal sizing and energy management of a grid-integrated solar photovoltaic wind turbine hybrid renewable energy system integrated with electrolyzer and hydrogen storage tank to simultaneously meet electricity and hydrogen demands considering the case study of Dijon France. Mixed Integer Linear Programming optimization problem is formulated to evaluate two objective case scenarios: single objective and multi-objective minimizing total annual costs and grid carbon emission footprint. The study incorporates various technical economic and environmental indicators focusing on the impact of sensitivity lying on various grid electricity purchase rates within the French electricity market prices. The results highlight that rising grid prices drive increased integration of renewable sources while lower prices favor ultimate grid dependency. Constant hydrogen demand necessitates the installation of two electrolyzers. Notably grid electricity prices above 60 e/MWh result increase in the size of the hydrogen tank and electrolyzer operation to prevent renewable energy losses. Grid prices above 140 e/MWh depict 70% of electrical and 80% of electrolyzer demand provided by the renewable generation resulting in a carbon emission below 0.0416 Mt of CO2 and 0.643 kgCO2 /kgH2 . Conversely grid prices below 20 e/MWh lead ultimately to 100% grid dependency with a higher carbon emission of approximately 0.14 Mt of CO2 and 4.13 kgCO2 /kgH2 reducing the total annual cost to 41.63 Million e. Increase in grid prices from 20e/MWh to 180 e/MWh resulted in increase of hydrogen specific costs from 1.23 to 3.58 e/kgH2 . Finally the Pareto front diagram is employed to illustrate the trade-off between total annual cost and carbon emission due to grid imports aiding in informed decision-making.
Efficient Solar-powered PEM Electrolysis for Sustainable Hydrogen Production: An Integrated Approach
Apr 2024
Publication
The coupling of photovoltaics (PVs) and PEM water electrolyzers (PEMWE) is a promising method for generating hydrogen from a renewable energy source. While direct coupling is feasible the variability of solar radiation presents challenges in efcient sizing. This study proposes an innovative energy management strategy that ensures a stable hydrogen production rate even with fuctuating solar irradiation. By integrating battery-assisted hydrogen production this approach allows for decentralized grid-independent renewable energy systems mitigating instability from PV intermittency. The system utilizes electrochemical storage to absorb excess energy during periods of low or very high irradiation which falls outside the electrolyzer’s optimal power input range. This stored energy then supports the PV system ensuring the electrolyzer operates near its nominal capacity and optimizing its lifetime. The system achieves an efciency of 7.78 to 8.81% at low current density region and 6.6% at high current density in converting solar energy into hydrogen.
Research on Energy Management in Hydrogen–Electric Coupled Microgrids Based on Deep Reinforcement Learning
Aug 2024
Publication
Hydrogen energy represents an ideal medium for energy storage. By integrating hydrogen power conversion utilization and storage technologies with distributed wind and photovoltaic power generation techniques it is possible to achieve complementary utilization and synergistic operation of multiple energy sources in the form of microgrids. However the diverse operational mechanisms varying capacities and distinct forms of distributed energy sources within hydrogen-coupled microgrids complicate their operational conditions making fine-tuned scheduling management and economic operation challenging. In response this paper proposes an energy management method for hydrogen-coupled microgrids based on the deep deterministic policy gradient (DDPG). This method leverages predictive information on photovoltaic power generation load power and other factors to simulate energy management strategies for hydrogen-coupled microgrids using deep neural networks and obtains the optimal strategy through reinforcement learning ultimately achieving optimized operation of hydrogen-coupled microgrids under complex conditions and uncertainties. The paper includes analysis using typical case studies and compares the optimization effects of the deep deterministic policy gradient and deep Q networks validating the effectiveness and robustness of the proposed method.
Integrated Home Energy Management with Hybrid Backup Storage and Vehicle-to-Home Systems for Enhanced Resilience, Efficiency, and Energy Independence in Green Buildings
Sep 2024
Publication
This study presents an innovative home energy management system (HEMS) that incorporates PV WTs and hybrid backup storage systems including a hydrogen storage system (HSS) a battery energy storage system (BESS) and electric vehicles (EVs) with vehicle-to-home (V2H) technology. The research conducted in Liaoning Province China evaluates the performance of the HEMS under various demand response (DR) scenarios aiming to enhance resilience efficiency and energy independence in green buildings. Four DR scenarios were analyzed: No DR 20% DR 30% DR and 40% DR. The findings indicate that implementing DR programs significantly reduces peak load and operating costs. The 40% DR scenario achieved the lowest cumulative operating cost of $749.09 reflecting a 2.34% reduction compared with the $767.07 cost in the No DR scenario. The integration of backup systems particularly batteries and fuel cells (FCs) effectively managed energy supply ensuring continuous power availability. The system maintained a low loss of power supply probability (LPSP) indicating high reliability. Advanced optimization techniques particularly the reptile search algorithm (RSA) are crucial in enhancing system performance and efficiency. These results underscore the potential of hybrid backup storage systems with V2H technology to enhance energy independence and sustainability in residential energy management.
Sustainable Integration of Green Hydrogen in Renewable Energy Systems for Residential and EV Applications
Jan 2024
Publication
The surge in interest surrounding renewable energy stems from concerns regarding pollution and the finite supply ofnonrenewable resources. Solar PV and wind hybrid renewable energy systems (HRES) are increasingly recognized as practicaland cost-effective solutions particularly in remote areas. However the intermittent nature of solar and wind power presents achallenge. To address this incorporating a hydrogen source into the system has been proposed. This study focuses onmodelling and sizing a hybrid energy system tailored for remote areas accommodating both home and electric vehicle loads.The simulation is conducted for Siliguri West Bengal India with the goal of optimizing productivity minimizing expensesand considering economic factors using HOMER Pro software. The integration of green hydrogen-based power generationwith photovoltaic and wind HRES emerges as an effective solution. Solar power in particular showcases promisingopportunities for the electrolysis process and HRES systems. The presented work facilitates the modelling of a green hydrogen-based green energy system taking into account capacity cost and emission constraints. Various case studies are conducted toenhance system efficiency and reduce the costs of energy (COE). In this paper three cases of grid-connected and three cases ofoff-grid or grid-disconnected systems are considered for highlighting the benefits of hydrogen energy incorporation in bothtypes of systems. This research contributes to sustainable energy solutions advancing a greener and more efficient energylandscape especially in addressing the recent development in load combinations of home and electric vehicle loads in bothgrid-connected as well as grid-disconnected system.
Fuelling a Clean Future: A Systematic Review of Techno-Economic and Life Cycle Assessments in E-Fuel Development
Aug 2024
Publication
The transition to sustainable energy has ushered in the era of electrofuels (e-fuels) which are synthesised using electricity from renewable sources water and CO2 as a sustainable alternative to fossil fuels. This paper presents a systematic review of the techno-economic (TEA) and life cycle assessments (LCAs) of e-fuel production. We critically evaluate advancements in production technologies economic feasibility environmental implications and potential societal impacts. Our findings indicate that while e-fuels offer a promising solution to reduce carbon emissions their economic viability depends on optimising production processes and reducing input material costs. The LCA highlights the necessity of using renewable energy for hydrogen production to ensure the genuine sustainability of e-fuels. This review also identifies knowledge gaps suggesting areas for future research and policy intervention. As the world moves toward a greener future understanding the holistic implications of e-fuels becomes paramount. This review aims to provide a comprehensive overview to guide stakeholders in their decision-making processes.
A Review of the Use of Hydrogen in Compression Ignition Engines with Dual-Fuel Technology and Techniques for Reducing NOx Emissions
Apr 2024
Publication
The use of compression ignition engines (CIEs) is associated with increased greenhouse gas emissions. It is therefore necessary to research sustainable solutions and reduce the negative environmental impact of these engines. A widely studied alternative is the use of H2 in dual-fuel mode. This review has been developed to include the most recent studies on the subject to collect and compare their main conclusions on performance and emissions. Moreover this study includes most relevant emission control strategies that have not been extensively analyzed in other reviews on the subject. The main conclusion drawn from the literature is the negative effect of the addition of H2 on NOx. This is due to the increase in temperature during combustion which increases NOx formation as the thermal mechanism predominates. Therefore to reduce these emissions three strategies have been studied namely exhaust gas recirculation (EGR) water injection (WI) and compression ratio (CR) reduction. The effect of these techniques on NOx reduction together with their effect on other analyzed performance parameters have been deeply analyzed. The studies reviewed in this work indicate that hydrogen is an alternative fuel for CIEs when used in conjunction with techniques that have proven to be effective in reducing NOx.
Multi-Objective Parameter Configuration Optimization of Hydrogen Fuel Cell Hybrid Power System for Locomotives
Sep 2024
Publication
Conventional methods of parameterizing fuel cell hybrid power systems (FCHPS) often rely on engineering experience which leads to problems such as increased economic costs and excessive weight of the system. These shortcomings limit the performance of FCHPS in real-world applications. To address these issues this paper proposes a novel method for optimizing the parameter configuration of FCHPS. First the power and energy requirements of the vehicle are determined through traction calculations and a real-time energy management strategy is used to ensure efficient power distribution. On this basis a multi-objective parameter configuration optimization model is developed which comprehensively considers economic cost and system weight and uses a particle swarm optimization (PSO) algorithm to determine the optimal configuration of each power source. The optimization results show that the system economic cost is reduced by 8.76% and 18.05% and the weight is reduced by 11.47% and 9.13% respectively compared with the initial configuration. These results verify the effectiveness of the proposed optimization strategy and demonstrate its potential to improve the overall performance of the FCHPS.
Strategic Public Relations Policy for Accelerating Hydrogen Acceptance: Insights from an Expert Survey in South Korea
Aug 2024
Publication
Hydrogen has great growth potential due to its green carbon-neutral nature but public acceptance is low due to negative perceptions of the dangers associated with hydrogen energy. Safety concerns particularly related to its flammability and explosiveness are an obstacle to hydrogen energy policy. In South Korea recent hydrogen-related explosions have exacerbated these concerns undermining public confidence. This study developed public relations (PR) strategies to manage risk perception and promote hydrogen energy acceptance by analyzing the opinions of government officials and experts using SWOT factors the TOWS matrix and the analytic hierarchy process. The findings highlight the importance of addressing weaknesses and threats in PR efforts. Key weaknesses include Korea’s technological lag and the low localization of core hydrogen technologies both of which hinder competitiveness and negatively impact public perception of hydrogen energy. Notable threats include deteriorating energy dependency and expanding global carbon regulations. This information can be used to influence attitudes and foster public acceptance of hydrogen energy policies. Emphasizing weaknesses and threats may result in more effective PR strategies even if they do not directly address the primary concerns of scientific experts. The persuasive insights identified in this study can support future policy communication and PR strategies.
The Use of Alternative Fuels for Maritime Decarbonization: Special Marine Environmental Risks and Solutons from an International Law Perspective
Jan 2023
Publication
The introduction of several alternative marine fuels is considered an important strategy for maritime decarbonization. These alternative marine fuels include liquefied natural gas (LNG) liquefied biogas (LBG) hydrogen ammonia methanol ethanol hydrotreated vegetable oil (HVO) etc. In some studies nuclear power and electricity are also included in the scope of alternative fuels for merchant ships. However the operation of alternative-fuel-powered ships has some special risks such as fuel spills vapor dispersion and fuel pool fires. The existing international legal framework does not address these risks sufficiently. This research adopts the method of legal analysis to examine the existing international legal regime for regulating the development of alternative-fuel-powered ships. From a critical perspective it evaluates and predicts the consequences of these policies together with their shortcomings. Also this research explores the potential solutions and countermeasures that might be feasible to deal with the special marine environmental risks posed by alternative-fuel-powered ships in the future.
Profitability of Hydrogen Production: Assessment of Investments in Electrolyser Under Various Market Circumstances
Aug 2024
Publication
Although hydrogen is increasingly seen as a crucial energy carrier in future zero-carbon energy system a profitable exploitation of electrolysers requires still high amounts of subsidies. To analyze the profitability of electrolysers attention has to be paid not only to the costs but also to the interaction between electricity and hydrogen markets. Using a model of internationally integrated electricity and hydrogen markets this paper analyses the profitability of electrolysers plants in various future market circumstances. We find that in particular the future supply of renewable electricity the demand for electricity as well as the prices of natural gas and carbon strongly affect the profitability of electrolysis. In order to make massive investments in electrolysers profitable with significantly lower subsidy requirements the amount of renewable electricity generation needs to grow strongly and the carbon prices should be higher while the demand for electricity should not increase accordingly. This research underscores the critical role of market conditions in shaping the viability of hydrogen electrolysis providing valuable insights for policymakers and stakeholders in the transition to a zero-carbon energy system.
Green Hydrogen and Wind Synergy: Assessing Economic Benefits and Optimal Operational Strategies
Aug 2024
Publication
Volatile electricity prices have raised concerns about the economic feasibility of wind projects in Finland. This study assesses the economic viability and optimal operational strategies for integrating wind-powered green hydrogen production systems. Utilizing modeling and optimization this research evaluates various wind farms in Western Finland over electricity market scenarios from 2019 to 2022 with forecasts extending to 2030. Key economic metrics considered include internal rate of return future value net present value (NPV) and the levelized cost of hydrogen (LCOH). Results indicate that integration of hydrogen production with wind farms shows economic benefits over standalone wind projects potentially reducing LCOH to €2.0/kgH2 by 2030 in regular and low electricity price scenarios and to as low as €0.6/kgH2 in high-price scenarios. The wind farm with the highest capacity factor achieves 47% reductions in LCOH and 22% increases in NPV underscoring the importance of strategic site selection and operational flexibility.
Recent Advancements of Polymeric Membranes in Anion Exchange Membrane Water Electrolyzer (AEMWE): A Critical Review
Apr 2023
Publication
The formation of green hydrogen from water electrolysis is one of the supreme methodologies for understanding the well-organized consumption of sporadic renewable energies and the carbon-free future. Among the different electrolysis techniques the evolving anion exchange membrane water electrolysis (AEMWE) shows the utmost promise for manufacturing green hydrogen in an inexpensive way. In the present review we establish the most current and noteworthy achievements of AEMWE which include the advancements in increasing the ionic conductivity and understanding the mechanism of degradation of AEM and the most important topics regarding the designing of the electrocatalyst. The crucial issues that affect the AEMWE behavior are highlighted and future constraints and openings are also discussed. Furthermore this review article provides the appreciated strategies for producing extremely dynamic and robust electrocatalysts and evolving the construction of AEMWE equipment.
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