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Net Zero The UK's Contribution to Stopping Global Warming
May 2019
Publication
This report responds to a request from the Governments of the UK Wales and Scotland asking the Committee to reassess the UK’s long-term emissions targets. Our new emissions scenarios draw on ten new research projects three expert advisory groups and reviews of the work of the IPCC and others.<br/>The conclusions are supported by detailed analysis published in the Net Zero Technical Report that has been carried out for each sector of the economy plus consideration of F-gas emissions and greenhouse gas removals.
Committee for Climate Change Fifth Carbon Budget: Central Scenario Data
Jul 2016
Publication
This spreadsheet contains data for two future UK scenarios: a "baseline" (i.e. no climate action after 2008 the start of the carbon budget system) and the "central" scenario underpinning the CCC's advice on the fifth carbon budget (the limit to domestic emissions during the period 2028-32).<br/>The central scenario is an assessment of the technologies and behaviours that would prepare for the 2050 target cost-effectively while meeting the other criteria in the Climate Change Act (2008) based on central views of technology costs fuel prices carbon prices and feasibility. It is not prescriptive nor is it the only scenario considered for meeting the carbon budgets. For further details on our scenarios and how they were generated see the CCC report Sectoral scenarios for the Fifth Carbon Budget. The scenario was constructed for the CCC's November 2015 report and has not been further updated for example to reflect outturn data for 2015 or changes to Government policy.
The Fourth Carbon Budget Review – Part 2 The Cost-effective Path to the 2050 Target
Nov 2013
Publication
This is the second document of a two-part review of the Fourth Carbon Budget which covers 2023 to 2027. The Fourth Carbon Budget agreed by the Government in June 2011 was scheduled to be reviewed in 2014. The first part of the review is available here: The Fourth Carbon Budget Review – part 1: assessment of climate risk and the international response (November 2013).<br/>According to the Climate Change Act 2008 carbon budgets can only be altered if there is a significant change in circumstances upon which the budget was set. Any such change in circumstances must be demonstrated through evidence and analysis.<br/>The Fourth Carbon Budget Review – part 2 considers the impacts of meeting the 2023-2027 budget. The review concludes that the impacts are small and manageable and identifies broader benefits associated with meeting the fourth carbon budget including: improved energy security improved air quality and reduced noise pollution.
Hydrogen as a Clean and Sustainable Energy Vector for Global Transition from Fossil-Based to Zero-Carbon
Dec 2021
Publication
Hydrogen is recognized as a promising and attractive energy carrier to decarbonize the sectors responsible for global warming such as electricity production industry and transportation. However although hydrogen releases only water as a result of its reaction with oxygen through a fuel cell the hydrogen production pathway is currently a challenging issue since hydrogen is produced mainly from thermochemical processes (natural gas reforming coal gasification). On the other hand hydrogen production through water electrolysis has attracted a lot of attention as a means to reduce greenhouse gas emissions by using low-carbon sources such as renewable energy (solar wind hydro) and nuclear energy. In this context by providing an environmentally-friendly fuel instead of the currently-used fuels (unleaded petrol gasoline kerosene) hydrogen can be used in various applications such as transportation (aircraft boat vehicle and train) energy storage industry medicine and power-to-gas. This article aims to provide an overview of the main hydrogen applications (including present and future) while examining funding and barriers to building a prosperous future for the nation by addressing all the critical challenges met in all energy sectors.
Meeting Carbon Budgets – Ensuring a Low-carbon Recovery
Jun 2010
Publication
As part of its statutory role the Committee provides annual reports to Parliament on the progress that Government is making in meeting carbon budgets and in reducing emissions of greenhouse gases.<br/>Meeting Carbon Budgets – ensuring a low-carbon recovery is the Committee’s 2nd progress report. Within this report we assess the latest emissions data and determine whether emissions reductions have occurred as a result of the recession or as a result of other external factors. We assess Government’s progress towards achieving emissions reductions in 4 key areas of: Power Buildings and Industry Transport and Agriculture.
The Fifth Carbon Budget: The Next Step Towards a Low-carbon Economy
Nov 2015
Publication
This report sets out our advice on the fifth carbon budget covering the period 2028-2032 as required under Section 4 of the Climate Change Act; the Government will propose draft legislation for the fifth budget in summer 2016.
Paths to Low-cost Hydrogen Energy at a Scale for Transportation Applications in the USA and China via Liquid-hydrogen Distribution Networks
Dec 2019
Publication
The cost of delivered H2 using the liquid-distribution pathway will approach $4.3–8.0/kg in the USA and 26–52 RMB/kg in China by around 2030 assuming large-scale adoption. Historically hydrogen as an industrial gas and a chemical feedstock has enjoyed a long and successful history. However it has been slow to take off as an energy carrier for transportation despite its benefits in energy diversity security and environmental stewardship. A key reason for this lack of progress is that the cost is currently too high to displace petroleum-based fuels. This paper reviews the prospects for hydrogen as an energy carrier for transportation clarifies the current drivers for cost in the USA and China and shows the potential for a liquid-hydrogen supply chain to reduce the costs of delivered H2. Technical and economic trade-offs between individual steps in the supply chain (viz. production transportation refuelling) are examined and used to show that liquid-H2 (LH2) distribution approaches offer a path to reducing the delivery cost of H2 to the point at which it could be competitive with gasoline and diesel fuel.
Public Acceptability of the Use of Hydrogen for Heating and Cooking in the Home: Results from Qualitative and Quantitative Research in UK<br/>Executive Summary
Nov 2018
Publication
This report for the CCC by Madano and Element Energy assesses the public acceptability of two alternative low-carbon technologies for heating the home: hydrogen heating and heat pumps.
These technologies could potentially replace natural gas in many UK households as part of the government’s efforts to decrease carbon emissions in the UK.
The report’s key findings are:
These technologies could potentially replace natural gas in many UK households as part of the government’s efforts to decrease carbon emissions in the UK.
The report’s key findings are:
- carbon emissions reduction is viewed as an important issue but there is limited awareness of the need to decarbonise household heating or the implications of switching over to low-carbon heating technologies
- acceptability of both heating technologies is limited by a lack of perceived tangible consumer benefit which has the potential to drive scepticism towards the switch over more generally
- heating technology preferences are not fixed at this stage although heat pumps appear to be the favoured option in this research studythree overarching factors were identified as influencing preferences for heating technologies.
- perceptions of the negative installation burden
- familiarity with the lived experience of using the technologies for heating
- perceptions of how well the technologies would meet modern heating needs both hydrogen heating and heat pumps face significant challenges to secure public acceptability
An Independent Assessment of the UK’s Clean Growth Strategy: From Ambition to Action
Nov 2018
Publication
This report provides the Committee on Climate Change’s response to the UK Government’s Clean Growth Strategy.
The report finds that:
The report finds that:
- The Government has made a strong commitment to achieving the UK’s climate change targets.
- Policies and proposals set out in the Clean Growth Strategy will need to be firmed up.
- Gaps to meeting the fourth and fifth carbon budgets remain. These gaps must be closed.
- Risks of under-delivery must be addressed and carbon budgets met on time.
Future Regulation of the Gas Grid
Jun 2016
Publication
The CCC has established a variety of viable scenarios in which UK decarbonisation targets can be met. Each has consequences for the way in which the UK’s gas network infrastructure is utilised. This report considers the implications of decarbonisation for the future regulation of the gas grid.<br/>The CCC’s 5th Carbon Budget envisaged different scenarios that would enable the UK to meet its emissions targets for 2050. These scenarios represent holistic analyses based on internally consistent combinations of different technologies which could deliver carbon reductions across different sectors of the economy.<br/>The CCC’s scenarios incorporate projections of the demand for natural gas to 2050. The scenarios imply that the volume of throughput on the gas networks1 and the nature and location of network usage is likely to change significantly to meet emissions targets. They are also characterised by significant uncertainty.<br/>Under some decarbonisation scenarios gas networks could be re-purposed to supply hydrogen instead of natural gas meaning there would be ongoing need for network infrastructure.<br/>In other scenarios gas demand in buildings is largely replaced by electric alternatives meaning portions of the low pressure gas distribution networks could be decommissioned.<br/>Patchwork scenarios are also possible in which there is a mixture of these outcomes across the country.<br/>In this project the CCC wished to assess the potential implications for gas networks under these different demand scenarios; and evaluate the associated challenges for Government and regulatory policy. The challenge for BEIS and Ofgem is how to regulate in a way that keeps options open while uncertainty persists about the best solution for the UK; and at the same time how best to make policy and regulatory decisions which would serve to reduce this uncertainty. Both Government and Ofgem have policy and regulatory levers that they can use – and we identify and evaluate such levers in this report.
The Role of Charging and Refuelling Infrastructure in Supporting Zero-emission Vehicle Sales
Mar 2020
Publication
Widespread uptake of battery electric plug-in hybrid and hydrogen fuel-cell vehicles (collectively zero-emissions vehicles or ZEVs) could help many regions achieve deep greenhouse gas mitigation goals. Using the case of Canada this study investigates the extent to which increasing ZEV charging and refuelling availability may boost ZEV sales relative to other ZEV-supportive policies. We adapt a version of the Respondent-based Preferences and Constraints (REPAC) model using 2017 survey data from 1884 Canadian new vehicle-buyers to simulate the sales impacts of increasing electric vehicle charging access at home work public destinations and on highways as well as increasing hydrogen refuelling station access. REPAC is built from a stated preference choice model and represents constraints in supply and consumer awareness as well as dynamics in ZEV policy out to 2030. Results suggest that new ZEV market share from 2020 to 2030 does not substantially benefit from increased infrastructure. Even when electric charging and hydrogen refuelling access are simulated to reach “universally” available levels by 2030 ZEV sales do not rise by more than 1.5 percentage points above the baseline trajectory. On the other hand REPAC simulates ZEV market share rising as high as 30% by 2030 with strong ZEV-supportive policies even without the addition of charging or refuelling infrastructure. These findings stem from low consumer valuation of infrastructure found in the stated preference model. Results suggest that achieving ambitious ZEV sale targets requires a comprehensive suite of policies beyond a focus on charging and refuelling infrastructure.
Meeting Carbon Budgets – 2014 Progress Report to Parliament
Jul 2014
Publication
This is our sixth statutory report to Parliament on progress towards meeting carbon budgets. In it we consider the latest data on emissions and their drivers. This year the report also includes a full assessment of how the first carbon budget (2008-2012) was met drawing out policy lessons and setting out what is required for the future to stay on track for the legislated carbon budgets and the 2050 target. The report includes assessment at the level of the economy the non-traded and traded sectors the key emitting sectors and the devolved administrations. Whilst the first carbon budget has been met and progress made on development and implementation of some policies the main conclusion is that strengthening of policies will be needed to meet future budgets.
Electric and Hydrogen Buses: Shifting from Conventionally Fuelled Cars in the UK
May 2020
Publication
For the UK to meet their national target of net zero emissions as part of the central Paris Agreement target further emphasis needs to be placed on decarbonizing public transport and moving away from personal transport (conventionally fuelled vehicles (CFVs) and electric vehicles (EVs)). Electric buses (EBs) and hydrogen buses (HBs) have the potential to fulfil requirements if powered from low carbon renewable energy sources.
A comparison of carbon dioxide (CO2) emissions produced from conventionally fuelled buses (CFB) EBs and HBs between 2017 and 2050 under four National Grid electricity scenarios was conducted. In addition emissions per person at different vehicle capacity levels (100% 75% 50% and 25%) were projected for CFBs HBs EBs and personal transport assuming a maximum of 80 passengers per bus and four per personal vehicle.
Results indicated that CFVs produced 30 g CO2km−1 per person compared to 16.3 g CO2 km−1 per person by CFBs by 2050. At 100% capacity under the two-degree scenario CFB emissions were 36 times higher than EBs 9 times higher than HBs and 12 times higher than EVs in 2050. Cumulative emissions under all electricity scenarios remained lower for EBs and HBs.
Policy makers need to focus on encouraging a modal shift from personal transport towards sustainable public transport primarily EBs as the lowest level emitting vehicle type. Simple electrification of personal vehicles will not meet the required targets. Simultaneously CFBs need to be replaced with EBs and HBs if the UK is going to meet emission targets.
A comparison of carbon dioxide (CO2) emissions produced from conventionally fuelled buses (CFB) EBs and HBs between 2017 and 2050 under four National Grid electricity scenarios was conducted. In addition emissions per person at different vehicle capacity levels (100% 75% 50% and 25%) were projected for CFBs HBs EBs and personal transport assuming a maximum of 80 passengers per bus and four per personal vehicle.
Results indicated that CFVs produced 30 g CO2km−1 per person compared to 16.3 g CO2 km−1 per person by CFBs by 2050. At 100% capacity under the two-degree scenario CFB emissions were 36 times higher than EBs 9 times higher than HBs and 12 times higher than EVs in 2050. Cumulative emissions under all electricity scenarios remained lower for EBs and HBs.
Policy makers need to focus on encouraging a modal shift from personal transport towards sustainable public transport primarily EBs as the lowest level emitting vehicle type. Simple electrification of personal vehicles will not meet the required targets. Simultaneously CFBs need to be replaced with EBs and HBs if the UK is going to meet emission targets.
Quantitative Evaluations of Hydrogen Diffusivity in V-X (X = Cr, Al, Pd) Alloy Membranes Based on Hydrogen Chemical Potential
Jan 2021
Publication
Vanadium (V) has higher hydrogen permeability than Pd-based alloy membranes but exhibits poor resistance to hydrogen-induced embrittlement. The alloy elements are added to reduce hydrogen solubility and prevent hydrogen-induced embrittlement. To enhance hydrogen permeability the alloy elements which improve hydrogen diffusivity in V are more suitable. In the present study hydrogen diffusivity in V-Cr V-Al and V-Pd alloy membranes was investigated in view of the hydrogen chemical potential and compared with the previously reported results of V-Fe alloy membranes. The additions of Cr and Fe to V improved the mobility of hydrogen atoms. In contrast those of Al and Pd decreased hydrogen diffusivity. The first principle calculations revealed that the hydrogen atoms cannot occupy the first-nearest neighbour T sites (T1 sites) of Al and Pd in the V crystal lattice. These blocking effects will be a dominant contributor to decreasing hydrogen diffusivity by the additions of Al and Pd. For V-based alloy membranes Fe and Cr are more suitable alloy elements compared with Al and Pd in view of hydrogen diffusivity.
Operation Analysis of Selected Domestic Appliances Supplied with Mixture of Nitrogen-Rich Natural Gas with Hydrogen
Dec 2021
Publication
This is article presents the results of the testing of the addition of a hydrogen-to-nitrogen-rich natural gas of the Lw group and its influence on the operation of selected gas-fired domestic appliances. The tests were performed on appliances used for the preparation of meals and hot water production for hygienic and heating purposes. The characteristics of the tested gas appliances are also presented. The burners and their controllers with which the tested appliances were equipped were adapted for the combustion of Lw natural gas. The tested appliances reflected the most popular designs for domestic gas appliances in their group used both in Poland and in other European countries. The tested appliances were supplied with nitrogen-rich natural gas of the Lw group and a mixture of this gas with hydrogen at 13.2% content. The article presents the approximate percentage compositions of the gases used during the tests and their energy parameters. The research was focused on checking the following operating parameters and the safety of the tested appliances: the rated heat input thermal efficiency combustion quality ignition flame stability and transfer. The article contains an analysis of the test results referring in detail to the issue of decreasing the heat input of the appliances by lowering the energy parameters of the nitrogen-rich natural gas of the Lw group mixture with a hydrogen addition and how it influenced the thermal efficiency achieved by the appliances. The conclusions contain an explanation regarding among other things how the design of an appliance influences the thermal efficiency achieved by it in relation to the heat input decrease. In the conclusions on the basis of the research results answers have been provided to the following questions: (1) Whether the hydrogen addition to the nitrogen-rich natural gas of the Lw group will influence the safe and proper operation of domestic gas appliances; (2) What hydrogen percentage can be added to the nitrogen-rich natural gas of the Lw group in order for the appliances adapted for combusting it to operate safely and effectively without the need for modifying them?
Two-Stage Energy Management Strategies of Sustainable Wind-PV-Hydrogen-Storage Microgrid Based on Receding Horizon Optimization
Apr 2022
Publication
Hydrogen and renewable electricity-based microgrid is considered to be a promising way to reduce carbon emissions promote the consumption of renewable energies and improve the sustainability of the energy system. In view of the fact that the existing day-ahead optimal operation model ignores the uncertainties and fluctuations of renewable energies and loads a two-stage energy management model is proposed for the sustainable wind-PV-hydrogen-storage microgrid based on receding horizon optimization to eliminate the adverse effects of their uncertainties and fluctuations. In the first stage the day-ahead optimization is performed based on the predicted outpower of WT and PV the predicted demands of power and hydrogen loads. In the second stage the intra-day optimization is performed based on the actual data to trace the day-ahead operation schemes. Since the intra-day optimization can update the operation scheme based on the latest data of renewable energies and loads the proposed two-stage management model is effective in eliminating the uncertain factors and maintaining the stability of the whole system. Simulations show that the proposed two-stage energy management model is robust and effective in coordinating the operation of the wind-PV-hydrogen-storage microgrid and eliminating the uncertainties and fluctuations of WT PV and loads. In addition the battery storage can reduce the operation cost alleviate the fluctuations of the exchanged power with the power grid and improve the performance of the energy management model.
Optimized Operation Plan for Hydrogen Refueling Station with On-Site Electrolytic Production
Dec 2022
Publication
The cost reduction of hydrogen refueling stations (HRSs) is very important for the popularization of hydrogen vehicles. This paper proposes an optimized operation algorithm based on hydrogen energy demand estimation for on-site hydrogen refueling stations. Firstly the user’s hydrogen demand was estimated based on the simulation of their hydrogenation behavior. Secondly mixed integer linear programming method was used to optimize the operation of the hydrogen refueling station to minimize the unit hydrogen energy cost by using the peak–valley difference of the electricity price. We then used three typical scenario cases to evaluate the optimized operation method. The results show that the optimized operation method proposed in this paper can effectively reduce the rated configuration of electrolyzer and storage tank for HRS and can significantly reduce the unit hydrogen energy cost considering the construction cost compared with the traditional method. Therefore the optimization operation method of a local hydrogen production and hydrogen refueling station proposed in this paper can reduce the cost of a hydrogen refueling station and accelerate the popularization of hydrogen energy vehicles. Finally the scope of application of the proposed optimization method and the influence of the variation of the electricity price curve and the unit cost of the electrolyzer are discussed.
CFD Computations of Liquid Hydrogen Releases
Sep 2011
Publication
Hydrogen is widely recognized as an attractive energy carrier due to its low-level air pollution and its high mass-related energy density. However its wide flammability range and high burning velocity present a potentially significant hazard. A significant fraction of hydrogen is stored and transported as a cryogenic liquid (liquid hydrogen or LH2) as it requires much less volume compared to gaseous hydrogen. In order to exist as a liquid H2 must be cooled to a very low temperature 20.28 K. LH2 is a common liquid fuel for rocket applications. It can also be used as the fuel storage in an internal combustion engine or fuel cell for transport applications. Models for handling liquid releases both two-phase flashing jets and pool spills have been developed in the CFD-model FLACS. The very low normal boiling point of hydrogen (20 K) leads to particular challenges as this is significantly lower than the boiling points of oxygen (90 K) and nitrogen (77 K). Therefore a release of LH2 in the atmosphere may induce partial condensation or even freezing of the oxygen and nitrogen present in the air. A pool model within the CFD software FLACS is used to compute the spreading and vaporization of the liquid hydrogen depositing on the ground where the partial condensation or freezing of the oxygen and nitrogen is also taken into account. In our computations of two-phase jets the dispersed and continuous phases are assumed to be in thermodynamic and kinematic equilibrium. Simulations with the new models are compared against selected experiments performed at the Health and Safety Laboratory (HSL).
Renewable Hydrogen Production from Butanol: A Review
Dec 2017
Publication
Hydrogen production from butanol is a promising alternative when it is obtained from bio-butanol or bio-oil due to the higher hydrogen content compared to other oxygenates such as methanol ethanol or propanol. Catalysts and operating conditions play a crucial role in hydrogen production. Ni and Rh are metals mainly used for butanol steam reforming oxidative steam reforming and partial oxidation. Additives such as Cu can improve catalytic activity in many folds. Moreover support–metal interaction and catalyst preparation technique also play a decisive role in the stability and hydrogen production capacity of catalyst. Steam reforming technique as an option is more frequently researched due to higher hydrogen production capability in comparison to other thermochemical techniques despite its endothermic nature. The use of the oxidative steam reforming and partial oxidation has the advantages of requiring less energy and longer stability of catalysts. However the hydrogen yield is less. This article brings together and examines the latest research on hydrogen production from butanol via steam reforming oxidative steam reforming and partial oxidation reactions. In addition the review examines a few thermodynamic studies based on sorption-enhanced steam reforming and dry reforming where there is potential for hydrogen extraction.
Hydrogen Onboard Storage: An Insertion of the Probabilistic Approach Into Standards & Regulations?
Sep 2005
Publication
The growing attention being paid by car manufacturers and the general public to hydrogen as a middle and long term energy carrier for automotive purpose is giving rise to lively discussions on the advantages and disadvantages of this technology – also with respect to safety. In this connection the focus is increasingly and justifiably so on the possibilities offered by a probabilistic approach to loads and component characteristics: a lower weight obliged with a higher safety level basics for an open minded risk communication the possibility of a provident risk management the conservation of resources and a better and not misleading understanding of deterministic results. But in the case of adequate measures of standards or regulations completion there is a high potential of additional degrees of freedom for the designers obliged with a further increasing safety level. For this purpose what follows deals briefly with the terminological basis and the aspects of acceptance control conservation of resources misinterpretation of deterministic results and the application of regulations/standards.<br/>This leads into the initial steps of standards improvement which can be taken with relatively simple means in the direction of comprehensively risk-oriented protection goal specifications. By this it’s not focused on to provide to much technical details. It’s focused on the context of different views on probabilistic risk assessment. As main result some aspects of the motivation and necessity for the currently running pre-normative research studies within the 6th frame-work program of the EU will be shown.
Requirements for the Safety Assessment for the Approval of a Hydrogen Refueling Station
Sep 2007
Publication
The EC 6th framework research project HyApproval will draft a Handbook which will describe all relevant issues to get approval to construct and operate a Hydrogen Refuelling Station (HRS) for hydrogen vehicles. In WP3 of the HyApproval project it is under investigation which safety information competent authorities require to give a licence to construct an operate an HRS. The paper describes the applied methodology to collect the information from the authorities in 5 EC countries and the USA. The results of the interviews and recommendations for the information to include in the Handbook are presented.
Determination of Clearance Distances for Venting of Hydrogen Storage
Sep 2005
Publication
This paper discusses the results of computational fluid dynamics (CFD) modelling of hydrogen releases and dispersion outdoors during venting of hydrogen storage in real environment and geometry of a hydrogen refuelling or energy station for a given flow rate and dimensions of vent stack. The PHOENICS CFD software package was used to solve the continuity momentum and concentration equations with the appropriate boundary conditions buoyancy model and turbulence models. Also thermal effects resulting from potential ignition of flammable hydrogen clouds were assessed using TNO “Yellow Book” recommended approaches. The obtained results were then applied to determine appropriate clearance distances for venting of hydrogen storage for contribution to code development and station design considerations. CFD modelling of hydrogen concentrations and TNO-based modelling of thermal effects have proven to be reliable effective and relatively inexpensive tools to evaluate the effects of hydrogen releases.
Progress Report 2016: Meeting Carbon Budgets
Jun 2016
Publication
This is the CCC’s eighth annual report on the UK’s progress in meeting carbon budgets.
The report shows that greenhouse gas emissions have fallen rapidly in the UK power sector but that progress has stalled in other sectors such as:
The report also outlines the Committee’s view of key criteria for the government’s ’emissions reduction plan’ published later in 2017
The report shows that greenhouse gas emissions have fallen rapidly in the UK power sector but that progress has stalled in other sectors such as:
- heating in buildings
- transport
- industry
- agriculture
The report also outlines the Committee’s view of key criteria for the government’s ’emissions reduction plan’ published later in 2017
Reducing Emissions in Scotland – 2016 Progress Report
Sep 2016
Publication
This is the Committee’s fifth report on Scotland’s progress towards meeting emission reduction targets as requested by Scottish Ministers under the Climate Change (Scotland) Act 2009.<br/>The Scottish Act sets a long-term target to reduce emissions of greenhouse gases (GHGs) by at least 80% in 2050 relative to 1990 with an interim target to reduce emissions by 42% in 2020. Secondary legislation passed in October 2010 and October 2011 also set a series of annual emission reduction targets for 2010 to 2022 and 2023 to 2027 respectively. We advised the Scottish Government on annual targets for the period 2028 to 2032 in March 2016 and July 2016.<br/>The report reveals that Scotland’s annual emissions reduction target for 2014 was met with gross Scottish greenhouse gas emissions including international aviation and shipping falling by 8.6% in 2014. This compares to a 7.3% fall for the UK as a whole. Since 1990 gross Scottish emissions have fallen nearly 40% compared to nearly 33% at a UK level.
Reducing Emissions in Northern Ireland
Feb 2019
Publication
In this report the Committee sets out how Northern Ireland can reduce its greenhouse gas emissions between now and 2030 in order to meet UK-wide climate change targets.
The report’s key findings are:
The report’s key findings are:
- Existing policies are not enough to deliver this reduction
- There are excellent opportunities to close this gap and go beyond 35%
- Meeting the cost-effective path to decarbonisation in Northern Ireland will require action across all sectors of the economy and a more joined-up approach
Quantifying Greenhouse Gas Emissions
Apr 2017
Publication
In this report Quantifying Greenhouse Gas Emissions the Committee on Climate Change assesses how the UK’s greenhouse gas emissions are quantified where uncertainties lie and the implications for setting carbon budgets and measuring progress against climate change targets. The report finds that:
- The methodology for constructing the UK’s greenhouse gas inventory is rigorous but the process for identifying improvements could be strengthened.
- There is high confidence over large parts of the inventory. A small number of sectors contribute most to uncertainty and research efforts should be directed at improving these estimates.
- UK greenhouse gas emissions for 2014 were within ±3% of the estimated level with 95% confidence which is a low level of uncertainty by international standards.
- Methodology revisions in recent years have tended to increase estimated emissions but these changes have been within uncertainty margins.
- Statistical uncertainty in the current greenhouse gas inventory is low but could rise in future.
- Uncertainty also arises from sources of emissions not currently included in the inventory and from potential changes to IPCC guidelines.
- Independent external validation of greenhouse gas emissions is important and new monitoring techniques should be encouraged.
- Government should continue to monitor consumption-based greenhouse gas estimates and support continued research to improve methodology and reduce uncertainty in these estimates.
Integral Models for High Pressure Hydrogen - Methane Releases
Sep 2009
Publication
The development of hydrogen as energy carrier is promoted by the increasing in energy demand depletion of fossil resources and the global warming. However this issue relies primarily on the safety aspect which requires the knowledge in the case of gas release of the quantities such as the flammable cloud size release path and the location of the lower flammability limit of the mixture. The integral models for predicting the atmospheric dispersion were extensively used in previous works for low pressure releases such as pollutant and flammable gas transport. In the present investigation this approach is extended to the high pressure gas releases. The model is developed in the non-Boussinesq approximation and is based on Gaussian profiles for buoyant variable density jet or plume in stratified atmosphere with a crossflow. Validations have been performed on a broad range of hydrogen methane and air dispersion cases including vertical or horizontal jets or plumes into a quiescent atmosphere or with crosswind.
Reducing Emissions in Scotland – 2017 Progress Report
Sep 2017
Publication
The Scottish Act sets a long-term target to reduce emissions of greenhouse gases (GHGs) by at least 80% in 2050 relative to 1990 with an interim target to reduce emissions by 42% in 2020. Secondary legislation passed in October 2010 and October 2011 also set a series of annual emission reduction targets for 2010 to 2022 and 2023 to 2027 respectively. We advised the Scottish Government on annual targets for the period 2028 to 2032 in March 2016 and July 2016.<br/>The report reveals that Scotland’s annual emissions reduction target for 2014 was met with gross Scottish greenhouse gas emissions including international aviation and shipping falling by 8.6% in 2014. This compares to a 7.3% fall for the UK as a whole. Since 1990 gross Scottish emissions have fallen nearly 40% compared to nearly 33% at a UK level.
Reducing Emissions in Scotland 2019 Progress Report
Dec 2019
Publication
This is the eighth annual Progress Report to the Scottish Parliament required by Scottish Ministers under the Climate Change (Scotland) Act 2009. It assesses Scotland’s progress in achieving its legislated targets to reduce greenhouse gas emissions.<br/>Overall greenhouse gas emissions reduced by 3% in 2017 compared to a 10% fall in 2016. The fall was again led by the power sector due in large part to Scotland’s first full year of coal-free electricity generation. Recent performance in other sectors shows only incremental improvement at best and unless emissions reductions are delivered economy-wide Scotland is at risk of missing its new interim target of a 56% reduction in emissions by 2020. Setting a net-zero greenhouse gas emissions target for 2045 represents a step-change in ambition for Scotland. The Scottish Parliament’s 2030 target to reduce emissions by 75% will be extremely challenging to meet. It must be backed up by steps to drive meaningful emissions reductions immediately.<br/>Scotland’s Programme for Government 2019-20 alongside other recent policies sent a clear signal that the Scottish Government is taking its more ambitious targets seriously but there is much more to do.Scotland’s ability to deliver its net-zero target is contingent on action taken in the UK and vice versa.
Hydrogen in a Low-carbon Economy
Nov 2018
Publication
This report by the Committee on Climate Change (CCC) assesses the potential role of hydrogen in the UK’s low-carbon economy.
It finds that hydrogen:
It finds that hydrogen:
- is a credible option to help decarbonise the UK energy system but its role depends on early Government commitment and improved support to develop the UK’s industrial capability
- can make an important contribution to long-term decarbonisation if combined with greater energy efficiency cheap low-carbon power generation electrified transport and new ‘hybrid’ heat pump systems which have been successfully trialled in the UK
- could replace natural gas in parts of the energy system where electrification is not feasible or is prohibitively expensive for example in providing heat on colder winter days industrial heat processes and back-up power generation
- is not a ‘silver bullet’ solution; the report explores some commonly-held misconceptions highlighting the need for careful planning
- Government must commit to developing a low-carbon heat strategy within the next three years
- Significant volumes of low-carbon hydrogen should be produced in a carbon capture and storage (CCS) ‘cluster’ by 2030 to help the industry grow
- Government must support the early demonstration of the everyday uses of hydrogen in order to establish the practicality of switching from natural gas to hydrogen
- There is low awareness amongst the general public of reasons to move away from natural gas heating to low-carbon alternatives
- A strategy should be developed for low-carbon heavy goods vehicles (HGVs) which encourages a move away from fossil fuels and biofuels to zero-emission solutions by 2050
Safety Demands for Automotive Hydrogen Storage Systems
Sep 2005
Publication
Fuel storage systems for vehicles require a fail-safe design strategy. In case of system failures or accidents the control electronics have to switch the system into a safe operation mode. Failure Mode and Effect Analysis (FMEA) or Failure Tree Analysis (FTA) are performed already in the early design phase in order to minimize the risk of design failures in the fuel storage system. Currently the specifications of requirements for pressurized and liquid hydrogen fuel tanks are based on draft UN-ECE Regulations developed by the European Integrated Hydrogen Project (EIHP). Used materials and accessories shall be compatible with hydrogen. A selection of metallic and non-metallic materials will be presented. Complex components have to be optimised by FEM simulations in order to determine weak spots in the design which will be overstressed in case of pressure thermal expansion or dynamic vibrations. According to automotive standards the performance of liquid hydrogen fuel tank systems has to be verified in various destructive and non-destructive tests.
Effect of Hydrogen on the Tensile Behavior of Austenitic Stainless Steels 316L Produced by Laser-Powder Bed Fusion
Apr 2021
Publication
Hydrogen was doped in austenitic stainless steel (ASS) 316L tensile samples produced by the laser-powder bed fusion (L-PBF) technique. For this aim an electrochemical method was conducted under a high current density of 100 mA/cm2 for three days to examine its sustainability under extreme hydrogen environments at ambient temperatures. The chemical composition of the starting powders contained a high amount of Ni approximately 12.9 wt.% as a strong austenite stabilizer. The tensile tests disclosed that hydrogen charging caused a minor reduction in the elongation to failure (approximately 3.5% on average) and ultimate tensile strength (UTS; approximately 2.1% on average) of the samples using a low strain rate of 1.2 × 10−4 s−1. It was also found that an increase in the strain rate from 1.2 × 10−4 s−1 o 4.8 ×10−4 s−1 led to a reduction of approximately 3.6% on average for the elongation to failure and 1.7% on average for UTS in the pre-charged samples. No trace of martensite was detected in the X-ray diffraction (XRD) analysis of the fractured samples thanks to the high Ni content which caused a minor reduction in UTS × uniform elongation (UE) (GPa%) after the H charging. Considerable surface tearing was observed for the pre-charged sample after the tensile deformation. Additionally some cracks were observed to be independent of the melt pool boundaries indicating that such boundaries cannot necessarily act as a suitable area for the crack propagation.
Experimental Investigation of Hydrogen Jet Fire Mitigation by Barrier Walls
Sep 2009
Publication
Hydrogen jet flames resulting from ignition of unintended releases can be extensive in length and pose significant radiation and impingement hazards. One possible mitigation strategy to reduce exposure to jet flames is to incorporate barriers around hydrogen storage and delivery equipment. While reducing the extent of unacceptable consequences the walls may introduce other hazards if not properly configured. This paper describes experiments carried out to characterize the effectiveness of different barrier wall configurations at reducing the hazards created by jet fires. The hazards that are evaluated are the generation of overpressure during ignition the thermal radiation produced by the jet flame and the effectiveness of the wall at deflecting the flame.<br/>The tests were conducted against a vertical wall (1-wall configuration) and two “3-wall” configurations that consisted of the same vertical wall with two side walls of the same dimensions angled at 135° and 90°. The hydrogen jet impinged on the center of the central wall in all cases. In terms of reducing the radiation heat flux behind the wall the 1-wall configuration performed best followed by the 3-wall 135° configuration and the 3-wall 90°. The reduced shielding efficiency of the three-wall configurations was probably due to the additional confinement created by the side walls that limited the escape of hot gases to the sides of the wall and forced the hot gases to travel over the top of the wall.<br/>The 3-wall barrier with 135° side walls exhibited the best overall performance. Overpressures produced on the release side of the wall were similar to those produced in the 1-wall configuration. The attenuation of overpressure and impulse behind the wall was comparable to that of the three-wall configuration with 90° side walls. The 3-wall 135° configuration’s ability to shield the back side of the wall from the heat flux emitted from the jet flame was comparable to the 1-wall and better than the 3-wall 90° configuration. The ratio of peak overpressure (from in front of the wall and from behind the wall) showed that the 3-wall 135° configuration and the 3-wall 90° configuration had a similar effectiveness. In terms of the pressure mitigation the 3-wall configurations performed significantly better than the 1-wall configuration
Reducing Emissions in Scotland – 2018 Progress Report
Sep 2019
Publication
This is the Committee’s seventh report on Scotland’s progress towards meetings emissions targets as requested by Scottish Ministers under the Climate Change (Scotland) Act 2009.
Overall Scotland continues to outperform the rest of the UK in reducing its greenhouse gas emissions but successful strategies for energy and waste mask a lack of progress in other parts of the Scottish economy.
The report shows that Scotland’s total emissions fell by 10% in 2016 compared to 2015. The lion’s share of this latest drop in emissions came from electricity generation.
The key findings are:
Overall Scotland continues to outperform the rest of the UK in reducing its greenhouse gas emissions but successful strategies for energy and waste mask a lack of progress in other parts of the Scottish economy.
The report shows that Scotland’s total emissions fell by 10% in 2016 compared to 2015. The lion’s share of this latest drop in emissions came from electricity generation.
The key findings are:
- Overall Scotland met its annual emissions targets in 2016.
- Scotland’s progress in reducing emissions from the power sector masks a lack of action in other areas particularly transport agriculture forestry and land use.
- Low-carbon heat transport agriculture and forestry sector policies need to improve in order to hit 2032 emissions targets.
- The Scottish Government’s Climate Change Plan – published in February 2018 – now has sensible expectations across each sector to reduce emissions.
The New Facility for Hydrogen and Fuel Cell Vehicle Safety Evaluation
Sep 2005
Publication
For the evaluation of hydrogen and fuel cell vehicle safety a new comprehensive facility was constructed in our institute. The new facility includes an explosion resistant indoor vehicle fire test building and high pressure hydrogen tank safety evaluation equipment. The indoor vehicle fire test building has sufficient strength to withstand even an explosion of a high pressure hydrogen tank of 260 liter capacity and 70 MPa pressure. It also has enough space to observe vehicle fire flames of not only hydrogen but also other conventional fuels such as gasoline or compressed natural gas. The inside dimensions of the building are a 16 meter height and 18 meter diameter. The walls are made of 1.2 meter thick reinforced concrete covered at the insides with steel plate. This paper shows examples of hydrogen vehicle fires compared with other fuel fires and hydrogen high pressure tank fire tests utilizing several kinds of fire sources. Another facility for evaluation of high pressure hydrogen tank safety includes a 110 MPa hydrogen compressor with a capacity of 200 Nm3/h a 300 MPa hydraulic compressor for burst tests of 70 MPa and higher pressure tanks and so on. This facility will be used for not only the safety evaluation of hydrogen and fuel cell vehicles but also the establishment of domestic/international regulations codes and standards.
Propulsion of a Hydrogen-fuelled LH2 Tanker Ship
Mar 2022
Publication
This study aims to present a philosophical and quantitative perspective of a propulsion system for a large-scale hydrogen-fuelled liquid-hydrogen (LH2) tanker ship. Established methods are used to evaluate the design and performance of an LH2-carrier propulsion system for JAMILA a ship designed with four cylindrical LH2 tanks bearing a total capacity of ~280000 m3 along with cargo and using the boil-off as propulsion and power fuel. Additionally the ship propulsion system is evaluated based on the ship resistance requirements and a hydrogen-fuelled combined-cycle gas turbine is modelled to achieve the dual objectives of high efficiency and zero-carbon footprint. The required inputs primarily involve the off-design and degraded performance of the gas-turbine topping cycle and the proposed power plant operates with a total output power of 50 M.W. The results reveal that the output power allows ship operation at a great speed even with a degraded engine and adverse ambient conditions.
Zero Emission HGV Infrastructure Requirements
May 2019
Publication
The Committee on Climate Change commissioned Ricardo Energy and Environment to carry out research to assess the infrastructure requirements and costs for the deployment of different zero emission heavy goods vehicle (HGV) technology options. The infrastructure considered includes hydrogen refuelling stations ultra-rapid charge points at strategic locations electric overhead recharging infrastructure on the roads and hybrid solutions combining these options.
The research concluded:
It is feasible to build refuelling infrastructure to support the deployment of zero emission HGVs so that they constitute the vast majority of vehicles on the roads by 2050.
Looking at infrastructure alone deploying hydrogen refuelling stations is the cheapest of the options costing a total of £1.7bn in capital expenditure in the time period from now until 2060. The strategic deployment of ultra-rapid charge points is the most expensive at £10.7bn. In all scenarios a significant number of smaller electric HGVs are deployed as these options are available and operating on the streets today. The cost of installing chargers at depots for these vehicles is included.
When the costs of the fuel as well as the infrastructure are included the costs of deploying electricity or hydrogen HGVs are cheaper compared to the continued use of diesel.
Moving to zero-carbon infrastructure for HDVs is a significant challenge and requires planning co-ordination supply chains resource and materials and a skilled workforce as well as strong government policy to enable the market to deliver.
The Report can be found here
The research concluded:
It is feasible to build refuelling infrastructure to support the deployment of zero emission HGVs so that they constitute the vast majority of vehicles on the roads by 2050.
Looking at infrastructure alone deploying hydrogen refuelling stations is the cheapest of the options costing a total of £1.7bn in capital expenditure in the time period from now until 2060. The strategic deployment of ultra-rapid charge points is the most expensive at £10.7bn. In all scenarios a significant number of smaller electric HGVs are deployed as these options are available and operating on the streets today. The cost of installing chargers at depots for these vehicles is included.
When the costs of the fuel as well as the infrastructure are included the costs of deploying electricity or hydrogen HGVs are cheaper compared to the continued use of diesel.
Moving to zero-carbon infrastructure for HDVs is a significant challenge and requires planning co-ordination supply chains resource and materials and a skilled workforce as well as strong government policy to enable the market to deliver.
The Report can be found here
Safety of Hydrogen-fueled Motor Vehicles with IC Engines.
Sep 2005
Publication
Clarification of questions of safety represents a decisive contribution to the successful introduction of vehicles fuelled by hydrogen. At the moment the safety of hydrogen is being discussed and investigated by various bodies. The primary focus is on fuel-cell vehicles with hydrogen stored in gaseous form. This paper looks at the safety of hydrogen-fuelled vehicles with an internal combustion engine and liquefied hydrogen storage. The safety concept of BMW’s hydrogen vehicles is described and the specific aspects of the propulsion and storage concepts discussed. The main discussion emphasis is on the utilization of boil-off parking of the vehicles in an enclosed space and their crash behaviour. Theoretical safety observations are complemented by the latest experimental and test results. Finally reference is made to the topic-areas in the field of hydrogen safety in which cooperative research work could make a valuable contribution to the future of the hydrogen-powered vehicle.
The Future of Hydrogen
Jun 2019
Publication
At the request of the government of Japan under its G20 presidency the International Energy Agency produced this landmark report to analyse the current state of play for hydrogen and to offer guidance on its future development.
The report finds that clean hydrogen is currently enjoying unprecedented political and business momentum with the number of policies and projects around the world expanding rapidly. It concludes that now is the time to scale up technologies and bring down costs to allow hydrogen to become widely used. The pragmatic and actionable recommendations to governments and industry that are provided will make it possible to take full advantage of this increasing momentum.
Hydrogen and energy have a long shared history – powering the first internal combustion engines over 200 years ago to becoming an integral part of the modern refining industry. It is light storable energy-dense and produces no direct emissions of pollutants or greenhouse gases. But for hydrogen to make a significant contribution to clean energy transitions it needs to be adopted in sectors where it is almost completely absent such as transport buildings and power generation.
The Future of Hydrogen provides an extensive and independent survey of hydrogen that lays out where things stand now; the ways in which hydrogen can help to achieve a clean secure and affordable energy future; and how we can go about realising its potential.
Link to Document on IEA Website
The report finds that clean hydrogen is currently enjoying unprecedented political and business momentum with the number of policies and projects around the world expanding rapidly. It concludes that now is the time to scale up technologies and bring down costs to allow hydrogen to become widely used. The pragmatic and actionable recommendations to governments and industry that are provided will make it possible to take full advantage of this increasing momentum.
Hydrogen and energy have a long shared history – powering the first internal combustion engines over 200 years ago to becoming an integral part of the modern refining industry. It is light storable energy-dense and produces no direct emissions of pollutants or greenhouse gases. But for hydrogen to make a significant contribution to clean energy transitions it needs to be adopted in sectors where it is almost completely absent such as transport buildings and power generation.
The Future of Hydrogen provides an extensive and independent survey of hydrogen that lays out where things stand now; the ways in which hydrogen can help to achieve a clean secure and affordable energy future; and how we can go about realising its potential.
Link to Document on IEA Website
UK Business Opportunities of Moving to a Low-carbon Economy
Mar 2017
Publication
The following report accompanies the Committee on Climate Change’s 2017 report on energy prices and bills. It was written by Ricardo Energy and Environment.
The report provides an analysis of the opportunities to UK businesses to supply global markets with low carbon materials and goods and services. The report considers: the position of the current UK low carbon economy the size of the market opportunity for UK businesses in 2030 and 2050 the barriers to UK business capturing a larger share of the global market the opportunity to increase the UK’s share of future global markets
Link to Document
The report provides an analysis of the opportunities to UK businesses to supply global markets with low carbon materials and goods and services. The report considers: the position of the current UK low carbon economy the size of the market opportunity for UK businesses in 2030 and 2050 the barriers to UK business capturing a larger share of the global market the opportunity to increase the UK’s share of future global markets
Link to Document
Flame Characteristics of High-Pressure Hydrogen Gas Jet
Sep 2005
Publication
It is expected that hydrogen will serve as a nonpolluting carrier of energy for the next generation of vehicles and guidelines for its safe use are required. Hydrogen-gas service stations for supplying fuel cell vehicles will have to handle high-pressure hydrogen gas but safety regulations for such installations have not received much investigation. In this study we experimentally investigated the flame characteristics of a rapid leakage of high-pressure hydrogen gas. A hydrogen jet diffusion flame was injected horizontally from convergent nozzles of various diameters between 0.1 and 4 mm at reservoir over pressures of between 0.01 and 40 MPa. The sizes of the flame were measured and experimental equations were obtained for the length and the width of the flame. Flame sizes depend not only on the nozzle diameter but also on the spouting pressure. Blow-off limits exists and are determined by the nozzle diameter and the spouting pressure. Furthermore the radiation from a hydrogen flame can be predicted from the flow rate of the gas and the distance from the flame.
Digital Navigation of Energy–structure–function Maps for Hydrogen-bonded Porous Molecular Crystals
Feb 2021
Publication
Energy–structure–function (ESF) maps can aid the targeted discovery of porous molecular crystals by predicting the stable crystalline arrangements along with their functions of interest. Here we compute ESF maps for a series of rigid molecules that comprise either a triptycene or a spiro-biphenyl core functionalized with six different hydrogen-bonding moieties. We show that the positioning of the hydrogen-bonding sites as well as their number has a profound influence on the shape of the resulting ESF maps revealing promising structure–function spaces for future experiments. We also demonstrate a simple and general approach to representing and inspecting the high-dimensional data of an ESF map enabling an efficient navigation of the ESF data to identify ‘landmark’ structures that are energetically favourable or functionally interesting. This is a step toward the automated analysis of ESF maps an important goal for closed-loop autonomous searches for molecular crystals with useful functions.
Sectoral Scenarios for the Fifth Carbon Budget
Nov 2015
Publication
This report forms part of the Committee’s advice on the level of the fifth carbon budget.<br/>The report describes the scenarios used by the Committee to inform its judgements over the cost-effective path to meeting the UK’s greenhouse reduction targets in the period 2028-2032.
Role of Chemical Kinetics on the Detonation Properties of Hydrogen, Natural Gas & Air Mixtures
Sep 2005
Publication
The first part of the present work is to validate a detailed kinetic mechanism for the oxidation of hydrogen – methane – air mixtures in a detonation waves. A series of experiments on auto-ignition delay times have been performed by shock tube technique coupled with emission spectrometry for H2 / CH4 / O2 mixtures highly diluted in argon. The CH4/H2 ratio was varied from 0 to 4 and the equivalence ratio from 0.4 up to 1. The temperature range was from 1250 K to 2000 K and the pressure behind reflected shock waves was between 0.15 and 1.6 MPa. A correlation was proposed between temperature (K) concentration of chemical species (mol m-3) and ignition delay times. The experimental auto-ignition delay times were compared to the modelled ones using four different mechanisms from the literature: GRI [22] Marinov et al. [23] Hughes et al. [24] Konnov [25]. A large discrepancy was generally found between the different models. The Konnov’s model that predicted auto-ignition delay times close to the measured ones has been selected to calculate the ignition delay time in the detonation waves. The second part of the study concerned the experimental determination of the detonation properties namely the detonation velocity and the cell size. The effect of the initial composition hydrogen to methane ratio and the amount of oxygen in the mixture as well as the initial pressure on the detonation velocity and on the cell size were investigated. The ratio of methane / (methane + hydrogen) varied between 0 and 0.6 for 2 different equivalence ratio (0.75 and 1) while the initial pressure was fixed to 10 kPa. A correlation was established between the characteristic cell size and the ignition delay time behind the leading shock of the detonation. It was clearly showed that methane has an important inhibitor effect on the detonation of these combustible mixtures.
Hydrogen – Analysis
Jun 2020
Publication
Hydrogen technologies maintained strong momentum in 2019 awakening keen interest among policy makers. It was a record year for electrolysis capacity becoming operational and several significant announcements were made for upcoming years. The fuel cell electric vehicle market almost doubled owing to outstanding expansion in China Japan and Korea. However low-carbon production capacity remained relatively constant and is still off track with the SDS. More efforts are needed to: scale up to reduce costs; replace high-carbon with low-carbon hydrogen in current applications; and expand hydrogen use to new applications.
Link to Document on IEA Website
Link to Document on IEA Website
Scenarios for Deployment of Hydrogen in Meeting Carbon Budgets (E4tech)
Nov 2015
Publication
This research considers the potential role of hydrogen in meeting the UK’s carbon budgets. It was written by consultancy E4tech.<br/>The CCC develops scenarios for the UK’s future energy system to assess routes to decarbonisation and to advise UK Government on policy options. Uncertainty to 2050 is considerable and so different scenarios are needed to assess different trajectories targets and technology combinations. Some of these scenarios assess specific technologies or fuels which have the potential to make a significant contribution to future decarbonisation.<br/>Hydrogen is one such fuel. It has been included in limited quantities in some CCC scenarios but not extensively examined in part due to perceived or anticipated higher costs than some other options. But as hydrogen technology is developed and deployed the cost projections and other performance indicators have become more favourable.
Experimental Study of Hot Inert Gas Jet Ignition of Hydrogen-Oxygen Mixture
Sep 2005
Publication
Experiments were performed to investigate the diffusion ignition process that occurs when hot inert gas (argon or nitrogen) is injected into the stoichiometric hydrogen-oxygen mixture at the test section. Detonation wave initiated by spark plug in the driver section in stoichiometric acetylene-oxygen mixture At P=0.5 MPa and room temperature propagates as incident shockwave in the driven section through inert gas after bursting the diaphragm separating the sections. At the end wall of driver section the inert gas is heated behind the reflected shock wave and then injected in to the test section with the stoichiometric hydrogen-oxygen mixture through the hole 8mm in diameter. An increase of the initial pressure of the combustible mixture in the test section from 0.2 to 0.6MPa resulted in decrease of the minimum temperature of injected gas causing ignition from 1650K to 850K. At the same time the induction time for ignition process has increased from 190 to 320μs when hot argon was injected. For the injection of hot nitrogen an increase of the initial pressure of the combustible mixture from 0.2 to 0.4 MPa resulted in decrease of the minimum temperature of injected inert gas giving ignition from 1150K to 850Kand an increase of the induction time from 170 to 240μs.The results of experiments indicate that ignition occurs when the static enthalpy of injected mass of inert gas exceeds some critical value. The mechanism of ignition process was also studied by schlieren photography.
The Techno-economics Potential of Hydrogen Interconnectors for Electrical Energy Transmission and Storage
Dec 2021
Publication
This research introduces a ‘Hydrogen Interconnector System’ (HIS) as a novel method 7 for transporting electrical energy over long distances. The system takes electricity from 8 stranded renewable energy assets converts it to hydrogen in an electrolyser plant transports 9 hydrogen to the demand centre via pipeline where it is reconverted to electricity in either a 10 gas turbine or fuel cell plant. This paper evaluates the competitiveness of the technology with 11 High Voltage Direct Current (HVDC) systems calculating the following techno-economic 12 indicators; Levelised Cost Of Electricity (LCOE) and Levelised Cost Of Storage (LCOS). The 13 results suggest that the LCOE of the HIS is competitive with HVDC for construction in 2050 14 with distance beyond 350km in case of all scenarios for a 1GW system. The LCOS is lower 15 than an HVDC system using large scale hydrogen storage in 6 out of 12 scenarios analysed 16 including for construction from 2025. The HIS was also applied to three case studies with 17 the results showing that the system outperforms HVDC from LCOS perspectives in all cases 18 and has 15-20% lower investment costs in 2 studies analysed.
Energy Essentials: A Guide to Hydrogen
Jan 2020
Publication
Climate change and air quality concerns have pushed clean energy up the global agenda. As we switch over to new cleaner technologies and fuels our experience of using power heat and transport are going to change transforming the way we live work and get from A to B. Explore this guide to find out what hydrogen is how it is made transported and used what the experience would be like in the home for transport and for businesses and discover what the future of hydrogen might be.
Visit the Energy Institute website for more information
Visit the Energy Institute website for more information
Measuring and Modelling Unsteady Radiation of Hydrogen Combustion
Sep 2005
Publication
Burning hydrogen emits thermal radiation in UV NIR and IR spectral range. Especially in the case of large cloud explosion the risk of heat radiation is commonly underestimated due to the non-visible flame of hydrogen-air combustion. In the case of a real explosion accident organic substances or inert dust might be entrained from outer sources to produce soot or heated solids to substantially increase the heat release by continuum radiation. To investigate the corresponding combustion phenomena different hydrogen-air mixtures were ignited in a closed vessel and the combustion was observed with fast scanning spectrometers using a sampling rate up to 1000 spectra/s. In some experiments to take into account the influence of organic co-combustion a spray of a liquid glycol-ester and milk powder was added to the mixture. The spectra evaluation uses the BAM code of ICT to model bands of reaction products and thus to get the temperatures. The code calculates NIR/IR-spectra (1 - 10 μm) of non-homogenous gas mixtures of H2O CO2 CO NO and HCl taking into consideration also emission of soot particles. It is based on a single line group model and makes also use of tabulated data of H2O and CO2 and a Least Squares Fit of calculated spectra to experimental ones enables the estimation of flame temperatures. During hydrogen combustion OH emits an intense spectrum at 306 nm. This intermediary radical allows monitoring the reaction progress. Intense water band systems between 1.2 and 3 μm emit remarkable amounts of heat radiation according to a measured flame temperature of 2000 K. At this temperature broad optically-thick water bands between 4.5 μm and 10 μm contribute only scarcely to the total heat output. In case of co-combustion of organic materials additional emission bands of CO and CO2 as well as a continuum radiation of soot and other particles occur and particularly increase the total thermal output drastically.
Getting Net Zero Done- The Crucial Role of Decarbonised Gas and How to Support It
May 2020
Publication
The term ‘decarbonised gas’ refers to biogases hydrogen and carbon capture utilisation and storage (CCUS). This strategy paper sets out how decarbonised gas can help to get net zero done by tackling the hard-to-decarbonise sectors – industry heavy transport and domestic heating – which together account for around 40% of UK greenhouse gas emissions. It also illustrates the crucial importance of supportive public opinion and sets out in detail how decarbonised gas can help to ensure that net zero is achieved with public support. The report is based on extensive quantitative and qualitative opinion research on climate change in general net zero emissions in the UK and the specific decarbonised gas solutions in homes transport and industry. The full quantitative data is contained in the Supplements tab.<br/><a href="https://www.dgalliance.org/wp-content/uploads/2020/05/DGA-Getting-Net-Zero-Done-final-May-2020.pdf"/><a href="https://www.dgalliance.org/wp-content/uploads/2020/05/DGA-Getting-Net-Zero-Done-final-May-2020.pdf"/>
Gas Future Scenarios Project- Final Report: A Report on a Study for the Energy Networks Association Gas Futures Group
Nov 2010
Publication
When looking out to 2050 there is huge uncertainty surrounding how gas will be consumed transported and sourced in Great Britain (GB). The extent of the climate change challenge is now widely accepted and the UK Government has introduced a legislative requirement for aggressive reductions in carbon dioxide (CO2) emissions out to 2050. In addition at European Union (EU) level a package of measures has been implemented to reduce greenhouse gas emissions improve energy efficiency and significantly increase the share of energy produced from renewable sources by 2020. These policy developments naturally raise the question of what role gas has to play in the future energy mix.
To help inform this debate the Energy Networks Association Gas Futures Group (ENA GFG) commissioned Redpoint and Trilemma to undertake a long-range scenario-based modelling study of the future utilisation of gas out to 2050 and the consequential impacts of this for gas networks. Our modelling assumptions draw heavily on the Department of Energy and Climate Change (DECC) 2050 Pathways analysis and we consider that our conclusions are fully compatible with both DECC‟s work and current EU policy objectives.
Link to document
To help inform this debate the Energy Networks Association Gas Futures Group (ENA GFG) commissioned Redpoint and Trilemma to undertake a long-range scenario-based modelling study of the future utilisation of gas out to 2050 and the consequential impacts of this for gas networks. Our modelling assumptions draw heavily on the Department of Energy and Climate Change (DECC) 2050 Pathways analysis and we consider that our conclusions are fully compatible with both DECC‟s work and current EU policy objectives.
Link to document
National Training Facility for Hydrogen Safety. Five year plan for HAMMER
Sep 2005
Publication
A suitably trained emergency response force is an essential component for safe implementation of any type of fuel infrastructure. Because of the relative newness of hydrogen as a fuel however appropriate emergency response procedures are not yet well understood by responder workforces across the United States and around the world. A significant near-term training effort is needed to ensure that the future hydrogen infrastructure can be developed and operated with acceptable incident risk. Efforts are presently underway at the HAMMER site in Washington State to develop curricula related to hydrogen properties and behavior identification of problems (e.g. incorrect equipment installation) and appropriate response and other relevant information intended for classroom instruction. In addition a number of hands-on training props are planned for realistic simulation of hydrogen incidents in order to convey proper response procedures in high-pressure cryogenic high leakage or other high-risk accident situations. Surveys of emergency responders fire marshals regulatory authorities manufacturers and others are being undertaken to ensure that the capabilities developed and offered at HAMMER will meet the acknowledged need. This paper describes the training curricula and props anticipated at HAMMER and is intended to provide useful information to others planning similar training programs.
Effect of Hydrogen–diesel Dual-fuel Usage on Performance, Emissions and Diesel Combustion in Diesel Engines
Jul 2016
Publication
Diesel engines are inevitable parts of our daily life and will be in the future. Expensive after-treatment technologies to fulfil normative legislations about the harmful tail-pipe emissions and fuel price increase in recent years created expectations from researchers for alternative fuel applications on diesel engines. This study investigates hydrogen as additive fuel in diesel engines. Hydrogen was introduced into intake manifold using gas injectors as additive fuel in gaseous form and also diesel fuel was injected into cylinder by diesel injector and used as igniter. Energy content of introduced hydrogen was set to 0% 25% and 50% of total fuel energy where the 0% references neat diesel operation without hydrogen injection. Test conditions were set to full load at 750 900 1100 1400 1750 and finally 2100 r/min engine speed. Variation in engine performance emissions and combustion characteristics with hydrogen addition was investigated. Hydrogen introduction into the engine by 25% and 50% of total charge energy reveals significant decrease in smoke emissions while dramatic increase in nitrogen oxides. With increasing hydrogen content a slight rise is observed in total unburned hydrocarbons although CO2 and CO gaseous emissions reduced considerably. Maximum in-cylinder gas pressure and rate of heat release peak values raised with hydrogen fraction.
Experimental Study on Hydrogen Explosions in a Full-scale Hydrogen Filling Station Model
Sep 2005
Publication
In order for fuel cell vehicles to develop a widespread role in society it is essential that hydrogen refuelling stations become established. For this to happen there is a need to demonstrate the safety of the refuelling stations. The work described in this paper was carried out to provide experimental information on hydrogen outflow dispersion and explosion behaviour. In the first phase homogeneous hydrogen-air-mixtures of a known concentration were introduced into an explosion chamber and the resulting flame speed and overpressures were measured. Hydrogen concentration was the dominant factor influencing the flame speed and overpressure. Secondly high-pressure hydrogen releases were initiated in a storage room to study the accumulation of hydrogen. For a steady release with a constant driving pressure the hydrogen concentration varied as the inlet airflow changed depending on the ventilation area of the room the external wind conditions and also the buoyancy induced flows generated by the accumulating hydrogen. Having obtained this basic data the realistic dispersion and explosion experiments were executed at full-scale in the hydrogen station model. High-pressure hydrogen was released from 0.8-8.0mm nozzle at the dispenser position and inside the storage room in the full-scale model of the refuelling station. Also the hydrogen releases were ignited to study the overpressures that can be generated by such releases. The results showed that overpressures that were generated following releases at the dispenser location had a clear correlation with the time of ignition distance from ignition point.
A Hydrogen-Air Explosion in a Process Plant: A Case History
Sep 2005
Publication
In the summer of 1985 a severe hydrogen-air explosion occurred in an ammonia plant in Norway. The accident resulted in two fatalities and the destruction of the building where the explosion took place. This paper presents the main findings from an investigation in 1985 and 1986 of the gas explosion and its consequences. The event started when a gasket in a water pump was blown out. The water pump was situated inside a 100 m long 10 m wide and 7 m high building. The pump was feeding water to a vessel containing hydrogen gas at pressure of 30 bars. This pressure caused a back flow of water flow through the pump and out through the failed gasket. The hydrogen reached the leakage point after about 3 minutes. The discharge of gas lasted some 20 to 30 seconds before the explosion occurred. The total mass of the hydrogen discharge was estimated at 10 to 20 kg hydrogen. The main explosion was very violent and it is likely that the gas cloud detonated. The ignition source was almost certainly a hot bearing. Several damage indicators were used to estimate the amount of hydrogen that exploded. The indicators include deflection of pipes and panels distances traveled by fragments and the distribution of glass breakage. We found that 3.5 to 7 kg of hydrogen must have been burning violently in the explosion. Window glass was broken up to 700 m from the centre of the explosion. Concrete blocks originally part of the north wall of the building and weighing 1.2 metric tons were thrown up to 16 meters. The roof of the building was lifted by an estimated 1.5 meters before resettling. The displacement of the roof caused a guillotine break of a 350 mm diameter pipe connected to the vessel that was the source of the original gas discharge. The gas composition in the vessel was 65 - 95 % hydrogen. This resulted in a large horizontal jet fire lasting about 30 seconds. Minor explosions occurred in the plant culvert system.<br/><br/>To our knowledge this gas explosion is one of the largest industrial hydrogen explosions reported. We believe this case history is a valuable reference for those who are investigating the nature of accidental<br/>hydrogen explosions.
Gas Goes Green: Delivering the Pathway to Net Zero
May 2020
Publication
Gas Goes Green brings together the engineering expertise from the UK’s five gas network operators building on the foundations of our existing grid infrastructure innovation projects and the wider scientific community. This is a blueprint to meet the challenges and opportunities of climate change delivering net zero in the most cost effective and least disruptive way possible.<br/>Delivering our vision is not just an engineering challenge but will involve active participation from policy makers regulators the energy industry and consumers. Gas Goes Green will undertake extensive engagement to deliver our programme and collaborate with existing projects already being delivered across the country.<br/>Britain’s extensive gas network infrastructure provides businesses and the public with the energy they need at the times when they need it the most. The gas we deliver plays a critical role in our everyday lives generating electricity fuelling vehicles heating our homes and providing the significant amounts of energy UK heavy industry needs. The Gas Goes Green programme aims to ensure that consumers continue to realise these benefits by transitioning our infrastructure into a net zero energy system.
Pathways to Net-Zero: Decarbonising the Gas Networks in Great Britain
Oct 2019
Publication
Natural gas plays a central role in the UK energy system today but it is also a significant source of greenhouse gas (GHG) emissions. The UK committed in 2008 to reduce GHG emissions by at least 80% compared to 1990 levels by 2050. In June 2019 a more ambitious target was adopted into law and the UK became the first major economy to commit to “net-zero” emissions by 2050. In this context the Energy Networks Association (ENA) commissioned Navigant to explore the role that the gas sector can play in the decarbonisation of the Great Britain (GB) energy system. In this report we demonstrate that low carbon and renewable gases can make a fundamental contribution to the decarbonisation pathway between now and 2050.
Explosion Characteristics of Hydrogen-air and Hydrogen-Oxygen Mixtures at Elevated Pressures
Sep 2005
Publication
An essential problem for the operation of high pressure water electrolyzers and fuel cells is the permissible contamination of hydrogen and oxygen. This contamination can create malfunction and in the worst case explosions in the apparatus and gas cylinders. In order to avoid dangerous conditions the exact knowledge of the explosion characteristics of hydrogen/air and hydrogen/oxygen mixtures is necessary. The common databases e.g. the CHEMSAFE® database published by DECHEMA BAM and PTB contains even a large number of evaluated safety related properties among other things explosion limits which however are mainly measured according to standard procedures under atmospheric conditions.<br/>Within the framework of the European research project “SAFEKINEX” and other research projects the explosion limits explosion pressures and rates of pressure rise (KG values) of H2/air and H2/O2 mixtures were measured at elevated conditions of initial pressures and temperatures by the Federal Institute of Materials Research and Testing (BAM). Empirical equations of the temperature influence could be deduced from the experimental values. An anomaly was found at the pressure influence on the upper explosion limits of H2/O2 and H2/air mixtures in the range of 20 bars. In addition explosion pressures and also rates of pressure rises have been measured for different hydrogen concentrations inside the explosion range. Such data are important for constructive explosion protection measures. Furthermore the mainly used standards for the determination of explosion limits have been compared. Therefore it was interesting to have a look at the systematic differences between the new EN 1839 tube and bomb method ASTM E 681-01 and German DIN 51649-1.
Progressing the Gas Goes Green Roadmap to Net Zero Webinar
Dec 2021
Publication
The Gas Goes Green Programme developed by the gas networks and the Energy Networks Association (ENA) describes a viable pathway to the injection of hydrogen and biomethane as a practical step towards the decarbonisation of the UK gas sector and will play a key role in the UK’s Net Zero energy strategy. It therefore follows that technical and management teams in the supply chain and related industries will need a sound understanding of the issues surrounding this deployment. This video shares the industry’s progress towards implementing the Gas Goes Green programme. Presenters including Oliver Lancaster CEO IGEM Dr Thomas Koller Programme Lead Gas Goes Green at the Energy Network Association (ENA) and Ian McCluskey CEng FIMechE FIGEM Head of Technical and Policy IGEM share their views on what has already been achieved and explain what they feel still needs to be done to develop the decarbonised gas network of tomorrow.
2050 Energy Scenarios: The UK Gas Networks Role in a 2050 Whole Energy System
Jul 2016
Publication
Energy used for heat accounts (in terms of final consumption) for approximately 45% of our total energy needs and is critical for families to heat their homes on winter days. Decarbonising heat while still meeting peak winter heating demands is recognised as a big perhaps the biggest challenge for the industry. The way heat has been delivered in the UK has not fundamentally changed for decades and huge investments have been made in gas infrastructure assets ranging from import terminals to networks through to the appliances in our homes. Changing how heat is delivered whichever way is chosen will be a major economic and practical challenge affecting families and businesses everywhere. Any plan to decarbonise will need to address power and transport alongside heat. Our report has also looked at potential decarbonisation of power and transport as part of a whole energy system approach.
In this report we explore ways that the heat sector can be decarbonised by looking at four possible future scenarios set in 2050. These stylised scenarios present illustrative snapshots of alternative energy solutions. The scenarios do not present a detailed roadmap – indeed the future may include some elements from each. We have analysed the advantages disadvantages and costs of each scenario. All our scenarios meet the 2050 Carbon emissions targets. In this report we have concentrated on reductions to CO2 emissions and we have not considered other greenhouse gases.
In this report we explore ways that the heat sector can be decarbonised by looking at four possible future scenarios set in 2050. These stylised scenarios present illustrative snapshots of alternative energy solutions. The scenarios do not present a detailed roadmap – indeed the future may include some elements from each. We have analysed the advantages disadvantages and costs of each scenario. All our scenarios meet the 2050 Carbon emissions targets. In this report we have concentrated on reductions to CO2 emissions and we have not considered other greenhouse gases.
Large-Scale Hydrogen Deflagrations and Detonations
Sep 2005
Publication
Large-scale deflagration and detonation experiments of hydrogen and air mixtures provide fundamental data needed to address accident scenarios and to help in the evaluation and validation of numerical models. Several different experiments of this type were performed. Measurements included flame front time of arrival (TOA) using ionization probes blast pressure heat flux high-speed video standard video and infrared video. The large-scale open-space tests used a hemispherical 300-m3 facility that confined the mixture within a thin plastic tent that was cut prior to initiating a deflagration. Initial homogeneous hydrogen concentrations varied from 15% to 30%. An array of large cylindrical obstacles was placed within the mixture for some experiments to explore turbulent enhancement of the combustion. All tests were ignited at the bottom center of the facility using either a spark or in one case a small quantity of high explosive to generate a detonation. Spark-initiated deflagration tests were performed within the tunnel using homogeneous hydrogen mixtures. Several experiments were performed in which 0.1 kg and 2.2 kg of hydrogen were released into the tunnel with and without ventilation. For some tunnel tests obstacles representing vehicles were used to investigate turbulent enhancement. A test was performed to investigate any enhancement of the deflagration due to partial confinement produced by a narrow gap between aluminium plates. The attenuation of a blast wave was investigated using a 4-m-tall protective blast wall. Finally a large-scale hydrogen jet experiment was performed in which 27 kg of hydrogen was released vertically into the open atmosphere in a period of about 30 seconds. The hydrogen plume spontaneously ignited early in the release.
Analysis Methodology for Hydrogen Behaviour in Accident Scenarios
Sep 2005
Publication
Hydrogen is not more dangerous than current fossil energy carriers but it behaves differently. Therefore hydrogen specific analyses and countermeasures will be needed to support the development of safe hydrogen technologies. A systematic step-by-step procedure for the mechanistic analysis of hydrogen behaviour and mitigation in accidents is presented. The procedure can be subdivided into four main parts:<br/>1) 3D modelling of the H2-air mixture generation<br/>2) hazard evaluation for this mixture based on specifically developed criteria for flammability flame acceleration and detonation on-set<br/>3) numerical simulation of the appropriate combustion regime using verified 3D-CFD codes and<br/>4) consequence analysis based on the calculated pressure and temperature loads.
CFD Modeling OF LH2 Dispersion Using the ADREA-HF Code
Sep 2011
Publication
In the present work the computational fluid dynamics (CFD) code ADREA-HF has been applied to simulate the very recent liquefied hydrogen spill experiments performed by the Health Safety Laboratory (HSL). The experiment consists of four LH2 release trials over concrete at a fixed rate of 60 lt/min but with different release direction height and duration. In the modeling the hydrogen source was treated as a two phase jet enabling simultaneous modeling of pool formation spreading as well as hydrogen vapor dispersion. Turbulence was modeled with the standard k- model modified for buoyancy effects. The effect of solidification of the atmospheric humidity was taken into account. The predicted concentration at the experimental sensors? locations was compared with the observed one. The results from the comparison of the predicted concentration with and without solidification of the atmospheric humidity indicate that the released heat from the solidification affects significantly the buoyant behavior of the hydrogen vapor. Therefore the simulation with solidification of the atmospheric humidity is in better agreement with the experiment.
An Intercomparison Exercise on the Capabilities of CFD Models to Predict Deflagration of a Large-Scale H2-Air Mixture in Open Atmosphere
Sep 2005
Publication
This paper presents a compilation of the results supplied by HySafe partners participating in the Standard Benchmark Exercise Problem (SBEP) V2 which is based on an experiment on hydrogen combustion that is first described. A list of the results requested from participants is also included. The main characteristics of the models used for the calculations are compared in a very succinct way by using tables. The comparison between results together with the experimental data when available is made through a series of graphs. The results show quite good agreement with the experimental data. The calculations have demonstrated to be sensitive to computational domain size and far field boundary condition.
Towards Hydrogen Safety Education and Training
Sep 2005
Publication
The onset and further development of the hydrogen economy are known to be constrained by safety barriers as well as by the level of public acceptance of new applications. Educational and training programmes in hydrogen safety which are currently absent in Europe are considered to be a key instrument in lifting these limitations and to ensure the safe introduction of hydrogen as an energy carrier. Therefore the European Network of Excellence ‘Safety of Hydrogen as an Energy Carrier’ (NoE HySafe) embarked on the establishment of the e-Academy of Hydrogen Safety. This work is led by the University of Ulster and carried out in cooperation with international partners from five other universities (Universidad Politecnica de Madrid Spain; University of Pisa Italy; Warsaw University of Technology Poland; Instituto Superior Technico Portugal; University of Calgary Canada) two research institutions (Forschungszentrum Karlsruhe and Forschungszentrum Juelich Germany) and one enterprise (GexCon Norway). The development of an International Curriculum on Hydrogen Safety Engineering aided by world-class experts from within and outside NoE HySafe is of central importance to the establishment of the e-Academy of Hydrogen Safety. Despite its key role in identifying the knowledge framework of the subject matter and its role in aiding educators with the development of teaching programmes on hydrogen safety no such curriculum appears to have been developed previously. The current structure of the International Curriculum on Hydrogen Safety Engineering and the motivation behind it are described in this paper. Future steps in the development of a system of hydrogen safety education and training in Europe are briefly described.
A Safety Assessment of Hydrogen Supply Piping System by Use of FDS
Sep 2017
Publication
At least once air filling a piping from main hydrogen pipe line to an individual home end should be replaced with hydrogen gas to use the gas in the home. Special attention is required to complete the replacing operation safely because air and supplied hydrogen may generate flammable/explosive gas mixture in the piping. The most probable method to fulfill the task is that at first an inert gas is used to purge air from the piping and then hydrogen will be supplied into the piping. It is easily understood that the amount of the inert gas consumed by this method is much to purge whole air especially in long piping system. Hence to achieve more economical efficiency an alternative method was considered. In this method previously injected nitrogen between air and hydrogen prevents them from mixing. The key point is that how much nitrogen is required to prevent the dangerous mixing and keep the condition in the piping safe. The authors investigated to find the minimum amount of nitrogen required to keep the replacing operation safe. The main objective of this study is to assess the effect of nitrogen and estimate a pipe length that the safety is maintained under various conditions by using computational fluid dynamic (CFD). The effects of the amount of injected nitrogen hydrogen-supply conditions and the structure of piping system are discussed.
HyDeploy Gas Safe Webinar
Nov 2020
Publication
HyDeploy is a pioneering hydrogen energy project designed to help reduce UK CO2 emissions and reach the Government’s net zero target for 2050.
As the first ever live demonstration of hydrogen in homes HyDeploy aims to prove that blending up to 20% volume of hydrogen with natural gas is a safe and greener alternative to the gas we use now. It is providing evidence on how customers don’t have to change their cooking or heating appliances to take the blend which means less disruption and cost for them.
As the first ever live demonstration of hydrogen in homes HyDeploy aims to prove that blending up to 20% volume of hydrogen with natural gas is a safe and greener alternative to the gas we use now. It is providing evidence on how customers don’t have to change their cooking or heating appliances to take the blend which means less disruption and cost for them.
Path to Hydrogen Competitiveness: A Cost Perspective
Jan 2020
Publication
This latest Hydrogen Council report shows that the cost of hydrogen solutions will fall sharply within the next decade – and sooner than previously expected. As scale up of hydrogen production distribution equipment and component manufacturing continues cost is projected to decrease by up to 50% by 2030 for a wide range of applications making hydrogen competitive with other low-carbon alternatives and in some cases even conventional options.
Significant cost reductions are expected across different hydrogen applications. For more than 20 of them such as long-distance and heavy-duty transportation industrial heating and heavy industry feedstock which together comprise roughly 15% of global energy consumption the hydrogen route appears the decarbonisation option of choice – a material opportunity.
The report attributes this trajectory to scale-up that positively impacts the three main cost drivers:
To deliver on this opportunity supporting policies will be required in key geographies together with investment support of around $70 billion in the lead up to 2030 in order to scale up and achieve hydrogen competitiveness. While this figure is sizable it accounts for less than 5% of annual global spending on energy. For comparison support provided to renewables in Germany totalled roughly $30 billion in 2019.
The study is based on real industry data with 25000 data points gathered and analysed from 30 companies using a rigorous methodology. The data was collected and analytical support provided by McKinsey & Company and it represents the entire hydrogen value chain across four key geographies (US Europe Japan/Korea and China). Data was also reviewed by an independent advisory group comprised of recognised hydrogen and energy transition experts.
You can download the full report from the Hydrogen Council website here
The executive summary can be found here
Significant cost reductions are expected across different hydrogen applications. For more than 20 of them such as long-distance and heavy-duty transportation industrial heating and heavy industry feedstock which together comprise roughly 15% of global energy consumption the hydrogen route appears the decarbonisation option of choice – a material opportunity.
The report attributes this trajectory to scale-up that positively impacts the three main cost drivers:
- Strong fall in the cost of producing low carbon and renewable hydrogen;
- Lower distribution and refuelling costs thanks to higher load utilisation and scale effect on infrastructure utilisation; and
- Dramatic drop in the cost of components for end-use equipment under scaling up of manufacturing.
To deliver on this opportunity supporting policies will be required in key geographies together with investment support of around $70 billion in the lead up to 2030 in order to scale up and achieve hydrogen competitiveness. While this figure is sizable it accounts for less than 5% of annual global spending on energy. For comparison support provided to renewables in Germany totalled roughly $30 billion in 2019.
The study is based on real industry data with 25000 data points gathered and analysed from 30 companies using a rigorous methodology. The data was collected and analytical support provided by McKinsey & Company and it represents the entire hydrogen value chain across four key geographies (US Europe Japan/Korea and China). Data was also reviewed by an independent advisory group comprised of recognised hydrogen and energy transition experts.
You can download the full report from the Hydrogen Council website here
The executive summary can be found here
How Hydrogen Empowers the Energy Transition
Jan 2017
Publication
This report commissioned by the Hydrogen Council and announced in conjunction with the launch of the initiative at the World Economic Forum in January 2017 details the future potential that hydrogen is ready to provide and sets out the vision of the Council and the key actions it considers fundamental for policy makers to implement to fully unlock and empower the contribution of hydrogen to the energy transition.
In this paper we explore the role of hydrogen in the energy transition including its potential recent achievements and challenges to its deployment. We also offer recommendations to ensure that the proper conditions are developed to accelerate the deployment of hydrogen technologies with the support of policymakers the private sector and society.
You can download the full report from the Hydrogen Council website here
In this paper we explore the role of hydrogen in the energy transition including its potential recent achievements and challenges to its deployment. We also offer recommendations to ensure that the proper conditions are developed to accelerate the deployment of hydrogen technologies with the support of policymakers the private sector and society.
You can download the full report from the Hydrogen Council website here
Opportunity and Cost of Green Hydrogen in Kuwait: A Preliminary Assessment
Apr 2021
Publication
On April 7 2021 OIES with and the Kuwait Foundation for the Advancement of Sciences (KFAS) held the annual OIES-KFAS Workshop on Energy Transition Post-Pandemic in the Gulf. During the hydrogen session a paper titled “Opportunity and Cost of Green Hydrogen in Kuwait: A Preliminary Assessment” co-authored by Dr. Manal Shehabi was presented.
Like others states in the GCC Kuwait is seeking to explore hydrogen as part of its energy transition projects. The presentation highlights key technological opportunities for green hydrogen in Kuwait followed by a techno-economic assessments of producing it. Results of utilized hydrogen production model show that for production in 2032 average levelized cost of hydrogen (LCOH) is $3.23/kg using PEM technology & $4.41/kg using SOEC technology. Results indicate that green hydrogen in Kuwait is more competitive than in other regions but currently not competitive (>$1.5/kg) with oil coal and gas in absence of carbon taxes.
The research paper can be found on their website
Like others states in the GCC Kuwait is seeking to explore hydrogen as part of its energy transition projects. The presentation highlights key technological opportunities for green hydrogen in Kuwait followed by a techno-economic assessments of producing it. Results of utilized hydrogen production model show that for production in 2032 average levelized cost of hydrogen (LCOH) is $3.23/kg using PEM technology & $4.41/kg using SOEC technology. Results indicate that green hydrogen in Kuwait is more competitive than in other regions but currently not competitive (>$1.5/kg) with oil coal and gas in absence of carbon taxes.
The research paper can be found on their website
Safety System Design for Mitigating Risks of Intended Hydrogen Releases from Thermally Activated Pressure Relief Device of Onboard Storage
Sep 2019
Publication
All vehicular high-pressure hydrogen tanks are equipped with thermally-activated pressure relief devices (TPRDs) required by Global Technical Regulation. This safety device significantly reduces the risk of tank catastrophic rupture by venting the hydrogen pressure outside. However the released flammable hydrogen raises additional safety problems. Japan Automobile Research Institute has demonstrated that in the vehicle fire event once the TPRD opens the hydrogen fires will engulf the whole vehicle making it difficult for the drivers and passenger to evacuate from the vehicle. This paper designs a new safety system to solve the evacuation problem. The safety system includes a rotatable pressure relief device with a motor a sensory system that consists of infrared sensors ultrasonic radar and temperature sensors a central control unit and an alarm device. The new design of the pressure relief device allows the system actively adjusting the release direction towards void open space outside the vehicle to minimize the risks of hydrogen fires. The infrared sensors located at the roof of the vehicles collect info inside the vehicle and the ultrasonic radar detect the region outside the vehicle. Temperature sensors tell when to trigger the alarm and set the motor in standby mode and the central control unit determines where to rotate based on the info from the infrared sensors and ultrasonic radars. A control strategy is also proposed to operate the safety system in an appropriate way. The cost-benefit analysis show that the new safety system can significantly reduce the risks of intended hydrogen releases from onboard pressure relief devices with total cost increases by less than 1% of the vehicle cost making it a good cost-effective engineering solution.
Impact of Depth on Underground Hydrogen Storage Operations in Deep Aquifers
Mar 2024
Publication
Underground hydrogen storage in geological structures is considered appropriate for storing large amounts of hydrogen. Using the geological Konary structure in the deep saline aquifers an analysis of the influence of depth on hydrogen storage was carried out. Hydrogen injection and withdrawal modeling was performed using TOUGH2 software assuming different structure depths. Changes in the relevant parameters for the operation of an underground hydrogen storage facility including the amount of H2 injected in the initial filling period cushion gas working gas and average amount of extracted water are presented. The results showed that increasing the depth to approximately 1500 m positively affects hydrogen storage (flow rate of injected hydrogen total capacity and working gas). Below this depth the trend was reversed. The cushion gas-to-working gas ratio did not significantly change with increasing depth. Its magnitude depends on the length of the initial hydrogen filling period. An increase in the depth of hydrogen storage is associated with a greater amount of extracted water. Increasing the duration of the initial hydrogen filling period will reduce the water production but increase the cushion gas volume.
Economic Impact Assessment: Hydrogen is Ready to Power the UK’s Green Recovery
Aug 2020
Publication
Hydrogen solutions have a critical role to play in the UK not only in helping the nation meet its net-zero target but in creating the economic growth and jobs that will kickstart the green recovery.
The Government must act now to ensure that the UK capitalises on the opportunity presented by hydrogen and builds a world-leading industry.
COVID-19 has caused significant economic upheaval across the country with unemployment expected to reach up to 14.8 per cent by the end of 20201. The UK must identify those areas of the economy which have significant economic growth potential and can deliver long-term and sustainable increases in GVA and jobs. It will be important to consider regional factors and ensure that investment is targeted in those areas that have been hardest hit by the crisis.
Many major economies have identified hydrogen as a key part of both decarbonisation and economic recovery. As part of its stimulus package Germany announced a €9billion investment in green hydrogen solutions aiming to deploy 5GW by 2030. The Hydrogen Council estimates a future hydrogen and equipment market worth $2.5 trillion globally by 2050 supporting 30 million new jobs.
Hydrogen offers the UK a pathway to deep cost-effective decarbonisation while delivering economic growth and job creation. It should therefore be at the heart of the Government’s green recovery programme ensuring that the UK builds back better and greener.
The Government must act now to ensure that the UK capitalises on the opportunity presented by hydrogen and builds a world-leading industry.
COVID-19 has caused significant economic upheaval across the country with unemployment expected to reach up to 14.8 per cent by the end of 20201. The UK must identify those areas of the economy which have significant economic growth potential and can deliver long-term and sustainable increases in GVA and jobs. It will be important to consider regional factors and ensure that investment is targeted in those areas that have been hardest hit by the crisis.
Many major economies have identified hydrogen as a key part of both decarbonisation and economic recovery. As part of its stimulus package Germany announced a €9billion investment in green hydrogen solutions aiming to deploy 5GW by 2030. The Hydrogen Council estimates a future hydrogen and equipment market worth $2.5 trillion globally by 2050 supporting 30 million new jobs.
Hydrogen offers the UK a pathway to deep cost-effective decarbonisation while delivering economic growth and job creation. It should therefore be at the heart of the Government’s green recovery programme ensuring that the UK builds back better and greener.
You can download the whole document from the Hydrogen Taskforce website at the following links
- Economic Impact Assessment Summary
- Economic impact Assessment Methodology
- Economic impact Assessment of the Hydrogen Value Chain of the UK infographic
- Imperial College Consultants Review of the EIA.
Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage
Oct 2017
Publication
Hydrogen has a very diverse chemistry and reacts with most other elements to form compounds which have fascinating structures compositions and properties. Complex metal hydrides are a rapidly expanding class of materials approaching multi-functionality in particular within the energy storage field. This review illustrates that complex metal hydrides may store hydrogen in the solid state act as novel battery materials both as electrolytes and electrode materials or store solar heat in a more efficient manner as compared to traditional heat storage materials. Furthermore it is highlighted how complex metal hydrides may act in an integrated setup with a fuel cell. This review focuses on the unique properties of light element complex metal hydrides mainly based on boron nitrogen and aluminum e.g. metal borohydrides and metal alanates. Our hope is that this review can provide new inspiration to solve the great challenge of our time: efficient conversion and large-scale storage of renewable energy.
Experimental Measurements of Structural Displacement During Hydrogen Vented Deflagrations for FE Model Validation
Sep 2017
Publication
Vented deflagration tests were conducted by UNIPI at B. Guerrini Laboratory during the experimental campaign for HySEA project. Experiments included homogeneous hydrogen-air mixture in a 10-18% vol. range of concentrations contained in an about 1 m3 enclosure called SSE (Small Scale Enclosure). Displacement measurements of a test plate were taken in order to acquire useful data for the validation of FE model developed by IMPETUS Afea. In this paper experimental facility displacement measurement system and FE model are briefly described then comparison between experimental data and simulation results is discussed.
Non-adiabatic Blowdown Model: A Complimentary Tool for the Safety Design of Tank-TPRD System
Sep 2017
Publication
Previous studies have demonstrated that while blowdown pressure is reproduced well by both adiabatic and isothermal analytical models the dynamics of temperature cannot be predicted well by either model. The reason for the last is heat transfer to cooling during expansion gas from the vessel wall. Moreover when exposed to an external fire the temperature inside the vessel increases i.e. when a thermally activated pressure relief device (TPRD) is still closed with subsequent pressure increase that may lead to a catastrophic rupture of the vessel. The choice of a TPRD exit orifice size and design strategy are challenges: to provide sufficient internal pressure drop in a fire when the orifice size is too small; to avoid flame blow off expected with the decrease of pressure during the blowdown; to decrease flame length of subsequent jet fire as much as possible by the decrease of the orifice size under condition of sufficient fire resistance provisions to avoid pressure peaking phenomenon etc. The adiabatic model of blowdown [1] was developed using the Abel-Nobel equation of state and the original theory of underexpanded jet [2]. According to experimental observations e.g. [3] heat transfer plays a significant role during the blowdown. Thus this study aims to modify the adiabatic blowdown model to include the heat transfer to non-ideal gas. The model accounts for a change of gas temperature inside the vessel due to two “competing” processes: the decrease of temperature due to gas expansion and the increase of temperature due to heat transfer from the surroundings e.g. ambience or fire through the vessel wall. This is taken into account in the system of equations of adiabatic blowdown model through the change of energy conservation equation that accounts for heat from outside. There is a need to know the convective heat transfer coefficient between the vessel wall and the surroundings and wall size and properties to define heat flux to the gas inside the vessel. The non-adiabatic model is validated against available experimental data. The model can be applied as a new engineering tool for the inherently safer design of hydrogen tank-TPRD system.
Hydrocarbon Production by Continuous Hydrodeoxygenation of Liquid Phase Pyrolysis Oil with Biogenous Hydrogen Rich Synthesis Gas
Feb 2019
Publication
This paper presents a beneficial combination of biomass gasification and pyrolysis oil hydrodeoxygenation for advanced biofuel production. Hydrogen for hydrodeoxygenation (HDO) of liquid phase pyrolysis oil (LPP oil) was generated by gasification of softwood. The process merges dual fluidized bed (DFB) steam gasification which produces a hydrogen rich product gas and the HDO of LPP oil. Synthesis gas was used directly without further cleaning and upgrading by making use of the water gas-shift (WGS) reaction. The water needed for the water gas-shift reaction was provided by LPP oil. HDO was successfully performed in a lab scale over 36 h time on stream (TOS). Competing reactions like the Boudouard reaction and Sabatier reaction were not observed. Product quality was close to Diesel fuel specification according to EN 590 with a carbon content of 85.4 w% and a residual water content of 0.28 w%. The water-gas shift reaction was confirmed by CO/CO2-balance high water consumption and 28% less hydrogen consumption during HDO.
Safety and Environmental Standards for Fuel Storage Sites
Jan 2009
Publication
The main purpose of this report is to specify the minimum standards of control which should be in place at all establishments storing large volumes of gasoline.<br/>The PSLG also considered other substances capable of giving rise to a large flammable vapour cloud in the event of a loss of primary containment. However to ensure priority was given to improving standards of control to tanks storing gasoline PSLG has yet to determine the scale and application of this guidance to such substances. It is possible that a limited number of other substances (with specific physical properties and storage arrangements) will be addressed in the future.<br/>This report also provides guidance on good practice in relation to secondary and tertiary containment for facilities covered by the CA Control of Major Accident Hazards (COMAH) Parts of this guidance may also be relevant to other major hazard establishments.
Catalytic Effect of MoS2 on Hydrogen Storage Thermodynamics and Kinetics of an As-milled YMg11Ni Alloy
Jul 2017
Publication
In this study YMg11Ni and YMg11Ni + 5 wt% MoS2 (named YMg11Ni–MoS2) alloys were prepared by mechanical milling to examine the effect of adding MoS2 on the hydrogen storage performance of a Y–Mg–Ni-based alloy. The as-cast and milled alloys were tested to identify their structures by X-ray diffraction and transmission electron microscopy. The isothermal hydrogen storage thermodynamics and dynamics were identified through an automatic Sieverts apparatus and the non-isothermal dehydrogenation performance was investigated by thermogravimetry and differential scanning calorimetry. The dehydrogenation activation energy was calculated by both Arrhenius and Kissinger methods. Results revealed that adding MoS2produces a very slight effect on hydrogen storage thermodynamics but causes an obvious reduction in the hydrogen sorption and desorption capacities because of the deadweight of MoS2. The addition of MoS2significantly enhances the dehydrogenation performance of the alloy such as lowering dehydrogenation temperature and enhancing dehydrogenation rate. Specifically the initial desorption temperature of the alloy hydride lowers from 549.8 K to 525.8 K. The time required to desorb hydrogen at 3 wt% H2 is 1106 456 363 and 180 s corresponding to hydrogen desorption temperatures at 593 613 633 and 653 K for the YMg11Ni alloy and 507 208 125 and 86 s at identical conditions for the YMg11Ni–5MoS2 alloy. The dehydrogenation activation energy (Ea) values with and without added MoS2are 85.32 and 98.01 kJ mol−1. Thus a decrease in Ea value by 12.69 kJ mol−1 occurs and is responsible for the amelioration of the hydrogen desorption dynamics by adding a MoS2 catalyst.
Hydrogen Production by Electrochemical Reaction Using Ethylene Glycol with Terephthalic Acid
Jan 2021
Publication
In this study ethylene glycol (EG) and terephthalic acid (TPA) were used to generate hydrogen using copper electrodes in an alkaline aqueous solution and the corresponding reaction mechanism was experimentally investigated. Both EG and TPA produced hydrogen; however TPA consumed OH− inhibiting the production of intermediary compounds of EG and causing EG to actively react with H2O ultimately leading to enhanced hydrogen production. In addition the initiation potential of water decomposition of the EG and TPA alkaline aqueous solution was 1.0 V; when 1.8 V (vs. RHE) was applied the hydrogen production reached 440 mmol L−1 which was substantially greater than the hydrogen production rate of 150 mmol L−1 during water decomposition.
Exploring Future Promising Technologies in Hydrogen Fuel Cell Transportation
Jan 2022
Publication
The purpose of this research was to derive promising technologies for the transport of hydrogen fuel cells thereby supporting the development of research and development policy and presenting directions for investment. We also provide researchers with information about technology that will lead the technology field in the future. Hydrogen energy as the core of carbon neutral and green energy is a major issue in changing the future industrial structure and national competitive advantage. In this study we derived promising technology at the core of future hydrogen fuel cell transportation using the published US patent and paper databases (DB). We first performed text mining and data preprocessing and then discovered promising technologies through generative topographic mapping analysis. We analyzed both the patent DB and treatise DB in parallel and compared the results. As a result two promising technologies were derived from the patent DB analysis and five were derived from the paper DB analysis.
Energy Innovation Needs Assessment: Hydrogen & Fuel Cells
Nov 2019
Publication
The Energy Innovation Needs Assessment (EINA) aims to identify the key innovation needs across the UK’s energy system to inform the prioritisation of public sector investment in low-carbon innovation. Using an analytical methodology developed by the Department for Business Energy & Industrial Strategy (BEIS) the EINA takes a system level approach and values innovations in a technology in terms of the system-level benefits a technology innovation provides. This whole system modelling in line with BEIS’s EINA methodology was delivered by the Energy Systems Catapult (ESC) using the Energy System Modelling Environment (ESMETM) as the primary modelling tool.
To support the overall prioritisation of innovation activity the EINA process analyses key technologies in more detail. These technologies are grouped together into sub-themes according to the primary role they fulfil in the energy system. For key technologies within a sub-theme innovations and business opportunities are identified. The main findings at the technology level are summarised in sub-theme reports. An overview report will combine the findings from each sub-theme to provide a broad system-level perspective and prioritisation.
This EINA analysis is based on a combination of desk research by a consortium of economic and engineering consultants and stakeholder engagement. The prioritisation of innovation and business opportunities presented is informed by a workshop organised for each sub-theme assembling key stakeholders from the academic community industry and government.
This report was commissioned prior to advice being received from the CCC on meeting a net zero target and reflects priorities to meet the previous 80% target in 2050. The newly legislated net zero target is not expected to change the set of innovation priorities rather it will make them all more valuable overall. Further work is required to assess detailed implications.
To support the overall prioritisation of innovation activity the EINA process analyses key technologies in more detail. These technologies are grouped together into sub-themes according to the primary role they fulfil in the energy system. For key technologies within a sub-theme innovations and business opportunities are identified. The main findings at the technology level are summarised in sub-theme reports. An overview report will combine the findings from each sub-theme to provide a broad system-level perspective and prioritisation.
This EINA analysis is based on a combination of desk research by a consortium of economic and engineering consultants and stakeholder engagement. The prioritisation of innovation and business opportunities presented is informed by a workshop organised for each sub-theme assembling key stakeholders from the academic community industry and government.
This report was commissioned prior to advice being received from the CCC on meeting a net zero target and reflects priorities to meet the previous 80% target in 2050. The newly legislated net zero target is not expected to change the set of innovation priorities rather it will make them all more valuable overall. Further work is required to assess detailed implications.
Hydrolysis Hydrogen Production Mechanism of Mg10Ni10Ce Alloy Surface Modified by SnO2 Nanotubes in Different Aqueous Systems
May 2020
Publication
(Mg-10wt.%Ni)-10wt.%Ce (Mg10Ni10Ce) was ball-milled with SnO2 nanotubes and Mg10Ni10Ce-xSnO2 (x=0 5 10 and 15wt.%) composites have been prepared. The phase compositions microstructures morphologies and hydrolysis H2 generation performance in different aqueous systems (distilled water tap water and simulated seawater) have been investigated and the corresponding hydrolysis mechanism of Mg10Ni10Ce and Mg10Ni10Ce-SnO2 has been proposed. Adding a small amount of SnO2 nanotubes can significantly enhance the hydrolysis reaction of Mg10Ni10Ce especially the initial hydrolysis kinetics and the final H2 generation yield. Unfortunately the Mg10Ni10Ce-xSnO2 hardly react with distilled water at room temperature. The hydrolysis reaction rate of Mg10Ni10Ce-5SnO2 composite in tap water is still very slow with only 17.3% generation yield after 1 hour at 303 K. Fortunately in simulated seawater (3.5wt.% NaCl solution) the hydrolytic H2 generation behavior of the Mg10Ni10Ce-5SnO2 composite has been greatly improved which can release as high as 468.6 mL/g H2 with about 60.9% generation yield within 30 s at 303 K. The Cl- destroys the passivation layer on Mg-Ni-Ce alloy surface and the added SnO2 nanotubes accelerate the hydrolysis reaction rate and enhance the H2 generation yield. The Mg10Ni10Ce-5SnO2 composite can rapidly generate a large amount of H2 in simulate seawater in a short time which is expected to be applied on portable H2 generators in the future.
Challenges in the Use of Hydrogen for Maritime Applications
Jan 2021
Publication
Maritime shipping is a key factor that enables the global economy however the pressure it exerts on the environment is increasing rapidly. In order to reduce the emissions of harmful greenhouse gasses the search is on for alternative fuels for the maritime shipping industry. In this work the usefulness of hydrogen and hydrogen carriers is being investigated as a fuel for sea going ships. Due to the low volumetric energy density of hydrogen under standard conditions the need for efficient storage of this fuel is high. Key processes in the use of hydrogen are discussed starting with the production of hydrogen from fossil and renewable sources. The focus of this review is different storage methods and in this work we discuss the storage of hydrogen at high pressure in liquefied form at cryogenic temperatures and bound to liquid or solid-state carriers. In this work a theoretical introduction to different hydrogen storage methods precedes an analysis of the energy-efficiency and practical storage density of the carriers. In the final section the major challenges and hurdles for the development of hydrogen storage for the maritime industry are discussed. The most likely challenges will be the development of a new bunkering infrastructure and suitable monitoring of the safety to ensure safe operation of these hydrogen carriers on board the ship.
Structural Response for Vented Hydrogen Deflagrations: Coupling CFD and FE Tools
Sep 2017
Publication
This paper describes a methodology for simulating the structural response of vented enclosures during hydrogen deflagrations. The paper also summarises experimental results for the structural response of 20-foot ISO (International Organization for Standardization) containers in a series of vented hydrogen deflagration experiments. The study is part of the project Improving hydrogen safety for energy applications through pre-normative research on vented deflagrations (HySEA). The project is funded by the Fuel Cells and Hydrogen 2 Joint Undertaking under grant agreement No 671461. The HySEA project focuses on vented hydrogen deflagrations in containers and smaller enclosures with internal congestion representative of industrial applications. The structural response modelling involves one-way coupling of pressure loads taken either directly from experiments or from simulations with the computational fluid dynamics (CFD) tool FLACS to the non-linear finite element (FE) IMPETUS Afea Solver. The performance of the FE model is evaluated for a range of experiments from the HySEA project in both small-scale enclosures and 20-foot ISO containers. The paper investigates the sensitivity of results from the FE model to the specific properties of the geometry model. The performance of FLACS is evaluated for a selected set of experiments from the HySEA project. Furthermore the paper discusses uncertainties associated with the combined modelling approach.
Integrated Ni-P-S Nanosheets Array as Superior Electrocatalysts for Hydrogen Generation
Jan 2017
Publication
Searching for efficient and robust non-noble electrocatalysts for hydrogen generation is extremely desirable for future green energy systems. Here we present the synthesis of integrated Ni-P-S nanosheets array including Ni2P and NiS on nickel foam by a simple simultaneous phosphorization and sulfurization strategy. The resultant sample with optimal composition exhibits superior electrocatalytic performance for hydrogen evolution reaction (HER) in a wide pH range. In alkaline media it can generate current densities of 10 20 and 100 mA cm−2 at low overpotentials of only −101.9 −142.0 and −207.8 mV with robust durability. It still exhibits high electrocatalytic activities even in acid or neutral media. Such superior electrocatalytic performances can be mainly attributed to the synergistic enhancement of the hybrid Ni-P-S nanosheets array with integration microstructure. The kind of catalyst gives a new insight on achieving efficient and robust hydrogen generation.
Hydrogen or Batteries for Grid Storage? A Net Energy Analysis
Apr 2015
Publication
Energy storage is a promising approach to address the challenge of intermittent generation from renewables on the electric grid. In this work we evaluate energy storage with a regenerative hydrogen fuel cell (RHFC) using net energy analysis. We examine the most widely installed RHFC configuration containing an alkaline water electrolyzer and a PEM fuel cell. To compare RHFC's to other storage technologies we use two energy return ratios: the electrical energy stored on invested (ESOIe) ratio (the ratio of electrical energy returned by the device over its lifetime to the electrical-equivalent energy required to build the device) and the overall energy efficiency (the ratio of electrical energy returned by the device over its lifetime to total lifetime electrical-equivalent energy input into the system). In our reference scenario the RHFC system has an ESOIeratio of 59 more favorable than the best battery technology available today (Li-ion ESOIe= 35). (In the reference scenario RHFC the alkaline electrolyzer is 70% efficient and has a stack lifetime of 100 000 h; the PEM fuel cell is 47% efficient and has a stack lifetime of 10 000 h; and the round-trip efficiency is 30%.) The ESOIe ratio of storage in hydrogen exceeds that of batteries because of the low energy cost of the materials required to store compressed hydrogen and the high energy cost of the materials required to store electric charge in a battery. However the low round-trip efficiency of a RHFC energy storage system results in very high energy costs during operation and a much lower overall energy efficiency than lithium ion batteries (0.30 for RHFC vs. 0.83 for lithium ion batteries). RHFC's represent an attractive investment of manufacturing energy to provide storage. On the other hand their round-trip efficiency must improve dramatically before they can offer the same overall energy efficiency as batteries which have round-trip efficiencies of 75–90%. One application of energy storage that illustrates the trade-off between these different aspects of energy performance is capturing overgeneration (spilled power) for later use during times of peak output from renewables. We quantify the relative energetic benefit of adding different types of energy storage to a renewable generating facility using [EROI]grid. Even with 30% round-trip efficiency RHFC storage achieves the same [EROI]grid as batteries when storing overgeneration from wind turbines because its high ESOIeratio and the high EROI of wind generation offset the low round-trip efficiency.
The Curious Case of the Conflicting Roles of Hydrogen in Global Energy Scenarios
Oct 2019
Publication
As energy systems transition from fossil-based to low-carbon they face many challenges particularly concerning energy security and flexibility. Hydrogen may help to overcome these challenges with potential as a transport fuel for heating energy storage conversion to electricity and in industry. Despite these opportunities hydrogen has historically had a limited role in influential global energy scenarios. Whilst more recent studies are beginning to include hydrogen the role it plays in different scenarios is extremely inconsistent. In this perspective paper reasons for this inconsistency are explored considering the modelling approach behind the scenario scenario design and data assumptions. We argue that energy systems are becoming increasingly complex and it is within these complexities that new technologies such as hydrogen emerge. Developing a global energy scenario that represents these complexities is challenging and in this paper we provide recommendations to help ensure that emerging technologies such as hydrogen are appropriately represented. These recommendations include: using the right modelling tools whilst knowing the limits of the model; including the right sectors and technologies; having an appropriate level of ambition; and making realistic data assumptions. Above all transparency is essential and global scenarios must do more to make available the modelling methods and data assumptions used.
What Role for Hydrogen in Turkey’s Energy Future?
Nov 2021
Publication
Since early 2020 Turkey has been considering the role of hydrogen in its energy future with a view to producing a hydrogen strategy in the next few months. Unlike many other countries considering the role of hydrogen Turkey has only recently (October 2021) ratified the Paris Agreement addressing climate change and its interest is driven more by geopolitical strategic and energy security concerns. Specifically with concerns about the high share of imported energy particularly gas from Russia it sees hydrogen as part of a policy to increase indigenous energy production. Turkey already has a relatively high share of renewable power generation particularly hydro and recent solar auctions have resulted in low prices leading to a focus on potential green hydrogen production. However it still generates over half of its electricity from fossil fuel including over 25% from coal and lignite. Against that background it provides an interesting case study on some of the key aspects that a country needs to consider when looking to incorporate low-carbon hydrogen into the development of their energy economy.
The research paper can be found on their website
The research paper can be found on their website
Hydrogen Scaling Up: A Sustainable Pathway for the Global Energy Transition
Nov 2017
Publication
Deployed at scale hydrogen could account for almost one-fifth of total final energy consumed by 2050. This would reduce annual CO2 emissions by roughly 6 gigatons compared to today’s levels and contribute roughly 20% of the abatement required to limit global warming to two degrees Celsius.
On the demand side the Hydrogen Council sees the potential for hydrogen to power about 10 to 15 million cars and 500000 trucks by 2030 with many uses in other sectors as well such as industry processes and feedstocks building heating and power power generation and storage. Overall the study predicts that the annual demand for hydrogen could increase tenfold by 2050 to almost 80 EJ in 2050 meeting 18% of total final energy demand in the 2050 two-degree scenario. At a time when global populations are expected to grow by two billion people by 2050 hydrogen technologies have the potential to create opportunities for sustainable economic growth.
“The world in the 21st century must transition to widespread low carbon energy use” said Takeshi Uchiyamada Chairman of Toyota Motor Corporation and co-chair of the Hydrogen Council. “Hydrogen is an indispensable resource to achieve this transition because it can be used to store and transport wind solar and other renewable electricity to power transportation and many other things. The Hydrogen Council has identified seven roles for hydrogen which is why we are encouraging governments and investors to give it a prominent role in their energy plans. The sooner we get the hydrogen economy going the better and we are all committed to making this a reality.”
Achieving such scale would require substantial investments; approximately US$20 to 25 billion annually for a total of about US$280 billion until 2030. Within the right regulatory framework – including long-term stable coordination and incentive policies – the report considers that attracting these investments to scale the technology is feasible. The world already invests more than US$1.7 trillion in energy each year including US$650 billion in oil and gas US$300 billion in renewable electricity and more than US$300 billion in the automotive industry.
“This study confirms the place of hydrogen as a central pillar in the energy transition and encourages us in our support of its large-scale deployment. Hydrogen will be an unavoidable enabler for the energy transition in certain sectors and geographies. The sooner we make this happen the sooner we will be able to enjoy the needed benefits of Hydrogen at the service of our economies and our societies” said Benoît Potier Chairman and CEO Air Liquide. “Solutions are technologically mature and industry players are committed. We need concerted stakeholder efforts to make this happen; leading this effort is the role of the Hydrogen Council.”
The launch of the new roadmap came during the Sustainability Innovation Forum in the presence of 18 senior members of the Hydrogen led by co-chairs Takeshi Uchiyamada Chairman of Toyota and Benoît Potier Chairman and CEO Air Liquide and accompanied by Prof. Aldo Belloni CEO of The Linde Group Woong-chul Yang Vice Chairman of Hyundai Motor Company and Anne Stevens Board Member of Anglo American. During the launch the Hydrogen Council called upon investors policymakers and businesses to join them in accelerating deployment of hydrogen solutions for the energy transition. It was also announced that Woong-chul Yang of Hyundai Motor Company will succeed Takeshi Uchiyamada of Toyota in the rotating role of the Council’s co-chair and preside the group together with Benoit Potier CEO Air Liquide in 2018. Mr Uchiyamada is planning to return as Co-chairman in 2020 coinciding with the Tokyo Olympic and Paalympic Games an important milestone for showcasing hydrogen society and mobility.
You can download the full report from the Hydrogen Council website here
On the demand side the Hydrogen Council sees the potential for hydrogen to power about 10 to 15 million cars and 500000 trucks by 2030 with many uses in other sectors as well such as industry processes and feedstocks building heating and power power generation and storage. Overall the study predicts that the annual demand for hydrogen could increase tenfold by 2050 to almost 80 EJ in 2050 meeting 18% of total final energy demand in the 2050 two-degree scenario. At a time when global populations are expected to grow by two billion people by 2050 hydrogen technologies have the potential to create opportunities for sustainable economic growth.
“The world in the 21st century must transition to widespread low carbon energy use” said Takeshi Uchiyamada Chairman of Toyota Motor Corporation and co-chair of the Hydrogen Council. “Hydrogen is an indispensable resource to achieve this transition because it can be used to store and transport wind solar and other renewable electricity to power transportation and many other things. The Hydrogen Council has identified seven roles for hydrogen which is why we are encouraging governments and investors to give it a prominent role in their energy plans. The sooner we get the hydrogen economy going the better and we are all committed to making this a reality.”
Achieving such scale would require substantial investments; approximately US$20 to 25 billion annually for a total of about US$280 billion until 2030. Within the right regulatory framework – including long-term stable coordination and incentive policies – the report considers that attracting these investments to scale the technology is feasible. The world already invests more than US$1.7 trillion in energy each year including US$650 billion in oil and gas US$300 billion in renewable electricity and more than US$300 billion in the automotive industry.
“This study confirms the place of hydrogen as a central pillar in the energy transition and encourages us in our support of its large-scale deployment. Hydrogen will be an unavoidable enabler for the energy transition in certain sectors and geographies. The sooner we make this happen the sooner we will be able to enjoy the needed benefits of Hydrogen at the service of our economies and our societies” said Benoît Potier Chairman and CEO Air Liquide. “Solutions are technologically mature and industry players are committed. We need concerted stakeholder efforts to make this happen; leading this effort is the role of the Hydrogen Council.”
The launch of the new roadmap came during the Sustainability Innovation Forum in the presence of 18 senior members of the Hydrogen led by co-chairs Takeshi Uchiyamada Chairman of Toyota and Benoît Potier Chairman and CEO Air Liquide and accompanied by Prof. Aldo Belloni CEO of The Linde Group Woong-chul Yang Vice Chairman of Hyundai Motor Company and Anne Stevens Board Member of Anglo American. During the launch the Hydrogen Council called upon investors policymakers and businesses to join them in accelerating deployment of hydrogen solutions for the energy transition. It was also announced that Woong-chul Yang of Hyundai Motor Company will succeed Takeshi Uchiyamada of Toyota in the rotating role of the Council’s co-chair and preside the group together with Benoit Potier CEO Air Liquide in 2018. Mr Uchiyamada is planning to return as Co-chairman in 2020 coinciding with the Tokyo Olympic and Paalympic Games an important milestone for showcasing hydrogen society and mobility.
You can download the full report from the Hydrogen Council website here
An Overview of the Recent Advances of Additive‐Improved Mg(BH4)2 for Solid‐State Hydrogen Storage Material
Jan 2022
Publication
Recently hydrogen (H2) has emerged as a superior energy carrier that has the potential to replace fossil fuel. However storing H2 under safe and operable conditions is still a challenging process due to the current commercial method i.e. H2 storage in a pressurised and liquified state which requires extremely high pressure and extremely low temperature. To solve this problem re‐ search on solid‐state H2 storage materials is being actively conducted. Among the solid‐state H2 storage materials borohydride is a potential candidate for H2 storage owing to its high gravimetric capacity (majority borohydride materials release >10 wt% of H2). Mg(BH4)2 which is included in the borohydride family shows promise as a good H2 storage material owing to its high gravimetric capacity (14.9 wt%). However its practical application is hindered by high thermal decomposition temperature (above 300 °C) slow sorption kinetics and poor reversibility. Currently the general research on the use of additives to enhance the H2 storage performance of Mg(BH4)2 is still under investigation. This article reviews the latest research on additive‐enhanced Mg(BH4)2 and its impact on the H2 storage performance. The future prospect and challenges in the development of additive‐ enhanced Mg(BH4)2 are also discussed in this review paper. To the best of our knowledge this is the first systematic review paper that focuses on the additive‐enhanced Mg(BH4)2 for solid‐state H2 storage.
Carbon Capture and Storage (CCS): The Way Forward
Mar 2018
Publication
Mai Bui,
Claire S. Adjiman,
André Bardow,
Edward J. Anthony,
Andy Boston,
Solomon Brown,
Paul Fennell,
Sabine Fuss,
Amparo Galindo,
Leigh A. Hackett,
Jason P. Hallett,
Howard J. Herzog,
George Jackson,
Jasmin Kemper,
Samuel Krevor,
Geoffrey C. Maitland,
Michael Matuszewski,
Ian Metcalfe,
Camille Petit,
Graeme Puxty,
Jeffrey Reimer,
David M. Reiner,
Edward S. Rubin,
Stuart A. Scott,
Nilay Shah,
Berend Smit,
J. P. Martin Trusler,
Paul Webley,
Jennifer Wilcox and
Niall Mac Dowell
Carbon capture and storage (CCS) is broadly recognised as having the potential to play a key role in meeting climate change targets delivering low carbon heat and power decarbonising industry and more recently its ability to facilitate the net removal of CO2 from the atmosphere. However despite this broad consensus and its technical maturity CCS has not yet been deployed on a scale commensurate with the ambitions articulated a decade ago. Thus in this paper we review the current state-of-the-art of CO2 capture transport utilisation and storage from a multi-scale perspective moving from the global to molecular scales. In light of the COP21 commitments to limit warming to less than 2 °C we extend the remit of this study to include the key negative emissions technologies (NETs) of bioenergy with CCS (BECCS) and direct air capture (DAC). Cognisant of the non-technical barriers to deploying CCS we reflect on recent experience from the UK's CCS commercialisation programme and consider the commercial and political barriers to the large-scale deployment of CCS. In all areas we focus on identifying and clearly articulating the key research challenges that could usefully be addressed in the coming decade.
Detonability of Binary H2/Ch4 - Air Mixture
Sep 2009
Publication
Abatement of greenhouse gas emissions and diversification of energy sources will probably lead to an economy based on hydrogen. In order to evaluate safety conditions during transport and distribution experimental data is needed on the detonation of Hydrogen/Natural gas blend mixtures. The aim of this study is to constitute detonation and deflagration to detonation transition (DDT) database of H2/CH4-air mixtures. More precisely the detonability of such mixtures is evaluated by the detonation cell size and the DDT run up distance measurements. Large experimental conditions are investigated (i) various equivalence ratios from 0.6 to 3 (ii) various H2 molar fraction x ( ( )2 2 4x H H CH= + ) from 0.5 to 1 (iii) different initial pressure P0 from 0.2 to 2 bar at fixed ambient temperature T0=293 K. Detonation pressures P velocities D and cell sizes ? were measured in two smooth tubes with different i.d. d (52 and 106 mm). For DDT data minimum DDT run up distances LDDT were determined in the d=52 mm tube containing a 2.8 m long Schelkin spiral with a blockage ratio BR = 0.5 and a pitch equal to the diameter. Measured detonation velocities D are very close to the Chapman Jouguet values (DCJ). Concerning the effect of detonation cell size ? follows a classical U shaped- curve with a minimum close to =1 and concerning the effect of x ? decreases when x increases. The ratio ik L?= obtained from different chemical kinetics (Li being the ZND induction length) is well approximated by the value 40 in the range 0.5 < x < 0.9 and 50 for x 0.9. Minimum DDT run up distance LDDT varies from 0.36 to 1.1m when x varies from 1 to 0.8. The results show that LDDT obeys the linear law LDDT ~ 30-40? previously validated in H2/Air mixtures. Adding Hydrogen in Natural Gas promotes the detonability of the mixtures and for x 0.65 these mixtures are considered more sensitive than common heavy Alkane-Air mixtures.
A Socio-technical Perspective on the Scope for Ports to Enable Energy Transition
Jan 2021
Publication
The paper applies the multi-level perspective (MLP) in a descriptive study of three Norwegian ports to shed new light on the sociotechnical processes that structure their efforts to develop into zero emission energy hubs. While exogenous pressures cause tensions over port governance the studied ports utilize their full spectre of functions; as landlords operators authorities and community managers to enable transition. The respective approaches vary related to their local context market situation and social networks including port's relations with their owners. Individual orientations and organizational capacity further influence their engagement with radical innovation niches (e.g. OPS hydrogen LNG). The study highlights the active role of ports in sustainability transition. It shows how the interaction between geographical factors and institutional work influences the scope for new solutions around the individual port and how this makes for different feedback loops and contributions to sustainability transition in wider transport and energy systems.
Thermal Loading Cases of Hydrogen High Pressure Storage Cylinders
Sep 2007
Publication
Composite cylinders with metal liner are used for the storage of compressed hydrogen in automotive application. These hybrid pressure cylinders are designed for a nominal working pressure of up to 70 MPa. They also have to withstand a temperature range between -40°C and +85°C according GRPE draft [1] and for short periods up to a maximum temperature of 140°C during filling (fast filling) [2]. In order to exploit the material properties efficiently with a high degree of lightweight optimization and a high level of safety on the same time a better understanding of the structural behavior of hybrid designs is necessary. Work on this topic has been carried out in the frame of a work package on safety aspects and regulation (Subproject SAR) of the European IP StorHy (www.storhy.net). The temperature influence on the composite layers is distinctive due to there typical polymer material behavior. The stiffness of the composite layer is a function of temperature which influences global strains and stress levels (residual stresses) in operation. In order to do an accurate fatigue assessment of composite hybrid cylinders a realistic modeling of a representative temperature load is needed. For this climate data has been evaluated which were collected in Europe over a period of 30 years [3]. Assuming that the temperature follows a Gaussian (normal) distribution within the assessed period of 30 years it is possible to generate a frequency distribution for different temperature classes for the cold extreme and the hot extreme. Combining these distributions leads to the overall temperature range distribution (frequency over temperature classes). The climatic temperature influence the filling temperature and the pressure load have to be considered in combination with the operation profile of the storage cylinder to derive a complete load vector for an accurate assessment of the lifetime and safety level.
Numerical Simulation of The Laminar Hydrogen Flame In The Presence of a Quenching Mesh
Sep 2009
Publication
Recent studies of J.H. Song et al. and S.Y. Yang et al. have been concentrated on mitigation measures against hydrogen risk. The authors have proposed installation of quenching meshes between compartments or around the essential equipment in order to contain hydrogen flames. Preliminary tests were conducted which demonstrated the possibility of flame extinction using metallic meshes of specific size.<br/>Considerable amount of numerical and theoretical work on flame quenching phenomenon has been performed in the second half of the last century and several techniques and models have been proposed to predict the quenching phenomenon of the laminar flame system. Most of these models appreciated the importance of heat loss to the surroundings as a primary cause of extinguishment in particular the heat transfer by conduction to the containing wall. The supporting simulations predict flame-quenching structure either between parallel plates (quenching distance) or inside a tube of a certain diameter (quenching diameter).<br/>In the present study the flame quenching is investigated assuming the laminar hydrogen flame propagating towards a quenching mesh using two-dimensional configuration and the earlier developed models. It is shown that due to a heat loss to a metallic grid the flame can be quenched numerically.
Hyper Experiments on Catastrophic Hydrogen Releases Inside a Fuel Cell Enclosure
Sep 2009
Publication
As a part of the experimental work of the EC-funded project HYPER Pro-Science GmbH performed experiments to evaluate the hazard potential of a severe hydrogen leakage inside a fuel cell cabinet. During this study hydrogen distribution and combustion experiments were performed using a generic enclosure model with the dimensions of the fuel cell "Penta H2" provided by ARCOTRONICS (now EXERGY Fuel Cells) to the project partner UNIPI for their experiments on small foreseeable leaks. Hydrogen amounts of 1.5 to 15 g H2 were released within one second into the enclosure through a nozzle with an internal diameter of 8 mm. In the distribution experiments the effects of different venting characteristics and different amounts of internal enclosure obstruction on the hydrogen concentrations measured at fixed positions in- and outside the model were investigated. Based on the results of these experiments combustion experiments with ignition positions in- and outside the enclosure and two different ignition times were performed. BOS (Background-Oriented-Schlieren) observation combined with pressure and light emission measurements were performed to describe the characteristics and the hazard potential of the induced hydrogen combustions. The experiments provide new experimental data on the distribution and combustion behaviour of hydrogen that is released into a partly vented and partly obstructed enclosure with different venting characteristics.
SGN Aberdeen Vision Project: Final Report
May 2020
Publication
The Aberdeen Vision Project could deliver CO2 savings of 1.5MtCO2/y compared with natural gas. A dedicated pipeline from St Fergus to Aberdeen would enable the phased transfer of the Aberdeen regional gas distribution system to 20% then 100% hydrogen.
The study has demonstrated that 2% hydrogen can be injected into the National Transmission System (NTS) at St Fergus and its distribution through the system into the gas distribution network. Due to unique regional attributes the Aberdeen region could lead the UK in the conversion to largescale clean hydrogen. A 200MW hydrogen generation plant is planned to suit 2% blend into the NTS followed by a build out to supply the Aberdeen gas networks and to enable low cost hydrogen transport applications.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
The study has demonstrated that 2% hydrogen can be injected into the National Transmission System (NTS) at St Fergus and its distribution through the system into the gas distribution network. Due to unique regional attributes the Aberdeen region could lead the UK in the conversion to largescale clean hydrogen. A 200MW hydrogen generation plant is planned to suit 2% blend into the NTS followed by a build out to supply the Aberdeen gas networks and to enable low cost hydrogen transport applications.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
Numerical Investigation of a Vertical Surface on the Flammable Extent of Hydrogen and Methane Vertical Jets
Sep 2011
Publication
The effect of vertical surface on the extent of high pressure unignited jets of both hydrogen and methane is studied using computer fluid dynamics simulations performed with FLACS Hydrogen. Results for constant flow rate through a 6.35 mm round leak orifice from 100 barg 250 barg 400 barg 550 barg and 700 barg compressed gas systems are presented for vertical jets. To quantify the effect of the surface on the jet the jet exit is positioned at various distances from the surface ranging from 0.029 m to 12 m. Free jets simulations are performed for comparison purposes.
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