Applications & Pathways

Ammonia is a particularly promising hydrogen carrier due to its relatively low cost high energy density its liquid storage and to its production from renewable sources. Thus in recent years great attention is devoted to this fuel for realizing next generation refueling stations according to a carbon-free energy economy. In this paper a distributed onsite refueling station (200 kg/day of hydrogen filling 700-bar HFCEVs (Hybrid Fuel Cell Electric Vehicles) with about 5 kg of hydrogen in 5 min) based on ammonia feeding is studied from the energy and economic point of views. The station is designed with a modular configuration consisting of more sections: i) the hydrogen production section ii) the electric energy supplier section iii) the compression and storage section and the refrigeration/dispenser section. The core of the station is the hydrogen production section that is based on an ammonia cracking reactor and its auxiliaries; the electric energy demand necessary for the station operation (i.e. the hydrogen compression and refrigeration) is satisfied by a PEMFC (Proton-Exchange Membrane Fuel Cell) power module. Energy performance according to the hydrogen daily demand has been evaluated and the estimation of the levelized cost of hydrogen (LCOH) has been carried out in order to establish the cost of the hydrogen at the pump that can assure the feasibility of this novel refueling station.

Hydrogen is a promising fuel to decarbonise aviation. Storage in liquid form is favoured for long-haul aircraft; storage as a high-pressure gas is preferred otherwise. The exergy expended during the compression or liquefaction process is stored as physical exergy in the fuel. Most discussions around hydrogen-fuelled aviation ignore this very significant exergy content. When combusted in an engine the chemical energy of hydrogen can produce around 60 MJ of work per kg. The work that can be extracted from the physical exergy depends strongly on the method used. This paper presents an exergy analysis considering a range of storage conditions operating conditions and work-extraction methods. For reasonable gas-turbine operating conditions upwards of 16 MJ/kg might be extracted from compressed hydrogen (at 700 bar) and 30 MJ/kg from LH2. This additional work representing 25–50 % of the shaft work produced by combustion has been by and large neglected.

Stringent CO2 reduction targets and tightening emission regulations have intensified interest in hydrogen internal combustion engines (H2ICEs) as a clean and robust solution for the heavy-duty (HD) sector. This study experimentally compares port fuel injection (PFI) early low-pressure direct injection (LPDI) and late LPDI strategies on a single-cylinder HD H2ICE under steady-state medium and high loads. The injection timing and fuel pressure are varied to study the overall influences on a single-cylinder heavy-duty H2ICE. PFI and early LPDI deliver high charge homogeneity but reduced volumetric efficiency compared to late LPDI. At medium load all three strategies achieve ~41 % gross indicated thermal efficiency (gITE). Increasing LPDI pressure from 12.8 to 20 bar enhances mixture uniformity cutting BSNOx emissions by up to 75 %. At high load early LPDI reaches 41.7 % gITE with low NOx (0.72 g/kWh) while late LPDI benefits from reduced heat transfer loss and compression work achieving 42.4 % gITE. However late injection also increases BSNOx (9.3 g/kWh) unburnt H2 (435 ppm) and pressure rise rate (19.7 bar/◦CA). These results highlight LPDI’s potential for high efficiency with injection timing and pressure as key levers to balance emissions and performance.

Green hydrogen will play a crucial role in the future of emission reduction in air traffic in the long-term as it will completely eliminate CO2 emissions and significantly reduce other pollutants such as contrails and nitrogen oxides. Hydrogen offers a promising alternative to kerosene for short- and medium-haul flights particularly through direct combustion and hydrogen fuel cell technology in new aircraft concepts. Against the background of the immense capital-intensive infrastructure adjustments that are required at airports for this purpose and the simultaneously high future hydrogen demand for the shipping industry this paper analyses the emission savings potential in Europe if airports near seaports would switch to hydrogen-powered flight connections.

Maritime and aviation transport are widely recognised as sectors where reducing greenhouse gas emissions is particularly challenging due to their reliance on energy-dense fuels and the challenges associated with direct electrification. These sectors face increasing pressure to defossilise and reduce emissions in line with global climate goals while simultaneously facing unique technological operational and economic uncertainties. This study addresses a key research gap by comparing the maritime and aviation sectors for common factors and sector-specific differences in their transition to green e-fuels produced from renewable electricity and sustainable CO2. A techno-economic assessment is conducted to evaluate alternative fuel and propulsion options using the levelised cost of mobility framework. The analysis also incorporates the pricing of non-CO2 greenhouse gases and air pollutant emissions. Results show that e-ammonia or e-LNG combustion is the most cost-effective option for maritime transport when emission costs are excluded whereas hydrogen fuel cells become more economical when these costs are internalised. In aviation e-kerosene use in conventional aircraft presents the lowest costs regardless of the year or emission pricing. The findings highlight the importance of considering unique characteristics of each sector and tailored defossilisation and decarbonisation strategies that consider sector-specific constraints. To sustainably meet the growing demand for transport fuels rapid investments in renewable electricity generation electrolysers and e-fuel synthesis are essential. Development of strong regulatory frameworks and financial instruments will be critical to support early deployment of e-fuels and minimise the risks.

In Southern Italy near the Mediterranean Sea mobility services like cars bicycles scooters and materialhandling forklifts are frequently required in addition to multimodal local transportation services such as trains ferry boats and airplanes. This research proposes an innovative concept of hydrogen valley virtually simulated in Matlab/Simulink environment located in Calabria. As a novelty hydrogen is produced centrally and delivered via fuel cell hybrid trains to seven hydrogen refueling stations serving various mobility hubs. The centralized production facility operates with a nominal capacity of about 4 tons/day producing hydrogen via PEM electrolysis and storing hydrogen at 200 bar with a hydrogen compressor. As the size of vehicle fleets and the cost of acquiring renewable energy through power purchase agreements vary the hydrogen valley is examined from both a technical and an economic perspective analyzing: the values of the levelized cost of hydrogen the energy consumption and the energy efficiency of the energy systems. Specifically the levelized cost of hydrogen reached competitive values close to 5 €/kg of hydrogen under the most optimistic scenarios with fleet conversions of more than 60 % and a power purchase agreement price lower than 150 €/MWh. Then the benefits of hydrogen rail transport in terms of emissions reduction and health from an economic standpoint are compared to conventional diesel trains and fully electric trains saving respectively 3.2 ktons/year and 0.4 ktons/year of carbon dioxide equivalent emissions and corresponding economic benefits of respectively 51 and 0.548 million euros.

The use of aluminum-based products is widespread and growing particularly in industries such as automotive food packaging and construction. Obtaining aluminum is expensive and energy-intensive making the recycling of existing products essential for economic and environmental viability. This work explores the potential of using green hydrogen as a replacement for natural gas in the smelting and refining furnaces in aluminum recycling facilities. The adoption of green hydrogen has the potential to curtail approximately 4.54 Ktons/year of CO2 emissions rendering it a sustainable and economically advantageous solution. The work evaluates the economic viability of a case study through assessing the Net Present Value (NPV) and the Internal Rate of Return (IRR). Furthermore it is employed single- and multi-parameter sensitivity analyses to obtain insight on the most relevant conditions to achieve economic viability. Results demonstrate that integrating on-site green hydrogen generation yields a favorable NPV of €57370 an IRR of 9.83% and a 19.63-year payback period. The primary factors influencing NPV are the initial electricity consumption stack and the H2 price.

The integration of wind and solar energy with green hydrogen technologies represents an innovative approach toward achieving sustainable energy solutions. This review examines state-ofthe-art strategies for synthesizing renewable energy sources aimed at improving the efficiency of hydrogen (H2 ) generation storage and utilization. The complementary characteristics of solar and wind energy where solar power typically peaks during daylight hours while wind energy becomes more accessible at night or during overcast conditions facilitate more reliable and stable hydrogen production. Quantitatively hybrid systems can realize a reduction in the levelized cost of hydrogen (LCOH) ranging from EUR 3.5 to EUR 8.9 per kilogram thereby maximizing the use of renewable resources but also minimizing the overall H2 production and infrastructure costs. Furthermore advancements such as enhanced electrolysis technologies with overall efficiencies rising from 6% in 2008 to over 20% in the near future illustrate significant progress in this domain. The review also addresses operational challenges including intermittency and scalability and introduces system topologies that enhance both efficiency and performance. However it is essential to consider these challenges carefully because they can significantly impact the overall effectiveness of hydrogen production systems. By providing a comprehensive assessment of these hybrid systems (which are gaining traction) this study highlights their potential to address the increasing global energy demands. However it also aims to support the transition toward a carbon-neutral future. This potential is significant because it aligns with both environmental goals and energy requirements. Although challenges remain the promise of these systems is evident.

The use of hydrogen as a source of fuel for marine applications is relatively nascent. As the maritime industry pivots to the use of alternate low and zero-emission fuels to adapt to a changing regulatory landscape hydrogen energy needs to present and substantiate a technical and commercially viable use case to secure its value proposition in the future fuel mix. This paper leverages the technoeconomic and environmental assessment previously performed on HyForce a hydrogen-fuelled harbour tug which has shown encouraging results for both technical and commercial aspects. This study aims to create a digital twin of HyForce to accurately predict her operability in real-world scenarios. The results from this study identify the strengths and drawbacks of the proposed use case. This is achieved by embedding the detailed design of HyForce in a virtual environment to further evaluate its operational performance through Computational Fluid Dynamics (CFD) simulations of realistic environmental conditions such as wind wave sea currents and friction attributed to the properties of seawater. The results from this study indicate a base case power requirement of 93 kW to 1892 kW to achieve speeds of 5 to 12 knots in the absence of external environmental influences. Consequently the speed of HyForce has a profound impact on total resistance peaking at 97.3 kN at 12 knots. Seawater properties such as low seawater temperature of 0C and a high salinity of 50g/kg increased friction. Additionally wind speeds of 10 m/s acting on HyForce delivered a resistance of 3 kN. However these will be well mitigated through the design of the propulsion system which will be able to deliver a thrust power of 1892 kW and with assistance from the energy storage systems produce 2 MW of power to overcome the resistance experienced. The findings presented in this paper can serve as a foundation for constructing a robust model for the development of a predictive controller for future work. This controller has the potential to optimize the configuration of hydrogen and battery energy storage aligning with desired cost functions.

The decarbonization of industrial process heat is one of the bigger challenges of the global energy transition. Process heating accounts for about 20% of final energy demand in Germany and the situation is similar in other industrialized nations around the globe. Process heating is indispensable in the manufacturing processes of products and materials encountered every day ranging from food beverages paper and textiles to metals ceramics glass and cement. At the same time process heating is also responsible for significant greenhouse gas emissions as it is heavily dependent on fossil fuels such as natural gas and coal. Thus process heating needs to be decarbonized. This review article explores the challenges of decarbonizing industrial process heat and then discusses two of the most promising options the use of electric heating technologies and the substitution of fossil fuels with low-carbon hydrogen in more detail. Both energy carriers have their specific benefits and drawbacks that have to be considered in the context of industrial decarbonization but also in terms of necessary energy infrastructures. The focus is on high-temperature process heat (>400 ◦C) in energy-intensive basic materials industries with examples from the metal and glass industries. Given the heterogeneity of industrial process heating both electricity and hydrogen will likely be the most prominent energy carriers for decarbonized high-temperature process heat each with their respective advantages and disadvantages.