Applications & Pathways
Study of the Permeation Flowrate of an Innovative Way to Store Hydrogen in Vehicles
Oct 2021
Publication
With the global warming of the planet new forms of energy are being sought as an alternative to fossil fuels. Currently hydrogen (H2) is seen as a strong alternative for fueling vehicles. However the major challenge in the use of H2 arises from its physical properties. An earlier study was conducted on the storage of H2 used as fuel in road vehicles powered by spark ignition engines or stacks of fuel cells stored under high pressure inside small spheres randomly packed in an envelope tank. Additionally the study evaluated the performance of this new storage system and compared it with other storage systems already applied by automakers in their vehicles. The current study aims to evaluate the H2 leaks from the same storage system when inserted in any road vehicle parked in conventional garages and to show the compliance of these leaks with European Standards provided that an appropriate choice of materials is made. The system’s compliance with safety standards was proved. Regarding the materials of each component of the storage system the best option from the pool of materials chosen consists of aluminum for the liner of the spheres and the envelope tank CFEP for the structural layer of the spheres and Si for the microchip.
Varying Load Distribution Impacts on the Operation of a Hydrogen Generator Plant
Oct 2021
Publication
This study advances several methods to evaluate the operation of a hydrogen generator plant. The model developed helps customize plants that contain multiple generators of varying powers using a decision module which determines the most efficient plant load distribution. Evaluation indices to assess individual devices within the plant are proposed and system flexibility maximizes the amount of renewable energy stored. Three case studies examined the variable load distribution of an electrolysis system connected to a 40 MW wind farm for energy storage purposes and incorporated a “night-valley” operational strategy. These methods facilitate the selection of the proper plant configuration and provide estimates for individual device effectiveness within the system.
Combustion Characteristics of Diesel-hydrogen Dual Fuel Engine at Low Load
May 2013
Publication
In the present study hydrogen utilization as diesel engine fuel at low load operation was investigated. Hydrogen cannot be used directly in a diesel engine due to its auto ignition temperature higher than that of diesel fuel. One alternative method is to use hydrogen in enrichment or induction. To investigate the combustion characteristics of this dual fuel engine a single cylinder diesel research engine was converted to utilize hydrogen as fuel. Hydrogen was introduced to the intake manifold using a mixer before entering the combustion chamber. The engine was run at a constant speed of 2000 rpm and 10 Nm load. Hydrogen was introduced at the flow rate of 21.4 36.2 and 49.6 liter/minute. Specific energy consumption indicated efficiency and cylinder pressure were investigated. At this low load the hydrogen enrichment reduced the cylinder peak pressure and the engine efficiency. The reaction progress variable and combustion rate of reaction were slower as shown by the CFD calculation.
Hydrogen as an Energy Vector to Optimize the Energy Exploitation of a Self-consumption Solar Photovoltaic Facility in a Dwelling House
Nov 2019
Publication
Solar photovoltaic (PV) plants coupled with storage for domestic self-consumption purposes seem to be a promising technology in the next years as PV costs have decreased significantly and national regulations in many countries promote their installation in order to relax the energy requirements of power distribution grids. However electrochemical storage systems are still unaffordable for many domestic users and thus the advantages of self-consumption PV systems are reduced. Thus in this work the adoption of hydrogen systems as energy vectors between a PV plant and the energy user is proposed. As a preliminary study in this work the design of a PV and hydrogen-production self-consumption plant for a single dwelling is described. Then a technical and economic feasibility study conducted by modeling the facility within the Homer Energy Pro energy systems analysis tool is reported. The proposed system will be able to provide back not only electrical energy but also thermal energy through a fuel cell or refined water covering the fundamental needs of the householders (electricity heat or cooling and water). Results show that although the proposed system effectively increases the energy local use of the PV production and reduces significantly the energy injections or demands into/from the power grid avoiding power grid congestions and increasing the nano-grid resilience operation and maintenance costs may reduce its economic attractiveness for a single dwelling.
The Implications of Ambitious Decarbonisation of Heat and Road Transport for Britain’s Net Zero Carbon Energy Systems
Oct 2021
Publication
Decarbonisation of heating and road transport are regarded as necessary but very challenging steps on the pathway to net zero carbon emissions. Assessing the most efficient routes to decarbonise these sectors requires an integrated view of energy and road transport systems. Here we describe how a national gas and electricity transmission network model was extended to represent multiple local energy systems and coupled with a national energy demand and road transport model. The integrated models were applied to assess a range of technologies and policies for heating and transport where the UK’s 2050 net zero carbon emissions target is met. Overall annual primary energy use is projected to reduce by between 25% and 50% by 2050 compared to 2015 due to ambitious efficiency improvements within homes and vehicles. However both annual and peak electricity demands in 2050 are more than double compared with 2015. Managed electric vehicle charging could save 14TWh/year in gas-fired power generation at peak times and associated emissions whilst vehicle-to-grid services could provide 10GW of electricity supply during peak hours. Together managed vehicle charging and vehicle-to-grid supplies could result in a 16% reduction in total annual energy costs. The provision of fast public charging facilities could reduce peak electricity demand by 17GW and save an estimated £650 million annually. Although using hydrogen for heating and transport spreads the hydrogen network costs between homeowners and motorists it is still estimated to be more costly overall compared to an all-electric scenario. Bio-energy electricity generation plants with carbon capture and storage are required to drive overall energy system emissions to net zero utilisation of which is lowest when heating is electrified and road transport consists of a mix of electric and hydrogen fuel-cell vehicles. The analysis demonstrates the need for an integrated systems approach to energy and transport policies and for coordination between national and local governments.
A Review of Hydrogen Direct Injection for Internal Combustion Engines: Towards Carbon-Free Combustion
Nov 2018
Publication
A paradigm shift towards the utilization of carbon-neutral and low emission fuels is necessary in the internal combustion engine industry to fulfil the carbon emission goals and future legislation requirements in many countries. Hydrogen as an energy carrier and main fuel is a promising option due to its carbon-free content wide flammability limits and fast flame speeds. For spark-ignited internal combustion engines utilizing hydrogen direct injection has been proven to achieve high engine power output and efficiency with low emissions. This review provides an overview of the current development and understanding of hydrogen use in internal combustion engines that are usually spark ignited under various engine operation modes and strategies. This paper then proceeds to outline the gaps in current knowledge along with better potential strategies and technologies that could be adopted for hydrogen direct injection in the context of compression-ignition engine applications—topics that have not yet been extensively explored to date with hydrogen but have shown advantages with compressed natural gas.
Experimental Investigation of the Effect of Hydrogen Addition on Combustion Performance and Emissions Characteristics of a Spark Ignition High Speed Gasoline Engine
Sep 2014
Publication
Considering energy crises and pollution problems today much work has been done for alternative fuels for fossil fuels and lowering the toxic components in the combustion products. Expert studies proved that hydrogen one of the prominent alternative energy source which has many excellent combustion properties that can be used for improving combustion and emissions performance of gasoline-fuelled spark ignition (SI) engines. This article experimentally investigated the performance and emission characteristics of a high speed single cylinder SI engine operating with different hydrogen gasoline blends. For this purpose the conventional carburetted high speed SI engine was modified into an electronically controllable engine with help of electronic control unit (ECU) which dedicatedly used to control the injection timings and injection durations of gasoline. Various hydrogen enrichment levels were selected to investigate the effect of hydrogen addition on engine brake mean effective pressure (Bmep) brake thermal efficiency volumetric efficiency and emission characteristics. The test results demonstrated that combustion performances fuel consumption and brake mean effective pressure were eased with hydrogen enrichment. The experimental results also showed that the brake thermal efficiency was higher than that for the pure gasoline operation. Moreover HC and CO emissions were all reduced after hydrogen enrichment.
Assessment of the Economic Efficiency of the Operation of Low-Emission and Zero-Emission Vehicles in Public Transport in the Countries of the Visegrad Group
Nov 2021
Publication
Transport is one of the key sectors of the European economy. However the intensive development of transport caused negative effects in the form of an increase in the emission of harmful substances. The particularly dramatic situation took place in the V4 countries. This made it necessary to implement solutions reducing emissions in transport including passenger transport. Such activities can be implemented in the field of implementation of low-emission and zero-emission vehicles for use. That is why the European Union and the governments of the Visegrad Group countries have developed numerous recommendations communications laws and strategies that order carriers to implement low- and zero-emission mobility. Therefore transport organizers and communication operators faced the choice of the type of buses. From an economic point of view each entrepreneur is guided by the economic efficiency of the vehicles used. Hence the main aim of the article was to conduct an economic evaluation of the operational efficiency of ecological vehicles. As more than 70% of vehicles in use in the European Union are still diesel driven the economic efficiency assessment was also made for vehicles with traditional diesel drive. To conduct the research the method of calculating the total cost of ownership of vehicles in operation was used. As a result of the research it was found that electric buses are the cheapest in the entire period of use (15 years) and then those powered by CNG. On the other hand the cost of using hydrogen buses is the highest. This is due to the high purchase prices of these vehicles. However the EU as well as the governments of individual countries support enterprises and communication operators by offering them financing for investments. The impact of the forecasted fuel and energy prices and the planned inflation on operating costs was also examined. In this case the analyses showed that the forecasted changes in fuel and energy prices as well as the expected inflation will significantly affect the costs of vehicle operation and the economic efficiency of using various types of drives. These changes will have a positive impact on the implementation of zero-emission vehicles into exploitation. Based on the analyses it was found that in 2035 hydrogen buses will have the lowest operating costs.
Preliminary Design of a Self-Sufficient Electrical Storage System Based on Electrolytic Hydrogen for Power Supply in a Residential Application
Oct 2021
Publication
The use of renewable energy and hydrogen technology is a sustainable solution for the intermittent feature of renewable energies. Hence the aim of the present work is to design a self-sufficient system for a one-family house by coupling a solar photovoltaic array and an anion exchange membrane water electrolyzer (AEMWE). The first step is the selection of the photovoltaic panel by using PV-SYST 7.0 software. Then the hydrogen production system is calculated by coupling the electrolyzer and photovoltaic panel current–potential curves. A fuel cell is selected to use the hydrogen produced when solar energy is not available. Finally the hydrogen storage tank is also estimated to store hydrogen for a design basis of four consecutive cloudy days according to the hydrogen consumption of the fuel cell. The whole system is designed by a simple procedure for a specific location in Ciudad Real (Spain) for January which is known as the coldest month of the year. The simple procedure described in this work could be used elsewhere and demonstrated that the hydrogen production at low scale is a suitable technology to use renewable energy for self-energy supporting in a residential application without any connection to the grid.
Integration Design and Operation Strategy of Multi-Energy Hybrid System Including Renewable Energies, Batteries and Hydrogen
Oct 2020
Publication
In some areas the problem of wind and solar power curtailment is prominent. Hydrogen energy has the advantage of high storage density and a long storage time. Multi-energy hybrid systems including renewable energies batteries and hydrogen are designed to solve this problem. In order to reduce the power loss of the converter an AC-DC hybrid bus is proposed. A multi-energy experiment platform is established including a wind turbine photovoltaic panels a battery an electrolyzer a hydrogen storage tank a fuel cell and a load. The working characteristics of each subsystem are tested and analyzed. The multi-energy operation strategy is based on state monitoring and designed to enhance hydrogen utilization energy efficiency and reliability of the system. The hydrogen production is guaranteed preferentially and the load is reliably supplied. The system states are monitored such as the state of charge (SOC) and the hydrogen storage level. The rated and ramp powers of the battery and fuel cell and the pressure limit of the hydrogen storage tank are set as safety constraints. Eight different operation scenarios comprehensively evaluate the system’s performance and via physical experiments the proposed operation strategy of the multi-energy system is verified as effective and stable.
The Role of Renewable Hydrogen and Inter-seasonal Storage in Decarbonising Heat – Comprehensive Optimisation of Future Renewable Energy Value Chains
Nov 2018
Publication
Demands for space and water heating constitute a significant proportion of the total energy demands in Great Britain and are predominantly satisfied through natural gas which makes the heat sector a large emitter of carbon dioxide. Renewable hydrogen which can be injected into the gas grid or used directly in processes for generating heat and/or electricity is being considered as a low-carbon alternative energy carrier to natural gas because of its suitability for large-scale long- and short-term storage and low transportation losses all of which help to overcome the intermittency and seasonal variations in renewables. This requires new infrastructures for production storage transport and utilisation of renewable hydrogen – a hydrogen value chain – the design of which involves many interdependent decisions such as: where to locate wind turbines; where to locate electrolysers close to wind generation or close to demands; whether to transport energy as electricity or hydrogen and how; where to locate storage facilities; etc. This paper presents the Value Web Model a novel and comprehensive spatio-temporal mixed-integer linear programming model that can simultaneously optimise the design planning and operation of integrated energy value chains accounting for short-term dynamics inter-seasonal storage and investments out to 2050. It was coupled with GIS modelling to identify candidate sites for wind generation and used to optimise a number of scenarios for the production of hydrogen from onshore and offshore wind turbines in order to satisfy heat demands. The results show that over a wide range of scenarios the optimal pathway to heat is roughly 20% hydrogen and 80% electricity. Hydrogen storage both in underground caverns and pressurised tanks is a key enabling technology.
Optimization of Hydrogen Cost and Transport Technology in France and Germany for Various Production and Demand Scenarios
Jan 2021
Publication
Green hydrogen for mobility represents an alternative to conventional fuel to decarbonize the transportation sector. Nevertheless the thermodynamic properties make the transport and the storage of this energy carrier at standard conditions inefficient. Therefore this study deploys a georeferenced optimal transport infrastructure for four base case scenarios in France and Germany that differs by production distribution based on wind power potential and demand capacities for the mobility sector at different penetration shares for 2030 and 2050. The restrained transport network to the road infrastructure allows focusing on the optimum combination of trucks operating at different states of aggregations and storage technologies and its impact on the annual cost and hydrogen flow using linear programming. Furthermore four other scenarios with production cost investigate the impact of upstream supply chain cost and eight scenarios with daily transport and storage optimization analyse the modeling method sensitivity. The results show that compressed hydrogen gas at a high presser level around 500 bar was on average a better option. However at an early stage of hydrogen fuel penetration substituting compressed gas at low to medium pressure levels by liquid organic hydrogen carrier minimizes the transport and storage costs. Finally in France hydrogen production matches population distribution in contrast to Germany which suffers from supply and demand disparity.
Comprehensive Analysis of the Combustion of Low Carbon Fuels (Hydrogen, Methane and Coke Oven Gas) in a Spark Ignition Engine through CFD Modeling
Nov 2021
Publication
The use of low carbon fuels (LCFs) in internal combustion engines is a promising alternative to reduce pollution while achieving high performance through the conversion of the high energy content of the fuels into mechanical energy. However optimizing the engine design requires deep knowledge of the complex phenomena involved in combustion that depend on the operating conditions and the fuel employed. In this work computational fluid dynamics (CFD) simulation tools have been used to get insight into the performance of a Volkswagen Polo 1.4L port-fuel injection spark ignition engine that has been fueled with three different LCFs coke oven gas (COG) a gaseous by-product of coke manufacture H2 and CH4. The comparison is made in terms of power pressure temperature heat release flame growth speed emissions and volumetric efficiency. Simulations in Ansys® Forte® were validated with experiments at the same operating conditions with optimal spark advance wide open throttle a wide range of engine speed (2000–5000 rpm) and air-fuel ratio (λ) between 1 and 2. A sensitivity analysis of spark timing has been added to assess its impact on combustion variables. COG with intermediate flame growth speed produced the greatest power values but with lower pressure and temperature values at λ = 1.5 reducing the emissions of NO and the wall heat transfer. The useful energy released with COG was up to 16.5% and 5.1% higher than CH4 and H2 respectively. At richer and leaner mixtures (λ = 1 and λ = 2) similar performances were obtained compared to CH4 and H2 combining advantages of both pure fuels and widening the λ operation range without abnormal combustion. Therefore suitable management of the operating conditions maximizes the conversion of the waste stream fuel energy into useful energy while limiting emissions.
Challenges and Prospects of Renewable Hydrogen-based Strategies for Full Decarbonization of Stationary Power Applications
Oct 2021
Publication
The exponentially growing contribution of renewable energy sources in the electricity mix requires large systems for energy storage to tackle resources intermittency. In this context the technologies for hydrogen production offer a clean and versatile alternative to boost renewables penetration and energy security. Hydrogen production as a strategy for the decarbonization of the energy sources mix has been investigated since the beginning of the 1990s. The stationary sector i.e. all parts of the economy excluding the transportation sector accounts for almost three-quarters of greenhouse gases (GHG) emissions (mass of CO2-eq) in the world associated with power generation. While several publications focus on the hybridization of renewables with traditional energy storage systems or in different pathways of hydrogen use (mainly power-to-gas) this study provides an insightful analysis of the state of art and evolution of renewable hydrogen-based systems (RHS) to power the stationary sector. The analysis started with a thorough review of RHS deployments for power-to-power stationary applications such as in power generation industry residence commercial building and critical infrastructure. Then a detailed evaluation of relevant techno-economic parameters such as levelized cost of energy (LCOE) hydrogen roundtrip efficiency (HRE) loss of power supply probability (LPSP) self-sufficiency ratio (SSR) or renewable fraction (fRES) is provided. Subsequently lab-scale plants and pilot projects together with current market trends and commercial uptake of RHS and fuel cell systems are examined. Finally the future techno-economic barriers and challenges for short and medium-term deployment of RHS are identified and discussed.
Energy Management Strategies for a Zero-emission Hybrid Domestic Ferry
Oct 2021
Publication
The paper presents three approaches for the sizing and control of a maritime hybrid power-plant equipped with proton exchange membrane fuel cells and batteries. The study focuses on three different power-plant configurations including the energy management strategy and the power-plant component sizing. The components sizing is performed following the definition of the energy management strategy using the sequential optimization approach. These configurations are tested using a dynamic model developed in Simulink. The simulations are carried out to validate the technical feasibility of each configuration for maritime use. Each energy management strategy is developed to allow for the optimization of a chosen set of parameters such as hydrogen consumption and fuel cell degradation. It is observed that in the hybrid power-plant optimization there are always trade-offs and the optimization should be carried out by prioritizing primary factors the ship owner considers most important for day-to-day operations.
What Will Fuel Transport Systems of the Future?
Nov 2011
Publication
This paper seeks to decry the notion of a single solution or “silver bullet” to replace petroleum products with renewable transport fuel. At different times different technological developments have been in vogue as the panacea for future transport needs: for quite some time hydrogen has been perceived as a transport fuel that would be all encompassing when the technology was mature. Liquid biofuels have gone from exalted to unsustainable in the last ten years. The present flavor of the month is the electric vehicle. This paper examines renewable transport fuels through a review of the literature and attempts to place an analytical perspective on a number of technologies.
Well to Wheel Analysis of Low Carbon Alternatives for Road Traffic
Sep 2015
Publication
Several alternative fuel–vehicle combinations are being considered for replacement of the internal combustion engine (ICE) vehicles to reduce greenhouse gas (GHG) emissions and the dependence on fossil fuels. The International Energy Agency has proposed the inclusion of low carbon alternatives such as electricity hydrogen and biofuels in the transport sector for reducing the GHG emissions and providing a sustainable future. This paper compares the use of these alternative fuels viz. electricity hydrogen and bio-ethanol in combination with battery electric vehicle (BEV) and fuel cell electric vehicle (FCEV) technologies on the basis of their overall efficiency and GHG emissions involved in the conversion of the primary energy source to the actual energy required at wheels through a well-to-wheel analysis. The source of energy for electricity production plays a major role in determining the overall efficiency and the GHG emissions of a BEV. Hence electricity production mix of Germany (60% fossil fuel energy) France (76% nuclear energy) Sweden and Austria (60 and 76% renewable energy respectively) the European Union mix (48% fossil fuel energy) and the United States of America (68% fossil fuel energy) are considered for the BEV analysis. In addition to the standard hydrogen based FCEVs CNG and bio-ethanol based FCEVs are analysed. The influence of a direct ethanol fuel cell (DEFC) on GHG emissions and overall chain efficiency is discussed. In addition to the standard sources of bio-ethanol (like sugarcane corn etc.) sources like wood waste and wheat straw are included in the analysis. The results of this study suggest that a BEV powered by an electricity production mix dominated by renewable energy and bio-ethanol based DEFC electric vehicles offer the best solution in terms of GHG emissions efficiency and fossil fuel dependency. Bio-ethanol as a fuel has the additional advantage to be implemented readily in ICE vehicles followed by advancements through reformer based FCEVs and DEFC electric vehicles. Although important this analysis does not include the health effects of the alternative vehicles. Bio-ethanol used in an ICE may lead to increased emission of acetaldehydes which however might not be the case if it is used in fuel cells.
Hydrogen Fuel Cell Vehicles; Current Status and Future Prospect
Jun 2019
Publication
The hazardous effects of pollutants from conventional fuel vehicles have caused the scientific world to move towards environmentally friendly energy sources. Though we have various renewable energy sources the perfect one to use as an energy source for vehicles is hydrogen. Like electricity hydrogen is an energy carrier that has the ability to deliver incredible amounts of energy. Onboard hydrogen storage in vehicles is an important factor that should be considered when designing fuel cell vehicles. In this study a recent development in hydrogen fuel cell engines is reviewed to scrutinize the feasibility of using hydrogen as a major fuel in transportation systems. A fuel cell is an electrochemical device that can produce electricity by allowing chemical gases and oxidants as reactants. With anodes and electrolytes the fuel cell splits the cation and the anion in the reactant to produce electricity. Fuel cells use reactants which are not harmful to the environment and produce water as a product of the chemical reaction. As hydrogen is one of the most efficient energy carriers the fuel cell can produce direct current (DC) power to run the electric car. By integrating a hydrogen fuel cell with batteries and the control system with strategies one can produce a sustainable hybrid car
Comparison of Hydrogen Powertrains with the Battery Powered Electric Vehicle and Investigation of Small-Scale Local Hydrogen Production Using Renewable Energy
Jan 2021
Publication
Climate change is one of the major problems that people face in this century with fossil fuel combustion engines being huge contributors. Currently the battery powered electric vehicle is considered the predecessor while hydrogen vehicles only have an insignificant market share. To evaluate if this is justified different hydrogen power train technologies are analyzed and compared to the battery powered electric vehicle. Even though most research focuses on the hydrogen fuel cells it is shown that despite the lower efficiency the often-neglected hydrogen combustion engine could be the right solution for transitioning away from fossil fuels. This is mainly due to the lower costs and possibility of the use of existing manufacturing infrastructure. To achieve a similar level of refueling comfort as with the battery powered electric vehicle the economic and technological aspects of the local small-scale hydrogen production are being investigated. Due to the low efficiency and high prices for the required components this domestically produced hydrogen cannot compete with hydrogen produced from fossil fuels on a larger scale
H2 Green Hydrogen Discussion Paper: Victorian Hydrogen Investment Program
Nov 2019
Publication
This discussion paper is for stakeholders who would like to shape the development of Victoria’s emerging green hydrogen sector identifying competitive advantages and priority focus areas for industry and the Victorian Government.<br/>The Victorian Government is using this paper to focus on the economic growth and sector development opportunities emerging for a Victorian hydrogen industry powered by renewable energy also known as ‘green’ hydrogen. In addition this paper seeks input from all stakeholders on how where and when the Victorian Government can act to establish a thriving green hydrogen economy.<br/>Although green hydrogen is the only type of hydrogen production within the scope of this discussion paper the development of the VHIP aligns with the policies projects and initiatives which support these other forms of hydrogen production. The VHIP is considering the broad policy landscape and actively coordinating with related hydrogen programs policies and strategies under development including the Council of Australian Governments (COAG) Energy Council’s National Hydrogen Strategy to ensure a complementary approach. In Victoria there are several programs and strategies in development and underway that have linkages with hydrogen and the VHIP.
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