Hydrogen Blending
Hydrogen Addition to a Commercial Self-aspirating Burner and Assessment of a Practical Burner Modification Strategy to Improve Performance
Jul 2023
Publication
The ability for existing burners to operate safely and efficiently on hydrogen-blended fuels is a primary concern for the many industries looking to adopt hydrogen as an alternative fuel. This study investigates the efficacy of increasing fuel injector diameter as a simple modification strategy to extend the hydrogen-blending limits before flashback. The collateral effects of this modification are quantified with respect to a set of key performance criteria. The results show that the unmodified burner can sustain up to 50 vol% hydrogen addition before flashback. Increasing the fuel injector diameter reduces primary aeration allowing for stable operation on up to 100% hydrogen. The flame length visibility and radiant heat transfer properties are all increased as a result of the reduced air entrainment with a trade-off reported for NOx emissions where in addition to the effects of hydrogen reducing air entrainment further increases NOx emissions.
Modelling of Hydrogen Blending into the UK Natural Gas Network Driven by a Solid Oxide Fuel Cell for Electricity and District Heating System
Aug 2023
Publication
A thorough investigation of the thermodynamics and economic performance of a cogeneration system based on solid oxide fuel cells that provides heat and power to homes has been carried out in this study. Additionally different percentages of green hydrogen have been blended with natural gas to examine the techno-economic performance of the suggested cogeneration system. The energy and exergy efficiency of the system rises steadily as the hydrogen blending percentage rises from 0% to 20% then slightly drops at 50% H2 blending and then rises steadily again until 100% H2 supply. The system’s minimal levelised cost of energy was calculated to be 4.64 £/kWh for 100% H2. Artificial Neural Network (ANN) model was also used to further train a sizable quantity of data that was received from the simulation model. Heat power and levelised cost of energy estimates using the ANN model were found to be extremely accurate with coefficients of determination of 0.99918 0.99999 and 0.99888 respectively.
Composition Tracking of Natural Gas-Hydrogen Mixtures in Pipeline Flow Using High-resolution Schemes
Jul 2024
Publication
A transient pipeline flow model with gas composition tracking is solved for studying the operation of a natural gas pipeline under nonisothermal flow conditions in a hydrogen injection scenario. Two approaches to high-resolution pipeline flow modeling based on the WENO scheme are presented and compared with the implicit finite difference method. The high-resolution models are capable of capturing fast fluid transients and tracking the step changes in the composition of the transported mixture. The implicit method assumes the decoupling of the flow model components in order to enhance calculation efficiency. The validation of the composition tracking results against actual gas transmission pipeline indicates that both models exhibit good prediction performance with normalized root mean square errors of 0.406% and 1.48% respectively. Under nonisothermal flow conditions the prediction response of the reduced model against a high-resolution flow model with respect to the mass and energy linepack is at most 3.20%.
Estimating Greenhouse Gas Emissions from Hydrogen-Blended Natural Gas Networks
Dec 2024
Publication
Methane is a significant contributor to anthropogenic greenhouse gas emissions. Blending hydrogen with natural gas in existing networks presents a promising strategy to reduce these emissions and support the transition to a carbon-neutral energy system. However hydrogen’s potential for atmospheric release raises safety and environmental concerns necessitating an assessment of its impact on methane emissions and leakage behavior. This study introduces a methodology for estimating how fugitive emissions change when a natural gas network is shifted to a 10% hydrogen blend by combining analytical flowrate models with data from sampled leaks across a natural gas network. The methodology involves developing conversion factors based on existing methane emission rates to predict corresponding hydrogen emissions across different sections of the network including mainlines service lines and facilities. Our findings reveal that while the overall volumetric emission rates increase by 5.67% on the mainlines and 3.04% on the service lines primarily due to hydrogen’s lower density methane emissions decrease by 5.95% on the mainlines and 8.28% on the service lines. However when considering the impact of a 10% hydrogen blend on the Global Warming Potential the net reduction in greenhouse gas emissions is 5.37% for the mainlines and 7.72% for the service lines. This work bridges the gap between research on hydrogen leakage and network readiness which traditionally focuses on safety and environmental sustainability studies on methane emission.
Numerical Simulation of Hydrogen–Coal Blending Combustion in a 660 MW Tangential Boiler
Feb 2024
Publication
With the adjustment of energy structure the utilization of hydrogen energy has been widely attended. China’s carbon neutrality targets make it urgent to change traditional coal-fired power generation. The paper investigates the combustion of pulverized coal blended with hydrogen to reduce carbon emissions. In terms of calorific value the pulverized coal combustion with hydrogen at 1% 5% and 10% blending ratios is investigated. The results show that there is a significant reduction in CO2 concentration after hydrogen blending. The CO2 concentration (mole fraction) decreased from 15.6% to 13.6% for the 10% hydrogen blending condition compared to the non-hydrogen blending condition. The rapid combustion of hydrogen produces large amounts of heat in a short period which helps the ignition of pulverized coal. However as the proportion of hydrogen blending increases the production of large amounts of H2O gives an overall lower temperature. On the other hand the temperature distribution is more uniform. The concentrations of O2 and CO in the upper part of the furnace increased. The current air distribution pattern cannot satisfy the adequate combustion of the fuel after hydrogen blending.
Analysis of Operational Parameters and Emissions in a Domestic Natural Gas Heating Appliance with Hydrogen Blending
Dec 2024
Publication
The weather-dependent nature of renewable energy production has led to periodic overproduction making hydrogen production a practical solution for storing excess energy. In addition to conventional storage methods such as physical tanks or chemical bonding using the existing natural gas network as a storage medium has also proven to be effective. Households can play a role in this process as well. The purpose of these experiments is to evaluate the parameters of a household heating device currently in use but not initially designed for hydrogen operation. The appliance used in the tests has a closed combustion chamber with a natural draft induced by a density difference which is a common type. The tests were conducted at nominal load with a mix of 0–40 V/V% hydrogen and natural gas; no flashbacks or other issues occurred. As the hydrogen ratio increased from 0 to 40 V/V% the input heat decreased from 3.9 kW to 3.4 kW. The NOx concentration in the flue gas dropped from 26.2 ppm to 14.2 ppm and the CO2 content decreased from 4.5 V/V% to 3.4 V/V%. However the CO con centration slightly increased from 40.0 ppm to 44.1 ppm. Despite these changes efficiency remained stable fluctuating between 86.9% and 87.0%. The internal flame cone height was 3.27 mm when using natural gas but reduced sharply to just 0.38 mm when using 62 V/V% hydrogen. In addition to the fact that the article examines a group of devices that has been rarely investigated but is also widely distributed it also provides valuable experience for other experiments since the experiments were carried out with a higher hydrogen ratio compared to previous works.
Effect of Gas Composition and Initial Turbulence on the Propagation Dynamics of Premixed Flames of Hydrogen-blended Natural Gas Fuel
Jul 2024
Publication
In order to reduce carbon emissions the effects of gas composition and initial turbulence on the premixed flame dynamics of hydrogen-blended natural gas were investigated. The results show that an increase in hydrogen content leads to earlier formation of flame wrinkles. When the equivalence ratio is 1 and hydrogen blending ratio is below 20% Tulip flames appear approximately 2.25 m away from the ignition point. When hydrogen blending ratio exceeds 20% Tulip flames appear approximately 1.3 m away from the ignition point and twisted Tulip flames appear approximately 2.5 m away from the ignition position. During the 0.05 m process of flame propagation downstream from ignition point flame propagation velocity increases by about 2 m/s for every 10% increase in hydrogen content. The increase in hydrogen content has the most significant impact on the flame propagation velocity during the ignition stage. The average flame propagation velocity increases with the increase of hydrogen blending ratio. The greater the initial turbulence the more obvious the stretching deformation of flame front structure. With the increase of wind speed the flame propagation velocity first increases and then decreases. At a wind speed of 3 m/s the flame propagation velocity reaches its maximum value.
Blending Hydrogen in Existing Natural Gas Pipelines: Integrity Consequences from a Fitness for Service Perspective
Jun 2023
Publication
Blending hydrogen in existing natural gas pipelines compromises steel integrity because it increases fatigue crack growth promotes subcritical cracking and decreases fracture toughness. In this regard several laboratories reported that the fracture toughness measured in a hydrogen containing gaseous atmosphere KIH can be 50% or less than KIC the fracture toughness measured in air. From a pipeline integrity perspective fracture mechanics predicts that injecting hydrogen in a natural gas pipeline decreases the failure pressure and the size of the critical flaw at a given pressure level. For a pipeline with a given flaw size as shown in this work the effect of hydrogen embrittlement (HE) in the predicted failure pressure is largest when failure occurs by brittle fracture. The HE effect on failure pressure diminishes with a decreasing crack size or increasing fracture toughness. The safety margin after a successful hydrostatic test is reduced and therefore the time between hydrotests should be decreased. In this work all those effects were quantified using a crack assessment methodology (level 2 API 579-ASME FFS) considering literature values for KIH and KIC reported for an API 5L X52 pipeline steel. To characterize different scenarios various crack sizes were assumed including a small crack with a size close to the detection limit of current in-line inspection techniques and a larger crack that represents the largest crack size that could survive a hydrotest to 100% of the steel specified minimum yield stress. The implications of a smaller failure pressure and smaller critical crack size on pipeline integrity are discussed in this paper.
Numerical Simulation of Diffusion Characteristics and Hazards in Multi-Hole Leakage from Hydrogen-Blended Natural Gas Pipelines
Aug 2025
Publication
In this study a 3D model is developed to simulate multi-hole leakage scenarios in buried pipelines transporting hydrogen-blended natural gas (HBNG). By introducing three parameters—the First Dangerous Time (FDT) Ground Dangerous Range (GDR) and Farthest Dangerous Distance (FDD)—to characterize the diffusion hazard of the gas mixture this study further analyzes the effects of the number of leakage holes hole spacing hydrogen blending ratio (HBR) and soil porosity on the diffusion hazard of the gas mixture during leakage. Results indicate that gas leakage exhibits three distinct phases: initial independent diffusion followed by an intersecting accelerated diffusion stage and culminating in a unified-source diffusion. Hydrogen exhibits the first two phases whereas methane undergoes all three and dominates the GDR. Concentration gradients for multi-hole leakage demonstrate similarities to single-hole scenarios but multi-hole leakage presents significantly higher hazards. When the inter-hole spacing is small diffusion characteristics converge with those of single-hole leakage. Increasing HBR only affects the gas concentration distribution near the leakage hole with minimal impact on the overall ground danger evolution. Conversely variations in soil porosity substantially impact leakage-induced hazards. The outcomes of this study will support leakage monitoring and emergency management of HBNG pipelines.
Ultrasonic Time-of-flight Measurement of Hydrogen Blending Ratios for Industrial Combustion Applications
Oct 2025
Publication
Hydrogen blending offers significant potential for decarbonizing natural gas-based thermal processes particularly in the steel and cement sectors. Due to its distinct combustion properties compared to natural gas – such as lower minimum air requirements and altered flame speeds – the hydrogen fraction of the fuel must be monitored for combustion control. In this study we present an ultrasonic time-of-flight measurement system for hydrogen concentrations of 0–40% in natural gas. The system is verified with test gas mixtures at laboratory scale and validated in a technical-scale setup using a real blower burner (< 60 kW). We evaluate uncertainty of the hydrogen fraction measurement and analyze the influence of varying natural gas compositions. We show that standard uncertainties below 4% can be achieved without knowledge of the specific natural gas composition. Our results provide insights for measurement system design and support the safe application of hydrogen in thermal systems for industrial processes.
Towards Decarbonizing Gas: A Generic Optimal Gas Flow Model with Linepack Constraints for Assessing the Feasibility of Hydrogen Blending in Existing Gas Networks
Aug 2025
Publication
Hydrogen blending into natural gas networks is a promising pathway to decarbonize the gas sector but requires bespoke fluid-dynamic models to accurately capture the properties of hydrogen and assess its feasibility. This paper introduces a generalizable optimal transient gas flow model for transporting homogeneous natural gashydrogen mixtures in large-scale networks. Designed for preliminary planning the model assesses whether a network can operate under a given hydrogen blending ratio without violating existing constraints such as pressure limits pipeline and compressor capacity. A distinguishing feature of the model is a multi-day linepack management strategy that engenders realistic linepack profiles by precluding mathematically feasible but operationally unrealistic solutions thereby accurately reflecting the flexibility of the gas system. The model is demonstrated on Western Australia’s 7560 km transmission network using real system topology and demand data from several representative days in 2022. Findings reveal that the system can accommodate up to 20 % mol hydrogen potentially decarbonizing 7.80 % of gas demand.
Dissociative Adsorption of Hydrogen in Hydrogen-Blended Natural Gas Pipelines: A First Principles and Thermodynamic Analysis
Jun 2025
Publication
This study employs first principles calculations and thermodynamic analyses to investigate the dissociative adsorption of hydrogen on the Fe(110) surface. The results show that the adsorption energies of hydrogen at different sites on the iron surface are −1.98 eV (top site) −2.63 eV (bridge site) and −2.98 eV (hollow site) with the hollow site being the most stable adsorption position. Thermodynamic analysis further reveals that under operational conditions of 25 ◦C and 12 MPa the Gibbs free energy change (∆G) for hydrogen dissociation is −1.53 eV indicating that the process is spontaneous under pipeline conditions. Moreover as temperature and pressure increase the spontaneity of the adsorption process improves thus enhancing hydrogen transport efficiency in pipelines. These findings provide a theoretical basis for optimizing hydrogen transport technology in natural gas pipelines and offer scientific support for mitigating hydrogen embrittlement improving pipeline material performance and developing future hydrogen transportation strategies and safety measures.
Numerical Simulation of Natural Gas/Hydrogen Combustion in a Novel Laboratory Combustor
Jun 2025
Publication
Hydrogen is a promising fuel in the current transition to zero-net CO2 emissions. However most practical combustion equipment is not yet ready to burn pure hydrogen without adaptation. In the meantime blending hydrogen with natural gas is an interesting option. This work reports a computational study of the performance of swirl-stabilized natural gas/hydrogen flames in a novel combustion chamber design. The combustor employs an air-staging strategy introducing secondary air through a top-mounted plenum in a direction opposite to the fuel jet. The thermal load is fixed at 5 kW and the effects of fuel composition (hydrogen molar fraction ranging from zero to one) excess air coefficient (λ = 1.3 1.5 or 1.7) and primary air fraction (α = 50–100%) on the velocity temperature and emissions are analysed. The results show that secondary air changes the flow pattern reducing the central recirculation zone and lowering the temperature in the primary reaction zone while increasing it further downstream. Secondary air improves the performance of the combustor for pure hydrogen flames reducing NO emissions to less than 50 ppm for λ = 1.3 and 50% primary air. For natural gas/hydrogen blends a sufficiently high excess air level is required to keep CO emissions within acceptable limits.
Numerical Investigation on the Diffusion and Ventilation Characteristics of Hydrogen-Blended Natural Gas Leakage in Indoor Spaces
Oct 2025
Publication
The blending of hydrogen significantly impacts the diffusion and safety characteristics of natural gas within indoor environments. This study employs ANSYS Fluent 2021 R1 to numerically investigate the diffusion and ventilation characteristics of hydrogen-blended natural gas (HBNG) leakage in indoor spaces. A physical and mathematical model of gas leakage from pipelines is established to study hazardous areas flammable regions ventilation characteristics alarm response times safe ventilation rates and the concentration distribution of leaked gas. The effects of hydrogen blending ratio (HBR) ventilation conditions and space dimensions on leakage diffusion and safety are analyzed. Results indicate that HBNG leakage forms vertical concentration stratification in indoor spaces with ventilation height being negatively correlated with gas concentration and flammable regions. In the indoor space conditions of this study by improving ventilation conditions the hazardous area can be reduced by up to 92.67%. Increasing HBR substantially expands risk zones—with pure hydrogen producing risk volumes over five times greater than natural gas. Mechanical ventilation significantly enhances indoor safety. Safe ventilation rates escalate with hydrogen content providing quantitative safety criteria for HBNG implementation. The results underscore the critical influence of HBR and ventilation strategy on risk assessment providing essential insights for the safe indoor deployment of HBNG.
Numerical Simulation Study of Gas Stratification in Hydrogen-Enriched Natural Gas Pipelines
Jun 2025
Publication
Hydrogen blending in natural gas pipelines facilitates renewable energy integration and cost-effective hydrogen transport. Due to hydrogen’s lower density and higher leakage potential compared to natural gas understanding hydrogen concentration distribution is critical. This study employs ANSYS Fluent 2022 R1 with a realizable k-ε model to analyze flow dynamics of hydrogen–methane mixtures in horizontal and undulating pipelines. The effects of hydrogen blending ratios pressure (3–8 MPa) and pipeline geometry were systematically investigated. Results indicate that in horizontal pipelines hydrogen concentrations stabilize near initial values across pressure variations with minimal deviation (maximum increase: 1.6%). In undulating pipelines increased span length of elevated sections reduces maximum hydrogen concentration while maintaining proximity (maximum increase: 0.65%) to initial levels under constant pressure. Monitoring points exhibit concentration fluctuations with changing pipeline parameters though no persistent stratification occurs. However increasing the undulating height elevation difference leads to an increase in the maximum hydrogen concentration at the top of the pipeline rising from 3.74% to 9.98%. The findings provide theoretical insights for safety assessments of hydrogen–natural gas co-transport and practical guidance for pipeline design optimization.
Performance Assessment and Predictive Modeling of a Hybrid Hydrogen-Natural Gas Water Heater Using Experimental Data and Machine Learning
Aug 2025
Publication
In response to the global need to reduce greenhouse gas emissions and advance the decarbonization of thermal energy systems this study evaluates the performance of a tankless water heater operating with hydrogen–natural gas blends. The objective is to improve thermal efficiency and reduce pollutant emissions without requiring major modifications to existing equipment. Experimental tests were conducted at three thermal power levels (35 40 and 45 kW) and four hydrogen volume fractions (0% 20% 40% and 60%) analyzing operational variables such as temperatures flow rates efficiency and NOx emissions. Results show that efficiency increases with hydrogen content particularly at lower power levels reaching a maximum of 56%. NOx emissions tend to rise with both power and hydrogen fraction although this effect can be mitigated by controlling the water flow rate. In addition machine learning models were trained to predict efficiency and emissions with the scaled Support Vector Regression (SVR) model achieving R² values above 90% for both outputs. This approach not only enables system optimization but also represents a step toward the implementation of digital twins and opens the door to monitoring indirect variables offering broad potential for predictive applications in thermal equipment.
Comprehensive Experimental Assessment of NOx Emissions in Swirling Diffusion Flames of Natural Gas-hydrogen Blends
Oct 2025
Publication
In the transformation process from fossil-fuel based to carbon-neutral combustion full or partial replacement of natural gas with hydrogen is considered in numerous industrial applications. As hydrogen flames yield significantly higher NOX emissions than natural gas flames understanding what factors influence these emissions in flames of natural gas/hydrogen blends is crucial for the retrofitting process. Our work is concerned with the simplest form of industrial retrofitting where hydrogen is injected into the natural gas line without any modifications to the burner construction while keeping the burner power constant. We provide quantifications of NOX emissions with respect to changes in hydrogen content (pure natural gas to 100% hydrogen) swirl number (S=0.6 to S=1.4) excess air ratio ( = 1 to =4.5) and air preheat (ambient air to 300 ◦C). The changes were determined in small steps and over a large range. The emission data is to be used in industrial CFD for both validation and tuning therefore Laser Doppler Velocimetry was used for precise determination of the burner inlet conditions. Key findings of the investigation include that for hydrogen flames the NOX emission index [mg/kWh] is 1.2 to 3 times larger than for pure natural gas flames at similar firing conditions. The steepest increase in NOX emissions occurs above 75% volume fraction of hydrogen in the fuel. For natural gas flames NOX emissions peak at 1.3 to 1.4 excess air while the maximum for hydrogen and natural gas/hydrogen blends lays at =1.6. NOX emissions decrease slightly as the swirl number increases but this effect is minor in comparison to the effects of hydrogen content excess air ratio and air temperature.
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