Production & Supply Chain
Efficiently Coupling Water Electrolysis with Solar PV for Green Hydrogen Production
Aug 2025
Publication
Solar-driven water electrolysis has emerged as a prominent technology for the production of green hydrogen facilitated by advancements in both water electrolyzers and solar cells. Nevertheless the majority of integrated solar-to-hydrogen systems still struggle to exceed 20% efficiency particularly in large-scale applications. This limitation arises from suboptimal coupling methodologies and system-level inefficiencies that have rarely been analyzed. To address these challenges this study investigates the fundamental principles of solar hydrogen production and examines key energy losses in photovoltaic-electrolyzer systems. Subsequently it systematically discusses optimization strategies across three dimensions: (1) enhancing photovoltaic (PV) system output under variable irradiance (2) tailoring electrocatalysts and electrolyzer architectures for high-performance operation and (3) minimizing coupling losses through voltage-matching technologies and energy storage devices. Finally we review existing large-scale solar hydrogen infrastructure and propose strategies to overcome barriers related to cost durability and scalability. By integrating material innovation with system engineering this work offers insights to advance solar-powered electrolysis toward industrial applications.
Feasibility Assessment into the Use of Hybrid Gas-hydride Tanks for Use in Improving the Flexibility of Offshore Hydrogen Production using Wind Power
Oct 2025
Publication
Offshore hydrogen production offers a promising solution for harnessing wind energy far from shore by using hydrogen as an energy carrier instead of electrical cables. Flexibility in hydrogen production systems is crucial to maximising the conversion of intermittent wind energy into hydrogen. To improve the performance of lowpressure compressed gas buffer stores hybrid gas-hydride tanks have been identified as a viable solution increasing useable storage density from 1.2 kg m− 3 to 6.3 kg m− 3 with just a 5 vol% addition of hydride. This study evaluates the reduction in tank volume reduction in cost and enhancements in useable storage density achieved by integrating different hydrides under varying temperature conditions. Using hydrogen mass flow rate profiles a storage mass target was determined for optimisation. The results demonstrate that hybrid gas-hydride tanks can reduce tank size by around 80 % lowering costs by 24 % and achieve a 5.1-fold improvement in useable storage density.
Development of Sustainability Assessment Framework for Preliminary Design of Chemical Process: Hydrogen Production as Case Study
Aug 2025
Publication
Sustainable process design has become increasingly important in transitioning from conventional to sustainable chemical production yet comprehensive sustainability assessment at the preliminary design stage remains a challenge. This study addresses this gap by proposing a hierarchical framework that integrates the Principles Criteria and Indicators (PC&I) method with multi-criteria decision-making (MCDM) tools including entropy weighting TOPSIS and weighted addition. The framework guides the systematic selection of sustainability indicators across economic environmental and social dimensions. To validate its applicability a case study on hydrogen production via four process routes natural gas reforming biomass-derived syngas methanol purge gas recovery and alkaline electrolysis is conducted. Results show that the methanol purge gas process exhibits the best overall sustainability followed by biomass syngas and alkaline electrolysis. The case demonstrates the framework’s capability to differentiate between alternatives under conflicting sustainability dimensions. This work provides a structured and replicable approach to support sustainable decision-making in early-stage chemical process design.
A Comprehensive Review of Green Hydrogen Technology: Electrolysis Methods, Topologies and Control Strategies, Applications
Oct 2025
Publication
As a pivotal clean energy carrier for achieving carbon neutrality green hydrogen technology has attracted growing global attention. This review systematically examines four mainstream water electrolysis technologies—alkaline electrolysis proton exchange membrane electrolysis solid oxide electrolysis and anion exchange membrane electrolysis—analyzing their fundamental principles material challenges and development trends. It further classifies and compares power electronic converter topologies including non-isolated and isolated DC–DC converters as well as AC–DC converter architectures and summarizes advanced control strategies such as dynamic power regulation and fault-tolerant operation aimed at enhancing system efficiency and stability. A holistic “electrolyzer–power converter–control strategy” integration framework is proposed to provide tailored technological solutions for diverse application scenarios. Finally the challenges and future prospects of green hydrogen across the energy transportation and industrial sectors are discussed underscoring its potential to accelerate the global transition toward a sustainable low-carbon energy system.
Experimental Investigation of Hydrogen Production Performance of PEM Electrolyze
Jul 2025
Publication
As global awareness of environmental protection increases hydrogen is seen as a promising solution due to its high energy density and zero-emission combustion. The PEM electrolyze combined with renewable energy power generation is an effective method to solve the problem of hydrogen production. The market competitiveness of PEM electrolyte will be enhanced in the future and the equipment cost can be reduced by 35.8%. The fast dynamic response performance of PEM electrolyzes especially during start-up and shutdown affects system flexibility and stability. The 190 Nm3/h test platform is established to study the fast dynamic response performance considering the cold startup thermal start-up and shutdown behaviors. The results shown that the 190 Nm³/h PEM electrolyze required 6340 s to achieve cold start-up 1100 s to achieve thermal start-up and 855 s to complete shutdown. When operating stably the temperature fluctuation of the PEM remains below 5 °C demonstrating the excellent temperature control performance. However during cold start-up and shutdown the concentrations of hydrogen and oxygen fluctuate significantly which can easily lead to a decrease in system performance. These findings provide guidance for optimizing the design and operating parameters of PEM Electrolyze systems.
Learning in Green Hydrogen Production: Insights from a Novel European Dataset
Jun 2025
Publication
The cost reduction of electrolysers is critical for scaling up green hydrogen production and achieving decarbonization targets. This study presents a novel and comprehensive dataset of electrolyser projects in Europe. It includes full cost and capacity details for each project and capturing project-specific characteristics such as technology type location and project type for the period 2005–2030. We apply the learning curve methodology to assess cost reductions across different electrolyser technologies and project sizes. Our findings indicate a significant learning effect for PEM and AEL electrolysers in the last 20 years with learning rates of 32.1% and 22.9% respectively. While AEL cost reductions are primarily driven by scaling effects PEM electrolysers benefit from both technological advancements and economies of scale. Small-scale electrolysers exhibit a stronger learning effect (25%) whereas large-scale projects show no clear cost reductions due to their early stage of deployment. Projections based on our learning rates suggest that reaching Europe’s 2030 target of 40 GW electrolyser capacity would require an estimated total investment of 14 billion EUR. These results align closely with previous studies and such predictions are closed to estimates from other organization. The dataset is publicly available allowing for further analysis and periodic updates to track cost trends.
Artificial Intelligence-based Multi-objective Optimization of a Solar-driven System for Hydrogen Production with Integrated Oxygen and Power Co-generation Across Different Climates
Oct 2025
Publication
This study develops and optimizes a solar-powered system for hydrogen generation with oxygen and power coproducts addressing the need for efficient scalable carbon-free energy solutions. The system combines a linear parabolic collector a Steam Rankine cycle and a Proton Exchange Membrane Electrolyzer (PEME) to produce electricity for electrolysis. Thermodynamic modeling was accomplished in Engineering Equation Solver while a hybrid Artificial Intelligence (AI) framework combining Artificial Neural Networks and Genetic Algorithms in Statistica coupled with Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) decision support optimized technical and economic performance. Optimization considered seven key decision variables covering collector design thermodynamic inputs and component efficiencies. The optimization achieved energy and exergy efficiencies of 30.83 % and 26.32 % costing 47.02 USD/h and avoiding CO2 emissions equivalent to 190 USD/ton. Economic and exergy analyses showed the solar and hydrogen units had the highest costs (38.17 USD/h and 9.61 USD/h) with 4503 kWh of exergy destruction to generate 575 kWh of electricity. A case study across six cities suggested that Perth Bunbury and Adelaide with higher solar irradiance delivered the highest annual power and hydrogen outputs consistent with irradiance–electrolyzer correlation. Unlike conventional single-site studies this work delivers a climate-responsive multi-city analysis integrating solar thermal and PEME within an AI-driven framework. By linking techno-economic performance with quantified environmental value and co-production synergies of hydrogen oxygen and electricity the study highlights a novel pathway for scalable clean hydrogen measurable CO2 reductions and global decarbonization with future work focused on digital twins and dynamic uncertainty-aware optimization.
Harnessing Wind for Hydrogen: Comparative MCDM-GIS Assessment of Optimal Plant Locations
Jul 2025
Publication
This research aimed to perform an in-depth comparative analysis of MCDM methods utilizing ArcGIS Pro 3.0.2 to identify the most suitable sites for wind-powered hydrogen production plants in Erbil Governorate Iraq. VIKOR TOPSIS SAW and Weighted Overlay techniques were implemented and applied to evaluate various criteria. A comparative analysis determined that VIKOR had the highest consistency and robustness making it the most suitable approach for selecting a site for windpowered hydrogen facilities. Spatial analysis showed that the southern and southwestern regions of Erbil Governorate were the most favourable areas for hydrogen generation. Wind turbine technical feasibility assessments identified the E112/4500 and V126e3.45 turbine models as the most efficient for these regions with high annual hydrogen production. The spatial configuration including the optimal turbine spacing had a significant effect on the capacity and production potential. ArcPro integration with MCDM significantly enhanced spatial analysis providing high-resolution data processing and advanced visualization capabilities.
Case Study of a Greenfield Blue Hydrogen Plant: A Comparative Analysis of Production Methods
Jun 2025
Publication
Blue hydrogen is a key pathway for reducing greenhouse gas emissions while utilizing natural gas with carbon capture and storage (CCS). This study conducts a techno-economic and environmental analysis of a greenfield blue hydrogen plant in Saskatchewan Canada integrating both SMR and ATR technologies. Unlike previous studies that focus mainly on production units this research includes all process and utility systems such as H2 and CO2 compression air separation refrigeration co-generation and gas dehydration. Aspen HYSYS simulations revealed ATR’s energy demand is 10% lower than that of SMR. The hydrogen production cost was USD 3.28/kg for ATR and USD 3.33/kg for SMR while a separate study estimated a USD 2.2/kg cost for design without utilities highlighting the impact of indirect costs. Environmental analysis showed ATR’s lower Global Warming Potential (GWP) compared to SMR reducing its carbon footprint. The results signified the role of utility integration site conditions and process selection in optimizing energy efficiency costs and sustainability.
Hydrogen Generation through Solar Photocatalytic Processes: A Review of the Configuration and the Properties of Effective Metal-Based Semiconductor Nanomaterials
Oct 2017
Publication
Photocatalytic water splitting and organic reforming based on nano-sized composites are gaining increasing interest due to the possibility of generating hydrogen by employing solar energy with low environmental impact. Although great efforts in developing materials ensuring high specific photoactivity have been recently recorded in the literature survey the solar-to-hydrogen energy conversion efficiencies are currently still far from meeting the minimum requirements for real solar applications. This review aims at reporting the most significant results recently collected in the field of hydrogen generation through photocatalytic water splitting and organic reforming with specific focus on metal-based semiconductor nanomaterials (e.g. metal oxides metal (oxy)nitrides and metal (oxy)sulfides) used as photocatalysts under UVA or visible light irradiation. Recent developments for improving the photoefficiency for hydrogen generation of most used metal-based composites are pointed out. The main synthesis and operating variables affecting photocatalytic water splitting and organic reforming over metal-based nanocomposites are critically evaluated.
Modeling Porosity Distribution Strategies in PEM Water Electrolyzers: A Comparative Analytical and Numerical Study
Jun 2025
Publication
Proton exchange membrane water electrolyzers (PEMWEs) are a promising technology for green hydrogen production. However the adoption of PEMWE-based hydrogen production systems remains limited due to several challenges including high material costs limited performance and durability and difficulties in scaling the technology. Computational modeling serves as a powerful tool to address these challenges by optimizing system design improving material performance and reducing overall costs thereby accelerating the commercial rollout of PEMWE technology. Despite this conventional models often oversimplify key components such as porous transport and catalyst layers by assuming constant porosity and neglecting the spatial heterogeneity found in real electrodes. This simplification can significantly impact the accuracy of performance predictions and the overall efficiency of electrolyzers. This study develops a mathematical framework for modeling variable porosity distributions—including constant linearly graded and stepwise profiles—and derives analytical expressions for permeability effective diffusivity and electrical conductivity. These functions are integrated into a three-dimensional multi-domain COMSOL simulation to assess their impact on electrochemical performance and transport behavior. The results reveal that although porosity variations have minimal effect on polarization at low voltages they significantly influence internal pressure species distribution and gas evacuation at higher loads. A notable finding is that reversing stepwise porosity—placing high porosity near the membrane rather than the channel—can alleviate oxygen accumulation and improve current density. A multi-factor comparison highlights this reversed configuration as the most favorable among the tested strategies. The proposed modeling approach effectively connects porous media theory and systemlevel electrochemical analysis offering a flexible platform for the future design of porous electrodes in PEMWE and other energy conversion systems.
Green Hydrogen Generation by Water Photoelectrolysis: Economic and Environmental Analysis
Mar 2025
Publication
Water photoelectrolysis cells based on photoelectrochemical water splitting seem to be an interesting alternative to other traditional green hydrogen generation processes (e.g. water electrolysis). Unfortunately the practical application of this technology is currently hindered by several difficulties: low solar-to-hydrogen (STH) efficiency expensive electrode materials etc. A novel concept based on a tandem photoelectrolysis cell configuration with an anion-conducting membrane separating the photoanode from the photocathode has already been proposed in the literature. This approach allows the use of low-cost metal oxide electrodes and nickel-based co-catalysts. In this paper we conducted a study to evaluate the economic and environmental sustainability of this technology using the environmental life cycle cost. Preliminary results have revealed two main interesting aspects: the negligible percentage of externalities in the total cost.
Assessment of Carbon-abatement Pricing to Maximize the Value of Electrolytic Hydrogen in Emissions-intensive Power Sectors
Aug 2025
Publication
Electrolytic hydrogen can support the decarbonization of the power sector. Achieving cost-effective power-to-gas-to-power (PGP) integration through targeted emissions pricing can accelerate the adoption of electrolytic hydrogen in greenhouse gas-intensive power sectors. This study develops a framework for assessing the economic viability of electrolytic hydrogen-based PGP systems in fossil fuel-dependent grids while considering the competing objectives of the electricity system operator a risk-averse investor and the government. Here we show that given the risk-averse investor’s inherent pursuit of profit maximization a break-even carbon abatement cost of at least 57 Canadian Dollars per tonne of CO₂ by 2030 from the government with a shift in electricity market dispatch rules from sole system marginal pricereduction to system-wide emissions reduction is essential to stimulate price discovery for low-cost hydrogen production and contingency reserve provision by the PGP system. This work can help policymakers capture and incentivize the role of electrolytic hydrogen in low-carbon power sector planning.
Retrofitted Production of Bio-hydrogen. Large-scale Biowaste Valorization via Solar-based Gasification
Aug 2025
Publication
Hydrogen production from gasification of biowaste generates large volumes of CO2 due to endothermic biowaste decomposition. Alternatively the Sun can provide that energy. To evaluate the yield and performance of solarbased gasifiers at country scale a multi-scale approach is required. First the operation of a solar gasifier is analyzed by developing a two-phase model validated and scaled to industrial level. Next the performance and yield of such technology as a function of the radiation received is studied taking Spain as a case study. The results were promising obtaining a syngas rich in H2. However tar and char were not reduced due to insufficient temperature. Scale-up studies revealed energy losses to the environment in the industrial-scale gasifier which suggested the use of segmented heating. In turn diameters no larger than 0.8 m and biomass feeding rates below 0.85 kg/s highlight the deployment of a modular design due to particle size limitations. Finally the large-scale waste valorization showed that the gasifier can only operate in Spain in the summer months. It can run over 180 h/month and more than 250 days/year only in C´ adiz and Santa Cruz de Tenerife which also showed the highest yearly production capacities.
Wetting of the Microporous Layer at the Cathode of an Anion Exchange Membrane Water Electrolyzer
Aug 2025
Publication
Water management is crucial for the performance of anion exchange membrane water electrolyzers (AEM-WEs) to maintain membrane hydration and enable phase separation between hydrogen gas and liquid water. Therefore careful material selection for the anode and cathode is essential to enhance reactant/product transport and optimize water management under ‘dry cathode’ conditions. This study investigates the wetting characteristics of two commercially available porous transport layers (PTLs) used in AEM-WE: carbon paper and carbon paper with a microporous layer (MPL). Wettability was measured under static quasi-static and dynamic conditions to assess the effect of water and electrolytes (NaOH KOH K2CO3) across concentrations (up to 1 M) and operational temperatures (20 °C to 92 °C). Carbon paper exhibits mild hydrophobicity (advancing contact angles of ∼120° however with receding contact angle ∼0°) whereas carbon paper with MPL demonstrates superhydrophobicity (advancing and receding contact angles >145° and low contact angle hysteresis) maintaining a stable Cassie-Baxter wetting state. Dynamic wetting experiments confirmed the robustness of the superhydrophobicity in carbon paper with MPL facilitating phase separation between hydrogen gas and liquid water. The presence of supporting electrolytes did not significantly affect wettability and the materials retained hydrophobic properties across different temperatures. These findings highlight the importance of MPLs in optimizing water transport and gas rejection within AEM-WEs ensuring efficient and stable operation under “dry cathode” conditions. These PTLs (with and without the addition of the MPL) were integrated into AEM-WE and polarization curves were run. Preliminary data in a specific condition suggested the presence of the MPL within the PTL enhance AEM-WE performance.
Stimulating Efficiency for Proton Exchange Membrane Water Splitting Electrolyzers: From Material Design to Electrode Engineering
Jun 2025
Publication
Proton exchange membrane water electrolyzers (PEMWEs) are a promising technology for large-scale hydrogen production yet their industrial deployment is hindered by the harsh acidic conditions and sluggish oxygen evolution reaction (OER) kinetics. This review provides a comprehensive analysis of recent advances in iridium-based electrocatalysts (IBEs) emphasizing novel optimization strategies to enhance both catalytic activity and durability. Specifically we critically examine the mechanistic insights into OER under acidic conditions revealing key degradation pathways of Ir species. We further highlight innovative approaches for IBE design including (i) morphology and support engineering to improve stability (ii) structure and phase modulation to enhance catalytic efficiency and (iii) electronic structure tuning for optimizing interactions with reaction intermediates. Additionally we assess emerging electrode engineering strategies and explore the potential of non-precious metal-based alternatives. Finally we propose future research directions focusing on rational catalyst design mechanistic clarity and scalable fabrication for industrial applications. By integrating these insights this review provides a strategic framework for advancing PEMWE technology through highly efficient and durable OER catalysts.
Can Hydrogen Be Produced Cost-Effectively from Heavy Oil Reservoirs?
Oct 2025
Publication
The potential for hydrogen production from heavy oil reservoirs has gained significant attention as a dual-benefit process for both enhanced oil recovery and low-carbon energy generation. This study investigates the technical and economic feasibility of producing hydrogen from heavy oil reservoirs using two primary in situ combustion gasification strategies: cyclic steam/air and CO2 + O2 injection. Through a comprehensive analysis of technical barriers economic drivers and market conditions we assess the hydrogen production potential of each method. While both strategies show promise they face considerable challenges: the high energy demands associated with steam generation in the steam/air strategy and the complexities of CO2 procurement capture and storage in the CO2 + O2 method. The novelty of this work lies in combining CMG-STARS reservoir simulations with GoldSim techno-economic modeling to quantify hydrogen yields production costs and oil–hydrogen revenue trade-offs under realistic field conditions. The analysis reveals that under current technological and market conditions the cost of hydrogen production significantly exceeds the market price rendering the process economically uncompetitive. Furthermore the dominance of oil production as the primary revenue source in both methods limits the economic viability of hydrogen production. Unless substantial advancements are made in technology or a more cost-efficient production strategy is developed hydrogen production from heavy oil reservoirs is unlikely to become commercially viable in the near term. This study provides crucial insights into the challenges that must be addressed for hydrogen production from heavy oil reservoirs to be considered a competitive energy source.
Hydrogen Production Power Supply with Low Current Ripple Based on Virtual Impedance Technology Suitable for Offshore Wind–Solar–Storage System
Oct 2025
Publication
Hydrogen production from water electrolysis can not only reduce greenhouse gas emissions but also has abundant raw materials which is one of the ideal ways to produce hydrogen from new energy. The hydrogen production power supply is the core component of the new energy electrolytic water hydrogen production device and its characteristics have a significant impact on the efficiency and purity of hydrogen production and the service life of the electrolytic cell. In essence the DC/DC converter provides the large current required for hydrogen production. For the converter its input still needs the support of a DC power supply. Given the maturity and technical characteristics of new energy power generation integrating energy storage into offshore energy systems enables stable power supply. This configuration not only mitigates energy fluctuations from renewable sources but also further reduces electrolysis costs providing a feasible pathway for large-scale commercialization of green hydrogen production. First this paper performs a simulation analysis on the wind–solar hybrid energy storage power generation system to demonstrate that the wind–solar–storage system can provide stable power support. It places particular emphasis on the significance of hydrogen production power supply design—this focus stems primarily from the fact that electrolyzers impose specific requirements on high operating current levels and low current ripple which exert a direct impact on the electrolyzer’s service life hydrogen production efficiency and operational safety. To suppress the current ripple induced by high switching frequency and high output current traditional approaches typically involve increasing the output inductor. However this method substantially increases the volume and weight of the device reduces the rate of current change and ultimately results in a degradation of the system’s dynamic response performance. To this end this paper focuses on developing a virtual impedance control technology aiming to reduce the ripple amplitude while avoiding an increase in the filter inductor. Owing to constraints in current experimental conditions this research temporarily relies on simulation data. Specifically a programmable power supply is employed to simulate the voltage output of the wind–solar–storage hybrid system thereby bringing the simulation as close as possible to the actual operating conditions of the wind–solar–storage hydrogen production system. The experimental results demonstrate that the proposed method can effectively suppress the ripple amplitude maintain high operating efficiency and ultimately meet the expected research objectives. That makes it particularly suitable as a high-quality power supply for offshore hydrogen production systems that have strict requirements on volume and weight.
Advancing Hydrogen Sustainability in Alberta: Life Cycle Sustainability Assessment of Hydrogen Production Pathways
Oct 2025
Publication
This study conducts a Life Cycle Sustainability Assessment (LCSA) of hydrogen production pathways in Alberta Canada evaluating environmental economic and social dimensions. Eight pathways are analyzed: steam methane reforming (SMR) with and without carbon capture and storage (CCS) autothermal reforming (ATR) with and without CCS and with and without grid electricity as well as alkaline electrolysis using grid and wind electricity. While alkaline electrolysis with wind electricity shows the best performance under the climate change and ozone depletion categories ATR + CCS (CO2 capture rate of 91 % no-grid electricity) demonstrates the strongest performance in seven of nine environmental impact categories being the worst performer in none and having the lowest social risks. Economically SMR and ATR without CCS exhibit the lowest levelized cost of hydrogen followed by ATR + CCS (CO2 capture rate of 91 % no-grid electricity). ATR + CCS (CO2 capture rate of 91 % no-grid electricity) emerges as a promising pathway offering an overall balance of sustainability under the current study’s assumptions. The results suggest that a blue hydrogen to electricity scenario where ATR + CCS with 100 % on-site hydrogen-fueled power generation replaces grid electricity may be the most suitable pathway for hydrogen production in Alberta. Key recommendations include optimizing environmental performance in climate change and ozone depletion impacts reducing costs and mitigating social risks in ATR pathways. This LCSA supports policies and investments to advance hydrogen’s role in Alberta’s decarbonization and energy transition.
Highly Selective Production of ‘‘Jadeite Hydrogen” from the Catalytic Decomposition of Diesel
Mar 2025
Publication
Clean hydrogen (H2) is highly desirable for the sustainable development of society in the era of carbon neutrality. However the current capability of water electrolysis and steam methane (CH4) reforming to produce green and blue H2 is very limited mainly due to the high production cost difficult scale-up technology or operational risk. Here we propose the direct catalytic decomposition of diesel using a nano-Fe-based catalyst to produce the so-called ‘‘jadeite H2” while simultaneously fixing the carbon from the diesel in the form of carbon nanotubes (CNTs). Efforts are made to understand the suppression mechanism of the CH4 byproduct such as by tuning the catalyst type space velocity and reaction time. The optimal green index (GI)—that is the molar ratio of H2/carbon in a gaseous state—of the proposed technology exceeds 42 which is far higher than those of any previously reported chemical vapor deposition (CVD) method. Moreover the carbon footprint (CFP) of the proposed technology is far lower than those of grey H2 blue H2 and other dehydrogenation technologies. Compared with most of the technologies mentioned above the energy consumption (per mole of H2) and reactor amplification of the proposed technology validate its high efficiency and great practical feasibility.
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