Transmission, Distribution & Storage
Overview of Hydrogen Storage and Transportation Technology in China
Jul 2023
Publication
In response to the global climate change and the need for green and low-carbon development hydrogen energy has been recognized as a clean energy source that can achieve carbon neutrality unlike fossil fuels. As a country with a shortage of energy resources the development of hydrogen energy is of significant importance for China to adjust its energy structure and accelerate the new era of energy transformation. Based on the development of China’s hydrogen energy industry this paper elaborates on the current status and development trends of key technologies in the entire industrial chain of hydrogen energy in various stages including production storage transportation and application and identifies the problems and challenges of hydrogen energy development. The paper focuses on the analysis of hydrogen storage and transportation application scenarios and clarifies the selection of hydrogen storage and transportation technologies in different scenarios. To achieve healthy devel opment of China’s hydrogen energy industry it is necessary to strengthen top-level design make strategic planning encourage large-scale state-owned energy enterprises to play a leading role promote the development of the entire industry chain increase technological research and development efforts prevent the risk of core technology constraints and vigorously promote the application of hydrogen energy to realize the construction of a hydrogen energy society.
Hydrogen Storage Minimisation under Industrial Flexibility Constraints: A Techno-economic Analysis of Off-grid Green Ammonia Production
Feb 2025
Publication
Electrifying ammonia production using renewable energy (RE) and water electrolysis is a critical step in the worldwide transition from fossil fuels to alternative energy sources. However the common requirement that the ammonia reactor operate at a steady production level harms the system’s economic feasibility due to the large hydrogen and battery storage required to overcome RE variability. In this study we examine the sensitivity of the plant storage capacity requirement to the flexibility of the ammonia reactor. We examine two aspects of ammonia reactor flexibility: ramping rate flexibility and the range of operation (turndown flexibility). We develop a storage dispatch and ammonia reactor scheduling optimization which computes the minimum storage requirement given a RE generation profile and set of reactor flexibility parameters. We optimize across a sweep of flexibility parameters for two locations in the United States. We find that turndown flexibility is the most important while ramping flexibility has little effect on the overall storage requirement. Further we see that seasonal variability in the RE generation profile is the primary driver of high storage capacity requirement. We find that with a turndown flexibility of 60% of the ammonia plants rated capacity which is understood to be achievable with existing ammonia reactor technology the storage capacity was reduced by 84 % in one of the locations we examined which resulted in a 22% decrease in the levelized cost of ammonia with pipe-based hydrogen storage.
Integrated Battery and Hydrogen Energy Storage for Enhanced Grid Power Savings and Green Hydrogen Utilization
Aug 2024
Publication
This study explores the integration and optimization of battery energy storage systems (BESSs) and hydrogen energy storage systems (HESSs) within an energy management system (EMS) using Kangwon National University’s Samcheok campus as a case study. This research focuses on designing BESSs and HESSs with specific technical specifications such as energy capacities and power ratings and their integration into the EMS. By employing MATLAB-based simulations this study analyzes energy dynamics grid interactions and load management strategies under various operational scenarios. Real-time data from the campus are utilized to examine energy consumption renewable energy generation grid power fluctuations and pricing dynamics providing key insights for system optimization. This study finds that a BESS manages energy fluctuations between 0.5 kWh and 3.7 kWh over a 24 h period with battery power remaining close to 4 W for extended periods. Grid power fluctuates between −5 kW and 75 kW while grid prices range from 75 to 120 USD/kWh peaking at 111 USD/kWh. Hydrogen energy storage varies from 1 kWh to 8 kWh with hydrogen power ranging from −40 kW to 40 kW. Load management keeps power stable at around 35 kW and PV power integration peaks at 48 kW by the 10th h. The findings highlight that BESSs and HESSs effectively manage energy distribution and storage improving system efficiency reducing energy costs by approximately 15% and enhancing grid stability by 20%. This study underscores the potential of BESSs and HESSs in stabilizing grid operations and integrating renewable energy. Future directions include advancements in storage technologies enhanced EMS capabilities through artificial intelligence and machine learning and the development of smart grid infrastructures. Policy recommendations stress the importance of regulatory support and stakeholder collaboration to drive innovation and scale deployment ensuring a sustainable energy future.
Hydrogen in Natural Gas Grids: Prospects and Recommendations About Gas Flow Meters
Aug 2024
Publication
To inject green hydrogen (H2) into the existing natural gas (NG) infrastructure is one way to decarbonize the European energy system. However asset readiness is necessary to be successful. Preliminary analysis and experimental results about the compatibility of hydrogen and natural gas mixtures (H2NG) with the actual gas grids make the scientific community confident about the feasibility. Nevertheless specific technical questions need more research. A significant topic of debate is the impact of H2NG mixtures on the performance of state-ofthe-art fiscal measuring devices which are essential for accurate billing. Identifying and addressing any potential degradation in their metrological performance due to H2NG is critical for decision-making. However the literature lacks data about the gas meters’ technologies currently installed in the NG grids such as a comprehensive overview of their readiness at different concentrations while data are fragmented among different sources. This paper addresses these gaps by analyzing the main characteristics and categorizing more than 20000 gas meters installed in THOTH2 project partners’ grids and by summarizing the performance of traditional technologies with H2NG mixtures and pure H2 based on literature review operators experience and manufacturers knowledge. Based on these insights recommendations are given to stakeholders on overcoming the identified barriers to facilitate a smooth transition.
CFD Simulations of Hydrogen Tank Fuelling: Sensitivity to Turbulence Model and Grid Resolution
Dec 2023
Publication
CFD modelling of compressed hydrogen fuelling provides information on the hydrogen and tank structure temperature dynamics required for onboard storage tank design and fuelling protocol development. This study compares five turbulence models to develop a strategy for costeffective CFD simulations of hydrogen fuelling while maintaining a simulation accuracy acceptable for engineering analysis: RANS models k-ε and RSM; hybrid models SAS and DES; and LES model. Simulations were validated against the fuelling experiment of a Type IV 29 L tank available in the literature. For RANS with wall functions and blended models with near-wall treatment the simulated average hydrogen temperatures deviated from the experiment by 1–3% with CFL ≈ 1–3 and dimensionless wall distance y + ≈ 50–500 in the tank. To provide a similar simulation accuracy the LES modelling approach with near-wall treatment requires mesh with wall distance y + ≈ 2–10 and demonstrates the best-resolved flow field with larger velocity and temperature gradients. LES simulation on this mesh however implies a ca. 60 times longer CPU time compared to the RANS modelling approach and 9 times longer compared to the hybrid models due to the time step limit enforced by the CFL ≈ 1.0 criteria. In all cases the simulated pressure histories and inlet mass flow rates have a difference within 1% while the average heat fluxes and maximum hydrogen temperature show a difference within 10%. Compared to LES the k-ε model tends to underestimate and DES tends to overestimate the temperature gradient inside the tank. The results of RSM and SAS are close to those of LES albeit of 8–9 times faster simulations.
The Potential of Polymers and Glass to Enhance Hydrogen Storage Capicity: A Mathematical Approach
Dec 2024
Publication
This manuscript contributes to understanding the role of hydrogen in different materials emphasizing polymers and composite materials to increase hydrogen storage capacity in those materials. Hydrogen storage is critical in advancing and optimizing sustainable energy solutions that are essential for improving their performance. Capillary arrays which offer increased surface area and optimized storage geometries present a promising avenue for enhancing hydrogen uptake. This work evaluates various polymers and glass for their mechanical properties and strength with 700 bar inner pressure loads within capillary tubes. A theoretical mathematical approach was employed to quantify the impact of material properties on storage capacity. Our results demonstrate that certain polymers (e.g. Zylon AS Dyneema SK99) and glass types (S-2 Glass) exhibit superior hydrogen storage potential due to their enhanced strength and low density. These findings suggest that integrating the proposed materials into capillary array systems can significantly improve hydrogen storage efficiency (15–37 wt.% and 37–40 g/L) making them viable candidates for next-generation energy storage systems. This study provides valuable insights into material selection and structural design strategies for high-capacity hydrogen storage technologies.
Optimum Geological Storage Depths for Structural H2 Geo-storage
Sep 2021
Publication
H2 geo-storage has been suggested as a key technology with which large quantities of H2 can be stored and withdrawn again rapidly. One option which is currently explored is H2 storage in sedimentary geologic for mations which are geographically widespread and potentially provide large storage space. The mechanism which keeps the buoyant H2 in the subsurface is structural trapping where a caprock prevents the H2 from rising by capillary forces. It is therefore important to assess how much H2 can be stored via structural trapping under given geo-thermal conditions. This structural trapping capacity is thus assessed here and it is demonstrated that an optimum storage depth for H2 exists at a depth of 1100 m at which a maximum amount of H2 can be stored. This work therefore aids in the industrial-scale implementation of a hydrogen economy.
A Review of Type V Composite Pressure Vessels and Automated Fibre Placement Based Manufacturing
Feb 2023
Publication
Hydrogen is emerging as a promising future energy medium in a wide range of industries. For mobile applica tions it is commonly stored in a gaseous state within high-pressure composite overwrapped pressure vessels (COPVs). The current state of the art pressure vessel technology known as Type V eliminates the internal polymer gas barrier used in Type IV vessels and instead relies on carbon fibre laminate to provide structural properties and prevent gas leakage. Achieving this functionality at high pressure poses several engineering challenges that have thus far prohibited commercial application. Additionally the traditional manufacturing process for COPVs filament winding has several constraints that limit the design space. Automated fibre placement (AFP) a highly flexible robotic composites manufacturing technique has the potential to replace filament winding for composite pressure vessel manufacturing and provide pathways for further vessel optimi sation. A combination of both AFP and Type V technology could provide an avenue for a new generation of highperformance composite pressure vessels. This critical review presents key work on industry-standard Type IV vessels alongside the current state of Type V CPV technology including manufacturing developments challenges cost relevance to commercial standards and future fabrication solutions using AFP. Additionally a novel Type V CPV design concept for a two-piece AFP produced vessel is presented.
Is Renewable Energy Storage Sustainable? A Review
Jan 2025
Publication
Transformation of energy supply systems into green intensifies the use of renewable energy sources. Renewables cannot continuously supply energy. Therefore energy storage systems are very important in the whole system of generation and distribution. Anyway energy storage systems have many issues in terms of sustainability. This paper classified energy storage and analyzed issues in their sustainability solutions. In addition it determines the key performance indicators that define the sustainability of energy storage systems. This analysis determined many sustainability problems presented by the information for each key performance indicator. The least negative impact is shown for the performance of mechanical energy storage and sensible/latent heat storage. The production of green hydrogen green ammonia and biogas showed some negative impact. The worst sustainability is related to energy storage technologies or electrochemical energy storage technologies.
Study of Thermal Behavior on Multi-tank Cascade System for Ship-borne Hydrogen Storage Tank Using a New Design Configuration
Feb 2025
Publication
Hydrogen tanks (HT) with different connection modes are an integral part of the shipborne hydrogen fuel cell system. To ensure the safe and reliable operation of the shipborne multi-tank cascade system this study innovatively develops 3D models of four different connection modes for the shipborne multi-tank cascade system namely Type-22 Type-211 Type-121 and Type-112. Through computational fluid dynamics (CFD) numerical simulation the variations in parameters of different multi-tank cascade systems during the hydrogen storage process are analyzed. The results indicate that the maximum temperature of Type-112 is 271.107K which is 2.220% 4.779% and 3.993% lower than that of Type-22 Type-211 and Type-121 respectively and thus the optimal parameters such as the initial temperature in the tank and pre-cooling temperature are derived. Type-112's maximum temperature is reduced by 14.02% and 16.66% compared to systems connected solely in series or in parallel. The study identifies the optimal structure and reasonable hydrogen storage parameters effectively reducing heat generation during the refueling process while optimizing space utilization thereby strongly ensuring the stability of hydrogen storage and opening up new avenues for addressing related hydrogen storage issues in the future.
Hydrogen Storage Technology, and Its Challenges: A Review
Mar 2025
Publication
This paper aims to present an overview of the current state of hydrogen storage methods and materials assess the potential benefits and challenges of various storage techniques and outline future research directions towards achieving effective economical safe and scalable storage solutions. Hydrogen is recognized as a clean secure and costeffective green energy carrier with zero emissions at the point of use offering significant contributions to reaching carbon neutrality goals by 2050. Hydrogen as an energy vector bridges the gap between fossil fuels which produce greenhouse gas emissions global climate change and negatively impact health and renewable energy sources which are often intermittent and lack sustainability. However widespread acceptance of hydrogen as a fuel source is hindered by storage challenges. Crucially the development of compact lightweight safe and cost-effective storage solutions is vital for realizing a hydrogen economy. Various storage methods including compressed gas liquefied hydrogen cryocompressed storage underground storage and solid-state storage (material-based) each present unique advantages and challenges. Literature suggests that compressed hydrogen storage holds promise for mobile applications. However further optimization is desired to resolve concerns such as low volumetric density safety worries and cost. Cryo-compressed hydrogen storage also is seen as optimal for storing hydrogen onboard and offers notable benefits for storage due to its combination of benefits from compressed gas and liquefied hydrogen storage by tackling issues related to slow refueling boil-off and high energy consumption. Material-based storage methods offer advantages in terms of energy densities safety and weight reduction but challenges remain in achieving optimal stability and capacities. Both physical and material-based storage approaches are being researched in parallel to meet diverse hydrogen application needs. Currently no single storage method is universally efficient robust and economical for every sector especially for transportation to use hydrogen as a fuel with each method having its own advantages and limitations. Moreover future research should focus on developing novel materials and engineering approaches in order to overcome existing limitations provide higher energy density than compressed hydrogen and cryo-compressed hydrogen storage at 70 MPa enhance costeffectiveness and accelerate the deployment of hydrogen as a clean energy vector.
Modeling the Impact of Hydrogen Embrittlement on the Fracture Toughness of Low-Carbon Steel Using a Machine Learning Approach
May 2025
Publication
This study aims to advance the understanding of hydrogen embrittlement (HE) in low-carbon and low-alloy steels by developing a predictive framework for assessing fracture toughness (FT) a critical parameter for mitigating HE in hydrogen infrastructure. A machine learning (ML) model was constructed by analyzing data from relevant literature to evaluate the fracture toughness of steels exposed to hydrogen environments. Seven ML modeling techniques were initially considered with four selected for detailed evaluation based on predictive accuracy. The chosen modeling techniques were k-nearest neighbors (KNN) random forest (RF) gradient boosting (GB) and decision tree regression (DT). The selected models were further evaluated for their predictive accuracy and reliability and the best model was used to perform parametric studies to investigate the impact of relevant parameters on FT. According to the results the KNN model demonstrated reliable predictive performance supported by high R-squared values and low error metrics. Among the variables considered hydrogen pressure and yield strength emerged as the most influential with hydrogen pressure alone accounting for 32% of the variation in FT. The model revealed a distinct trend in FT behavior showing a significant decline at low hydrogen pressures (0–6.9 MPa) and a plateau at higher pressures (>8 MPa) indicating a saturation point. Alloying element contents specifically those of carbon and phosphorus also played a notable role in FT prediction. Additionally the study confirmed that low concentrations of oxygen (
Technical Feasibility Analysis of Green Energy Storage Options and Hornsea Wind Farms
Apr 2025
Publication
The global transition towards clean energy sources is becoming essential to reduce reliance on conventional fuels and mitigate carbon emissions. In the future the clean energy storage landscape green hydrogen and green ammonia (powered by renewable energy sources) are emerging as key players. This study explores the prospectives and feasibility of producing and storing offshore green hydrogen and green ammonia. The potential power output of Hornsea one and Hornsea two winds farms in the United Kingdom was calculated using real wind data. The usable electricity from the Hornsea one wind farm was 5.83 TWh/year and from the Hornsea two wind farm it was 6.44 TWh/year harnessed to three different scenarios for the production and storage of green ammonia and green hydrogen. Scenario 1 fulfil the requirement of green hydrogen storage for flexible ammonia production but consumes more energy for green hydrogen compression. Scenario 2 does not offer any hydrogen storage which is not favourable in terms of flexibility and market demand. Scenario 3 offers both a direct routed supply of produced hydrogen for green ammonia synthesis and a storage facility for green hydrogen storage. Detailed mathematical calculations and sensitivity analysis was performed based on the total energy available to find out the energy storage capacity in terms of the mass of green hydrogen and green ammonia produced. Sensitivity analysis in the case of scenario 3 was conducted to determine the optimal percentage of green hydrogen going to the storage facility. Based on the cost evaluation of three different presented scenarios the levelized cost of hydrogen (LCOH) is between USD 5.30 and 5.97/kg and the levelized cost of ammonia (LCOA) is between USD 984.16 and USD 1197.11/tonne. These prices are lower compared to the current UK market. The study finds scenario 3 as the most appropriate way in terms of compression energy savings flexibility for the production and storage capacity that depends upon the supply and demand of these green fuels in the market and a feasible amount of green hydrogen storage.
The Role of Long-term Hydrogen Storage in Decarbonizing Remote Communities in Canada: An Optimization Framework with Economic, Environmental and Social Objectives
Nov 2024
Publication
Many small Canadian communities lack access to electricity grids relying instead on costly and polluting diesel generators despite the local availability of renewable energies like solar and wind. The intermittent nature of these sources limits reliable power supply; thus hydrogen is proposed as a cost-effective and ecofriendly long-term energy storage solution. However it remains uncertain whether hydrogen storage can significantly contribute to a 100% renewable energy system (100RES) given the diverse characteristics of these communities. Additionally the potential for fully renewable infrastructure to reduce costs mitigate adverse environmental impacts and enhance social impact is still unclear. A multi-period optimization model that balances economic environmental and social objectives to determine the optimal configuration of 100RESs for isolated communities is introduced and utilized to evaluate hydrogen as an energy storage solution to seasonal fluctuations. By identifying the best combinations of technologies tailored to local conditions and priorities this study offers valuable insights for policymakers supporting the transition to sustainable energy and achieving national climate goals. The results demonstrate that hydrogen could serve as an excellent longterm energy storage option to address energy shortages during the winter. Different combinations and sizes of energy generation and storage technologies are selected based on the characteristics of each community. For instance a community in the northern territories with high wind speeds low solar radiation extremely low temperatures and limited biomass resources should optimally rely on wind turbines to meet 80.7% of its total energy demand resulting in a 62.0% cost reduction and a 49.5% decrease in environmental impact compared to the existing diesel-based system. By 2050 all communities are projected to reduce energy costs per capita with northern territories achieving 33% and coastal areas achieving 55% cost reductions eventually leading to the utilization of hydrogen as the main energy storage medium.
Biogeochemical Interactions and Their Role in European Underground Hydrogen Storage
Sep 2025
Publication
Integrating renewable energy requires robust large-scale storage solutions to balance intermittent supply. Underground hydrogen storage (UHS) in geological formations such as salt caverns depleted hydrocarbon reservoirs or aquifers offers a promising way to store large volumes of energy for seasonal periods. This review focuses on the biological aspects of UHS examining the biogeochemical interactions between H2 reservoir minerals and key hydrogenotrophic microorganisms such as sulfate-reducing bacteria methanogens acetogens and iron-reducing bacteria within the gas–liquid–rock–microorganism system. These microbial groups use H2 as an electron donor triggering biogeochemical reactions that can affect storage efficiency through gas loss and mineral dissolution–precipitation cycles. This review discusses their metabolic pathways and the geochemical interactions driven by microbial byproducts such as H2S CH4 acetate and Fe2+ and considers biofilm formation by microbial consortia which can further change the petrophysical reservoir properties. In addition the review maps 76 ongoing European projects focused on UHS showing 71% target salt caverns 22% depleted hydrocarbon reservoirs and 7% aquifers with emphasis on potential biogeochemical interactions. It also identifies key knowledge gaps including the lack of in situ kinetic data limited field-scale monitoring of microbial activity and insufficient understanding of mineral–microbe interactions that may affect gas purity. Finally the review highlights the need to study microbial adaptation over time and the influence of mineralogy on tolerance thresholds. By analyzing these processes across different geological settings and integrating findings from European research initiatives this work evaluates the impact of microbial and geochemical factors on the safety efficiency and long-term performance of UHS.
Laboratory Evaluation of Cyclic Underground Hydrogen Storage in the Temblor Sandstone of the San Joaquin Basin, California
Jun 2025
Publication
Underground Hydrogen Storage (UHS) in depleted oil and gas reservoirs could provide a cost-effective solution to balance seasonal fluctuations in renewable energy generation. However data and knowledge on UHS at subsurface conditions are limited so it is difficult to estimate how effective this type of storage could be. In this study we perform high pressure experiment to measure the effectiveness of cyclic hydrogen (H2) storage in a specimen of Temblor sandstone retrieved from the San Joaquin Basin of California. Our experiment mimics reservoir pressure conditions to measure H2-brine relative permeability and fluid-rock interactions over the course of ten charging and discharging cycles. Initial gas breakthrough occurred at 15 % to 25 % H2 saturation in the specimen with 3 % NaCl brine as the resident fluid. Continuing injecting to 4 pore volumes (PV) of H2 yielded an asymptotic H2 saturation of 38 % to 41 % a level often referred to as the irreducible gas saturation based on two-phase flow. The boundary condition in this study mimics the near wellbore region which experiences bidirectional H2 flow. This bi-directional flow led to evaporative drying of the specimen resulting in 94 % H2 saturation at the end of 10th cycle. This indicates that cyclic flow and evaporative drying can lead to more efficient reservoir storage where a larger fraction of the reservoir porosity is usable to store H2. The produced gas stream consisted of H2 mixed with 8 % to 22 % H2O indicating formation dry-out by evaporation. Meanwhile produced water chemistry indicated calcite and silicate dissolution with calcite sourced from fossil fragments. This led to a loss of cementation and weakened the rock sample. Combined our results indicate dry-out compaction increased H2 saturation rock weakening and permeability loss during cyclic UHS. Overall we anticipate that the combined effects should lead to higher than anticipated UHS storage efficiency per volume of sandstone reservoir rock.
Hydrogen Storage with Gravel and Pipes in Lakes and Reservoirs
Sep 2024
Publication
Climate change is projected to have substantial economic social and environmental impacts worldwide. Currently the leading solutions for hydrogen storage are in salt caverns and depleted natural gas reservoirs. However the required geological formations are limited to certain regions. To increase alternatives for hydrogen storage this paper proposes storing hydrogen in pipes filled with gravel in lakes hydropower and pumped hydro storage reservoirs. Hydrogen is insoluble in water non-toxic and does not threaten aquatic life. Results show the levelized cost of hydrogen storage to be 0.17 USD kg−1 at 200 m depth which is competitive with other large scale hydrogen storage options. Storing hydrogen in lakes hydropower and pumped hydro storage reservoirs increases the alternatives for storing hydrogen and might support the development of a hydrogen economy in the future. The global potential for hydrogen storage in reservoirs and lakes is 3 and 12 PWh respectively. Hydrogen storage in lakes and reservoirs can support the development of a hydrogen economy in the future by providing abundant and cheap hydrogen storage.
Design and Analysis of Hydrogen Storage Tank with Different Materials by Ansys
Dec 2019
Publication
Pressure vessels are used for large commercial and industrial applications such as softening filtration and storage. It is expected that high-pressure hydrogen storage vessels will be widely used in hydrogen-fuelled vehicles. Progressive failure properties the burst pressure and fatigue life should be taken into account in the design of composite pressure vessels. In this work the model and analysis of hydrogen storage vessels along with complete structural and thermal analysis. Liquid hydrogen is seen as an outstanding candidate for the fuel of high altitude long-endurance unmanned aircraft. The design of lightweight and super-insulated storage tanks for cryogenic liquid hydrogen is since long identified as crucial to enable the adoption of the liquid hydrogen. The basic structural design of the airborne cryogenic liquid hydrogen tank was completed in this paper. The problem of excessive heat leakage of the traditional support structure was solved by designing and using a new insulating support structure. The thermal performance of the designed tank was evaluated. The structure of the tank was analyzed by the combination of the film container theory and finite element numerical simulation method. The structure of the adiabatic support was analyzed by using the Hertz contact theory and numerical simulation method. A simple and effective structure analysis method for a similar container structure and point-contact support structure was provided. Bases for further structural optimization design of hydrogen tank will be provided also. The analysis will be carried out with different materials like titanium nickel alloy and some coated powders like alumina Titania and zirconium oxide. The results will be compared with that.
Design, Analysis, and Testing of a Type V Composite Pressure Vessel for Hydrogen Storage
Dec 2024
Publication
Hydrogen as a zero-emission fuel produces only water when used in fuel cells making it a vital contributor to reducing greenhouse gas emissions across industries like transportation energy and manufacturing. Efficient hydrogen storage requires lightweight high-strength vessels capable of withstanding high pressures to ensure the safe and reliable delivery of clean energy for various applications. Type V composite pressure vessels (CPVs) have emerged as a preferred solution due to their superior properties thus this study aims to predict the performance of a Type V CPV by developing its numerical model and calculating numerical burst pressure (NBP). For the validation of the numerical model a Hydraulic Burst Pressure test is conducted to determine the experimental burst pressure (EBP). The comparative study between NBP and EBP shows that the numerical model provides an accurate prediction of the vessel’s performance under pressure including the identification of failure locations. These findings highlight the potential of the numerical model to streamline the development process reduce costs and accelerate the production of CPVs that are manufactured by prepreg hand layup process (PHLP) using carbon fiber/epoxy resin prepreg material.
Gas Storage in Geological Formations: A Comparative Review on Carbon Dioxide and Hydrogen Storage
Feb 2024
Publication
Carbon dioxide and hydrogen storage in geological formations at Gt scale are two promising strategies toward net-zero carbon emissions. To date investigations into underground hydrogen storage (UHS) remain relatively limited in comparison to the more established knowledge body of underground carbon dioxide storage (UCS). Despite their analogous physical processes can be used for accelerating the advancements in UHS technology the existing distinctions possibly may hinder direct applicability. This review therefore contributes to advancing our fundamental understanding on the key differences between UCS and UHS through multi-scale comparisons. These comparisons encompass key factors influencing underground gas storage including storage media trapping mechanisms and respective fluid properties geochemical and biochemical reactions and injection scenarios. They provide guidance for the conversion of our existing knowledge from UCS to UHS emphasizing the necessity of incorporating these factors relevant to their trapping and loss mechanisms. The article also outlines future directions to address the crucial knowledge gaps identified aiming to enhance the utilisation of geological formations for hydrogen and carbon dioxide storage.
Hydrogen Diffusion into Water and Cushion Gases - Relevance for Hydrogen Geo-storage
Dec 2024
Publication
Hydrogen (H2) has been recognized as a promising solution to reduce carbon dioxide (CO2) emissions. H2 is considered a green energy carrier for energy storage transport and usage and it can be produced from renewable energy resources (such as solar hydropower and wind energy). However H2 is a highly diffusive compound compared to other natural gases raising concerns about the possibility of H2 loss in geo-storage (e.g. in underground geological formations such as depleted oil/gas reservoirs aquifers or shale formations) or H2 leak via pipelines when blending H2 with natural gas in existing pipeline systems. Thus understanding H2 diffusion in subsurface formations and pipeline systems is vital. However despite its importance only limited data is available to assess the above situations. Therefore in this study molecular dynamics simulations were used to predict the self-diffusion coefficients of H2 in water and cushion gases (CH4 and N2) at relevant geothermal conditions (i.e. 300 K–373 K and pressures up to 50 MPa). The findings showed that H2 self-diffusion in methane and nitrogen increases with increasing temperature but decreases with increasing pressure. However H2 selfdiffusion in water increases with increasing temperature but is not impacted by increasing or decreasing pres sure. The results also indicated that the rate of H2 self-diffusion in cushion gas is faster than in water about exceeding two-digit times. Furthermore the outcomes reported extended or new data on H2 self-diffusion for the binary system of H2–H2O H2–CH4 and H2–N2. This study is beneficial and contributes to assessing efficiency and safety for executing H2 transportation and underground hydrogen storage (UHS) schemes.
An Efficient Renewable Hybridization Based on Hydrogen Storage for Peak Demand Reduction: A Rule-based Energy Control and Optimisation Using Machine Learning Techniques
Dec 2022
Publication
The present study proposes and thoroughly examines a novel approach for the effective hybridization of solar and wind sources based on hydrogen storage to increase grid stability and lower peak load. The parabolic trough collector vanadium chloride thermochemical cycle hydrogen storage tank alkaline fuel cells thermal energy storage and absorption chiller make up the suggested smart system. Additionally the proposed system includes a wind turbine to power the electrolyzer unit and minimize the size of the solar system. A rule-based control technique establishes an intelligent two-way connection with energy networks to compensate for the energy expenses throughout the year. The transient system simulation (TRNSYS) tool and the engineering equation solver program are used to conduct a comprehensive techno-economic-environmental assessment of a Swedish residential building. A four-objective optimization utilizing MATLAB based on the grey wolf algorithm coupled with an artificial neural network is used to determine the best trade-off between the indicators. According to the results the primary energy saving carbon dioxide reduction rate overall cost and purchased energy are 80.6 % 219 % 14.8 $/h and 24.9 MWh at optimal conditions. From the scatter distribution it can be concluded that fuel cell voltage and collector length should be maintained at their lowest domain and the electrode area is an ineffective parameter. The suggested renewable-driven smart system can provide for the building’s needs for 70 % of the year and sell excess production to the local energy network making it a feasible alternative. Solar energy is far less effective in storing hydrogen over the winter than wind energy demonstrating the benefits of combining renewable energy sources to fulfill demand. By lowering CO2 emissions by 61758 kg it is predicted that the recommended smart renewable system might save 7719 $ in environmental costs equivalent to 6.9 ha of new reforestation.
Underground Hydrogen Storage in Sandstone Reservoirs: Effects of Geochemical Reactivity of Hydrogen on Reservoir Performance
Jan 2025
Publication
Underground hydrogen storage in porous rocks is a promising method to stabilize renewable energy fluctuations. However data on the geochemical reactivity of hydrogen with reservoir rocks and its potential effects on reservoir performance are limited. This study investigates the geochemical reactivity of hydrogen with Bunt sandstein reservoir sandstones from northern Germany collected at a depth of about 2.5 km. Experiments were performed at 100 ◦C and 150 bar hydrogen partial pressure for four weeks examining scenarios with dry hydrogen synthetic saline fluid with hydrogen synthetic saline fluid with helium (as a control) and an oxidation environment (air). We measured permeability porosity magnetic susceptibility and fluid element concentration before and after the experiments. Results showed no significant mineral changes attributed to hydrogen. Mag netic susceptibility indicated no formation of magnetic minerals such as magnetite and pyrrhotite. Minor var iations in permeability and porosity were attributed to anhydrite dissolution from fluid chemistry nonequilibrium. Overall our findings suggest hydrogen interactions with Buntsandstein sandstone (no pyrite content) at temperatures up to 100 ◦C do not risk hydrogen loss or reservoir performance degradation.
Evaluating the Hydrogen Storage Potential of Shut Down Oil and Gas Fields Along the Norwegian Continental Shelf
Apr 2023
Publication
The underground hydrogen storage (UHS) capacities of shut down oil and gas (O&G) fields along the Norwegian continental shelf (NCS) are evaluated based on the publicly available geological and hydrocarbon production data. Thermodynamic equilibrium and geochemical models are used to describe contamination of hydrogen loss of hydrogen and changes in the mineralogy. The contamination spectrum of black oil fields and retrograde gas fields are remarkably similar. Geochemical models suggest limited reactive mineral phases and meter-scale hydrogen diffusion into the caprock. However geochemical reactions between residual oil reservoir brine host rock and hydrogen are not yet studied in detail. For 23 shut down O&G fields a theoretical maximum UHS capacity of ca. 642 TWh is estimated. We conclude with Frigg Nordost Frigg and Odin as the best-suited shut down fields for UHS having a maximum UHS capacity of ca. 414 TWh. The estimates require verification by site-specific dynamic reservoir models.
Wind–Photovoltaic–Electrolyzer-Underground Hydrogen Storage System for Cost-Effective Seasonal Energy Storage
Nov 2024
Publication
Photovoltaic (PV) and wind energy generation result in low greenhouse gas footprints and can supply electricity to the grid or generate hydrogen for various applications including seasonal energy storage. Designing integrated wind–PV–electrolyzer underground hydrogen storage (UHS) projects is complex due to the interactions between components. Additionally the capacities of PV and wind relative to the electrolyzer capacity and fluctuating electricity prices must be considered in the project design. To address these challenges process modelling was applied using cost components and parameters from a project in Austria. The hydrogen storage part was derived from an Austrian hydrocarbon gas field considered for UHS. The results highlight the impact of the renewable energy source (RES) sizing relative to the electrolyzer capacity the influence of different wind-to-PV ratios and the benefits of selling electricity and hydrogen. For the case study the levelized cost of hydrogen (LCOH) is EUR 6.26/kg for a RES-to-electrolyzer capacity ratio of 0.88. Oversizing reduces the LCOH to 2.61 €/kg when including electricity sales revenues or EUR 4.40/kg when excluding them. Introducing annually fluctuating electricity prices linked to RES generation results in an optimal RES-to-electrolyzer capacity ratio. The RES-to-electrolyzer capacity can be dynamically adjusted in response to market developments. UHS provides seasonal energy storage in areas with mismatches between RES production and consumption. The main cost components are compression gas conditioning wells and cushion gas. For the Austrian project the levelized cost of underground hydrogen storage (LCHS) is 0.80 €/kg with facilities contributing EUR 0.33/kg wells EUR 0.09/kg cushion gas EUR 0.23/kg and OPEX EUR 0.16/kg. Overall the analysis demonstrates the feasibility of integrated RES–hydrogen generation-seasonal energy storage projects in regions like Austria with systems that can be dynamically adjusted to market conditions.
The Impact of Impurity Gases on the Hydrogen Embrittlement Behavior of Pipeline Steel in High-Pressure H2 Environments
May 2024
Publication
The use of hydrogen-blended natural gas presents an efficacious pathway toward the rapid large-scale implementation of hydrogen energy with pipeline transportation being the principal method of conveyance. However pipeline materials are susceptible to hydrogen embrittlement in high-pressure hydrogen environments. Natural gas contains various impurity gases that can either exacerbate or mitigate sensitivity to hydrogen embrittlement. In this study we analyzed the mechanisms through which multiple impurity gases could affect the hydrogen embrittlement behavior of pipeline steel. We examined the effects of O2 and CO2 on the hydrogen embrittlement behavior of L360 pipeline steel through a series of fatigue crack growth tests conducted in various environments. We analyzed the fracture surfaces and assessed the fracture mechanisms involved. We discovered that CO2 promoted the hydrogen embrittlement of the material whereas O2 inhibited it. O2 mitigated the enhancing effect of CO2 when both gases were mixed with hydrogen. As the fatigue crack growth rate increased the influence of impurity gases on the hydrogen embrittlement of the material diminished.
A Thermodynamic Model for Cryogenic Liquid Hydrogen Fuel Tanks
Apr 2024
Publication
Hydrogen is used as a fuel in various fields such as aviation space and automobiles due to its high specific energy. Hydrogen can be stored as a compressed gas at high pressure and as a liquid at cryogenic temperatures. In order to keep liquid hydrogen at a cryogenic temperature the tanks for storing liquid hydrogen are required to have insulation to prevent heat leakage. When liquid hydrogen is vaporized by heat inflow a large pressure is generated inside the tank. Therefore a technology capable of predicting the tank pressure is required for cryogenic liquid hydrogen tanks. In this study a thermodynamic model was developed to predict the maximum internal pressure and pressure behavior of cryogenic liquid hydrogen fuel tanks. The developed model considers the heat inflow of the tank due to heat transfer the phase change from liquid to gas hydrogen and the fuel consumption rate. To verify the accuracy of the proposed model it was compared with the analyses and experimental results in the referenced literature and the model presented good results. A cryogenic liquid hydrogen fuel tank was simulated using the proposed model and it was confirmed that the storage time along with conditions such as the fuel filling ratio of liquid hydrogen and the fuel consumption rate should be considered when designing the fuel tanks. Finally it was confirmed that the proposed thermodynamic model can be used to sufficiently predict the internal pressure and the pressure behavior of cryogenic liquid hydrogen fuel tanks.
Solubility of Water in Hydrogen at High Pressures: A Molecular Simulation Study
Aug 2019
Publication
Hydrogen is one of the most popular alternatives for energy storage. Because of its low volumetric energy density hydrogen should be compressed for practical storage and transportation purposes. Recently electrochemical hydrogen compressors (EHCs) have been developed that are capable of compressing hydrogen up to P = 1000 bar and have the potential of reducing compression costs to 3 kWh/kg. As EHC compressed hydrogen is saturated with water the maximum water content in gaseous hydrogen should meet the fuel requirements issued by the International Organization for Standardization (ISO) when refuelling fuel cell electric vehicles. The ISO 14687−2:2012 standard has limited the water concentration in hydrogen gas to 5 μmol water per mol hydrogen fuel mixture. Knowledge on the vapor liquid equilibrium of H2O−H2 mixtures is crucial for designing a method to remove H2O from compressed H2. To the best of our knowledge the only experimental high pressure data (P > 300 bar) for the H2O−H2 phase coexistence is from 1927 [J. Am. Chem. Soc. 1927 49 65−78]. In this paper we have used molecular simulation and thermodynamic modeling to study the phase coexistence of the H2O−H2 system for temperatures between T = 283 K and T = 423 K and pressures between P = 10 bar and P = 1000 bar. It is shown that the Peng-Robinson equation of state and the Soave Redlich-Kwong equation of state with van der Waals mixing rules fail to accurately predict the equilibrium coexistence compositions of the liquid and gas phase with or without fitted binary interaction parameters. We have shown that the solubility of water in compressed hydrogen is adequately predicted using force-field-based molecular simulations. The modeling of phase coexistence of H2O−H2 mixtures will be improved by using polarizable models for water. In the Supporting Information we present a detailed overview of available experimental vapor−liquid equilibrium and solubility data for the H2O−H2 system at high pressures.
Safe Pipelines for Hydrogen Transport
Jun 2024
Publication
The hydrogen compatibility of two X65 pipeline steels for transport of hydrogen gas is investigated through microstructural characterization hydrogen permeation measurements and fracture mechanical testing. The investigated materials are a quenched and tempered pipeline steel with a fine-grained homogeneously distributed ferrite-bainite microstructure and hot rolled pipeline steel with a ferrite-pearlite banded microstructure. All tests are performed both under electrochemical and gaseous hydrogen charging conditions. A correlation between electrochemical hydrogen charging and gaseous charging is determined. The results point to inherent differences in the interaction between hydrogen and the two material microstructures. Further research is needed to unveil the influence of material microstructure on hydrogen embrittlement.
Lifecycle Management of Hydrogen Pipelines: Design, Maintenance, and Rehabilitation Strategies for Canada’s Clean Energy Transition
Jan 2025
Publication
This paper examines the crucial elements of pipeline-based hydrogen transportation highlighting the particular difficulties and technical developments required to guarantee the sustainable effective and safe supply of hydrogen. This study lists the essential phases of hydrogen pipeline management from design to repair as the relevance of hydrogen infrastructure in the worldwide energy transition continues to rise. It discusses the upkeep monitoring operation and rehabilitation procedures for aged pipelines with an emphasis on the cutting-edge techniques and technology used to mitigate the dangers related to hydrogen’s unique features such as leakage and embrittlement. Together with highlighting the legislative and regulatory frameworks that enable the infrastructure this paper also discusses the material economic and environmental difficulties related to hydrogen pipelines. Lastly it emphasizes how crucial it is to fund research create cutting-edge materials and implement sophisticated monitoring systems to guarantee the long-term dependability and safety of hydrogen pipelines. These initiatives will be crucial in allowing hydrogen’s contribution to the future of renewable energy together with international collaboration on regulatory standards.
Numerical Estimation of the Structural Integrity in an Existing Pipeline Network for the Transportation of Hydrogen Mixture in the Future
Jan 2025
Publication
Hydrogen is gaining attention due to its potential to address key challenges in the sectors of energy transportation and industry since it is a much cleaner energy source when compared to fossil fuels. The transportation of hydrogen from the point of its production to the point of use can be performed by road rail sea pipeline networks or a combination of the abovementioned. Being in the preliminary stage of hydrogen use the utilization of the already existing natural gas pipeline networks for hydrogen mixtures transportation has been suggested as an efficient means of expanding hydrogen infrastructure. Yet exploring this alternative major challenges such as the pre-existence of cracks in the pipelines and the effect of hydrogen embrittlement on the material of the pipelines exist. In this paper the macroscopic numerical modeling of pipeline segments with the use of the finite element method is performed. In more details the structural integrity of intact and damaged pipeline segments of different geometry and mechanical properties was estimated. The effect of the pipeline geometry and material has been investigated in terms of stress contours with and without the influence of hydrogen. The results suggest that the structural integrity of the pipeline segments is more compromised by pre-existing longitudinal cracks which might lead to an increase in the maximum value of equivalent Von Mises stress by up to four times depending on their length-tothickness ratio. This effect becomes more pronounced with the existence of hydrogen in the pipeline network.
Comparative Analysis of Hydrogen vs. Methane Pipeline Transport Systems with Integrated Methane Pyrolysis for Low-carbon Hydrogen Supply
Jan 2025
Publication
Establishing a climate-neutral energy system is among the most urgent challenges facing humanity with the natural gas network forming a critical component of energy and commodity infrastructure. The hydrogen economy based on climate-neutral hydrogen which serves as both energy source and raw-material for numerous sectors offers a promising pathway for significant reduction in CO2 emissions. However the lack of an extensive hydrogen infrastructure underscores the need for transitional solutions. Given this infrastructure gap and the urgency to establish a reliable and less emission-intensive commodity network methane pyrolysis (MP) emerges as a promising technology for supporting the transition to a climate-neutral energy system. Within this context this study evaluates the intricacies of long-distance pipeline transport of hydrogen (H2) and methane (CH4) focusing on the placement of MP units. The primary goal is to provide “turquoise hydrogen” produced from natural gas via MP along with solid carbon from distant locations to industrial consumers. Two configurations are assessed: Configuration I represents a centralized supply concept transporting molecular hydrogen while Configuration II delivers methane to consumers for on-site hydrogen production. The reference system covers a transport distance of 500 km extending to 4000 km with recompression stations every 125 km. The transport capacity of the hydrogen pipeline is set at 13 GW with the methane mass flow set to match the equivalent hydrogen output chemically bound in methane. A parameter study examines power requirements and global warming impact (GWI) over various transport distances. For distances between 2000 and 4000 km Configuration II requires less power (Δ = 229.4–443.0 MW) and results in GWI savings of 0.25 to 0.37 kgCO2-eq.kgH2−1 owing primarily to the lower specific energy consumption for methane transport compared to hydrogen. The study concludes that the electricity mix of the exporting and importing regions significantly affects the GWI of hydrogen supply with the MP unit contributing a substantial part (6.92 kgCO2-eq.kgH2−1) to the total GWI. The approach of Configuration I is favorable for regions with a low-GWI electricity supply while Configuration II is better suited for regions where the electricity mixes of both the exporting and importing regions are similar.
Review on Onshore and Offshore Large-scale Seasonal Hydrogen Storage for Electricity Generation: Focusing on Improving Compression, Storage, and Roundtrip Efficiency
Jun 2024
Publication
This article presents a comprehensive review of the current landscape and prospects of large-scale hydrogen storage technologies with a focus on both onshore and offshore applications and flexibility. Highlighting the evolving technological advancements it explores storage and compression techniques identifying potential research directions and avenues for innovation. Underwater hydrogen storage and hybrid metal hydride com pressed gas tanks have been identified for offshore buffer storage as well as exploration of using metal hydride slurries to transport hydrogen to/from offshore wind farms coupled with low pressure high flexibility elec trolyser banks. Additionally it explores the role of metal hydride hydrogen compressors and the integration of oxyfuel processes to enhance roundtrip efficiency. With insights into cost-effectiveness environmental and technology considerations and geographical factors this review offers insights for policymakers researchers and industry stakeholders aiming to advance the deployment of large-scale hydrogen storage systems in the transition towards sustainable energy.
Sustainable Hydrogen Generation and Storage - A Review
Aug 2023
Publication
In 21st century the energy demand has grown incredibly due to globalization human population explosion and growing megacities. This energy demand is being mostly fulfilled by fossil-based sources which are non-renewable and a major cause of global warming. Energy from these fossil-based sources is cheaper however challenges exist in terms of climate change. This makes renewable energy sources more promising and viable for the future. Hydrogen is a promising renewable energy carrier for fulfilling the increasing energy demand due to its high energy density non-toxic and environment friendly characteristics. It is a non-toxic energy carrier as combustion of hydrogen produces water as the byproduct whereas other conventional fuels produce harmful gases and carcinogens. Because of its lighter weight hydrogen leaks are also easily dispersed in the atmosphere. Hydrogen is one of the most abundant elements on Earth yet it is not readily available in nature like other fossil fuels. Hence it is a secondary energy source and hydrogen needs to be produced from water or biomass-based feedstock for it to be considered renewable and sustainable. This paper reviews the renewable hydrogen generation pathways such as water splitting thermochemical conversion of biomass and biological conversion technologies. Purification and storage technologies of hydrogen is also discussed. The paper also discusses the hydrogen economy and future prospects from an Indian context. Hydrogen purification is necessary because of high purity requirements in particular applications like space fuel cells etc. Various applications of hydrogen are also addressed and a cost comparison of various hydrogen generation technologies is also analyzed. In conclusion this study can assist researchers in getting a better grasp of various renewable hydrogen generation pathways it's purification and storage technologies along with applications of hydrogen in understanding the hydrogen economy and its future prospect.
Evaluation and Outlook for Australian Renewable Energy Export via Circular Liquid Hydrogen Carriers
Oct 2023
Publication
To combat global temperature rise we need affordable clean and renewable energy that does not add carbon to the atmosphere. Hydrogen is a promising option because it can be used as a carbon-free energy source. However storing and transporting pure hydrogen in liquid or gaseous forms is challenging. To overcome the limitations associated with conventional compressed and liquefied hydrogen or physio-chemical adsorbents for bulk storage and transport hydrogen can be attached to other molecules known as hydrogen carriers. Circular carriers which involve the production of CO2 or nitrogen during the hydrogen recovery process include substances such as methanol ammonia or synthetic natural gas. These carriers possess higher gravimetric and volumetric hydrogen densities (i.e. 12.5 wt% and 11.88 MJ/L for methanol) than cyclic carriers (i.e. 6.1 wt% and 5.66 MJ/L for methylcyclohexane (MCH)) which produce cyclic organic chemicals during dehydrogenation. This makes circular carriers particularly appealing for the Australian energy export market. Furthermore the production-decomposition cycle of circular carriers can be made carbon-neutral if they are derived from renewable H2 sources and combined with atmospheric or biomass-based CO2 or nitrogen. The key parameters are investigated in this study focusing on circular hydrogen carriers relevant to Australia. The parameters are ranked from 0 (worst) to 10 (best) depending on the bandwidth of the parameter in this review. Methanol shows great potential as a cost-effective solution for long-distance transport of renewable energy being a liquid at standard conditions with a boiling point of 64.7 °C. Methane is also an important hydrogen carrier due to the availability of natural gas infrastructure and its role as a significant export product for Australia.
Exploring European Hydrogen Demand Variations under Tactical Uncertainty with Season Hydrogen Storage
Aug 2025
Publication
Achieving a net-zero energy system in Europe by 2050 will likely require large-scale deployment of hydrogen and seasonal energy storage to manage variability in renewable supply and demand. This study addresses two key objectives: (1) to develop a modeling framework that integrates seasonal storage into a stochastic multihorizon capacity expansion model explicitly capturing tactical uncertainty across timescales; and (2) to assess the impact of seasonal hydrogen storage on long-term investment decisions in European power and hydrogen infrastructure under three hydrogen demand scenarios. To this end the multi-horizon stochastic programming model EMPIRE is extended with tactical stages within each investment period enabling operational decisions to be modeled as a multi-stage stochastic program. This approach captures short-term uncertainty while preserving long-term investment foresight. Results show that seasonal hydrogen storage considerably enhances system flexibility displacing the need for up to 600 TWh/yr of dispatchable generation in Europe after 2040 and sizing down cross-border hydrogen transmission capacities by up to 12%. Storage investments increase by factors of 5–14 which increases the investments in variable renewables and improve utilization particularly solar. Scenarios with seasonal storage also show up to 6% lower total system costs and more balanced infrastructure deployment across regions. These findings underline the importance of modeling temporal uncertainty and seasonal dynamics in long-term energy system planning.
Geomechanical and Geochemical Considerations for Hydrogen Storage in Shale and Tight Reservoirs
Aug 2025
Publication
Underground hydrogen storage (UHS) in shale and tight reservoirs offers a promising solution for large-scale energy storage playing a critical role in the transition to a hydrogenbased economy. However the successful deployment of UHS in these low-permeability formations depends on a thorough understanding of the geomechanical and geochemical factors that affect storage integrity injectivity and long-term stability. This review critically examines the geomechanical aspects including stress distribution rock deformation fracture propagation and caprock integrity which govern hydrogen containment under subsurface conditions. Additionally it explores key geochemical challenges such as hydrogen-induced mineral alterations adsorption effects microbial activity and potential reactivity with formation fluids to evaluate their impact on storage feasibility. A comprehensive analysis of experimental studies numerical modeling approaches and field applications is presented to identify knowledge gaps and future research directions.
A Review of Hydrogen Storage and Transportation: Progresses and Challenges
Aug 2024
Publication
This review aims to summarize the recent advancements and prevailing challenges within the realm of hydrogen storage and transportation thereby providing guidance and impetus for future research and practical applications in this domain. Through a systematic selection and analysis of the latest literature this study highlights the strengths limitations and technological progress of various hydrogen storage methods including compressed gaseous hydrogen cryogenic liquid hydrogen organic liquid hydrogen and solid material hydrogen storage as well as the feasibility efficiency and infrastructure requirements of different transportation modes such as pipeline road and seaborne transportation. The findings reveal that challenges such as low storage density high costs and inadequate infrastructure persist despite progress in high-pressure storage and cryogenic liquefaction. This review also underscores the potential of emerging technologies and innovative concepts including metal–organic frameworks nanomaterials and underground storage along with the potential synergies with renewable energy integration and hydrogen production facilities. In conclusion interdisciplinary collaboration policy support and ongoing research are essential in harnessing hydrogen’s full potential as a clean energy carrier. This review concludes that research in hydrogen storage and transportation is vital to global energy transformation and climate change mitigation.
Mechanical Testing Methods for Assessing Hydrogen Embrittlement in Pipeline Steels: A Review
Oct 2025
Publication
As the transport of gaseous hydrogen and its use as a low carbon-footprint energy vector become increasingly likely scenarios both the scientific literature and technical standards addressing the compatibility of pipeline steels with high-pressure hydrogen environments are rapidly expanding. This work presents a detailed review of the most relevant hydrogen embrittlement testing methodologies proposed in standards and the academic literature. The focus is placed on testing approaches that support design-oriented assessments rather than simple alloy qualification for hydrogen service. Particular attention is given to tensile tests (conducted on smooth and notched specimens) as well as to J-integral and fatigue tests performed following the fracture mechanics’ approach. The influences of hydrogen partial pressure and deformation rate are critically examined as these parameters are essential for ensuring meaningful comparisons across different studies.
Prioritization of the Critical Factors of Hydrogen Transportation in Canada Using the Intuitionistic Fuzzy AHP Method
Jun 2025
Publication
Hydrogen is a potential source of imminent clean energy in the future with its transportation playing a crucial role in allowing large-scale deployment. The challenge lies in selecting an effective sustainable and scalable transportation alternative. This study develops a multi-criteria decision-making (MCDM) framework based on the intuitionistic fuzzy analytic hierarchy process (IF-AHP) to evaluate land-based hydrogen transportation alternatives across Canada. The framework includes uncertainty and decision-maker hesitation through the application of triangular intuitionistic fuzzy numbers (TIFNs). Seven factors their subsequent thirty-three subfactors and three alternatives to hydrogen transportation were identified through a literature review. Pairwise comparison was aggregated among factors subfactors and alternatives from three decision makers using an intuitionistic fuzzy weighted average and priority weights were computed using entropy-based weight. The results show that safety and economic efficiency emerged as the most influential factors in the evaluation of hydrogen transportation alternatives followed by environmental impact security and social impact and public health in ascending order. Among the alternatives tube truck transport obtained the highest overall weight (0.3551) followed by pipelines (0.3272) and rail lines (0.3251). The findings suggest that the tube ruck is currently the most feasible transport option for land-based hydrogen distribution that aims to provide a transition of Canada’s energy mix.
A Multi-Stage Resilience Enhancement Method for Distribution Networks Employing Transportation and Hydrogen Energy Systems
Sep 2025
Publication
The resilience and sustainable development of modern power distribution systems faces escalating challenges due to increasing renewable integration and extreme events. Traditional single-system approaches often overlook the spatiotemporal coordination of cross-domain restoration resources. In this paper we propose a multi-stage resilience enhancement method that employs transportation and hydrogen energy systems. This approach coordinates the pre-event preventive allocation and multi-stage collaborative scheduling of diverse restoration resources including remote-controlled switches (RCSs) mobile hydrogen emergency resources (MHERs) and hydrogen production and refueling stations (HPRSs). The proposed framework supports cross-stage dynamic optimization scheduling enabling the development of adaptive resource dispatch strategies tailored to the characteristics of different stages including prevention fault isolation and service restoration. The model is applicable to complex scenarios involving dynamically changing network topologies and is formulated as a mixed-integer linear programming (MILP) problem. Case studies based on the IEEE 33-bus system show that the proposed method can restore a distribution system’s resilience to approximately 87% of its normal level following extreme events.
Altering Carbonate Wettability for Hydrogen Storage: The Role of Surfactant and CO2 Floods
Oct 2025
Publication
Underground hydrogen storage (UHS) in depleted oil and gas fields is pivotal for balancing large-scale renewable-energy systems yet the wettability of reservoir rocks in contact with hydrogen after decades of Enhanced Oil Recovery (EOR) operations remains poorly quantified. This work experimentally investigates how two common EOR legacies cationic surfactant (city-trimethyl-ammonium bromide CTAB) and supercritical carbon dioxide (SC–CO2) flooding alter rock–water–Hydrogen (H2) wettability in carbonate formations. Contact angles were measured on dolomite and limestone rock slabs at 30–75 ◦C and 3.4–17.2 MPa using a high-pressure captive-bubble cell. Crude-oil aging shifted clean dolomite from strongly water-wet (θ ~ 28–29◦) to intermediate-wet (θ ≈ 84◦). Subsequent immersion in dilute CTAB solutions (0.5–2 wt %) fully reversed this effect restoring or surpassing the original water-wetness (θ ≈ 21–28◦). Limestone samples exposed to SC-CO2 at 60–80 ◦C became more hydrophilic (θ ≈ 18–30◦) relative to untreated controls; moderate carbonate dissolution (≤6 × 103 ppm Ca2+) produced the most significant improvement in water-wetness whereas severe dissolution yielded diminishing returns. These findings show that many mature reservoirs are already water-wet (post-CO2) or can be easily re-wetted (via residual CTAB). Across all scenarios sample wettability showed little sensitivity to pressure but higher temperature consistently promoted stronger water-wetness. Future work should include dynamic core-flooding experiments with realistic reservoir.
Evaluating the Potential for Underground Hydrogen Storage (UHS) in Lithuania: A Review of Geological Viability and Storage Integrity
Feb 2025
Publication
The aim of this study is to review and identify H2 storage suitability in geological reservoirs of the Republic of Lithuania. Notably Lithuania can store clean H2 effectively and competitively because of its wealth of resources and well-established infrastructure. The storage viability in Lithuanian geological contexts is highlighted in this study. In addition when it comes to injectivity and storage capacity salt caverns and saline aquifers present less of a challenge than other kinds of storage medium. Lithuania possesses sizable subterranean reservoirs (Cambrian rocks) that can be utilized to store H2. For preliminary assessment the cyclic H2 injection and production simulation is performed. A 10-year simulation of hydrogen injection and recovery in the Syderiai saline aquifer demonstrated the feasibility of UHS though efficiency was reduced by nearly 50% when using a single well for both injection and production. The study suggests using separate wells to improve efficiency. However to guarantee economic injectivity and containment security a detailed assessment of the geological structures is required specifically at the pore scale level. The volumetric approach estimated a combined storage capacity of approximately 898.5 Gg H2 (~11 TWh) for the Syderiai and Vaskai saline aquifers significantly exceeding previous estimates. The findings underscore the importance of detailed geological data and further research on hydrogen-specific factors to optimize UHS in Lithuania. Addressing technical geological and environmental challenges through multidisciplinary research is essential for advancing UHS implementation and supporting Lithuania’s transition to a sustainable energy system. UHS makes it possible to maximize the use of clean energy reduce greenhouse gas emissions and build a more sustainable and resilient energy system. Hence intensive research and advancements are needed to optimize H2 energy for broader applications in Lithuania.
Development of an Experimental Setup for Testing X52 Steel SENT Specimens in Electrolytic Hydrogen to Explore Repurposing Potential of Pipelines
Apr 2025
Publication
Hydrogen is considered a key alternative to fossil fuels in the broader context of ecological transition. Repurposing natural gas pipelines for hydrogen transport is one of the challenges of this approach. However hydrogen can diffuse into metallic lattices leading to hydrogen embrittlement (HE). For this reason typically ductile materials can experience unexpected brittle fractures and it is therefore necessary to assess the HE propensity of the current pipeline network to ensure its fitness for hydrogen transport. This study examines the relationship between the microstructure of the circumferential weld joint in X52 pipeline steel and hydrogen concentration introduced electrolytically. Base material heat affected zone and fused zone were subjected to 1800 3600 7200 and 14400 s of continuous charging with a current density J = − 10 mA/cm2 in an acid solution. Results showed that the fusion zone absorbed the most hydrogen across all charging times while the base material absorbed more hydrogen than the heat-affected zone due to the presence of non-metallic inclusions. Fracture toughness was assessed using single edge notch tension specimens (SENT) in air and electrolytic hydrogen. Results indicate that the base material is particularly vulnerable to hydrogen environments exhibiting the greatest reduction in toughness when exposed to hydrogen compared to air.
Hydrogen Storage Potential in Underground Coal Gasification Cavities: A MD Simulation of Hydrogen Adsorption and Desorption Behavior in Coal Nanopores
May 2025
Publication
Underground hydrogen storage (UHS) in geological formations presents a viable option for long-term large-scale H2 storage. A physical coal model was constructed based on experimental tests and a MD simulation was used to investigate the potential of UHS in underground coal gasification (UCG) cavities. We investigated H2 behavior under various conditions including temperatures ranging from 278.15 to 348.15 K pressures in the range of 5–20 MPa pore sizes ranging from 1 to 20 nm and varying water content. We also examined the competitive adsorption dynamics of H2 in the presence of CH4 and CO2 . The findings indicate that the optimal UHS conditions for pure H2 involve low temperatures and high pressures. We found that coal nanopores larger than 7.5 nm optimize H2 diffusion. Additionally higher water content creates barriers to hydrogen diffusion due to water molecule clusters on coal surfaces. The preferential adsorption of CO2 and CH4 over H2 reduces H2 -coal interactions. This work provides a significant understanding of the microscopic behaviors of hydrogen in coal nanopores at UCG cavity boundaries under various environmental factors. It also confirms the feasibility of underground hydrogen storage (UHS) in UCG cavities.
The Link Between Microstructural Heterogeneity and Hydrogen Redistribution
Jul 2025
Publication
Green hydrogen is likely to play a major role in decarbonising the aviation industry. It is crucial to understand the effects of microstructure on hydrogen redistribution which may be implicated in the embrittlement of candidate fuel system metals. We have developed a multiscale finite element modelling framework that integrates micromechanical and hydrogen transport models such that the dominant microstructural effects can be efficiently accounted for at millimetre length scales. Our results show that microstructure has a significant effect on hydrogen localisation in elastically anisotropic materials which exhibit an interesting interplay between microstructure and millimetre-scale hydrogen redistribution at various loading rates. Considering 316L stainless steel and nickel a direct comparison of model predictions against experimental hydrogen embrittlement data reveals that the reported sensitivity to loading rate may be strongly linked with rate-dependent grain scale diffusion. These findings highlight the need to incorporate microstructural characteristics in hydrogen embrittlement models.
Modeling and Simulation of Coupled Biochemical and Two-phase Compositional Flow in Underground Hydrogen Storage
Aug 2025
Publication
Integrating microbial activity into underground hydrogen storage models is crucial for simulating longterm reservoir behavior. In this work we present a coupled framework that incorporates bio-geochemical reactions and compositional flow models within the Matlab Reservoir Simulation Toolbox (MRST). Microbial growth and decay are modeled using a double Monod formulation with populations influenced by hydrogen and carbon dioxide availability. First a refined Equation of State (EoS) is employed to accurately capture hydrogen dissolution thereby improving phase behavior and modeling of microbial activity. The model is then discretized using a cell-centered finite-volume method with implicit Euler time discretization. A fully coupled fully implicit strategy is considered. Our implementation builds upon MRST’s compositional module by incorporating the Søreide–Whitson EoS microbial reaction kinetics and specific effects such as bio-clogging and molecular diffusion. Through a series of 1D 2D and 3D simulations we analyze the effects of microbialinduced bio-geochemical transformations on underground hydrogen storage in porous media.These results highlight that accounting for bio-geochemical effects can substantially impact hydrogen loss purity and overall storage performance.
Hydrogen Storage Potential of Unlined Granite Rock Caverns: Experimental and Numerical Investigations on Geochemical Interactions
Jun 2025
Publication
Underground Hydrogen Storage (UHS) offers a promising solution for large-scale energy storage yet suitable geological formations are often scarce. Unlined rock caverns (URCs) constructed in crystalline rocks like granite present a novel alternative particularly in regions where salt caverns or porous media are unsuitable. Despite their potential URCs remain largely unexplored for hydrogen storage. This study addresses this gap by providing one of the first comprehensive investigations into the geochemical interactions between hydrogen and granite host rock using a combined experimental and numerical approach. Granite powder samples were exposed to hydrogen and inert gas (N₂) in brine at room temperature and 5 MPa pressure for 14 weeks. Results showed minimal reactivity of silicate minerals with hydrogen indicated by negligible differences in elemental concentrations between H₂ and N₂ atmospheres. A validated geochemical model demonstrated that existing thermodynamic databases can accurately predict silicate‑hydrogen interactions. Additionally a kinetic batch model was developed to simulate long-term hydrogen storage under commercial URC conditions at Haje. The model predicts a modest 0.65 % increase in mineral volume over 100 years due to mineral precipitation which decreases net porosity and potentially enhances hydrogen containment by limiting leakage pathways. These findings support the feasibility of granite URCs for UHS providing a stable long-term storage option in regions lacking traditional geological formations. By filling a critical knowledge gap this study advances scalable hydrogen storage solutions contributing to the development of resilient renewable energy infrastructure.
A Cost-Optimizing Analysis of Energy Storage Technologies and Transmission Lines for Decarbonizing the UK Power System by 2035
Mar 2025
Publication
The UK net zero strategy aims to fully decarbonize the power system by 2035 anticipating a 40–60% increase in demand due to the growing electrification of the transport and heating sectors over the next thirteen years. This paper provides a detailed technical and economic analysis of the role of energy storage technologies and transmission lines in balancing the power system amidst large shares of intermittent renewable energy generation. The analysis is conducted using the cost-optimizing energy system modelling framework REMix developed by the German Aerospace Center (DLR). The obtained results of multiple optimization scenarios indicate that achieving the lowest system cost with a 73% share of electricity generated by renewable energy sources is feasible only if planning rules in England and Wales are flexible enough to allow the construction of 53 GW of onshore wind capacity. This flexibility would enable the UK to become a net electricity exporter assuming an electricity trading market with neighbouring countries. Depending on the scenario 2.4–11.8 TWh of energy storage supplies an average of 11% of the electricity feed-in with underground hydrogen storage representing more than 80% of that total capacity. In terms of storage converter capacity the optimal mix ranges from 32 to 34 GW of lithium-ion batteries 13 to 22 GW of adiabatic compressed air energy storage 4 to 24 GW of underground hydrogen storage and 6 GW of pumped hydro. Decarbonizing the UK power system by 2035 is estimated to cost $37–56 billion USD with energy storage accounting for 38% of the total system cost. Transmission lines supply 10–17% of the total electricity feed-in demonstrating that when coupled with energy storage it is possible to reduce the installed capacity of conventional power plants by increasing the utilization of remote renewable generation assets and avoiding curtailment during peak generation times.
A Multi-objective Decision-making Framework for Renewable Energy Transportation
Aug 2025
Publication
The mismatch in renewable energy generation potential levelized cost and demand across different geographies highlight the potential of a future global green energy economy through the trade of green fuels. This potential and need call for modeling frameworks to make informed decisions on energy investments operations and regulations. In this work we present a multi-objective optimization framework for modeling and optimizing energy transmission strategies considering different generation locations transportation modes and often conflicting objectives of cost environmental impact and transportation risk. An illustrative case study on supplying renewable energy to Germany demonstrates the utility of the framework across diverse options and trade-offs. Sensitivity analysis reveals that the optimal energy carrier and transmission strategy depend on distance demand and existing infrastructure that can be re-purposed. The framework is adaptable across geographies and scales to offer actionable insights to guide investment operational and regulatory decisions in renewable energy and hydrogen supply chains.
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