Brazil
Hydrogen Risk Assessment in Sao Paulo State, Brazil
Sep 2011
Publication
Sao Paulo State Environmental Protection Agency CETESB Brazil adopts a so called Reference Distance (RD) from hazardous substances storage facilities to populated places as a decision making tool for the application of a simplified or a full Risk Analysis (RA). As for hydrogen RD was set up based on instantaneous release scenarios where consequences reaching off-site population were estimated for delayed ignition ending up in vapor cloud explosion (VCE) with a 0.1 bar blast wave overpressure as a chosen endpoint corresponding to a 1%2of death probability range. Procedures for RD evaluation and further adoption by CETESB are presented in this paper.
The Crucial Role of the Lewis Number in Jet Ignition
Sep 2011
Publication
During the early phase of the transient process following a hydrogen leak into the atmosphere a contact surface appears separating hot air from cold hydrogen. Locally the interface is approximately planar. Diffusion occurs potentially leading to ignition. This process was analyzed by Lin˜a´n and Crespo (1976) for Lewis number unity and Lin˜a´n and Williams (1993) for Lewis number less than unity. In addition to conduction these processes are affected by expansion due to the flow which leads to a temperature drop. If chemistry is very temperature-sensitive then the reaction rate peaks close to the hot region where relatively little fuel is present. Indeed the Arrhenius rate drops rapidly as temperature drops much more so than fuel concentration. However the small fuel concentration present close to the airrich side depends crucially upon the balance between fuel diffusion and heat diffusion hence the fuel Lewis number. For Lewis number unity the fuel concentration present due to diffusion is comparable to the rate of consumption due to chemistry. If the Lewis number is less than unity fuel concentration brought in by diffusion is large compared with temperature-controlled chemistry. For a Lewis number greater than unity diffusion is not strong enough to bring in as much fuel as chemistry would be able to burn and combustion is controlled by fuel diffusion. In the former case combustion occurs faster leading to a localized ignition at a finite time determined by the analysis. As long as the temperature drop due to the expansion associated with the multidimensional nature of the jet does not lower significantly the reaction rate up to that point ignition in the jet takes place. For fuel Lewis number greater than unity first the reaction rate is much lower. Second chemistry does not lead to a defined ignition. Eventually expansion will affect the process and ignition does not take place. In summary it appears that the reason why hydrogen is the only fuel for which jet ignition has been observed is a Lewis number effect coupled with a high speed of sound hence a high initial temperature discontinuity.
Effects of Chemical Kinetics on Ignition of Hydrogen Jets
Sep 2013
Publication
During the early phase of the transient process following a hydrogen leak into the atmosphere a contact surface appears separating air heated by the leading shock from hydrogen cooled by expansion. Locally the interface is approximately planar. Diffusion leads to a temperature decrease on the air side and an increase in the hydrogen-filled region and mass diffusion of hydrogen into air and of air into hydrogen potentially resulting in ignition. This process was analyzed by Li ˜nan and Crespo [1] for unity Lewis number and Li ˜nan and Williams [2] for Lewis number less than unity. We included in the analysis the effect of a slow expansion [3 4] leading to a slow drop in temperature which occurs in transient jets. Chemistry being very temperature-sensitive the reaction rate peaks close to the hot side of the interface where only a small fuel concentration present close to the warm air-rich side which depends crucially upon the fuel Lewis number. For Lewis number unity the fuel concentration due to diffusion is comparable to the rate of consumption by chemistry. If the Lewis number is less than unity diffusion brings in more fuel than temperature-controlled chemistry consumes. For a Lewis number greater than unity diffusion is not strong enough to bring in as much fuel as chemistry would burn; combustion is controlled by fuel diffusion. If the temperature drop due to expansion associated with the multidimensional jet does not lower significantly the reaction rate up to that point analysis shows that ignition in the jet takes place. For fuel Lewis number greater than unity chemistry does not lead to a defined explosion so that eventually expansion will affect the process; ignition does not take place [3 4]. In the current paper these results are extended to consider multistep chemical kinetics but for otherwise similar assumptions. High activation energy is no longer applicable. Instead results are obtained in the short time limit still as a perturbation superimposed to the self-similar solution to the chemically frozen diffusion solution. In that approximation the initiation step which consumes fuel and oxidant is taken to be slow compared with steps that consume one of the reactants and an intermediate species. The formulation leads to a two point boundary value problem for set of coupled rate equations plus an energy equation for perturbations. These equations are linear with variable co-effcients. The coupled problem is solved numerically using a split algorithm in which chemical reaction is solved for frozen diffusion while diffusion is solved for frozen chemistry. At each time step the still coupled linear problem is solved exactly by projecting onto the eigenmodes of the stiff matrix so that the solution is unaffected by stiffness. Since in the short time limit temperature is only affected at the perturbation level the matrix depends only on the similarity variable x t but it is otherwise time-independent. As a result determination of the eigenvalues and eigenvectors is only done once (using Maple) for the entire range of discretized values of the similarity variable. The diffusion problem consists of a set of independent equations for each species. Each of these is solved using orthogonal decomposition onto Hermite polynomials for the homogeneous part plus a particular solution proportional to time for the non-homogeneous (source) terms. That approach can be implemented for different kinetic schemes.
Introductory Course on Hydrogen Safety at CENEH-UNICAMP
Sep 2013
Publication
The course is an introduction to the procedures for safe handling of hydrogen flammable and toxic gases by small users working in the field of hydrogen and fuel cells. Theoretical and practical aspects are emphasized aiming at identifying the main hazards and reduce the risks associated with the use of these gases. Topics: 1. Market hydrogen production fuel cells and energy storage; 2. International System of Units Comparison between the ideal gas and real gases; 3. Safety of gases and hydrogen; 4. Cylinders fittings and valves for gases and hydrogen; 5. Purge of gases; 6. Infrastructure for gases and hydrogen; 7. Accidents with hydrogen.
Licensing a Fuel Cell Bus and a Hydrogen Fueling Station in Brazil
Sep 2011
Publication
The Brazilian Fuel Cell Bus Project is being developed by a consortium comprising 14 national and international partners. The project was initially supported by the GEF/UNDP and MME/FINEP Brazil. The national coordination is under responsibility of MME and EMTU/SP the São Paulo Metropolitan Urban Transport Company that also controls the bus operation and bus routes. This work reports the efforts done in order to obtain the necessary licenses to operate the first fuel cell buses for regular service in Brazil as well as the first commercial hydrogen fueling station to attend the vehicles.
Quantitative Risk Analysis Of Gaseous Hydrogen Storage Unit
Sep 2005
Publication
A quantitative risk analysis to a central pressurized storage tank for gaseous hydrogen has been performed to attend requirements of licensing procedures established by the State Environment Agency of São Paulo State Brazil. Gaseous hydrogen is used to feed the reactor to promote hydrogenation at the surfactant unit. HAZOP was the hazard identification technique selected. System components failures were defined by event and fault tree analysis. Quantitative risk analysis was complied to define the acceptability concepts on societal and individual risks required by the State Environmental Agency to approve the installation operation license. Acceptable levels to public society from the analysis were reached. Safety recommendations to the gaseous hydrogen central were proposed to assure minimization of risk to the near-by community operators environment and property.
Combustion Characteristics of Premixed Hydrogen/Air in an Undulate Microchannel
Jan 2022
Publication
This work reports a numerical investigation of microcombustion in an undulate microchannel using premixed hydrogen and air to understand the effect of the burner design on the flame in order to obtain stability of the flame. The simulations were performed for a fixed equivalence ratio and a hyperbolic temperature profile imposed at the microchannel walls in order to mimic the heat external losses occurred in experimental setups. Due to the complexity of the flow dynamics combined with the combustion behavior the present study focuses on understanding the effect of the fuel inlet rate on the flame characteristics keeping other parameters constant. The results presented stable flame structure regardless of the inlet velocity for this type of design meaning that a significant reduction in the heat flux losses through the walls occurred allowing the design of new simpler systems. The increase in inlet velocity increased the flame extension with the flame being stretched along the microchannel. For higher velocities flame separation was observed with two detected different combustion zones and the temperature profiles along the burner centerline presented a non-monotonic decrease due to the dynamics of the vortices observed in the convex regions of the undulated geometry walls. The geometry effects on the flame structure flow field thermal evolution and species distribution for different inlet velocities are reported and discussed.
Use of Hydrogen as Fuel: A Trend of the 21st Century
Jan 2022
Publication
The unbridled use of fossil fuels is a serious problem that has become increasingly evident over the years. As such fuels contribute considerably to environmental pollution there is a need to find new sustainable sources of energy with low emissions of greenhouse gases. Climate change poses a substantial challenge for the scientific community. Thus the use of renewable energy through technologies that offer maximum efficiency with minimal pollution and carbon emissions has become a major goal. Technology related to the use of hydrogen as a fuel is one of the most promising solutions for future systems of clean energy. The aim of the present review was to provide an overview of elements related to the potential use of hydrogen as an alternative energy source considering its specific chemical and physical characteristics as well as prospects for an increase in the participation of hydrogen fuel in the world energy matrix.
Green Hydrogen and Energy Transition: Current State and Prospects in Portugal
Jan 2023
Publication
Hydrogen is a promising commodity a renewable secondary energy source and feedstock alike to meet greenhouse gas emissions targets and promote economic decarbonization. A common goal pursued by many countries the hydrogen economy receives a blending of public and private capital. After European Green Deal state members created national policies focused on green hydrogen. This paper presents a study of energy transition considering green hydrogen production to identify Portugal’s current state and prospects. The analysis uses energy generation data hydrogen production aspects CO2 emissions indicators and based costs. A comprehensive simulation estimates the total production of green hydrogen related to the ratio of renewable generation in two different scenarios. Then a comparison between EGP goals and Portugal’s transport and energy generation prospects is made. Portugal has an essential renewable energy matrix that supports green hydrogen production and allows for meeting European green hydrogen 2030–2050 goals. Results suggest that promoting the conversion of buses and trucks into H2-based fuel is better for CO2 reduction. On the other hand given energy security thermoelectric plants fueled by H2 are the best option. The aggressive scenario implies at least 5% more costs than the moderate scenario considering economic aspects.
Renewable Energy Potentials and Roadmap in Brazil, Austria, and Germany
Mar 2024
Publication
The emerging energy transition is particularly described as a move towards a cleaner lower-carbon system. In the context of the global shift towards sustainable energy sources this paper reviews the potential and roadmap for hydrogen energy as a crucial component of the clean energy landscape. The primary objective is to present a comprehensive literature overview illuminating key themes trends and research gaps in the scientific discourse concerning hydrogen production and energy policy. This review focuses particularly on specified geographic contexts with an emphasis on understanding the unique energy policies related to renewable energy in Brazil Austria and Germany. Given their distinct social systems and developmental stages this paper aims to delineate the nuanced approaches these countries adopt in their pursuit of renewable energy and the integration of hydrogen within their energy frameworks. Brazil exhibits vast renewable energy potential particularly in wind and solar energy sectors positioning itself for substantial growth in the coming years. Germany showcases a regulatory framework that promotes innovation and technological expansion reflecting its highly developed social system and commitment to transitioning away from fossil fuels. Austria demonstrates dedication to decarbonization particularly through the exploration of biomethane for residential heating and cooling.
Using the Jet Stream for Sustainable Airship and Balloon Transportation of Cargo and Hydrogen
Jul 2019
Publication
The maritime shipping sector is a major contributor to CO2 emissions and this figure is expected to rise in coming decades. With the intent of reducing emissions from this sector this research proposes the utilization of the jet stream to transport a combination of cargo and hydrogen using airships or balloons at altitudes of 10–20 km. The jet streams flow in the mid-latitudes predominantly in a west–east direction reaching an average wind speed of 165 km/h. Using this combination of high wind speeds and reliable direction hydrogen-filled airships or balloons could carry hydrogen with a lower fuel requirement and shorter travel time compared to conventional shipping. Jet streams at different altitudes in the atmosphere were used to identify the most appropriate circular routes for global airship travel. Round-the-world trips would take 16 days in the Northern Hemisphere and 14 in the Southern Hemisphere. Hydrogen transport via the jet stream due to its lower energy consumption and shorter cargo delivery time access to cities far from the coast could be a competitive alternative to maritime shipping and liquefied hydrogen tankers in the development of a sustainable future hydrogen economy.
Comparative Exergy and Environmental Assessment of the Residual Biomass Gasification Routes for Hydrogen and Ammonia Production
Jul 2023
Publication
The need to reduce the dependency of chemicals on fossil fuels has recently motivated the adoption of renewable energies in those sectors. In addition due to a growing population the treatment and disposition of residual biomass from agricultural processes such as sugar cane and orange bagasse or even from human waste such as sewage sludge will be a challenge for the next generation. These residual biomasses can be an attractive alternative for the production of environmentally friendly fuels and make the economy more circular and efficient. However these raw materials have been hitherto widely used as fuel for boilers or disposed of in sanitary landfills losing their capacity to generate other by-products in addition to contributing to the emissions of gases that promote global warming. For this reason this work analyzes and optimizes the biomass-based routes of biochemical production (namely hydrogen and ammonia) using the gasification of residual biomasses. Moreover the capture of biogenic CO2 aims to reduce the environmental burden leading to negative emissions in the overall energy system. In this context the chemical plants were designed modeled and simulated using Aspen plus™ software. The energy integration and optimization were performed using the OSMOSE Lua Platform. The exergy destruction exergy efficiency and general balance of the CO2 emissions were evaluated. As a result the irreversibility generated by the gasification unit has a relevant influence on the exergy efficiency of the entire plant. On the other hand an overall negative emission balance of −5.95 kgCO2/kgH2 in the hydrogen production route and −1.615 kgCO2/kgNH3 in the ammonia production route can be achieved thus removing from the atmosphere 0.901 tCO2/tbiomass and 1.096 tCO2/tbiomass respectively.
Hydrogen Deep Ocean Link: A Global Sustainable Interconnected Energy Grid
Mar 2022
Publication
The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. This paper analyses an innovative proposal for the creation of hydrogen ocean links. It intends to fill existing gaps in the creation of a hydrogen economy with the increase in flexibility and viability for hydrogen production consumption compression storage and transportation. The main concept behind the proposals presented in this paper consists of using the fact that the pressure in the deep sea is very high which allows a thin and cheap HDPE tank to store and transport large amounts of pressurized hydrogen in the deep sea. This is performed by replacing seawater with pressurized hydrogen and maintaining the pressure in the pipes similar to the outside pressure. Hydrogen Deep Ocean Link has the potential of increasing the interconnectivity of different regional energy grids into a global sustainable interconnected energy system.
Hydrogen Deep Ocean Link: A Global Sustainable Interconnected Energy Grid<br/><br/><br/>
Mar 2022
Publication
The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. This paper analyses an innovative proposal for the creation of hydrogen ocean links. It intends to fill existing gaps in the creation of a hydrogen economy with the increase in flexibility and viability for hydrogen production consumption compression storage and transportation. The main concept behind the proposals presented in this paper consists of using the fact that the pressure in the deep sea is very high which allows a thin and cheap HDPE tank to store and transport large amounts of pressurized hydrogen in the deep sea. This is performed by replacing seawater with pressurized hydrogen and maintaining the pressure in the pipes similar to the outside pressure. Hydrogen Deep Ocean Link has the potential of increasing the interconnectivity of different regional energy grids into a global sustainable interconnected energy system.
A Geospatial Method for Estimating the Levelised Cost of Hydrogen Production from Offshore Wind
Jan 2023
Publication
This paper describes the development of a general-purpose geospatial model for assessing the economic viability of hydrogen production from offshore wind power. A key feature of the model is that it uses the offshore project's location characteristics (distance to port water depth distance to gas grid injection point). Learning rates are used to predict the cost of the wind farm's components and electrolyser stack replacement. The notional wind farm used in the paper has a capacity of 510 MW. The model is implemented in a geographic information system which is used to create maps of levelised cost of hydrogen from offshore wind in Irish waters. LCOH values in 2030 spatially vary by over 50% depending on location. The geographically distributed LCOH results are summarised in a multivariate production function which is a simple and rapid tool for generating preliminary LCOH estimates based on simple site input variables.
A Theoretical Study Using the Multiphase Numerical Simulation Technique for Effective Use of H2 as Blast Furnaces Fuel
Jun 2017
Publication
We present a numerical simulation procedure for analyzing hydrogen oxygen and carbon dioxide gases injections mixed with pulverized coals within the tuyeres of blast furnaces. Effective use of H2 rich gas is highly attractive into the steelmaking blastfurnace considering the possibility of increasing the productivity and decreasing the specific emissions of carbon dioxide becoming the process less intensive in carbon utilization. However the mixed gas and coal injection is a complex technology since significant changes on the inner temperature and gas flow patterns are expected beyond to their effects on the chemical reactions and heat exchanges. Focusing on the evaluation of inner furnace status under such complex operation a comprehensive mathematical model has been developed using the multi interaction multiple phase theory. The BF considered as a multiphase reactor treats the lump solids (sinter small coke pellets granular coke and iron ores) gas liquids metal and slag and pulverized coal phases. The governing conservation equations are formulated for momentum mass chemical species and energy and simultaneously discretized using the numerical method of finite volumes. We verified the model with a reference operational condition using pulverized coal of 215 kg per ton of hot metal (kg thm−1). Thus combined injections of varying concentrations of gaseous fuels with H2 O2 and CO2 are simulated with 220 kg thm−1 and 250 kg thm−1 coals injection. Theoretical analysis showed that stable operations conditions could be achieved with productivity increase of 60%. Finally we demonstrated that the net carbon utilization per ton of hot metal decreased 12%.
Levelised Cost of Transmission Comparison for Green Hydrogen and Ammonia in New-build Offshore Energy Infrastructure: Pipelines, Tankers, and HVDC
Mar 2024
Publication
As the global market develops for green hydrogen and ammonia derived from renewable electricity the bulk transmission of hydrogen and ammonia from production areas to demand-intensive consumption areas will increase. Repurposing existing infrastructure may be economically and technically feasible but increases in supply and demand will necessitate new developments. Bulk transmission of hydrogen and ammonia may be effected by dedicated pipelines or liquefied fuel tankers. Transmission of electricity using HVDC lines to directly power electrolysers producing hydrogen near the demand markets is another option. This paper presents and validates detailed cost models for newly-built dedicated offshore transmission methods for green hydrogen and ammonia and carries out a techno-economic comparison over a range of transmission distances and production volumes. New pipelines are economical for short distances while new HVDC interconnectors are suited to medium-large transmission capacities over a wide range of distances and liquefied gas tankers are best for long distances.
Effect on Diesel Engine Performance Parameters Using Hydrogen and Oxygen Produced on Demand
Oct 2022
Publication
Hydrogen is seen as a future energy carrier since its chemical compounds make up a large part of the Earth’s surface. This study sought to analyze the impact related to the inclusion of hydrogen and oxygen gases produced on demand by an alkaline electrolyzer to the engine added directly through the fuel intake line. For this purpose performance parameters were monitored such as liquid fuel consumption and greenhouse gas emissions and correlated to any effect observed on the engine’s power output and combustion behavior. A 58 kVA nominal power motor-generator was used coupled with a resistive load bank (20 kW) where two fuel configurations were tested (diesel injection only and a mixture of diesel hydrogen and oxygen) and compared. A total of 42 tests were performed considering both the admission gases into the fuel intake line and also diesel supply only for baseline. A substantial decrease in fuel consumption was observed (7.59%) when the blend configuration was used despite a decrease in the engine’s work (1.07%). It was also possible to see a common pattern between NO and NO2 emissions for both fuel configurations while the behavior of the CO2 and CO emissions indicated a higher complete diesel burning fraction when using the gases on demand. Therefore we can verify that the use of hydrogen and oxygen gases produced on demand in the fuel intake line is a promising alternative to provide a decrease in liquid fuel consumption and an overall improvement in engine combustion.
A Review on Industrial Perspectives and Challenges on Material, Manufacturing, Design and Development of Compressed Hydrogen Storage Tanks for the Transportation Sector
Jul 2022
Publication
Hydrogen fuel cell technology is securing a place in the future of advanced mobility and the energy revolution as engineers explore multiple paths in the quest for decarbonization. The feasibility of hydrogen-based fuel cell vehicles particularly relies on the development of safe lightweight and cost-competitive solutions for hydrogen storage. After the demonstration of hundreds of prototype vehicles today commercial hydrogen tanks are in the first stages of market introduction adopting configurations that use composite materials. However production rates remain low and costs high. This paper intends to provide an insight into the evolving scenario of solutions for hydrogen storage in the transportation sector. Current applications in different sectors of transport are covered focusing on their individual requirements. Furthermore this work addresses the efforts to produce economically attractive composite tanks discussing the challenges surrounding material choices and manufacturing practices as well as cutting-edge trends pursued by research and development teams. Key issues in the design and analysis of hydrogen tanks are also discussed. Finally testing and certification requirements are debated once they play a vital role in industry acceptance.
The BioSCWG Project: Understanding the Trade-Offs in the Process and Thermal Design of Hydrogen and Synthetic Natural Gas Production
Oct 2016
Publication
This article presents a summary of the main findings from a collaborative research project between Aalto University in Finland and partner universities. A comparative process synthesis modelling and thermal assessment was conducted for the production of Bio-synthetic natural gas (SNG) and hydrogen from supercritical water refining of a lipid extracted algae feedstock integrated with onsite heat and power generation. The developed reactor models for product gas composition yield and thermal demand were validated and showed conformity with reported experimental results and the balance of plant units were designed based on established technologies or state-of-the-art pilot operations. The poly-generative cases illustrated the thermo-chemical constraints and design trade-offs presented by key process parameters such as plant organic throughput supercritical water refining temperature nature of desirable coproducts downstream indirect production and heat recovery scenarios. The evaluated cases favoring hydrogen production at 5 wt. % solid content and 600 ◦C conversion temperature allowed higher gross syngas and CHP production. However mainly due to the higher utility demands the net syngas production remained lower compared to the cases favoring BioSNG production. The latter case at 450 ◦C reactor temperature 18 wt. % solid content and presence of downstream indirect production recorded 66.5% 66.2% and 57.2% energetic fuel-equivalent and exergetic efficiencies respectively
Experimental Validation of a Modular Skid for Hydrogen Production in a Hybrid Microgrid
Jul 2025
Publication
This article presents the development integration and experimental validation of a modular microgrid for sustainable hydrogen production addressing global electricity demand and environmental challenges. The system was designed for initial validation in a thermoelectric power plant environment with scalability to other applications. Centered on a six-compartment skid it integrates photovoltaic generation battery storage and a liquefied petroleum gas generator to emulate typical cogeneration conditions together with a high-purity proton exchange membrane electrolyzer. A supervisory control module ensures real-time monitoring and energy flow management following international safety standards. The study also explores the incorporation of blockchain technology to certify the renewable origin of hydrogen enhancing traceability and transparency in the green hydrogen market. The experimental results confirm the system’s technical feasibility demonstrating stable hydrogen production efficient energy management and islanded-mode operation with preserved grid stability. These findings highlight the strategic role of hydrogen as an energy vector in the transition to a cleaner energy matrix and support the proposed architecture as a replicable model for industrial facilities seeking to combine hydrogen production with advanced microgrid technologies. Future work will address large-scale validation and performance optimization including advanced energy management algorithms to ensure economic viability and sustainability in diverse industrial contexts.
Renewable Hydrogen Production from Butanol Steam Reforming over Nickel Catalysts Promoted by Lanthanides
Oct 2021
Publication
Hydrogen is mainly produced by steam reforming of natural gas a non-renewable resource. Alternative and renewable routes for hydrogen production play an important role in reducing dependence on oil and minimizing the emission of greenhouse gases. In this work butanol a model compound of bio-oil was employed for hydrogen production by steam reforming. The reaction was evaluated for 30 h in a tubular quartz reactor at 500 ◦C atmospheric pressure GHSV of 500000 h−1 and an aqueous solution feed of 10% v/v butanol. For this reaction catalysts with 20 wt.% NiO were prepared by wet impregnation using three supports: γ-alumina and alumina modified with 10 wt.% of cerium and lanthanum oxides. Both promoters increased the reduction degree of the catalysts and decreased catalyst acidity which is closely related to coke formation and deactivation. Ni/La2O3– Al2O3 presented a higher nickel dispersion (14.6%) which combined with other properties led to a higher stability higher mean hydrogen yield (71%) and lower coke formation per mass (56%). On the other hand the nonpromoted catalyst suffered a significant deactivation associated with coke formation favored by its highest acidity (3.1 µmol m−2 ).
Optimized Configuration of Diesel Engine-Fuel Cell-Battery Hybrid Power Systems in a Platform Supply Vessel to Reduce CO2 Emissions
Mar 2022
Publication
The main objective of this paper is to select the optimal configuration of a ship’s power system considering the use of fuel cells and batteries that would achieve the lowest CO2 emissions also taking into consideration the number of battery cycles. The ship analyzed in this work is a Platform Supply Vessel (PSV) used to support oil and gas offshore platforms transporting goods equipment and personnel. The proposed scheme considers the ship’s retrofitting. The ship’s original main generators are maintained and the fuel cell and batteries are installed as complementary sources. Moreover a sensitivity analysis is pursued on the ship’s demand curve. The simulations used to calculate the CO2 emissions for each of the new hybrid configurations were developed using HOMER software. The proposed solutions are auxiliary generators three types of batteries and a protonexchange membrane fuel cell (PEMFC) with different sizes of hydrogen tanks. The PEMFC and batteries were sized as containerized solutions and the sizing of the auxiliary engines was based on previous works. Each configuration consists of a combination of these solutions. The selection of the best configuration is one contribution of this paper. The new configurations are classified according to the reduction of CO2 emitted in comparison to the original system. For different demand levels the results indicate that the configuration classification may vary. Another valuable contribution of this work is the sizing of the battery and hydrogen storage systems. They were installed in 20 ft containers since the installation of batteries fuel cells and hydrogen tanks in containers is widely used for ship retrofit. As a result the most significant reduction of CO2 emissions is 10.69%. This is achieved when the configuration includes main generators auxiliary generators a 3119 kW lithium nickel manganese cobalt (LNMC) battery a 250 kW PEMFC and 581 kg of stored hydrogen.
Optimal Energy Management System Using Biogeography Based Optimization for Grid-connected MVDC Microgrid with Photovoltaic, Hydrogen System, Electric Vehicles and Z-source Converters
Oct 2021
Publication
Currently the technology associated with charging stations for electric vehicles (EV) needs to be studied and improved to further encourage its implementation. This paper presents a new energy management system (EMS) based on a Biogeography-Based Optimization (BBO) algorithm for a hybrid EV charging station with a configuration that integrates Z-source converters (ZSC) into medium voltage direct current (MVDC) grids. The EMS uses the evolutionary BBO algorithm to optimize a fitness function defining the equivalent hydrogen consumption/generation. The charging station consists of a photovoltaic (PV) system a local grid connection two fast charging units and two energy storage systems (ESS) a battery energy storage (BES) and a complete hydrogen system with fuel cell (FC) electrolyzer (LZ) and hydrogen tank. Through the use of the BBO algorithm the EMS manages the energy flow among the components to keep the power balance in the system reducing the equivalent hydrogen consumption and optimizing the equivalent hydrogen generation. The EMS and the configuration of the charging station based on ZSCs are the main contributions of the paper. The behaviour of the EMS is demonstrated with three EV connected to the charging station under different conditions of sun irradiance. In addition the proposed EMS is compared with a simpler EMS for the optimal management of ESS in hybrid configurations. The simulation results show that the proposed EMS achieves a notable improvement in the equivalent hydrogen consumption/generation with respect to the simpler EMS. Thanks to the proposed configuration the output voltage of the components can be upgraded to MVDC while reducing the number of power converters compared with other configurations without ZSC.
Hydrogen Fuel Cell Aircraft for the Nordic Market
Mar 2024
Publication
A model for a fuel cell propelled 50 PAX hydrogen aircraft is developed. In terms of year 2045 Nordic air travel demand this aircraft is expected to cover 97% of travel distances and 58% of daily passenger volume. Using an ATR 42 as a baseline cryogenic tanks and fuel cell stacks are sized and propulsion system masses updated. Fuselage and wing resizing are required which increases mass and wetted area. Sizing methods for the multi-stack fuel cell and the cryogenic tanks are implemented. The dynamic aircraft model is updated with models for hydrogen consumption and tank pressure control. For the Multi-layer insulation (MLI) tank a trade study is performed. A ventilation pressure of 1.76 bar and 15 MLI layers are found to be optimal for the design mission. A return-without-refuel mission is explored where for a 10-hour ground hold 38.4% of the design range is retained out of the theoretically achievable 50%.
An Alkaline-Acid Glycerol Electrochemical Reformer for Simultaneous Production of Hydrogen and Electricity
Apr 2022
Publication
This study shows the results for the first time of an glycerol alkaline-acid electrolyzer. Such a configuration allows spontaneous operation producing energy and hydrogen simultaneously as a result of the utilization of the neutralization and fuel chemical energy. The electroreformer—built with a 20 wt% Pd/C anode and cathode and a Na+ -pretreated Nafion® 117—can simultaneously produce hydrogen and electricity in the low current density region whereas it operates in electrolysis mode at high current densities. In the spontaneous region the maximum power densities range from 1.23 mW cm−2 at 30 ◦C to 11.9 mW cm−2 at 90 ◦C with a concomitant H2 flux ranging from 0.0545 STP m−3 m−2 h −1 at 30 ◦C to 0.201 STP m−3 m−2 h −1 at 90 ◦C due to the beneficial effect of the temperature on the performance. Furthermore over a chronoamperometric test the electroreformer shows a stable performance over 12 h. As a challenge proton crossover from the cathode to the anode through the cation exchange Nafion® partially reduces the pH gradient responsible for the extra electromotive force thus requiring a less permeable membrane.
Application of Levelized and Environmental Cost Accounting Techniques to Demonstrate the Feasibility of Green Hydrogen-Powered Buses in Brazil
Feb 2025
Publication
Background: This study applied levelized cost of hydrogen (LCOH) and environmental cost accounting techniques to evaluate the feasibility of producing green hydrogen (GH2) via alkaline electrolysis for use in a bus fleet in Fortaleza Brazil. Methods: A GH2 plant with a 3 MW wind tower was considered in this financial project. A sensitivity analysis was conducted to assess the economic viability of the project considering the influence of production volume the number of electrolysis kits financing time and other kay economic indices. Revenue was derived from the sale of by-products including green hospital oxygen (GHO2) and excess wind energy. A life cycle assessment (LCA) was performed to quantify material and emission flows throughout the H2 production chain. A zero-net hydrogen price scenario was tested to evaluate the feasibility of its use in urban transportation. Results: The production of GH2 in Brazil using alkaline electrolysis powered by wind energy proved to be economically viable for fueling a hydrogen-powered bus fleet. For production volumes ranging from 8.89 to 88.9 kg H2/h the sensitivity analysis revealed high economic performance achieving a net present value (NPV) between USD 19.4 million and USD 21.8 million a payback period of 1–4 years an internal rate of return (IRR) of 24–90% and a return on investment (ROI) of 300–1400%. The LCOH decreased with increased production ranging from 56 to 25 USD/MWh. Over the project timeline GH2 production and use in the bus fleet reduced CO2 emissions by 53000–287000 t CO2 eq. The fuel cell bus fleet project demonstrated viability through fuel cost savings and revenue from carbon credit sales highlighting the economic social and environmental sustainability of GH2 use in urban transportation in Brazil.
Impact of Fuel Production Technologies on Energy Consumption and GHG Emissions from Diesel and Electric–Hydrogen Hybrid Buses in Rio de Janeiro, Brazil
Apr 2023
Publication
In view of the GHG reduction targets to be met Brazilian researchers are looking for cleaner alternatives to energy sources. These alternatives are primarily to be applied in the transport sector which presents high energy consumption as well as high CO2 emissions. In this sense this research developed an LCI study considering two bus alternatives for the city of Rio de Janeiro: diesel-powered internal combustion buses (ICEB) and a hydrogen-powered polymer fuel cell hybrid bus (FCHB). For the FCHB three hydrogen production methods were also included: water electrolysis (WE) ethanol steam reforming (ESR) and natural gas steam reforming (NGSR). The research was aimed at estimating energy consumption including the percentage of energy that is renewable as well as CO2 emissions. The results show diesel as the energy source with the highest emissions as well as the highest fossil energy consumption. Regarding the alternatives for hydrogen production water electrolysis stood out with the lowest emissions.
Hydrogen Environmental Benefits Depend on the Way of Production: An Overview of the Main Processes Production and Challenges by 2050
Jun 2021
Publication
Hydrogen (H2) is presented as an important alternative for clean energy and raw material in the modern world. However the environmental benefits are linked to its process of production. Herein the chemical aspects advantages/disadvantages and challenges of the main processes of H2 production from petroleum to water are described. The fossil fuel (FF)-based methods and the state-of-art strategies are outlined to produce hydrogen from water (electrolysis) wastewater and seawater. In addition a discussion based on a color code to classify the cleanliness of hydrogen production is introduced. By the end a summary of the hydrogen value chain addresses topics related to the financial aspects and perspective for 2050: green hydrogen and zero-emission carbon.
Brazil’s New Green Hydrogen Industry: An Assessment of Its Macroeconomic Viability Through an Input–Output Approach
Dec 2024
Publication
This manuscript explores the role of green hydrogen produced through ethanol reforming in accelerating Brazil’s transition to a low-carbon economic framework. Despite ongoing efforts to lessen carbon dependence Brazil’s reliance on biofuels and other renewable energy sources remains inadequate for fully achieving its decarbonization objectives. Green hydrogen presents a vital opportunity to boost energy sustainability especially in sectors that are challenging to decarbonize such as industry and transportation. By analyzing Brazil’s input–output (I-O) table using data from the Brazilian Institute of Geography and Statistics (IBGE) this study evaluates the macroeconomic potential of green hydrogen focusing on GDP growth and employment generation. Furthermore the research explores green hydrogen systems’ economic feasibility and potential impact on future energy policies offering valuable insights for stakeholders and decision-makers. In addition this investigation highlights Brazil’s abundant renewable resources and identifies the infrastructural investments necessary to support a green hydrogen economy. The findings aim to strengthen Brazil’s national decarbonization strategy and serve as a model for other developing nations transitioning to clean energy.
Increasing Energy Efficiency of Hydrogen Refueling Stations via Optimal Thermodynamic Paths
Sep 2023
Publication
This work addresses the energy efficiency of hydrogen refueling stations (HRS) using a first principles model and optimal control methods to find minimal entropy production operating paths. The HRS model shows good agreement with experimental data achieving maximum state of charge and temperature discrepancies of 1 and 7% respectively. Model solution and optimization is achieved at a relatively low computational time (40 s) when compared to models of the same degree of accuracy. The entropy production mapping indicates the flow control valve as the main source of irreversibility accounting for 85% of the total entropy production in the process. The minimal entropy production refueling path achieves energy savings from 20 to 27% with respect to the SAE J2601 protocol depending on the ambient temperature. Finally the proposed method under nearreversible refueling conditions shows a theoretical reduction of 43% in the energy demand with respect to the SAE J2601 protocol.
Economic and Environmental Assessment of Hydrogen Production from Brazilian Energy Grid
Apr 2023
Publication
The Brazilian energy grid is considered as one of the cleanest in the world because it is composed of more than 80% of renewable energy sources. This work aimed to apply the levelized costs (LCOH) and environmental cost accounting techniques to demonstrate the feasibility of producing hydrogen (H2 ) by alkaline electrolysis powered by the Brazilian energy grid. A project of hydrogen production with a lifetime of 20 years had been evaluated by economical and sensitivity analysis. The production capacity (8.89 to 46.67 kg H2/h) production volume (25 to 100%) hydrogen sale price (1 to 5 USD/kg H2 ) and the MAR rate were varied. Results showed that at 2 USD/kg H2 all H2 production plant sizes are economically viable. On this condition a payback of fewer than 4 years an IRR greater than 31 a break-even point between 56 and 68% of the production volume and a ROI above 400% were found. The sensitivity analysis showed that the best economic condition was found at 35.56 kg H2/h of the plant size which generated a net present value of USD 10.4 million. The cost of hydrogen varied between 1.26 and 1.64 USD/kg and a LCOH of 37.76 to 48.71 USD/MWh. LCA analysis showed that the hydrogen production project mitigated from 26 to 131 thousand tons of CO2 under the conditions studied.
Solid Air Hydrogen Liquefaction, the Missing Link of the Hydrogen Economy
Mar 2023
Publication
The most challenging aspect of developing a green hydrogen economy is long-distance oceanic transportation. Hydrogen liquefaction is a transportation alternative. However the cost and energy consumption for liquefaction is currently prohibitively high creating a major barrier to hydrogen supply chains. This paper proposes using solid nitrogen or oxygen as a medium for recycling cold energy across the hydrogen liquefaction supply chain. When a liquid hydrogen (LH2) carrier reaches its destination the regasification process of the hydrogen produces solid nitrogen or oxygen. The solid nitrogen or oxygen is then transported in the LH2 carrier back to the hydrogen liquefaction facility and used to reduce the energy consumption cooling gaseous hydrogen. As a result the energy required to liquefy hydrogen can be reduced by 25.4% using N2 and 27.3% using O2. Solid air hydrogen liquefaction (SAHL) can be the missing link for implementing a global hydrogen economy.
Electrochemical Looping Green Hydrogen Production by Using Water Electrochemically Treated as a Raw Material for the Electrolyzer
May 2025
Publication
In this study the applicability of an integrated-hybrid process was performed in a divided electrochemical cell for removing organic matter from a polluted effluent with simultaneous production of green H2. After that the depolluted water was reused for the first time in the cathodic compartment once again in the same cell to be a viable environmental alternative for converting water into energy (green H2) with higher efficiency and reasonable cost requirements. The production of green H2 in the cathodic compartment (Ni-Fe-based steel stainless (SS) mesh as cathode) in concomitance with the electrochemical oxidation (EO) of wastewater in the anodic compartment (boron-doped diamond (BDD) supported in Nb as anode) was studied (by applying different current densities (j = 30 60 and 90 mA cm−2 ) at 25 ◦C) in a divided-membrane type electrochemical cell driven by a photovoltaic (PV) energy source. The results clearly showed that in the first step the water anodically treated by applying 90 mA cm−2 for 180 min reached high-quality water parameters. Meanwhile green H2 production was greater than 1.3 L with a Faradaic efficiency of 100%. Then in a second step the water anodically treated was reused in the cathodic compartment again for a new integrated-hybrid process with the same electrodes under the same experimental conditions. The results showed that the reuse of water in the cathodic compartment is a sustainable strategy to produce green H2 when compared to the electrolysis using clean water. Finally two implied benefits of the proposed process are the production of green H2 and wastewater cleanup both of which are equally significant and sustainable. The possible use of H2 as an energetic carrier in developing nations is a final point about sustainability improvements. This is a win-win solution.
Advances, Progress, and Future Directions of Renewable Wind Energy in Brazil (2000–2025–2050)
May 2025
Publication
Brazil has emerged as one of the global leaders in adopting renewable energy standing out in the implementation of onshore wind energy and more recently in the development of future offshore wind energy projects. Onshore wind energy has experienced exponential growth in the last decade positioning Brazil as one of the countries with the largest installed capacity in the world by 2023 with 30 GW. Wind farms are mainly concentrated in the northeast region where winds are constant and powerful enabling efficient and cost-competitive generation. Although in its early stages offshore wind energy presents significant potential of 1228 GW due to Brazil’s extensive coastline which exceeds 7000 km. Offshore wind projects promise greater generating capacity and stability as offshore winds are more constant than onshore winds. However their development faces challenges such as high initial costs environmental impacts on marine ecosystems and the need for specialized infrastructure. From a sustainability perspective this article discusses that both types of wind energy are key to Brazil’s energy transition. They reduce dependence on fossil fuels generate green jobs and foster technological innovation. However it is crucial to implement policies that foster synergy with green hydrogen production and minimize socio-environmental impacts such as impacts on local communities and biodiversity. Finally the article concludes that by 2050 Brazil is expected to consolidate its leadership in renewable energy by integrating advanced technologies such as larger more efficient turbines energy storage systems and green hydrogen production. The combination of onshore and offshore wind energy and other renewable sources could position the country as a global model for a clean sustainable and resilient energy mix.
Design and Layout Planning of a Green Hydrogen Production Facility
May 2025
Publication
In response to the greenhouse gas (GHG) reduction targets set by the Paris Agreement green hydrogen has become a key solution for global decarbonisation. However research on the design of green hydrogen production facilities remains limited particularly in Brazil. This study bridges this gap by developing a comprehensive design for a green hydrogen production plant powered by an 81 MW photovoltaic (PV) system in Ceará Brazil. The facility layout equipment sizing and resource requirements were determined using the Systematic Layout Planning (SLP) method based on the available energy for daily hydrogen production. The design also integrates safety regulations including local standards in Ceará as well as raw material needs and production capacity. This study delivers a detailed facility layout specifying equipment placement and capacity based on the PV plant’s output while ensuring compliance with safety protocols. This research contributes to the green hydrogen literature by providing a structured methodology for facility design serving as a reference for future projects and fostering the advancement of green hydrogen technology particularly in developing countries.
Analysis of the Sugarcane Biomass Use to Produce Green Hydrogen: Brazilian Case Study
Feb 2025
Publication
Conventional hydrogen production processes which often involve fossil raw materials emit significant amounts of carbon dioxide into the atmosphere. This study critically evaluates the feasibility of using sugarcane biomass as an energy source to produce green hydrogen. In the 2023/2024 harvest Brazil the world’s largest sugarcane producer processed approximately 713.2 million metric tons of sugarcane. This yielded 45.68 million metric tons of sugar and 29.69 billion liters of first-generation ethanol equivalent to approximately 0.0416 liters of ethanol per kilogram of sugarcane. A systematic literature review was conducted using Scopus and Clarivate Analytics Web of Science resulting in the assessment of 335 articles. The study has identified seven potential biohydrogen production methods including two direct approaches from second-generation ethanol and five from integrated bioenergy systems. Experimental data indicate that second-generation ethanol can yield 594 MJ per metric ton of biomass with additional energy recovery from lignin combustion (1705 MJ per metric ton). Moreover advances in electrocatalytic reforming and plasma-driven hydrogen production have demonstrated high conversion efficiencies addressing key technical barriers. The results highlight Brazil’s strategic potential to integrate biohydrogen production within its existing bioenergy infrastructure. By leveraging sugarcane biomass for green hydrogen the country can contribute significantly to the global transition to sustainable energy while enhancing its energy security.
Hydrogen Production Plant Retrofit for Green H2: Experimental Validation of a High-Efficiency Retrofit of an Alkaline Hydrogen Plant Using an Isolated DC Microgrid
Oct 2025
Publication
Given the climate change observed in the past few decades sustainable development and the use of renewable energy sources are urgent. In this scenario hydrogen production through electrolyzers is a promising renewable source and energy vector because of its ultralow greenhouse emissions and high energy content. Hydrogen can be used in a variety of applications from transportation to electricity generation contributing to the diversification of the energy matrix. In this context this paper presents an autonomous isolated DC microgrid system for generating and storing electrical energy to be exclusively used for feeding an electrolyzer hydrogen production plant which has been retrofitted for green hydrogen production. Experimental verification was performed at Itaipu Parquetec which consists of an alkaline electrolysis unit directly integrated with a battery energy storage system and renewable sources (e.g. photovoltaic and wind) by using an isolated DC microgrid concept based on DC/DC and AC/DC converters. Experimental results revealed that the new electrolyzer DC microgrid increases the system’s overall efficiency in comparison to the legacy thyristor-based power supply system by 26% and it autonomously controls the energy supply to the electrolyzer under optimized conditions with an extremely low output current ripple. Another advantage of the proposed DC microgrid is its ability to properly manage the startup and shutdown process of the electrolyzer plant under power generation outages. This paper is the result of activities carried out under the R&D project of ANEEL program No. PD-10381-0221/2021 entitled “Multiport DC-DC Converter and IoT System for Intelligent Energy Management” which was conducted in partnership with CTG-Brazil.
Natural Hydrogen in Uruguay: Catalog of H2-Generating Rocks, Prospective Exploration Areas, and Potential Systems
Feb 2025
Publication
The increasing demand for carbon-free energy in recent years has positioned hydrogen as a viable option. However its current production remains largely dependent on carbon-emitting sources. In this context natural hydrogen generated through geological processes in the Earth’s subsurface has emerged as a promising alternative. The present study provides the first national-scale assessment of natural dihydrogen (H2) potential in Uruguay by developing a catalog of potential H2-generating rocks identifying prospective exploration areas and proposing H2 systems there. The analysis includes a review of geological and geophysical data from basement rocks and onshore sedimentary basins. Uruguay stands out as a promising region for natural H2 exploration due to the significant presence of potential H2-generating rocks in its basement such as large iron formations (BIFs) radioactive rocks and basic and ultrabasic rocks. Additionally the Norte Basin exhibits potential efficient cap rocks including basalts and dolerites with geological analogies to the Mali field. Indirect evidence of H2 in a free gas phase has been observed in the western Norte Basin. This suggests the presence of a potential H2 system in this area linked to the Arapey Formation basalts (seal) and Mesozoic sandstones (reservoir). Furthermore the proposed H2 system could expand exploration opportunities in northeastern Argentina and southern Brazil given the potential presence of similar play/tramp.
O&G, Geothermal Systems, and Natural Hydrogen Well Drilling: Market Analysis and Review
Mar 2025
Publication
Developing clean and renewable energy instead of the ones related to hydrocarbon resources has been known as one of the different ways to guarantee reduced greenhouse gas emissions. Geothermal systems and native hydrogen exploration could represent an opportunity to diversify the global energy matrix and lower carbon-related emissions. All of these natural energy sources require a well to be drilled for its access and/or extractions similar to the petroleum industry. The main focuses of this technical–scientific contribution and research are (i) to evaluate the global energy matrix; (ii) to show the context over the years and future perspectives on geothermal systems and natural hydrogen exploration; and (iii) to present and analyze the importance of developing technologies on drilling process optimization aiming at accessing these natural energy resources. In 2022 the global energy matrix was composed mainly of nonrenewable sources such as oil natural gas and coal where the combustion of fossil fuels produced approximately 37.15 billion tons of CO2 in the same year. In 2023 USD 1740 billion was invested globally in renewable energy to reduce CO2 emissions and combat greenhouse gas emissions. In this context currently about 353 geothermal power units are in operation worldwide with a capacity of 16335 MW. In addition globally there are 35 geothermal power units under pre-construction (project phase) 93 already being constructed and recently 45 announced. Concerning hydrogen the industry announced 680 large-scale project proposals valued at USD 240 billion in direct investment by 2030. In Brazil the energy company Petroleo Brasileiro SA (Petrobras Rio de Janeiro Brazil) will invest in the coming years nearly USD 4 million in research involving natural hydrogen generation and since the exploration and access to natural energy resources (oil and gas natural hydrogen and geothermal systems among others) are achieved through the drilling of wells this document presents a technical–scientific contextualization of social interest.
Evaluation of Technological Alternatives for the Energy Transition of Coal-Fired Power Plants, with a Multi-Criteria Approach
Aug 2025
Publication
This paper investigates technological pathways for the conversion of coal-fired power plants toward sustainable energy sources using an integrated multi-criteria decisionmaking approach that combines Proknow-C AHP and PROMETHEE. Eight alternatives were identified: full conversion to natural gas full conversion to biomass coal and natural gas hybridization coal and biomass hybridization electricity and hydrogen cogeneration coal and solar energy hybridization post-combustion carbon capture systems and decommissioning with subsequent reuse. The analysis combined bibliographic data (26 scientific articles and 13 patents) with surveys from 14 energy experts using Total Decision version 1.2.1041.0 and Visual PROMETHEE version 1.1.0.0 software tools. Based on six criteria (environmental structural technical technological economic and social) the most viable option was full conversion to natural gas (ϕ = +0.0368) followed by coal and natural gas hybridization (ϕ = +0.0257) and coal and solar hybridization (ϕ = +0.0124). These alternatives emerged as the most balanced in terms of emissions reduction infrastructure reuse and cost efficiency. In contrast decommissioning (ϕ = −0.0578) and carbon capture systems (ϕ = −0.0196) were less favorable. This study proposes a structured framework for strategic energy planning that supports a just energy transition and contributes to the United Nations Sustainable Development Goals (SDGs) 7 and 13 highlighting the need for public policies that enhance the competitiveness and scalability of sustainable alternatives.
Combustion and Specific Fuel Consumption Evaluation of a Single-cylinder Engine Fueled with Ethanol, Gasoline, and a Hydrogen-rich Mixture
Mar 2024
Publication
This study evaluates the effects of adding a hydrogen gaseous mixture (HGM) to primary fuel in a single cylinder research engine (SCRE). Storage and transportation of high-purity hydrogen limit the application of this gas. With the development of fuel reforming methods using hydrogenenriched mixtures in spark-ignited internal combustion engines is a convenient option to fossil fuels. Ethanol and gasoline were used as primary fuel by direct injection (DI) and gaseous mixture was added by fumigation system (FS). The experimental analysis was developed in Spark Ignition (SI) four-stroke engine 4 valves and 0.45 L of cubic capacity. For each operation condition and primary fuel spark timing and amount of HGM were adjusted in order to keep air-fuel ratio stochiometric (λ = 100). However the spark timing and the percentage of gas varied aiming to evaluate the behavior of the air-fuel mixture. It was evaluated the specific fuel consumption and the evolution of the combustion process. The results showed that the addition of reformed gas promotes acceleration of the combustion process ethanol and gasoline. Results were expressive when using ethanol. A reduction in fuel-specific consumption - for this fuel - with combustion centralized which did not occur when gasoline was employed.
Detonation Processes Application to Increase Thermal Efficiency in Gas Turbine Cycles: Case Study for Hydrogen Enriched Fuels
Dec 2024
Publication
This work describes a thermodynamic comparison of the thermal efficiency of gas turbine engines featuring a conventional combustion chamber and a detonation combustion chamber using methane ethanol and mixtures of both ethanol and hydrogen and methane and hydrogen as fuels. The composition of gases was determined by the minimization of the Gibbs free energy whereas temperature pressure and velocity of detonation waves were determined by the Chapman-Jouguet theory. The results obtained here show that the DCC gas turbine cycle has a higher net work output and thermal efficiency than the CCC gas turbine cycle for all fuels studied in this work. The maximum thermal efficiency obtained with the DCC gas turbine cycle is indeed 57.22% which represents a 53.75% improvement over the maximum thermal efficiency obtained with the CCC gas turbine cycle (which has a peak thermal efficiency of 37.22%) under the same pressure ratio and turbine inlet temperature.
Hydrogen in Burners: Economic and Environmental Implications
Nov 2024
Publication
For centuries fossil fuels have been the primary energy source but their unchecked use has led to significant environmental and economic challenges that now shape the global energy landscape. The combustion of these fuels releases greenhouse gases which are critical contributors to the acceleration of climate change resulting in severe consequences for both the environment and human health. Therefore this article examines the potential of hydrogen as a sustainable alternative energy source capable of mitigating these climate impacts. It explores the properties of hydrogen with particular emphasis on its application in industrial burners and furnaces underscoring its clean combustion and high energy density in comparison to fossil fuels and also examines hydrogen production through thermochemical and electrochemical methods covering green gray blue and turquoise pathways. It discusses storage and transportation challenges highlighting methods like compression liquefaction chemical carriers (e.g. ammonia) and transport via pipelines and vehicles. Hydrogen combustion mechanisms and optimized burner and furnace designs are explored along with the environmental benefits of lower emissions contrasted with economic concerns like production and infrastructure costs. Additionally industrial and energy applications safety concerns and the challenges of large-scale adoption are addressed presenting hydrogen as a promising yet complex alternative to fossil fuels.
Hydrogen Balloon Transportation: A Cheap and Efficiency Mode to Transport Hydrogen
Nov 2023
Publication
The chances of a global hydrogen economy becoming a reality have increased significantly since the COVID pandemic and the war in Ukraine and for net zero carbon emissions. However intercontinental hydrogen transport is still a major issue. This study suggests transporting hydrogen as a gas at atmospheric pressure in balloons using the natural flow of wind to carry the balloon to its destination. We investigate the average wind speeds atmospheric pressure and temperature at different altitudes for this purpose. The ideal altitudes to transport hydrogen with balloons are 10 km or lower and hydrogen pressures in the balloon vary from 0.25 to 1 bar. Transporting hydrogen from North America to Europe at a maximum 4 km altitude would take around 4.8 days on average. Hydrogen balloon transportation cost is estimated at 0.08 USD/kg of hydrogen which is around 12 times smaller than the cost of transporting liquified hydrogen from the USA to Europe. Due to its reduced energy consumption and capital cost in some locations hydrogen balloon transportation might be a viable option for shipping hydrogen compared to liquefied hydrogen and other transport technologies.
Life Cycle Assessment and Exergoenvironmental Analysis of a Double-Effect Vapor Absorption Chiller Using Green Hydrogen, Natural Gas, and Biomethane
Dec 2024
Publication
This study conducts a life cycle assessment and exergoenvironmental evaluation of a double-effect vapor absorption chiller (DEAC) with a cooling capacity of 352 kW employing three different energy sources: natural gas biomethane and green hydrogen. The main objectives of this paper are as follows: (i) provide an exergoenvironmental model for DEAC technologies (ii) evaluation of a case-study where a DEAC is used to cover the cooling demand of a specific university building in the Northeast of Brazil and (iii) evaluate the scenario where the DEAC is fed by green hydrogen (GH2) and compare it with conventional energy resources (natural gas and biomethane). In order to develop the exergoenvironmental model two methodologies are essential: a thermodynamic analysis and a Life Cycle Assessment (LCA). The thermodynamic analysis was carried out using the Engineering Equation Solver (EES: 10.998) software. The LCA has been developed through the open-source software openLCA version 1.10.3 with the Ecoinvent 3.7.1 life cycle inventory database whereas the chosen life cycle inventory assessment (LCIA) method was the ReCiPe Endpoint LCA method (Humanitarian medium weighting–H A). The main results indicate that green hydrogen provides a 99.84% reduction in environmental impacts compared to natural gas during the operational phase while biomethane reduces these impacts by 54.21% relative to natural gas. In the context of life cycle assessment (LCA) green hydrogen decreases fossil resource depletion by 18% and climate change-related emissions by 33.16% compared to natural gas. This study contributes to enhancing the understanding of the environmental and exergoenvironmental impacts of a double-effect vapor absorption chiller by varying the fuel usage during the operational phase.
Use of Depleted Oil and Gas Reservoirs as Bioreactors to Produce Hydrogen and Capture Carbon Dioxide
Aug 2025
Publication
The biological production of hydrogen offers a renewable and potentially sustainable alternative for clean energy generation. In Northeast Brazil depleted oil reservoirs (DORs) present a unique opportunity to integrate biotechnology with existing fossil fuel infrastructure. These subsurface formations rich in residual hydrocarbons (RH) and native H2 producing microbiota can be repurposed as bioreactors for hydrogen production. This process often referred to as “Gold Hydrogen” involves the in situ microbial conversion of RH into H2 typically via dark fermentation and is distinct from green blue or grey hydrogen due to its reliance on indigenous subsurface biota and RH. Strategies include nutrient modulation and chemical additives to stimulate native hydrogenogenic genera (Clostridium Petrotoga Thermotoga) or the injection of improved inocula. While this approach has potential environmental benefits such as integrated CO2 sequestration and minimized surface disturbance it also presents risks namely the production of CO2 and H2S and fracturing which require strict monitoring and mitigation. Although infrastructure reuse reduces capital expenditures achieving economic viability depends on overcoming significant technical operational and biotechnological challenges. If widely applied this model could help decarbonize the energy sector repurpose legacy infrastructure and support the global transition toward low-carbon technologies.
Evaluating the Economic Influence of Water Sources on Green Hydrogen Production: A Cost Analysis Approach
Sep 2024
Publication
The production of green hydrogen requires significant water usage making the economic evaluation of different water sources crucial for optimizing the Levelized Cost of Hydrogen (LCOH). This study examines the economic impact of using seawater groundwater grid water industrial wastewater and rainwater for hydrogen production through PEM electrolysis considering the water abstraction transport treatment and storage costs across various plant sizes (1 MW 10 MW 20 MW 50 MW and 100 MW) were assessed and a sensitivity analysis on electricity prices was conducted. Findings reveal that while water-related costs are minimal.
A Systematic Study on Techno-Economic Evaluation of Hydrogen Production
Sep 2023
Publication
This paper aims to perform a systematic review with a bibliometric approach of the technoeconomic evaluation studies of hydrogen production. To achieve this objective a comprehensive outline of hydrogen production processes from fossil and renewable sources is presented. The results reveal that electrolysis classified as water splitting is the most investigated process in the literature since it contributes to a reduction in greenhouse gas emissions and presents other advantages such as maturity and applicability energy efficiency flexibility and energy storage potential. In addition the processes of gasification classified as thermochemical and steam reforming classified as catalytic reforming are worth mentioning. Regarding the biological category there is a balance between research on photo fermentation and dark fermentation. The literature on the techno-economic evaluation of hydrogen production highlights significant gaps including a scarcity of comprehensive studies a lack of emphasis on commercial viability an absence of sensitivity analysis and the need for comparative analyses between production technologies.
An Updated Review of Recent Applications and Perspectives of Hydrogen Production from Biomass by Fermentation: A Comprehensive Analysis
Mar 2024
Publication
Dayana Nascimento Dari,
Isabelly Silveira Freitas,
Francisco Izaias da Silva Aires,
Rafael Leandro Fernandes Melo,
Kaiany Moreira dos Santos,
Patrick da Silva Sousa,
Paulo Gonçalves de Sousa Junior,
Antônio Luthierre Gama Cavalcante,
Francisco Simão Neto,
Jessica Lopes da Silva,
Érico Carlos de Castro,
Valdilane Santos Alexandre,
Ana M. da S. Lima,
Juliana de França Serpa,
Maria C. M. de Souza and
José C. S. dos Santos
Fermentation is an oxygen-free biological process that produces hydrogen a clean renewable energy source with the potential to power a low-carbon economy. Bibliometric analysis is crucial in academic research to evaluate scientific production identify trends and contributors and map the development of a field providing valuable information to guide researchers and promote scientific innovation. This review provides an advanced bibliometric analysis and a future perspective on fermentation for hydrogen production. By searching WoS we evaluated and refined 62087 articles to 4493 articles. This allowed us to identify the most important journals countries institutions and authors in the field. In addition the ten most cited articles and the dominant research areas were identified. A keyword analysis revealed five research clusters that illustrate where research is progressing. The outlook indicates that a deeper understanding of microbiology and support from energy policy will drive the development of hydrogen from fermentation.
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