Canada
Development of Effective Hydrogen Production and Process Electrification Systems to Reduce the Environmental Impacts of the Methanol Production Process
Jun 2025
Publication
The methanol industry responsible for around 10% of GHG emissions in the chemical sector faces growing challenges due to its environmental impacts. This article aims to reduce the lifecycle environmental impacts of the CO2-to-methanol process by exploring advanced electrification methods for hydrogen production and CO2 conversion. The process analysis and comprehensive life cycle assessment (LCA) are conducted on four different methanol production pathways: conventional natural gas CO2 hydrogenation trireforming of methane (TRM) and the novel electrified combined reforming (ECRM) by including two hydrogen production routes: PEM electrolysis and the innovative plasma-assisted methane pyrolysis. The LCA was performed using the ReCiPe method covering midpoint and endpoint categories across four Canadian provinces—British Columbia Alberta Ontario and Quebec. The efficient plasma technology improves environmental performance for all pathways. The plasma-assisted CO2 hydrogenation pathway in British Columbia and Quebec shows the lowest GHG emissions achieving -2.01 and -1.72 kg CO2/kg MeOH respectively. In Alberta the conventional pathway has the lowest impact followed by plasmaassisted TRM. The CO2 hydrogenation with the PEM pathway shows the highest GHG emissions at 8.00 kg CO2/kg MeOH highlighting the challenges of using hydrogen from PEM electrolysis in regions with carbon-intensive electricity grids. However the inclusion of carbon black as a byproduct further reduces the environmental impact making these plasma-assisted pathways more viable. This LCA study underscores the influence of regional factors and technology choices on the sustainability of methanol production with an example of a 107% reduction in GHG emissions when plasma-assisted ECRM is shifting from Alberta to Quebec.
Evaluation of Green and Blue Hydrogen Production Potential in Saudi Arabia
Sep 2024
Publication
The Kingdom of Saudi Arabia has rich renewable energy resources specifically wind and solar in addition to geothermal beside massive natural gas reserves. This paper investigates the potential of both green and blue hydrogen production for five selected cities in Saudi Arabia. To accomplish the said objective a techno-economic model is formulated. Four renewable energy scenarios are evaluated for a total of 1.9 GW installed capacity to reveal the best scenario of Green Hydrogen Production (GHP) in each city. Also Blue Hydrogen Production (BHP) is investigated for three cases of Steam Methane Reforming (SMR) with different percentages of carbon capture. The economic analysis for both GHP and BHP is performed by calculating the Levelized Cost of Hydrogen (LCOH) and cash flow. The LCOH for GHP range for all cities ($3.27/kg -$12.17/kg)) with the lowest LCOH is found for NEOM city (50% PV and 50% wind) ($3.27/kg). LCOH for BHP are $0.534/kg $0.647/kg and $0.897/kg for SMR wo CCS/U SMR 55% CCS/U and SMR 90% CCS/U respectively.
Development of a Novel Renewable Energy-based Integrated System Coupling Biomass and H2S Sources for Clean Hydrogen Production
Oct 2024
Publication
The present work aims to develop a novel integrated energy system to produce clean hydrogen power and biochar. The Palmaria palmata a type of seaweed and hydrogen sulfide from the industrial gaseous waste streams are taken as potential feedstock. A combined thermochemical approach is employed for the processing of both feedstocks. For clean hydrogen production the zinc sulfide thermochemical cycle is employed. Both stoichiometric and non-stoichiometric equilibrium-based models of the proposed plant design are developed in the Aspen Plus software and a comprehensive thermodynamic analysis of the system is also performed by evaluating energy and exergy efficiencies. The study further explores the modeling simulation and parametric analyses of various subsections to enhance the hydrogen and biochar production rate. The parametric analyses show that the first step of the thermochemical cycle (sulfurization reaction) follows stoichiometric pathway and the ZnO to H2S ratio of 1 represents the optimal point for reactant conversion. On the other hand the second step of the thermochemical cycle (regeneration reaction) does not follow a stoichiometric pathway and ZnS conversion of 12.87% is achieved at a high temperature of 1400oC. It is found that a hydrogen production rate of 0.71 mol/s is achieved with the introduction of 0.27 mol/s of H2S. The energy and exergy efficiencies of the zinc sulfide thermochemical cycle are found to be 65.23% and 35.58% respectively. A biochar production rate of 0.024 kg/s is obtained with the Palmaria palmata fed rate of 0.097 kg/s. The Palmaria to biochar energy and exergy efficiencies are found to be 55.43% and 45.91% respectively. The overall energy and exergy efficiencies of the proposed plant are determined to be 72.88% and 50.03% respectively.
A Review of Hydrogen Leak Detection Regulations and Technologies
Aug 2024
Publication
Hydrogen (H2 ) is positioned as a key solution to the decarbonization challenge in both the energy and transportation sectors. While hydrogen is a clean and versatile energy carrier it poses significant safety risks due to its wide flammability range and high detonation potential. Hydrogen leaks can occur throughout the hydrogen value chain including production storage transportation and utilization. Thus effective leak detection systems are essential for the safe handling storage and transportation of hydrogen. This review aims to survey relevant codes and standards governing hydrogen-leak detection and evaluate various sensing technologies based on their working principles and effectiveness. Our analysis highlights the strengths and limitations of the current detection technologies emphasizing the challenges in achieving sensitive and specific hydrogen detection. The results of this review provide critical insights into the existing technologies and regulatory frameworks informing future advancements in hydrogen safety protocols.
Synergy-based Hydrogen Pricing in Hydrogen-Integrated Electric Power System: Sensititivy Analysis
Nov 2024
Publication
Hydrogen price significantly impacts its potential as a viable alternative in the sustainable energy transition. This study introduces a synergy-based Hydrogen Pricing Mechanism (HPM) within an integrated framework. The HPM leverages synergy between a Renewable-Penetrated Electric Power System (RP-EPS) and a Hydrogen Energy System (HES). Utilizing the Alternating Direction Method of Multipliers (ADMM) it facilitates data exchange quantifying integration levels and simplifying the complexities. The study assesses the HPM’s operational sensitivity across various scenarios of hydrogen generation transportation and storage. It also evaluates the benefits of synergy-based versus stand-alone HPMs. Findings indicate that the synergy-based HPM effectively integrates infrastructure and operational improvements from both EPS and HES leading to optimized hydrogen pricing.
Optimizing Sustainable Energy Systems: A Comparative Study of Geothermal-powered Desalination for Green Hydrogen Production
Oct 2024
Publication
The synergy between hydrogen and water is crucial in moving towards a sustainable energy future. This study explores the integration of geothermal energy with desalination and hydrogen production systems to address water and clean energy demands. Two configurations one using multi-effect distillation (MED) and the other reverse osmosis (RO) were designed and compared. Both configurations utilized geothermal energy with MED directly using geothermal heat and RO converting geothermal energy into electricity to power desalination. The systems are evaluated based on various performance indicators including net power output desalinated water production hydrogen production exergy efficiency and levelized costs. Multi-objective optimization using an artificial neural network (ANN) and genetic algorithm (GA) was conducted to identify optimal operational conditions. Results highlighted that the RO-based system demonstrated higher water production efficiency achieving a broader range of optimal solutions and lower levelized costs of water (LCOW) and hydrogen production while the MED-based system offered economic advantages under specific conditions. A case study focused on Canada illustrated the potential benefits of these systems in supporting hydrogen-powered vehicles and residential water needs emphasizing the significant impact of using high-quality desalinated water to enhance the longevity and efficiency of proton exchange membrane electrolyzers (PEME). This research provides valuable insights into the optimal use of geothermal energy for sustainable water and hydrogen production.
Environmental Implications of Solid Oxide Fuel Cell System for Hydrogen Sustainability
Jan 2025
Publication
Hydrogen known for its high energy content and clean combustion is promising in the energy transition. This study explores the environmental impact of a solid oxide fuel cell (SOFC) system. 1 kg of hydrogen production at 1 bar serves as the functional unit. The SOFC system generates hydrogen electricity and heat across five modes. Results indicate that the SOFC system achieves a global warming potential of 0.17–9.50 kg CO2 -eq/FU using the system expansion method. Regional analysis shows that areas with high renewable electricity shares experience increased CO2 emissions due to functional unit decision. The exergy allocation method is less sensitive to electricity sources and seasonal emission profiles than system expansion. Comparing eight production routes the SOFC system using biomethane (−5.46 kg CO2 -eq/FU) outperforms steam methane reforming (11 kg CO2 -eq/FU) and biomass gasification (1.49 kg CO2 -eq/FU). These insights are valuable for advancing renewable energy initiatives and effectively mitigating climate change.
Optimization of the Design of Underground Hydrogen Storage in Salt Caverns in Southern Ontario, Canada
Jan 2025
Publication
With the issue of energy shortages becoming increasingly serious the need to shift to sustainable and clean energy sources has become urgent. However due to the intermittent nature of most renewable energy sources developing underground hydrogen storage (UHS) systems as backup energy solutions offers a promising solution. The thick and regionally extensive salt deposits in Unit B of Southern Ontario Canada have demonstrated significant potential for supporting such storage systems. Based on the stratigraphy statistics of unit B this study investigates the feasibility and stability of underground hydrogen storage (UHS) in salt caverns focusing on the effects of cavern shape geometric parameters and operating pressures. Three cavern shapes—cylindrical cone-shaped and ellipsoid-shaped—were analyzed using numerical simulations. Results indicate that cylindrical caverns with a diameter-to-height ratio of 1.5 provide the best balance between storage capacity and structural stability while ellipsoid-shaped caverns offer reduced stress concentration but have less storage space posing practical challenges during leaching. The results also indicate that the optimal pressure range for maintaining stability and minimizing leakage lies between 0.4 and 0.7 times the vertical in situ stress. Higher pressures increase storage capacity but lead to greater stress displacements and potential leakage risks while lower pressure leads to internal extrusion tendency for cavern walls. Additionally hydrogen leakage rate drops with the maximum working pressure yet total leakage mass keeps a growing trend.
An Advanced Design to Generate Power and Hydrogen with CO2 Capturing and Storage for Cleaner Applications
Nov 2024
Publication
The present study aims to conduct a thermodynamic analysis of a novel concept that synergistically integrates clean hydrogen and power production with a liquified natural gas (LNG) regasification system. The designed integrated energy system aims to achieve hydrogen production power production liquified natural gas regasification carbon capture storage and in situ recirculation. Hydrogen sulfide (H2S) from industrial waste streams is used as a major feedstock and filtration combustion of H2S is employed as a hydrogen production method. CO2 obtained from the combustion process is liquified and pumped at a high pressure to recirculated back to the CO2 cycle power generation combustion process. The flu gas obtained after expansion on the turbine is condensed and CO2 is captured and pressurized. The entire plant is simulated in the Aspen Plus simulation environment and a comprehensive thermodynamic assessment including the energy and exergy analysis is conducted. Additionally several parametric studies and assessments of various factors influencing the system's performance are conducted. From the sensitivity analyses it is found that at 20% CO2 recirculation the hydrogen production rate decreases by 31.81% when the operating pressure is increased from 0.05 bar to 3 bar. The adiabatic temperature is reduced by 39.72% 35.37% and 32.85% when 50% 60% and 70% CO2 is recirculated in the oxidant stream at an oxygen to natural gas (ONG) ratio of 0.5. The energy and exergy efficiencies of the system are found to be 71.48% and 60.69% respectively. The present system avoids 2571.94 tons/yr of CO2 emissions for clean hydrogen production and 1426.27 tons/yr of CO2 for clean power production which would otherwise be emitted from steam methane reforming and coal gasification.
Look-ahead Scheduling of Energy-Water Nexus Integrated with Power2X Conversion Technologies under Multiple Uncertainties
Aug 2023
Publication
Co-optimizing energy and water resources in a microgrid can increase efficiency and improve economic performance. Energy-water storage (EWS) devices are crucial components of a high-efficient energy-water microgrid (EWMG). The state of charge (SoC) at the end of the first day of operation is one of the most significant variables in EWS devices since it is used as a parameter to indicate the starting SoC for the second day which influences the operating cost for the second day. Hence this paper examines the benefits and applicability of a lookahead optimization strategy for an EWMG integrated with multi-type energy conversion technologies and multienergy demand response to supply various energy-water demands related to electric/hydrogen vehicles and commercial/residential buildings with the lowest cost for two consecutive days. In addition a hybrid info-gap/robust optimization technique is applied to cover uncertainties in photovoltaic power and electricity prices as a tri-level optimization framework without generating scenarios and using the probability distribution functions. Duality theory is also used to convert the problem into a single-level MILP so that it can be solved by CPLEX. According to the findings the implemented energy-water storage systems and look-ahead strategy accounted for respectively 4.03% and 0.43% reduction in the total cost.
Advances in Hospital Energy Systems: Genetic Algorithm Optimization of a Hybrid Solar and Hydrogen Fuel Cell Combined Heat and Power
Sep 2024
Publication
This paper presents an innovative Fuel Cell Combined Heat and Power (FC–CHP) system designed to enhance energy efficiency in hospital settings. The system primarily utilizes solar energy captured through photovoltaic (PV) panels for electricity generation. Excess electricity is directed to an electrolyzer for water electrolysis producing hydrogen which is stored in high-pressure tanks. This hydrogen serves a dual purpose: it fuels a boiler for heating and hot water needs and powers a fuel cell for additional electricity when solar production is low. The system also features an intelligent energy management system that dynamically allocates electrical energy between immediate consumption hydrogen production and storage while also managing hydrogen release for energy production. This study focuses on optimization using genetic algorithms to optimize key components including the peak power of photovoltaic panels the nominal power of the electrolyzer fuel cell and storage tank sizes. The objective function minimizes the sum of investment and electricity costs from the grid considering a penalty coefficient. This approach ensures optimal use of renewable energy sources contributing to energy efficiency and sustainability in healthcare facilities.
Enabling Safe and Sustainable Hydrogen Mobility: Circular Economy-Driven Management of Hydrogen Vehicle Safety
Sep 2023
Publication
Hydrogen vehicles encompassing fuel cell electric vehicles (FCEVs) are pivotal within the UK’s energy landscape as it pursues the goal of net-zero emissions by 2050. By markedly diminishing dependence on fossil fuels FCEVs including hydrogen vehicles wield substantial influence in shaping the circular economy (CE). Their impact extends to optimizing resource utilization enabling zero-emission mobility facilitating the integration of renewable energy sources supplying adaptable energy storage solutions and interconnecting diverse sectors. The widespread adoption of hydrogen vehicles accelerates the UK’s transformative journey towards a sustainable CE. However to fully harness the benefits of this transition a robust investigation and implementation of safety measures concerning hydrogen vehicle (HV) use are indispensable. Therefore this study takes a holistic approach integrating quantitative risk assessment (QRA) and an adaptive decision-making trial and evaluation laboratory (DEMATEL) framework as pragmatic instruments. These methodologies ensure both the secure deployment and operational excellence of HVs. The findings underscore that the root causes of HV failures encompass extreme environments material defects fuel cell damage delivery system impairment and storage system deterioration. Furthermore critical driving factors for effective safety intervention revolve around cultivating a safety culture robust education/training and sound maintenance scheduling. Addressing these factors is pivotal for creating an environment conducive to mitigating safety and risk concerns. Given the intricacies of conducting comprehensive hydrogen QRAs due to the absence of specific reliability data this study dedicates attention to rectifying this gap. A sensitivity analysis encompassing a range of values is meticulously conducted to affirm the strength and reliability of our approach. This robust analysis yields precise dependable outcomes. Consequently decision-makers are equipped to discern pivotal underlying factors precipitating potential HV failures. With this discernment they can tailor safety interventions that lay the groundwork for sustainable resilient and secure HV operations. Our study navigates the intersection of HVs safety and sustainability amplifying their importance within the CE paradigm. Using the careful amalgamation of QRA and DEMATEL methodologies we chart a course towards empowering decision-makers with the insights to steer the hydrogen vehicle domain to safer horizons while ushering in an era of transformative eco-conscious mobility.
Investigation of a Community-based Clean Energy System Holistically with Renewable and Hydrogen Energy Options for Better Sustainable Development
Jan 2024
Publication
This study develops a novel community-based integrated energy system where hydrogen and a combination of renewable energy sources are considered uniquely for implementation. In this regard three different communities situated in Kenya the United States and Australia are studied for hydrogen production and meeting the energy demands. To provide a variety of energy demands this study combines a multigenerational geothermal plant with a hybrid concentrated solar power and photovoltaic solar plant. Innovations in hydrogen production and renewable energy are essential for reducing carbon emissions. By combining the production of hydrogen with renewable energy sources this system seeks to move away from the reliance on fossil fuels and toward sustainability. The study investigates various research subjects using a variety of methods. The performance of the geothermal source is considered through energetic and exergetic thermodynamic analysis. The software System Advisor Model (SAM) and RETscreen software packages are used to analyze the other sub-systems including Concentrate Solar PV solar and Combined Heat and Power Plant. Australian American and Kenyan communities considered for this study were found to have promising potential for producing hydrogen and electricity from renewable sources. The geothermal output is expected to be 35.83 MW 122.8 MW for space heating 151.9 MW for industrial heating and 64.25 MW for hot water. The overall geothermal energy and exergy efficiencies are reported as 65.15% and 63.54% respectively. The locations considered are expected to have annual solar power generation and hydrogen production capacities of 158MW 237MW 186MW 235 tons 216 tons and 313 tons respectively.
Case Study: Quantitative Risk Assessment of Hydrogen Blended Natural Gas for an Existing Distribution Network and End-use Equipment in Fort Saskatchewan, Alberta
Sep 2023
Publication
In a first-of-its-kind project for Alberta ATCO Gas and Pipelines Ltd. (ATCO) began delivering a 5% blend of hydrogen (H2) in natural gas into a subsection of the existing Fort Saskatchewan natural gas distribution system (approximately 2100 customers). The project was commissioned in October 2022 with the intention of increasing the blend to 20% H₂ in 2023. As part of project due diligence ATCO in partnership with DNV undertook Quantitative Risk Assessments (QRAs) to understand any risks associated with the introduction of blended gas into its existing distribution system and to its customers. This paper describes key findings from the QRAs through the comparison of risks associated with H2 blended natural gas at concentrations of 5% and 20% H₂ and the current natural gas configuration. The impact of operating pressure and hydrogen blend composition formed a sensitivity study completed as part of this work. To provide context and to help interpret the results an individual risk (IR) level of 1 × 10-6 per year was utilised as a reference threshold for the limit of the ‘broadly acceptable’ risk level and juxtaposed against comparable risk scenarios. Although adding hydrogen increases the IR of ignited releases from mains services meters regulators and end user appliances the ignited release IR was always well below the broadly acceptable reference criterion for all operating pressures and blend cases considered as part of the project. The IR associated with carbon monoxide poisoning dominates the overall IR and the results demonstrate that the reduction in carbon monoxide poisoning associated with the introduction of H₂ blended natural gas negates any incremental risk associated with ignited releases due to H₂ blended gas. The paper also explains how the results of the QRA were incorporated into Engineering Assessments as per the requirements of CSA Z662:19 [1] to justify the conversion of existing natural gas infrastructure to H₂ blended gas infrastructure.
Assessment of Fuel Switching as a Decarbonization Strategy in the Cement Sector
May 2024
Publication
Limiting global warming and the pursuit of a net-zero global society by 2050 emphasizes the need to transform the hard-to-abate industrial sectors. The cement sector is the second-largest source of global industrial emissions accounting for 8% of worldwide greenhouse gas emissions. Fuel switching in the cement sector is a decarbonization pathway that has not been explored in detail; previous studies involving fuel switching in the sector either view it from an energy efficiency lens or focus on a single technology. In this study a framework is developed to evaluate and directly compare six fuel switching options (including hydrogen biomass municipal solid waste and natural gas) from 2020 to 2050. Capital costs non-energy operating costs energy costs and carbon costs are used to calculate marginal abatement costs and emulate cost based-market decisions. The developed framework is used to conduct a case study for Canada using the LEAP-Canada model. This study shows that cumulative energy-related greenhouse gas emissions can be reduced by up to 21% between 2020 and 2050 with negative marginal abatement costs. Multiple fuel switching decarbonization pathways were established reducing the likelihood that locality prevents meaningful emissions reduction and suggesting that with low-carbon fuel and electricity policies the sector can take significant steps towards emissions reduction. The developed framework can be applied to jurisdictions around the world for decision making as nations move towards eliminating emissions from cement production.
Predictive Modelling of Hydrogen Production from Agricultural and Forestry Residues through a Thermo-catalytic Reforming Process
Sep 2025
Publication
Hydrogen produced from renewable sources is crucial for decarbonizing hard-to-abate sectors and achieving netzero targets. This study examines hydrogen production through the novel thermo-catalytic reforming (TCR) process using agricultural and forestry residues. The research aims to develop and optimize regression models that integrate feedstock properties (ash hydrogen-to-carbon molar ratio and lignin) and process parameters (reactor and reformer temperatures) to predict yields of hydrogen (H2) syngas methane (CH4) and carbon dioxide (CO2). Three biomass feedstocks – softwood pellets (SWPs) hardwood pellets (HWPs) and wheat straw pellets (WSPs) – were analyzed at reactor temperatures of 400–550 ◦C and reformer temperatures of 500–700 ◦C. Predictive models for H2 (R2 = 0.9642 RMSE = 1.0639) and syngas (R2 = 0.9894 RMSE = 0.0140) yields show strong agreement and accuracy between the predicted and experimental values. In contrast the models for CH4 and CO2 yields show higher variability in the predictions. Reformer temperature was the most significant parameter influencing the yields of H2 and syngas. The optimal H2 yields predicted for the model were obtained for HWPs at 550/700 ◦C (26.67 g H2/kg dry biomass) followed by SWPs at 550/700 ◦C (24.11 g H2/kg dry biomass) and WSPs at 550/685.2 ◦C (18.78 g H2/kg dry biomass). The volumetric syngas yields were highest for HWPs at 550/700 ◦C (0.831 Nm3 /kg dry biomass) followed by SWPs (0.777 Nm3 /kg dry biomass) and WSPs (0.634 Nm3 /kg dry biomass). This study demonstrates that regression modelling accurately predicts H2 and syngas yields which would help to expand the applicability of TCR technology for large-scale hydrogen production contributing to the decarbonization of the energy sector.
Techno-economic Analysis of a Renewable-based Hybrid Energy system for Utility and Transportation Facilities in a Remote Community of Northern Alberta
Jun 2023
Publication
Many off-grid communities in Canada are dependent on diesel generators to fulfill their utility and transportation needs causing destructive environmental impact. This study aims to optimize and investigate the technoeconomic feasibility of a hybrid renewable energy system to satisfy the 1.6 MWh/day electricity 184.2 kWh/day thermal and 428.38 kg/year hydrogen demand simultaneously Trout Lake a remote community of Northern Alberta. A novel hybrid energy system consisting of solar PV wind turbine electrolyzer hydrogen tank battery fuel cell hydrogen boiler and thermal load controller has been proposed to generate electricity heat and hydrogen by renewables which reduce carbon emission utilizing the excess energy (EE). Five different scenarios were developed in HOMER Pro software and the results were compared to identify the best combination of hybrid renewable energy systems. The results indicate that the fifth scenario is the optimal renewable energy system that provides a lower cost of energy (COE) at $0.675/kWh and can reduce 99.99% carbon emission compared to the diesel-based system. Additionally the utilization of thermal load controller battery and fuel cell improved the system’s reliability increasing renewable fraction (RF) (93.5%) and reducing EE (58.3%) significantly. In comparison to the diesel-based systems it is also discovered that battery energy storage is the most affordable option while fuel cells are the more expensive choice for remote community. Sensitivity analyses are performed to measure the impact of different dominating factors on COE EE and RF.
Analysis of Infrastructure Requirements for Sustainable Transportation Technologies
Jul 2025
Publication
At present transportation energy comes primarily from fossil fuels. In order to mitigate the effects of greenhouse gas emissions it is necessary to transition to low-carbon transportation technologies. These technologies can include battery electric vehicles fuel cell vehicles and biofuel vehicles. This transition includes not only the development and production of suitable vehicles but also the development of appropriate infrastructure. For example in the case of battery electric vehicles this infrastructure would include additional grid capacity for battery charging. For fuel cell vehicles infrastructure could include facilities for the production of suitable electrofuels which again would require additional grid capacity. In the present paper we look at some specific examples of infrastructure requirements for battery electric vehicles and vehicles using hydrogen and other electrofuels in either internal combustion engines or fuel cells. Analysis includes the necessary additional grid capacity energy storage requirements and land area associated with renewable energy generation by solar photovoltaics and wind. The present analysis shows that the best-case scenario corresponds to the use of battery electric vehicles powered by electricity from solar photovoltaics. This situation corresponds to a 47% increase in grid electricity generation and the utilization of 1.7% of current crop land.
Impact of Cell Design and Conditioning on Polymer Electrolyte Membrane Water Electrolyzer Operation
Nov 2024
Publication
Integration of polymer electrolyte membrane water electrolyzers (PEMWEs) for clean hydrogen generation requires a robust understanding of the impact cell designs and conditioning protocols have on operation and stability. Here catalyst-coated electrode and catalyst-coated membrane cells employing Pt/C cathode catalyst layer an IrO2 anode catalyst layer with a platinized titanium mesh or a carbon paper with a microporous layer as the porous transport layer were developed. The impact of cell conditioning above and below 0.25 A cm− 2 was investigated using advanced electrochemical impedance spectroscopy analyses and microscopic imaging with the electrochemical response related to physicochemical processes. Operation below 0.25 A cm− 2 prior to operation above 0.25 A cm− 2 resulted in anode corrosion and titanium cation contamination increasing the cell voltage at 1 A cm− 2 by 200 mV compared to uncontaminated cells. Conditioning above 0.25 A cm− 2 led to nonnegligible hydrogen transport resistances due to cathode flooding that resulted in a ca. 50 mV contribution at 1 A cm− 2 and convoluted with the anode impedance response. The presence of a microporous layer increased catalyst utilization but increased the cell voltage by 300 mV at 1 A cm− 2 due to increased anodic mass transport resistances. These results yield critical insights into the impact of PEMWE cell design and operation on corresponding cell performance and stability while highlighting the need for application dependent standardized operating protocols and operational windows.
Techno-economic Assessment of a Solar-powered Green Hydrogen Storage Concept Based on Reversible Solid Oxide Cells for Residential Micro-grid: A Case Study in Calgary
Feb 2025
Publication
Solar photovoltaic (PV)-based electricity production has gained significant attention for residential applications in recent years. However the sustainability and economic feasibility of PV systems are highly dependent on their grid-connected opportunities which may diminish with the increasing penetration of renewable energy sources into the grid. Therefore securing reliable energy storage is crucial for both grid-connected and off-grid PV-based residential facilities. Given the high capital costs and environmental issues associated with batteries hydrogen energy emerges as a superior option for medium to large residential applications. This paper proposes an innovative concept for PV-based green hydrogen production storage and utilization using solid oxide cells within residential micro-grids. It includes comprehensive techno-economic and environmental analyses of the proposed system utilizing dynamic solar data with a case study focusing on Calgary. The results indicate that seasonal hydrogen storage significantly enhances the feasibility of meeting the electricity demand of an off-grid residential community consisting of 525 households connected to a 4.6 MW solar farm. With the inclusion of Canadian clean hydrogen tax incentives the monthly cost per household is approximately $319 potentially decreasing to $239 with advancements in solid oxide cell technology and extended lifetimes of up to 80000 h. Furthermore implementing this system in Calgary could result in a monthly reduction of at least 250 kg of CO2 emissions per household.
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