Germany
Magnetically Induced Convection Enhances Water Electrolysis in Microgravity
Aug 2025
Publication
Since the early days of space exploration the efficient production of oxygen and hydrogen via water electrolysis has been a central task for regenerative life-support systems. Water electrolysers are however challenged by the near-absence of buoyancy in microgravity resulting in hindered gas bubble detachment from electrodes and diminished electrolysis efficiencies. Here we show that a commercial neodymium magnet enhances water electrolysis with current density improvements of up to 240% in microgravity by exploiting the magnetic polarization of the electrolyte and the magnetohydrodynamic force. We demonstrate that these interactions enhance gas bubble detachment and displacement through magnetic convection and achieve passive gas–liquid phase separation. Two model magnetoelectrolytic cells a proton-exchange membrane electrolyser and a magnetohydrodynamic drive were designed to leverage these forces and produce oxygen and hydrogen at near-terrestrial efficiencies in microgravity. Overall this work highlights achievable lightweight low-maintenance and energy-efficient phase separation and electrolyser technologies to support future human spaceflight architectures.
A Game Theory Approach in Hydrogen Supply Chain Resilience: Focus on Pricing, Sourcing, and Transmission Security
Jun 2025
Publication
This study examines the pricing and assesses resilience methods in hydrogen supply chains by thoroughly analyzing two main disruption scenarios. The model examines a scenario in which a hydrogen production company depends on a Renewable Power plant (RP) for its electricity supply. Ensuring a steady and efficient hydrogen supply chain is crucial but outages at renewable power sources provide substantial obstacles to sustainability and operational continuity. Therefore in the event of disruptions at the RP the company has two options for maintaining resilience: either sourcing electricity from a Fossil fuel Power plant (FP) through a grid network to continue hydrogen production or purchasing hydrogen directly from another company and utilizing third-party transportation for delivery. Using a game theoretic approach we examine how different methods affect demand satisfaction cost implications and environmental sustainability. The study employs sensitivity analysis to evaluate the impact of different disruption probabilities on each scenario. In addition a unique sensitivity analysis is performed to examine the resilience of transmission security to withstand disruptions. This study evaluates how investments in security measures affect the strength and stability of the supply chain in various scenarios of disruption. Our research suggests that the first scenario offers greater reliability and cost-effectiveness along with a higher resilience rate compared to the second scenario. Furthermore the examination of the environmental impact shows that the first scenario has a smaller amount of CO2 emissions per kg of hydrogen. This study offers important insights for supply chain managers to optimize resilience measures hence improving reliability reducing costs and minimizing environmental effects.
Working with Uncertainty in Life cycle Costing: New Approach Applied to the Case Study on Proton Exchange Membrane Water Electrolysis
Jul 2025
Publication
Hydrogen recognized as a critical energy source requires green production methods such as proton exchange membrane water electrolysis (PEMWE) powered by renewable energy. This is a key step toward sustainable development with economic analysis playing an essential role. Life cycle costing (LCC) is commonly used to evaluate economic feasibility but traditional LCC analyses often provide a single cost outcome which limits their applicability across diverse regional contexts. To address these challenges a Python-based tool is developed in this paper integrating a bottom-up approach with net present value (NPV) calculations and Monte Carlo simulations. The tool allows users to manage uncertainty by intervening in the input data producing a range of outcomes rather than a single deterministic result thus offering greater flexibility in decision-making. Applying the tool to a 5 MW PEMWE plant in Germany the total cost of ownership (TCO) is estimated to range between €52 million and €82.5 million with hydrogen production costs between 5.5 and 11.4 €/kg H2. There is a 95% probability that actual costs fall within this range. Sensitivity analysis reveals that energy prices are the key contributors to LCC accounting for 95% of the variance in LCC while iridium membrane materials and power electronics contribute to 75% of the variation in construction-phase costs. These findings underscore the importance of renewable energy integration and circular economy strategies in reducing LCC.
IEA TCP Task 43 - Recommendations for Safety Distances Methodology for Alkaline and PEM Electrolyzers
Sep 2025
Publication
Elena Vyazmina,
Richard Chang,
Benjamin Truchot,
Katrina M. Groth,
Samantha E. Wismer,
Sebastien Quesnel,
David Torrado,
Nicholas Hart,
Thomas Jordan,
Karen Ramsey-Idem,
Deborah Houssin-Agbomson,
Simon Jallais,
Christophe Bernard,
Lucie Bouchet,
Ricardo Ariel Perez,
Lee Phillips,
Marcus Runefors,
Jerome Hocquet and
Andrei V. Tchouvelev
Currently local regulations governing hydrogen installations vary by geographical region and by country leading to discrepancies in safety and separation distance requirements for similar hydrogen systems. This work carried out in the frame of IEA TCP H2 Task 43 (IEA TCP H2 2022) aims to provide an overview of various methodologies and recommendations established for risk management and consequence assessment in the event of accidental scenarios. It focuses on a case study involving industrial electrolyzers utilizing alkaline and PEM technologies. The research incorporates lessons learned from past incidents offers recommendations for mitigation measures reviews existing methodologies and highlights areas of divergence. Additionally it proposes strategies for harmonization. The study also emphasizes the most significant scenarios and the corresponding leakage sizes
Interactions Between Gas Hydrate and Hydrogen in Nature: Laboratory Evidence of Hydrogen Incorporation
Oct 2025
Publication
Natural hydrogen is generated via serpentinization radiolysis and organic metagenesis in geological settings. After expulsion from the source and along its upward migration path the free gas may encounter hydratebearing sediments. To simulate this natural scenario CH4 hydrate and CH4 + C3H8 hydrate were synthesized at 5.0 MPa and exposed to a hydrogen-containing gas mixture. In-situ Raman spectroscopic measurements demonstrated the incorporation of H2 molecules into the hydrate phase even at a partial pressure of 0.5 MPa. Exsitu Raman spectroscopic characterization of hydrates formed from a CH4 + H2 gas mixture at 5.0 MPa confirmed the H2 inclusion within the large cavities of structure I. The results show that the interactions between H2 and the natural gas hydrate phase range from the incorporation of H2 molecules into the hydrate phase to the rapid dissociation of the gas hydrate depending on thermodynamic conditions and H2 concentration in the coexisting gas phase.
Analysis of Specific Failure Conditions in Electrified Propulsion Systems using Cryogenic Hydrogen as a Primary Energy Carrier
Aug 2025
Publication
In order to minimize emissions of the aerospace sector and thus its impact on the climate several novel concepts of propulsion systems for aircraft are being developed. Many of these concepts do not use an energy source based on the combustion of hydrocarbons but other means of energy generation and storage like hydrogen fuel cells and corresponding hydrogen storage systems. The use of hydrogen as a primary energy carrier in aircraft poses novel and different hazards when compared to conventional propulsion and fuel storage systems. The study described in the present paper identifies analyzes and evaluates failure conditions and corresponding hazards that are associated with the electrified propulsion systems. Mitigation strategies to prevent failures to occur or decrease their severity are recommended. The effects of the assessed failures on aircraft crew and occupants are classified as catastrophic hazardous or major as defined in the according Certification Specifications. Failure Conditions occurring at the aircraft system and subsystem levels are considered and their effect on the aircraft and propulsion system is assessed. The hazards identified mostly emerge due to the properties of the gaseous or liquid hydrogen. They include the flammability of gaseous hydrogen and the very low temperatures of cryogenic liquid hydrogen as well as the installation of high voltage power infrastructure and high capacity heat exchangers.
A real Assessment in the Design of a Try-Out Grid-Tied Solar PV-Green Hydrogen-Battery Storage Microgrid System for Industrial Application in South Africa
Sep 2025
Publication
The carbon emission reduction mission requires a multifaceted approach in which green hydrogen is expected to play a key role. The accelerated adoption of green hydrogen technologies is vital to this journey towards carbon neutrality by 2050. However the energy transition involving green hydrogen requires a data-driven approach to ensure that the benefits are realised. The introduction of testing sites for green hydrogen technologies will be crucial in enabling the performance testing of various components within the green hydrogen value chain. This study involves an areal assessment of a selected test site for the installation of a grid-tied solar PV-green hydrogen-battery storage microgrid system at a factory facility in South Africa. The evaluation includes a site energy audit to determine the consumption profile and an analysis of the location’s weather pattern to assess its impact on the envisaged microgrid. Lastly a design of the microgrid is conceptualised. A 39 kW photovoltaic system powers the microgrid which comprises a 22 kWh battery storage system 10 kW of electrolyser capacity an 8 kW fuel cell and an 800 L hydrogen storage capacity between 30 and 40 bars.
Sequential System for Hydrogen and Methane Production from Sucrose Wastewater: Effects of Substrate Concentration and Addition of FE2+ Ions
Oct 2025
Publication
A two-stage system is used for hydrogen (H2) and methane (CH4) production from sucrose wastewater. The H2- producing reactor is operated at pH temperature (T) and hydraulic retention time (HRT) of 5.5 35 ◦C 24 h respectively. While operating conditions of 7–8 pH 35 ◦C T and 144 h HRT are used to conduct the CH4 production stage. The effects of two different parameters as sucrose concentration (5 10 and 20 g/L) and addition of ferrous ions (60 and 120 mg/L) are investigated. Both H2 and CH4 productions are increased at high sucrose concentrations. However the optimum H2 and CH4 yields of 163.2 mL-H2/g-sucrose and 211.8 mL-CH4/g-TVS are obtained at 5 g-sucrose/L. At 5 g-sucrose/L addition of Fe2+ increases the H2 yield to 192.5 and 176.2 mLH2/g-sucrose corresponding to 60 and 120 mg-Fe2+/L respectively. Higher removal efficiencies and total energy recovery are measured using the two-stage system than the single-stage reactor.
Comprehensive Experimental Assessment of NOx Emissions in Swirling Diffusion Flames of Natural Gas-hydrogen Blends
Oct 2025
Publication
In the transformation process from fossil-fuel based to carbon-neutral combustion full or partial replacement of natural gas with hydrogen is considered in numerous industrial applications. As hydrogen flames yield significantly higher NOX emissions than natural gas flames understanding what factors influence these emissions in flames of natural gas/hydrogen blends is crucial for the retrofitting process. Our work is concerned with the simplest form of industrial retrofitting where hydrogen is injected into the natural gas line without any modifications to the burner construction while keeping the burner power constant. We provide quantifications of NOX emissions with respect to changes in hydrogen content (pure natural gas to 100% hydrogen) swirl number (S=0.6 to S=1.4) excess air ratio ( = 1 to =4.5) and air preheat (ambient air to 300 ◦C). The changes were determined in small steps and over a large range. The emission data is to be used in industrial CFD for both validation and tuning therefore Laser Doppler Velocimetry was used for precise determination of the burner inlet conditions. Key findings of the investigation include that for hydrogen flames the NOX emission index [mg/kWh] is 1.2 to 3 times larger than for pure natural gas flames at similar firing conditions. The steepest increase in NOX emissions occurs above 75% volume fraction of hydrogen in the fuel. For natural gas flames NOX emissions peak at 1.3 to 1.4 excess air while the maximum for hydrogen and natural gas/hydrogen blends lays at =1.6. NOX emissions decrease slightly as the swirl number increases but this effect is minor in comparison to the effects of hydrogen content excess air ratio and air temperature.
In-service and Repair Welding of Pressurized Hydrogen Pipelines - A Review on Current Challenges and Strategies
Aug 2025
Publication
Hydrogen is the energy carrier for a sustainable future without fossil fuels. As this requires a reliable transportation infrastructure the conversion of existing natural gas (NG) grids is an essential part of the worldwide individual national hydrogen strategies in addition to newly erected pipelines. In view of the known effect of hydrogen embrittlement the compatibility of the materials already in use (typically low-alloy steels in a wide range of strengths and thicknesses) must be investigated. Initial comprehensive studies on the hydrogen compatibility of pipeline materials indicate that these materials can be used to a certain extent. Nevertheless the material compatibility for hydrogen service is currently of great importance. However pipelines require frequent maintenance and repair work. In some cases it is necessary to carry out welding work on pipelines while they are under pressure e.g. the well-known tapping of NG grids. This in-service welding brings additional challenges for hydrogen operations in terms of additional hydrogen absorption during welding and material compatibility. The challenge can be roughly divided into two parts: (1) the possible austenitization of the inner piping material exposed to hydrogen which can lead to additional hydrogen absorption and (2) the welding itself causes an increased temperature range. Both lead to a significantly increased hydrogen solubility in the respective materials compared to room temperature. In that connection the knowledge on hot tapping on hydrogen pipelines is rare so far due to the missing service experiences. Fundamental experimental investigations are required to investigate the possible transferability of the state-of-the-art concepts from NG to hydrogen pipeline grids. This is necessary to ensure that no critical material degradation occurs due to the potentially increased hydrogen uptake. For this reason the paper introduces the state of the art in pipeline hot tapping encompassing current research projects and their individual solution strategies for the problems that may arise for future hydrogen service. Methods of material testing their limitations and possible solutions will be presented and discussed.
Degradation Mechanisms of a Proton Exchange Membrane Water Electrolyzer Stack Operating at High Current Densities
Sep 2025
Publication
On the path to an emission free energy economy proton exchange membrane water electrolysis (PEMWE) is a promising technology for a sustainable production of green hydrogen at high current densities and thus high production rates. Long lifetime increasing the current density and the reduction of platinum group metal loadings are major challenges for a widespread implementation of PEMWE. In this context this work investigates the aging of a PEMWE stack operating at 4 A cm-2 which is twice the nominal current density of commercial electrolyzers. Specifically an 8-cells PEMWE stack using catalyst coated membranes (CCMs) with different platinum group metal (PGM) loading was operated for 2200 h. To understand degradation phenomena physical ex-situ analyses such as scanning electron microscopy (SEM) atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS) were carried out. The same aging mechanism were observed in all cells independent on their position in stack or the specific PGM loading of the membrane electrode assembly (CCM): (i) a decrease of ohmic resistance over time related to membrane thinning (ii) a significant loss of ionomer at anodes (iii) loss of noble metal from the electrodes leading to deposition of small Ir and Pt concentrations in the membrane (iv) heterogeneous enrichment of Ti on the cathode side likely originating from the cathode-side of the Ti bipolar plates (BPPs). These results are in good agreement with the electrochemical performance loss. Thus we were able to identify the degradation phenomena that dominate under high-current operation and their impact on performance.
A Two-Layer HiMPC Planning Framework for High-Renewable Grids: Zero-Exchange Test on Germany 2045
Oct 2025
Publication
High-renewables grids are planned in min but judged in milliseconds; credible studies must therefore resolve both horizons within a single model. Current adequacy tools bypass fast frequency dynamics while detailed simulators lack multi-hour optimization leaving investors without a unified basis for sizing storage shifting demand or upgrading transfers. We present a two-layer Hierarchical Model Predictive Control framework that links 15-min scheduling with 1-s corrective action and apply it to Germany’s four TSO zones under a stringent zero-exchange stress test derived from the NEP 2045 baseline. Batteries vehicleto-grid pumped hydro and power-to-gas technologies are captured through aggregators; a decentralized optimizer pre-positions them while a fast layer refines setpoints as forecasts drift; all are subject to inter-zonal transfer limits. Year-long simulations hold frequency within ±2 mHz for 99.9% of hours and below ±10 mHz during the worst multi-day renewable lull. Batteries absorb sub-second transients electrolyzers smooth surpluses and hydrogen turbines bridge week-long deficits—none of which violate transfer constraints. Because the algebraic core is modular analysts can insert new asset classes or policy rules with minimal code change enabling policy-relevant scenario studies from storage mandates to capacity-upgrade plans. The work elevates predictive control from plantscale demonstrations to system-level planning practice. It unifies adequacy sizing and dynamic-performance evaluation in a single optimization loop delivering an open scalable blueprint for high-renewables assessments. The framework is readily portable to other interconnected grids supporting analyses of storage obligations hydrogen roll-outs and islanding strategies.
Sensitivity Analysis of Geological Parameters to Evaluate Uncertainty in Underground Hydrogen Storage Performance for a Saline Aquifer at Ketzin (Germany)
May 2025
Publication
A numerical sensitivity analysis of a hydrogen pore storage system is carried out on a reservoir-scale geological model of the Ketzin site (Germany) to analyze the influence of uncertainty in geological parameters and fluid properties on storage performance. Therefore the following physical geological parameters and fluid properties were investigated: Porosity and permeability of the reservoir rock the brine salinity relative permeability and capillary pressure and mechanical dispersion. The range of the applied parameters is based on experimental and field data of the chosen location obtained during the former CO2 storage projects at the Ketzin site from 2008 to 2013. Using the open-source reservoir software MUFITS for the numerical simulations strong differences between the results can be observed. The results were evaluated based on measures to quantify performance such as the ratio of produced hydrogen mass to produced cushion gas (nitrogen) productivity index and sustainability index. The strongest impact on the performance parameters was observed with variations in the capillary pressure and the relative permeability curves followed by the absolute permeabilities while the least impact was seen with changes in the porosity and salinity of the brine. This work is not only crucial as a pre-feasibility study for the Ketzin storage site for hydrogen storage but also as a basis for decision-making for other potential storage sites in sedimentary basins.
Low-emission Hydrogen: Global Value Chain Opportunities for Latecomers and Industrial Policy Challenges
Jul 2025
Publication
To meet decarbonization targets demand for low-emission hydrogen is increasing. A considerable share of supply will come from latecomer countries. We study how latecomer countries and firms participate in the emerging global low-emission hydrogen economy and how industrial policies can help maximize societal benefits. This requires a specific conceptualization of industrial policy: First the latecomer condition calls for specific policy mixes as latecomers typically cannot build on established innovation systems and network externalities and rather need to combine FDI attraction with measures strengthening absorptive capacity and ensuring knowledge transfer from FDI to domestic firms; second low-emission hydrogen is a policy-induced alternative that requires creating entirely new firm ecosystems while competing with lower-cost emission-intensive incumbent technologies. Hence industrial policies need to account for enhanced coordination failure and internalization of environmental costs. We analyze the published national hydrogen strategies of 20 latecomer economies and derive a novel typology differentiating four hydrogen-specific industrial development pathways. For each pathway we assess entry barriers and risks identify the policies suggested in the country strategies and discuss how likely those are to be successful. The novel pathway typology and comparison of associated policy mixes may help policymakers maximize the gains of hydrogen investments.
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