Germany
Degradation Mechanisms of a Proton Exchange Membrane Water Electrolyzer Stack Operating at High Current Densities
Sep 2025
Publication
On the path to an emission free energy economy proton exchange membrane water electrolysis (PEMWE) is a promising technology for a sustainable production of green hydrogen at high current densities and thus high production rates. Long lifetime increasing the current density and the reduction of platinum group metal loadings are major challenges for a widespread implementation of PEMWE. In this context this work investigates the aging of a PEMWE stack operating at 4 A cm-2 which is twice the nominal current density of commercial electrolyzers. Specifically an 8-cells PEMWE stack using catalyst coated membranes (CCMs) with different platinum group metal (PGM) loading was operated for 2200 h. To understand degradation phenomena physical ex-situ analyses such as scanning electron microscopy (SEM) atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS) were carried out. The same aging mechanism were observed in all cells independent on their position in stack or the specific PGM loading of the membrane electrode assembly (CCM): (i) a decrease of ohmic resistance over time related to membrane thinning (ii) a significant loss of ionomer at anodes (iii) loss of noble metal from the electrodes leading to deposition of small Ir and Pt concentrations in the membrane (iv) heterogeneous enrichment of Ti on the cathode side likely originating from the cathode-side of the Ti bipolar plates (BPPs). These results are in good agreement with the electrochemical performance loss. Thus we were able to identify the degradation phenomena that dominate under high-current operation and their impact on performance.
A Two-Layer HiMPC Planning Framework for High-Renewable Grids: Zero-Exchange Test on Germany 2045
Oct 2025
Publication
High-renewables grids are planned in min but judged in milliseconds; credible studies must therefore resolve both horizons within a single model. Current adequacy tools bypass fast frequency dynamics while detailed simulators lack multi-hour optimization leaving investors without a unified basis for sizing storage shifting demand or upgrading transfers. We present a two-layer Hierarchical Model Predictive Control framework that links 15-min scheduling with 1-s corrective action and apply it to Germany’s four TSO zones under a stringent zero-exchange stress test derived from the NEP 2045 baseline. Batteries vehicleto-grid pumped hydro and power-to-gas technologies are captured through aggregators; a decentralized optimizer pre-positions them while a fast layer refines setpoints as forecasts drift; all are subject to inter-zonal transfer limits. Year-long simulations hold frequency within ±2 mHz for 99.9% of hours and below ±10 mHz during the worst multi-day renewable lull. Batteries absorb sub-second transients electrolyzers smooth surpluses and hydrogen turbines bridge week-long deficits—none of which violate transfer constraints. Because the algebraic core is modular analysts can insert new asset classes or policy rules with minimal code change enabling policy-relevant scenario studies from storage mandates to capacity-upgrade plans. The work elevates predictive control from plantscale demonstrations to system-level planning practice. It unifies adequacy sizing and dynamic-performance evaluation in a single optimization loop delivering an open scalable blueprint for high-renewables assessments. The framework is readily portable to other interconnected grids supporting analyses of storage obligations hydrogen roll-outs and islanding strategies.
Sensitivity Analysis of Geological Parameters to Evaluate Uncertainty in Underground Hydrogen Storage Performance for a Saline Aquifer at Ketzin (Germany)
May 2025
Publication
A numerical sensitivity analysis of a hydrogen pore storage system is carried out on a reservoir-scale geological model of the Ketzin site (Germany) to analyze the influence of uncertainty in geological parameters and fluid properties on storage performance. Therefore the following physical geological parameters and fluid properties were investigated: Porosity and permeability of the reservoir rock the brine salinity relative permeability and capillary pressure and mechanical dispersion. The range of the applied parameters is based on experimental and field data of the chosen location obtained during the former CO2 storage projects at the Ketzin site from 2008 to 2013. Using the open-source reservoir software MUFITS for the numerical simulations strong differences between the results can be observed. The results were evaluated based on measures to quantify performance such as the ratio of produced hydrogen mass to produced cushion gas (nitrogen) productivity index and sustainability index. The strongest impact on the performance parameters was observed with variations in the capillary pressure and the relative permeability curves followed by the absolute permeabilities while the least impact was seen with changes in the porosity and salinity of the brine. This work is not only crucial as a pre-feasibility study for the Ketzin storage site for hydrogen storage but also as a basis for decision-making for other potential storage sites in sedimentary basins.
Low-emission Hydrogen: Global Value Chain Opportunities for Latecomers and Industrial Policy Challenges
Jul 2025
Publication
To meet decarbonization targets demand for low-emission hydrogen is increasing. A considerable share of supply will come from latecomer countries. We study how latecomer countries and firms participate in the emerging global low-emission hydrogen economy and how industrial policies can help maximize societal benefits. This requires a specific conceptualization of industrial policy: First the latecomer condition calls for specific policy mixes as latecomers typically cannot build on established innovation systems and network externalities and rather need to combine FDI attraction with measures strengthening absorptive capacity and ensuring knowledge transfer from FDI to domestic firms; second low-emission hydrogen is a policy-induced alternative that requires creating entirely new firm ecosystems while competing with lower-cost emission-intensive incumbent technologies. Hence industrial policies need to account for enhanced coordination failure and internalization of environmental costs. We analyze the published national hydrogen strategies of 20 latecomer economies and derive a novel typology differentiating four hydrogen-specific industrial development pathways. For each pathway we assess entry barriers and risks identify the policies suggested in the country strategies and discuss how likely those are to be successful. The novel pathway typology and comparison of associated policy mixes may help policymakers maximize the gains of hydrogen investments.
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