France

Next generation of hydrogen energy based vehicles is expected to come into widespread use in the near future. Various topics related to hydrogen including production storage and application of hydrogen as an energy carrier have become subjects of discussion in the framework of various European and International projects. Safety information is vital to support the successful introduction into mainstream and public acceptance of hydrogen as an energy carrier. One of such issues which is seeking major attention is related to hydrogen powered vehicles parked inside a confined area (such as in a private garage). It is of utmost importance to predict if uncontrolled release of hydrogen from a vehicle parked inside a confined area can create an explosive atmosphere. Subsequently how the preventive measures can be implied to control these explosive atmospheres if present inside a confined area? There is a little guidance currently developed for confined areas accommodating hydrogen fuelled vehicles. It is essential that mitigation measures for such conditions become established.<br/>Characterization of different scenarios those may arise in a real situation from hydrogen fuelled vehicle parked inside a garage and furthermore the investigation of an optimal ventilation rate for hydrogen risk mitigation are some of the main objectives described in the framework of the present study. This work is an effort to provide detail experimental information’s in view of establishing guidelines for hydrogen powered vehicles parked inside a private garage. The present work is developed in the framework of a European Network of Excellence HySafe and French project DRIVE. Present paper describes a purpose built realistic Garage test facility at CEA to study the dispersion of hydrogen leakage. The studied test cases evaluate the influence of injected volumes of hydrogen and the initial conditions at the leakage source on the dispersion and mixing characteristics inside the free volume of the unventilated garage. The mixing process and build-up of hydrogen concentration is measured for the duration of 24 hours. Due to safety reasons helium gas is used to simulate the hydrogen dispersion characteristics.

INERIS has set up large-scale fully instrumented experiments to study the formation of flammable clouds resulting from a finite duration spillage of hydrogen in a quiescent room (80 m3 chamber). Concentration temperature and mass flow measurements were monitored during the release period and several hours after. Experiments were carried out for mass flow rates ranging from 02 g/s to 1 g/s. The instrumentation allowed the observation and quantification of rich hydrogen layers stratification effects. This paper presents both the experimental facility and the test results. These experimental results can be used to assess and benchmark CFD tools capabilities.

Polymer electrolyte membrane (PEM) water electrolysis has demonstrated its potentialities in terms of cell efficiency (energy consumption ≈ 4.0-4.2 kW/Nm3 H2) and gas purity (> 99.99% H2). Current research activities are aimed at increasing operating pressure up to several hundred bars for direct storage of hydrogen in pressurized vessels. Compared to atmospheric pressure electrolysis high-pressure operation yields additional problems especially with regard to safety considerations. In particular the rate of gases (H2 and O2) cross-permeation across the membrane and their water solubility both increase with pressure. As a result gas purity is affected in both anodic and cathodic circuits and this can lead to the formation of explosive gas mixtures. To prevent such risks two different solutions reported in this communication have been investigated. First the chemical modification of the solid polymer electrolyte in order to reduce cross-permeation phenomena. Second the use of catalytic H2/O2 recombiners to maintain H2 levels in O2 and O2 levels in H2 at values compatible with safety requirements.

The paper presents an overview of the main results of the EC NOE HySafe activity to estimate an allowable hydrogen permeation rate for automotive legal requirements and standards. The work was undertaken as part of the HySafe internal project InsHyde.<br/>A slow long term hydrogen release such as that due to permeation from a vehicle into an inadequately ventilated enclosed structure is a potential risk associated with the use of hydrogen in automotive applications. Due to its small molecular size hydrogen permeates through the containment materials found in compressed gaseous hydrogen storage systems and is an issue that requires consideration for containers with non-metallic (polymer) liners. Permeation from compressed gaseous hydrogen storage systems is a current hydrogen safety topic relevant to regulatory and standardisation activities at both global and regional levels.<br/>Various rates have been proposed in different draft legal requirements and standards based on different scenarios and the assumption that hydrogen dispenses homogeneously. This paper focuses on the development of a methodology by HySafe Partners (CEA NCSRD. University of Ulster and Volvo Technology) to estimate an allowable upper limit for hydrogen permeation in automotive applications by investigating the behaviour of hydrogen when released at small rates with a focus on European scenario. The background to the activity is explained. reasonable scenarios are identified a methodology proposed and a maximum hydrogen permeation rate from road vehicles into enclosed structures is estimated The work is based on conclusions from the experimental and numerical investigations described by CEA NCSRD and the University of Ulster in related papers.

In case of severe accidents in Pressurized Water Reactors a great amount of hydrogen can be released the resulting heterogeneous gaseous mixture (hydrogen-air-steam) can be flammable or inert and the pressure effects could alter the confinement of the reactor. Water spray systems have been designed in order to reduce overpressures in the containment but the presence of water droplets could enhance flame propagation through turbulence or generate flammable mixtures since the steam present in the vessel could condense on the droplets and could not inert the mixture anymore. However beneficial effects would be heat sinks and homogenization of mixtures. On-going work is devoted to the modelling of the interaction between fine water droplets and a hydrogen-air flame. We present in this paper an unsteady Lumped Parameter model in detail with a special focus on hydrogen-air flame propagation in the presence of water droplets. The effects of the initial concentration of droplets steam and hydrogen concentrations on flame propagation are discussed in the paper and a comparison between this model and our previous steady Lumped-Parameter model highlights the features of the unsteady approach. This physical model can serve as a validation tool for a CFD modelling. The results will be further validated against experimental data.

This paper deals with the build-up of concentration when a continuous source of helium is supplied in an air-filled enclosure. Our aim is to reproduce the results of a small-scale experimental study. To begin with the size of the experiment is reduced from 1/10 to 3/5 for the present analysis. Hypotheses are made in order to reduce the dimension of the real problem. Numerical simulations are carried out on fine grids without any turbulence modelling. The flow structure and the concentration profile of the resulting flow are analyzed and compared with theoretical results.

We present results from hydrogen dispersion simulations from a pressurized reservoir at constant flow rate in the presence and absence of a wall. The dispersion simulations are performed using a commercial finite volume solver. Validation of the approach is discussed. Constant concentration envelopes corresponding to the 2% 4% and 15% hydrogen concentration in air are calculated for a subcritical vertical jet and for an equivalent subcritical horizontal jet from a high pressure reservoir. The consequences of ignition and the resulting overpressure are calculated for subcritical horizontal and vertical hydrogen jets and in the latter case compared to available experimental data.

In response to the exceptional circumstances stemming from the coronavirus pandemic the annual IEA Global Energy Review has expanded its coverage to include real-time analysis of developments to date in 2020 and possible directions for the rest of the year. In addition to reviewing 2019 energy and CO2 emissions data by fuel and country for this section of the Global Energy Review we have tracked energy use by country and fuel over the past three months and in some cases – such as electricity – in real time. Some tracking will continue on a weekly basis. The uncertainty surrounding public health the economy and hence energy over the rest of 2020 is unprecedented. This analysis therefore not only charts a possible path for energy use and CO2 emissions in 2020 but also highlights the many factors that could lead to differing outcomes. We draw key lessons on how to navigate this once-in-a-century crisis.

Link to Document on IEA websitte

The development of hydrogen as energy carrier is promoted by the increasing in energy demand depletion of fossil resources and the global warming. However this issue relies primarily on the safety aspect which requires the knowledge in the case of gas release of the quantities such as the flammable cloud size release path and the location of the lower flammability limit of the mixture. The integral models for predicting the atmospheric dispersion were extensively used in previous works for low pressure releases such as pollutant and  flammable gas transport. In the present investigation this approach is extended to the high pressure gas releases. The model is developed in the non-Boussinesq approximation and is based on Gaussian profiles for buoyant variable density jet or plume in stratified atmosphere with a crossflow. Validations have been performed on a broad range of hydrogen methane and air dispersion cases including vertical or horizontal jets or plumes into a quiescent atmosphere or with crosswind.

The first part of the present work is to validate a detailed kinetic mechanism for the oxidation of hydrogen – methane – air mixtures in a detonation waves. A series of experiments on auto-ignition delay times have been performed by shock tube technique coupled with emission spectrometry for H2 / CH4 / O2 mixtures highly diluted in argon. The CH4/H2 ratio was varied from 0 to 4 and the equivalence ratio from 0.4 up to 1. The temperature range was from 1250 K to 2000 K and the pressure behind reflected shock waves was between 0.15 and 1.6 MPa. A correlation was proposed between temperature (K) concentration of chemical species (mol m-3) and ignition delay times. The experimental auto-ignition delay times were compared to the modelled ones using four different mechanisms from the literature: GRI [22] Marinov et al. [23] Hughes et al. [24] Konnov [25]. A large discrepancy was generally found between the different models. The Konnov’s model that predicted auto-ignition delay times close to the measured ones has been selected to calculate the ignition delay time in the detonation waves. The second part of the study concerned the experimental determination of the detonation properties namely the detonation velocity and the cell size. The effect of the initial composition hydrogen to methane ratio and the amount of oxygen in the mixture as well as the initial pressure on the detonation velocity and on the cell size were investigated. The ratio of methane / (methane + hydrogen) varied between 0 and 0.6 for 2 different equivalence ratio (0.75 and 1) while the initial pressure was fixed to 10 kPa. A correlation was established between the characteristic cell size and the ignition delay time behind the leading shock of the detonation. It was clearly showed that methane has an important inhibitor effect on the detonation of these combustible mixtures.