United Kingdom

The research focuses on enhancing hydrogen production using a blend of municipal solid waste (MSW) with Biomass and mixed plastic waste (MPW) under the Bioenergy with Carbon Capture Utilisation and Storage (BECCUS) concept. The key challenges include optimising the feedstock blends and gasification process parameters to maximise hydrogen yield and carbon dioxide capture. This study introduces a novel approach that employs sorption-enhanced gasification and a high-temperature regenerator reactor. Using this method syngas streams with high hydrogen contents of up to 93 mol% and 66 mol% were produced respectively. Thermodynamic simulations with Aspen Plus® validated the integrated system for achieving high-purity hydrogen (99.99 mol%) and effective carbon dioxide isolation. The system produced 70.33 molH2 /kgfeed when using steam as a gasifying agent while 37.95 molH2 /kgfeed was produced under air gasification conditions. Case I employed a mixture of MSW and wood residue at a ratio of 1:1.25 with steam and calcium oxide added at 2:1 and 0.92:1 respectively resulting in 68.80 molH2 /kgfeed and a CO2 capture efficiency of 92 %. Case II utilised MSW and MPW at a 1:1 ratio with steam and calcium oxide at 2:1 and 0.4:1 respectively producing 100.17 molH2 /kgfeed and achieving a 90.09 % CO2 capture efficiency. The optimised parameters significantly improve hydrogen yield and carbon capture offering valuable insights for BECCUS applications.

Green hydrogen is likely to play a major role in decarbonising the aviation industry. It is crucial to understand the effects of microstructure on hydrogen redistribution which may be implicated in the embrittlement of candidate fuel system metals. We have developed a multiscale finite element modelling framework that integrates micromechanical and hydrogen transport models such that the dominant microstructural effects can be efficiently accounted for at millimetre length scales. Our results show that microstructure has a significant effect on hydrogen localisation in elastically anisotropic materials which exhibit an interesting interplay between microstructure and millimetre-scale hydrogen redistribution at various loading rates. Considering 316L stainless steel and nickel a direct comparison of model predictions against experimental hydrogen embrittlement data reveals that the reported sensitivity to loading rate may be strongly linked with rate-dependent grain scale diffusion. These findings highlight the need to incorporate microstructural characteristics in hydrogen embrittlement models.

With the transition to a fully renewable energy grid arises the need for a green source of stability and baseload support which classical renewable generation such as wind and solar cannot offer due to their uncertain and highly-variable generation. In this paper we study whether green hydrogen can close this gap as a source of supplemental generation and storage. We design a two-stage mixed-integer stochastic optimization model that accounts for uncertainties in renewable generation. Our model considers the investment in renewable plants and hydrogen storage as well as the operational decisions for running the hydrogen storage systems. For the data considered we observe that a fully renewable network driven by green hydrogen has a greater potential to succeed when wind generation is high. In fact the main investment priorities revealed by the model are in wind generation and in liquid hydrogen storage. This long-term storage is more valuable for taking full advantage of hydrogen than shorter-term intraday hydrogen gas storage. In addition we note that the main driver for the potential and profitability of green hydrogen lies in the electricity demand and prices as opposed to those for gas. Our model and the investment solutions proposed are robust with respect to changes in the investment costs. All in all our results show that there is potential for green hydrogen as a source of baseload support in the transition to a fully renewable-powered energy grid.

From an environmental standpoint carbon-free energy carriers such as ammonia and hydrogen are essential for future energy systems. However their hightemperature chemical behavior remains insufficiently understood posing challenges for the development and optimization of advanced combustion technologies. Ammonia in particular is globally available and cost-effective especially for energy-intensive industries. The addition of ammonia or hydrogen to methane significantly reduces the accuracy of existing predictive models. Therefore validated and detailed data are urgently needed to enable reliable design and performance predictions. This review highlights the compatibility of ammonia with existing combustion infrastructure facilitating a smoother transition to more sustainable heating methods without the need for entirely new systems. Applications in high-temperature heating processes such as metal processing ceramics and glass production and power generation are of particular interest. This review focuses on the systematic assessment of alternative fuel mixtures comprising ammonia and hydrogen as well as natural gas with particular consideration of existing safety-related parameters and combustion characteristics. Fundamental quantities such as the laminar burning velocity are discussed in the context of their relevance for fuel mixtures and their scalability toward turbulent flame propagation which is of critical importance for industrial burner and reactor design. The influence of fuel composition on ignition limits is examined as these are essential parameters for safety margin definitions and operational boundary conditions. Furthermore flame stability in mixed-fuel systems is addressed to evaluate the practical feasibility and robustness of combustion under varying process conditions. A detailed overview of current diagnostic and analysis methods follows encompassing both pollutant measurement techniques and the detection of key radical species. These diagnostics form the experimental basis for reaction kinetics modeling and mechanism validation. Given the importance of emission formation in combustion systems a dedicated subsection summarizes major emission trends even though a comprehensive treatment would exceed the scope of this review. Thermal radiation effects which are highly relevant for heat transfer and system efficiency in large-scale applications are then reviewed. In parallel current developments in numerical simulation approaches for industrial-scale combustion systems are presented including aspects of model accuracy boundary conditions and computational efficiency. The review also incorporates insights from materials engineering particularly regarding high-temperature material performance corrosion resistance and compatibility with combustion products. Based on these interdisciplinary findings operational strategies for high-temperature furnaces are outlined and selected industrial reference systems are briefly presented. This integrated approach aims to support the design optimization and safe operation of next-generation combustion technologies utilizing carbon-free or low-carbon fuels.

This study presents a techno-economic environmental risk analysis (TERA) of large-scale green hydrogen production using Alkaline Water Electrolysis (AWE) and Proton Exchange Membrane (PEM) systems. The analysis integrates commercial data market insights and academic forecasts to capture variability in capital expenditure (CAPEX) efficiency electricity cost and capacity factor. Using Libya as a case study 81 scenarios were modelled for each technology to assess financial and operational trade-offs. For AWE CAPEX is projected between $311 billion and $905.6 billion for 519 GW (gigawatts) of installed capacity equivalent to 600–1745 $/kW. PEM systems show a wider range of $612 billion to $1020 billion for 510 GW translating to 1200–2000 $/kW. Results indicate that AWE while requiring greater land use provides significant cost advantages due to lower capital intensity and scalability. In contrast PEM systems offer compact design and operational flexibility but at substantially higher costs. The five most economical scenarios for both technologies consistently feature low CAPEX and high efficiency while sensitivity analyses confirm these two parameters as the dominant cost drivers. The findings emphasise that technology choice should reflect context-specific priorities such as land availability budget and performance needs. This study provides actionable guidance for policymakers and investors developing cost-effective hydrogen infrastructure in emerging green energy markets.

Reducing CO2 emissions is an increasingly important goal in general aviation. The dual-fuel hydrogen–kerosene combustion process has proven to be a suitable technology for use in small aircraft. This robust and reliable technology significantly reduces CO2 emissions due to the carbon-free combustion of hydrogen during operation while pure kerosene or sustainable aviation fuel (SAF) can be used in safety-critical situations or in the event of fuel supply issues. Previous studies have demonstrated the potential of this technology in terms of emissions performance and efficiency while also highlighting challenges related to abnormal combustion phenomena such as knocking and pre-ignition which limit the maximum achievable hydrogen energy share. However the causes of such phenomena—especially regarding the role of lubricating oils—have not yet been sufficiently investigated in hydrogen engines making this a crucial area for further development. In this paper investigations at the TU Wien Institute of Powertrain and Automotive Technology concerning the role of different engine oils in influencing pre-ignition tendencies in a hydrogen–kerosene dual-fuel engine are described. A specialized test procedure was developed to account for the unique combustion characteristics of the dual-fuel process along with a detailed purge procedure to minimize oil carryover. Multiple engine oils with varying compositions were tested to evaluate their influence on pre-ignition tendencies with a particular focus on additives containing calcium magnesium and molybdenum known for their roles in detergent and anti-wear properties. Additionally the study addressed the contribution of particles to pre-ignition occurrences. The results indicate that calcium and magnesium exhibit no notable impact on pre-ignition behavior; however the addition of molybdenum results in a pronounced reduction in pre-ignition events which could enable a higher hydrogen energy share and thus decrease CO2 emissions in the context of hydrogen dual-fuel aviation applications.

Achieving transport decarbonization depends on electric vehicle (EV) and fuel cell vehicle (FCV) deployment yet their material demands and impacts vary by vehicle type. This study explores how powertrain preferences in light-duty vehicles (LDVs) and heavy-duty vehicles (HDVs) shape future resource use and material-related environmental outcomes. Using dynamic material flow analysis and prospective life cycle assessment we assess three scenarios. In the S3 EV-dominant scenario 2050 lithium and cobalt demand rises by up to 11.9-fold and 1.8-fold relative to 2020 with higher global warming and human toxicity impacts. The S2 FCV-dominant scenario leads to a 21.7-fold increase in platinum-group metal demand driving up freshwater ecotoxicity and particulate emissions. A balanced S1 scenario EVs in LDVs and FCVs in HDVs yields moderate material demand and environmental burdens. These findings demonstrate that no single pathway can fully resolve material-related impacts while combining EVs and FCVs across LDVs and HDVs enables a more balanced and sustainable transition.

The hydrogen energy industry is rapidly developing positioning hydrogen refueling stations (HRSs) as critical infrastructure for hydrogen fuel cell vehicles. Within these stations hydrogen compressors serve as the core equipment whose performance and reliability directly determine the overall system’s economy and safety. This article systematically reviews the working principles structural features and application status of mechanical hydrogen compressors with a focus on three prominent types based on reciprocating motion principles: the diaphragm compressor the hydraulically driven piston compressor and the ionic liquid compressor. The study provides a detailed analysis of performance bottlenecks material challenges thermal management issues and volumetric efficiency loss mechanisms for each compressor type. Furthermore it summarizes recent technical optimizations and innovations. Finally the paper identifies current research gaps particularly in reliability hydrogen embrittlement and intelligent control under high-temperature and high-pressure conditions. It also proposes future technology development pathways and standardization recommendations aiming to serve as a reference for further R&D and the industrialization of hydrogen compression technology.

The adoption of clean hydrogen is expected to transform the global energy landscape reducing greenhouse gas emissions bridging gaps in renewable energy integration and driving innovation across multiple sectors. In the medical and pharmaceutical industries hydrogen offers unique opportunities for transformative progress. This review critically examines recent advances in three domains: hydrogen fuel cells as reliable scalable and sustainable energy solutions for hospitals; molecular hydrogen as a therapeutic and preventive medical gas particularly for brain disorders; and hydrogenation technologies for the efficient and sustainable pharmaceutical production. Despite encouraging advancements widespread adoption remains limited by economic constraints regulatory gaps and limited clinical evidence. Addressing these barriers through technological innovation largescale studies and life-cycle sustainability assessments is essential to translate hydrogen’s full potential into clinical and industrial practice. Responsible adoption of green hydrogen is poised to reshape the clinical approach to global health and enhance the quality of life for people worldwide.

Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion with marked changes in thermochemical properties leading to significant issues such as limited operational range flashback and instability particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated highlighting the intricate interplay between swirling flow structures and reaction kinetics which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions diminishing past ~0.3 MPa with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data generated using Detached Eddy Simulations (DES) were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames contributing to the development of cleaner combustion technologies.