United Kingdom
A Critical Review of Cushion Gas in Underground Hydrogen Storage: Thermophysical Properties, Interfacial Interactions, and Numerical Perspectives
Nov 2025
Publication
Underground hydrogen storage (UHS) represents a large-scale energy storage system aiming to ensure a consistent supply by storing hydrogen generated from surplus energy. In the practice of UHS cushion gas is typically injected into the formation to maintain reservoir pressure for efficient hydrogen withdrawal. This paper reviews the impact of cushion gas on the performance of UHS from both experimental and numerical simulation perspectives. The thermophysical (e.g. density viscosity compressibility and solubility) and petrophysical (interfacial tension wettability and relative permeability) properties as well as the mixing and diffusion behavior of different cushion gases were compared. The corresponding impact of different cushion gases on plume migration and trapping potential is then discussed. Furthermore this review critically analyzes and explains the impact of various factors on the performance of UHS including the type of cushion gas the composition of cushion gas mixtures the volume of injected cushion gas and the effects of bio-methanation processes. The corresponding analysis specifically focuses on key performance indicators including H2 recovery factor formation pressure brine production and H2 outflow purity. Thus this review provides a comprehensive analysis of the role of cushion gas in UHS offering insight into the effective management and optimization of cushion gas injection in field-scale UHS operations.
Optimal Possibilistic-robust Operation of Multi-energy Microgrids Considering Infrastructure Hydrogen Storage Capability
Nov 2025
Publication
In sustainable energy transitions the utilization of hydrogen is crucial providing flexibility in the operation of net-zero emission renewable-based energy systems. This paper presents a study on the optimal operation of netzero emission multi-energy future microgrids that utilize hydrogen as an alternative fuel instead of natural gas. The electrolyzers’ output is injected into the hydrogen grid to meet demand or converted back to electricity later using generating units owing to the storage capability of pipes called linepack. For this purpose a detailed mathematical model is developed to simulate the main characteristics of grids (e.g. voltage current hydrogen flow and pressure) as well as various components (e.g. renewable systems electrolyzers and hydrogen-fired units). To become more realistic a possibilistic-robust approach is developed to account for the uncertainty arising from the lack of real-world implementation. By representing a case study a test is performed to evaluate the possibility of employing a low-pressure gas grid to meet the demand for hydrogen. After that the effects of electrolyzers are analyzed in the presence and absence of the uncertainty consideration approach. The result indicates that despite hydrogen’s lower energy density compared to natural gas it is still feasible to satisfy the same energy demand level considering the technical characteristics of the grid. The integration of electrolyzers can reduce wind curtailment by 2 % and supplement hydrogen demand by 50 %. A higher level of conservatism in the possibilistic-robust approach leads to an increase in the mean value of the objective function and a reduction in the standard deviation under the realization of uncertain parameters which provides the decisionmakers with a more realistic insight.
Optimal Sizing and Energy Management for Fuel Cell Electric Vehicles with 3D-ordered MEAs: A Pareto Frontier Study
Oct 2025
Publication
Fuel cell electric vehicles (FCEVs) are zero-emission but face cost and power density challenges. To mitigate these limitations a novel 3D-ordered nano-structured self-supporting membrane electrode assembly (MEA) has been developed. This paper investigates the optimal component sizing of the battery and fuel cell in FCEVs equipped with 3D-ordered MEAs integrating the energy management. To explore the trade-offs between component cost operational cost and fuel cell degradation the sizing and energy management problem is formulated into a multi-objective optimisation problem. A Pareto frontier (PF) study is conducted using the decomposed multi-objective evolutionary algorithm (MOEA/D) for a more diverse distribution of feasible solutions. The modular design of fuel cells is derived from a scaled and stressed experiment. After executing MOEA/D across the three aggressive driving cycles power source configurations are selected from the corresponding PFs based on objective trade-offs ensuring robustness of the overall system. The optimisation performance of the MOEA/D is compared with that of the multi-objective Particle Swarm Optimisation. In addition the selected powertrain configurations are evaluated and compared through standard and realworld driving cycles in a simulation environment. This paper also performs a sensitivity analysis to reveal the influence of diverse component unit costs and hydrogen price. The results indicate that the mediumsized configuration consisting of a 63.31 kW fuel cell stack and a 52.15 kWh battery pack delivers the best overall performance. It achieves a 26.71% reduction in component cost and up to 12.76% savings in hydrogen consumption across various driving conditions. These findings provide valuable insights into the design and optimisation of fuel cell systems for FCEVs.
Cutting-edge Advances in Hydrogen Applications for the Medical and Pharmaceutical Industries
Oct 2025
Publication
The adoption of clean hydrogen is expected to transform the global energy landscape reducing greenhouse gas emissions bridging gaps in renewable energy integration and driving innovation across multiple sectors. In the medical and pharmaceutical industries hydrogen offers unique opportunities for transformative progress. This review critically examines recent advances in three domains: hydrogen fuel cells as reliable scalable and sustainable energy solutions for hospitals; molecular hydrogen as a therapeutic and preventive medical gas particularly for brain disorders; and hydrogenation technologies for the efficient and sustainable pharmaceutical production. Despite encouraging advancements widespread adoption remains limited by economic constraints regulatory gaps and limited clinical evidence. Addressing these barriers through technological innovation largescale studies and life-cycle sustainability assessments is essential to translate hydrogen’s full potential into clinical and industrial practice. Responsible adoption of green hydrogen is poised to reshape the clinical approach to global health and enhance the quality of life for people worldwide.
Beyond Industrial Decarbonisation Strategy: Lessons from the Bottom-up Policy Mix in the United Kingdom, 2021-2023
Nov 2025
Publication
Industrial decarbonisation (ID) is a new challenge in the transition to net zero. The ID challenge is complicated because it covers a wide range of industries and processes and therefore a policy mix approach is appropriate. Because of multiple interactions with existing areas of regulation the bottom-up policy mix as defined by Ossenbrink et al. (2019) is likely to be particularly important for the successful implementation of ID policy. In this article we build on the policy mix literature by positing how bottom-up policy instrument mixes may fail to be consistent and comprehensive not only because of conflicting goals and missing instruments but also due to missing information. We also consider how integrating policy functions centrally may help top-down policy mix coherence but work against bottom-up coherence processes. We illustrate our argument through a case study of the first detailed examination of industrial decarbonisation policy and regulation for a major OECD country i.e. the UK. Utilizing a robust and extensive original dataset of 118 expert interviews we show how the top-down policy mix focused on supporting innovation in hydrogen and carbon capture and storage is layered on top of a range of policies and regulations including spatial planning environmental pollution regulation health and safety rules gas standards and skills policy. Solving problems of inconsistency and a lack of comprehensiveness in instruments is slowed by insufficient coordination and resources.
Marine Hydrogen Pressure Reducing Valves: A Review on Multi-Physics Coupling, Flow Dynamics, and Structural Optimization for Ship-Borne Storage Systems
Oct 2025
Publication
As a zero-carbon energy carrier hydrogen is playing an increasingly vital role in the decarbonization of maritime transportation. The hydrogen pressure reducing valve (PRV) is a core component of ship-borne hydrogen storage systems directly influencing the safety efficiency and reliability of hydrogen-powered vessels. However the marine environment— characterized by persistent vibrations salt spray corrosion and temperature fluctuations— poses significant challenges to PRV performance including material degradation flow instability and reduced operational lifespan. This review comprehensively summarizes and analyzes recent advances in the study of high-pressure hydrogen PRVs for marine applications with a focus on transient flow dynamics turbulence and compressible flow characteristics multi-stage throttling strategies and valve core geometric optimization. Through a systematic review of theoretical modeling numerical simulations and experimental studies we identify key bottlenecks such as multi-physics coupling effects under extreme conditions and the lack of marine-adapted validation frameworks. Finally we conducted a preliminary discussion on future research directions covering aspects such as the construction of coupled multi-physics field models the development of marine environment simulation experimental platforms the research on new materials resistant to vibration and corrosion and the establishment of a standardized testing system. This review aims to provide fundamental references and technical development ideas for the research and development of high-performance marine hydrogen pressure reducing valves with the expectation of facilitating the safe and efficient application and promotion of hydrogen-powered shipping technology worldwide.
Tailored Heat Treatments to Characterise the Fracture Resistance of Critical Weld Regions in Hydrogen Transmission Pipelines
Nov 2025
Publication
A new protocol is presented to directly characterise the toughness of microstructural regions present within the weld heat-affected zone (HAZ) the most vulnerable location governing the structural integrity of hydrogen transport pipelines. Heat treatments are tailored to obtain bulk specimens that replicate predominantly ferriticbainitic bainitic and martensitic microstructures present in the HAZ. These are applied to a range of pipeline steels to investigate the role of manufacturing era (vintage versus modern) chemical composition and grade. The heat treatments successfully reproduce the hardness levels and microstructures observed in the HAZ of existing natural gas pipelines. Subsequently fracture experiments are conducted in air and pure H2 at 100 bar revealing a reduced fracture resistance and higher hydrogen embrittlement susceptibility of the HAZ microstructures with initiation toughness values as low as 32 MPa√ m. The findings emphasise the need to adequately consider the influence of microstructure and hard brittle zones within the HAZ.
Single Step Electrified Hydrogen Production from Methane in a Gliding Arc/fluidized Bed Reactor
Nov 2025
Publication
In this work a plasma fluidized bed reactor has been studied as an electrified methane decomposition reactor for sustainable hydrogen production. A combined 3D rotating gliding arc/fluidized bed reactor assembly demonstrates a stable operation with a CH4/Ar mixture containing up to 8 vol% of CH4. The reactor provides a 97.2 % H2 selectivity at a methane conversion of 16.6 % and energy costs of 10.6 kJ L− 1 . This performance provides a new benchmark for electrified H2 production with a potential to utilise renewable electricity. In addition carbon materials are produced. The characterizations show difference in the morphology of the materials collected in different reactor zones.
Insights from Swirl Number and Ambient Pressure Variations with a Hydrogen/Ammonia Swirl Stabilized Diffusion Flame
Oct 2025
Publication
Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion with marked changes in thermochemical properties leading to significant issues such as limited operational range flashback and instability particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated highlighting the intricate interplay between swirling flow structures and reaction kinetics which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions diminishing past ~0.3 MPa with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data generated using Detached Eddy Simulations (DES) were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames contributing to the development of cleaner combustion technologies.
Competition and Equilibrium in Future Global Renewable Hydrogen Trade: A Game-theoretic Analysis
Nov 2025
Publication
Global renewable hydrogen trade is expected to play a key role in decarbonizing future energy systems. Yet hydrogen exporters may deviate from perfectly competitive behaviour to influence prices similarly to the existing fossil fuel market with important implications for consumer welfare and the pace of the energy transition. This study develops a global renewable hydrogen trade model that captures potential strategic interactions among exporters using a Stackelberg game-theoretic framework. The model is formulated as an Equilibrium Problem with Equilibrium Constraints (EPEC) and solved under three alternative equilibria: a profitmaximizing Nash equilibrium a cost-minimizing Nash equilibrium and a welfare-maximizing benchmark representing perfect competition. Results indicate that producers may strategically reduce their export quantities by up to 40 % relative to perfect competition to maximize profits. Such behaviour raises prices to a minimum of 4.5 USD/kg in 2050 across major import markets thereby significantly eroding consumer surplus. Strategic behaviour of dominant exporters also shifts trade flows reshaping the global allocation of hydrogen supply. Sensitivity analysis further reveals that financing costs play a key role in shaping strategic producers’ behaviour with lower financing costs helping to reduce prices and stimulate demand. These findings highlight the implications of imperfect competition in global hydrogen trade and suggest that policy measures may be needed to mitigate potential negative consequences.
A CFD Comparison of Interfacial Phase Change Models for Boil-off, Self-pressurisation and Thermal Stratification in Liquid Hydrogen Storage Tanks
Nov 2025
Publication
Liquid hydrogen (LH2 ) is a promising energy carrier for future clean fuel technologies. However its cryogenic storage and handling pose significant challenges particularly due to self-pressurisation and boil-off from ambient heat ingress. Accurate modelling of these phenomena is essential for the safe and efficient design of LH2 storage systems. A key aspect of such modelling is the selection and implementation of an appropriate interfacial phase change model. This study presents a comparative assessment of three widely used phase change models; the Schrage model the Modified Energy Jump (MeJ) model and the Lee model. A parametric study was conducted across three coefficients for each model with validation performed against five experimental benchmark cases from NASA’s K-Site and MHTB cryogenic tanks focusing on planar interface problems with thermally induced phase change under normal gravity. A CFD approach using STAR-CCM+ was employed to evaluate each model’s ability to predict tank pressure temperature and boil-off behaviour. The Schrage model demonstrated the most robust and accurate results exhibiting minimal sensitivity to coefficient variation and offering both numerical stability and physical fidelity. It demonstrated a maximum mean absolute percentage error (MAPE) of just 3.0% in its pressurisation predictions. The MeJ model showed comparable accuracy when its heat transfer coefficient was appropriately selected highlighting its reliance on an empirically derived coefficient. In contrast the Lee model performed the poorest exhibiting numerical divergence at high coefficient values and substantial deviation in its prediction of self-pressurisation with errors of up to 11% MAPE. These findings provide practical guidance for the selection and implementation of phase change models in CFD simulations and highlight key considerations for modelling LH2 storage tanks in industrial applications.
Techno-economic Analysis of Technologies for Decarbonizing Low- and Medium-Temperature Industrial Heat
Dec 2025
Publication
Decarbonizing industrial heat is critical for achieving climate targets. This study evaluates the economic viability of technologies for decarbonizing industrial heat in Europe through a techno-economic analysis. High-temperature heat pumps (HTHPs) and electric hydrogen and biomass boilers are compared in terms of levelized cost of heat (LCOH) under various scenarios including the impact of thermal storage leveraging dynamic electricity prices. In scenarios for the year 2030 we show that HTHPs leveraging free excess heat achieve LCOH values at least 30% to 60% lower than hydrogen boilers and up to 37% lower than biomass boilers. Integrating daily thermal storage reduces LCOH by up to 15% for heat pumps and 27% for electric boilers. By 2050 anticipated cost and efficiency improvements further enhance the competitiveness of heat pumps. These results highlight the economic advantage of HTHPs particularly when integrating excess heat and thermal storage.
Sustainable Power System Transition Pathways: Regional Decarbonisation and Resource Conservation Aided by Small Modular Reactors
Oct 2025
Publication
Clean energy technologies offer promising pathways for low-carbon transitions yet their feasibility remains uncertain particularly in rapidly developing regions. This study develops a Factorial Multi-Stochastic Optimization-driven Equilibrium (FMOE) model to assess the economic and environmental impacts of clean power deployment. Using Small Modular Reactors (SMRs) in Guangdong China as a case study the model reveals that SMRs can reduce system costs and alleviate GDP losses supporting provincial-level Nationally Determined Contributions (NDCs). If offshore wind capital costs fall to 40 % of SMRs’ SMR deployment may no longer be necessary after 2030. Otherwise SMRs could supply 22 % of capacity by 2040. The FMOE model provides a robust adaptable framework for evaluating emerging technologies under uncertainty and supports sustainable power planning across diverse regional contexts. This study offers valuable insights into the resource and economic implications of clean energy strategies contributing to global carbon neutrality and efficient energy system design.
Rooftop Agrivoltaic Powered Onsite Hydrogen Production for Insulated Gasochromic Smart Glazing and Hydrogen Vehicles: A Holistic Approach to Sustainable Residential Building
Nov 2025
Publication
The study focused on designing a sustainable building involving rooftop agrivoltaics advanced glazing technologies and onsite hydrogen production for a residential property in Birmingham UK where green hydrogen produced by harnessing electricity generated by agrivoltaics system on rooftop of the building is employed to change the transparency of vacuum gasochromic glazing and refuel hydrogen-powered fuel cell vehicle using storage hydrogen for a sustainable building approach. The change in the transparency of the glazing reduces the energy requirement of the building according to the occupant’s requirement and weather conditions. This research investigates the performance of various rooftop agrivoltaic systems including vertical optimal 30◦ tilt and dome setups for both monofacial and bifacial agrivoltaic consisting of tomato farming. Promising results were observed for agrivoltaic systems with consistent tomato production of 0.31 kg/m2 with varying shading experienced due to the different photovoltaic setups. Maximum electricity is produced by bifacial 30◦ with 7919 kWh though the lowest LCOE can be observed by monofacial 30◦ with £0.061/kWh. It also compares the efficiency of vacuum gasochromic windows against double glazing vacuum double glazing electrochromic and gasochromic options which can play an essential role in energy saving and reduced carbon emission. Vacuum gasochromic demonstrated the lowest U-value of 1.32 Wm2 K though it has the highest thickness with 24.6 mm. Additionally the study examines the feasibility of small-scale green hydrogen production from the electricity generated by agrivoltaics to fuel hydrogen vehicles and glazing considering the economic viability. The results suggested that the hydrogen required by the glazing accounts for 52.56 g annually and the maximum distance that can be covered theoretically is by bifacial 30◦ which is approximately 64.23 km per day. The interdisciplinary approach aims to optimise land use enhance energy efficiency and promote sustainable urban agriculture to contribute to the UK’s goal of increasing solar energy capacity and achieving net-zero emissions while addressing food security concerns. The findings of this study have potential implications for urban planning renewable energy integration especially solar and sustainable residential design.
A Comprehensive Review on the Compatability of Polymeric Materials for Hydrogen Transportation and Storage
Nov 2025
Publication
This review evaluates the current state of the art on polymeric materials for hydrogen transportation and storage highlighting the importance of developing a sustainable hydrogen infrastructure worldwide. It analyses different polymeric materials used for hydrogen transportation and storage applications including high-density polyethylene (HDPE) polytetrafluoroethylene (PTFE) polyimides (PI) polyether ether ketone (PEEK) polyamide ethylene propylene diene monomer (EPDM) polyvinylidene fluoride (PVDF) and fluorinated ethylene propylene (FEP). These materials are assessed using key characteristics such as hydrogen permeability mechanical strength chemical resistance and thermal stability. The review finds that while PEEK and polyimides exhibit the highest thermal stability (up to 400 °C) and pressure resistance (300–400 bar) HDPE remains the most cost-effective option for low-pressure applications. PTFE and FEP offer the lowest hydrogen permeability (<0.01 cm3 mm/m2·day·bar) making them ideal for sealing and lining in hydrogen storage systems. Furthermore key research gaps are identified and suggestions for future research and development directions are outlined. This comprehensive review is a valuable resource for researchers and engineers working towards sustainable hydrogen infrastructure development.
Quantifying Conservatism in ASME B31.12 Option A for Hydrogen Pipeline Repurposing
Nov 2025
Publication
Hydrogen is a key enabler of the energy transition and repurposing existing natural gas pipelines offers a costeffective pathway for large-scale hydrogen transport. However hydrogen embrittlement raises integrity concerns and current design standards such as ASME B31.12 Option A adopt highly conservative safety margins without a quantified reliability basis. This study evaluates whether the conservative safety margins in ASME B31.12 Option A for hydrogen pipelines can be safely relaxed. A semi-elliptical flaw (depth 0.25t length 1.5t) is assessed using the Failure Assessment Diagram (FAD) method and Monte Carlo simulations with up to 2.5 × 107 iterations. Fracture toughness is fixed at 69.3 MPa√m while wall thickness and yield strength vary statistically. Three design scenarios explore safety factor products from 0.388 to 0.720 at 0 ◦C and 20 ◦C. Results show that flaw acceptability is maintained in all deterministic cases and the probability of failure remains below 10− 6 . No failures occur when the safety factor product drops below 0.637. The analysis uses only codified flaw assumptions and public material data. These findings confirm that Option A provides a highly conservative envelope and demonstrate the value of a reliability-based approach for assessing hydrogen pipeline repurposing while addressing the gap between prescriptive standards and quantified reliability. This integrated FAD–probabilistic framework demonstrates that Option A includes significant conservatism and supports a reliability-based approach to evaluate hydrogen pipeline repurposing without experimental inputs.
State and Disturbance Estimation with Supertwisting Sliding Mode Control for Frequency Regulation in Hydrogen Based Microgrids
Nov 2025
Publication
This study considers the use of an enhanced super-twisting sliding mode control (STSMC) scheme via the incorporation of a hybrid extended state observer (ESO) and a higher order sliding mode observer (HOSMO) state estimation and disturbance observer (DO) based on exponential decay embedded via a tracking element in order to hasten the estimation of disturbance thus improving performance significantly. This scheme is employed to generate single and multiple control signals per agent based on the microgrid’s presented components such as energy storage devices and renewable energy sources (RESs) alongside the harness of a puma optimizer (PO) metaheuristics scheme to optimize each area regulator’s performance. The sliding surface incorporated is chosen based on desired control objectives. Adjusting the constricted area frequency and reducing tie-line power transfer fluctuations are considered the primary goals for frequency regulation in a multi-area power system. Also based on the presented simulations adequate performance in terms of minimum chattering low complexity fast convergence and adequate robustness has been achieved. Using various microgrid peripheral components such as a multi-terminal soft open point (SOP) with a dedicated terminal for hydrogen energy storage alongside the proposed enhanced STSMC the frequency change and power transfer rate of change are maintained within the range of ×10−6 values substantially preserving proper performance compared to other simulated scenarios. In regard to the final simulated case involving SOP the following has been achieved: steady state errors of 2.538×10−6 Hz for ΔF1 3.125×10−6 Hz for ΔF2 and 1.920×10−6 p.u for ΔPtie alongside peak disturbance overshoot reduction in comparison to stochastic case of 99.580% 99.605% and 99.771% for same mentioned elements respectively. Also a reduction in peak disturbance undershoot of 95.589% 99.547% and 99.573% respectively has been achieved. Thus the enhanced STSMC can effectively mitigate frequency fluctuations and tie-line power transfer abnormalities.
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