Korea, Republic of

Raney Ni (R-Ni) electrodes are used as hydrogen evolution reaction catalysts in alkaline water electrolysis (AWE). However they are not durable because of reverse current-induced oxidation and catalyst damage from H2 bubbles. Reverse current triggers Ni phase changes and mechanical stress leading to catalyst delamination while bubbles block active sites increase resistance and cause structural damage. These issues have been addressed individually but not simultaneously. In this study a P-doped Ni (NiP) protective layer is electroplated on the R-Ni electrode to overcome both challenges. The NiP protective layer inhibits oxidation reducing Ni phase changes and preventing catalyst delamination. Enhanced surface wettability minimizes nucleation and facilitates faster bubble detachment reducing bubble-related damage. Electrochemical tests reveal that NiP/R-Ni exhibits a 26 mV lower overpotential than that of R-Ni at −400 mA cm−2 indicating higher catalytic activity. Accelerated degradation tests (ADTs) demonstrate the retention of the NiP/R-Ni catalyst layer with only a 25 mV increase in overpotential after ADT which is significantly less than that of R-Ni. Real-time impedance analysis reveals the presence of small rapidly detaching bubbles on NiP/R-Ni. Overall the NiP protective layer on R-Ni simultaneously mitigates both reverse current and H2 bubble-induced degradation improving catalytic activity and durability during AWE.

Injection timing in low-pressure hydrogen direct injection (H2LPDI) engines plays a critical role in optimising gas jet structure and mixture formation due to the complex and transient nature of ambient air flow and density inside the cylinder. This study systematically investigates the macroscopic characteristics of gas jet development at five distinct injection timings from 210 to 120 ◦CA bTDC with the intake valve closure (IVC) as a reference point in a motored inline four-cylinder spark-ignition engine at 2000 rpm and 160 Nm load using low-pressure injection of 3.5 MPa. Optical access was made with two endoscopes: one for high-speed imaging and the other for laser insertion to realise laser shadowgraph imaging of the gas jet delivered using a side-mounted outwardopening pintle nozzle injector. The experimental results reveal spatial and temporal variations in jet morphology penetration spreading angle and mixture dispersion as a function of injection timing. Pre-IVC injection (210 ◦CA bTDC) produced a narrow mean cone angle of ~40◦ and the highest penetration-rate proxy (0.49) whereas postIVC injection (120 ◦CA bTDC) retained a wider ~53◦ cone yet reduced the penetration rate to 0.28 while increasing the sheet-based mixing index from − 0.084 to − 0.106. Pre-IVC injection occurring under low ambient pressure and with active intake airflow was found to produce elongated jets with enhanced penetration and mixing rates though accompanied by substantial cyclic variations. Conversely post-IVC injection was strongly influenced by a fully developed tumble flow which redirected the jet trajectory towards the pent-roof and facilitated mixing through increased turbulence. However the elevated air density constrained the jet penetration. At-IVC injection resulted in a more uniform and stable jet structure. However the lack of convective flow constrained the overall mixing effectiveness. Quantitative analysis of jet spreading angle pixel intensity gradient and centroid movement using 100 consecutive cycles confirms the critical role of injection timing in shaping the gas jet development as suggested by the images.

The present investigation aims to provide a comparative assessment of using hydrogen-enriched wood waste-derived producer gas (PG) for a dual-fuel diesel engine fueled with a 20% Jatropha biodiesel/80% diesel blend (BD20) with the traditional mode. The experiments were conducted at 23°bTDC of injection timing 240 bar of injection pressure 17.5:1 of compression ratio and 1500 rpm of engine speed under various engine loads. Gas carburetor induction (GCI) port injection (PI) and inlet manifold injection (IMI) methods were used to supply H2-enriched PG while B20 is directly injected into the combustion chamber. Among all the combinations the IMI method provided the highest brake thermal efficiency of 30.91% the lowest CO emission of 0.08% and smoke opacity discharge of 49.26 HSU while NOx emission reached 1744.32 ppm which was lower than that of the PI mode. Furthermore the IMI method recorded the highest heat release rate of 91.17 J/°CA and peak cylinder pressure of 83.29 bar reflecting superior combustion quality. Finally using the IMI method for H2-enriched PG in dual-fuel diesel engines could improve combustion efficiency reduce greenhouse gas emissions and improve fuel economy showing that the combination of BD20 with H2-enriched PG offers a cleaner more sustainable and economically viable technology.

This extensive study delves into analyzing carbon dioxide (CO2)-capturing green hydrogen plant exploring its operation using multiple electrolysis techniques and examining their efficiency and impact on environment. The solar energy is used for the electrolysis to make hydrogen. Emitted CO2 from thermal power plants integrate with green hydrogen and produces methanol. It is a process crucial for mitigating environmental damage and fostering sustainable energy practices. The findings demonstrated that solid oxide electrolysis is the most effective process by which hydrogen can be produced with significant rate of 90 % efficiency. Moreover proton exchange membrane (PEM) becomes a viable and common method with an 80 % efficiency whereas the alkaline electrolysis has a moderate level of 63 % efficiency. Additionally it was noted that the importance of seasonal fluctuations where the capturing of CO2 is maximum in summer months and less in the winter is an important factor to consider in order to maximize the working of the plant and the allocation of resources.