Institution of Gas Engineers & Managers
Effects of Operating Parameters on Combustion Characteristics of Hydrogen-Doped Natural Gas
Oct 2025
Publication
The operational optimization of industrial boilers utilizing hydrogen-enriched natural gas is constrained by two critical gaps: insufficient understanding of the coupled effects of hydrogen blending ratio equivalence ratio and boiler load on combustion performance— compounded by unresolved challenges of combustion instability flashback and elevated NOx emissions—and a lack of systematic investigations combining these parameters in industrial-scale systems (prior studies often focus on single variables like hydrogen fraction). To address this a comprehensive computational fluid dynamics (CFD) analysis was conducted on a 2.1 MW industrial boiler employing the Steady Laminar Flamelet Model (SLFM) with a modified k-ε turbulence model and the GRI-Mech 3.0 mechanism. Simulations covered hydrogen fractions (f(H2) = 0–25%) equivalence ratios (Φ = 0.8–1.2) and load conditions (15–100%). All NOx emissions reported herein are normalized to 3.5% O2 (mg/Nm3 ) for regulatory comparison. Results show that increasing the hydrogen content raises the flame temperature and NOx emissions while reducing CO and unburned hydrocarbons; a higher equivalence ratio elevates temperature and NOx with Φ = 0.8 balancing efficiency and emission control; and reducing load significantly lowers furnace temperature and NO emissions. Notably the boiler’s unique staged-combustion configuration (81% fuel supply to the central rich-combustion nozzle 19% to the concentric lean-combustion nozzle) was found to mitigate NOx formation by 15–20% compared to single-inlet burner designs and its integrated cyclone blades (generating maximum swirling velocity of 14.2 m/s at full load) enhanced fuel–air mixing which became particularly critical for maintaining combustion stability at low loads (≤20%) and high hydrogen blending ratios (≥20%). This study provides quantitative trade-off insights between combustion efficiency and pollutant formation offering actionable guidance for the safe efficient operation of hydrogen-enriched natural gas in industrial boilers.
Simulation of the Hydrogen Railway Engine Performance Under Different Load Conditions and Control Parameters
Oct 2025
Publication
The article examines the use of hydrogen fuel as an alternative to traditional diesel fuel for internal combustion engines (ICE) in railway applications. The main objective of the study is to analyze the operational consumption of hydrogen fuel based on the mathematical modeling of the working cycle of the EMD 12-645E3C engine installed on CIE 071 locomotives used in freight and passenger service. The article provides information on the design features of the EMD 12-645E3C engine its technical parameters and the results of bench tests. The indicator parameters of the engine at various controller positions are determined and analyzed and the results of mathematical modeling of its operation on hydrogen fuel are presented. Particular attention is paid to changes in indicator parameters including the maximum combustion pressure and the peak gas temperature in the cylinder as well as comparing the mass consumption of diesel and hydrogen fuel. The study results demonstrate that the use of hydrogen allows the engine to maintain effective power across all operational modes while simultaneously reducing energy costs up to 8%. In this case the pressure and temperature of the gases in the cylinder increased by 3–6% and 5–8%. Recommendations are also provided regarding technical challenges associated with transitioning to hydrogen fuel including the modernization of the combustion chamber fuel system and safety system.
Assessment of the Use of a Passive Pre-Chamber in a Marine Engine Fueled with Ammonia–Hydrogen Mixtures
Oct 2025
Publication
This study investigates the combustion process in a marine spark-ignition engine fueled with an ammonia–hydrogen blend (15% hydrogen by volume) using a passive pre-chamber. A 3D-CFD model supported by a 1D engine model was employed to analyze equivalence ratios between 0.7 and 0.9 and pre-chamber nozzle diameters from 7 to 3 mm. Results indicate that combustion is consistently initiated by turbulent jets but at an equivalence ratio of 0.7 the charge combustion is incomplete. For lean mixtures reducing nozzle size improves flame propagation although not sufficiently to ensure stable operation. At an equivalence ratio of 0.8 reducing the nozzle diameter from 7 to 5 mm advances CA50 by about 6 CAD while further reduction causes minor variations. At richer conditions nozzle diameter plays a negligible role. Optimal performance was achieved with a 7 mm nozzle at equivalence ratio 0.8 delivering about 43% efficiency and 1.17 MW per cylinder.
Development of DC-DC Converters for Fuel-Cell Hybrid Power Systems in a Lift-Cruise Unmanned Aerial Vehicle
Oct 2025
Publication
Lift–cruise-type unmanned aerial vehicles (UAVs) powered by hydrogen fuel cells often integrate secondary energy storage devices to improve responsiveness to load fluctuations during different flight phases which necessitates an efficient energy management strategy that optimizes power allocation among multiple power sources. This paper presents an innovative fuel cell DC–DC converter (FDC) design for the hybrid power system of a lift–cruise-type UAV comprising a multi-stack fuel cell system and a battery. The novelty of this work lies in the development of an FDC suitable for a multi-stack fuel cell system through a dual-input single-output converter structure and a control algorithm. To integrate inputs supplied from two hydrogen fuel cell stacks into a single output a controller with a single voltage controller–dual current controller structure was applied and its performance was verified through simulations and experiments. Load balancing was maintained even under input asymmetry and fault-tolerant performance was evaluated by analyzing the FDC output waveform under a simulated single-stack input failure. Furthermore under the assumed flight scenarios the results demonstrate that stable and efficient power supply is achieved through power-supply mode switching and application of a power distribution algorithm.
Application and Research Progress of Mechanical Hydrogen Compressors in Hydrogen Refueling Stations: Structure, Performance, and Challenges
Nov 2025
Publication
The hydrogen energy industry is rapidly developing positioning hydrogen refueling stations (HRSs) as critical infrastructure for hydrogen fuel cell vehicles. Within these stations hydrogen compressors serve as the core equipment whose performance and reliability directly determine the overall system’s economy and safety. This article systematically reviews the working principles structural features and application status of mechanical hydrogen compressors with a focus on three prominent types based on reciprocating motion principles: the diaphragm compressor the hydraulically driven piston compressor and the ionic liquid compressor. The study provides a detailed analysis of performance bottlenecks material challenges thermal management issues and volumetric efficiency loss mechanisms for each compressor type. Furthermore it summarizes recent technical optimizations and innovations. Finally the paper identifies current research gaps particularly in reliability hydrogen embrittlement and intelligent control under high-temperature and high-pressure conditions. It also proposes future technology development pathways and standardization recommendations aiming to serve as a reference for further R&D and the industrialization of hydrogen compression technology.
Addressing Spatiotemporal Mismatch via Hourly Pipeline Scheduling: Regional Hydrogen Energy Supply Optimization
Nov 2025
Publication
The rapid adoption of hydrogen fuel cell vehicles (HFCVs) in the Beijing–Tianjin–Hebei (BTH) hub accentuates the mismatch between renewable-based hydrogen supply in Hebei and concentrated demand in Beijing and Tianjin. We develop a mixed-integer linear model that co-configures a hydrogen pipeline network and optimizes hourly flow schedules to minimize annualized cost and CO2 emissions simultaneously. For 15000 HFCVs expected in 2025 (137 t d−1 demand) the Pareto-optimal design consists of 13 production plants 43 pipelines and 38 refueling stations delivering 50767 t yr−1 at 68% pipeline utilization. Hebei provides 88% of the hydrogen 70% of which is consumed in the two megacities. Hourly profiles reveal that 65% of electrolytic output coincides with local wind–solar peaks whereas refueling surges arise during morning and evening rush hours; the proposed schedule offsets the 4–6 h mismatch without additional storage. Transport distances are 40% < 50 km 35% 50–200 km and 25% > 200 km. Raising the green hydrogen share from 10% to 70% increases total system cost from USD 1.56 bn to USD 2.73 bn but cuts annual CO2 emissions from 142 kt to 51 kt demonstrating the trade-off between cost and decarbonization. The model quantifies the value of sub-day pipeline scheduling in resolving spatial–temporal imbalances for large-scale low-carbon hydrogen supply.
An Overview of Development and Challenges in the Use of Hydrogen as a Fuel for a Dual-Fuel Diesel Engine
Nov 2025
Publication
The gradual exhaustion of fossil fuel reserves along with the adverse effects of their consumption on global climate drives the need for research into alternative energy sources that can meet the growing demand in a sustainable and eco-friendly way. Among these hydrogen stands out as one of the most promising options for the automotive sector being the cleanest available fuel and capable of being produced from renewable resources. This paper reviews the existing literature on compression ignition engines operating in a dualfuel configuration where diesel serves as the ignition source and hydrogen is used to enhance the combustion process. The reviewed studies focus on engine systems with hydrogen injection into the intake manifold. The investigations analyzed the influence of hydrogen energy fraction on combustion characteristics engine performance combustion stability and exhaust emissions in diesel/hydrogen dual-fuel engines operating under full or near-full-load conditions. The paper identifies the main challenges hindering the widespread and commercial application of hydrogen in diesel/hydrogen dual-fuel engines and discusses potential methods to overcome the existing barriers in this area.
Techno-Economic Analysis of Green Hydrogen Energy Production in West Africa
Nov 2025
Publication
The United Nations has set a global vision towards emissions reduction and green growth through the Sustainable Development Goals (SDGs). Towards the realisation of SDGS 7 9 and 13 we focus on green hydrogen production as a potential pathway to achievement. Green hydrogen produced via water electrolysis powered by renewable energy sources represents a pivotal solution towards climate change mitigation. Energy access in West Africa remains a challenge and dependency on fossil fuels persists. So green hydrogen offers an opportunity to harness abundant solar resources reduce carbon emissions and foster economic development. This study evaluates the techno-economic feasibility of green hydrogen production in five West African countries: Ghana Nigeria Mali Niger and Senegal. The analyses cover the solar energy potential hydrogen production capacities and economic viability using the Levelised Cost of Hydrogen (LCOH) and Net Present Value (NPV). Results indicate substantial annual hydrogen production potential with LCOH values competitive with global benchmarks amidst the EU’s Carbon Border Adjustment Mechanism (CBAM). Despite this potential several barriers exist including high initial capital costs policy and regulatory gaps limited technical capacity and water resource constraints. We recommend targeted strategies for strengthening policy frameworks fostering international partnerships enhancing regional infrastructure integration and investing in capacity-building initiatives. By addressing these barriers West Africa can be a key player in the global green hydrogen market.
Life Cycle of Fuel Cells: From Raw Materials to End-of-Life Management
Nov 2025
Publication
Fuel cells are highly efficient electrochemical devices that convert the chemical energy of fuel directly into electrical energy while generating minimal pollutant emissions. In recent decades they have established themselves as a key technology for sustainable energy supply in the transport sector stationary systems and portable applications. In order to assess their real contribution to environmental protection and energy efficiency a comprehensive analysis of their life cycle Life Cycle Assessment (LCA) is necessary covering all stages from the extraction of raw materials and the production of components through operation and maintenance to decommissioning and recycling. Particular attention is paid to the environmental challenges associated with the extraction of platinum catalysts the production of membranes and waste management. Economic aspects such as capital costs the price of hydrogen and maintenance costs also have a significant impact on their widespread implementation. This manuscript presents detailed mathematical models that describe the electrochemical characteristics energy and mass balances degradation dynamics and cost structures over the life cycle of fuel cells. The models focus on proton exchange membrane fuel cells (PEMFCs) with possible extensions to other types. LCA is applied to quantify environmental impacts such as global warming potential (GWP) while the levelized cost of electricity (LCOE) is used to assess economic viability. Particular attention is paid to the sustainability challenges of platinum catalyst extraction membrane production and end-of-life material recovery. By integrating technical environmental and economic modeling the paper provides a systematic perspective for optimizing fuel cell deployment within a circular economy.
Cost-Optimal Design of a Stand-Alone PV-Driven Hydrogen Production and Refueling Station Using Genetic Algorithms
Nov 2025
Publication
Driven by the growing availability of funding opportunities electrolyzers have become increasingly accessible unlocking significant potential for large-scale green hydrogen production. The goal of this investigation is to develop a techno-economic optimization framework for the design of a stand-alone photovoltaic (PV)-driven hydrogen production and refueling station with the explicit objective of minimizing the levelized cost of hydrogen (LCOH). The system integrates PV generation a proton-exchange-membrane electrolyzer battery energy storage compression and high-pressure hydrogen storage to meet the daily demand of a fleet of fuel cell buses. Results show that the optimal configuration achieves an LCOH of 11 €/kg when only fleet demand is considered whereas if surplus hydrogen sales are accounted for the LCOH reduces to 7.98 €/kg. The analysis highlights that more than 75% of total investment costs are attributable to PV and electrolysis underscoring the importance of capital incentives. Financial modeling indicates that a subsidy of about 58.4% of initial CAPEX is required to ensure a 10% internal rate of return under EU market conditions. The proposed methodology provides a reproducible decision-support tool for optimizing off-grid hydrogen refueling infrastructure and assessing policy instruments to accelerate hydrogen adoption in heavy-duty transport.
Optimal Dispatch Model for Hybrid Energy Storage in Low-Carbon Integrated Energy Systems
Nov 2025
Publication
Integrated Energy Systems (IESs) which leverage the synergistic coordination of electricity heat and gas networks serve as crucial enablers for a low-carbon transition. Current research predominantly treats energy storage as a subordinate resource in dispatch schemes failing to simultaneously optimise IES economic efficiency and storage operators’ profit maximisation thereby overlooking their potential value as independent market entities. To address these limitations this study establishes an operator-autonomous management framework incorporating electrical thermal and hydrogen storage in IESs. We propose a joint optimal dispatch model for hybrid energy storage systems in low-carbon IES operation. The upper-level model minimises total system operation costs for IES operators while the lower-level model maximises net profits for independent storage operators managing various storage assets. These two levels are interconnected through power price and carbon signals. The effectiveness of the proposed model is verified by setting up multiple scenarios for example analysis.
Hydrogen-Rich Gaseous Mixture for Enhanced Combustion in a Flex-Fuel Engine: An Experimental Analysis
Nov 2025
Publication
This experimental study examines the effect of adding a hydrogen-enriched synthetic gaseous mixture (HGM’) on the combustion and fuel conversion efficiency of a singlecylinder research engine (SCRE). The work assesses the viability of using this mixture as a supplemental fuel for flex-fuel engines operating under urban driving cycling conditions. An SCRE the AVL 5405 model was employed operating with ethanol and gasoline as primary fuels through direct injection (DI) and a volumetric compression ratio of 11.5:1. The HGM’ was added in the engine’s intake via fumigation (FS) with volumetric proportions ranging from 5% to 20%. The tests were executed at 1900 rpm and 2500 rpm engine speeds with indicated mean effective pressures (IMEPs) of 3 and 5 bar. When HGM’s 5% v/v was applied at 2500 rpm the mean indicated effective pressure of 3 bar was observed. A decrease of 21% and 16.5% in the ISFC was observed when using gasoline and ethanol as primary fuels respectively. The usage of an HGM’ combined with gasoline or ethanol proved to be a relevant and economically accessible strategy in the improvement of the conversion efficiency of combustion fuels once this gaseous mixture could be obtained through the vapor-catalytic reforming of ethanol giving up the use of turbochargers or lean and ultra-lean burn strategies. These results demonstrated the potential of using HGM’ as an effective alternative to increase the efficiency of flex-fuel engines.
Hydrogen Diffusivity and Hydrogen Traps Behavior of a Tempered and Untempered Martensitic Steel
Nov 2025
Publication
The effect of tempering temperature and tempering time on the density of hydrogen traps hydrogen diffusivity and microhardness in a vanadium-modified AISI 4140 martensitic steel was determined. Tempering parameters were selected to activate the second third and fourth tempering stages. These conditions were intended to promote specific microstructural transformations. Permeability tests were performed using the electrochemical method developed by Devanathan and Stachurski and microhardness was measured before and after these tests. It was observed that hydrogen diffusivity is inversely proportional to microhardness while the density of hydrogen traps is directly proportional to microhardness. The lowest hydrogen diffusivity the highest trap density and the highest microhardness were obtained in the as-quenched condition and the tempering at 286 ◦C for 0.25 h. In contrast tempering at a temperature corresponding to the fourth tempering stage increases hydrogen diffusivity and decreases the density of hydrogen traps and microhardness. However as the tempering time or temperature increases the opposite occurs which is attributed to the formation of alloy carbides. Finally hydrogen has a softening effect for tempering temperatures corresponding to the fourth tempering stage tempering times of 0.25 h and in the as-quenched condition. However with increasing tempering time hydrogen has a hardening effect.
Scaling Green Hydrogen: Production, Storage, Techno-economics and Global Perspectives
Nov 2025
Publication
Hydrogen has emerged as a key green energy carrier for deep decarbonisation offering a viable pathway to reduce emissions from carbon-intensive industries while enabling greater integration of renewable energy source into the global energy system. This study provides a comprehensive review of green hydrogen production technologies storage methods and industrial applications alongside the financial and regulatory landscape shaping its large-scale deployment. From techno-economic viewpoints alkaline electrolysis offers cost advantages at approximately USD 270/kW compared with proton membrane exchange and solid oxide electrolysis. Storage technologies show levelised costs of USD 2.48–15.61/kg H2 with scalability to gigawatt level surpassing battery systems. Hydrogen adoption enables substantial decarbonisation in hard-to-abate sectors with deployments estimated to cut more than 1 Mtonne CO2 emissions annually in steelmaking and more than 100 ktonne in cement production. This study underscores the importance of international cooperation outlining pathways for countries with abundant renewable resources (e.g. Canada Australia) to emerge as major hydrogen producers while nations with strong demand (e.g. Japan South Korea) act as market catalysts. Finally investment dynamics government incentives regulatory frameworks and targeted policy recommendations are reviewed to provide a holistic perspective for building a resilient and sustainable hydrogen ecosystem.
Utilizing Oxygen from Green Hydrogen Production in Wastewater Treatment Plant Aeration: A Techno-economic Analysis
Nov 2025
Publication
The growing demand for green hydrogen is driving the expansion of water electrolysis. The resulting oxygen byproduct offers potential added value when used in sectors with high oxygen demand such as wastewater treatment. This study investigates the techno-economic viability of using electrolysis oxygen to supplement conventional air blowers in the aeration process of municipal wastewater treatment plants (WWTPs) to reduce aeration costs and thereby improve the overall economics of hydrogen production. A comprehensive system model is developed incorporating renewable electricity supply water electrolysis hydrogen compression storage and transport as well as WWTP aeration via conventional air blowers and electrolysis oxygen. Results show that electrolysis oxygen can reduce WWTP aeration costs by up to 68%. If these cost reductions are attributed as a benefit to the hydrogen system they correspond to hydrogen supply cost savings of up to 0.39 EUR/kgH2. However the analysis indicates that economic viability is substantially influenced by factors such as the distance of hydrogen transport from the WWTP to the European Hydrogen Backbone feed-in point which should not exceed 25 km and the alignment between the scale of hydrogen production and the size of the WWTP with cost-effective integration being particularly feasible for larger WWTPs (≥500000 PE).
Hydrogen Utilization for Decarbonizing the Dairy Industry: A Techno-economic Scenario Analysis
Nov 2025
Publication
This study investigates the integration of on-site green hydrogen as a substitute for methane in steam generation in the dairy industry specifically in the production of Parmigiano Reggiano cheese. This represents a novel application of green hydrogen in industrial dairy processing with the potential to reduce greenhouse gas emissions. Hydrogen is assumed to be generated via electrolysis powered by photovoltaic energy. A comprehensive techno-economic assessment was conducted with simulations covering key design variables such as hydrogen fraction in steam production photovoltaic panel orientation and storage pressure. A wide range of scenarios was defined in order to account for variability in system structures and performance and a comprehensive economic assessment was then carried out using a Monte Carlo simulation approach and a sensitivity analysis. Results indicate that in all scenarios the net present value over a 15-year period remains negative when benefits are limited to methane savings. Indeed the high capital expenditure associated with hydrogen systems presents a major barrier. The most favorable cases occur at low hydrogen shares with seasonal storage while full conversion to hydrogen maximizes CO2 abatement but is least economical. With public funding the emissions saved per euro of public support range from 1.58 to 2.14 kg CO2eq/€.
Techno-economic Optimization of Hydrogen-based Hybrid Renewable Energy Systems for Rural Electrification in Sub-Saharan Africa: Case Study of a Photovoltaic/Wind/Hydrogen System in Dargalla, Cameroon
Nov 2025
Publication
Hybrid renewable energy systems (HRESs) are an effective tool for addressing the challenges of rural electrification in sub-Saharan Africa (SSA). However their viability is limited by the lifespan environmental impacts high costs and inefficiency of conventional energy storage technologies (battery and pumped-hydro). This study examines a hydrogen-based energy storage system combined with photovoltaic (PV) and wind energy for the electrification of Dargalla a village in northern Cameroon. The goal is to meet community and agricultural electricity needs while optimizing the system. The analysis utilized HOMER software to simulate model and optimize the system. The optimal architecture consisted of a 50-kW photovoltaic (PV) array a 10-kW wind turbine a 10-kW fuel cell a 30-kW electrolyser a 25-kg hydrogen tank and a 10-kW converter. The optimised system’s net present cost and cost of energy were assessed at USD 138202 and USD 0.443/kWh respectively. Sensitivity analysis results showed that areas with high wind speeds would be mainly suitable for the proposed system. Moreover with the upcoming decrease in the costs of fuel cells and PV components such systems are expected to become more economically viable in the future leading to the conclusion that integration of hydrogen-based energy storage technology in HRESs in SSA can effectively address the United Nations Sustainable Development Goals (UNSDG) and the historic Paris Climate Agreement (HCA).
Decarbonization of Hard-to-abate Industries under Water Constraints via Renewable Hydrogen Infrastructure Planning
Nov 2025
Publication
Achieving global decarbonization is essential to mitigate climate change yet heat-intensive industries remain challenging to decarbonize through electrification alone. Green hydrogen offers a clean alternative to replace fossil fuels and fossil fuel–based hydrogen but its deployment requires careful planning and robust economic assessment. This study addresses the optimal design of a green hydrogen supply chain in a Mediterranean region where ceramics and cement dominate as energy-intensive industries while oil refining is the main consumer of fossil fuel–based hydrogen. The region also faces freshwater scarcity due to its climate and the high demand for water from tourism and agriculture. A Mixed-Integer Linear Programming (MILP) model is developed to minimize the total cost of supplying green hydrogen by determining the optimal size and location of renewable energy sources integrating desalinated seawater from existing desalination plants as feedstock and designing the infrastructure connecting production storage and demand centers. The cost-optimal configuration includes 3.4 GW of PEM electrolyzers requiring 41.1 m3 /h of desalinated seawater supplied by existing desalination plants along with 5.1 GW of wind and 12 GW of solar power as renewable energy sources for large-scale hydrogen production. Results show that supplying green hydrogen to these industries can avoid approximately 4.4 million tons of CO2 emissions annually achieving a levelized cost of hydrogen (LCOH) of $2.18/kg for the period 2030–2050. Beyond this case study the proposed framework provides a replicable methodology for planning hydrogen-based energy systems in regions facing similar water and decarbonization challenges.
Technical and Environmental Assessment of New Green Iron Production Strategies using Hydrogen
Nov 2025
Publication
In order to assess the decarbonization potential and overall environmental benefits of new reduction pathways in the ironmaking industry using hydrogen to produce Direct Reduced Iron (DRI) a coupled approach combining process simulation for rigorous technical and energy evaluation of iron ore conversion and Life Cycle Assessment (LCA) for environmental assessment was developed and extended to two alternative renewable heating strategies: (i) electric gas heating and (ii) solar reactor heating. The entire hydrogen-based ironmaking process including conversion in a shaft reactor gas and solid heating gas recycling and electrolysis was therefore simulated. The hydrogen-based reduction of iron ores in the shaft reactor was modeled using a rigorous reactor model describing the reduction of multi-layer iron ore pellets in countercurrent gas–solid moving beds with the particularity of representing the dual influence of particle size and temperature on conversion. The remainder of the process including gas recycling and hydrogen production was simulated using ProSim software. The hydrogen-based green ironmaking scenarios were then compared to MIDREX NG a leading natural gas-based reduction technology. Hydrogen-based scenarios powered by the French electricity mix reduce carbon footprints by 53 % for electric gas heating and 57 % for solar reactor heating potentially reaching 82 % (− 0.79 kgCO2-eq/kgDRI) with low-carbon electricity (hydro nuclear). Compared to MIDREX NG the energy requirements of both hydrogen-based scenarios are primarily determined by the use of electricity for hydrogen production illustrating the importance of hydrogen production for the assessment of future hydrogen-based green ironmaking.
Heat Transfer Enhancement in Regenerative Cooling Channels: Numerical Analysis of Single- and Double-row Cylindrical Ribs with Supercritical Hydrogen
Nov 2025
Publication
The thermal protection of rocket engine combustion chambers presents a critical challenge in supersonic flight applications. This study numerically investigates the enhancement of heat transfer and coolant flow characteristics in regenerative cooling channels through cylindrical rib integration employing ANSYS Fluent with SST k-ω turbulence modeling to evaluate single- and double-row configurations (0.75–1.25 mm diameter) under supercritical hydrogen conditions (3 MPa 300 K inlet). Results demonstrate that rib-induced turbulence disrupts thermal boundary layers with a 1.25 mm single-row design achieving a 13.67 % reduction in peak wall temperature compared to smooth channels while double-row arrangements show diminishing returns due to increased flow resistance. The thermal performance factor (η = (Nu/Nu₀)/(f/f₀) 1/3) reveals Case 3′s superiority (21.88 % improvement over the smooth channel configuration) in balancing heat transfer enhancement against pressure drop penalties (9.23–20.93 % for single-row 8.26–18.7 % for double-row). Notably density-driven flow acceleration near heated walls mitigates pressure losses through localized viscosity reduction. Furthermore cylindrical ribs reduce thermal stratification by up to 30 % in single-row configurations with double-row designs providing additional temperature homogenization at the cost of increased flow resistance. These findings offer critical insights for optimizing rib-enhanced cooling systems in high-performance rocket engines achieving simultaneous thermal efficiency and hydraulic performance improvements.
In-situ CO2 Capture by DFMs to Enhance Hydrogen Production and Regeneration Performance of Biomass-H2O Gasification
Nov 2025
Publication
Developing green hydrogen energy can alleviate the problem of CO2 emissions caused by excessive use of fossil fuels. In-situ capture of CO2 for enhanced H2 production in zero-carbon energy biomass-H2O gasification can achieve the dual effects of green H2 production and negative carbon. The study used red mud (RM) to modify CaO and prepare dual-functional materials (DFMs). And the in-situ CO2 capture enhanced H2 production and regeneration cycle performance of DFMs in biomass-H2O gasification were studied and the influence of biomass ash on the H2 production and low-temperature (650 ◦C) regeneration performance of DFMs in the cycle was analyzed. The results are as follows: In DFMs catalyzed biomass-H2O gasification due to the continuous deposition of alkali and alkaline earth metals (AAEMs) in biomass ash with increasing cycle times its catalytic effect increased H2 production by 27 % after twenty cycles and the pore structure degradation and cycle stability of DFMs decreased by 44.71 %. DFMs have demonstrated excellent catalytic performance and cycling stability in the catalytic removal of ash from biomass. After twenty cycles the production of H2 only decreased by 20.59 % and the performance of CaO decreased by 26.67 % demonstrating the enormous potential of DFMs for in-situ CO2 capture and enhanced H2 production.
Flame Curvature in Heat-loss-affected Lean Hydrogen Flames: A One-dimensional Manifold Approach
Oct 2025
Publication
Curvature effects are incorporated into a one-dimensional composition-space formulation of a non-unity Lewis number lean premixed flame with strong heat loss. The results of this new canonical problem successfully compare with direct numerical simulations (DNS) of a lean hydrogen-air flame propagating in a narrow channel with heat conduction through the confining plates. The complex dynamics of the flame front consisting of isolated flame kernels are analyzed through the various terms arising from the projection of the fuel and energy equations onto a moving scalar reference frame attached to the reaction zone. Novelty and significance statement A novel one-dimensional flame model incorporating curvature and differential diffusion effects is introduced to address non-unity Lewis number lean premixed flames with strong heat loss. This canonical flame model arises from the projection of temperature and fuel gradient magnitude onto composition space. The framework is employed to analyze flame front dynamics and identify the reaction zones governing flame kernel propagation and heat release. The composition-space flame structure shows strong agreement between the canonical problem and direct numerical simulations (DNS) of a lean hydrogen-air flame propagating in a narrow channel with heat conduction.
Carbon Capture and Storage: A Comprehensive Review on Current Trends, Techniques, and Future Prospects in North America
Nov 2025
Publication
Climate-change mitigation in North America demands rapid deep cuts in carbon-dioxide emissions from hard-toabate industrial power-generation and transport sectors. Carbon capture and storage (CCS) is one of the few technological routes that can decouple continued use of fossil-derived energy and materials from their climate externalities. Yet deployment across the US and Canada still trails the scale implied by regional net-zero pledges. This review addresses that gap by synthesizing technical economic policy and social dimensions of CCS and complements global syntheses with a granular assessment of North America’s unique emission profile infrastructure advantages and regulatory frameworks. Methodologically the review disaggregates the CCS chain into six pillars: (i) current emission baselines; (ii) capture systems icluding post- pre- and oxy-combustion chemical-looping combustion (CLC) and direct air capture (DAC); (iii) capture technologies (e.g. absorption adsorption membrane cryogenic and hybrid processes); (iv) storage pathways (geological oceanic and emerging biological or mineral options); (v) cross-cutting economic policy and social factors; and (vi) deployment status plus future outlook. Post-combustion capture remains the most retrofit-ready option for the region’s ageing coal and gas fleet yet solvent regeneration still imposes energy penalties of 8–10 percentagepoints. Pre-combustion and oxy-fuel routes offer thermodynamic advantages for new-build plants but require high-capex gasifiers or cryogenic air separation units slowing adoption. Emerging CLC and DAC concepts could unlock low-carbon fuels and negative emissions respectively but remain costly and pre-commercial. No single technology meets all performance criteria making hybrid configurations—such as membrane–cryogenic or membrane–amine schemes—particularly promising. North America’s subsurface offers multi-teratonne theoretical storage capacity in saline formations depleted hydrocarbon reservoirs and CO2-EOR sites suggesting physical room is not the bottleneck. Instead economics dominate: levelized capture costs today range from around $15/tCO2 in natural-gas processing to over $120/t in power and cement and long-distance pipeline networks are sparse outside existing enhanced oil recovery (EOR) corridors. Recent federal incentives can shift project economics decisively yet policy volatility and permitting hurdles still threaten investment certainty. Societal acceptance emerges as another critical lever. Surveys reveal generally favorable attitudes toward CCS in principle but heightened opposition to local storage projects. Transparent monitoring–verification frameworks benefit-sharing mechanisms and durable bipartisan policies are therefore essential to secure a “social licence” for large-scale CO2 injection. This review concludes that widescale CCS in North America is technically feasible and increasingly cost-competitive when paired with robust incentives abundant storage capacity and existing pipeline know-how. Realizing its full mitigation potential will hinge on coordinated build-out of transport networks harmonized federal–provincial regulations continued R&D into low-energy capture materials and integrated assessments that weigh CCS alongside renewables efficiency and negative-emission strategies. The roadmap presented herein provides stakeholders with actionable insights to accelerate that transition positioning North America as both a proving ground and a global exemplar for scalable responsibly governed CCS.
Seawater as Feedstock for Large-scale Green Hydrogen Production: A Technical Review from a Desalination Perspective
Nov 2025
Publication
This study examines the technical feasibility of using seawater as a feedstock for green hydrogen production with a focus on system design and water treatment aspects. Both direct and indirect seawater splitting approaches are considered. Direct seawater electrolysis is excluded from further consideration due to unresolved challenges such as parasitic side reactions and electrode degradation. For make-up water generation thermal desalination and seawater reverse osmosis (SWRO) were evaluated. Thermal desalination though potentially powered by waste heat from electrolysis was deemed impractical due to its dependence on the electrolyzer plant’s heat management system which complicates overall plant control. In contrast SWRO operates as a standalone system and imposes minimal impact on hydrogen production costs through competing power consumption making it the preferred option for large-scale applications. Alkaline Water Electrolysis (AWE) and Proton Exchange Membrane (PEM) electrolysis are identified as the only currently available industrial-scale electrolyzer technologies. A Balance of Plant analysis revealed key water treatment interfaces including make-up water systems required for both technologies and a loop purification system specific to PEM systems. A design study translated the identified requirements into practical plant configurations providing a detailed evaluation of treatment options and implementation strategies. The study concluded with an outlook on future water-focused research laying the groundwork for continued advancements in support of large-scale green hydrogen production.
Multi-scale Modeling and Experimental Analysis of Sewage Sludge Gasification: Thermochemical Insights for Hydrogen Production
Nov 2025
Publication
The management of sewage sludge presents a pressing environmental and economic challenge due to its increasing global production and complex hazardous composition. Gasification offers a viable method for converting this waste into valuable energy resources. This study investigates whether integrating experimental and computational techniques can enhance the understanding and optimization of sludge gasification. Two types of sewage sludge SSG from Rethymno and SSD from Dubai were evaluated using an entrained flow gasifier under controlled thermal and flow conditions. The methodology combines equilibrium modeling computational fluid dynamics (CFD) drop tube reactor (DTR) experiments and artificial neural network (ANN) modeling. The ANN was combined with Kissinger analysis to obtain kinetics from the ANN outputs and derive thermodynamic parameters used to enhance CFD fidelity. Gas composition analysis and scanning electron microscopy (SEM) revealed that SSD decomposes more easily with a lower activation energy (42.29–138.31 kJ/mol) and a lower Gibbs free energy. In contrast SSG demonstrated greater thermal stability and reactivity. SSG achieved consistently higher cold gas efficiency (CGE) reaching 53.66 % in equilibrium modeling 45.50 % in CFD and 38.90 % in experiments compared to SSD’s 48.86 % 37.81 % and 31.19 % respectively. SEM imaging confirmed an increase in porosity and surface area for SSG after gasification. These results indicate that the type of sludge has a significant impact on energy recovery and that ANN-calibrated thermokinetics and CFD enhance process predictability. This integrated method scales hydrogen generation and promotes sustainable waste-toenergy technology.
Enhancing Hydrogen Storage hrough Processable Porous Composite Membranes
Nov 2025
Publication
Hydrogen (H2) is a promising energy carrier for decarbonization; however efficient storage remains a key challenge. Porous materials offer potential for enhanced H2 densification and may enable the development of next-generation lightweight storage systems. A major limitation of such materials is their fine powder form which hampers retention and processability. In this study composite membranes comprising a polymer of intrinsic microporosity (PIM-1) matrix and a polytriphenylamine (PTPA)-based conjugated microporous polymer (CMP) filler were developed. The composites are mechanically robust forming self-standing membranes that retain stability under high temperatures and humidity. H2 storage capacities of the membranes showed excess gravimetric uptakes of 1.03 wt% at 1 bar and 1.84 wt% at 50 bar (77 K) with total capacities reaching 3.22 wt% at 100 bar. These values are significantly higher than those of pristine PIM-1 which achieved 0.87 wt% 1.64 wt % and 2.89 wt% under the same conditions. Net adsorption isotherms demonstrate the potential of the composites to outperform conventional compression storage up to 10 bar at 77 K. Additionally the composites exhibit high mass transfer coefficients (3.42 min− 1 ) indicating strong H2 affinity and faster charging rates compared with the pristine PIM-1 membrane (2.79 min− 1 ).
A Critical Review of Cushion Gas in Underground Hydrogen Storage: Thermophysical Properties, Interfacial Interactions, and Numerical Perspectives
Nov 2025
Publication
Underground hydrogen storage (UHS) represents a large-scale energy storage system aiming to ensure a consistent supply by storing hydrogen generated from surplus energy. In the practice of UHS cushion gas is typically injected into the formation to maintain reservoir pressure for efficient hydrogen withdrawal. This paper reviews the impact of cushion gas on the performance of UHS from both experimental and numerical simulation perspectives. The thermophysical (e.g. density viscosity compressibility and solubility) and petrophysical (interfacial tension wettability and relative permeability) properties as well as the mixing and diffusion behavior of different cushion gases were compared. The corresponding impact of different cushion gases on plume migration and trapping potential is then discussed. Furthermore this review critically analyzes and explains the impact of various factors on the performance of UHS including the type of cushion gas the composition of cushion gas mixtures the volume of injected cushion gas and the effects of bio-methanation processes. The corresponding analysis specifically focuses on key performance indicators including H2 recovery factor formation pressure brine production and H2 outflow purity. Thus this review provides a comprehensive analysis of the role of cushion gas in UHS offering insight into the effective management and optimization of cushion gas injection in field-scale UHS operations.
Thermal Energy Integration and Optimization in a Biomass-fueled Multi-generation System for Power, Hydrogen, and Freshwater Production
Nov 2025
Publication
This work investigates a biomass-driven multi-generation system designed for simultaneous power freshwater and hydrogen production addressing the interlinked energy-waterenvironment nexus. The configuration integrates Brayton supercritical carbon dioxide (SCO2) organic Rankine cycle (ORC) and thermoelectric generator (TEG) subsystems to maximize utilization of biomass-derived syngas. The recovered energy drives a reverse osmosis (RO) desalination unit for freshwater production and an alkaline electrolyzer for hydrogen generation followed by two-stage compression for storage. Under baseline conditions the system generates 1.99 MW of electricity 9.38 kg/h of hydrogen and 88.6 m3 /h of freshwater with an overall exergetic efficiency of 20.25 % emissions intensity of 0.85 kg/kWh and a payback period of 5.87 years. The Brayton cycle accounts for 49.3 % of the total cost rate while the gasifier exhibits the highest exergy destruction at 46 %. Sensitivity analyses show that varying biomass moisture content (10–30 %) and operating temperatures (700–900 ◦C) significantly influence system performance. Using a data-driven optimization framework that combines artificial neural networks (ANN) and a genetic algorithm (GA) the system’s exergetic efficiency improves to 21.76 % freshwater output rises to 90.96 m3 /h and emissions intensity decreases to 0.877 kg/kWh. Additionally optimization reduces the total cost rate by 2.71 % leading to a payback period of 5.4 years and enhances the system’s overall performance by 12.64 %.
A Comparative Study Between Small-scale and Large-scale Photovoltaic Hydrogen Production under Tropical Climate: A Case Study in Santo Domingo, Dominican Republican
Nov 2025
Publication
This study investigates the potential of green hydrogen production from small and large-scale photovoltaic water electrolysis systems under tropical climate conditions with particular emphasis on the Levelized Cost of Hydrogen (LCOH) in Santo Domingo Dominican Republic. The hydrogen production system was developed using MATLAB/SIMULINK R2023b. The system simulation incorporates a commercial proton exchange membrane (PEM) electrolyzer driven by a DC/DC converter is also evaluated under varying environmental scenarios based on real meteorological data for temperature and solar irradiance. Dynamic simulations were performed to analyze the relationship between solar resource availability and hydrogen production. Results indicate that at small-scale 3.68 kWp PV + 0.017 kW PEM LCOH is 104.52 USD/kg for PV-only compared to 17.09 USD/kg for a grid sourced electricity case. At large-scale 100 MWp PV + 60 MWe PEM LCOH falls to 7.05 USD/kg under PVonly operation Utilization factor Uf = 0.31 and 3.61 USD/kg with grid supplied backup Uf = 0.85 illustrating the massive cost reduction achievable through economies of scale. Model validation showed a high degree of accuracy with an average percentage error of 1.41 % when comparing simulated and manufacturer provided parameters curves. A comparative carbon footprint analysis demonstrated the environmental advantages of PV driven hydrogen production over conventional fossil fuels methods. These findings are especially relevant for such climates and support the advancement of Sustainable Development Goals 7 and 13 positioning green hydrogen as a key vector for the clean energy transition.
Optimal Possibilistic-robust Operation of Multi-energy Microgrids Considering Infrastructure Hydrogen Storage Capability
Nov 2025
Publication
In sustainable energy transitions the utilization of hydrogen is crucial providing flexibility in the operation of net-zero emission renewable-based energy systems. This paper presents a study on the optimal operation of netzero emission multi-energy future microgrids that utilize hydrogen as an alternative fuel instead of natural gas. The electrolyzers’ output is injected into the hydrogen grid to meet demand or converted back to electricity later using generating units owing to the storage capability of pipes called linepack. For this purpose a detailed mathematical model is developed to simulate the main characteristics of grids (e.g. voltage current hydrogen flow and pressure) as well as various components (e.g. renewable systems electrolyzers and hydrogen-fired units). To become more realistic a possibilistic-robust approach is developed to account for the uncertainty arising from the lack of real-world implementation. By representing a case study a test is performed to evaluate the possibility of employing a low-pressure gas grid to meet the demand for hydrogen. After that the effects of electrolyzers are analyzed in the presence and absence of the uncertainty consideration approach. The result indicates that despite hydrogen’s lower energy density compared to natural gas it is still feasible to satisfy the same energy demand level considering the technical characteristics of the grid. The integration of electrolyzers can reduce wind curtailment by 2 % and supplement hydrogen demand by 50 %. A higher level of conservatism in the possibilistic-robust approach leads to an increase in the mean value of the objective function and a reduction in the standard deviation under the realization of uncertain parameters which provides the decisionmakers with a more realistic insight.
Circular Bioenergy Pathway for Sustainable Hydrogen Production with Carbon Capture: Technical, Economic & Environmental Assessment
Nov 2025
Publication
The accelerating global demand for hydrogen is pushing for renewable and waste derived hydrogen production processes where date palm waste (DPW) has been identified as an available and unexploited agricultural residue that has the potential to be a sustainable source of hydrogen. The current work focuses on developing and evaluating four different process configurations in terms of energy environment and economics for producing hydrogen from DPW using Aspen Plus® simulation tool. Case 1 represents the standalone DPW gasification with CO₂ capture via methanol absorption Case 2 represents the DPW gasification with CaO-based chemical looping for CO₂ capture Case 3 represents the DPW gasification integrated with steam methane reforming (SMR) and methanol-based CO₂ capture and Case 4 represents the DPW gasification integrated with SMR and CaO-based CO₂ capture. Each case was evaluated in terms of syngas composition hydrogen production lower heating value CO₂ captured utility demand process efficiency and H2 production cost. Hydrogen production ranged from 974.55 t/year (Case 1) and 988.83 t/year (Case 2) to 2032.32 t/year (Case 3) and 2048.61 t/year (Case 4). CO₂ capture was also more effective in Case 4 (16929.49 t/year) compared to Case 1 (7676.30 t/year). Process efficiency improved from 33 % in Case 1 to 47 % in Case 2 and from 32 % in Case 3 to further to 55 % in Case 4. Economically Case 1 offered the highest hydrogen production cost ($5.03/kg) followed by Case 2 ($4.77/kg) while Case 3 and Case 4 achieved significantly lower production costs of $2.89/kg and $2.69/kg respectively.
High‑Entropy Amorphous Catalysts for Water Electrolysis: A New Frontier
Sep 2025
Publication
High‐entropy amorphous catalysts (HEACs) integrate multielement synergy with structural disorder making them promising candidates for water splitting. Their distinctive features—including flexible coordination environments tunable electronic structures abundant unsaturated active sites and dynamic structural reassembly—collectively enhance electrochemical activity and durability under operating conditions. This review summarizes recent advances in HEACs for hydrogen evolution oxygen evolution and overall water splitting highlighting their disorder-driven advantages over crystalline counterparts. Catalytic performance benchmarks are presented and mechanistic insights are discussed focusing on how multimetallic synergy amorphization effect and in‐situ reconstruction cooperatively regulate reaction pathways. These insights provide guidance for the rational design of next‐generation amorphous high‐entropy electrocatalysts with improved efficiency and durability.
OH* Chemiluminescence in Non-premixed Industrial Natural Gas/hydrogen Flames under Air-fuel and Oxy-fuel Conditions: Kinetic Modeling and Experimental Validation
Oct 2025
Publication
The application of OH* chemiluminescence diagnostics is becoming increasingly prevalent in the combustion characterization of hydrogen. As the current literature is lacking a systematic study of OH* chemiluminescence in non-premixed turbulent natural gas (NG) and hydrogen (H2 ) flames the present work was designed to address this research gap. Therefore extensive experiments were performed on a semi-industrial burner operating at 50–100 kW in NG/H2–Air/O2 combustion modes which were complemented by comprehensive numerical simulations including 1D laminar counterflow diffusion flamelet calculations and full 3D CFD simulations of the semi-industrial furnace setup. In this way an OH* chemistry model is presented that accurately predicts the global reaction zone characteristics and their difference between CH4 and H2 in air-fired and oxygen-fired flames. The comprehensive numerical approach in conjunction with the subsequent study of different operating conditions yielded novel insights into both combustion modeling and the underlying thermochemical phenomena providing an essential contribution to the transition of the thermal energy sector towards hydrogen as an alternative carbon-free fuel.
Towards the Decarbonization of the Maritime Industry: Design of a Novel Methodology for the Sustainable Strategy Assessment
Oct 2025
Publication
The growing concern about the increase in European Union (EU)’s total CO2 emissions due to maritime activities and the ambitious goal of net zero emissions they are asked to fulfil by 2050 are leading the way to the adoption of new sustainable strategies. In this article a novel methodology for the classification of the sustainable actions is proposed. Moreover new indicators have been designed to compare the level of sustainable development of each port. Among them a new coefficient for the assessment of the Ports’ Potential Sustainability (PPS) have been designed. Main results showed that 56% of the actions were in the improvement and environmentally sustainable group while 19% were shift-economic actions related to the installation of technologies. As a matter of the fact all European ports under analysis have adopted cold ironing system which can reduce up to 4% of the global shipping emissions. Similarly 50% of them have already integrated renewables energies and prioritize equipment electrification in their processes. Finally the most relevant projects to optimize the energy consumption of daily operations and the main challenges that still need to be addressed have been analyzed showing the current trends maritime sector is undertaking to advance towards the sustainable development.
Life Cycle and Economic Viability Assessment of Clean Hydrogen as a Fuel in Corn Drying
Oct 2025
Publication
This study presents a comparative life cycle and economic assessment of using clean hydrogen as a sustainable alternative to natural gas and propane for corn grain drying. The study compares the environmental performance limited to GWP100 and cost-effectiveness of hydrogen from various renewable sources (hydro wind solar) and plasma pyrolysis of natural gas against conventional fossil fuels under two delivery scenarios: pipeline and trucking. A life cycle assessment is conducted using Open LCA to quantify the carbon intensity of each fuel from cradle to combustion at multiple energy requirements based on four burner efficiencies across each scenario. In parallel economic analysis is conducted by calculating the fuel cost required per ton of dried corn grains at each efficiency across both scenarios. The results indicate that green hydrogen consistently outperforms current fuels in terms of emissions but it is generally more expensive at lower burner efficiencies and in trucking scenarios. However the cost competitiveness of green hydrogen improves significantly at higher efficiency and with pipeline infrastructure development it can become more economical when compared to propane. Hydrogen produced via plasma pyrolysis offers high environmental and economic costs due to its electricity and natural gas requirements. Sensitivity analysis further explores the impact of a 50% reduction in hydrogen production and transportation costs revealing that hydrogen could become a viable option for grain drying in both pipeline and trucking scenarios. This study highlights the long-term potential of hydrogen in reducing carbon emissions and offers insights into the economic feasibility of hydrogen adoption in agricultural drying processes. The findings suggest that strategic investments in hydrogen infrastructure could significantly enhance the sustainability of agricultural practices paving the way for a greener future in food production.
Advanced Analytical Modeling of Polytropic Gas Flow in Pipelines: Unifying Flow Regimes for Efficient Energy Transport
Oct 2025
Publication
In the present work a new analytical model of polytropic flow in constant-diameter pipelines is developed to accurately describe the flow of compressible gases including natural gas and hydrogen explicitly accounting for heat exchange between the fluid and the environment. In contrast to conventional models that assume isothermal or adiabatic conditions the proposed model simultaneously accounts for variations in pressure temperature density and entropy i.e. it is based on a realistic polytropic gas flow formulation. A system of differential equations is established incorporating the momentum continuity energy and state equations of the gas. An implicit closed-form solution for the specific volume along the pipeline axis is then derived. The model is universal and allows the derivation of special cases such as adiabatic isothermal and isentropic flows. Numerical simulations demonstrate the influence of heat flow on the variation in specific volume highlighting the critical role of heat exchange under real conditions for the optimization and design of energy systems. It is shown that achieving isentropic flow would require the continuous removal of frictional heat which is not practically feasible. The proposed model therefore provides a clear reproducible and easily visualized framework for analyzing gas flows in pipelines offering valuable support for engineering design and education. In addition a unified sensitivity analysis of the analytical solutions has been developed enabling systematic evaluation of parameter influence across the subsonic near-critical and heated flow regimes.
Decarbonised H2 Recovery and CO2 Capture Using a Cost-effective Membrane Plant: A Step Towards Energy Transition
Oct 2025
Publication
Separation of H2 from CO2 is crucial in industry since they are the products of water gas shift reaction. In addition the demand for pure H2 as well as the potential reuse of CO2 as reactant are increasing as a consequence of the transition from fossil fuels to decarbonization processes. In this scenario this work aims to propose a possible solution to get simultaneously pure H2 and CO2 meeting the world’s requirements in terms of reduction of CO2 emissions and transition to cleaner energy. A simulated plant combining Pd-based and SAPO-34 membrane modules is able to provide pure H2 with a final recovery higher than 97%. In addition the entire CO2 fed to SAPO-34 unit is recovered in the permeate stream with a concentration of 97.7%. A cost analysis shows that feed gas gives a higher contribution than compression heat exchange and membranes (e.g. 70 20 3 and 7% respectively). Net profit and net present value are positive within a specific feed gas price range (e.g. net profit up to 0.10 and 0.155 $/Nm3 depending on the labour cost set) showing that the process can be cost-effective and profitable. H2 purification cost ranges between 2.6 and 7.8 $/kg.
Hydrogen Strategies Under Uncertainty: Risk-Averse Choices for Green Hydrogen Pathways
Oct 2025
Publication
The last decade has been characterized by a growing environmental awareness and the rise of climate change concerns. Continuous advancement of renewable energy technologies in this context has taken a central stage on the global agenda leading to a diverse array of innovations ranging from cutting-edge green energy production technologies to advanced energy storage solutions. In this evolving context ensuring the sustainability of energy systems—through the reduction of carbon emissions enhancement of energy resilience and responsible resource integration—has become a primary objective of modern energy planning. The integration of hydrogen technologies for power-to-gas (P2G) and power-topower (P2P) and energy storage systems is one of the areas where the most remarkable progress is being made. However real case implementations are lagging behind expectations due to large-scale investments needed which under high energy price uncertainty act as a barrier to widespread adoption. This study proposes a risk-averse approach for sizing an Integrated Hybrid Energy System considering the uncertainty of electricity and gas prices. The problem is formulated as a mixed-integer program and tested on a real-world case study. The analysis sheds light on the value of synergies and innovative solutions that hold the promise of a cleaner more sustainable future for generations to come.
Modeling Hydrogen-Assisted Combustion of Liquid Fuels in Compression-Ignition Engines Using a Double-Wiebe Function
Oct 2025
Publication
This article discusses the potential of using the double-Wiebe function to model combustion in a compression-ignition engine fueled by diesel fuel or its substitutes such as hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) and hydrogen injected into the engine intake manifold. The hydrogen amount ranged from 0 to 35% of the total energy content of the fuels burned. It was found that co-combustion of liquid fuel with hydrogen is characterized by two distinct combustion phases: premixed and diffusion combustion. The premixed phase occurring just after ignition is characterized by a rapid combustion rate which increases with an increase in hydrogen injected. The novelty in this work is the modified formula for a double-Wiebe function and the proposed parameters of this function depending on the amount of hydrogen added for co-combustion with liquid fuel. To model this combustion process the modified double-Wiebe function was proposed which can model two phases with different combustion rates. For this purpose a normalized HRR was calculated and based on this curve coefficients for the double-Wiebe function were proposed. Satisfactory consistency with the experiment was achieved at a level determined by the coefficient of determination (R-squared) of above 0.98. It was concluded that the presented double-Wiebe function can be used to model combustion in 0-D and 1-D models for fuels: RME and HVO with hydrogen addition.
Numerical Study of Liquid Hydrogen Internal Flow in Liquid Hydrogen Storage Tank
Oct 2025
Publication
As a key zero-carbon energy carrier the accurate measurement of liquid hydrogen flow in its industrial chain is crucial. However the ultra-low temperature ultra-low density and other properties of liquid hydrogen can introduce calibration errors. To enhance the measurement accuracy and reliability of liquid hydrogen flow this study investigates the heat and mass transfer within a 1 m3 non-vented storage tank during the calibration process of a liquid hydrogen flow standard device that integrates combined dynamic and static gravimetric methods. The vertical tank configuration was selected to minimize the vapor–liquid interface area thereby suppressing boil-off gas generation and enhancing pressure stability which is critical for measurement accuracy. Building upon research on cryogenic flow standard devices as well as tank experiments and simulations this study employs computational fluid dynamics (CFD) with Fluent 2024 software to numerically simulate liquid hydrogen flow within a non-vented tank. The thermophysical properties of hydrogen crucial for the accuracy of the phase-change simulation were implemented using high-fidelity real-fluid data from the NIST Standard Reference Database as the ideal gas law is invalid under the cryogenic conditions studied. Specifically the Lee model was enhanced via User-Defined Functions (UDFs) to accurately simulate the key phasechange processes involving coupled flash evaporation and condensation during liquid hydrogen refueling. The simulation results demonstrated good agreement with NASA experimental data. This study systematically examined the effects of key parameters including inlet flow conditions and inlet liquid temperature on the flow characteristics of liquid hydrogen entering the tank and the subsequent heat and mass transfer behavior within the tank. The results indicated that an increase in mass flow rate elevates tank pressure and reduces filling time. Conversely a decrease in the inlet liquid hydrogen temperature significantly intensifies heat and mass transfer during the initial refueling stage. These findings provide important theoretical support for a deeper understanding of the complex physical mechanisms of liquid hydrogen flow calibration in non-vented tanks and for optimizing calibration accuracy.
Insights from Swirl Number and Ambient Pressure Variations with a Hydrogen/Ammonia Swirl Stabilized Diffusion Flame
Oct 2025
Publication
Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion with marked changes in thermochemical properties leading to significant issues such as limited operational range flashback and instability particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated highlighting the intricate interplay between swirling flow structures and reaction kinetics which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions diminishing past ~0.3 MPa with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data generated using Detached Eddy Simulations (DES) were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames contributing to the development of cleaner combustion technologies.
Hybrid Renewable Energy Systems for Off-Grid Electrification: A Comprehensive Review of Storage Technologies, Metaheuristic Optimization Approaches and Key Challenges
Nov 2025
Publication
Hybrid Renewable Energy Systems (HRESs) are a practical solution for providing reliable low-carbon electricity to off-grid and remote communities. This review examines the role of energy storage within HRESs by systematically comparing electrochemical mechanical thermal and hydrogen-based technologies in terms of technical performance lifecycle cost operational constraints and environmental impact. We synthesize findings from implemented off-grid projects across multiple countries to evaluate real-world performance metrics including renewable fraction expected energy not supplied (EENS) lifecycle cost and operation & maintenance burdens. Special attention is given to the emerging role of hydrogen as a long-term and cross-sector energy carrier addressing its technical regulatory and financial barriers to widespread deployment. In addition the paper reviews real-world implementations of off-grid HRES in various countries summarizing practical outcomes and lessons for system design and policy. The discussion also includes recent advances in metaheuristic optimization algorithms which have improved planning efficiency system reliability and cost-effectiveness. By combining technological operational and policy perspectives this review identifies current challenges and future directions for developing sustainable resilient and economically viable HRES that can accelerate equitable electrification in remote areas. Finally the review outlines key limitations and future directions calling for more systematic quantitative studies long-term field validation of emerging technologies and the development of intelligent Artificial Intelligence (AI)-driven energy management systems within broader socio-techno-economic frameworks. Overall this work offers concise insights to guide researchers and policymakers in advancing the practical deployment of sustainable and resilient HRES.
The Energy Transition in Colombia: Government Projections and Realistic Scenarios
Nov 2025
Publication
Energy transition is crucial for climate change mitigation and Sustainable Development Goals (SDGs) and has been a key government focus in Colombia since 2022 which must carefully consider its energy roadmap. This study evaluates three potential scenarios for achieving nearly 100% renewable energy by 2035: replacing fossil fuels with biofuels using hydrogen for transport and industrial heat and relying entirely on renewable electricity. This paper discusses these scenarios’ technical economic and social challenges including the need for substantial investments in renewable energy technologies and energy storage systems to replace fossil fuels. The discussion highlights the importance of balancing energy security environmental concerns and economic growth while addressing social priorities such as poverty eradication and access to healthcare and education. The results show that while the Colombian government’s energy transition goals are commendable a rapid energy transition requires 4 to 8 times the government’s projected 34 billion USD investment making it economically unfeasible. Notably focusing on wind photovoltaic and green hydrogen systems which need storage is too costly. Furthermore replacing fossil fuels in transport is impractical though increasing biofuel production could partially substitute fossil fuels. Less energy-intensive alternatives like trains and waterway transport should be considered to reduce energy demand and carbon footprint.
Enhancing Regional Integrated Energy Systems Through Seasonal Hydrogen Storage: Insights from a Stackelberg Game Model
Nov 2025
Publication
This study enhances regional integrated energy systems by proposing a Stackelberg planning–operation model with seasonal hydrogen storage addressing source–network separation. An equilibrium algorithm is developed that integrates a competitive search routine with mixed-integer optimization. In the price–energy game framework the hydrogen storage operator is designated as the leader while energy producers load aggregators and storage providers act as followers facilitating a distributed collaborative optimization strategy within the Stackelberg game. Using an industrial park in northern China as a case study the findings reveal that the operator’s initiative results in a revenue increase of 38.60% while producer profits rise by 6.10% and storage-provider profits surge by 108.75%. Additionally renewable accommodation reaches 93.86% reflecting an absolute improvement of 20.60 percentage points. Total net energy imbalance decreases by 55.70% and heat-loss load is reduced by 31.74%. Overall the proposed approach effectively achieves cross-seasonal energy balancing and multi-party gains providing an engineering-oriented reference for addressing energy imbalances in regional integrated energy systems.
Hydrogen Blending as a Transitional Solution for Decarbonizing the Jordanian Electricity Generation Sector
Nov 2025
Publication
While renewable energy deployment has accelerated in recent years fossil fuels continue to play a dominant role in electricity generation worldwide. This necessitates the development of transitional strategies to mitigate greenhouse gas emissions from this sector while gradually reducing reliance on fossil fuels. This study investigates the potential of blending green hydrogen with natural gas as a transitional solution to decarbonize Jordan’s electricity sector. The research presents a comprehensive techno-economic and environmental assessment evaluating the compatibility of the Arab Gas Pipeline and major power plants with hydrogen–natural gas mixtures considering blending limits energy needs environmental impacts and economic feasibility under Jordan’s 2030 energy scenario. The findings reveal that hydrogen blending between 5 and 20 percent can be technically achieved without major infrastructure modifications. The total hydrogen demand is estimated at 24.75 million kilograms per year with a reduction of 152.7 thousand tons of carbon dioxide per annum. This requires 296980 cubic meters of water per year equivalent to only 0.1 percent of the National Water Carrier’s capacity indicating a negligible impact on national water resources. Although technically and environmentally feasible the project remains economically constrained requiring a carbon price of $1835.8 per ton of carbon dioxide for economic neutrality.
Hydrothermal Treatment of Kitchen Waste as a Strategy for Dark Fermentation Biohydrogen Production
Nov 2025
Publication
This study presents an innovative approach to the production of hydrogen from liquids following hydrothermal treatment of biowaste offering a potential solution for renewable energy generation and waste management. By combining biological and hydrothermal processes the efficiency of H2 production can be significantly improved contributing to a reduced carbon footprint and lower reliance on fossil fuels. The inoculum used was fermented sludge from a wastewater treatment plant which had been thermally pretreated to enhance microbial activity towards hydrogen production. Kitchen waste consisting mainly of plant-derived materials (vegetable matter) was used as a substrate. The process was conducted in batch 1-L bioreactors. The results showed that higher pretreatment temperatures (up to 180 ◦C) increased the hydrolysis of compounds and enhanced H2 production. However temperatures above 180 ◦C resulted in the formation of toxic compounds such as catechol and hydroquinone which inhibited H2 production. The highest hydrogen production was achieved at 180 ◦C (approximately 66 mL H2/gTVSKW). The standard Gompertz model was applied to describe the process kinetics and demonstrated an excellent fit with the experimental data (R2 = 0.99) confirming the model’s suitability for optimizing H2 production. This work highlights the potential of combining hydrothermal and biological processes to contribute to the development of sustainable energy systems within the circular economy.
Green Hydrogen Market and Green Cryptocurrencies: A Dynamic Correlation Analysis
Nov 2025
Publication
The urgent need to mitigate climate change has elevated green hydrogen as a sustainable alternative to fossil fuels while green cryptocurrencies have emerged to address the environmental concerns of traditional cryptocurrency mining. This study investigates the dynamic correlation between the green hydrogen market and selected green cryptocurrencies (Cardano Stellar Hedera Algorand and Chia) from July 2021 to April 2024 utilizing the Dynamic Conditional Correlation GARCH (DCC-GARCH) model with robustness checks using EGARCH and GJR-GARCH specifications. Our findings reveal significant correlations with peaks reaching up to 50% in 2022 a period likely influenced by the Russia-Ukraine conflict. Subsequently a decline in these correlations was observed in 2023. These results underscore the interconnectedness of sustainability-driven markets suggesting potential contagion effects during periods of global instability. The high persistence of correlation shocks (α + β values approaching unity) indicates that correlation regimes tend to be long- lasting with important implications for portfolio diversification and risk management strategies. Robustness checks using EGARCH and GJR-GARCH specifications confirmed qualitatively similar patterns reinforcing the validity of our findings into the evolving landscape of green finance and energy
Application of Machine Learning and Data Augmentation Algorithms in the Discovery of Metal Hydrides for Hydrogen Storage
Nov 2025
Publication
The development of efficient and sustainable hydrogen storage materials is a key challenge for realizing hydrogen as a clean and flexible energy carrier. Among various options metal hydrides offer high volumetric storage density and operational safety yet their application is limited by thermodynamic kinetic and compositional constraints. In this work we investigate the potential of machine learning (ML) to predict key thermodynamic properties—equilibrium plateau pressure enthalpy and entropy of hydride formation—based solely on alloy composition using Magpie-generated descriptors. We significantly expand an existing experimental dataset from ~400 to 806 entries and assess the impact of dataset size and data augmentation using the PADRE algorithm on model performance. Models including Support Vector Machines and Gradient Boosted Random Forests were trained and optimized via grid search and cross-validation. Results show a marked improvement in predictive accuracy with increased dataset size while data augmentation benefits are limited to smaller datasets and do not improve accuracy in underrepresented pressure regimes. Furthermore clustering and cross-validation analyses highlight the limited generalizability of models across different material classes though high accuracy is achieved when training and testing within a single hydride family (e.g. AB2). The study demonstrates the viability and limitations of ML for accelerating hydride discovery emphasizing the importance of dataset diversity and representation for robust property prediction.
Performance Analysis of Natural Gas Centrifugal Compressors Under Hydrogen-Blended Conditions
Nov 2025
Publication
The transport of natural gas blended with hydrogen is a key strategy for the low-carbon energy transition. However the influence mechanism of its thermo-physical property variations on centrifugal compressor performance remains insufficiently understood. This study systematically investigates the effects of the hydrogen blending ratio (HBR 0–30%) inlet temperature and rotational speed on key compressor parameters (pressure ratio polytropic efficiency and outlet temperature) through numerical simulations. In order to evaluate the influence of hydrogen blending on the performance and stability of centrifugal compressors a three-dimensional model of the compressor was established and the simulation conducted was verified with the experimental data. Results indicate that under constant inlet conditions both the pressure ratio and outlet temperature decrease with increasing HBR while polytropic efficiency remains relatively stable. Hydrogen blending significantly expands the surge margin shifting both surge and choke lines downward and consequently reducing the stable operating range by 27.11% when hydrogen content increases from 0% to 30%. This research provides theoretical foundations and practical guidance for optimizing hydrogen-blended natural gas centrifugal compressor design and operational control.
Green Hydrogen as a Decarbonization Pathway for Steel Industry in Pakistan
Nov 2025
Publication
The global steel industry emits 1.92 tons of CO2 per ton of output and faces urgent pressure to decarbonize. In Pakistan the sector accounts for 0.29 tons of CO2 per ton of output with limited mitigation frameworks in place. Green hydrogen (GH2)-based steelmaking offers a strategic pathway toward decarbonization. However realizing its potential depends on access to renewable energy. Despite Pakistan’s substantial technical wind potential of 340 GW grid limitations currently restrict wind power to only 4% of national electricity generation. This study explores GH2 production through sector coupling and power wheeling repurposing curtailed wind energy from Sindh to supply Karachi’s steel industry and proposing a phased roadmap for GH enabling fossil fuel substitution industrial resilience and alignment with global carbon-border regulations.
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